trans-2-Hexen-1-ol supplier

Name
trans-2-Hexen-1-ol
EINECS 213-191-2
CAS No. 928-95-0
Article Data82
CAS DataBase
Density 0.844
Solubility

Stability

Stable. Flammable. Incompatible with strong oxidizing agents,strong acids.

Toxicology

Skin, eye and respiratory irritant.

Toxicity data
(The meaning o

Melting Point 54.63°C
Formula C6H12 O
Boiling Point 158 - 160 C (61 - 62 C at 12 mm Hg)
Molecular Weight 100.161
Flash Point 54 ºC
Transport Information UN 1987
Appearance colourless liquid
Safety Moderately toxic by ingestion. Mildly toxic by skin contact. A skin irritant. Flammable liquid when exposed to heat, sparks, or flame. When heated to decomposition it emits acrid smoke and fumes. See also ALCOHOL, DENATURED; ALCOHOLS, C6-12; ALCOHOLS, C9-11; ALCOHOLS, C12-13, ETHOXYLATED; ALCOHOLS, C12-15, ETHOXYLATED; ALCOHOLS, C12-16, ETHOXYLATED; ALCOHOLS, C14-15, ETHOXYLATED; ALCOHOLS, C16-18, ETHOXYLATED; ALCOHOLS, C8-10, ETHOXYLATED PROPOXYLATED; ALCOHOLS, C12-15, ETHOXYLATED PROPOXYLATED; ALCOHOLS, N.O.S..
Risk Codes R10;R36/37/38
Molecular Structure
Hazard Symbols
Synonyms 2-Hexen-1-ol,(E)- (8CI); 2-Hexen-1-ol, trans- (7CI); (2E)-2-Hexen-1-ol; (E)-2-Hexen-1-ol;(E)-2-Hexene-1-ol; (E)-2-Hexenol; 1-Hydroxy-2-trans-hexene;n-Hex-trans-2-en-1-ol; trans-2-Hexen-1-ol; trans-2-Hexene-1-ol;trans-2-Hexenol; trans-4-Ethyl-2-buten-1-ol
PSA 20.23000
LogP 1.33500

Synthetic route

: 113997-32-3
trans-tert-butyl(hex-2-en-1-yloxy)dimethylsilane

: 928-95-0
(E)-2-Hexen-1-ol

Conditions

Conditions	Yield
With phosphomolybdic acid hydrate; silica gel In tetrahydrofuran at 20℃; for 0.5h;	97%
With hafnium tetrakis(trifluoromethanesulfonate) In methanol at 20℃; for 1h;	96%

: 88738-36-7
(E)-1-(methoxymethoxy)hex-2-ene

: 928-95-0
(E)-2-Hexen-1-ol

Conditions

Conditions	Yield
With pyridinium p-toluenesulfonate In butanone for 10h; Heating;	94%

: 88738-35-6
(E)-1-(2-Methoxy-ethoxymethoxy)-hex-2-ene

: 928-95-0
(E)-2-Hexen-1-ol

Conditions

Conditions	Yield
With pyridinium p-toluenesulfonate In butanone for 11h; Heating;	94%

: 6728-26-3
(E)-2-Hexenal

: 928-95-0
(E)-2-Hexen-1-ol

Conditions

Conditions	Yield
With bis(cyclopentadienyl)dihydrozirconium In isopropyl alcohol at 130℃; for 8h;	93%
With phosphotungstic acid; sodium tetrahydroborate In methanol	93%
With isopropyl alcohol; zirconium(IV) oxide for 6h; Rate constant; Heating;	92%

: 764-60-3
hex-2-yn-1-ol

: 928-95-0
(E)-2-Hexen-1-ol

Conditions

Conditions	Yield
With lithium aluminium tetrahydride In tetrahydrofuran for 5h; Heating;	90%
With lithium aluminium tetrahydride In tetrahydrofuran for 1.5h; Heating;	90.5%
With lithium aluminium tetrahydride In tetrahydrofuran; diethyl ether for 2h; Heating;	87%

: 27829-72-7
ethyl (E)-hex-2-enoate

: 928-95-0
(E)-2-Hexen-1-ol

Conditions

Conditions	Yield
With diisobutylaluminium hydride at 0 - 20℃;	85%
With diisobutylaluminium hydride In dichloromethane; toluene at -78 - 20℃; Inert atmosphere;	79%
With lithium aluminium tetrahydride In diethyl ether at 20℃; for 3h; Heating;	55%

: 88088-14-6
3-Methylselanyl-hex-1-ene

: 928-95-0
(E)-2-Hexen-1-ol

Conditions

Conditions	Yield
With dihydrogen peroxide In pyridine; dichloromethane at 20℃;	85%

: 6728-26-3
(E)-2-Hexenal

A: 928-95-0
(E)-2-Hexen-1-ol

B: C12H22O2

Conditions

Conditions	Yield
With acetic acid; zinc In water at 20℃; for 0.333333h; Green chemistry;	A 21% B 79%

: 4798-44-1
1-hexene-3-ol

: 928-95-0
(E)-2-Hexen-1-ol

Conditions

Conditions	Yield
With methanesulfonic acid In tetrahydrofuran; water at 20℃; for 12h;	76%

: 170209-06-0
(2S*,3S*)-1-Acetoxy-2,3-epoxyhexane

: 928-95-0
(E)-2-Hexen-1-ol

Conditions

Conditions	Yield
With tellurium; lithium triethylborohydride In tetrahydrofuran at 0℃; for 0.2h;	70%

: 73881-10-4
(E)-1-bromo-2-hexene

: 928-95-0
(E)-2-Hexen-1-ol

Conditions

Conditions	Yield
With potassium hydroxide; tetrafluoroboric acid; sodium hydrogencarbonate; mercury(II) oxide In 1,4-dioxane 1.) room temp., 2 h;	65%

: 6728-26-3
(E)-2-Hexenal

A: 928-95-0
(E)-2-Hexen-1-ol

B: 111-27-3
hexan-1-ol

Conditions

Conditions	Yield
With Beauveria sulfurescens In dimethyl sulfoxide at 20℃; for 48h;	A 37% B 63%
With hydrogen In hexane at 50℃; under 30003 Torr; for 18h; Reagent/catalyst; Autoclave; chemoselective reaction;

: 11997-33-4
(E)-tert-butyl(hex-2-en-1-yloxy)diphenylsilane

: 928-95-0
(E)-2-Hexen-1-ol

Conditions

Conditions	Yield
With tetrabutyl ammonium fluoride In tetrahydrofuran at 20℃; for 0.75h;	53%

: 6728-26-3
(E)-2-Hexenal

A: 928-95-0
(E)-2-Hexen-1-ol

B: 114612-53-2
(4E,8E)-dodeca-4,8-diene-6,7-diol

: 67470-00-2, 67470-02-4, 72200-34-1, 114612-52-1, 114612-53-2
dl-(E,E)-6,7-dihydroxydodeca-4,8-diene

Conditions

Conditions	Yield
With zinc In water at 70℃; for 2h; Green chemistry;	A 10% B n/a C n/a
With acetic acid; zinc In ethanol at 20℃; Flow reactor;

...Expand

: 930-22-3
epoxybutene

: 60-29-7
diethyl ether

: 925-90-6
ethylmagnesium bromide

A: 928-95-0
(E)-2-Hexen-1-ol

B: 688-99-3
5-hexen-3-ol

C: 53045-70-8
2-ethylbut-3-en-1-ol

...Expand

: 123-73-9
trans-Crotonaldehyde

: 64-17-5
ethanol

: 928-95-0
(E)-2-Hexen-1-ol

Conditions

Conditions	Yield
at 350℃; ueber Lebedew-Katalysator;

: 13419-69-7
(E)-2-Hexenoic acid

: 928-95-0
(E)-2-Hexen-1-ol

Conditions

Conditions	Yield
With lithium aluminium tetrahydride

: 64-17-5
ethanol

: 123-72-8
butyraldehyde

: 928-95-0
(E)-2-Hexen-1-ol

Conditions

Conditions	Yield
at 350℃; ueber Lebedew-Katalysator;

: 927-68-4
bromoethyl acetate

: 123-72-8
butyraldehyde

: 928-95-0
(E)-2-Hexen-1-ol

Conditions

Conditions	Yield
With tetrahydrofuran; magnesium; mercury dichloride Erwaermen des Reaktionsgemisches mit wss.Kalilauge;

: 18913-31-0
2,3-butadien-1-ol

: 925-90-6
ethylmagnesium bromide

: 928-95-0
(E)-2-Hexen-1-ol

Conditions

Conditions	Yield
With copper(l) iodide In diethyl ether

: 7045-86-5
2-methyl-4,7-dihydro-1,3-dioxepine

: 925-90-6
ethylmagnesium bromide

A: 14850-23-8
trans-4-Octene

B: 928-94-9
(Z)-2-hexen-1-ol

C: 928-95-0
(E)-2-Hexen-1-ol

D: 78-92-2, 15892-23-6
iso-butanol

Conditions

Conditions	Yield
1,2-bis(diphenylphosphino)ethane nickel(II) chloride for 5h; Product distribution; Ambient temperature; regio- and stereoselectivity of Ni-catalyzed alkylation; various Grignard reagents;	A 47 % Chromat. B n/a C n/a D n/a
1,2-bis(diphenylphosphino)ethane nickel(II) chloride for 5h; Ambient temperature; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

...Expand

: 6728-26-3
(E)-2-Hexenal

A: 928-95-0
(E)-2-Hexen-1-ol

B: 66-25-1
hexanal

Conditions

Conditions	Yield
With lithium aluminium tetrahydride In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide at -78℃; for 60h;	A 52 % Chromat. B 2 % Chromat.

: 6728-26-3
(E)-2-Hexenal

A: 928-95-0
(E)-2-Hexen-1-ol

B: 66-25-1
hexanal

C: 111-27-3
hexan-1-ol

Conditions

Conditions	Yield
With copper(l) iodide; lithium aluminium tetrahydride In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide at -78℃; for 60h;	A 12 % Chromat. B 63 % Chromat. C 1 % Chromat.

...Expand

: 13894-63-8
methyl (E)-hex-2-enoate

: 928-95-0
(E)-2-Hexen-1-ol

Conditions

Conditions	Yield
With diisobutylaluminium hydride In diethyl ether at -78℃;
With diisobutylaluminium hydride In tetrahydrofuran at -78 - 20℃;

: 592-41-6
1-hexene

A: 928-94-9
(Z)-2-hexen-1-ol

B: 928-95-0
(E)-2-Hexen-1-ol

Conditions

Conditions	Yield
With oxygen; rose bengal; triphenylphosphine Product distribution; multistep reaction: 1.) EtOH, 25 deg C, irradiation; other temperature (50 deg C); photosensitised oxidation of olefins, reduction of the hydroperoxides formed;

: 592-41-6
1-hexene

A: 928-95-0
(E)-2-Hexen-1-ol

B: 4798-44-1
1-hexene-3-ol

Conditions

Conditions	Yield
With oxygen; cobalt(II) acetate; triphenylphosphine Product distribution; multistep reaction: 1.) 25 deg C; other temperature (50 deg C); other catalysts; autooxidation of olefins, reduction of the hydroperoxides formed;

: 4050-45-7
trans-2-hexene

A: 928-95-0
(E)-2-Hexen-1-ol

B: 4798-58-7, 29478-27-1
(E)-hex-4-en-3-ol

C: 4798-44-1
1-hexene-3-ol

D: 29478-26-0
(S,R)-trans-3-hexen-2-ol

E: 29478-31-7
cis-3-hexen-2-one

Conditions

Conditions	Yield
With oxygen; cobalt(II) acetate; triphenylphosphine Product distribution; multistep reaction: 1.) 25 deg C; other temperature (50 deg C); other catalysts; autooxidation of olefins, reduction of the hydroperoxides formed;

...Expand

: 4798-44-1
1-hexene-3-ol

A: 928-94-9
(Z)-2-hexen-1-ol

B: 928-95-0
(E)-2-Hexen-1-ol

Conditions

Conditions	Yield
triphenylsilyl perrhenate In dichloromethane at 0 - 30℃; Thermodynamic data; Product distribution; Rate constant; ΔH(excit.), ΔS(excit.);

: 109-99-9
tetrahydrofuran

: 927-68-4
bromoethyl acetate

: 123-72-8
butyraldehyde

magnesium: magnesium

mercury (II)-chloride: mercury (II)-chloride

: 928-95-0
(E)-2-Hexen-1-ol

Conditions

Conditions	Yield
Erhitzen des Reaktionsprodukts mit wss.Kalilauge;

...Expand

: 928-95-0
(E)-2-Hexen-1-ol

: 6399-81-1
triphenylphosphine hydrobromide

: 88517-93-5
<(E)-hex-2-enyl>triphenylphosphonium bromide

Conditions

Conditions	Yield
In benzene for 10h; Heating;	100%

: 928-95-0
(E)-2-Hexen-1-ol

: 6728-26-3
(E)-2-Hexenal

Conditions

Conditions	Yield
With oxygen; 2,2,6,6-tetramethyl-piperidine-N-oxyl; copper(l) chloride In N,N-dimethyl-formamide at 25℃; for 1.75h;	100%
With manganese(IV) oxide; 3-mercapto-2-(mercaptomethyl)-ethyl propanoate; 4 A molecular sieve In dichloromethane Heating;	100%
With 2,3-dicyano-5,6-dichloro-p-benzoquinone In dichloromethane at 20℃; for 16h; Inert atmosphere;	99%

: 928-95-0
(E)-2-Hexen-1-ol

: 106498-75-3
2,3-epoxyhexanol

Conditions

Conditions	Yield
With tert.-butylhydroperoxide In chloroform for 4h; Catalytic behavior; Reflux;	100%
With tert.-butylhydroperoxide In acetonitrile at 80℃; for 24h; Catalytic behavior; Reagent/catalyst;	100%
With tributyl-n-octylphosphonium peroxotantalate; dihydrogen peroxide In water at 0℃; Reagent/catalyst; Schlenk technique; chemoselective reaction;	100%

: 928-95-0
(E)-2-Hexen-1-ol

: 124-63-0
methanesulfonyl chloride

: 99704-81-1
trans-2-hexenyl mesylate

Conditions

Conditions	Yield
With triethylamine In dichloromethane at -15℃; for 1h; Green chemistry;	100%
With triethylamine In dichloromethane at -15℃; for 1.5h;	100%
With triethylamine In tetrahydrofuran at 0℃; for 3h;	99%

: 928-95-0
(E)-2-Hexen-1-ol

: 98-59-9
p-toluenesulfonyl chloride

: 205882-94-6
trans-2-hexenyl tosylate

Conditions

Conditions	Yield
With n-butyllithium In tetrahydrofuran; hexane at -80℃; for 48h;	100%
With n-butyllithium 1) hexane, THF, -78 deg C, 2) -78 deg C, 72 h; Multistep reaction;
With potassium hydroxide

: 928-95-0
(E)-2-Hexen-1-ol

: anti-2,3-dichloro-1-hexanol

Conditions

Conditions	Yield
With pyridine; 1,4-diaza-bicyclo[2.2.2]octane; tetraethylammonium trichloride In dichloromethane Ambient temperature;	100%

: 928-95-0
(E)-2-Hexen-1-ol

: 3282-30-2
pivaloyl chloride

: 1194667-13-4
(E)-hex-2-enyl pivalate

Conditions

Conditions	Yield
at 20℃; for 0.0833333h; Neat (no solvent);	100%

: 928-95-0
(E)-2-Hexen-1-ol

: 4903-36-0
N-phenyl-benzimidoyl chloride

: 188122-37-4
(E)-hex-2enyl N-phenylbenzimidate

Conditions

Conditions	Yield
Stage #1: (E)-2-Hexen-1-ol With sodium hydride In tetrahydrofuran; mineral oil at 0 - 30℃; for 1.25h; Stage #2: N-phenyl-benzimidoyl chloride In tetrahydrofuran; mineral oil at 0 - 20℃; for 20h;	100%

: 928-95-0
(E)-2-Hexen-1-ol

: N-benzyl-2,4-dinitro-benzenesulfonamide

: 1391485-27-0
(E)-N-benzyl-N-(hex-2-enyl)-2',4'-dinitrobenzenesulfonamide

Conditions

Conditions	Yield
With triphenylphosphine; diethylazodicarboxylate In tetrahydrofuran at 0 - 20℃; for 19h;	100%

: 928-95-0
(E)-2-Hexen-1-ol

A: 14850-23-8
trans-4-Octene

B: 821-11-4
(E)-2-butene-1,4-diol

Conditions

Conditions	Yield
With C37H40Cl2N2ORuS2 In tetrahydrofuran-d8 at 45℃; for 1h; Inert atmosphere;	A 100% B 100%

: 928-95-0
(E)-2-Hexen-1-ol

: 108-24-7
acetic anhydride

: 2497-18-9
(E)-2-hexen-1-yl acetate

Conditions

Conditions	Yield
With scandium tris(trifluoromethanesulfonate) In acetonitrile for 0.0833333h;	99%
With dmap In diethyl ether at 20℃; for 16h; Inert atmosphere;	89%
With triethylamine; dmap In dichloromethane at 20℃;	88%

: 928-95-0
(E)-2-Hexen-1-ol

: 545-06-2
trichloroacetonitrile

: 51479-70-0
(E)-2,2,2-trichloroacetimidic acid hex-2-enyl ester

Conditions

Conditions	Yield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In dichloromethane at 20℃; for 2h;	99%
With potassium hydroxide; tetra(n-butyl)ammonium hydrogensulfate In dichloromethane at -15 - 25℃; for 1h;	95%
With sodium hydride 1.) THF, 0 deg C, 1 h, 2.) THF, 1.5 h, RT; Yield given. Multistep reaction;
With sodium hydride 1.) THF, 0 deg C, 1 h, 2.) THF, RT, 1.5 h; Multistep reaction;
With 1,8-diazabicyclo[5.4.0]undec-7-ene In dichloromethane at 4℃; for 0.1h;

: 928-95-0
(E)-2-Hexen-1-ol

: 19689-92-0
cyclohexanone O-acetyl oxime

: 2497-18-9
(E)-2-hexen-1-yl acetate

Conditions

Conditions	Yield
With Cp*2Sm(THF)2 In toluene for 0.1h; Ambient temperature;	99%

: 928-95-0
(E)-2-Hexen-1-ol

: 18162-48-6
tert-butyldimethylsilyl chloride

: 113997-32-3
trans-tert-butyl(hex-2-en-1-yloxy)dimethylsilane

Conditions

Conditions	Yield
With 1H-imidazole In dichloromethane at 0 - 20℃; Inert atmosphere;	99%
With 1H-imidazole In N,N-dimethyl-formamide at 20℃;
Wittig Reaction;

: 928-95-0
(E)-2-Hexen-1-ol

: 75-25-2
Bromoform

: C7H12Br2O

Conditions

Conditions	Yield
With sodium hydroxide; N-benzyl-N,N,N-triethylammonium chloride In water	99%

: 928-95-0
(E)-2-Hexen-1-ol

: 616-05-7
2-bromohexanoic acid

: 1206535-33-2
2-bromohexanoic acid (E)-2-hexenyl ester

Conditions

Conditions	Yield
Stage #1: 2-bromohexanoic acid With dicyclohexyl-carbodiimide In tetrahydrofuran at 20℃; for 0.25h; Inert atmosphere; Stage #2: (E)-2-Hexen-1-ol With dmap In tetrahydrofuran Inert atmosphere;	99%
Stage #1: 2-bromohexanoic acid With dicyclohexyl-carbodiimide In tetrahydrofuran at 20℃; for 0.25h; Inert atmosphere; Stage #2: (E)-2-Hexen-1-ol With dmap In tetrahydrofuran at 20℃; Inert atmosphere;

: 928-95-0
(E)-2-Hexen-1-ol

: 4083-64-1
Tosyl isocyanate

: 1437784-91-2
(E)-hex-2-en-1-yl tosylcarbamate

Conditions

Conditions	Yield
In dichloromethane at 0 - 20℃; for 2h;	99%
In dichloromethane at 20℃; for 2h;	99%

: 117-99-7
2-Hydroxybenzophenone

: 928-95-0
(E)-2-Hexen-1-ol

: C19H20O2

Conditions

Conditions	Yield
With di-isopropyl azodicarboxylate; triphenylphosphine In tetrahydrofuran at 0℃;	99%

: 110-87-2
3,4-dihydro-2H-pyran

: 928-95-0
(E)-2-Hexen-1-ol

: 119771-54-9
2-[((E)-Hex-2-enyl)oxy]-tetrahydro-pyran

Conditions

Conditions	Yield
With lanthanum(III) nitrate at 20℃; for 3h;	98%
With ruthenium(III) acetate at 20℃; for 24h;	95%
With molybdenyl acetylacetonate In chloroform for 4h; Heating;	70%
With pyridinium p-toluenesulfonate In dichloromethane at 20℃; for 4h;

: 928-95-0
(E)-2-Hexen-1-ol

: 89395-00-6
2,3-epoxyhexan-1-ol

Conditions

Conditions	Yield
With dihydrogen peroxide; K2[{W(O)(O2)2(H2O)}2(μ-O)]*2H2O In water at 31.84℃; for 5h;	98%
With dihydrogen peroxide In acetonitrile at 50℃; for 4h;	94%
With dihydrogen peroxide; tetraphenylphosphonium; sodium hydrogencarbonate; WO(O2)(QO)4 In acetonitrile at 25℃; for 0.5h;	90%

: 928-95-0
(E)-2-Hexen-1-ol

: 177272-50-3
1-Bromo-1-phenylsulfanyl-3,3,3-trifluoroprop-1-ene

: 177272-48-9
{(E)-3,3,3-Trifluoro-2-[((E)-hex-2-enyl)oxy]-propenylsulfanyl}-benzene

Conditions

Conditions	Yield
With sodium hydride In diethyl ether for 1h; Ambient temperature;	98%

: 75-77-4
chloro-trimethyl-silane

: 928-95-0
(E)-2-Hexen-1-ol

: 265135-87-3
(+/-)-1-(1-hexenyl)-1-(trimethylsilyl)methanol

Conditions

Conditions	Yield
Stage #1: chloro-trimethyl-silane; (E)-2-Hexen-1-ol With n-butyllithium In tetrahydrofuran; hexane at -78 - 0℃; Stage #2: With tert.-butyl lithium In tetrahydrofuran; hexane; pentane at -78 - -30℃; anti-Brook rearrangement;	98%
Stage #1: (E)-2-Hexen-1-ol With n-butyllithium In tetrahydrofuran at -78℃; for 1h; Stage #2: chloro-trimethyl-silane In tetrahydrofuran at -78℃; for 2.5h; Stage #3: With sec.-butyllithium In tetrahydrofuran at -78℃; for 2h;	68%
Stage #1: (E)-2-Hexen-1-ol With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 1h; Inert atmosphere; Stage #2: chloro-trimethyl-silane In tetrahydrofuran; hexane for 2.5h; Inert atmosphere; Stage #3: With sec.-butyllithium In tetrahydrofuran; hexane; cyclohexane for 2h; Inert atmosphere;	57%

: 928-95-0
(E)-2-Hexen-1-ol

: 24424-99-5
di-tert-butyl dicarbonate

: 872672-17-8
(E)-tert-butyl hex-2-en-1-yl carbonate

Conditions

Conditions	Yield
With dmap Heating;	98%
Stage #1: (E)-2-Hexen-1-ol With n-butyllithium In tetrahydrofuran; hexane at 0℃; for 0.5h; Inert atmosphere; Stage #2: di-tert-butyl dicarbonate In tetrahydrofuran; hexane at 0 - 20℃; Inert atmosphere;	95%
With tetra(n-butyl)ammonium hydrogensulfate
With tetra(n-butyl)ammonium hydrogensulfate; sodium hydroxide In water
In dichloromethane for 12h; Molecular sieve;

: 928-95-0
(E)-2-Hexen-1-ol

: 69032-16-2
benzyloxycarbonyl isocyanate

: benzyl trans-hexa-2-enyl imidodicarbonate

Conditions

Conditions	Yield
In dichloromethane at 20℃; for 3h;	98%

: 928-95-0
(E)-2-Hexen-1-ol

: 530-62-1
1,1'-carbonyldiimidazole

: (E)-hex-2-en-1-yl 1H-imidazole-1-carboxylate

Conditions

Conditions	Yield
In dichloromethane at 20℃; for 4h;	98%
In dichloromethane at 20℃; for 4h; Inert atmosphere;

: 928-95-0
(E)-2-Hexen-1-ol

: 89478-86-4
1-bromovinyl p-tolyl sulphone

: 89478-89-7
1-{1-Bromo-2-[((E)-hex-2-enyl)oxy]-ethanesulfonyl}-4-methyl-benzene

Conditions

Conditions	Yield
With sodium hydride for 5h; Ambient temperature;	97%

: 928-95-0
(E)-2-Hexen-1-ol

: 127-65-1
chloroamine-T

: ((2S*,3R*)-3-propyl-1-tosylaziridin-2-yl)methanol

Conditions

Conditions	Yield
With phenyltrimethylammonium tribromide In acetonitrile at 25℃; for 12h;	97%
With iodine; Aliquat 336 at 20℃; for 3h;	79%
With iodine; silica gel; potassium carbonate In water at 20℃; for 3h;	58%
With phenyltrimethylammonium tribromide In acetonitrile at 20℃; for 12h; Sharpless aziridination;

: 928-95-0
(E)-2-Hexen-1-ol

: 105-58-8
Diethyl carbonate

: 120989-95-9
ethyl (E)-hex-2-en-1-yl carbonate

Conditions

Conditions	Yield
aluminum oxide; cesium fluoride at 129.85℃; for 0.333333h;	97%
With MgLa mixed oxide at 125℃; for 2h;	96%

: 928-95-0
(E)-2-Hexen-1-ol

: 73881-10-4
(E)-1-bromo-2-hexene

Conditions

Conditions	Yield
With tetrabutylammomium bromide; (chloro-phenylthio-methylene)dimethylammonium chloride In dichloromethane at 20℃; Bromination;	96%
With phosphorus tribromide In diethyl ether	90%
With phosphorus tribromide In dichloromethane at 25℃; for 3h; Inert atmosphere;	89%

trans-2-Hexen-1-ol Chemical Properties

IUPAC Name: (E)-hex-2-en-1-ol
Molecular Formula: C₆H₁₂O
EINECS: 213-191-2
Liansport Information: UN 1987 3/PG 3
Density: 0.843 g/cm³
Molecular Weight: 100.18g/mol
Boiling Point: 159.6 °C at 760 mmHg
Flash Point: 61.7 °C
Solubility: soluble in alc, propylene glycol, fixed oils; very sltly sol in water.
Stability: stable, flammable, incompatible with strong oxidizing agents,strong acids.
Properties:Colorless liquid; fruity-green odor
Freely Rotating Bonds: 4
Polar Surface Area: 9.23Å²
Index of Refraction: 1.442
Molar Refractivity: 31.43 cm³
Molar Volume: 118.6 cm³
Polarizability: 12.46× 10^-24cm³
Surface Tension: 28.7 dyne/cm
Enthalpy of Vaporization: 46.15 kJ/mol
Vapour Pressure: 0.873 mmHg at 25°C
The Cas Register Number of 2-Hexen-1-ol, (E)- is 928-95-0.The chemical synonyms of 2-Hexen-1-ol, (E)- (CAS No.928-95-0) are (2E)-2-Hexen-1-ol ; (E)-2-Hexen-1-ol ; (E)-2-Hexene-1-ol ; (E)-2-hexenol ; (E)-Hex-2-en-1-ol ; (E)-hex-2-enol ; 2-(E)-hexenol ; 2-hexen-1-0l .Product categories of 2-Hexen-1-ol, (E)- (CAS No.928-95-0) are alcohol Flavor ; Alphabetical Listings ; Flavors and Fragrances ; G-H ; Acyclic ; Alkenes ; Organic Building Blocks .The molecular structure of 2-Hexen-1-ol, (E)- (CAS No.928-95-0) is .

trans-2-Hexen-1-ol Uses

It is used as flavor in food.

trans-2-Hexen-1-ol Toxicity Data With Reference

1.	skn-rbt 500 mg/24H	FCTXAV Food and Cosmetics Toxicology. 12 (1974),911.
2.	orl-rat LD50:3500 mg/kg	FCTXAV Food and Cosmetics Toxicology. 12 (1974),911.
3.	skn-rbt LD50:4500 mg/kg	FCTXAV Food and Cosmetics Toxicology. 12 (1974),911.

trans-2-Hexen-1-ol Consensus Reports

Reported in EPA TSCA Inventory.

trans-2-Hexen-1-ol Safety Profile

Moderately toxic by ingestion. Mildly toxic by skin contact. A skin irritant. Flammable liquid when exposed to heat, sparks, or flame. When heated to decomposition it emits acrid smoke and fumes. See also ALCOHOL, DENATURED; ALCOHOLS, C6-12; ALCOHOLS, C9-11; ALCOHOLS, C12-13, ETHOXYLATED; ALCOHOLS, C12-15, ETHOXYLATED; ALCOHOLS, C12-16, ETHOXYLATED; ALCOHOLS, C14-15, ETHOXYLATED; ALCOHOLS, C16-18, ETHOXYLATED; ALCOHOLS, C8-10, ETHOXYLATED PROPOXYLATED; ALCOHOLS, C12-15, ETHOXYLATED PROPOXYLATED; ALCOHOLS, N.O.S..
Hazard Codes: Irritant Xi
Risk Statements:10-36/37/38
R10:Flammable.
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements:26-36
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36:Wear suitable protective clothing.
HazardClass:3

Product Name

trans-2-Hexen-1-ol

Stability

Toxicology

Synthetic route

trans-2-Hexen-1-ol Chemical Properties

trans-2-Hexen-1-ol Uses

trans-2-Hexen-1-ol Toxicity Data With Reference

trans-2-Hexen-1-ol Consensus Reports

trans-2-Hexen-1-ol Safety Profile

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