Zirconyl chloride octahydrate supplier

Name
Zirconyl chloride octahydrate
EINECS 231-717-9
CAS No. 13520-92-8
Density 1.91 g/cm³
Solubility soluble in water
Melting Point 400 °C (dec.)
Formula ZrOCl₂^.8(H₂O)
Boiling Point 210°C
Molecular Weight 322.252
Flash Point
Transport Information
Appearance solid
Safety 26-36/37/39-45-27
Risk Codes 34-22
Molecular Structure
Hazard Symbols C
Synonyms Dichlorooxozirconiumoctahydrate;Zirconium chloride oxide (ZrCl2O) octahydrate;Zirconium chlorideoxide, octahydrate;Zirconium dichloride monoxide octahydrate;Zirconiumdichloride oxide octahydrate;Zirconium monoxide dichloride octahydrate;Zirconium oxy dichloride octahydrate;Zirconium oxychloride octahydrate (ZrOCl2.8H2O);
PSA 90.91000
LogP 0.74580

Synthetic route

: 7647-01-0
hydrogenchloride

: zirconium(IV) carbonate

: 13520-92-8
ziconium(IV) oxychloride octahydrate

Conditions

Conditions	Yield
In hydrogenchloride byproducts: CO2; Zr(CO3)2 dissolved in concd. HCl, refluxed for 1 h; cooled, filtered, washed with cold concd. HCl, recrystd. from aq. HCl, air dried;

: 13520-92-8
ziconium(IV) oxychloride octahydrate

: 756-79-6
dimethyl methane phosphonate

: zirconium bis(methylphosphonate)

Conditions

Conditions	Yield
With aq. HCl In water reflux (24 h or 112 h); aq. HBr or H2O alone may also be used; filtration, washing (H2O; acetone), drying (40°C, 18 h, then 200°C, 24 h); elem. anal.;	99%

: 13520-92-8
ziconium(IV) oxychloride octahydrate

: 594-45-6
ethanesulfonic acid

: zirconium acetate hydroxide

: 7732-18-5
water

: C2H3O2(1-)*Zr(4+)*0.8H2O*0.9O(2-)*0.2C2H5O3S(1-)*HO(1-)

Conditions

Conditions	Yield
In water	95%

...Expand

: 13520-92-8
ziconium(IV) oxychloride octahydrate

: 594-45-6
ethanesulfonic acid

: zirconium acetate hydroxide

: 7732-18-5
water

: C2H3O2(1-)*Zr(4+)*0.5H2O*1.25O(2-)*0.5C2H5O3S(1-)

Conditions

Conditions	Yield
In water	95%

...Expand

: 13520-92-8
ziconium(IV) oxychloride octahydrate

: 594-45-6
ethanesulfonic acid

: zirconium acetate hydroxide

: 7732-18-5
water

: 0.6C2H3O2(1-)*Zr(4+)*2H2O*1.3O(2-)*0.8C2H5O3S(1-)

Conditions

Conditions	Yield
In water	95%

...Expand

: 13520-92-8
ziconium(IV) oxychloride octahydrate

: 594-45-6
ethanesulfonic acid

: zirconium acetate hydroxide

: 7732-18-5
water

: 0.4C2H3O2(1-)*Zr(4+)*2.2H2O*0.9O(2-)*1.8C2H5O3S(1-)

Conditions

Conditions	Yield
In water	95%

...Expand

: 13520-92-8
ziconium(IV) oxychloride octahydrate

: 594-45-6
ethanesulfonic acid

: zirconium acetate hydroxide

: 7732-18-5
water

: Zr(4+)*3H2O*0.6O(2-)*2.8C2H5O3S(1-)

Conditions

Conditions	Yield
In water	95%

...Expand

: 13520-92-8
ziconium(IV) oxychloride octahydrate

: 10213-10-2
sodium tungstate (VI) dihydrate

: ZrW2O7((OH)1.5Cl0.5)*2H2O

Conditions

Conditions	Yield
With hydrogenchloride In water at 160℃; Autoclave;	95%

: 13520-92-8
ziconium(IV) oxychloride octahydrate

: 142-45-0
Acetylenedicarboxylic acid

: Zr6O4(OH)4(12+)*6C4O4(2-)

Conditions

Conditions	Yield
Stage #1: ziconium(IV) oxychloride octahydrate; Acetylenedicarboxylic acid With acetic acid In N,N-dimethyl-formamide Sonication; Stage #2: In N,N-dimethyl-formamide at 85℃; for 6h; Sealed tube;	94%

: 13520-92-8
ziconium(IV) oxychloride octahydrate

: 142-45-0
Acetylenedicarboxylic acid

: Zr6O4(OH)4(12+)*6C4HClO4(2-)

Conditions

Conditions	Yield
Stage #1: ziconium(IV) oxychloride octahydrate; Acetylenedicarboxylic acid With acetic acid In water; N,N-dimethyl-formamide for 0.0333333h; Sonication; Stage #2: at 85℃; for 6h; Sealed tube;	94%

: 13520-92-8
ziconium(IV) oxychloride octahydrate

: 12125-01-8
ammonium fluoride

: potassium fluoride

: potassium oleate

A: potassium zirconium heptafluoride

B: potassium chloride

Conditions

Conditions	Yield
Stage #1: ziconium(IV) oxychloride octahydrate; potassium oleate With Elaidic Acid; oleylamine at 20℃; for 2h; Stage #2: ammonium fluoride; potassium fluoride In water at 50 - 200℃; for 12.5h; Reagent/catalyst; Autoclave;	A 89.4% B n/a

...Expand

: 13520-92-8
ziconium(IV) oxychloride octahydrate

: 12125-01-8
ammonium fluoride

: potassium fluoride

: potassium oleate

: potassium zirconium heptafluoride

Conditions

Conditions	Yield
Stage #1: ziconium(IV) oxychloride octahydrate; potassium oleate With Elaidic Acid; oleylamine at 20℃; for 2h; Stage #2: ammonium fluoride; potassium fluoride In water at 50 - 200℃; for 12.5h; Autoclave;	89.4%

...Expand

: 13520-92-8
ziconium(IV) oxychloride octahydrate

: 110-17-8
(2E)-but-2-enedioic acid

: zirconium fumarate

Conditions

Conditions	Yield
With acetic acid In water at 85℃; Microwave irradiation; Flow reactor; Green chemistry;	88%

: 13520-92-8
ziconium(IV) oxychloride octahydrate

: 2,4,6-tris[4-(phosphonomethyl)phenyl]-1,3,5-triazine

: 7732-18-5
water

: Zr(H4ttbmp)2*10H2O

Conditions

Conditions	Yield
With hydrogen fluoride In methanol at 80℃; for 48h;	86%

...Expand

: 13520-92-8
ziconium(IV) oxychloride octahydrate

: 4672-35-9
piperidinomethylphosphonic acid

: 7664-39-3
hydrogen fluoride

: Zr(4+)*2F(1-)*O3PCH2NC5H10(2-)=ZrF2(O3PCH2NC5H10)

Conditions

Conditions	Yield
In propan-1-ol; water a soln. piperidine-compound in n-propanol-water was added to a soln. of Zr-compound and HF, maintained in closed plastic vessel at 80°C for 3 days; ppt. was centrifuged, washed with propanol-water, dried in an oven at 70°C; elem. anal.;	85%

...Expand

: 13520-92-8
ziconium(IV) oxychloride octahydrate

: 64-18-6
formic acid

: 554-95-0
benzene-1,3,5-tricarboxylic acid

: 68-12-2, 33513-42-7
N,N-dimethyl-formamide

: Zr6O4(12+)*2C9H3O6(3-)*6HO(1-)*2CH2O2*1.5C3H7NO*20H2O

Conditions

Conditions	Yield
at 130℃; for 0.48h;	85%

...Expand

: 13520-92-8
ziconium(IV) oxychloride octahydrate

: 66-71-7
1,10-Phenanthroline

: 122630-45-9, 150063-91-5, 7361-93-5
salicylaldehyde anthranilic acid

: 2-[(2-hydroxybenzylidine)amino]benzoic acid 4,5-diazaphenanthrene oxoaquo zirconium chloride dihydrate

Conditions

Conditions	Yield
In ethanol for 12h; Reflux;	84%

...Expand

: 13520-92-8
ziconium(IV) oxychloride octahydrate

: 12125-01-8
ammonium fluoride

: sodium fluoride

: 16558-02-4
sodium oleate

: 3Na(1+)*ZrF7(3-)=Na3ZrF7

Conditions

Conditions	Yield
Stage #1: ziconium(IV) oxychloride octahydrate; sodium oleate With Elaidic Acid; oleylamine at 20℃; for 6h; Stage #2: ammonium fluoride; sodium fluoride In water at 25℃; for 12.5h;	83.1%

...Expand

: 13520-92-8
ziconium(IV) oxychloride octahydrate

: 7732-18-5
water

: 1-((3,5-di-tert-butyl-2-hydroxybenzylidene)amino)naphthalen-2-ol-5‑sodium sulfonate

: C25H30NO8SZr(1-)*Na(1+)

Conditions

Conditions	Yield
at 80℃; for 3h;	82%

...Expand

: 13520-92-8
ziconium(IV) oxychloride octahydrate

: 554-95-0
benzene-1,3,5-tricarboxylic acid

: 2C9H3O6(3-)*6H2O*10HO(1-)*Zr6O4(16+)

Conditions

Conditions	Yield
With acetic acid In water at 95℃; for 5h; Microwave irradiation; Green chemistry; Large scale;	81%

: 13520-92-8
ziconium(IV) oxychloride octahydrate

: 298-46-4
carbamazepin

: [ZrO(carbamazepine)2(H2O)]Cl2*8H2O

Conditions

Conditions	Yield
In ethanol for 3h; Reflux;	79.8%

: 13520-92-8
ziconium(IV) oxychloride octahydrate

: 1-cyclopropyl-6-fluoro-8-methoxy-4-oxo-7-(tetrahydro-1H-pyrrolo[3,4-b]pyridin)-6(2H,7H,7aH)-yl-1,4-dihydroquionoline-3-carboxylicacid

: 7732-18-5
water

: [ZrO(moxifloxacin)2Cl]Cl*15H2O

Conditions

Conditions	Yield
In methanol methanolic soln. of ZrOCl2*8H2O was added to moxifloxacin in methanol, stirred at room temp. for 22 h; slow evapn., ppt. was filtered off, washed with bidistilled water several times, dried over CaCl2 in desecrator, ppt. was filtered off, dried invac. over CaCl2; elem. anal.;	78.34%

...Expand

: 13520-92-8
ziconium(IV) oxychloride octahydrate

: 6,6′-((1E,1′E)-((4-chloro-1,2-phenylene)bis(azaneylylidene))bis(methaneylylidene))bis(2-ethoxy phenol)

: C24H21ClN2O5Zr*2H2O

Conditions

Conditions	Yield
In ethanol at 70℃; for 3h;	74%

: 13520-92-8
ziconium(IV) oxychloride octahydrate

: 1426080-33-2
(3E)-2-(hydroxyimino)-N-p-tolyl-3-(p-tolylimino)butanamide

: C18H20Cl2N3O4Zr*H2O

Conditions

Conditions	Yield
In ethanol; N,N-dimethyl acetamide Reflux;	73%

: 13520-92-8
ziconium(IV) oxychloride octahydrate

: 1,3,5-triamino-1,3,5-trideoxy-cis-inositol-tri-N,N',N"-propionic acid trihydrochloride

: 7732-18-5
water

: bis[μ3-3,3',3''-({[1R-(1α,2α,3α,4α,5α,6α)]-2,4,6-trihydroxylato-1κ2O2O6, 2κ2O2O6,2κ2O2O4,3κ2O4O6-cyclohexane-1,3,5-triyl}triimino-1κN1,2κN3,3κN5)tripropanoato-1κO,2κO',3κO'']trizirconium(IV) pentadecahydrate

Conditions

Conditions	Yield
With sodium hydroxide for 72h; pH=3.5; Reflux;	72%
With sodium hydroxide for 72h; pH=3.5; Reflux;	72%

...Expand

: 13520-92-8
ziconium(IV) oxychloride octahydrate

: 64-18-6
formic acid

: 4,4',4'',4'''-((4,4',4'',4'''-(porphyrin-5,10,15,20-tetrayl)tetrakis(benzoyl))tetrakis(azanediyl))tetrabenzoic acid

: 68-12-2, 33513-42-7
N,N-dimethyl-formamide

: [Zr6(μ3-O)4(μ3-OH)4(OH)4(H2O)4](L)2*12H2O*45(N,N-dimethylformamide)*33HCOOH

Conditions

Conditions	Yield
at 120℃; for 48h; Autoclave;	72%

...Expand

: 13520-92-8
ziconium(IV) oxychloride octahydrate

: 1401997-94-1
N-phosphonoethyl-4-carboxypyridinium chloride

: 7664-39-3
hydrogen fluoride

: 1401997-91-8
C8H9F3NO5PZr

Conditions

Conditions	Yield
at 80℃; for 72h;	71%

...Expand

: 13520-92-8
ziconium(IV) oxychloride octahydrate

: 4282-31-9
Thiophene-2,5-dicarboxylic acid

: 4C6H2O4S(2-)*4H2O*8HO(1-)*Zr6O4(16+)

Conditions

Conditions	Yield
With acetic acid In water at 95℃; for 1h; Microwave irradiation; Green chemistry; Large scale;	70%

: 13520-92-8
ziconium(IV) oxychloride octahydrate

: 64-18-6
formic acid

: 554-95-0
benzene-1,3,5-tricarboxylic acid

: 7732-18-5
water

: Zr-MOF-808

Conditions

Conditions	Yield
In N,N-dimethyl-formamide at 100℃; for 48h; Inert atmosphere; Schlenk technique;	70%

...Expand

: 13520-92-8
ziconium(IV) oxychloride octahydrate

: Na3[α-PW12O40]*11H2O

: 660-68-4
diethyl amine hydrochloride

: (Et2NH2)8[(α-PW11O39Zr(μ-OH)(H2O))2]

Conditions

Conditions	Yield
With Na2CO3; HCl In water to a soln. of polyoxotungstate in water was added Na2CO3, stirred for 20min., ZrCl2O*8H2O was added, stirred for 5 min, 1 M aq. HCl was added f or 1 min, stirred for 15 min, a soln. of Hf-compound in aq. HCl was added, stirred for 30 min; passed through a folded filter paper, evapd. at 40°C, stirred for1 min in a water bath at more than 90°C, (C2H5)2NH2Cl was added, stirred for 5 min, cooled to roomtemp., filtered, washed with C2H5OH, d ried in vac. for 2 h; elem. anal.;	69.7%

Yield

With Na2CO3; HCl In water to a soln. of polyoxotungstate in water was added Na2CO3, stirred for 20min., ZrCl2O*8H2O was added, stirred for 5 min, 1 M aq. HCl was added f or 1 min, stirred for 15 min, a soln. of Hf-compound in aq. HCl was added, stirred for 30 min; passed through a folded filter paper, evapd. at 40°C, stirred for1 min in a water bath at more than 90°C, (C2H5)2NH2Cl was added, stirred for 5 min, cooled to roomtemp., filtered, washed with C2H5OH, d ried in vac. for 2 h; elem. anal.;

69.7%

...Expand

: 13520-92-8
ziconium(IV) oxychloride octahydrate

: 1071-83-6
N-(phosphonemethyl)glycine

: 7664-39-3
hydrogen fluoride

: Zr(4+)*F(1-)*2C3H5NO5P(3-)*3H(1+)

Conditions

Conditions	Yield
at 80℃; for 48h; pH=2.17;	68%

...Expand

Zirconyl chloride octahydrate Standards and Recommendations

OSHA PEL: TWA 5 mg(Zr)/m³; STEL 10 mg(Zr)/m³
ACGIH TLV: TWA 5 mg(Zr)/m³; STEL 10 mg(Zr)/m³; Not Classifiable as a Human Carcinogen
DFG MAK: 1 mg(Zr)/m³

Zirconyl chloride octahydrate Specification

The Zirconyl chloride oxide octahydrate is an organic compound with the formula ZrOCl₂^.8(H₂O). The IUPAC name of this chemical is oxozirconium octahydrate dihydrochloride. With the CAS registry number 13520-92-8, it is also named as Zirconium oxychloride octahydrate. The product's classification codes are Mutation data; Tumor data. Besides, it should be stored in a dry and well-ventilated place. It is used to manufacture zirconia. It is also used as rubber additives, paint drying, refractories, ceramics, glaze, and fiber treatment agent. It is widely used in rubber additives, paint driers, refractory and ceramic glaze.

Physical properties about Zirconyl chloride oxide octahydrate are: (1)#H bond acceptors: 1; (2)Polar Surface Area: 17.07 Å².

Preparation: this chemical can be prepared by zircon and caustic soda. This reaction will need reagent sulfuric acid, ammonia, hydrochloric acid.
ZrSiO₃+4NaOH→Na₂ZrO₃+NazSiO₃+2H₂O
Na₂ZrO₃+3H₂SO₄→Zr(SO₄)₂+Na₂SO₄+3H₂O
Zr(SO₄)2+4NH₃^.H₂O→Zr(OH)₄↓+2(NH₄)₂SO₄Zr(OH)₄+2HCl+5H₂O→ZrOCl₂^.8(H₂O)

When you are using this chemical, please be cautious about it as the following:
It is harmful if swallowed. Please take off immediately all contaminated clothing. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Besides, this chemical can cause burns. When you are using it, wear suitable gloves and eye/face protection. In case of accident or if you feel unwell seek medical advice immediately (show the label where possible).

You can still convert the following datas into molecular structure:
(1)SMILES: O=[Zr].Cl.Cl.O.O.O.O.O.O.O.O
(2)InChI: InChI=1/2ClH.8H2O.O.Zr/h2*1H;8*1H2;;/r2ClH.OZr.8H2O/c;;1-2;;;;;;;;/h2*1H;;8*1H2
(3)InChIKey: FUBACIUATZGHAC-FUJGLDTFAK
(4)Std. InChI: InChI=1S/2ClH.8H2O.O.Zr/h2*1H;8*1H2;;
(5)Std. InChIKey: FUBACIUATZGHAC-UHFFFAOYSA-N

Product Name

Zirconyl chloride octahydrate

Synthetic route

Zirconyl chloride octahydrate Standards and Recommendations

Zirconyl chloride octahydrate Specification

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