Product Name

  • Name

    Sodium hypochlorite

  • EINECS 231-668-3
  • CAS No. 7681-52-9
  • Article Data173
  • CAS DataBase
  • Density 1.25 g/mL at 20 °C
  • Solubility decomposes in water
  • Melting Point -16 °C
  • Formula NaClO
  • Boiling Point 111°C
  • Molecular Weight 74.4422
  • Flash Point
  • Transport Information UN 1791 8/PG 3
  • Appearance colourless liquid with strong odour
  • Safety 26-36/37/39-45-50A-28A-36
  • Risk Codes 31-34-36/38-36/37/38
  • Molecular Structure Molecular Structure of 7681-52-9 (Sodium hypochlorite)
  • Hazard Symbols CorrosiveC,IrritantXi
  • Synonyms Hypochlorousacid, sodium salt (8CI,9CI);AD Gel;ActiPlus N 2818;AgClor 310;Antiformin;Aron Clean;B-K Liquid;Baso agri+;Belizna;Belkina;Carrel-Dakin solution;Chloros;Cloralex;Clorox;Comfor;Dakin's solution;Deosan;Dispatch;Dispatch(salt);Fox-Chlor;Hishikurin S;Hyclorite;Hypure;Hypure N;Javel water;Javelle water;Javex;Javex 5;Jomax Mold &;Mildew Stain Remover;Klorocin;Linely;Milton;Milton Sterilising Fluid;Modified Dakin's solution;Nades;Neo-cleaner;Neoseptal CL;Parozone;Purelox;Purin B;Sanrack P;Sodium chloride oxide (NaClO);Sodium hypochloride;Sodium hypochlorite;Sodiumhypochlorite (NaClO);Sodium hypochlorite (NaOCl);Sodium oxychloride;Solutions, Dakin's;Sunnysol 150;Super White L;Tsurukuron;XY 12;Youxiaolin;Sodium Hypochlorite solution;
  • PSA 23.06000
  • LogP 0.57070

Synthetic route

hydrazodicarboxamide
110-21-4

hydrazodicarboxamide

A

sodium hypochlorite
7681-52-9

sodium hypochlorite

B

sodium azide

sodium azide

C

hydrogen azide
916329-38-9

hydrogen azide

Conditions
ConditionsYield
With sodium hydroxide; sulfuric acid In water ice cooling; distn. with H2SO4;A n/a
B n/a
C 9%
With NaOH; H2SO4 In water ice cooling; distn. with H2SO4;A n/a
B n/a
C 9%
potassium chlorate
3811-04-9

potassium chlorate

potassium chloride

potassium chloride

sodium chloride
7647-14-5

sodium chloride

calcium chloride

calcium chloride

A

sodium hypochlorite
7681-52-9

sodium hypochlorite

B

oxygen
80937-33-3

oxygen

Conditions
ConditionsYield
With Na2Cr2O7 In water Electrolysis; influencce of electrode material;;
sodium chloride
7647-14-5

sodium chloride

A

sodium chlorate

sodium chlorate

B

sodium hypochlorite
7681-52-9

sodium hypochlorite

C

sodium chlorite
7758-19-2

sodium chlorite

D

sodium perchlorate

sodium perchlorate

Conditions
ConditionsYield
In water Electrolysis;
sodium chloride
7647-14-5

sodium chloride

A

sodium chlorate

sodium chlorate

B

sodium hypochlorite
7681-52-9

sodium hypochlorite

C

chlorine
7782-50-5

chlorine

Conditions
ConditionsYield
In water Electrolysis;
In water Electrolysis; chlorate formation as side reaction;;
sodium chloride
7647-14-5

sodium chloride

sodium hypochlorite
7681-52-9

sodium hypochlorite

Conditions
ConditionsYield
In water Electrolysis;
In water Electrolysis; Schuckert-process, monopolar arrangement, vessel of enamelled iron, cooled by water; carbon electrodes or carbon electrodes covered with Pt, electrodes used as stirrer;;
With CrO4(1-) In water byproducts: H, chromium chromate; Electrolysis; electrolysis without diaphragm, cathode reaction; additive alkalichromates, formation of chromium chromate, which act as diaphragm;;
sodium hydroxide
1310-73-2

sodium hydroxide

sodium hypochlorite
7681-52-9

sodium hypochlorite

Conditions
ConditionsYield
With chlorine In not given Electrolysis; NaOH formed at cathode and chlorine formed at anode; gas proofed anode region, asbestos diaphragm; mixing of NaOH and chlorine in a special region;;
With chlorine In not given Electrolysis; NaOH formed at cathode and chlorine formed at anode; anode: coal plates or rods with coke pieces; passing catholyte into anode region;;
With chlorine In not given Electrolysis; NaOH formed at cathode and chlorine formed at anode; cell of ungazed tone plates filled with pieces of C; alternative connection to positive and negative pole;;
chlorine
7782-50-5

chlorine

sodium hydroxide
1310-73-2

sodium hydroxide

A

sodium hypochlorite
7681-52-9

sodium hypochlorite

B

sodium chloride
7647-14-5

sodium chloride

Conditions
ConditionsYield
In neat (no solvent) 170kg NaOH, 63kg Cl2, 60°C, cyclindric rotating vessel, 1.5h;; product-mixture:24% NaClO, 25.5% NaCl, 43% NaOH;;
In neat (no solvent) 170kg NaOH, 63kg Cl2, 60°C, cyclindric rotating vessel, 1.5h, sintering of product to increase stability;; product-mixture:24% NaClO, 25.5% NaCl, 43% NaOH;;
In not given byproducts: H2O; react. is reversible;;
In neat (no solvent) reaction of finely atomized alkaline hydroxide soln. with Cl2;; mixture;;
In water
chlorine
7782-50-5

chlorine

sodium hydroxide
1310-73-2

sodium hydroxide

sodium hypochlorite
7681-52-9

sodium hypochlorite

Conditions
ConditionsYield
In sodium hydroxide Cl2 passed through carbonate-free soln. of NaOH at -5...0°C;
In water sparging chlorine into 0.3 M aq. soln. of NaOH; UV monitoring;
In water residual alkalinity: 1g/l; not isolated;;
calcium hypochlorite
7778-54-3

calcium hypochlorite

sodium hypochlorite
7681-52-9

sodium hypochlorite

Conditions
ConditionsYield
With Na-phosphates In neat (no solvent)
With NaHSO4 or NaH2PO4 or NaO2CCO2H In water other solvents possible; addn. of the solvent to the mixture of the solid components just before use;;
With NaHSO4 or NaH2PO4 or NaO2CCO2H In water
With Na-phosphates In neat (no solvent)
With NaHSO4 or NaH2PO4 or NaO2CCO2H In water other solvents possible; addn. of the solvent to the mixture of the solid components just before use;;
calcium hypochlorite
7778-54-3

calcium hypochlorite

sodium cation
17341-25-2

sodium cation

sodium hypochlorite
7681-52-9

sodium hypochlorite

Conditions
ConditionsYield
In water react. at ion exchange resin;; solns. with 1-3% active chlorine;;
In water react. at ion exchange resin;; solns. with 1-3% active chlorine;;
calcium hypochlorite
7778-54-3

calcium hypochlorite

sodium hydroxide
1310-73-2

sodium hydroxide

sodium hypochlorite
7681-52-9

sodium hypochlorite

Conditions
ConditionsYield
With boric acid In water boric acid+Ca(ClO)2 in water distillation, first 100 ml distillate colected in 200 ml containing NaOH;
calcium hypochlorite
7778-54-3

calcium hypochlorite

sodium carbonate
497-19-8

sodium carbonate

A

sodium hypochlorite
7681-52-9

sodium hypochlorite

B

sodium hydroxide
1310-73-2

sodium hydroxide

Conditions
ConditionsYield
In water byproducts: CaCO3; dissolving mixture of dry Ca(OCl)2, containing Ca(OH)2, and Na2CO3 in H2O;; pptn. of CaCO3; formation of a NaOCl and NaOH soln.;;
calcium hypochlorite
7778-54-3

calcium hypochlorite

sodium carbonate
497-19-8

sodium carbonate

sodium hypochlorite
7681-52-9

sodium hypochlorite

Conditions
ConditionsYield
With (borax or MgCO3) In water byproducts: CaCO3; hot Na2CO3-soln. which may contain borax or MgCO3;; not isolated;;
In neat (no solvent)
With (borax or MgCO3) In water byproducts: CaCO3; hot Na2CO3-soln. which may contain borax or MgCO3;; not isolated;;
With sodium hydrogencarbonate In water pH=9.5;
In neat (no solvent)
calcium hypochlorite
7778-54-3

calcium hypochlorite

Chlorkalk
15944-13-5

Chlorkalk

sodium carbonate
497-19-8

sodium carbonate

sodium hypochlorite
7681-52-9

sodium hypochlorite

Conditions
ConditionsYield
In water byproducts: CaCO3; not isolated;;
In water byproducts: CaCO3; not isolated;;
calcium hypochlorite
7778-54-3

calcium hypochlorite

sodium hydrogencarbonate
144-55-8

sodium hydrogencarbonate

sodium hypochlorite
7681-52-9

sodium hypochlorite

Conditions
ConditionsYield
With (borax or MgCO3) In water byproducts: CaCO3; hot NaHCO3-soln. which may contain borax or MgCO3;; not isolated;;
With (borax or MgCO3) In water byproducts: CaCO3; hot NaHCO3-soln. which may contain borax or MgCO3;; not isolated;;
water
7732-18-5

water

sodium chloride
7647-14-5

sodium chloride

A

sodium chlorate

sodium chlorate

B

sodium hypochlorite
7681-52-9

sodium hypochlorite

C

sodium perchlorate

sodium perchlorate

Conditions
ConditionsYield
With sodium hydroxide; sodium dichromate; sodium chromate(VI) In water Kinetics; Electrolysis; in a glass cylindrical cell without a diaphragm; constant pH maintainedwithin 0.05-0.1 by buffering (Na2CrO4 and Na2Cr2O7 with addn. of NaOH or HCl); expts. conducted at c.d. 10 A/l by periodic method or with continuous introduction of NaCl feed soln.; not isolated, detected by polarization curves; gas anal.;
water
7732-18-5

water

sodium chloride
7647-14-5

sodium chloride

sodium hypochlorite
7681-52-9

sodium hypochlorite

Conditions
ConditionsYield
In water Electrolysis; electrolysis of sea-water, graphite-electrodes;; not isolated;;
In water Electrolysis; 65-100g NaCl/l, 15°C;;
In water Electrolysis; apparatus described;; not isolated;;
water
7732-18-5

water

chlorine
7782-50-5

chlorine

sodium carbonate
497-19-8

sodium carbonate

sodium hypochlorite
7681-52-9

sodium hypochlorite

Conditions
ConditionsYield
In water byproducts: NaHCO3; Na2CO3 suspended in satd. soln., filtration of NaHCO3;; solns. with 5-12% active chlorine; not isolated;;
In water 100g Na2CO3/l;; <20g active chlorine per l; not isolated;;
In water 100g Na2CO3/l;; <20g active chlorine per l; not isolated;;
In water byproducts: NaHCO3; Na2CO3 suspended in satd. soln., filtration of NaHCO3;; solns. with 5-12% active chlorine; not isolated;;
chlorine dioxide
10049-04-4, 25052-55-5

chlorine dioxide

sodium hydroxide
1310-73-2

sodium hydroxide

sodium hypochlorite
7681-52-9

sodium hypochlorite

Conditions
ConditionsYield
With dihydrogen peroxide In water; toluene satn. of toluene with a ClO2/N2-mixture (ratio 20:80) at 0°C, neutralization with NaOH, introduction of ClO2/N2, addn. of 30% NaOH and 15-20% H2O2, separation of layers, evapn. of lower layer;; 90% NaClO;;
sodium phosphate

sodium phosphate

sodium hypochlorite
7681-52-9

sodium hypochlorite

Conditions
ConditionsYield
With chloroamine In water react. with a chloroamine sol. in the aq. soln. of Na-salt;; chloride-free soln.;;
With chloroamine In water react. with a chloroamine sol. in the aq. soln. of Na-salt;; chloride-free soln.;;
hypochlorous anhydride
7791-21-1

hypochlorous anhydride

sodium hydroxide
1310-73-2

sodium hydroxide

sodium hypochlorite
7681-52-9

sodium hypochlorite

Conditions
ConditionsYield
In neat (no solvent) react. of solid NaOH with Cl2O in mixture with inert gases, temp. up to 100°C;;
In tetrachloromethane dissolving Cl2O in CCl4, react. with NaOH at 30-50°C;;
hypochlorous anhydride
7791-21-1

hypochlorous anhydride

chlorine
7782-50-5

chlorine

sodium hydroxide
1310-73-2

sodium hydroxide

sodium hypochlorite
7681-52-9

sodium hypochlorite

Conditions
ConditionsYield
In tetrachloromethane dissolving Cl2O and Cl2 in CCl4, react. with NaOH at 30-50°C;;
sodium chloride
7647-14-5

sodium chloride

A

sodium hypochlorite
7681-52-9

sodium hypochlorite

B

chlorine trioxide
13932-10-0

chlorine trioxide

Conditions
ConditionsYield
In water byproducts: H, Ca(OH)2; Electrolysis; electrolysis without diaphragm, cathode reaction; additive CaCl2; formation of acidic soln. and therefore formation of ClO3 because of pptn. of Ca(OH)2;;
In water byproducts: H, Ca(OH)2; Electrolysis; electrolysis without diaphragm, cathode reaction; additive CaCl2; formation of acidic soln. and therefore formation of ClO3 because of pptn. of Ca(OH)2;;
sodium hydrogencarbonate
144-55-8

sodium hydrogencarbonate

sodium chloride
7647-14-5

sodium chloride

sodium hypochlorite
7681-52-9

sodium hypochlorite

Conditions
ConditionsYield
In water Electrolysis; cell with diaphragm, anode compartment filled with satd. NaHCO3 soln. (not soda), cathode compartment satd. NaCl soln., low temp.;; soln. free of chloride but not stable at slightly elevated temp.;;
chlorine azide
13973-88-1

chlorine azide

sodium hypochlorite
7681-52-9

sodium hypochlorite

Conditions
ConditionsYield
With sodium hydroxide In not given byproducts: NaN3, H2O;
With NaOH In not given byproducts: NaN3, H2O;
chlorine azide
13973-88-1

chlorine azide

sodium hydroxide
1310-73-2

sodium hydroxide

A

sodium hypochlorite
7681-52-9

sodium hypochlorite

B

sodium azide

sodium azide

Conditions
ConditionsYield
In not given byproducts: H2O;
In not given byproducts: H2O; passing N3Cl into NaOH soln.;;
sodium cation
17341-25-2

sodium cation

sodium hypochlorite
7681-52-9

sodium hypochlorite

Conditions
ConditionsYield
With chloride lime In not given reaction of chloride lime with sodium salts;;
sodium cation
17341-25-2

sodium cation

hypochlorite
14380-61-1

hypochlorite

sodium hypochlorite
7681-52-9

sodium hypochlorite

Conditions
ConditionsYield
In water from strongly alk. soln. by evapn. at low temp.;; solid NaClO obtained;;
Conditions
ConditionsYield
In not given passing Cl into NaOH lye at temp. below 27°C; stirring; pptd. NaCl is removed; addn. of solid NaOH;; soln. of chloride chlorine and hypochlorite chlorine;;
With sodium carbonate In not given passing Cl into Na2CO3 soln.; formation of HClO and NaCl; reaction of HClO with acetanilide or p-nitroacetanilide to a chlorinated base, which decomposes with NaOH in NaOCl and the anilides;;
In not given reaction of Cl with concd. soln. of NaOH; concn. of NaOH soln. may be equivalent to NaOCl soln. or dild. NaOH soln. and addn. of NaOH to form concd. NaOCl soln.;; separation of pptd. NaCl from reaction vessel; concd. NaOCl soln. containing small amounts of chloride;;
With sodium carbonate In not given passing Cl into Na2CO3 soln.; formation of HClO and NaCl; reaction of HClO with acetanilide or p-nitroacetanilide to a chlorinated base, which decomposes with NaOH in NaOCl and the anilides;;
Conditions
ConditionsYield
In neat (no solvent) reaction of chlorine with powdered NaOH at 0°C;;
With air In not given passing Cl (dild. with 4-9 Vol. air) into NaOH lye to decrease formation of NaClO3;;
sodium hypochlorite
7681-52-9

sodium hypochlorite

chlorine
7782-50-5

chlorine

Conditions
ConditionsYield
In water pH=9.8 - 13.5; Product distribution / selectivity;100%
With sodium hydroxide; urea In water pH=6.5 - 13.4; Product distribution / selectivity;1.5%
With urea In water pH=5.6; Product distribution / selectivity;
sodium hypochlorite
7681-52-9

sodium hypochlorite

ammonia
7664-41-7

ammonia

ammonium chloride
12125-02-9

ammonium chloride

chloroamine
12190-75-9

chloroamine

Conditions
ConditionsYield
In water at -11 - -8℃; pH=~ 10;100%
In water at -15 - -7℃; pH=~ 10; Product distribution / selectivity;100%
In diethyl ether; water at -20 - -10℃; for 0.5h;
manganese(IV) oxide
1313-13-9

manganese(IV) oxide

sodium hypochlorite
7681-52-9

sodium hypochlorite

sodium hydroxide
1310-73-2

sodium hydroxide

permanganate(VII) ion

permanganate(VII) ion

Conditions
ConditionsYield
copper(II) sulfate In not given 80-90°C, 20 min; not isolated; UV/VIS spectrometry;98.5%
cobalt(II) nitrate In not given 80-90°C, 20 min; not isolated;73%
silver nitrate In not given 80-90°C, 20 min; not isolated;72%
iron(III) sulfate In not given 80-90°C, 20 min; not isolated;65%
sodium hypochlorite
7681-52-9

sodium hypochlorite

n-C3H7SO2CH3
40365-16-0

n-C3H7SO2CH3

heptafluoro-n-propyl(trichloromethyl)sulfone
40365-20-6

heptafluoro-n-propyl(trichloromethyl)sulfone

Conditions
ConditionsYield
In water 20°C, 72 h;98%
In water 20°C, 72 h;98%
sodium hypochlorite
7681-52-9

sodium hypochlorite

trisodium tri-μ-imidocyclotriphosphate

trisodium tri-μ-imidocyclotriphosphate

sodium trichloro imido metaphosphate

sodium trichloro imido metaphosphate

Conditions
ConditionsYield
In water react. of 23ml NaClO-soln. (0.294g Cl per ml soln.) with 12g Na3(PO2NH)3 within 3min (stirring, ice-cooling), dropwise addn. of 18ml aq. acetic acid (0.39g acid per ml soln.) at 12-18°C within 45min, addn. of an excess ethanol, pptn.;; extractn. with glacial acetic acid, washing with ethanol;;97%
In water react. of 23ml NaClO-soln. (0.294g Cl per ml soln.) with 12g Na3(PO2NH)3 within 3min (stirring, ice-cooling), dropwise addn. of 18ml aq. acetic acid (0.39g acid per ml soln.) at 12-18°C within 45min, addn. of an excess ethanol, pptn.;; extractn. with glacial acetic acid, washing with ethanol;;97%
5-bromopyridine-3-ol
74115-13-2

5-bromopyridine-3-ol

sodium hypochlorite
7681-52-9

sodium hypochlorite

5-bromo-2-chloro-3-hydroxypyridine
286946-77-8

5-bromo-2-chloro-3-hydroxypyridine

Conditions
ConditionsYield
With sodium hydroxide In water96%
hydrogenchloride
7647-01-0

hydrogenchloride

sodium hypochlorite
7681-52-9

sodium hypochlorite

tetramethylammonium 3,3’-commo-bis(undecahydro-1,2-dicarba-3-cobalta-closo-undecaborate)(1-)
12305-41-8

tetramethylammonium 3,3’-commo-bis(undecahydro-1,2-dicarba-3-cobalta-closo-undecaborate)(1-)

tetramethylammonium 8,8'-dichloro-3,3'-cobalt(III)[bis(1,2-dicarbollide)]

tetramethylammonium 8,8'-dichloro-3,3'-cobalt(III)[bis(1,2-dicarbollide)]

Conditions
ConditionsYield
In water addn. of excess 10% aq. NaOCl and 6 M HCl to Co-complex, stirring (25°C, 24 h); MeCN addn., shaking, sepn. of org. layer, evapn;85%
sodium hypochlorite
7681-52-9

sodium hypochlorite

1,1,1,2,3,3,3-heptafluoro-2-methanesulfinyl-propane
40365-39-7

1,1,1,2,3,3,3-heptafluoro-2-methanesulfinyl-propane

heptafluoro-n-propyl(trichloromethyl)sulfone
40365-20-6

heptafluoro-n-propyl(trichloromethyl)sulfone

Conditions
ConditionsYield
82%
82%
sodium hypochlorite
7681-52-9

sodium hypochlorite

Dodecafluor-5-trifluormethylhexyl-methyl-sulfon
40365-18-2

Dodecafluor-5-trifluormethylhexyl-methyl-sulfon

5-trifluoromethyldodecafluorohexyl(trichloromethyl)sulfone
40365-22-8

5-trifluoromethyldodecafluorohexyl(trichloromethyl)sulfone

Conditions
ConditionsYield
In water 20°C, 36 h;81%
In water 20°C, 36 h;81%
sodium hypochlorite
7681-52-9

sodium hypochlorite

sodium thiosulfate

sodium thiosulfate

A

sodium tetrathionate

sodium tetrathionate

B

sodium sulfate
7757-82-6

sodium sulfate

Conditions
ConditionsYield
In not given in very weakly acidic soln.;A 20%
B 80%
In not given in very weakly acidic soln.;A 20%
B 80%
sodium hypochlorite
7681-52-9

sodium hypochlorite

trans-chloronitrosylbis(2,2'-bipyridine)ruthenium(PF6)2

trans-chloronitrosylbis(2,2'-bipyridine)ruthenium(PF6)2

trans-{RuCl(nitro)(2,2'-bipyridine)2}(PF6)

trans-{RuCl(nitro)(2,2'-bipyridine)2}(PF6)

Conditions
ConditionsYield
In water stirred for 24 h; collected, washed with water; elem. anal.;80%
sodium hypochlorite
7681-52-9

sodium hypochlorite

ammonium hexafluorophosphate

ammonium hexafluorophosphate

[Ru(NO2)(H2O)(C5H5N)2((C5H4N)2)](1+)*PF6(1-) = [Ru(NO2)(H2O)(C5H5N)2((C5H4N)2)]PF6

[Ru(NO2)(H2O)(C5H5N)2((C5H4N)2)](1+)*PF6(1-) = [Ru(NO2)(H2O)(C5H5N)2((C5H4N)2)]PF6

[RuO(NO2)((C5H5N))2((C5H4N)2)](1+)*PF6(1-) = [RuO(NO2)((C5H5N))2((C5H4N)2)]PF6

[RuO(NO2)((C5H5N))2((C5H4N)2)](1+)*PF6(1-) = [RuO(NO2)((C5H5N))2((C5H4N)2)]PF6

Conditions
ConditionsYield
In water stirred for 2-3 h at room temp.; filtered off, washed (cold water), dried (vac.); elem. anal.;80%
sodium hypochlorite
7681-52-9

sodium hypochlorite

ammonium hexafluorophosphate

ammonium hexafluorophosphate

[Ru(NO2)(C5H5N)3((C5H4N)2)](1+)*PF6(1-) = [Ru(NO2)(C5H5N)3((C5H4N)2)]PF6

[Ru(NO2)(C5H5N)3((C5H4N)2)](1+)*PF6(1-) = [Ru(NO2)(C5H5N)3((C5H4N)2)]PF6

[RuO((C5H5N))3((C5H4N)2)](2+)*2PF6(1-) = [RuO((C5H5N))3((C5H4N)2)](PF6)2

[RuO((C5H5N))3((C5H4N)2)](2+)*2PF6(1-) = [RuO((C5H5N))3((C5H4N)2)](PF6)2

Conditions
ConditionsYield
In water stirred for 2-3 h at room temp.; filtered off, washed (cold water), dried (vac.); elem. anal.;80%
sodium hypochlorite
7681-52-9

sodium hypochlorite

[Ru(NO)(OH)(C10N2H8)(C5NH5)2](2+)*2PF6(1-) = [Ru(NO)(OH)(C10N2H8)(C5H5N)2](PF6)2

[Ru(NO)(OH)(C10N2H8)(C5NH5)2](2+)*2PF6(1-) = [Ru(NO)(OH)(C10N2H8)(C5H5N)2](PF6)2

[Ru(NO2)(O)(C10N2H8)(C5NH5)2](1+)*PF6(1-)*H2O = [Ru(NO2)(O)(C10N2H8)(C5H5N)2]PF6(H2O)

[Ru(NO2)(O)(C10N2H8)(C5NH5)2](1+)*PF6(1-)*H2O = [Ru(NO2)(O)(C10N2H8)(C5H5N)2]PF6(H2O)

Conditions
ConditionsYield
With NaOH In sodium hydroxide aq. NaOH; stirring (room temp., 2 - 3 h, pH.apprx.10); filtn., washing (cold water), drying (vac.);80%
sodium hypochlorite
7681-52-9

sodium hypochlorite

[(99)TcO(ethylene glycol)(N-benzyl-2-(1,4,7-triazononan-1-yl)acetamide)]Br
1365832-59-2

[(99)TcO(ethylene glycol)(N-benzyl-2-(1,4,7-triazononan-1-yl)acetamide)]Br

[(99)TcO3(N-benzyl-2-(1,4,7-triazononan-1-yl)acetamide)]Br*H2O
1365832-77-4

[(99)TcO3(N-benzyl-2-(1,4,7-triazononan-1-yl)acetamide)]Br*H2O

Conditions
ConditionsYield
With HCl In water according to Braband H., et al., Chem.-Eur. J., 2009, 15, 633; (N2); acidified soln. of NaOCl was added to aq. soln. of Tc compd.; reacted for 30 min; slowly evapd.; filtered; washed (satd. KBr); elem. anal.;80%
sodium hypochlorite
7681-52-9

sodium hypochlorite

cis-[Pt(1R,2R-1,2-trans-diaminocyclohexane)(NHC(O)C(CH3)3)2]*3H2O

cis-[Pt(1R,2R-1,2-trans-diaminocyclohexane)(NHC(O)C(CH3)3)2]*3H2O

water
7732-18-5

water

trans,cis,cis-[PtCl(OH)(1R,2R-1,2-trans-diaminocyclohexane)(NHC(O)C(CH3)3)2]

trans,cis,cis-[PtCl(OH)(1R,2R-1,2-trans-diaminocyclohexane)(NHC(O)C(CH3)3)2]

Conditions
ConditionsYield
In water stirred for 30 min; slowly evapd.; elem. anal.;78%
sodium hypochlorite
7681-52-9

sodium hypochlorite

C43H32NP2PtS(1+)*ClO4(1-)

C43H32NP2PtS(1+)*ClO4(1-)

C43H32NO2P2PtS(1+)*ClO4(1-)

C43H32NO2P2PtS(1+)*ClO4(1-)

Conditions
ConditionsYield
In acetonitrile at 20℃; for 1h; Inert atmosphere;78%
sodium hypochlorite
7681-52-9

sodium hypochlorite

(S)-tert-butyl 1-hydroxybutan-2-ylcarbamate
150736-72-4

(S)-tert-butyl 1-hydroxybutan-2-ylcarbamate

(2S)-2-(tert-butoxycarbonyl)aminobutyraldehyde
153371-25-6

(2S)-2-(tert-butoxycarbonyl)aminobutyraldehyde

Conditions
ConditionsYield
Stage #1: (S)-tert-butyl 1-hydroxybutan-2-ylcarbamate With 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; sodium hydrogencarbonate; sodium bromide In dichloromethane; water at 0 - 20℃;
Stage #2: sodium hypochlorite In dichloromethane; water at 0℃; for 1.16667h;
77%
sodium hypochlorite
7681-52-9

sodium hypochlorite

3-(prop-2-yn-1-yloxy)propan-1,2-diol
13580-38-6

3-(prop-2-yn-1-yloxy)propan-1,2-diol

3-(2,3,3-triiodo-2-propenyloxy)-propane-1,2-diol

3-(2,3,3-triiodo-2-propenyloxy)-propane-1,2-diol

Conditions
ConditionsYield
With sodium hydroxide; Ki; aqueous H2SO4 In water76%
With sodium hydroxide; Ki; aqueous H2SO4 In water76%
sodium hypochlorite
7681-52-9

sodium hypochlorite

1,1'-diacetylferrocene
1273-94-5

1,1'-diacetylferrocene

1,1'-bisferrocenedicarboxylic acid

1,1'-bisferrocenedicarboxylic acid

Conditions
ConditionsYield
In not given Fe-complex was reacted with NaOCl at 50°C for 5 h;75%
sodium hypochlorite
7681-52-9

sodium hypochlorite

1,1,1,2,3,3,3-heptafluoro-2-methanesulfonyl-propane
40365-17-1

1,1,1,2,3,3,3-heptafluoro-2-methanesulfonyl-propane

heptafluoroisopropyl(trichloromethyl)sulfone
40365-21-7

heptafluoroisopropyl(trichloromethyl)sulfone

Conditions
ConditionsYield
In water 20°C, 36 h;75%
In water 20°C, 36 h;75%

Sodium hypochlorite Consensus Reports

Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program.

Sodium hypochlorite Standards and Recommendations

DOT Classification:  8; Label: Corrosive

Sodium hypochlorite Specification

The Sodium hypochlorite is an organic compound with the formula NaClO. The IUPAC name of this chemical is sodium hypochlorite. With the CAS registry number 7681-52-9, it is also named as Hypochlorous acid, sodium salt. The product's categories are Industrial/Fine Chemicals; Biocide; Hypochlorites; Hypochlorites Essential Chemicals; Oxidation; Reagent Grade; Routine Reagents; Synthetic Reagents. Besides, it is colourless liquid with strong odour, which should be stored in a cool and well-ventilated place.

Physical properties about Sodium hypochlorite are: (1)ACD/LogP: 0.71; (2)ACD/LogD (pH 5.5): 0.71; (3)ACD/LogD (pH 7.4): 0.48; (4)ACD/BCF (pH 5.5): 2.03; (5)ACD/BCF (pH 7.4): 1.19; (6)#H bond acceptors: 1; (7)#H bond donors: 1; (8)Polar Surface Area: 20.23 Å2.

Preparation of Sodium hypochlorite: this is the only large scale industrial method of sodium hypochlorite production. In this process sodium hypochlorite (NaClO) and sodium chloride (NaCl) are formed when chlorine is passed into cold and dilute sodium hydroxide solution. It is prepared industrially by electrolysis with minimal separation between the anode and the cathode. The solution must be kept below 40 °C (by cooling coils) to prevent the undesired formation of sodium chlorate.
Cl2 + 2 NaOH → NaCl + NaClO + H2O

Uses of Sodium hypochlorite: in household form, sodium hypochlorite is used for removal of stains from laundry. It is particularly effective on cotton fiber, which stains easily but bleaches well. Sodium hypochlorite has been used for the disinfection of drinking water. In batch treatment operations, sodium hypochlorite has been used to treat more concentrated cyanide wastes, such as silver cyanide plating solutions. Sodium hypochlorite is now used in endodontics during root canal treatments.

When you are using this chemical, please be cautious about it as the following:
It contacts with acids liberates toxic gas and can cause burns. After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer). In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Besides, this chemical is irritating to eyes, respiratory system and skin. When you are using it, wear suitable gloves and eye/face protection. In case of accident or if you feel unwell seek medical advice immediately (show the label where possible).

You can still convert the following datas into molecular structure:
(1)SMILES: [Na+].[O-]Cl
(2)InChI: InChI=1/ClO.Na/c1-2;/q-1;+1
(3)InChIKey: SUKJFIGYRHOWBL-UHFFFAOYAD
(4)Std. InChI: InChI=1S/ClO.Na/c1-2;/q-1;+1
(5)Std. InChIKey: SUKJFIGYRHOWBL-UHFFFAOYSA-N

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
man TDLo intravenous 45mg/kg (45mg/kg) LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES

GASTROINTESTINAL: NAUSEA OR VOMITING
Annals of Emergency Medicine. Vol. 21, Pg. 1394, 1992.
mouse LD50 oral 5800mg/kg (5800mg/kg) BEHAVIORAL: CHANGES IN MOTOR ACTIVITY (SPECIFIC ASSAY)

GASTROINTESTINAL: OTHER CHANGES
Shokuhin Eiseigaku Zasshi. Food Hygiene Journal. Vol. 27, Pg. 553, 1986.
women TDLo oral 1gm/kg (1000mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

VASCULAR: BP LOWERING NOT CHARACTERIZED IN AUTONOMIC SECTION

SKIN AND APPENDAGES (SKIN): CORROSIVE: AFTER TOPICAL EXPOSURE
Human Toxicology. Vol. 7, Pg. 37, 1988.

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