Conditions | Yield |
---|---|
With ammonium formate; palladium on activated charcoal In methanol for 0.5h; Heating; | 98% |
3-hydroxyphenylboronic acid
recorcinol
Conditions | Yield |
---|---|
With oxygen; triethylamine In 2-methyltetrahydrofuran at 20℃; under 760.051 Torr; for 48h; Green chemistry; | 98% |
With oxygen; triethylamine In 2-methyltetrahydrofuran at 20℃; under 760.051 Torr; for 48h; UV-irradiation; | 98% |
With dihydrogen peroxide In water at 20℃; for 0.5h; | 91% |
Conditions | Yield |
---|---|
With sulfuric acid; water at 230℃; for 6h; Large scale; | 96.46% |
Stage #1: m-phenylenediamine In water at 20℃; for 0.5h; Stage #2: With sodium nitrite In water at 20℃; for 5h; Time; | 80% |
With hydrogenchloride at 180℃; | |
With sulfuric acid In water at 230℃; under 15001.5 Torr; for 7.5h; Reagent/catalyst; Temperature; Pressure; Autoclave; | 372 g |
Conditions | Yield |
---|---|
With sodium sulfite In water at 20℃; for 18h; Kinetics; Mechanism; Temperature; Green chemistry; | 96% |
Conditions | Yield |
---|---|
With sodium trimethylsilanethiolate In various solvent(s) at 185℃; for 24h; Mechanism; Product distribution; other reagents, other aryl methyl ethers; | 95% |
With hexamethyldisilathiane; sodium methylate In various solvent(s) at 185℃; for 24h; | 95% |
With L-Selectride In tetrahydrofuran at 67℃; for 96h; | 93% |
With hydrogenchloride In water at 250℃; under 37503.8 Torr; for 3h; Concentration; Autoclave; Inert atmosphere; Green chemistry; | 92% |
With pyridinium p-toluenesulfonate for 0.025h; microwave irradiation; | 75% |
Conditions | Yield |
---|---|
With aluminium(III) iodide; diisopropyl-carbodiimide In acetonitrile at 80℃; for 18h; | 95% |
With aluminium(III) iodide; diisopropyl-carbodiimide In acetonitrile at 80℃; for 18h; | 95% |
With aluminium(III) iodide In dimethyl sulfoxide; acetonitrile at 80℃; for 48h; | 78% |
With aluminium(III) iodide; dimethyl sulfoxide In acetonitrile at 80℃; for 18h; | 78% |
With aluminium(III) iodide; calcium oxide In acetonitrile at 80℃; for 18h; | 18% |
resorcin bis(tetrahydropyranyl)ether
recorcinol
Conditions | Yield |
---|---|
With montmorillonite K-10 In methanol at 40 - 50℃; for 0.6h; | 94% |
Conditions | Yield |
---|---|
sulfur trioxide In 4-methyl-2-pentanone at 70℃; for 0.166667h; Product distribution / selectivity; | A n/a B 94% |
Conditions | Yield |
---|---|
With glycolic Acid; copper hydroxide; sodium hydroxide In water; dimethyl sulfoxide at 120℃; for 6h; Inert atmosphere; Schlenk technique; | 93% |
With formic acid; oxygen; triethylamine; copper(ll) bromide In acetonitrile at 20℃; for 48h; Irradiation; | 90% |
With cesium hydroxide In water; dimethyl sulfoxide at 120℃; for 24h; Sealed tube; Inert atmosphere; | 88% |
With copper(I) oxide; 2-(N,N-dimethylamino)ethanol; water; potassium hydroxide In dimethyl sulfoxide at 100℃; for 24h; Reagent/catalyst; Temperature; Inert atmosphere; | 87% |
Kalischmelze; |
1,3-bis(allyloxy)benzene
recorcinol
Conditions | Yield |
---|---|
With ammonium formate; palladium on activated charcoal In methanol for 1h; Heating; | 92% |
Conditions | Yield |
---|---|
With sulfuric acid; sodium nitrite at 12.5 - 90℃; | 91.8% |
With sulfuric acid; water; sodium nitrite at -5 - 40℃; for 2h; Reagent/catalyst; Temperature; | 74.5% |
Stage #1: m-Hydroxyaniline With sulfuric acid; sodium nitrite In water at -8 - 25℃; for 0.25h; Stage #2: With water In acetic acid butyl ester at 75 - 80℃; for 0.25h; | 55% |
With sulfuric acid Diazotization.Verkochen der Diazoniumsulfatloesung; | |
Stage #1: m-Hydroxyaniline With hydrogenchloride; sodium nitrite In water at 1℃; for 0.5h; Stage #2: With potassium carbonate In water at 30℃; for 0.5h; Temperature; |
1,3-O-bis(tert-butyldimethylsilyl)resorcinol
recorcinol
Conditions | Yield |
---|---|
With potassium fluoride; hydrogen bromide In N,N-dimethyl-formamide at 25℃; for 2h; | 91% |
Conditions | Yield |
---|---|
With Fe2O3-SiO2 nanoparticles; air In water at 50℃; for 3h; Green chemistry; | 89% |
With [Cu6I2(μ4-I)2(μ4-5-phpymt)2]; triethylamine In water; acetonitrile for 48h; Catalytic behavior; Solvent; Time; UV-irradiation; | 74% |
recorcinol
Conditions | Yield |
---|---|
With aluminum (III) chloride; sodium iodide In methanol at 60℃; for 24h; Reagent/catalyst; Solvent; | 89% |
Conditions | Yield |
---|---|
With ammonium formate; palladium on activated charcoal In methanol for 1.5h; Heating; | 86% |
Conditions | Yield |
---|---|
With copper(I) oxide; tetra(n-butyl)ammonium hydroxide; 1,10-phenanthroline-4,7-diol In water at 110℃; for 24h; Inert atmosphere; Schlenk technique; Sealed tube; Green chemistry; | 86% |
1,3-bis(methoxymethyl)resorcinol
recorcinol
Conditions | Yield |
---|---|
With bismuth(III) chloride In water; acetonitrile at 50℃; for 2h; | 85% |
Conditions | Yield |
---|---|
With hydrogen iodide at 25℃; for 24h; Inert atmosphere; | A 12% B 85% |
With copper(I) oxide; sodium methylate In methanol at 185℃; for 12h; Autoclave; | A 50% B 43% |
Conditions | Yield |
---|---|
With nano magnetic sulfated zirconia (Fe3O4 at ZrO2/SO42-) In neat (no solvent) at 20℃; for 0.5h; Green chemistry; | 85% |
(E)-3-(2,4-dimethoxyphenyl)-2-propenoic acid
recorcinol
Conditions | Yield |
---|---|
With hydrogenchloride; water at 250℃; under 37503.8 Torr; for 4.5h; Sealed tube; Inert atmosphere; | 84% |
Conditions | Yield |
---|---|
With 2-di-tertbutylphosphino-3,4,5,6-tetramethyl-2',4',6'-triisopropyl-1,1'-biphenyl; potassium hydroxide; tris-(dibenzylideneacetone)dipalladium(0) In 1,4-dioxane; water at 100℃; for 17h; | 83% |
Kalischmelze; | |
bei der Kalischmelze; | |
In water Quantum yield; Ambient temperature; Irradiation; presence of O2 investigated; |
Conditions | Yield |
---|---|
Stage #1: 3,5-dihydroxyphenol With sodium hydroxide; hydrogen; Rh/Al2O3 at 20℃; under 2585.81 Torr; for 12h; Stage #2: With sulfuric acid for 9h; Heating; Further stages.; | 82% |
With sodium tetrahydroborate; water |
Conditions | Yield |
---|---|
Stage #1: 5-methoxyresorcinol With sodium hydroxide; hydrogen; Rh/Al2O3 In water under 2585.81 Torr; for 12h; Stage #2: With sulfuric acid for 9h; Heating; Further stages.; | 80% |
Conditions | Yield |
---|---|
With β-D-glucose; copper(II) acetate monohydrate; potassium hydroxide In water; dimethyl sulfoxide at 20 - 120℃; for 24h; | 80% |
Conditions | Yield |
---|---|
With copper dichloride In methanol; water for 3h; Heating; | 75% |
Conditions | Yield |
---|---|
With silver carbonate In dimethyl sulfoxide at 120℃; for 16h; | 71% |
Destillation; | |
With hydrogenchloride at 120℃; pH=1.40; Activation energy; Kinetics; Further Variations:; Temperatures; pH-values; |
Conditions | Yield |
---|---|
With pentamethylbenzene,; boron trichloride In dichloromethane at -78℃; for 0.333333h; | A 26% B 71% |
hydrogenchloride
7,7,7,15,15,15-hexamethyl-6,8,14,16-tetraoxa-7,15-distibatricyclo[11.3.1.1.(9,13)]octadeca-1,3,5,9,11,13-hexaene
A
trimethylantimony dichloride
B
recorcinol
Conditions | Yield |
---|---|
In ethanol excess soln. of acid addn. to Sb-compd., heating (3 h, reflux, water bath), soln. pouring to petri dish; sepn. by different solubility in benzene; | A 70% B 69% |
ethyl acetoacetate
recorcinol
7-hydroxy-4-methyl-chromen-2-one
Conditions | Yield |
---|---|
With trifluoroacetic acid at 100℃; for 0.5h; Pechmann condensation; Microwave irradiation; regioselective reaction; | 100% |
With silica-supported methanesulfonic acid catalyst In octadecane at 160℃; for 2h; Pechmann reaction; | 99% |
With iron(III) chloride In neat (no solvent) at 70℃; for 12h; Pechmann Condensation; Green chemistry; | 99% |
4-nitro-benzoyl chloride
recorcinol
3-(4-nitrobenzoyloxy)phenyl 4-nitrobenzoate
Conditions | Yield |
---|---|
With pyridine In tetrahydrofuran at 20℃; for 24h; | 100% |
With tetralin at 160℃; | |
With pyridine at 100℃; | |
With pyridine In toluene Heating; |
isobutyryl chloride
recorcinol
1-(2,4-dihydroxyphenyl)-2-methyl-1-propanone
Conditions | Yield |
---|---|
With boron trifluoride diethyl etherate at 20℃; | 100% |
at 90℃; | |
With aluminium trichloride; nitrobenzene at 40 - 50℃; |
ethyl 2-oxocyclohexane carboxylate
recorcinol
3-hydroxy-7,8,9,10-tetrahydrobenzo[c]chromen-6-one
Conditions | Yield |
---|---|
With sulfuric acid at 0 - 20℃; for 1h; Pechmann condensation; | 100% |
With sulfuric acid at 20℃; for 24h; | 98% |
With aluminum oxide; methanesulfonic acid at 20℃; for 0.166667h; Pechmann reaction; | 96% |
Conditions | Yield |
---|---|
With boron trifluoride diethyl etherate at 90℃; for 1.5h; Inert atmosphere; | 100% |
With zinc(II) chloride at 125 - 140℃; | |
With boron trifluoride |
Conditions | Yield |
---|---|
With trifluoroacetic acid at 100℃; for 0.5h; Pechmann condensation; Microwave irradiation; regioselective reaction; | 100% |
With zirconium(IV) oxychloride In ethanol at 60 - 65℃; for 24h; Pechmann reaction; | 98% |
With aluminum potassium sulfate dodecahydrate at 65℃; for 2h; Pechmann condensation; Neat (no solvent); | 93% |
Conditions | Yield |
---|---|
With benzyltriphenylphosphonium peroxodisulfate; potassium bromide In acetonitrile for 2h; Heating; | 100% |
With dihydrogen peroxide; potassium bromide In water; acetonitrile | 96% |
With DMd; sulfuric acid; sodium bromide In acetone at 20℃; for 0.0166667h; | 95% |
Conditions | Yield |
---|---|
Stage #1: recorcinol With sodium hydride In N,N-dimethyl-formamide; mineral oil at 0℃; for 0.25h; Inert atmosphere; Stage #2: chloromethyl methyl ether In N,N-dimethyl-formamide; mineral oil at 20℃; for 27h; Inert atmosphere; | 100% |
With sodium hydride In N,N-dimethyl-formamide at 0 - 20℃; | 99% |
Stage #1: recorcinol With sodium hydride In N,N-dimethyl-formamide; mineral oil at 0℃; Inert atmosphere; Stage #2: chloromethyl methyl ether In N,N-dimethyl-formamide; mineral oil at 0 - 20℃; for 5h; | 95% |
(4-chlorophenyl)(2-hydroxy-3,3-dimethyl-2,3-dihydroindol-1-yl)methanone
recorcinol
(4-Chloro-phenyl)-[2-(2,4-dihydroxy-phenyl)-3,3-dimethyl-2,3-dihydro-indol-1-yl]-methanone
Conditions | Yield |
---|---|
With boron trifluoride diethyl etherate In 1,4-dioxane at 40℃; for 10h; | 100% |
With boron trifluoride diethyl etherate In 1,4-dioxane at 40℃; for 10h; | 100% |
Conditions | Yield |
---|---|
ytterbium (III) tris-[tris-(nonafluorobutanesulfonyl)methide] In ethanol for 48h; Heating / reflux; | 100% |
With hydrogenchloride In ethanol; water at -10 - 90℃; for 20.1667h; | 82% |
With hydrogenchloride In ethanol at 20 - 90℃; for 17h; | 76% |
3-hydroxyphenylacetic acid
recorcinol
1-(2,4-dihydroxyphenyl)-2-(3-hydroxyphenyl)ethanone
Conditions | Yield |
---|---|
With boron trifluoride diethyl etherate for 1.5h; Reflux; | 100% |
With boron trifluoride diethyl etherate at 60 - 70℃; for 1h; | 93% |
With boron trifluoride diethyl etherate In toluene at 90℃; for 2h; | 57% |
With boron trifluoride diethyl etherate at 110℃; for 2h; Inert atmosphere; | |
With boron trifluoride diethyl etherate In N,N-dimethyl-formamide at 90℃; for 2h; |
m-methoxyphenylacetic acid
recorcinol
1-(2,4-dihydroxyphenyl)-2-(3-methoxyphenyl)ethanone
Conditions | Yield |
---|---|
With boron trifluoride diethyl etherate at 85℃; for 3h; | 100% |
With boron trifluoride diethyl etherate at 60 - 70℃; for 1h; | 96% |
With boron trifluoride diethyl etherate at 80 - 90℃; Inert atmosphere; | 74% |
methylphosphonous acid diphenyl ester
recorcinol
Conditions | Yield |
---|---|
at 60 - 241℃; under 0.750075 - 15.201 Torr; for 11h; | 100% |
Conditions | Yield |
---|---|
With potassium carbonate; copper(II) oxide In pyridine for 168h; Heating; | 100% |
cyclohexylacetic acid chloride
recorcinol
2-cyclohexyl-1-(2,4-dihydroxyphenyl)ethanone
Conditions | Yield |
---|---|
With boron trifluoride diethyl etherate at 20℃; Inert atmosphere; | 100% |
With aluminium trichloride In dichloromethane at 20 - 70℃; for 4h; | 40% |
(S)-3,7-dimethyloctanal
recorcinol
C64H96O8
Conditions | Yield |
---|---|
With hydrogenchloride In ethanol at 80℃; for 18h; | 100% |
benzyl bromide
2-bromo-5-methoxy-benzoic acid
recorcinol
3-(Benzyloxy)-8-methoxy-6H-benzo[c]chromen-6-one
Conditions | Yield |
---|---|
Stage #1: 2-bromo-5-methoxy-benzoic acid; recorcinol With sodium hydroxide; copper(II) sulfate Stage #2: benzyl bromide With caesium carbonate | 100% |
recorcinol
5,6-dichlorofluorescein
Conditions | Yield |
---|---|
Stage #1: 4,5-dichlorophthalic acid With methanesulfonic acid at 90℃; for 1h; Stage #2: recorcinol at 80 - 105℃; for 1h; | 100% |
2-(1-benzyl-pyrrol-2-yl)-4,6-dichloro-[1,3,5]triazine
recorcinol
Conditions | Yield |
---|---|
Stage #1: 2-(1-benzyl-pyrrol-2-yl)-4,6-dichloro-[1,3,5]triazine; recorcinol With aluminum (III) chloride In xylene at 50 - 85℃; for 3h; Friedel Crafts Acylation; Stage #2: With hydrogenchloride In water | 100% |
1,1'-bis(ethenyl-4-pyridyl)ferrocene
recorcinol
Conditions | Yield |
---|---|
In ethanol at room temp. for 7 d; elem. anal.; | 100% |
9-benzyl-6-chloro-9H-purine
recorcinol
4-(9-phenylmethyl-9H-purin-6-yl)-benzene-1,3-diol
Conditions | Yield |
---|---|
With trifluorormethanesulfonic acid; 1,1,1,3',3',3'-hexafluoro-propanol at 60℃; for 24h; | 100% |
With aluminum (III) chloride In 1,2-dichloro-ethane for 0.5h; Reflux; | 51% |
Conditions | Yield |
---|---|
In methanol | 100% |
1,1,3,3-tetramethyldisilazane
recorcinol
1,3-bis(dimethylsilyloxy)benzene
Conditions | Yield |
---|---|
With dimethylmonochlorosilane In tetrahydrofuran Reflux; | 100% |
Conditions | Yield |
---|---|
Stage #1: methyloxirane; recorcinol With potassium hydroxide In toluene at 48.8789℃; for 1.5h; Under N2; Stage #2: oxirane at 48.8789℃; for 2h; | 99.7% |
Conditions | Yield |
---|---|
Stage #1: acetyl chloride; recorcinol In chloroform at 20 - 65℃; for 4h; Large scale; Stage #2: In water Temperature; Large scale; | 99.5% |
bismuth(III) oxychloride at 20℃; for 0.0833333h; | 98% |
zirconium(IV) oxychloride at 20℃; for 0.0833333h; | 97% |
Conditions | Yield |
---|---|
With Sulfate; titanium(IV) oxide In dichloromethane at 40℃; for 0.0666667h; | 99% |
With iron(III) p-toluenesulfonate hexahydrate In acetonitrile at 20℃; for 0.833333h; | 99% |
With bismuth(lll) trifluoromethanesulfonate In acetonitrile at 20℃; for 0.166667h; | 98% |
Conditions | Yield |
---|---|
With triethylamine In ethyl acetate at 0 - 20℃; for 0.166667h; Green chemistry; | 99% |
With pyridine |
Conditions | Yield |
---|---|
With ethanol; water at 60 - 80℃; for 9h; Temperature; Green chemistry; | 99% |
With water In ethanol at 40 - 50℃; for 4h; Temperature; Large scale; | 97.6% |
With ethanol und Eintragen des Reaktionsgemisches in heisses Wasser; |
Empirical Formula: C6H6O2
Molecular Weight: 110.1106
Index of Refraction: 1.612
Molar Refractivity: 30.01 cm3
Molar Volume: 86.2 cm3
Surface Tension: 57.1 dyne/cm
Density: 1.275 g/cm3
Flash Point: 131.9 °C
Boiling Point: 280 °C at 760 mmHg
Vapour Pressure: 0.00229 mmHg at 25 °C
Melting point: 109-112 °C(lit.)
Storage tempreture: 0-6 °C
Water solubility: 140 g/100 mL
Sensitive: Light sensitive
Appearance: Crystals or powder
Structure of Resorcinol (CAS NO.108-46-3):
IUPAC Name: Benzene-1,3-diol
Canonical SMILES: C1=CC(=CC(=C1)O)O
InChI: InChI=1S/C6H6O2/c7-5-2-1-3-6(8)4-5/h1-4,7-8H
InChIKey: GHMLBKRAJCXXBS-UHFFFAOYSA-N
Product Category of Resorcinol (CAS NO.108-46-3): Color Former & Related Compounds;Developer;Functional Materials
Resorcinol (CAS NO.108-46-3) is used as an antiseptic and disinfectant, and is used 5 to 10% in ointments in the treatment of chronic skin diseases and eczema of a sub-acute character. One emerging use is as a template molecule in supramolecular chemistry. It is used as an analytical reagent for the qualitative determinaion of ketoses, and is the starting material for resorcinarene molecules and the initiating explosive lead styphnate. Resorcinol is also used as a chemical intermediate for the synthesis of pharmaceuticals and other organic compounds. It is used in the production of diazo dyes and plasticizers and as a UV absorber in resins.
3-Ethylphenol (CAS NO.620-17-7) is obtained on fusing many resins with potassium hydroxide, or by the distillation of Brazilwood extract. It also may be prepared synthetically by fusing 3-iodophenol, phenol-3-sulfonic acid or benzene-1,3-disulfonic acid with potassium carbonate; by the action of nitrous acid on 3-aminophenol; or by the action of 10% hydrochloric acid on 1,3-diaminobenzene. Many ortho- and para-compounds of the aromatic series also yield resorcinol on fusion with potassium hydroxide.
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
cat | LDLo | subcutaneous | 110mg/kg (110mg/kg) | BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD BLOOD: METHEMOGLOBINEMIA-CARBOXYHEMOGLOBIN | Archiv fuer Experimentelle Pathologie und Pharmakologie. Vol. 72, Pg. 241, 1913. |
dog | LDLo | intravenous | 700mg/kg (700mg/kg) | "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." Vol. 4, Pg. 1289, 1935. | |
frog | LDLo | parenteral | 270mg/kg (270mg/kg) | PERIPHERAL NERVE AND SENSATION: SPASTIC PARALYSIS WITH OR WITHOUT SENSORY CHANGE CARDIAC: OTHER CHANGES BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD | Naunyn-Schmiedeberg's Archiv fuer Experimentelle Pathologie und Pharmakologie. Vol. 166, Pg. 437, 1932. |
guinea pig | LDLo | subcutaneous | 400mg/kg (400mg/kg) | BEHAVIORAL: EXCITEMENT BEHAVIORAL: TETANY BEHAVIORAL: COMA | Revue Medicale de la Suisse Romande. Vol. 15, Pg. 561, 1895. |
human | LDLo | oral | 29mg/kg (29mg/kg) | "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York, Academic Press, Inc., 1969Vol. -, Pg. 519, 1969. | |
mouse | LD50 | intraperitoneal | 215mg/kg (215mg/kg) | Bulletin of Experimental Biology and Medicine Vol. 61, Pg. 291, 1966. | |
mouse | LD50 | oral | 200mg/kg (200mg/kg) | Japanese Journal of Toxicology. Vol. 4, Pg. 105, 1991. | |
mouse | LD50 | subcutaneous | 213mg/kg (213mg/kg) | Zeitschrift fuer die Gesamte Innere Medizin und Ihre Grenzgebiete. Vol. 2, Pg. 333, 1947. | |
rabbit | LD50 | skin | 3360mg/kg (3360mg/kg) | SKIN AND APPENDAGES (SKIN): PRIMARY IRRITATION: AFTER TOPICAL EXPOSURE | American Industrial Hygiene Association Journal. Vol. 37, Pg. 596, 1976. |
rat | LCLo | inhalation | 160mg/m3/1H (160mg/m3) | BIOFAX Industrial Bio-Test Laboratories, Inc., Data Sheets. Vol. 11-4/1970, | |
rat | LD50 | oral | 301mg/kg (301mg/kg) | BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD GASTROINTESTINAL: CHANGES IN STRUCTURE OR FUNCTION OF SALIVARY GLANDS LUNGS, THORAX, OR RESPIRATION: DYSPNEA | BIOFAX Industrial Bio-Test Laboratories, Inc., Data Sheets. Vol. 11-4/1970, |
rat | LDLo | subcutaneous | 400mg/kg (400mg/kg) | BEHAVIORAL: EXCITEMENT BEHAVIORAL: TETANY BEHAVIORAL: COMA | Revue Medicale de la Suisse Romande. Vol. 15, Pg. 561, 1895. |
Hazard Codes: Xn, N
Risk Statements:
22: Harmful if swallowed
50: Very Toxic to aquatic organisms
36/38: Irritating to eyes and skin
Safety Statements:
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
61: Avoid release to the environment. Refer to special instructions safety data sheet
Resorcinol , its cas register number is 108-46-3. It also can be called 1,3-Dihydroxybenzene ; 1,3-Benzenediol ; and 3-Hydroxycyclohexadien-1-one . It is hazardous, so the first aid measures and others should be known. Such as: When on the skin: first, should flush skin with plenty of water immediately for at least 15 minutes while removing contaminated clothing. Secondly, get medical aid. Or in the eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Then get medical aid soon. While, it's inhaled: Remove from exposure and move to fresh air immediately. Give artificial respiration while not breathing. When breathing is difficult, give oxygen. And as soon as to get medical aid. Then you have the ingesting of the product: Wash mouth out with water, and get medical aid immediately. Notes to physician: Treat supportively and symptomatically.
In addition, Resorcinol (CAS NO.108-46-3) absorbs moisture or water from the air. It may discolor on exposure to air and light. It is not compatible with strong oxidizing agents, bases, acid chlorides, iron, ferric salts, acid anhydrides, alkalies, albumin, iron salts, antipyrine, methanol, acetanilide, camphor, urethane, spirit nitrous ether, and you must not take it with incompatible materials, light, dust generation, exposure to air, exposure to moist air or water, heat. And also prevent it to broken down into hazardous decomposition products: Carbon monoxide, carbon dioxide.
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