Product Name

  • Name

    VINYL FLUORIDE

  • EINECS
  • CAS No. 75-02-5
  • Article Data92
  • CAS DataBase
  • Density 0,615 g/cm3
  • Solubility
  • Melting Point -160,5°C
  • Formula C2H3 F
  • Boiling Point -72°C
  • Molecular Weight 46.0442
  • Flash Point
  • Transport Information
  • Appearance
  • Safety Confirmed carcinogen. A poison. Mutation data reported. A very dangerous fire hazard. To fight fire, stop flow of gas. When heated to decomposition it emits toxic fumes of F. See also FLUORIDES.
  • Risk Codes R12;R40;
  • Molecular Structure Molecular Structure of 75-02-5 (VINYL FLUORIDE)
  • Hazard Symbols Flammable, dangerous fire and explosion risk. Toxic by inhalation. TLV: 2.6 mg(F)/m3.
  • Synonyms Ethylene,fluoro- (8CI); 1-Fluoroethene; 1-Fluoroethylene; FC 1141; Fluoroethene;Fluoroethylene; Monofluoroethene; Monofluoroethylene; R 1141; Vinyl fluoride
  • PSA 0.00000
  • LogP 1.09940

Synthetic route

1,1-difluoroethane
75-37-6

1,1-difluoroethane

acetylene
74-86-2

acetylene

1-fluoroethylene
75-02-5

1-fluoroethylene

Conditions
ConditionsYield
at 340℃; other temperatures, other catalysts;77.5%
1,1-difluoroethane
75-37-6

1,1-difluoroethane

1-fluoroethylene
75-02-5

1-fluoroethylene

Conditions
ConditionsYield
With hydrogen fluoride; Alpha-chromium oxide obtained from the pyrolysis of ammonium dichromate, treated with HF for 9 - 162h;29.8%
With hydrogen fluoride; chromium(III) oxide at 245 - 275℃; for 5 - 49h; Catalys was activated in a stream of HF up to 350 C;13.2%
With hydrogen fluoride; Alpha-chromium oxide obtained from the pyrolysis of ammonium dichromate, treated with HF at 200 - 245℃; for 15 - 47.5h;6%
1,1-difluoroethane
75-37-6

1,1-difluoroethane

A

ethene
74-85-1

ethene

B

1-fluoroethylene
75-02-5

1-fluoroethylene

C

acetylene
74-86-2

acetylene

Conditions
ConditionsYield
With hydrogen fluoride; Guingnet's green at 250 - 400℃; for 10 - 129h;A 0%
B 19.6%
C 0%
With hydrogen fluoride; Alpha-chromium oxide obtained from the pyrolysis of ammonium dichromate, treated with HF at 250 - 350℃;A 0%
B 19.3%
C 0%
With hydrogen fluoride; Alpha-chromium oxide prepared by the precipitation of chromium hydroxide from chromium nitrate followed by calcination in air at 500 C for 72 hours, treated with HF at 250 - 350℃;A 0%
B 19.9%
C 0%
diethyl ether
60-29-7

diethyl ether

1,1-difluoro-2-iodoethane
598-39-0

1,1-difluoro-2-iodoethane

phenylmagnesium bromide

phenylmagnesium bromide

A

fluorobenzene
462-06-6

fluorobenzene

B

iodobenzene
591-50-4

iodobenzene

C

biphenyl
92-52-4

biphenyl

D

1-fluoroethylene
75-02-5

1-fluoroethylene

Conditions
ConditionsYield
Zersetzen des Reaktionsproduktes mit Wasser; Produkt5: Stilben;
diethyl ether
60-29-7

diethyl ether

1,2-bromofluoroethane
358-97-4

1,2-bromofluoroethane

phenylmagnesium bromide

phenylmagnesium bromide

A

bromobenzene
108-86-1

bromobenzene

B

biphenyl
92-52-4

biphenyl

C

1-fluoroethylene
75-02-5

1-fluoroethylene

D

benzene
71-43-2

benzene

Conditions
ConditionsYield
Zersetzen des Reaktionsproduktes mit Wasser;
1-chloro-1-fluoroethane
1615-75-4

1-chloro-1-fluoroethane

A

1-fluoroethylene
75-02-5

1-fluoroethylene

B

chloroethylene
75-01-4

chloroethylene

Conditions
ConditionsYield
at 600℃;
1,2-difluoroethane
624-72-6

1,2-difluoroethane

1-fluoroethylene
75-02-5

1-fluoroethylene

Conditions
ConditionsYield
at 103.9 - 201.9℃;
With calcium sulfate at 350℃;
2-bromo-1,1-difluoroethane
359-07-9

2-bromo-1,1-difluoroethane

1-fluoroethylene
75-02-5

1-fluoroethylene

Conditions
ConditionsYield
With ethanol; zinc at 50℃;
1,1-difluoro-2-iodoethane
598-39-0

1,1-difluoro-2-iodoethane

1-fluoroethylene
75-02-5

1-fluoroethylene

Conditions
ConditionsYield
With diethyl ether; phenylmagnesium bromide
With diethyl ether; magnesium
With diethyl ether; potassium
With diethyl ether; sodium
1,2-bromofluoroethane
358-97-4

1,2-bromofluoroethane

1-fluoroethylene
75-02-5

1-fluoroethylene

Conditions
ConditionsYield
With ethanol; zinc
With diethyl ether; phenylmagnesium bromide
With potassium iodide
1,1,2-tribromoethane
78-74-0

1,1,2-tribromoethane

1-fluoroethylene
75-02-5

1-fluoroethylene

Conditions
ConditionsYield
With bromine; antimony(III) fluoride at 100℃; und Behandeln des Reaktionsprodukts mit Zink in Aethanol;
acetylene
74-86-2

acetylene

1-fluoroethylene
75-02-5

1-fluoroethylene

Conditions
ConditionsYield
With potassium cyanide; hydrogen fluoride; copper(l) cyanide; pyrographite at 160℃;
With hydrogen fluoride; mercury(II) oxide
With hydrogen fluoride; mercury(II) diacetate
1-fluoro-1-nitro-ethane
17003-27-9

1-fluoro-1-nitro-ethane

1-fluoroethylene
75-02-5

1-fluoroethylene

Conditions
ConditionsYield
With (thermolysis) at 300 - 340℃; Kinetics;
Vinyl bromide
593-60-2

Vinyl bromide

1-chloro-2,3,4,5,6-pentafluorobenzene
344-07-0

1-chloro-2,3,4,5,6-pentafluorobenzene

A

1-fluoroethylene
75-02-5

1-fluoroethylene

B

tetrafluorobezyne
5488-71-1

tetrafluorobezyne

Conditions
ConditionsYield
at 21.9℃; Irradiation;
Vinyl bromide
593-60-2

Vinyl bromide

A

(Z)-1-bromo-2-fluoroethylene
2366-31-6

(Z)-1-bromo-2-fluoroethylene

B

1-fluoroethylene
75-02-5

1-fluoroethylene

Conditions
ConditionsYield
With F at 0℃; under 112.5 Torr; Mechanism;
Hexafluorobenzene
392-56-3

Hexafluorobenzene

ethene
74-85-1

ethene

A

1-fluoroethylene
75-02-5

1-fluoroethylene

B

2,3,4,5,6-pentafluorostyrene
653-34-9

2,3,4,5,6-pentafluorostyrene

C

Pentafluorobenzene
363-72-4

Pentafluorobenzene

D

buta-1,3-diene
106-99-0

buta-1,3-diene

E

acetylene
74-86-2

acetylene

Conditions
ConditionsYield
Mechanism; Irradiation;A 8 % Chromat.
B 24 % Chromat.
C 12 % Chromat.
D 7 % Chromat.
E 19 % Chromat.
propene
187737-37-7

propene

A

methyl radical
2229-07-4

methyl radical

B

1-fluoroethylene
75-02-5

1-fluoroethylene

Conditions
ConditionsYield
With fluorine under 0.8 Torr; Mechanism; Product distribution; Irradiation; study of the branching ratio and radical products under multi-photon ionization conditions; other reagents and products;
ethane
74-84-0

ethane

A

methyl radical
2229-07-4

methyl radical

B

ethyl radical
2025-56-1

ethyl radical

C

ethene
74-85-1

ethene

D

1-fluoroethylene
75-02-5

1-fluoroethylene

E

acetylene
74-86-2

acetylene

Conditions
ConditionsYield
With fluorine photoelectron spectrum of the product mixture; the ethyl radical was investigated;
ethene
74-85-1

ethene

1-chloro-2,3,4,5,6-pentafluorobenzene
344-07-0

1-chloro-2,3,4,5,6-pentafluorobenzene

A

1-fluoroethylene
75-02-5

1-fluoroethylene

B

tetrafluorobezyne
5488-71-1

tetrafluorobezyne

Conditions
ConditionsYield
at 21.9℃; Irradiation;
ethene
74-85-1

ethene

monofluorocarbene
13453-52-6

monofluorocarbene

A

methylene
2465-56-7

methylene

B

Methyl fluoride
593-53-3

Methyl fluoride

C

1-fluoroethylene
75-02-5

1-fluoroethylene

D

1-fluoropropene
406-33-7

1-fluoropropene

E

acetylene
74-86-2

acetylene

Conditions
ConditionsYield
In gas Rate constant; Thermodynamic data; Ambient temperature; Irradiation; ΔH;
ethene
74-85-1

ethene

1-fluoroethylene
75-02-5

1-fluoroethylene

Conditions
ConditionsYield
With F In gas at -100℃; under 1E-07 Torr; Mechanism; Thermodynamic data; other temperatures, other collision energies; potential energy barrier to F atom addition to C2H4;
With F at -71.15 - 24.85℃; Kinetics; Substitution;
ethene
74-85-1

ethene

A

1-fluoroethylene
75-02-5

1-fluoroethylene

B

β-Fluoroethyl radical
28761-00-4

β-Fluoroethyl radical

Conditions
ConditionsYield
With fluorine In gas at 1226.9 - 2226.9℃; Rate constant;
2-fluoroethyl bromide
762-49-2

2-fluoroethyl bromide

1-fluoroethylene
75-02-5

1-fluoroethylene

Conditions
ConditionsYield
Mechanism; Irradiation;
Decomposition; Photolysis;
chloroethylene
75-01-4

chloroethylene

1-chloro-2,3,4,5,6-pentafluorobenzene
344-07-0

1-chloro-2,3,4,5,6-pentafluorobenzene

A

1-fluoroethylene
75-02-5

1-fluoroethylene

B

tetrafluorobezyne
5488-71-1

tetrafluorobezyne

Conditions
ConditionsYield
at 21.9℃; Irradiation;
1-fluoro-2-propanone
430-51-3

1-fluoro-2-propanone

A

ethane
74-84-0

ethane

B

ethene
74-85-1

ethene

C

1-fluoroethane
353-36-6

1-fluoroethane

D

1,2-difluoroethane
624-72-6

1,2-difluoroethane

E

1-fluoroethylene
75-02-5

1-fluoroethylene

Conditions
ConditionsYield
at 26.9℃; under 840 Torr; Rate constant; Product distribution; Irradiation; bath gas: He; further bath gases; further pressure;
1,3-difluoro-propan-2-one
453-14-5

1,3-difluoro-propan-2-one

A

Methyl fluoride
593-53-3

Methyl fluoride

B

1,2-difluoroethane
624-72-6

1,2-difluoroethane

C

1-fluoroethylene
75-02-5

1-fluoroethylene

Conditions
ConditionsYield
at 101.9 - 202.9℃; under 2.3 - 7.5 Torr; Irradiation;
1,1'-dichloro-2,2'-difluoroethene
79-35-6

1,1'-dichloro-2,2'-difluoroethene

A

ethene
74-85-1

ethene

B

1-fluoroethylene
75-02-5

1-fluoroethylene

C

1,2-difluoroethene
1691-13-0

1,2-difluoroethene

D

acetylene
74-86-2

acetylene

Conditions
ConditionsYield
With monosilane under 5 Torr; Mechanism; Product distribution; Irradiation; wave length 944.2 cm-1, ratio SiH4/C2Cl2F2 = 9.0;
1,1'-dichloro-2,2'-difluoroethene
79-35-6

1,1'-dichloro-2,2'-difluoroethene

A

1-fluoroethylene
75-02-5

1-fluoroethylene

B

acetylene
74-86-2

acetylene

Conditions
ConditionsYield
With monosilane under 5 Torr; Mechanism; Product distribution; Irradiation; wave length 1033.5 cm-1, ratio SiH4/C2Cl2F2 = 9.6;
2-fluoroethyl acetate
462-26-0

2-fluoroethyl acetate

A

ethene
74-85-1

ethene

B

1-fluoroethylene
75-02-5

1-fluoroethylene

Conditions
ConditionsYield
In toluene at 610℃; Product distribution;
2-fluoroethyl acetate
462-26-0

2-fluoroethyl acetate

1-fluoroethylene
75-02-5

1-fluoroethylene

Conditions
ConditionsYield
at 430.2 - 450.1℃; Rate constant;
1-fluoroethylene
75-02-5

1-fluoroethylene

RuH(C6H5)(CO)(P(C(CH3)3)2CH3)2
162291-59-0

RuH(C6H5)(CO)(P(C(CH3)3)2CH3)2

RuF(C2H3)(CO)(P(C(CH3)3)2CH3)2
878750-74-4

RuF(C2H3)(CO)(P(C(CH3)3)2CH3)2

Conditions
ConditionsYield
In benzene-d6 byproducts: C6H6; all manipulations under Ar atm.; soln. of Ru compd. reacted with C2H3F at 1 atm for 12 h at room temp.; detected by 31P(1H) NMR spectra;99%
With methyldi-t-butylphosphine In Cyclohexane-d12 byproducts: C6H6; all manipulations under Ar atm.; soln. of Ru and P compds. reacted in NMR tube with C2H3F at 1 atm for 12 h at room temp.; detected by 31P(1H) NMR spectra;99%
1-fluoroethylene
75-02-5

1-fluoroethylene

bis-trifluoromethyl-aminooxyl
2154-71-4

bis-trifluoromethyl-aminooxyl

C6H3F13N2O2
67329-58-2

C6H3F13N2O2

Conditions
ConditionsYield
for 21h; Ambient temperature;98%
1-fluoroethylene
75-02-5

1-fluoroethylene

tetrakis(trifluoromethyl)diphosphine
2714-60-5

tetrakis(trifluoromethyl)diphosphine

1,2-Bis-(bis-trifluoromethyl-phosphanyl)-1-fluoro-ethane
34250-88-9

1,2-Bis-(bis-trifluoromethyl-phosphanyl)-1-fluoro-ethane

Conditions
ConditionsYield
50°C (120 h);96%
Irradiation (UV/VIS); 20°C (94 h);59%
Irradiation;
1-fluoroethylene
75-02-5

1-fluoroethylene

[Ir2H(CO)2(μ-CO)(bis(diethylphosphino)methane)2][B(3,5-(CF3)2C6H3)4]
1357616-33-1

[Ir2H(CO)2(μ-CO)(bis(diethylphosphino)methane)2][B(3,5-(CF3)2C6H3)4]

A

[Ir2(H)(CO)3(μ-CCH2)(bis(diethylphosphino)methane)2][B(3,5-(CF3)2C6H3)4]
1357616-35-3

[Ir2(H)(CO)3(μ-CCH2)(bis(diethylphosphino)methane)2][B(3,5-(CF3)2C6H3)4]

B

[Ir2(H)2(CO)2(μ-H)(μ-CCHF)(bis(diethylphosphino)methane)2][B(3,5-(CF3)2C6H3)4]
1357616-37-5

[Ir2(H)2(CO)2(μ-H)(μ-CCHF)(bis(diethylphosphino)methane)2][B(3,5-(CF3)2C6H3)4]

Conditions
ConditionsYield
In dichloromethane-d2 (Ar); using Schlenk techniques; charging of NMR tube with (Ir2(CO)3(H)(PEt2CH2PEt2)2)(B((CF3)2C6H3)4), addn. of CD2Cl2, addn. of CFHCH2 via a gastight syringe, vigorous mixing for 30 min; monitoring by NMR, transferring to Schlenk tube, removal of solvent under vac., redissolving in Et2O, addn. of pentane, pptn.; elem. anal.;A 94%
B n/a
1-fluoroethylene
75-02-5

1-fluoroethylene

perfluoro(2,4-dimethyl-3-oxa-2,4-diazapentane)
6141-72-6

perfluoro(2,4-dimethyl-3-oxa-2,4-diazapentane)

A

O-[2-(Bis-trifluoromethyl-amino)-1-fluoro-ethyl]-N,N-bis-trifluoromethyl-hydroxylamine

O-[2-(Bis-trifluoromethyl-amino)-1-fluoro-ethyl]-N,N-bis-trifluoromethyl-hydroxylamine

B

O-[2-(Bis-trifluoromethyl-amino)-2-fluoro-ethyl]-N,N-bis-trifluoromethyl-hydroxylamine

O-[2-(Bis-trifluoromethyl-amino)-2-fluoro-ethyl]-N,N-bis-trifluoromethyl-hydroxylamine

Conditions
ConditionsYield
for 240h; Ambient temperature; in vacuo;A 93%
B 6%
1-fluoroethylene
75-02-5

1-fluoroethylene

1,1,2-Trifluoroethan
430-66-0

1,1,2-Trifluoroethan

Conditions
ConditionsYield
With xenon difluoride; silicon tetrafluoride at 20℃; for 5h; Fluorination;93%
1-fluoroethylene
75-02-5

1-fluoroethylene

N-chlorobistrifluoromethylamine
431-94-7

N-chlorobistrifluoromethylamine

A

1-(bis(trifluoromethyl)-amino)-2-fluoro-2-chloro-ethane
35060-90-3

1-(bis(trifluoromethyl)-amino)-2-fluoro-2-chloro-ethane

B

1-bis(trifluoromethyl)-amino-2-fluoro-2-chloro-ethane
35060-87-8

1-bis(trifluoromethyl)-amino-2-fluoro-2-chloro-ethane

Conditions
ConditionsYield
In gas Irradiation (UV/VIS); photolysis for 0.5 h;A 5%
B 91%
In neat (no solvent, gas phase) Irradiation (UV/VIS); photolysis for 0.5 h;A 5%
B 91%
at 25°C for 10 d in dark;A 7%
B 88%
1-fluoroethylene
75-02-5

1-fluoroethylene

N-bromobis(trifluoromethyl)amine
758-43-0

N-bromobis(trifluoromethyl)amine

A

1-(bis(trifluoromethyl)-amino)-2-bromo-1-fluoro-ethane

1-(bis(trifluoromethyl)-amino)-2-bromo-1-fluoro-ethane

B

1-bis(trifluoromethyl)-amino-2-bromo-2fluoro-ethane
25237-12-1

1-bis(trifluoromethyl)-amino-2-bromo-2fluoro-ethane

Conditions
ConditionsYield
Irradiation (UV/VIS); at 20°C for 16 h;A 6%
B 89%
Irradiation (UV/VIS); at 20°C for 16 h;A 6%
B 89%
for 16h; Ambient temperature;
at 20°C for 12 weeks in dark; ratio of (CF3)2NCH2CHFBr:(CF3)2NCHFCH2Br = 9:1;
at 20°C for 12 weeks in dark; ratio of (CF3)2NCH2CHFBr:(CF3)2NCHFCH2Br = 9:1;
1-fluoroethylene
75-02-5

1-fluoroethylene

N-Jod-bis(trifluormethyl)-amin
5764-87-4

N-Jod-bis(trifluormethyl)-amin

A

1-bis(trimethylfluoro)-amino-2-fluoro-2-iodo-ethane
35060-93-6

1-bis(trimethylfluoro)-amino-2-fluoro-2-iodo-ethane

B

1-(bis(trifluoromethyl)-amino)-2-iodo-1-fluoro-ethane
35060-88-9

1-(bis(trifluoromethyl)-amino)-2-iodo-1-fluoro-ethane

Conditions
ConditionsYield
Irradiation (UV/VIS); at 20°C for 1 h; in quartz tube;A 89%
B 7%
A 2%
B 89%
Irradiation (UV/VIS); at 20°C for 1 h; in quartz tube;A 89%
B 7%
1-fluoroethylene
75-02-5

1-fluoroethylene

bis(trifluoromethyl)phosphine
460-96-8

bis(trifluoromethyl)phosphine

2-Fluoroaethyl-bis(trifluoromethyl)phosphin
27393-67-5

2-Fluoroaethyl-bis(trifluoromethyl)phosphin

Conditions
ConditionsYield
Irradiation (UV/VIS); time of irradiation:44 h;88%
for 44h; Irradiation;
1-fluoroethylene
75-02-5

1-fluoroethylene

1,1,1,3-tetrachloro-3-fluoropropane
23153-22-2

1,1,1,3-tetrachloro-3-fluoropropane

Conditions
ConditionsYield
With tetrachloromethane; iron(III) chloride; iron; triethyl phosphate at 120 - 127℃; under 3000.3 - 6750.68 Torr; Autoclave; Inert atmosphere;86%
1-fluoroethylene
75-02-5

1-fluoroethylene

[Ir2H(CO)2(μ-CO)(bis(diethylphosphino)methane)2][B(3,5-(CF3)2C6H3)4]
1357616-33-1

[Ir2H(CO)2(μ-CO)(bis(diethylphosphino)methane)2][B(3,5-(CF3)2C6H3)4]

[Ir2(H)2(CO)2(μ-H)(μ-CCHF)(bis(diethylphosphino)methane)2][B(3,5-(CF3)2C6H3)4]
1357616-37-5

[Ir2(H)2(CO)2(μ-H)(μ-CCHF)(bis(diethylphosphino)methane)2][B(3,5-(CF3)2C6H3)4]

Conditions
ConditionsYield
With trimethylamine-N-oxide In dichloromethane (Ar); using Schlenk techniques; cooling of flask with soln. of (Ir2(CO)3(H)(PEt2CH2PEt2)2)B((CF3)2C6H3)4 in CH2Cl2 to -80°C, transferringof cooled CH2Cl2 soln. of Me3NO via cannula, addn. of CFHCH2, slow warm ing to room temp., stirring for 1 h; removal of solvent, monitoring by NMR;83%
Hoveyda-Grubbs catalyst second generation
301224-40-8

Hoveyda-Grubbs catalyst second generation

1-fluoroethylene
75-02-5

1-fluoroethylene

(RuCl2(CHF)(4,5-dihydro-1,3-dimesitylimidazol-2-ylidene))2

(RuCl2(CHF)(4,5-dihydro-1,3-dimesitylimidazol-2-ylidene))2

Conditions
ConditionsYield
In toluene byproducts: CH2CHC6H4OCH(CH3)2; High Pressure; (N2); exposure of toluene soln. of ruthenium compd. to vinyl fluoride at5 psig, cooling to -4°C, stirring for 3 h; cooling to -35°C for 30 min, filtration, wasing with pentane, drying in vac. for 30 min, stirring with benzene for 5 min, drying in vac. for 5 h, elem. anal.;81.3%
1-fluoroethylene
75-02-5

1-fluoroethylene

carbon monoxide
201230-82-2

carbon monoxide

2-fluoropropionaldehyde
814-66-4

2-fluoropropionaldehyde

Conditions
ConditionsYield
With hydrogen; dodecacarbonyltetrarhodium(0) In toluene at 80℃; under 68 Torr; for 18h;81%
tetrachloromethane
56-23-5

tetrachloromethane

1-fluoroethylene
75-02-5

1-fluoroethylene

1,1,1,3-tetrachloro-3-fluoropropane
23153-22-2

1,1,1,3-tetrachloro-3-fluoropropane

Conditions
ConditionsYield
With iron; triethyl phosphite at 120 - 125℃; under 2999.54 - 6205.94 Torr; for 8h; Temperature; Pressure; Autoclave; Inert atmosphere;81%
1-fluoroethylene
75-02-5

1-fluoroethylene

1,1,1,2,2,3,3-heptafluoro-3-iodo-propane
754-34-7

1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

1,1,1,2,2,3,3,5-octafluoro-5-iodopentane

1,1,1,2,2,3,3,5-octafluoro-5-iodopentane

Conditions
ConditionsYield
With dibenzoyl peroxide at 110 - 120℃; for 4h; Autoclave;80%
1-fluoroethylene
75-02-5

1-fluoroethylene

(2-Chlor-2-fluorethyl)schwefelpentafluorid
106821-13-0

(2-Chlor-2-fluorethyl)schwefelpentafluorid

Conditions
ConditionsYield
With pentafluorosulfanyl chloride at -35℃; for 4h; Irradiation;76%
1-fluoroethylene
75-02-5

1-fluoroethylene

butyryl chloride
141-75-3

butyryl chloride

1-Chloro-1-fluoro-hexan-3-one

1-Chloro-1-fluoro-hexan-3-one

Conditions
ConditionsYield
With iron(III) chloride In dichloromethane at 0℃; for 3h;76%
1-iodoheptadecafluorooctane
507-63-1

1-iodoheptadecafluorooctane

1-fluoroethylene
75-02-5

1-fluoroethylene

A

iodo-1H,1H,2H,2H-perfluorodecane
89608-43-5

iodo-1H,1H,2H,2H-perfluorodecane

B

1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,10,12-Nonadecafluoro-12-iodo-dodecane
89608-42-4

1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,10,12-Nonadecafluoro-12-iodo-dodecane

Conditions
ConditionsYield
With ethanolamine; triiron dodecarbonyl In ethanol at 60℃; for 5h;A 14%
B 75%
1-fluoroethylene
75-02-5

1-fluoroethylene

acetyl chloride
75-36-5

acetyl chloride

2-chloro-2-fluoroethyl methyl ketone

2-chloro-2-fluoroethyl methyl ketone

Conditions
ConditionsYield
With iron(III) chloride In dichloromethane at 0℃; for 3h;70%
1-fluoroethylene
75-02-5

1-fluoroethylene

Hexanoyl chloride
142-61-0

Hexanoyl chloride

1-Chloro-1-fluoro-octan-3-one

1-Chloro-1-fluoro-octan-3-one

Conditions
ConditionsYield
With iron(III) chloride In dichloromethane at 0℃; for 3h;65%
1-fluoroethylene
75-02-5

1-fluoroethylene

C2ClF5O3S

C2ClF5O3S

2-(2-Chloro-1-fluoro-ethoxy)-1,1,2,2-tetrafluoro-ethanesulfonyl fluoride

2-(2-Chloro-1-fluoro-ethoxy)-1,1,2,2-tetrafluoro-ethanesulfonyl fluoride

Conditions
ConditionsYield
In various solvent(s) at -110℃; for 18h;62%
1-fluoroethylene
75-02-5

1-fluoroethylene

N-bromobis(trifluoromethyl)amine
758-43-0

N-bromobis(trifluoromethyl)amine

Perfluoro-2-azapropen
371-71-1

Perfluoro-2-azapropen

Conditions
ConditionsYield
20°C, 12 weeks, darkness;61%
20°C, 12 weeks, darkness;61%
1-fluoroethylene
75-02-5

1-fluoroethylene

1-bromo-1-fluoroethylene
420-25-7

1-bromo-1-fluoroethylene

Conditions
ConditionsYield
With boron tribromide In dichloromethane at 20℃; under 1875.19 Torr; for 2h; Solvent; Temperature; Autoclave; Inert atmosphere;61%
1-fluoroethylene
75-02-5

1-fluoroethylene

Ethyl trichloroacetate
515-84-4

Ethyl trichloroacetate

2,2,4-Trichloro-4-fluoro-butyric acid ethyl ester
77147-44-5

2,2,4-Trichloro-4-fluoro-butyric acid ethyl ester

Conditions
ConditionsYield
copper(I) chloride In acetonitrile at 150℃; for 6h;60%
bis(triphenylphosphine)ethylenenickel(0)
23777-40-4

bis(triphenylphosphine)ethylenenickel(0)

1-fluoroethylene
75-02-5

1-fluoroethylene

CH2CHFNi(P(C6H5)3)2
25037-26-7

CH2CHFNi(P(C6H5)3)2

Conditions
ConditionsYield
In diethyl ether byproducts: ethylene; react. in ether at room temp.;;56%
In diethyl ether byproducts: ethylene; react. in ether at room temp.;;56%
1-fluoroethylene
75-02-5

1-fluoroethylene

benzoyl chloride
98-88-4

benzoyl chloride

3-Chloro-3-fluoro-1-phenyl-propan-1-one

3-Chloro-3-fluoro-1-phenyl-propan-1-one

Conditions
ConditionsYield
With iron(III) chloride In dichloromethane at 0℃; for 3h;50%
1-fluoroethylene
75-02-5

1-fluoroethylene

2-iodoyl-5-methylbenzoic acid
52548-14-8

2-iodoyl-5-methylbenzoic acid

C10H9FO2

C10H9FO2

Conditions
ConditionsYield
With sodium hydrogencarbonate In dimethyl sulfoxide at 20℃; for 6h; Inert atmosphere; Sealed tube; UV-irradiation; regioselective reaction;50%
1-fluoroethylene
75-02-5

1-fluoroethylene

4-methyl-benzoyl chloride
874-60-2

4-methyl-benzoyl chloride

3-Chloro-3-fluoro-1-p-tolyl-propan-1-one

3-Chloro-3-fluoro-1-p-tolyl-propan-1-one

Conditions
ConditionsYield
With iron(III) chloride In dichloromethane at 0℃; for 3h;49%

VINYL FLUORIDE Chemical Properties

Molecular formula: C2H3F
Molar mass: 46.04 g/mol
Appearance: Colorless gas with a faint, ethereal odor
Density: 2 g/cm3 (gas); 0.91 g/cm3 (liquid)
Melting point: -160.5 °C (-257 °F)
Boiling point: -72.2 °C (98 °F)
Solubility in water: Slightly soluble
Vapor pressure: 25 500 kPa
Other names: Fluoroethylene, Vinylfluoride, Vinyl fluoride monomer, Monofluoroethylene, VF, R 1141, UN 1860 (inhibited)
Vinyl fluoride(75-02-5) is an organic halide with the chemical formula CH2=CHF. It is a colorless gas with a faint etherlike odor. 
The Structure of Vinyl fluoride(75-02-5):

VINYL FLUORIDE History

Vinyl fluoride(75-02-5) was first prepared in 1901 by Frédéric Swarts (the Belgian chemist who was the first to prepare CFCs in 1892) using the reaction of zinc with 1,1-difluoro-2-bromoethane. Now it is synthesized by the reaction of acetylene and hydrogen fluoride.

VINYL FLUORIDE Uses

The principal use of Vinyl fluoride(75-02-5) is as the primary component in making polyvinyl fluoride, a polymer of the basic vinyl fluoride monomer.

VINYL FLUORIDE Production

Vinyl fluoride (75-02-5), the monomer for poly(vinyl fluoride), is manufactured by addition of hydrogen fluoride to acetylene:
             HC≡CH + HF →CH2=CHF

VINYL FLUORIDE Toxicity Data With Reference

1.   

otr-rat-ihl

   ARTODN    Archives of Toxicology. 47 (1981),71.
2.   

mnt-mus-ihl

   EMMUEG    Environmental and Molecular Mutagenesis. 19 (Suppl 20)(1992),5.

VINYL FLUORIDE Consensus Reports

NTP 10th Report on Carcinogens. Reported in EPA TSCA Inventory.

VINYL FLUORIDE Safety Profile

Confirmed carcinogen. A poison. Mutation data reported. A very dangerous fire hazard. To fight fire, stop flow of gas. When heated to decomposition it emits toxic fumes of F. See also FLUORIDES.
Hazard Codes: F
Risk Statements: 12-40
12:  Extremely Flammable 
40:  Limited evidence of a carcinogenic effect  
Safety Statements: 9-16-23-36/37/39
9:  Keep container in a well-ventilated place 
16:  Keep away from sources of ignition - No smoking 
23:  Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) 
36/37/39:  Wear suitable protective clothing, gloves and eye/face protection  
RIDADR: 1860
Hazard Note: Flammable
HazardClass: 2.1

VINYL FLUORIDE Standards and Recommendations

ACGIH TLV: TWA 1 ppm; Suspected Human Carcinogen
NIOSH REL: (Vinyl Chloride) TWA 1 ppm; CL 5 ppm/15M
DOT Classification:  2.1; Label: Flammable Gas
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