THIOPHOSGENE supplier | CasNO.463-71-8

Name
Thiophosgene
EINECS 207-341-6
CAS No. 463-71-8
Article Data64
CAS DataBase
Density 1.508
Solubility Decomposes SOLVENT − and SO_x. See also PHOSGENE.
Risk Codes R22;R23;R36/37/38
Molecular Structure
Hazard Symbols
Synonyms Thiophosgene(6CI,8CI);Carbon chlorosulfide;Carbonic dichloride, thio-;Carbonyl sulfidedichloride;Dichlorothiocarbonyl;Dichlorothioformaldehyde;Thiocarbonicdichloride;Thiocarbonyl chloride;Thiocarbonyl dichloride;
PSA 32.09000
LogP 1.74890

Synthetic route

: 56-23-5
tetrachloromethane

: 463-71-8
thiophosgene

Conditions

Conditions	Yield
With hydrogen sulfide Durchleiten durch eine gluehende Roehre;
With iron sulfide at 420 - 450℃;
With sulfur

: 15110-08-4
Bis(trichloromethyl)disulfane

A: 463-71-8
thiophosgene

B: 594-42-3
chlorothio-trichloro-methane

Conditions

Conditions	Yield
bei der Destillation unter gewoehnlichem Druck;

: ethyl-trichloromethyl sulfone

: 463-71-8
thiophosgene

Conditions

Conditions	Yield
Zersetzung beider Destillation unter gewoenlichem Druck;

: 96-36-6, 868-85-9
methyl phosphite

: 594-42-3
chlorothio-trichloro-methane

A: 463-71-8
thiophosgene

B: 119185-96-5
thiophosphoric acid O,O'-dimethyl ester-S-trichloromethyl ester

C: 813-77-4
Dimethyl chlorophosphate

...Expand

: 620-40-6
tribenzylamine

: 594-42-3
chlorothio-trichloro-methane

A: 463-71-8
thiophosgene

B: 100-44-7
benzyl chloride

Conditions

Conditions	Yield
at 100℃;

...Expand

: 594-42-3
chlorothio-trichloro-methane

: 762-04-9
phosphonic acid diethyl ester

A: 463-71-8
thiophosgene

B: 1189-83-9
thiophosphoric acid O,O'-diethyl ester-S-trichloromethyl ester

C: 814-49-3
diethyl chlorophosphate

...Expand

: 594-42-3
chlorothio-trichloro-methane

: 463-71-8
thiophosgene

: 20464-23-7
Dithiophosgen

petroleum ether: petroleum ether

: 463-71-8
thiophosgene

Conditions

Conditions	Yield
mit ultraviolettem Licht.Irradiation;

: 7647-01-0
hydrogenchloride

: 594-42-3
chlorothio-trichloro-methane

SnCl2: SnCl2

: 463-71-8
thiophosgene

...Expand

: 7647-01-0
hydrogenchloride

: 594-42-3
chlorothio-trichloro-methane

tin: tin

: 463-71-8
thiophosgene

...Expand

: 7647-01-0
hydrogenchloride

: 594-42-3
chlorothio-trichloro-methane

iron: iron

A: 56-23-5
tetrachloromethane

B: 463-71-8
thiophosgene

...Expand

: 64-19-7
acetic acid

: 594-42-3
chlorothio-trichloro-methane

iron: iron

A: 56-23-5
tetrachloromethane

B: 463-71-8
thiophosgene

...Expand

: 594-42-3
chlorothio-trichloro-methane

sulfur: sulfur

A: 56-23-5
tetrachloromethane

B: 463-71-8
thiophosgene

C: 15110-08-4
Bis(trichloromethyl)disulfane

D: 2532-50-5
perchlorodimethyltrisulfane

Conditions

Conditions	Yield
at 150 - 160℃;

...Expand

: 594-42-3
chlorothio-trichloro-methane

A: 56-23-5
tetrachloromethane

B: 463-71-8
thiophosgene

C disulfur dichloride: disulfur dichloride

Conditions

Conditions	Yield
at 20 - 25℃; UV-Bestrahlung unter Ausschluss von Luftfeuchtigkeit.Irradiation;

...Expand

: 56-23-5
tetrachloromethane

: 7553-56-2
iodine

iron sulfide: iron sulfide

: 463-71-8
thiophosgene

Conditions

Conditions	Yield
at 200℃;

...Expand

: 56-23-5
tetrachloromethane

: 7553-56-2
iodine

sulfur: sulfur

: 463-71-8
thiophosgene

Conditions

Conditions	Yield
at 200℃;

...Expand

: 556-64-9
methyl thiocyanate

: 7782-50-5
chlorine

A: 7647-01-0
hydrogenchloride

B: 463-71-8
thiophosgene

C: 594-42-3
chlorothio-trichloro-methane

Conditions

Conditions	Yield
namentlich an der Sonne;

...Expand

: 75-15-0
carbon disulfide

: 7782-50-5
chlorine

A: 56-23-5
tetrachloromethane

B: 463-71-8
thiophosgene

C disulfur dichloride: disulfur dichloride

Conditions

Conditions	Yield
bei gewoehnlicher Temperatur;

...Expand

: 556-64-9
methyl thiocyanate

A: 463-71-8
thiophosgene

B cyanuric acid chloride,perchloromethyl mercaptan: cyanuric acid chloride,perchloromethyl mercaptan

Conditions

Conditions	Yield
With chlorine

: 56-23-5
tetrachloromethane

A: 463-71-8
thiophosgene

B disulfur dichloride: disulfur dichloride

Conditions

Conditions	Yield
With sulfur at 180 - 200℃;

: 2532-50-5
perchlorodimethyltrisulfane

A: 56-23-5
tetrachloromethane

B: 463-71-8
thiophosgene

C: 594-42-3
chlorothio-trichloro-methane

D disulfur dichloride: disulfur dichloride

Conditions

Conditions	Yield
bei der Destillation unter gewoehnlichem Druck;
bei der Destillation unter gewoehnlichem Druck; Produkt5:Schwefelkohlenstoff;

...Expand

: 1454-96-2
chloromethyl-trichloromethyl sulfide

A: 56-23-5
tetrachloromethane

B: 463-71-8
thiophosgene

C: 67-66-3
chloroform

D S2cl2: S2cl2

Conditions

Conditions	Yield
at 20 - 25℃; bei der Chlorierung im UV-Licht;Produkt 5:Perchlormethylmercaptan;Produkt 6:Pentachlordimethylsulfid(?);Produkt 7:Hexachlordimethylsulfid(?).Irradiation;

...Expand

: phenyl-phosphinecarbothioic acid-thioanhydride

: 7782-50-5
chlorine

A: 7647-01-0
hydrogenchloride

B: 463-71-8
thiophosgene

C: 3497-00-5
phenylthiophosphonic acid dichloride

D phenylorthophosphinic acid tetrachloride: phenylorthophosphinic acid tetrachloride

...Expand

: 75-44-5
phosgene

: 463-71-8
thiophosgene

: 7783-06-4
hydrogen sulfide

: 594-42-3
chlorothio-trichloro-methane

: 463-71-8
thiophosgene

Conditions

Conditions	Yield
With iodine In acetic acid Kinetics; byproducts: HCl, S; 20°C, 96% acetic acid;
With iodine In acetic acid Kinetics; byproducts: HCl, S; 20°C, 96% acetic acid;

: 75-15-0
carbon disulfide

: 7782-50-5
chlorine

A: 10025-67-9
disulfur dichloride

B: 56-23-5
tetrachloromethane

C: 463-71-8
thiophosgene

Conditions

Conditions	Yield
In gas passing through glowing tube of porcelaine;;

...Expand

: 463-71-8
thiophosgene

: 64-04-0
phenethylamine

: 2257-09-2
Phenethyl isothiocyanate

Conditions

Conditions	Yield
With triethylamine In tetrahydrofuran at 0 - 20℃; for 1h;	100%
With sodium hydrogencarbonate In chloroform; water	90%
With water
In chloroform Heating;
With sodium hydroxide

: 463-71-8
thiophosgene

: 87504-24-3
1-(butylcarbamoyl)-1,3-dihydrobenz-imidazole-2-thione

: 90714-94-6
3-Butyl-2-thioxo-2,3-dihydro-1-thia-3,4a,9-triaza-fluoren-4-one

Conditions

Conditions	Yield
With triethylamine In acetone for 1h; Ambient temperature;	100%

: 463-71-8
thiophosgene

: 143603-29-6
4-amino-1-<1-(2-benzothienyl)cyclohexyl>-piperidine

: 143603-19-4
1-<1-(2-benzothienyl)cyclohexyl>-4-isothiocyanatopiperidine

Conditions

Conditions	Yield
With sodium hydrogencarbonate In chloroform at 20℃; for 0.166667h;	100%

: 463-71-8
thiophosgene

: 143603-44-5
trans-1-<4-amino-1-(2-benzothienyl)cyclohexyl>piperidine dihydrochloride

: 143603-62-7
trans-1-<1-(2-benzothienyl)-4-isothiocyanatocyclohexyl>piperidine hydrochloride

Conditions

Conditions	Yield
With sodium hydrogencarbonate In chloroform at 20℃; for 0.166667h;	100%

: 463-71-8
thiophosgene

: 79207-56-0
2-Ethoxy-5,5-dimethyl-2-thiazolin

: 81562-45-0
C11H16N2O2S3

Conditions

Conditions	Yield
at 90℃;	100%

: 463-71-8
thiophosgene

: 4815-24-1
2-amino-4,5-dimethyl-3-thiophenecarboxylic acid ethyl ester

: 85716-85-4
ethyl 2-isothiocyanato-4,5-dimethylthiophene-3-carboxylate

Conditions

Conditions	Yield
With calcium carbonate In chloroform; water at 0℃; for 3.5h;	100%
In acetone at 20℃; for 0.25h;	90%
With sodium hydrogencarbonate In chloroform for 0.5h;	83%

: 463-71-8
thiophosgene

: 3,5-di-O-benzoyl-D-xylofuranose

: 191538-37-1
3,5-di-O-benzoyl-α-D-xylo-furanose 1,2-thiocarbonate

Conditions

Conditions	Yield
With dmap; N-ethyl-N,N-diisopropylamine In dichloromethane for 0.25h;	100%

: 463-71-8
thiophosgene

: C27H24O9

: C28H22O9S

Conditions

Conditions	Yield
With dmap; N-ethyl-N,N-diisopropylamine In dichloromethane for 0.25h;	100%

: 463-71-8
thiophosgene

: 130707-75-4
α-[2-(4-aminophenyl)ethyl]-1,4,7,10-tetraazacyclododecane-1,4,7,10-tetraacetic acid

: α-[2-(4-isothiocyanatophenyl)-ethyl]-1,4,7,10-tetraazacyclododecane-1,4,7,10-tetraacetic acid

Conditions

Conditions	Yield
In chloroform; water at 20℃; for 2h; Condensation;	100%

: 463-71-8
thiophosgene

: 10227-29-9
methyl 2,3-di-O-methyl-β-D-glucopyranoside

: 372519-54-5
methyl 6-O-chlorothiocarbonyl-2,3-di-O-methyl-β-D-glucopyranoside

Conditions

Conditions	Yield
Stage #1: methyl 2,3-di-O-methyl-β-D-glucopyranoside With di(n-butyl)tin oxide In toluene for 2h; Heating; Stage #2: thiophosgene In toluene at 20℃; for 0.5h;	100%

: 463-71-8
thiophosgene

(Neu5Acα2,6-Galβ1,4-GlcNAcβ1,2-Manα1,6)(Neu5Acα2,6-Galβ1,4-GlcNAcβ1,2-Manα1,3)-Manβ1,4-GlcNAcβ1,4(Fucα1,6)-GlcNAcβ-NHCO(CH2)5NH2: (Neu5Acα2,6-Galβ1,4-GlcNAcβ1,2-Manα1,6)(Neu5Acα2,6-Galβ1,4-GlcNAcβ1,2-Manα1,3)-Manβ1,4-GlcNAcβ1,4(Fucα1,6)-GlcNAcβ-NHCO(CH2)5NH2

(Neu5Acα2,6-Galβ1,4-GlcNAcβ1,2-Manα1,6)(Neu5Acα2,6-Galβ1,4-GlcNAcβ1,2-Manα1,3)-Manβ1,4-GlcNAcβ1,4(Fucα1,6)-GlcNAcβ-NHCO(CH2)5NCS: (Neu5Acα2,6-Galβ1,4-GlcNAcβ1,2-Manα1,6)(Neu5Acα2,6-Galβ1,4-GlcNAcβ1,2-Manα1,3)-Manβ1,4-GlcNAcβ1,4(Fucα1,6)-GlcNAcβ-NHCO(CH2)5NCS

Conditions

Conditions	Yield
With sodium hydrogencarbonate In dichloromethane for 1.5h; pH=8.5;	100%

: 463-71-8
thiophosgene

(Neu5Acα2,3-Galβ1,4-GlcNAcβ1,2-Manα1,6)(Neu5Acα2,3-Galβ1,4-GlcNAcβ1,2-Manα1,3)-Manβ1,4-GlcNAcβ1,4(Fucα1,6)-GlcNAcβ-NHCO(CH2)5NH2: (Neu5Acα2,3-Galβ1,4-GlcNAcβ1,2-Manα1,6)(Neu5Acα2,3-Galβ1,4-GlcNAcβ1,2-Manα1,3)-Manβ1,4-GlcNAcβ1,4(Fucα1,6)-GlcNAcβ-NHCO(CH2)5NH2

(Neu5Acα2,3-Galβ1,4-GlcNAcβ1,2-Manα1,6)(Neu5Acα2,3-Galβ1,4-GlcNAcβ1,2-Manα1,3)-Manβ1,4-GlcNAcβ1,4(Fucα1,6)-GlcNAcβ-NHCO(CH2)5NCS: (Neu5Acα2,3-Galβ1,4-GlcNAcβ1,2-Manα1,6)(Neu5Acα2,3-Galβ1,4-GlcNAcβ1,2-Manα1,3)-Manβ1,4-GlcNAcβ1,4(Fucα1,6)-GlcNAcβ-NHCO(CH2)5NCS

Conditions

Conditions	Yield
With sodium hydrogencarbonate In dichloromethane for 1.5h; pH=8.5;	100%

: 463-71-8
thiophosgene

: 803733-52-0
2-[bis(carboxymethyl)aminomethyl]-2-[(4-nitrobenzyl)oxymethyl]propylene-1,3-dinitrilotetraacetic acid

: 2-[bis(carboxymethyl)aminomethyl]-2-[(4-isothiocyanatobenzyl)oxymethyl]propylene-1,3-dinitrilotetraacetic acid

Conditions

Conditions	Yield
Stage #1: 2-[bis(carboxymethyl)aminomethyl]-2-[(4-nitrobenzyl)oxymethyl]propylene-1,3-dinitrilotetraacetic acid With hydrogen; sodium carbonate; palladium on activated charcoal In water for 4.5h; Stage #2: thiophosgene In chloroform; water for 1h; Further stages.;	100%

: H5EPTPA-bz-NH2

: 463-71-8
thiophosgene

: {[1-({[3-(bis-carboxymethyl-amino)-propyl]-carboxymethyl-amino}-methyl)-2-(4-isothiocyanato-phenyl)-ethyl]-carboxymethyl-amino}-acetic acid

Conditions

Conditions	Yield
With hydrogenchloride In tetrachloromethane at 20℃; for 5h;	100%
With triethylamine In tetrahydrofuran for 12h; Inert atmosphere;	83.7%

: 463-71-8
thiophosgene

: 10-(4-aminophenyl)-2,8-diethyl-5,5-difluoro-1,3,7,9-tetramethyl-5H-dipyrrolo[1,2-c:2′,1′-f ]-[1,3,2]diazaborinin-4-ium-5-uide

: 4,4-difluoro-8-(4-isothiocyanatophenyl)-1,3,5,7-tetramethyl-2,6-diethyl-4-bora-3a,4a-diaza-s-indacene

Conditions

Conditions	Yield
In tetrahydrofuran at 70℃;	100%
With boron trifluoride diethyl etherate; triethylamine In dichloromethane at 0℃;	100%
In tetrahydrofuran treatment of boron compd. with 1 equiv. of thiophosgene in THF at 70°C;	100%
With triethylamine In dichloromethane at 0 - 20℃; for 0.25h; Inert atmosphere;

: 463-71-8
thiophosgene

: 207121-91-3
(S)-2-amino-N-benzyl-3,3-dimethylbutanamide

: 479423-19-3
(2S)-N-benzyl-2-isothiocyanato-3,3-dimethylbutanamide

Conditions

Conditions	Yield
With sodium hydrogencarbonate In dichloromethane at 5℃; for 0.333333h;	100%
With sodium hydrogencarbonate In dichloromethane at 0℃;
With sodium hydrogencarbonate In dichloromethane; water at 5℃; for 0.5h; Saturated solution;

: C23H28BF2N3

: 463-71-8
thiophosgene

: C24H26BF2N3S

Conditions

Conditions	Yield
In tetrahydrofuran at 70℃;	100%

: 463-71-8
thiophosgene

: 98-18-0
m-aminobenzenesulfonamide

: 23165-62-0
3-isothiocyanato-benzenesulfonamide

Conditions

Conditions	Yield
With sodium carbonate In water; acetone at 0 - 20℃; for 0.333333h;	100%
With hydrogenchloride In water at 20℃;	81%
In chloroform at 20℃; for 2h;
With hydrogenchloride
With triethylamine In tetrahydrofuran at 0 - 20℃; for 2.5h; Inert atmosphere;

: 5754-35-8
2-[1,3]dioxolan-2-yl-ethylamine

: 463-71-8
thiophosgene

: 1246860-85-4
C6H9NO2S

Conditions

Conditions	Yield
With calcium carbonate In dichloromethane; water at 20℃; for 18.0833h;	100%

: 960389-53-1
1-(3-bromophenyl)-1-(3-furyl)methanamine

: 463-71-8
thiophosgene

: 960389-55-3
3-[(3-Bromophenyl)(isothiocyanato)methyl]furan

Conditions

Conditions	Yield
With sodium hydrogencarbonate In dichloromethane; water at 0 - 20℃; for 1.5h;	100%
With sodium hydrogencarbonate In dichloromethane; water at 0 - 20℃; for 1.5h;	100%

: 463-71-8
thiophosgene

: 88-17-5
2-(trifluoromethyl)benzenamine

: 1743-86-8
2-(trifluoromethyl)phenyl isothiocyanate

Conditions

Conditions	Yield
In water at 20℃; for 12h;	100%
With sodium hydrogencarbonate In water at 0 - 20℃; for 24h; Inert atmosphere;	95%
With triethylamine In dichloromethane at 20℃; for 1h;

: 463-71-8
thiophosgene

: 170230-87-2
4'-amino-3'-ethylbenzonitrile

: 285124-08-5
4-cyano-2-ethylphenyl isothiocyanate

Conditions

Conditions	Yield
In toluene for 5h; Heating / reflux;	100%

: 78242-79-2
2-chloro-4-cyclopropylaniline

: 463-71-8
thiophosgene

: 871477-11-1
C10H8ClNS

Conditions

Conditions	Yield
With triethylamine In acetonitrile at 20℃; for 3h;	100%
With sodium hydrogencarbonate In dichloromethane at 20℃; for 1h;

: 871942-50-6
1-(3-bromophenyl)-1-[4-(trifluoromethoxy)phenyl]methanamine

: 463-71-8
thiophosgene

: 871942-51-7
1-bromo-3-{isothiocyanato[4-(trifluoromethoxy)phenyl]methyl}benzene

Conditions

Conditions	Yield
With sodium hydrogencarbonate In dichloromethane; water for 0.5h;	100%
With sodium hydrogencarbonate In dichloromethane; water for 0.5h; Inert atmosphere; Cooling with ice;

: p-[trans-4-(5-hexenyl)cyclohexyl]aniline

: 463-71-8
thiophosgene

: 108830-84-8
p-[trans-4-(5-hexenyl)cyclohexyl]phenylisothiocyanate

Conditions

Conditions	Yield
With triethylamine In chloroform; ethyl acetate; Petroleum ether	100%

: 463-71-8
thiophosgene

: 101349-30-8
methyl 4-amino-3-chlorobenzene-1-acetate

: methyl (3-chloro-4-isothiocyanatophenyl)acetate

Conditions

Conditions	Yield
With calcium carbonate In methylene chloride-water; dichloromethane	100%
With calcium carbonate In dichloromethane; water at 0 - 20℃; for 1.5h;	100%

: 463-71-8
thiophosgene

: 29632-74-4
2-fluro-4-iodoaniline

: 945530-32-5
2-fluoro-4-iodo-1-isothiocyanatobenzene

Conditions

Conditions	Yield
In chloroform; water at 20℃; for 16h;	100%
In chloroform; water at 20℃; for 16h;	100%
In dichloromethane; water at 20℃;	96.8%

: 39745-40-9
2-chloro-6-methyl-3-aminopyridine

: 463-71-8
thiophosgene

: 945988-81-8
2-chloro-3-isothiocyanato-6-methylpyridine

Conditions

Conditions	Yield
With sodium carbonate In dichloromethane at 20℃;	100%

: 1001847-07-9
C63H79F2NO18Si

: 463-71-8
thiophosgene

: 1001847-22-8
C64H77F2NO18SSi

Conditions

Conditions	Yield
With dmap In dichloromethane at 20℃; for 2h;	100%

: 463-71-8
thiophosgene

: 1146956-35-5
p-aminophenyl-di-tert-butylfluorosilane

: 1146956-40-2
di-tert-butylfluoro(4-isothiocyanatophenyl)silane

Conditions

Conditions	Yield
In toluene at 0℃; Reflux;	100%

THIOPHOSGENE Chemical Properties

IUPAC Name:Thiocarbonyl dichloride (463-71-8)
Synonyms: Carbon chlorosulfide ; Carbonchlorosulfide ; Carbonic dichloride, thio-; Carbonothioicdichloride ; Carbonyl chloride, thio- ; CSCl₂; Dichlorothiocarbonyl ; Phosgene, thio-
CAS: 463-71-8
MF: CCl₂S
MW: 114.98
MS:
EINECS: 207-341-6
Product Categories: Organics
Mol File: 463-71-8.mol
Surface Tension: 51.8 dyne/cm
Density: 1.579 g/cm³
Enthalpy of Vaporization: 30.13 kJ/mol
Boiling Point: 73 °C at 760 mmHg
Flashing point: 62 °C
Vapour Pressure: 127 mmHg at 25°C
Vapor density: 4 (vs air)
Refractive index: n20/D 1.548(lit.)
Storage temp: 2-8°C
Water Solubility : slow decomposition in cold, fast in hot water
Stability: Thiophosgene (463-71-8) is stable. but reacts violently with water to produce toxic fumes. Incompatible with water, alcohols. Refrigerate at 2-8°C

THIOPHOSGENE Uses

Thiophosgene (463-71-8) is intermediates in the preparation of sulfur acaricide Diafenthiuron, but also an important intermediate in the preparation of thio carbamate insecticides and herbicides.

THIOPHOSGENE Production

Phosgene sulfu is obtained by the reduction of Chloride methyl mercaptan. add potassium iodide into a mixture of entire chlorine methyl mercaptan, tetrachloroethane and water with stirring; add sulfur dioxide at room temperatur,with temperature automatically rising in the reaction , adjust ventilation to maintain the temperature at 50 ~ 70 °C. When temperature of reaction solution is not rising and sulfur dioxide absorption is no longer apparent, stop ventiling, put it aside until it is cool, take the sub-fractionation o organic layer , collect sulfur phosgene distillated below76 °C.

THIOPHOSGENE Toxicity Data With Reference

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
mouse	LD50	intravenous	100mg/kg (100mg/kg)		U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#04557,
rat	LD50	oral	929mg/kg (929mg/kg)		"Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku," Marhold, J.V., Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha, Czechoslovakia, 1972Vol. -, Pg. 13, 1972.

THIOPHOSGENE Safety Profile

Hazard Codes: T
Risk Statements: 22-23-36/37/38
22: Thiophosgene (463-71-8) is harmful if swallowed
23: Toxic by inhalation
36/37/38: Irritating to eyes, respiratory system and skin
Safety Statements: 7-9-36/37-45
36/37: Wear suitable protective clothing and gloves
7/9: Keep container tightly closed and in a well-ventilated place
45: In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
RIDADR: UN 2474 6.1/PG 2
WGK Germany: 1
RTECS: XN2450000
F :19-21
HazardClass: 6.1(a)
PackingGroup: II

THIOPHOSGENE Standards and Recommendations

DOT Classification: 6.1; Label: Poison

THIOPHOSGENE Specification

Chemical Properties: Thiophosgene (463-71-8) is reddish liquid .
General Description: A reddish liquid. Boiling point 73.5°C. A severe eye irritant. May severely burn skin on contact. Very toxic by inhalation and by skin absorption.
Air & Water Reactions: Reacts with water to evolve hydrogen chloride, carbon disulfide, and carbon dioxide. Reaction is slow unless the water is hot.
Reactivity Profile: Thiophosgene is incompatible with acids, diazo and azo compounds, halocarbons, isocyanates, aldehydes, alkali metals, nitrides, hydrides, and other strong reducing agents. Reactions with these materials generate heat and in many cases hydrogen gas. Liberates hydrogen sulfide upon reaction with acids.
Health Hazard: Inhalation causes irritation of respiratory system and delayed pulmonary edema. Vapor irritates eyes. Liquid burns skin and eyes. Ingestion causes irritation of mouth and stomach.

Product Name

Thiophosgene

Synthetic route

THIOPHOSGENE Chemical Properties

THIOPHOSGENE Uses

THIOPHOSGENE Production

THIOPHOSGENE Toxicity Data With Reference

THIOPHOSGENE Safety Profile

THIOPHOSGENE Standards and Recommendations

THIOPHOSGENE Specification

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