Platinum tetrachloride supplier

Name
Platinum tetrachloride
EINECS 236-645-1
CAS No. 13454-96-1
Article Data76
CAS DataBase
Density 4.303 g/cm³
Solubility 587 g/L (25 °C) in water
Melting Point 370 °C
Formula PtCl₄
Boiling Point
Molecular Weight 336.892
Flash Point
Transport Information UN 2923 8/PG 3
Appearance brown/red crystals
Safety 26-27-36/37/39-45-24-22
Risk Codes 22-34-42/43
Molecular Structure
Hazard Symbols C
Synonyms Platinumchloride (PtCl4) (6CI,7CI,8CI);Platinum(IV) chloride;Platinum(IV) tetrachloride;Tetrachloroplatinum;
PSA 0.00000
LogP 2.75550

Synthetic route

: 7791-25-5
sulfuryl dichloride

: 7440-06-4
platinum

: 13454-96-1
platinum(IV) chloride

Conditions

Conditions	Yield
In neat (no solvent) heating for some days to 150°C;;
In neat (no solvent) some days (150°C); platinum wire;;
In neat (no solvent) heating for some days to 150°C;;

: 7647-01-0
hydrogenchloride

: 7440-06-4
platinum

: 13454-96-1
platinum(IV) chloride

Conditions

Conditions	Yield
With tris-(2-chloro-ethyl)-amine In not given byproducts: NH3, N2; Pt is dissolved in a mixture of HCl and HN3;;
With HN3 In not given byproducts: NH3, N2; Pt is dissolved in a mixture of HCl and HN3;;

: 7782-50-5
chlorine

: 7440-06-4
platinum

: 13454-96-1
platinum(IV) chloride

Conditions

Conditions	Yield
In neat (no solvent) at 1700°C;;
In neat (no solvent) High Pressure; Pt metal reacted with Cl2 under pressure 50 atm in thick-wall quartz tube at 200°C for 5 d; XRD, IR, elem. anal.;
In neat (no solvent) at 1700°C;;

: 7782-50-5
chlorine

: 7440-06-4
platinum

A: 25909-39-1
platinum trichloride

B: 13454-96-1
platinum(IV) chloride

Conditions

Conditions	Yield
In neat (no solvent) platinum black is heated in a Cl2 stream to 360°C, fast cooling;;
In neat (no solvent) platinum black is heated in a Cl2 stream to 360°C, fast cooling;;

...Expand

: 10025-99-7
potassium tetrachloroplatinate(II)

: 13454-96-1
platinum(IV) chloride

Conditions

Conditions	Yield
With CoW12O40(5-) In water Kinetics; byproducts: CoW12O40(6-); oxidation of Pt(II) by Co(III)W12O40(5-) in H2O at 25.0°C; mechanism discussed; not isolated, detected by UV spectroscopy;

: 7790-46-7
platinum tetraiodide

A: dihydrogen hexachloroplatinate

B: 7553-56-2
iodine

C: 7790-99-0
Iodine monochloride

D: 13454-96-1
platinum(IV) chloride

Conditions

Conditions	Yield
With chlorine In water composition of product depends on amount of Cl2;
With Cl2 In water composition of product depends on amount of Cl2;

...Expand

: 7790-46-7
platinum tetraiodide

A: 7790-99-0
Iodine monochloride

B: 13454-96-1
platinum(IV) chloride

Conditions

Conditions	Yield
With chlorine in cold Cl2 flow;
With Cl2 in cold Cl2 flow;

: platinum(IV) chloride pentahydrate

: 13454-96-1
platinum(IV) chloride

Conditions

Conditions	Yield
byproducts: H2O; heating in vacuum at 215°C over KOH;
at 215°C in vacuum over KOH;
byproducts: H2O; heating in vacuum at 215°C over KOH;
at 215°C in vacuum over KOH;

: platinum diselenide

: 13454-96-1
platinum(IV) chloride

Conditions

Conditions	Yield
With chlorine in Cl2 flow at 300°C;	0%
With Cl2 in Cl2 flow at 300°C;	0%

: platinum diselenide

: 7784-34-1
arsenic trichloride

: 13454-96-1
platinum(IV) chloride

Conditions

Conditions	Yield
at 300°C;	0%
at 300°C;	0%

: 15619-71-3
PtCl2I2

: 7790-99-0
Iodine monochloride

A: 7553-56-2
iodine

B: 13454-96-1
platinum(IV) chloride

...Expand

: β-platinum(II) chloride

: 13454-96-1
platinum(IV) chloride

Conditions

Conditions	Yield
In neat (no solvent) heating (270 or 350°C, 24 h);

: 164793-21-9
barium platinum(IV) chloride

A: 13454-96-1
platinum(IV) chloride

B: 7440-06-4
platinum

C: barium(II) chloride

Conditions

Conditions	Yield
byproducts: Cl2; glow;
byproducts: Cl2; glow;

...Expand

: barium platinum(IV) chloride*6H2O

A: 13454-96-1
platinum(IV) chloride

B: barium(II) chloride

Conditions

Conditions	Yield
With water
With ethanol boiling;
With methanol

: magnesium platinum(IV) chloride*6H2O

: 13454-96-1
platinum(IV) chloride

Conditions

Conditions	Yield
In methanol byproducts: MgCl2;
In ethanol byproducts: MgCl2;
In methanol byproducts: MgCl2;
In ethanol byproducts: MgCl2;

: calcium platinum(IV) chloride*8H2O

: 13454-96-1
platinum(IV) chloride

Conditions

Conditions	Yield
With ethanol byproducts: CaCl2;
With methanol byproducts: CaCl2;
With ethanol byproducts: CaCl2;
With methanol byproducts: CaCl2;

: lead(II) platinum(IV) chloride*3H2O

A: 13454-96-1
platinum(IV) chloride

B: lead(II) chloride

Conditions

Conditions	Yield
In water partial decompn. in H2O soln.;
With ethanol
In water partial decompn. in H2O soln.;
With ethanol

: 7784-34-1
arsenic trichloride

: 7440-06-4
platinum

: 13454-96-1
platinum(IV) chloride

Conditions

Conditions	Yield
in a sealed tube;
in a sealed tube;

: 7782-49-2
selenium

: 7784-34-1
arsenic trichloride

: 7440-06-4
platinum

: 13454-96-1
platinum(IV) chloride

Conditions

Conditions	Yield
With chlorine heating in Cl2 flow for 0.5 h, then in a sealed tube at 250°C for more h; after selection of AsCl3 heating 1 h at 360°C in Cl2 flow; at 100°C in vacuum from AsCl3; at 200°C from SeCl4;
With Cl2 heating in Cl2 flow for 0.5 h, then in a sealed tube at 250°C for more h; after selection of AsCl3 heating 1 h at 360°C in Cl2 flow; at 100°C in vacuum from AsCl3; at 200°C from SeCl4;

...Expand

: ammonium hexachloroplatinate

: 13454-96-1
platinum(IV) chloride

Conditions

Conditions	Yield
With chlorine In neat (no solvent) byproducts: HCl, N2; loss of 12.23 wt.-% on heating at 360°C in stream of Cl2 for 5 hours;;
With Cl2 In neat (no solvent) byproducts: HCl, N2; loss of 12.23 wt.-% on heating at 360°C in stream of Cl2 for 5 hours;;

: potassium hexachloropalatinate(IV)

: 13454-96-1
platinum(IV) chloride

Conditions

Conditions	Yield
platinum In water byproducts: HCl; hydrolysis; establishment of equil. in darkness: 0.01-0.005 M aq. K2(PtCl6) soln. at 20°C within 200 days, no remarkable decompn. of 0.0025 M or more diluted soln. within 0.5 years; catalyst: Pt black; autocatalysis by hydrolysis product;;
In water byproducts: HCl; Irradiation (UV/VIS); hydrolysis, equil. reaction; establishment of equil. of 0.0025 M ore more diluted aq. K2(PtCl6) soln. within 2 days; reaction rate depends on intensity of light and autocatalysis of hydrolysis product;;
platinum In water byproducts: HCl; hydrolysis; establishment of equil. in darkness: 0.01-0.005 M aq. K2(PtCl6) soln. at 20°C within 200 days, no remarkable decompn. of 0.0025 M or more diluted soln. within 0.5 years; catalyst: Pt black; autocatalysis by hydrolysis product;;
In water byproducts: HCl; Irradiation (UV/VIS); hydrolysis, equil. reaction; establishment of equil. of 0.0025 M ore more diluted aq. K2(PtCl6) soln. within 2 days; reaction rate depends on intensity of light and autocatalysis of hydrolysis product;;

: dihydrogen hexachloroplatinate

: 13454-96-1
platinum(IV) chloride

Conditions

Conditions	Yield
With H2SO4 In not given in concd. soln.;
With sulfuric acid In not given in concd. soln.;

: 10026-03-6
selenium tetrachloride

: 7440-06-4
platinum

: 13454-96-1
platinum(IV) chloride

: dihydrogen hexachloroplatinate(IV) hexahydrate

: 13454-96-1
platinum(IV) chloride

Conditions

Conditions	Yield
With potassium hydroxide; chlorine byproducts: H2O; drying in vacuum over KOH for more d; then heating for 5 h in vacuum at 170°C over KOH;
at higher temp.;
decompn. at 110°C;

: dihydrogen hexachloroplatinate(IV) hexahydrate

A: 13454-96-1
platinum(IV) chloride

B: 7440-06-4
platinum

Conditions

Conditions	Yield
at 150°C for 24 h; formation of PtCl2is poor;
at 150°C for 24 h; formation of PtCl2is poor;

: dihydrogen hexachloroplatinate(IV) hexahydrate

A: 13454-96-1
platinum(IV) chloride

B: platinum(II) chloride

Conditions

Conditions	Yield
heating in dry air at 200°C for 4.5 h;
With hydrogenchloride in HCl flow, between 170 and 200°C; at 165°C only PtCl4 formed;
With HCl in HCl flow, between 170 and 200°C; at 165°C only PtCl4 formed;
heating in dry air at 200°C for 4.5 h;

: dihydrogen hexachloroplatinate(IV) hexahydrate

: 7782-50-5
chlorine

: 13454-96-1
platinum(IV) chloride

Conditions

Conditions	Yield
In neat (no solvent, solid phase) Pt compd. heated in corundum crucible in a quartz tube under Cl2 stream up to 513 K for 2-3 h;
In neat (no solvent, solid phase) H2PtCl6*6H2O in chlorine decomposed at 493 K for 8-10 h according to G. Brauer, Handbuch der Preparativen Anorganischen Chemie, Ferdinand Enke Verlag, Stuttgart, 1956; elem. anal.;

: sodium hexachloroplatinate

: 13454-96-1
platinum(IV) chloride

Conditions

Conditions	Yield
In ethanol byproducts: NaCl; partial decompn. of Na2(PtCl6) on boiling ethanolic soln. by presence of ether;;
In ethanol byproducts: NaCl; decompn. on boiling in ethanol;;
In ethanol byproducts: NaCl; partial decompn. of Na2(PtCl6) on boiling ethanolic soln. by presence of ether;;
In ethanol byproducts: NaCl; decompn. on boiling in ethanol;;

: 25909-39-1
platinum trichloride

: 13454-96-1
platinum(IV) chloride

Conditions

Conditions	Yield
With chlorine in Cl2 (1 atm) at 364°C it is an equilibrium;
With Cl2 in Cl2 (1 atm) at 364°C it is an equilibrium;

: 13454-96-1
platinum(IV) chloride

: 7439-95-4
magnesium

: 7440-06-4
platinum

Conditions

Conditions	Yield
In water reduction with Mg in neutral or acidic soln.;	100%
In water reduction with Mg in neutral or acidic soln.;	100%
In water reaction in neutral and acid solutions complete;;

: 90388-43-5
closo-1-Sn-2-(SiMe3)-3-(SiMe3)-2,3-C2B4H4

: 13454-96-1
platinum(IV) chloride

: 150378-21-5
1,2-bis(trimethylsilyl)-1,2-dicarba-closo-hexaborane(6)

Conditions

Conditions	Yield
In benzene byproducts: SnCl2, Pt; Sn-compd. soln. poured in react. flask with PtCl4 (vac., -23°C); warming (room temp.); monitoring by (11)B-NMR; volatiles fractionation, trap at -45°C collection of B-compd.; elem. anal.; residue in react. flask dissoln. (THF), soln. filtration, THF removal from filtrate, residue drying (80°C, vac.) gave solid SnCl2;	98%
In hexane Sn-compd. soln. poured in react. flask with PtCl4 (vac., -23°C); warming (room temp.); monitoring by (11)B-NMR; volatiles fractionation, trap at -45°C collection of B-compd.; elem. anal.; residue in react. flask dissoln. (THF), soln. filtration, THF removal from filtrate, residue drying (80°C, vac.) gave solid SnCl2;	98%
In chloroform byproducts: SnCl2, Pt; Sn-compd. soln. poured in react. flask with PtCl4 (vac., -23°C); warming (room temp.); monitoring by (11)B-NMR; volatiles fractionation, trap at -45°C collection of B-compd.; elem. anal.; residue in react. flask dissoln. (THF), soln. filtration, THF removal from filtrate, residue drying (80°C, vac.) gave solid SnCl2;	98%

: 112400-86-9
1-n-butyl-4-methylpyridinium chloride

: 13454-96-1
platinum(IV) chloride

: bis(1-butyl-4-methylpyridinium) hexachloroplatinate(IV)

Conditions

Conditions	Yield
In acetonitrile for 3h; Schlenk technique; Reflux;	98%

: 13454-96-1
platinum(IV) chloride

: 3-butyl-1,2-dimethylimidazolium chloride

: bis(1-butyl-2,3-dimethylimidazolium) hexachloroplatinate(IV)

Conditions

Conditions	Yield
In acetonitrile for 3h; Schlenk technique; Reflux;	96%

: 13454-96-1
platinum(IV) chloride

: 79917-90-1
1-butyl-3-methylimidazolium chloride

: bis(1-n-buthyl-3-methylimidazolium) hexachloroplatinate(IV)

Conditions

Conditions	Yield
In acetonitrile for 3h; Schlenk technique; Reflux;	95%

: 13454-96-1
platinum(IV) chloride

: 36322-90-4
Piroxicam

: C30H24Cl2N6O8PtS2

Conditions

Conditions	Yield
Stage #1: Piroxicam With sodium hydroxide In ethanol Stage #2: platinum(IV) chloride In ethanol for 3h; Reflux;	95%

: 148-24-3
8-quinolinol

: 13454-96-1
platinum(IV) chloride

: [Pt(8-hydroxyquinoline)2Cl2]2Cl*2H2O

Conditions

Conditions	Yield
pH=2;	90%

: 92348-89-5
bis(dimethylamine)chlor(methyl)boronium chloride

: 13454-96-1
platinum(IV) chloride

: 2((CH3)2NH)2BCl(CH3)(1+)*PtCl6(2-)={((CH3)2NH)2BCl(CH3)}2{PtCl6}

Conditions

Conditions	Yield
With hydrogenchloride In diethyl ether	89.3%
With HCl In diethyl ether	89.3%

: 965-52-6
4-hydroxy-N’-((5-nitrofuran-2-yl)methylene)benzohydrazide

: 7732-18-5
water

: 13454-96-1
platinum(IV) chloride

: [Pt(nifuroxazide)2Cl2]Cl2·2H2O

Conditions

Conditions	Yield
Stage #1: 4-hydroxy-N’-((5-nitrofuran-2-yl)methylene)benzohydrazide; platinum(IV) chloride In methanol at 20℃; for 24h; Stage #2: water	88%

...Expand

: 13454-96-1
platinum(IV) chloride

: 112853-36-8
2-cyano-2-(p-tolylhydrazono)thioacetamide

: [Pt(2-cyano-2-(p-tolylhydrazono)thioacetamide)2Cl2]Cl2*4H2O

Conditions

Conditions	Yield
In acetone at 20℃; for 24h;	87.67%

: bis(tetrabutylammonium) hexachloroplatinate(IV)

: 13454-96-1
platinum(IV) chloride

: [tetrabutylammonium]2[Pt2Cl10]

Conditions

Conditions	Yield
In thionyl chloride (N2); stirred at room temp. for 12 h; evapd., treated with toluene, filtered, dried (vac.); elem. anal.;	83%

: 2-methoxy-6-((2-(4-(trifluoromethyl) pyrimidin-2-yl)hydrazono)methyl)phenol

: 13454-96-1
platinum(IV) chloride

: C26H20Cl2F6N8O4Pt

Conditions

Conditions	Yield
In ethanol; acetone for 2h;	82%

: 89-51-0
Homophthalic acid

: 13454-96-1
platinum(IV) chloride

: 5144-89-8
1,10-phenanthroline hydrate

: 139940-18-4
1,10-phenanthroline platinum(IV) homophthalate

Conditions

Conditions	Yield
With KOH In water byproducts: HCl; soln. of PtCl4 in distd. H2O was mixed homogeneously with soln. of homophthalic acid in ethanol and refluxed for 1h, pH raised to 6.0 by addn. of ethanolic KOH, soln. of 1,10-phenanthroline in ethanol was added, heated at 70 °C for 1h, cooled;; formed ppt. was filtered, washed several times successively with distd. H2O and ethanol, dried in a vacuum desiccator over silica gel; elem. anal.;;	81%

Yield

With KOH In water byproducts: HCl; soln. of PtCl4 in distd. H2O was mixed homogeneously with soln. of homophthalic acid in ethanol and refluxed for 1h, pH raised to 6.0 by addn. of ethanolic KOH, soln. of 1,10-phenanthroline in ethanol was added, heated at 70 °C for 1h, cooled;; formed ppt. was filtered, washed several times successively with distd. H2O and ethanol, dried in a vacuum desiccator over silica gel; elem. anal.;;

81%

...Expand

: 263146-62-9
chromonethiobarbituric acid

: 7732-18-5
water

: 13454-96-1
platinum(IV) chloride

: [Pt(C15H9N2O6S)2(H2O)2](2+)*2Cl(1-)*3H2O=[Pt(C15H9N2O6S)2(H2O)2]Cl2*3H2O

Conditions

Conditions	Yield
With ammonium hydroxide In 1,4-dioxane; water byproducts: HCl; the complex was prepd. by mixing a hot aq. soln. of the metal chloride (2.5 mmol) with hot dioxane soln. of the ligand (5 mmol); the react. mixt. was then refluxed; aq. ammonia soln. (1:10) was slowly added with stirring (pH 5.0-5.5); the ppt. was filtered, washed with hot dioxane and diethyl ether and dried over anhyd. CaCl2; elem. anal.;	80%

Yield

With ammonium hydroxide In 1,4-dioxane; water byproducts: HCl; the complex was prepd. by mixing a hot aq. soln. of the metal chloride (2.5 mmol) with hot dioxane soln. of the ligand (5 mmol); the react. mixt. was then refluxed; aq. ammonia soln. (1:10) was slowly added with stirring (pH 5.0-5.5); the ppt. was filtered, washed with hot dioxane and diethyl ether and dried over anhyd. CaCl2; elem. anal.;

80%

...Expand

: 1-ethyl-3-methylimidazolium tetrachloroaluminate(III)

: 13454-96-1
platinum(IV) chloride

: bis(1-ethyl-3-methylimidazolium) hexachloroplatinate(IV)

Conditions

Conditions	Yield
In neat (no solvent) under N2 using Schlenk techniques; heating at 150°C for 1 h; cooling to room temp.; washed (dry benzene); recrystd. (acetonitrile/benzene); elem.anal.;	80%

: 2637-34-5
2-Mercaptopyridine

: 13454-96-1
platinum(IV) chloride

: 983-80-2
cis-1,2-bis-(diphenylphosphino)ethene

: 285547-29-7
cis-[Pt(η1-S-pyridine-2-thiolato)2(1,2-bis(diphenylphosphino)ethene)]

Conditions

Conditions	Yield
With Et3N In ethanol; benzene byproducts: Et3N*HCl; pyridine-2-thione in benzene with Et3N was added dropwise to soln. of PtCl4 in ethanol under stirring, solid ligand was added, stirred for 24 h; filtered, evapd. slowly, elem. anal.;	80%

...Expand

: 2637-34-5
2-Mercaptopyridine

: 13454-96-1
platinum(IV) chloride

: 1663-45-2
1,2-bis-(diphenylphosphino)ethane

: 285547-28-6
cis-[Pt(η1-S-pyridine-2-thiolato)2(1,2-bis(diphenylphosphino)ethane)]

Conditions

Conditions	Yield
With Et3N In ethanol; benzene byproducts: Et3N*HCl; pyridine-2-thione in benzene with Et3N was added dropwise to soln. of PtCl4 in ethanol under stirring, solid ligand was added, stirred for 24 h; filtered, evapd. slowly, elem. anal.;	80%

...Expand

: 7732-18-5
water

: 13454-96-1
platinum(IV) chloride

: 93270-70-3
1-(p-anisyl)-5-aminoimidazole-4-carboxamide

: [Pt(5-amino-1-(p-CH3OC6H4)imidazole-4-carboxamide)2(H2O)2]Cl4*2H2O

Conditions

Conditions	Yield
In ethanol; water mixed hot 1:1 EtOH-water soln. of metal salt with EtOH soln. of ligand in stoich. amts., refluxed; filtered, washed with EtOH and Et2O, dried in desiccator over anhyd. CaCl2, elem. anal.;	80%

...Expand

: 24608-93-3
pyridinioacetate

: 7732-18-5
water

: 13454-96-1
platinum(IV) chloride

: [Pt(2-(pyridin-1-ium-1-yl)acetate)2(H2O)3/2Cl2]Cl2

Conditions

Conditions	Yield
In ethanol for 1.5h; Reflux;	80%

...Expand

: 13454-96-1
platinum(IV) chloride

: 1-phenyl-3-n-hexyltriazene

: tetrakis(η1-1-phenyl-3-n-hexyltriazenido)platinum(IV)

Conditions

Conditions	Yield
With n-butyllithium In tetrahydrofuran byproducts: LiCl; dropwise addn. of n-butyllithium soln. (n-hexane) to triazene soln. (THF)with stirring excluding light and moisture, 15°C; after 30 min addn. of PtCl4; stirring, room temp., 12h; evapn.; dissoln. in hexamethyldisiloxane of 40°C; filtration; crystn. at 4°C within 2 d;	79.5%

: 24756-06-7
3-(2-(3-chlorophenyl)hydrazono)pentane-2,4-dione

: 13454-96-1
platinum(IV) chloride

: [Pt(3-[(3-chlorophenyl)hydrazono]pentane-2,4-dione)2Cl2]Cl2

Conditions

Conditions	Yield
In acetone at 20℃; for 24h;	78.6%

: 2637-34-5
2-Mercaptopyridine

: 23176-19-4
(diphenylphosphinomethyl)diphenylphosphine selenide

: 13454-96-1
platinum(IV) chloride

: 285547-33-3
cis-[Pt(η1-S-pyridine-2-thiolato)2(dppmPSe)]

Conditions

Conditions	Yield
With Et3N In ethanol; benzene byproducts: Et3N*HCl; pyridine-2-thione in benzene with Et3N was added dropwise to soln. of PtCl4 in ethanol under stirring, solid ligand was added, stirred for 24 h; filtered, evapd. slowly, elem. anal.;	78%

...Expand

: 2637-34-5
2-Mercaptopyridine

: 13454-96-1
platinum(IV) chloride

: 7688-25-7
1,4-di(diphenylphosphino)-butane

: 285547-31-1
cis-[Pt(η1-S-pyridine-2-thiolato)2(1,4-bis(diphenylphosphino)butane)]

Conditions

Conditions	Yield
With Et3N In ethanol; benzene byproducts: Et3N*HCl; pyridine-2-thione in benzene with Et3N was added dropwise to soln. of PtCl4 in ethanol under stirring, solid ligand was added, stirred for 24 h; filtered, evapd. slowly, elem. anal.;	78%

...Expand

: 1415685-09-4
C14H10N4O4S

: 13454-96-1
platinum(IV) chloride

: C28H19N8O8PtS2(2+)*2Cl(1-)*H2O

Conditions

Conditions	Yield
In ethanol at 60 - 70℃;	78%

: 13454-96-1
platinum(IV) chloride

: 7487-94-7
mercury (II) chloride

: lithium chloride

: Li(x)Pt3O4

Conditions

Conditions	Yield
In neat (no solvent) heating mixt. of LiCl, HgCl2 and PtCl4 (molar ratio 1:2:3) under steam at 425°C overnight; treated with warm aqua regia;	77%

...Expand

: 366-18-7
[2,2]bipyridinyl

: 89-51-0
Homophthalic acid

: 13454-96-1
platinum(IV) chloride

: 139940-17-3
2,2'-bipyridine platinum(IV) homophthalate

Conditions

Yield

With KOH In water byproducts: HCl; soln. of PtCl4 in distd. H2O was mixed homogeneously with soln. of homophthalic acid in ethanol and refluxed for 1h, pH raised to 6.0 by addn. of ethanolic KOH, soln. of 2,2'-bipyridine in ethanol was added, heated at 70 °C for 1h, cooled;; formed ppt. was filtered, washed several times successively with distd. H2O and ethanol, dried in a vacuum desiccator over silica gel; elem. anal.;;

76%

...Expand

: 1072-63-5
1-vinylimidazole

: 13454-96-1
platinum(IV) chloride

: [dichlorotetrakis(1-vinylimidazole)platinum(IV)] chloride

Conditions

Conditions	Yield
In water refluxed for 3 h; distd., cooled, poured into ice, ppt. is washed with ethanol and ether,dried in vac.;	75%
In ethanol refluxed for 3 h; distd., cooled, poured into ice, ppt. is filtd., dried in vac.;	65%
In acetone the azole is added to a soln. of PtCl4 in acetone with intense stirring(ratio PtCl4:azole 1:8); the ppt. is recrystd. from methanol, dried in vac., elem. anal.;	25%

: 2637-34-5
2-Mercaptopyridine

: 6737-42-4
1,3-bis-(diphenylphosphino)propane

: 13454-96-1
platinum(IV) chloride

: 285547-30-0
cis-[Pt(η1-S-pyridine-2-thiolato)2(1,3-bis(diphenylphosphino)propane)]

Conditions

Conditions	Yield
With Et3N In ethanol; benzene byproducts: Et3N*HCl; pyridine-2-thione in benzene with Et3N was added dropwise to soln. of PtCl4 in ethanol under stirring, solid ligand was added, stirred for 24 h; filtered, evapd. slowly, elem. anal.;	75%

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: 2637-34-5
2-Mercaptopyridine

: 54006-28-9
(diphenylphosphinomethyl)diphenylphosphine sulphide

: 13454-96-1
platinum(IV) chloride

: 285547-32-2
cis-[Pt(η1-S-pyridine-2-thiolato)2(dppmPS)]

Conditions

Conditions	Yield
With Et3N In ethanol; benzene byproducts: Et3N*HCl; pyridine-2-thione in benzene with Et3N was added dropwise to soln. of PtCl4 in ethanol under stirring, solid ligand was added, stirred for 24 h; filtered, evapd. slowly, elem. anal.;	75%

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: 7732-18-5
water

: 13454-96-1
platinum(IV) chloride

: 93270-67-8
1-(p-tolyl)-5-aminoimidazole-4-carboxamide

: [Pt(5-amino-1-(p-CH3C6H4)imidazole-4-carboxamide)2(H2O)2]Cl4*2H2O

Conditions

Conditions	Yield
In ethanol; water mixed hot 1:1 EtOH-water soln. of metal salt with EtOH soln. of ligand in stoich. amts., refluxed; filtered, washed with EtOH and Et2O, dried in desiccator over anhyd. CaCl2, elem. anal.;	73%

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Platinum tetrachloride Consensus Reports

Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program.

Platinum tetrachloride Standards and Recommendations

OSHA PEL: TWA 0.002 mg(Pt)/m³
ACGIH TLV: TWA 0.002 mg(Pt)/m³

Platinum tetrachloride Specification

The IUPAC name of Platinum(IV) chloride is tetrachloroplatinum. With the CAS registry number 13454-96-1 and EINECS 236-645-1, it is also named as Platinum chloride (PtCl4). The classification code are Mutation data; Reproductive Effect; Skin / Eye Irritant. It is brown/red crystals which is stable under normal temperature and pressure. Additionally, this chemical should be sealed in the container and stored in the cool and dry place.

The other characteristics of this product can be summarized as: (1)H-Bond Donor 0; (2)H-Bond Acceptor 0; (3)Rotatable Bond Count 0; (4)Exact Mass 336.837235; (5)MonoIsotopic Mass 334.840185; (6)Topological Polar Surface Area 0; (7)Heavy Atom Count 5; (8)Formal Charge 0; (9)Complexity 19.1; (10)Isotope Atom Count 0; (11)Covalently-Bonded Unit Count 1.

Preparation of Platinum(IV) chloride: It is mainly encountered in the handling of chloroplatinic acid, obtained by dissolving of Pt metal in aqua regia. Heating H₂PtCl₆ gives PtCl₄: H₂PtCl₆ → PtCl₄ + 2 HCl

Uses of Platinum(IV) chloride: It is used as analytical reagent and catalytic agent. It is also used in the extension and diffusion processes for semiconductor production.

When you are using this chemical, please be cautious about it as the following:
It is not only harmful if swallowed, but also may cause sensitization by inhalation and skin contact. And it can cause burns. So people should not breathe dust and avoid contact with skin. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. If you want to contact this product, you must wear suitable protective clothing, gloves and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)

People can use the following data to convert to the molecule structure.
1. Smiles:[Pt](Cl)(Cl)(Cl)Cl
2. InChI:InChI=1/4ClH.Pt/h4*1H;/q;;;;+4/p-4

The following are the toxicity data which has been tested.

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
rat	LD50	oral	276mg/kg (276mg/kg)		Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 21(7), Pg. 55, 1977.

Product Name

Platinum tetrachloride

Synthetic route

Platinum tetrachloride Consensus Reports

Platinum tetrachloride Standards and Recommendations

Platinum tetrachloride Specification

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