Conditions | Yield |
---|---|
With sodium hydroxide; sulfuric acid In water ice cooling; distn. with H2SO4; | A n/a B n/a C 9% |
With NaOH; H2SO4 In water ice cooling; distn. with H2SO4; | A n/a B n/a C 9% |
potassium chlorate
sodium chloride
A
sodium hypochlorite
B
oxygen
C
chlorate
Conditions | Yield |
---|---|
With Na2Cr2O7 In water Electrolysis; influencce of electrode material;; |
Conditions | Yield |
---|---|
In water Electrolysis; |
Conditions | Yield |
---|---|
In water Electrolysis; | |
In water Electrolysis; chlorate formation as side reaction;; |
Conditions | Yield |
---|---|
In water Electrolysis; | |
In water Electrolysis; Schuckert-process, monopolar arrangement, vessel of enamelled iron, cooled by water; carbon electrodes or carbon electrodes covered with Pt, electrodes used as stirrer;; | |
With CrO4(1-) In water byproducts: H, chromium chromate; Electrolysis; electrolysis without diaphragm, cathode reaction; additive alkalichromates, formation of chromium chromate, which act as diaphragm;; |
Conditions | Yield |
---|---|
With chlorine In not given Electrolysis; NaOH formed at cathode and chlorine formed at anode; gas proofed anode region, asbestos diaphragm; mixing of NaOH and chlorine in a special region;; | |
With chlorine In not given Electrolysis; NaOH formed at cathode and chlorine formed at anode; anode: coal plates or rods with coke pieces; passing catholyte into anode region;; | |
With chlorine In not given Electrolysis; NaOH formed at cathode and chlorine formed at anode; cell of ungazed tone plates filled with pieces of C; alternative connection to positive and negative pole;; |
chlorine
sodium hydroxide
A
sodium hypochlorite
B
sodium chloride
Conditions | Yield |
---|---|
In neat (no solvent) 170kg NaOH, 63kg Cl2, 60°C, cyclindric rotating vessel, 1.5h;; product-mixture:24% NaClO, 25.5% NaCl, 43% NaOH;; | |
In neat (no solvent) 170kg NaOH, 63kg Cl2, 60°C, cyclindric rotating vessel, 1.5h, sintering of product to increase stability;; product-mixture:24% NaClO, 25.5% NaCl, 43% NaOH;; | |
In not given byproducts: H2O; react. is reversible;; | |
In neat (no solvent) reaction of finely atomized alkaline hydroxide soln. with Cl2;; mixture;; | |
In water |
Conditions | Yield |
---|---|
In sodium hydroxide Cl2 passed through carbonate-free soln. of NaOH at -5...0°C; | |
In water sparging chlorine into 0.3 M aq. soln. of NaOH; UV monitoring; | |
In water residual alkalinity: 1g/l; not isolated;; |
Conditions | Yield |
---|---|
With Na-phosphates In neat (no solvent) | |
With NaHSO4 or NaH2PO4 or NaO2CCO2H In water other solvents possible; addn. of the solvent to the mixture of the solid components just before use;; | |
With NaHSO4 or NaH2PO4 or NaO2CCO2H In water | |
With Na-phosphates In neat (no solvent) | |
With NaHSO4 or NaH2PO4 or NaO2CCO2H In water other solvents possible; addn. of the solvent to the mixture of the solid components just before use;; |
Conditions | Yield |
---|---|
In water react. at ion exchange resin;; solns. with 1-3% active chlorine;; | |
In water react. at ion exchange resin;; solns. with 1-3% active chlorine;; |
Conditions | Yield |
---|---|
With boric acid In water boric acid+Ca(ClO)2 in water distillation, first 100 ml distillate colected in 200 ml containing NaOH; |
calcium hypochlorite
sodium carbonate
A
sodium hypochlorite
B
sodium hydroxide
Conditions | Yield |
---|---|
In water byproducts: CaCO3; dissolving mixture of dry Ca(OCl)2, containing Ca(OH)2, and Na2CO3 in H2O;; pptn. of CaCO3; formation of a NaOCl and NaOH soln.;; |
Conditions | Yield |
---|---|
With (borax or MgCO3) In water byproducts: CaCO3; hot Na2CO3-soln. which may contain borax or MgCO3;; not isolated;; | |
In neat (no solvent) | |
With (borax or MgCO3) In water byproducts: CaCO3; hot Na2CO3-soln. which may contain borax or MgCO3;; not isolated;; | |
With sodium hydrogencarbonate In water pH=9.5; | |
In neat (no solvent) |
calcium hypochlorite
Chlorkalk
sodium carbonate
sodium hypochlorite
Conditions | Yield |
---|---|
In water byproducts: CaCO3; not isolated;; | |
In water byproducts: CaCO3; not isolated;; |
Conditions | Yield |
---|---|
With (borax or MgCO3) In water byproducts: CaCO3; hot NaHCO3-soln. which may contain borax or MgCO3;; not isolated;; | |
With (borax or MgCO3) In water byproducts: CaCO3; hot NaHCO3-soln. which may contain borax or MgCO3;; not isolated;; |
Conditions | Yield |
---|---|
With sodium hydroxide; sodium dichromate; sodium chromate(VI) In water Kinetics; Electrolysis; in a glass cylindrical cell without a diaphragm; constant pH maintainedwithin 0.05-0.1 by buffering (Na2CrO4 and Na2Cr2O7 with addn. of NaOH or HCl); expts. conducted at c.d. 10 A/l by periodic method or with continuous introduction of NaCl feed soln.; not isolated, detected by polarization curves; gas anal.; |
Conditions | Yield |
---|---|
In water Electrolysis; electrolysis of sea-water, graphite-electrodes;; not isolated;; | |
In water Electrolysis; 65-100g NaCl/l, 15°C;; | |
In water Electrolysis; apparatus described;; not isolated;; |
Conditions | Yield |
---|---|
In water byproducts: NaHCO3; Na2CO3 suspended in satd. soln., filtration of NaHCO3;; solns. with 5-12% active chlorine; not isolated;; | |
In water 100g Na2CO3/l;; <20g active chlorine per l; not isolated;; | |
In water 100g Na2CO3/l;; <20g active chlorine per l; not isolated;; | |
In water byproducts: NaHCO3; Na2CO3 suspended in satd. soln., filtration of NaHCO3;; solns. with 5-12% active chlorine; not isolated;; |
Conditions | Yield |
---|---|
With dihydrogen peroxide In water; toluene satn. of toluene with a ClO2/N2-mixture (ratio 20:80) at 0°C, neutralization with NaOH, introduction of ClO2/N2, addn. of 30% NaOH and 15-20% H2O2, separation of layers, evapn. of lower layer;; 90% NaClO;; |
sodium hypochlorite
Conditions | Yield |
---|---|
With chloroamine In water react. with a chloroamine sol. in the aq. soln. of Na-salt;; chloride-free soln.;; | |
With chloroamine In water react. with a chloroamine sol. in the aq. soln. of Na-salt;; chloride-free soln.;; |
Conditions | Yield |
---|---|
In neat (no solvent) react. of solid NaOH with Cl2O in mixture with inert gases, temp. up to 100°C;; | |
In tetrachloromethane dissolving Cl2O in CCl4, react. with NaOH at 30-50°C;; |
hypochlorous anhydride
chlorine
sodium hydroxide
sodium hypochlorite
Conditions | Yield |
---|---|
In tetrachloromethane dissolving Cl2O and Cl2 in CCl4, react. with NaOH at 30-50°C;; |
Conditions | Yield |
---|---|
In water byproducts: H, Ca(OH)2; Electrolysis; electrolysis without diaphragm, cathode reaction; additive CaCl2; formation of acidic soln. and therefore formation of ClO3 because of pptn. of Ca(OH)2;; | |
In water byproducts: H, Ca(OH)2; Electrolysis; electrolysis without diaphragm, cathode reaction; additive CaCl2; formation of acidic soln. and therefore formation of ClO3 because of pptn. of Ca(OH)2;; |
Conditions | Yield |
---|---|
In water Electrolysis; cell with diaphragm, anode compartment filled with satd. NaHCO3 soln. (not soda), cathode compartment satd. NaCl soln., low temp.;; soln. free of chloride but not stable at slightly elevated temp.;; |
chlorine azide
sodium hypochlorite
Conditions | Yield |
---|---|
With sodium hydroxide In not given byproducts: NaN3, H2O; | |
With NaOH In not given byproducts: NaN3, H2O; |
Conditions | Yield |
---|---|
In not given byproducts: H2O; | |
In not given byproducts: H2O; passing N3Cl into NaOH soln.;; |
sodium cation
sodium hypochlorite
Conditions | Yield |
---|---|
With chloride lime In not given reaction of chloride lime with sodium salts;; |
Conditions | Yield |
---|---|
In water from strongly alk. soln. by evapn. at low temp.;; solid NaClO obtained;; |
Conditions | Yield |
---|---|
In not given passing Cl into NaOH lye at temp. below 27°C; stirring; pptd. NaCl is removed; addn. of solid NaOH;; soln. of chloride chlorine and hypochlorite chlorine;; | |
With sodium carbonate In not given passing Cl into Na2CO3 soln.; formation of HClO and NaCl; reaction of HClO with acetanilide or p-nitroacetanilide to a chlorinated base, which decomposes with NaOH in NaOCl and the anilides;; | |
In not given reaction of Cl with concd. soln. of NaOH; concn. of NaOH soln. may be equivalent to NaOCl soln. or dild. NaOH soln. and addn. of NaOH to form concd. NaOCl soln.;; separation of pptd. NaCl from reaction vessel; concd. NaOCl soln. containing small amounts of chloride;; | |
With sodium carbonate In not given passing Cl into Na2CO3 soln.; formation of HClO and NaCl; reaction of HClO with acetanilide or p-nitroacetanilide to a chlorinated base, which decomposes with NaOH in NaOCl and the anilides;; |
Conditions | Yield |
---|---|
In neat (no solvent) reaction of chlorine with powdered NaOH at 0°C;; | |
With air In not given passing Cl (dild. with 4-9 Vol. air) into NaOH lye to decrease formation of NaClO3;; |
Conditions | Yield |
---|---|
In water pH=9.8 - 13.5; Product distribution / selectivity; | 100% |
With sodium hydroxide; urea In water pH=6.5 - 13.4; Product distribution / selectivity; | 1.5% |
With urea In water pH=5.6; Product distribution / selectivity; |
Conditions | Yield |
---|---|
In water at -11 - -8℃; pH=~ 10; | 100% |
In water at -15 - -7℃; pH=~ 10; Product distribution / selectivity; | 100% |
In diethyl ether; water at -20 - -10℃; for 0.5h; |
Conditions | Yield |
---|---|
copper(II) sulfate In not given 80-90°C, 20 min; not isolated; UV/VIS spectrometry; | 98.5% |
cobalt(II) nitrate In not given 80-90°C, 20 min; not isolated; | 73% |
silver nitrate In not given 80-90°C, 20 min; not isolated; | 72% |
iron(III) sulfate In not given 80-90°C, 20 min; not isolated; | 65% |
sodium hypochlorite
n-C3H7SO2CH3
heptafluoro-n-propyl(trichloromethyl)sulfone
Conditions | Yield |
---|---|
In water 20°C, 72 h; | 98% |
In water 20°C, 72 h; | 98% |
sodium hypochlorite
Conditions | Yield |
---|---|
In water react. of 23ml NaClO-soln. (0.294g Cl per ml soln.) with 12g Na3(PO2NH)3 within 3min (stirring, ice-cooling), dropwise addn. of 18ml aq. acetic acid (0.39g acid per ml soln.) at 12-18°C within 45min, addn. of an excess ethanol, pptn.;; extractn. with glacial acetic acid, washing with ethanol;; | 97% |
In water react. of 23ml NaClO-soln. (0.294g Cl per ml soln.) with 12g Na3(PO2NH)3 within 3min (stirring, ice-cooling), dropwise addn. of 18ml aq. acetic acid (0.39g acid per ml soln.) at 12-18°C within 45min, addn. of an excess ethanol, pptn.;; extractn. with glacial acetic acid, washing with ethanol;; | 97% |
5-bromopyridine-3-ol
sodium hypochlorite
5-bromo-2-chloro-3-hydroxypyridine
Conditions | Yield |
---|---|
With sodium hydroxide In water | 96% |
hydrogenchloride
sodium hypochlorite
tetramethylammonium 3,3’-commo-bis(undecahydro-1,2-dicarba-3-cobalta-closo-undecaborate)(1-)
Conditions | Yield |
---|---|
In water addn. of excess 10% aq. NaOCl and 6 M HCl to Co-complex, stirring (25°C, 24 h); MeCN addn., shaking, sepn. of org. layer, evapn; | 85% |
sodium hypochlorite
1,1,1,2,3,3,3-heptafluoro-2-methanesulfinyl-propane
heptafluoro-n-propyl(trichloromethyl)sulfone
Conditions | Yield |
---|---|
82% | |
82% |
sodium hypochlorite
Dodecafluor-5-trifluormethylhexyl-methyl-sulfon
5-trifluoromethyldodecafluorohexyl(trichloromethyl)sulfone
Conditions | Yield |
---|---|
In water 20°C, 36 h; | 81% |
In water 20°C, 36 h; | 81% |
Conditions | Yield |
---|---|
In not given in very weakly acidic soln.; | A 20% B 80% |
In not given in very weakly acidic soln.; | A 20% B 80% |
sodium hypochlorite
Conditions | Yield |
---|---|
In water stirred for 24 h; collected, washed with water; elem. anal.; | 80% |
sodium hypochlorite
Conditions | Yield |
---|---|
In water stirred for 2-3 h at room temp.; filtered off, washed (cold water), dried (vac.); elem. anal.; | 80% |
sodium hypochlorite
Conditions | Yield |
---|---|
In water stirred for 2-3 h at room temp.; filtered off, washed (cold water), dried (vac.); elem. anal.; | 80% |
sodium hypochlorite
Conditions | Yield |
---|---|
With NaOH In sodium hydroxide aq. NaOH; stirring (room temp., 2 - 3 h, pH.apprx.10); filtn., washing (cold water), drying (vac.); | 80% |
sodium hypochlorite
[(99)TcO(ethylene glycol)(N-benzyl-2-(1,4,7-triazononan-1-yl)acetamide)]Br
[(99)TcO3(N-benzyl-2-(1,4,7-triazononan-1-yl)acetamide)]Br*H2O
Conditions | Yield |
---|---|
With HCl In water according to Braband H., et al., Chem.-Eur. J., 2009, 15, 633; (N2); acidified soln. of NaOCl was added to aq. soln. of Tc compd.; reacted for 30 min; slowly evapd.; filtered; washed (satd. KBr); elem. anal.; | 80% |
Conditions | Yield |
---|---|
In water stirred for 30 min; slowly evapd.; elem. anal.; | 78% |
Conditions | Yield |
---|---|
In acetonitrile at 20℃; for 1h; Inert atmosphere; | 78% |
sodium hypochlorite
(S)-tert-butyl 1-hydroxybutan-2-ylcarbamate
(2S)-2-(tert-butoxycarbonyl)aminobutyraldehyde
Conditions | Yield |
---|---|
Stage #1: (S)-tert-butyl 1-hydroxybutan-2-ylcarbamate With 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; sodium hydrogencarbonate; sodium bromide In dichloromethane; water at 0 - 20℃; Stage #2: sodium hypochlorite In dichloromethane; water at 0℃; for 1.16667h; | 77% |
sodium hypochlorite
3-(prop-2-yn-1-yloxy)propan-1,2-diol
Conditions | Yield |
---|---|
With sodium hydroxide; Ki; aqueous H2SO4 In water | 76% |
With sodium hydroxide; Ki; aqueous H2SO4 In water | 76% |
Conditions | Yield |
---|---|
In not given Fe-complex was reacted with NaOCl at 50°C for 5 h; | 75% |
sodium hypochlorite
1,1,1,2,3,3,3-heptafluoro-2-methanesulfonyl-propane
heptafluoroisopropyl(trichloromethyl)sulfone
Conditions | Yield |
---|---|
In water 20°C, 36 h; | 75% |
In water 20°C, 36 h; | 75% |
The Sodium hypochlorite is an organic compound with the formula NaClO. The IUPAC name of this chemical is sodium hypochlorite. With the CAS registry number 7681-52-9, it is also named as Hypochlorous acid, sodium salt. The product's categories are Industrial/Fine Chemicals; Biocide; Hypochlorites; Hypochlorites Essential Chemicals; Oxidation; Reagent Grade; Routine Reagents; Synthetic Reagents. Besides, it is colourless liquid with strong odour, which should be stored in a cool and well-ventilated place.
Physical properties about Sodium hypochlorite are: (1)ACD/LogP: 0.71; (2)ACD/LogD (pH 5.5): 0.71; (3)ACD/LogD (pH 7.4): 0.48; (4)ACD/BCF (pH 5.5): 2.03; (5)ACD/BCF (pH 7.4): 1.19; (6)#H bond acceptors: 1; (7)#H bond donors: 1; (8)Polar Surface Area: 20.23 Å2.
Preparation of Sodium hypochlorite: this is the only large scale industrial method of sodium hypochlorite production. In this process sodium hypochlorite (NaClO) and sodium chloride (NaCl) are formed when chlorine is passed into cold and dilute sodium hydroxide solution. It is prepared industrially by electrolysis with minimal separation between the anode and the cathode. The solution must be kept below 40 °C (by cooling coils) to prevent the undesired formation of sodium chlorate.
Cl2 + 2 NaOH → NaCl + NaClO + H2O
Uses of Sodium hypochlorite: in household form, sodium hypochlorite is used for removal of stains from laundry. It is particularly effective on cotton fiber, which stains easily but bleaches well. Sodium hypochlorite has been used for the disinfection of drinking water. In batch treatment operations, sodium hypochlorite has been used to treat more concentrated cyanide wastes, such as silver cyanide plating solutions. Sodium hypochlorite is now used in endodontics during root canal treatments.
When you are using this chemical, please be cautious about it as the following:
It contacts with acids liberates toxic gas and can cause burns. After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer). In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Besides, this chemical is irritating to eyes, respiratory system and skin. When you are using it, wear suitable gloves and eye/face protection. In case of accident or if you feel unwell seek medical advice immediately (show the label where possible).
You can still convert the following datas into molecular structure:
(1)SMILES: [Na+].[O-]Cl
(2)InChI: InChI=1/ClO.Na/c1-2;/q-1;+1
(3)InChIKey: SUKJFIGYRHOWBL-UHFFFAOYAD
(4)Std. InChI: InChI=1S/ClO.Na/c1-2;/q-1;+1
(5)Std. InChIKey: SUKJFIGYRHOWBL-UHFFFAOYSA-N
The toxicity data is as follows:
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
man | TDLo | intravenous | 45mg/kg (45mg/kg) | LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES GASTROINTESTINAL: NAUSEA OR VOMITING | Annals of Emergency Medicine. Vol. 21, Pg. 1394, 1992. |
mouse | LD50 | oral | 5800mg/kg (5800mg/kg) | BEHAVIORAL: CHANGES IN MOTOR ACTIVITY (SPECIFIC ASSAY) GASTROINTESTINAL: OTHER CHANGES | Shokuhin Eiseigaku Zasshi. Food Hygiene Journal. Vol. 27, Pg. 553, 1986. |
women | TDLo | oral | 1gm/kg (1000mg/kg) | BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) VASCULAR: BP LOWERING NOT CHARACTERIZED IN AUTONOMIC SECTION SKIN AND APPENDAGES (SKIN): CORROSIVE: AFTER TOPICAL EXPOSURE | Human Toxicology. Vol. 7, Pg. 37, 1988. |
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