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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

4-Chlorobenzylamine Manufacturer/High quality/Best price/In stock

Cas:104-86-9

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 4-Chlorobenzylamine supplier in China

Cas:104-86-9

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new api, intermedi

4-Chlorobenzylamine

Cas:104-86-9

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

4-Chlorobenzylamine

Cas:104-86-9

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

4-Chlorobenzylamine 104-86-9

Cas:104-86-9

Min.Order:1 Kilogram

FOB Price: $15.0 / 50.0

Type:Trading Company

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Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.

104-86-9 4-Chlorobenzylamine

Cas:104-86-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

China factory supply CAS 104-86-9 with best price

Cas:104-86-9

Min.Order:10 Gram

FOB Price: $146.0 / 176.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Name: 4-Chlorobenzylamine Synonyms: Chlorobenzylamin CAS: 104-86-9 MF: C7H9ClN Appearance:White powder Storage:Store in cool and dry place, away from sun light. Package:25kg/drum Application:Pharmaceutical Intermediate Transportation:By sea or

4-Chlorobenzylamine

Cas:104-86-9

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

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Hangzhou Sartort Biopharma Co., Ltd

Appearance:Clear slightly yellow liquid Storage:room temperature Package:200kg/drum Application:chemicals Transportation:Express/Sea/Air Port:Any port in China

4-Chlorobenzylamine with high quality

Cas:104-86-9

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

4-Chlorobenzylamine 104-86-9

Cas:104-86-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

4-Chlorobenzylamine

Cas:104-86-9

Min.Order:1 Kilogram

FOB Price: $45.0 / 56.0

Type:Trading Company

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LIDE PHARMACEUTICALS LIMITED

Advantage : LIDE PHARMACEUTICALS LTD. is a mid-small manufacturing-type enterprise, engaged in pharmaceutical intermediates of R&D, custom-made and production, and also involving trading chemicals for export. We have established the R&amp

4-Chlorobenzylamine/ LIDE PHARMA- Factory supply / Best price

Cas:104-86-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

4-Chlorobenzylamine

Cas:104-86-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

4-Chlorobenzylamine

Cas:104-86-9

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

4-Chlorobenzylamine

Cas:104-86-9

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

4-Chlorobenzylamine

Cas:104-86-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

4-Chlorobenzylamine

Cas:104-86-9

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Shanghai Minstar Chemical Co., Ltd

4-Chlorobenzylamine Basic information Product Name: 4-Chlorobenzylamine Synonyms: 4-Chlorobenzylamine, 97+%;4-ChlorobenzylaMine, 98% 2.5GR;Chlorobenzylamine,97%;Benzenemethanamine, 4-chloro-;4-ChlorobenzeneMethanaMine;4-CHLOROBENZYLAMINE,98 %;

4-Chlorobenzylamine

Cas:104-86-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Ality Chemical Corporation

Appearance:powder or granule ( refer to COA) Application:Librium, Valium

Factory Supply 4-Chlorobenzylamine

Cas:104-86-9

Min.Order:0

Negotiable

Type:Other

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

4-Chlorobenzylamine

Cas:104-86-9

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

4-Chlorobenzylamine

Cas:104-86-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

4-Chlorobenzylamine

Cas:104-86-9

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

4-Chlorobenzylamine

Cas:104-86-9

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

4-Chlorobenzylamine

Cas:104-86-9

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

4-chlorobenzylamine cas no. 104-86-9 98%

Cas:104-86-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

4-Chlorobenzylamine

Cas:104-86-9

Min.Order:0

Negotiable

Type:Other

inquiry

Lonwin Chemical Group Limited

Shanghai Lonwin Chemical company is a subsidiary of Lonwin Industry Group Limited, was established in 2011 and is headquartered in Shanghai, adjacent to China National Convention and Exhibition Center and Hongqiao transportation hub.Lonwinchem is

Best price 4-Chlorobenzylamine 104-86-9

Cas:104-86-9

Min.Order:100 Kilogram

FOB Price: $100.0 / 150.0

Type:Other

inquiry

GIHI CHEMICALS CO.,LIMITED

high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,or Intermediates,fine chemicals Transportation:air,sea,courier

4-Chlorobenzylamine

Cas:104-86-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec 4-Chlorobenzylamine 500g

Cas:104-86-9

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

4-ChlorobenzylaMine

Cas:104-86-9

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Synthetic route

4-chlorobenzaldehyde
104-88-1

4-chlorobenzaldehyde

4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

Conditions
ConditionsYield
With ammonium hydroxide; hydrogen In ethanol at 130℃; under 7500.75 Torr; for 12h; Autoclave;100%
With ammonia; hydrogen In methanol at 89.84℃; under 30003 Torr; for 3h;98%
With [pentamethylcyclopentadienyl*Ir(N-phenyl-2-pyridinecarboxamidate)Cl]; ammonium formate In methanol at 37℃; for 15h; chemoselective reaction;98%
4-Cyanochlorobenzene
623-03-0

4-Cyanochlorobenzene

4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

Conditions
ConditionsYield
With [Ru(H)(BH4)(CO)(PPh3)(3-(di-tert-butylphosphino)-N-((1-methyl-1H-imidazol-2 yl)methyl)propylamine)]; hydrogen In isopropyl alcohol at 70℃; for 3h; Inert atmosphere; Autoclave;99%
With ammonia; hydrogen In water; isopropyl alcohol at 80℃; under 15001.5 Torr; for 24h; Autoclave;98%
With C19H34Cl2CoN2P; hydrogen; sodium ethanolate; sodium triethylborohydride In benzene at 135℃; under 22502.3 Torr; for 36h; Autoclave;93%
4-chlorobenzaldoxime
3848-36-0

4-chlorobenzaldoxime

4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

Conditions
ConditionsYield
With (pyridine)(tetrahydroborato)zinc In tetrahydrofuran for 2.8h; Heating;96%
With sodium hydrogensulfate monohydrate; molybdenum(V) chloride; sodium cyanoborohydride In ethanol for 2.2h; Reflux;96%
With sodium tetrahydroborate at 20℃; for 0.0333333h; neat (no solvent, solid phase);95%
4-chlorobenzyl azide
27032-10-6

4-chlorobenzyl azide

4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

Conditions
ConditionsYield
With Amberlite IRA-400; borohydride form; copper(II) sulfate In methanol at 20℃; for 6h; Reduction;94%
With ammonium chloride; zinc In ethanol; water
With hydrogen; palladium In tetrahydrofuran; N,N-dimethyl-formamide at 50℃; under 6080.41 Torr; for 22h; Inert atmosphere;
With formic acid; 2,6-dimethyl-pyridine-3,5-dicarboxylic acid diethyl ester; N-ethyl-N,N-diisopropylamine In acetonitrile at 20℃; for 40h; Irradiation;84 %Chromat.
4-Cyanochlorobenzene
623-03-0

4-Cyanochlorobenzene

A

N,N-bis(4-chlorobenzyl)amine
21913-13-3

N,N-bis(4-chlorobenzyl)amine

B

4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

Conditions
ConditionsYield
With sodium tetrahydroborate; nickel dichloride In ethanol at 20℃; for 0.0833333h;A 7%
B 85%
With methanol; cobalt(II) chloride; diborane at -10℃; for 0.5h;A 9.4%
B 71.1%
With methanol; cobalt(II) chloride; diborane for 0.5h; Ambient temperature;A 52%
B 27%
1-Chloro-4-(chloromethyl)benzene
104-83-6

1-Chloro-4-(chloromethyl)benzene

4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

Conditions
ConditionsYield
With ammonium hydroxide; potassium dihydrogenphosphate In tert-butyl methyl ether at 20℃; for 0.5h; Reagent/catalyst; Solvent; Autoclave;85%
With hexamethylenetetramine
With hydrogenchloride; potassium hydride; 1,1,3,3-tetramethyldisilazane 1.) THF, 1 h, 0 deg C; 1 h, r.t.; Yield given. Multistep reaction;
With ammonia at 25℃; Kinetics; Activation energy; Temperature;
2-Chlorobenzonitrile
873-32-5

2-Chlorobenzonitrile

A

4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

B

benzylamine
100-46-9

benzylamine

Conditions
ConditionsYield
With potassium hydroxide; samarium diiodide In tetrahydrofuran for 0.0666667h; Ambient temperature;A 6%
B 77%
para-Chlorobenzyl alcohol
873-76-7

para-Chlorobenzyl alcohol

4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

Conditions
ConditionsYield
With ammonium hydroxide; C19H37IrN4(2+)*2I(1-) at 170℃; for 100h; Sealed tube;77%
With ammonia In toluene at 110℃; under 5250.53 Torr; for 20h;72%
Multi-step reaction with 2 steps
1: acetic acid; hydrogen bromide / 0.5 h / 0 °C
2: ammonia / ethanol; water / 4 h / 20 °C
View Scheme
2-(4-chloro-benzyl)-1H-isoindole-1,3(2H)-dione
131523-32-5

2-(4-chloro-benzyl)-1H-isoindole-1,3(2H)-dione

4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

Conditions
ConditionsYield
With hydrazine hydrate In 1,4-dioxane at 110℃; Gabriel Amine Synthesis; Inert atmosphere;74%
With hydrazine hydrate In ethanol for 3h; Inert atmosphere; Reflux;42%
With hydrazine hydrate In methanol for 1h; Heating;
4-chlorobenzamide
619-56-7

4-chlorobenzamide

4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

Conditions
ConditionsYield
With titanium tetrachloride; magnesium In tetrahydrofuran at 0 - 20℃; Inert atmosphere;72%
With sulfuric acid at 35 - 40℃; Electrolysis.an einer Bleikathode;
With 1,10-Phenanthroline; diethoxymethylane; iron(II) acetate In toluene at 100℃; for 28h; Inert atmosphere; chemoselective reaction;60 %Chromat.
methanol
67-56-1

methanol

4-chlorobenzyl azide
27032-10-6

4-chlorobenzyl azide

A

N,N-dimethyl-4-chlorobenzylamine
15184-98-2

N,N-dimethyl-4-chlorobenzylamine

B

4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

C

N-methyl-4-chlorobenzylamine
104-11-0

N-methyl-4-chlorobenzylamine

Conditions
ConditionsYield
With trans-RuCl(phenpyra-Me)(PPh3)2PF6; sodium hydroxide at 125℃; for 2.5h; Sealed tube; Inert atmosphere; Glovebox;A 5 %Chromat.
B 7 %Chromat.
C 69%
4-Cyanochlorobenzene
623-03-0

4-Cyanochlorobenzene

A

4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

B

benzylamine
100-46-9

benzylamine

Conditions
ConditionsYield
With potassium hydroxide; samarium diiodide In tetrahydrofuran for 0.05h; Ambient temperature;A 12%
B 56%
4-vinylbenzyl chloride
1073-67-2

4-vinylbenzyl chloride

4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

Conditions
ConditionsYield
With D-glucose; E. coli LZ220; ammonia; oxygen; ammonium chloride In aq. phosphate buffer at 30℃; for 24h; pH=8; Green chemistry; Enzymatic reaction;47%
N,N-bis(p-chlorobenzylamino)ethane dihydrobromide

N,N-bis(p-chlorobenzylamino)ethane dihydrobromide

A

6‐chloro‐1,2,3,4‐tetrahydroisoquinoline
33537-99-4

6‐chloro‐1,2,3,4‐tetrahydroisoquinoline

B

4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

Conditions
ConditionsYield
With aluminium trichloride In decalin at 180℃; for 2h;A 45%
B n/a
4-Cyanochlorobenzene
623-03-0

4-Cyanochlorobenzene

A

N,N-bis(4-chlorobenzyl)amine
21913-13-3

N,N-bis(4-chlorobenzyl)amine

B

4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

C

para-Chlorobenzyl alcohol
873-76-7

para-Chlorobenzyl alcohol

Conditions
ConditionsYield
With nickel dichloride; zinc In methanol for 4h; Heating;A 5%
B 37.4%
C 39.2%
With nickel dichloride; zinc In methanol for 4h; Heating;A 5%
B 37.4%
C 39.2%
(1E, 2E)-1,2-bis (4-chlorobenzylidene) hydrazine
41097-37-4

(1E, 2E)-1,2-bis (4-chlorobenzylidene) hydrazine

A

(1R,2S)-1,2-bis(4-chlorophenyl)ethane-1,2-diamine
86212-34-2, 91044-20-1, 98674-96-5, 74641-30-8

(1R,2S)-1,2-bis(4-chlorophenyl)ethane-1,2-diamine

B

4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

(1R,2R)-1,2-Bis-(4-chloro-phenyl)-ethane-1,2-diamine

(1R,2R)-1,2-Bis-(4-chloro-phenyl)-ethane-1,2-diamine

Conditions
ConditionsYield
With methanesulfonic acid; zinc In tetrahydrofuran at 25℃; for 8h; reduction;A n/a
B 35%
C n/a
With titanium tetrachloride; zinc In tetrahydrofuran at 25℃; for 8h; reduction;A n/a
B 13%
C n/a
4-chlorobenzaldoxime
3848-36-0

4-chlorobenzaldoxime

A

(1R,2S)-1,2-bis(4-chlorophenyl)ethane-1,2-diamine
86212-34-2, 91044-20-1, 98674-96-5, 74641-30-8

(1R,2S)-1,2-bis(4-chlorophenyl)ethane-1,2-diamine

B

4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

(1R,2R)-1,2-Bis-(4-chloro-phenyl)-ethane-1,2-diamine

(1R,2R)-1,2-Bis-(4-chloro-phenyl)-ethane-1,2-diamine

Conditions
ConditionsYield
With methanesulfonic acid; zinc In acetonitrile at 25℃; reduction;A n/a
B 32%
C n/a
With titanium tetrachloride; zinc In tetrahydrofuran at 25℃; reduction;A n/a
B 3%
C n/a
N-(4-chloro-benzyl)-phthalamic acid
17332-59-1

N-(4-chloro-benzyl)-phthalamic acid

4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

Conditions
ConditionsYield
With hydrogenchloride
(4-chloro-benzyl)-hexamethylenetetraminium; chloride
96634-13-8

(4-chloro-benzyl)-hexamethylenetetraminium; chloride

4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

Conditions
ConditionsYield
With hydrogenchloride; methanol
ammonium formate
540-69-2

ammonium formate

4-chlorobenzaldehyde
104-88-1

4-chlorobenzaldehyde

4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

Conditions
ConditionsYield
anschliessenden Behandeln mit wss.HCl;
4-chlorobenzaldehyde-O-methyl oxime
33499-37-5, 54615-09-7, 87861-05-0

4-chlorobenzaldehyde-O-methyl oxime

4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

Conditions
ConditionsYield
(i) B2H6, THF, (ii) aq. KOH; Multistep reaction;
(E)-N′-(4′-chlorobenzylidene)isonicotinohydrazide
6342-46-7

(E)-N′-(4′-chlorobenzylidene)isonicotinohydrazide

A

pyridine-4-methanol
586-95-8

pyridine-4-methanol

B

4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

Conditions
ConditionsYield
In water; N,N-dimethyl-formamide Mechanism; polarographic reduction,;
(Z)-p-chlorobenzaldehyde oxime
3717-23-5

(Z)-p-chlorobenzaldehyde oxime

4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

Conditions
ConditionsYield
With tetramethylammonium bromide Mechanism; polarographic reduction at pH=3, other supporting electrolytes; values of diffusion current constant;
4-chlorobenzaldehyde oxime
3717-24-6

4-chlorobenzaldehyde oxime

4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

Conditions
ConditionsYield
With tetramethylammonium bromide Mechanism; polarographic reduction at pH=3, other supporting electrolytes; values of diffusion current constant;
N-(4-chlorobenzyl)acetamide
57058-33-0

N-(4-chlorobenzyl)acetamide

A

acetic acid
64-19-7

acetic acid

B

4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

C

5-(Acetylamino-methyl)-2-chloro-benzenesulfonic acid

5-(Acetylamino-methyl)-2-chloro-benzenesulfonic acid

Conditions
ConditionsYield
With sulfuric acid In water at 60 - 92℃; Kinetics; Mechanism; Thermodynamic data; ΔH(excit.), ΔS(excit.);
C7H8ClN*H(1+)

C7H8ClN*H(1+)

C14H13NO
114444-46-1

C14H13NO

A

1-methyl-4-(phenylacetyl)pyridinium cation
124225-44-1

1-methyl-4-(phenylacetyl)pyridinium cation

B

4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

Conditions
ConditionsYield
In water at 25℃; Equilibrium constant; Rate constant;
3-amino-4-chlorobenzylamine dihydrochloride
102677-74-7

3-amino-4-chlorobenzylamine dihydrochloride

4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

Conditions
ConditionsYield
With hydrogenchloride; hypophosphorous acid; sodium nitrite 2.) 15 min; Multistep reaction;
C9H12ClNS*ClH
97732-00-8

C9H12ClNS*ClH

A

dimethylsulfide
75-18-3

dimethylsulfide

B

4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

Conditions
ConditionsYield
With iodide; hydrogen cation In water at 25℃; Rate constant; pH dependence (pH = 0.5-3.0), μ = 1.0 with KCl;
N-(4-chlorobenzyl)-S,S-dimethylsulfilimmonium chloride
97732-00-8

N-(4-chlorobenzyl)-S,S-dimethylsulfilimmonium chloride

A

dimethylsulfide
75-18-3

dimethylsulfide

B

4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

Conditions
ConditionsYield
With 3-nitro-5-thiobenzoic acid; hydrogen cation In water at 25℃; Rate constant; var. reductant thiol anions, ionic strength: μ = 1.0 with KCl, catalytic constants for buffer, leaving group effects;
4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

4-Ethoxy-2,3,5,6,7,8-hexahydro-chinazolin-2-on
98077-17-9

4-Ethoxy-2,3,5,6,7,8-hexahydro-chinazolin-2-on

4-(4-Chlor-benzylamino)-2,3,5,6,7,8-hexahydrochinazolin-2-on

4-(4-Chlor-benzylamino)-2,3,5,6,7,8-hexahydrochinazolin-2-on

Conditions
ConditionsYield
In N,N-dimethyl-formamide for 20.5h; Heating;100%
4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

N-(4-chlorobenzylidene)-4-chlorobenzylamine
31264-06-9

N-(4-chlorobenzylidene)-4-chlorobenzylamine

Conditions
ConditionsYield
With oxygen; methylene blue; potassium carbonate In acetonitrile at 20℃; for 10h; Irradiation; Green chemistry;100%
With oxygen at 100℃; for 8h; Time; Schlenk technique;99%
With oxygen; 2Co(2+)*2C12H6O4(2-)*C34H12Cl4N4O4*4C3H7NO In N,N-dimethyl-formamide at 40℃; for 6h; Irradiation;99%
1-(3-methylphenyl)-2-oxo-1,2-dihydropyridine-3-carboxylic acid

1-(3-methylphenyl)-2-oxo-1,2-dihydropyridine-3-carboxylic acid

4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

N-(4-chlorobenzyl)-1-(3-methylphenyl)-2-oxo-1,2-dihydropyridine-3-carboxamide
694479-04-4

N-(4-chlorobenzyl)-1-(3-methylphenyl)-2-oxo-1,2-dihydropyridine-3-carboxamide

Conditions
ConditionsYield
With 1-hydroxy-7-aza-benzotriazole; 2-(3H-[1,2,3]triazolo[4,5-b]pyridin-3-yl)-1,1,3,3-tetramethyluronium hexafluorophosphate(V); diisopropylamine In dichloromethane at 20℃; for 1h;100%
4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

N-[(tert-butoxy)carbonyl]-N-(2-oxo-3-phenylpropyl)glycine
305324-43-0

N-[(tert-butoxy)carbonyl]-N-(2-oxo-3-phenylpropyl)glycine

4-[(tert-butoxy)carbonyl]-1-[(4-chlorophenyl)methyl]-6-(phenylmethyl)piperazin-2-one
305324-50-9

4-[(tert-butoxy)carbonyl]-1-[(4-chlorophenyl)methyl]-6-(phenylmethyl)piperazin-2-one

Conditions
ConditionsYield
Stage #1: 4-chlorobenzylamine; N-[(tert-butoxy)carbonyl]-N-(2-oxo-3-phenylpropyl)glycine With sodium tris(acetoxy)borohydride; acetic acid at 25℃; Condensation;
Stage #2: With 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In N,N-dimethyl-formamide at 25℃; Cyclization;
100%
4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

N-[(tert-butoxy)carbonyl]-N-(2-oxo-4-phenylbutyl)glycine
305324-44-1

N-[(tert-butoxy)carbonyl]-N-(2-oxo-4-phenylbutyl)glycine

4-[(tert-butoxy)carbonyl]-1-[(4-chlorophenyl)methyl]-6-(2-phenylethyl)piperazin-2-one
305324-55-4

4-[(tert-butoxy)carbonyl]-1-[(4-chlorophenyl)methyl]-6-(2-phenylethyl)piperazin-2-one

Conditions
ConditionsYield
Stage #1: 4-chlorobenzylamine; N-[(tert-butoxy)carbonyl]-N-(2-oxo-4-phenylbutyl)glycine With sodium tris(acetoxy)borohydride; acetic acid at 25℃; Condensation;
Stage #2: With 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In N,N-dimethyl-formamide at 25℃; Cyclization;
100%
4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

1,1'-Thiocarbonyldiimidazole
6160-65-2

1,1'-Thiocarbonyldiimidazole

methyl iodide
74-88-4

methyl iodide

3-(4-chloro-benzylthiocarbamoyl)-1-methyl-3H-imidazol-1-ium; iodide

3-(4-chloro-benzylthiocarbamoyl)-1-methyl-3H-imidazol-1-ium; iodide

Conditions
ConditionsYield
Stage #1: 4-chlorobenzylamine; 1,1'-Thiocarbonyldiimidazole In acetonitrile at 20℃; for 1h;
Stage #2: methyl iodide In acetonitrile at 20℃;
100%
Cyclohexyl isocyanide
931-53-3

Cyclohexyl isocyanide

propionaldehyde
123-38-6

propionaldehyde

4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

2-hydroxynitrobenzene
88-75-5

2-hydroxynitrobenzene

2-[(4-chlorobenzyl)-(2-nitrophenyl)amino]-N-cyclohexylbutyramide

2-[(4-chlorobenzyl)-(2-nitrophenyl)amino]-N-cyclohexylbutyramide

Conditions
ConditionsYield
In methanol microwave irradiation;100%
In toluene at 60℃; for 20h; Ugi-Smiles coupling;90%
In methanol at 40℃; for 20h; Ugi reaction;74%
phosgene
75-44-5

phosgene

4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

4-chlorobenzyl isocyanate
30280-44-5

4-chlorobenzyl isocyanate

Conditions
ConditionsYield
In toluene100%
In toluene at 20℃; for 2.25h; Heating / reflux;100%
In toluene at 20℃; for 2.25h; Heating / reflux;100%
With triethylamine In dichloromethane; toluene at -20 - 25℃; for 4.08333h; Inert atmosphere;
2,6-Dibromopyridine
626-05-1

2,6-Dibromopyridine

4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

(6-bromopyridin-2-yl)(4-chlorobenzyl)amine
866546-12-5

(6-bromopyridin-2-yl)(4-chlorobenzyl)amine

Conditions
ConditionsYield
at 150℃; for 0.5h; Neat (no solvent); Microwave irradiation;100%
4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

N-[(tert-butoxy)carbonyl]piperidine-4-carboxylic acid
84358-13-4

N-[(tert-butoxy)carbonyl]piperidine-4-carboxylic acid

tert-butyl 4-(4-chlorobenzylcarbamoyl)piperidine-1-carboxylate
881833-22-3

tert-butyl 4-(4-chlorobenzylcarbamoyl)piperidine-1-carboxylate

Conditions
ConditionsYield
With 1-hydroxy-7-aza-benzotriazole; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In tetrahydrofuran at 20℃; for 16h;100%
With benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In N,N-dimethyl-formamide at 20℃; for 15h;88%
With 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triethylamine In dichloromethane at 20℃; for 18h;72%
Pyruvic aldehyde dimethyl acetal
6342-56-9

Pyruvic aldehyde dimethyl acetal

4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

(4-chloro-benzyl)-[2,2-dimethoxy-1-methyl-eth-(Z)-ylidene]-amine
919994-55-1

(4-chloro-benzyl)-[2,2-dimethoxy-1-methyl-eth-(Z)-ylidene]-amine

Conditions
ConditionsYield
In toluene for 3h; Heating / reflux;100%
N-tert-butyloxycarbonylpiperidin-4-one
79099-07-3

N-tert-butyloxycarbonylpiperidin-4-one

4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

4-(4-chloro-benzylamino)-piperidine-1-carboxylic acid tert-butyl ester
849106-37-2

4-(4-chloro-benzylamino)-piperidine-1-carboxylic acid tert-butyl ester

Conditions
ConditionsYield
With sodium tris(acetoxy)borohydride; acetic acid In 1,2-dichloro-ethane100%
With sodium tris(acetoxy)borohydride; acetic acid In 1,2-dichloro-ethane at 20℃; for 2h; Inert atmosphere;
4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

dimethyl acetylenedicarboxylate
762-42-5

dimethyl acetylenedicarboxylate

C13H14ClNO4
1012859-65-2

C13H14ClNO4

Conditions
ConditionsYield
In water at 20℃; for 2h; Michael-type addition;100%
In dichloromethane at 20℃; for 0.166667h;
In methanol for 0.5h; Reflux;
In dichloromethane at 20℃; Inert atmosphere;
4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

Benzoyl isothiocyanate
532-55-8

Benzoyl isothiocyanate

N-((4-chlorobenzyl)carbamothioyl)benzamide
145383-00-2

N-((4-chlorobenzyl)carbamothioyl)benzamide

Conditions
ConditionsYield
100%
In diethyl ether at 0 - 20℃; for 2h;
In acetone at 20℃;
(Z)-3-ethoxy-3-[(2-nitrophenyl)hydrazono]propanoic acid ethyl ester
100032-83-5

(Z)-3-ethoxy-3-[(2-nitrophenyl)hydrazono]propanoic acid ethyl ester

4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

(Z)-N-(4-chlorobenzyl)-3-ethoxy-3-[(2-nitrophenyl)hydrazono]propanamide

(Z)-N-(4-chlorobenzyl)-3-ethoxy-3-[(2-nitrophenyl)hydrazono]propanamide

Conditions
ConditionsYield
at 50℃; for 1h; Inert atmosphere; Microwave irradiation;100%
2-chloro-6,7-dimethoxy-3H-quinazolin-4-one
27631-29-4

2-chloro-6,7-dimethoxy-3H-quinazolin-4-one

4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

2-chloro-N-(4-chlorobenzyl)-6,7-dimethoxyquinazolin-4-amine
864291-36-1

2-chloro-N-(4-chlorobenzyl)-6,7-dimethoxyquinazolin-4-amine

Conditions
ConditionsYield
Stage #1: 2-chloro-6,7-dimethoxy-3H-quinazolin-4-one; 4-chlorobenzylamine In N,N-dimethyl-formamide at 20℃; for 29h;
Stage #2: With sodium hydroxide In water
100%
4-fluoro-3-nitro-benzoic acid methyl ester
329-59-9

4-fluoro-3-nitro-benzoic acid methyl ester

4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

methyl 4-(4-chlorobenzylamine)-3-nitrobenzoic acid ester
174422-22-1

methyl 4-(4-chlorobenzylamine)-3-nitrobenzoic acid ester

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine In tetrahydrofuran at 20℃; for 5h;100%
With N-ethyl-N,N-diisopropylamine In tetrahydrofuran at 20℃; for 5h;100%
With N-ethyl-N,N-diisopropylamine In tetrahydrofuran for 17h; Reflux;
With N-ethyl-N,N-diisopropylamine In tetrahydrofuran at 50℃; for 16h;
With N-ethyl-N,N-diisopropylamine In N,N-dimethyl-formamide at 150℃; for 0.0833333h; Inert atmosphere;
carbon disulfide
75-15-0

carbon disulfide

4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

4-chlorobenzylisothiocyanate
3694-45-9

4-chlorobenzylisothiocyanate

Conditions
ConditionsYield
Stage #1: carbon disulfide; 4-chlorobenzylamine In diethyl ether for 0.25h; Cooling with ice;
Stage #2: With dicyclohexyl-carbodiimide In diethyl ether at 20℃; for 24h;
100%
Stage #1: carbon disulfide; 4-chlorobenzylamine With triethylamine In tetrahydrofuran at 0 - 20℃; for 1.75h;
Stage #2: With p-toluenesulfonyl chloride In tetrahydrofuran at 0 - 20℃; for 1h;
85%
With dmap; di-tert-butyl dicarbonate; triethylamine In ethanol at 0 - 20℃; for 1h;71%
4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

Veratric acid
93-07-2

Veratric acid

N-(4-chlorobenzyl)-3,4-dimethoxybenzamide

N-(4-chlorobenzyl)-3,4-dimethoxybenzamide

Conditions
ConditionsYield
Stage #1: Veratric acid With 1-hydroxy-pyrrolidine-2,5-dione In dichloromethane at -10 - 0℃; for 0.166667h;
Stage #2: With dicyclohexyl-carbodiimide In dichloromethane for 2h; Reflux;
Stage #3: 4-chlorobenzylamine With triethylamine In methanol; dichloromethane for 2h; Reflux;
99.5%
4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

4-Cyanochlorobenzene
623-03-0

4-Cyanochlorobenzene

Conditions
ConditionsYield
With oxygen In acetone at 20℃; for 3.2h; Electrochemical reaction;99%
With potassium hydroxide; nickel copper formate; (Bu4N)2S2O8 In 1,2-dichloro-ethane at 20℃; for 13h; Oxidation;95%
With [hydroxy(tosyloxy)iodo]benzene; ammonium acetate In water; acetonitrile at 80℃; for 3h;92%
4-chlorobenzaldehyde
104-88-1

4-chlorobenzaldehyde

4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

N-(4-chlorobenzylidene)-4-chlorobenzylamine
31264-06-9

N-(4-chlorobenzylidene)-4-chlorobenzylamine

Conditions
ConditionsYield
In dichloromethane at 40℃; under 760.051 Torr; for 1.5h; Molecular sieve;99%
With magnesium sulfate In dichloromethane for 3h; Reflux;95%
In toluene for 24h; Condensation; Heating;56%
4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

N-[(2-methoxycarbonylbenzene)sulfenyl]-1,2-benzisothiazolin-3-one
54856-20-1

N-[(2-methoxycarbonylbenzene)sulfenyl]-1,2-benzisothiazolin-3-one

2-(4-chlorobenzyl)benzo[d]isothiazol-2(3H)-one
4322-81-0

2-(4-chlorobenzyl)benzo[d]isothiazol-2(3H)-one

Conditions
ConditionsYield
In toluene at 100℃; for 3h;99%
(R)-3-((S)-4-benzyl-2-oxooxazolidine-3-carbonyl)hex-5-enoic acid
1201482-15-6

(R)-3-((S)-4-benzyl-2-oxooxazolidine-3-carbonyl)hex-5-enoic acid

4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

(R)-3-((S)-4-benzyl-2-oxooxazolidine-3-carbonyl)-N-(4-chlorobenzyl)hex-5-enamide
1201482-18-9

(R)-3-((S)-4-benzyl-2-oxooxazolidine-3-carbonyl)-N-(4-chlorobenzyl)hex-5-enamide

Conditions
ConditionsYield
Stage #1: (R)-3-((S)-4-benzyl-2-oxooxazolidine-3-carbonyl)hex-5-enoic acid With benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; N-ethyl-N,N-diisopropylamine In dichloromethane at 0℃; for 0.5h;
Stage #2: 4-chlorobenzylamine With dmap In dichloromethane
99%
methyl 2-chloro-2-cyclopropylideneacetate
82979-45-1

methyl 2-chloro-2-cyclopropylideneacetate

4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

methyl 2-(4-chlorobenzylamino)cyclobut-1-enecarboxylate
1239987-62-2

methyl 2-(4-chlorobenzylamino)cyclobut-1-enecarboxylate

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine; lithium iodide In N,N-dimethyl-formamide at 0 - 20℃; for 72h; Michael condensation; Inert atmosphere;99%
4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

ethyl 4,4,4-trifluoroacetoacetate
372-31-6

ethyl 4,4,4-trifluoroacetoacetate

ethyl 3-(4-chlorobenzyl)amino-4,4,4-trifluorobut-2-enoate
1384849-55-1

ethyl 3-(4-chlorobenzyl)amino-4,4,4-trifluorobut-2-enoate

Conditions
ConditionsYield
Stage #1: 4-chlorobenzylamine With acetic acid In chloroform at 20℃; for 0.0833333h;
Stage #2: ethyl 4,4,4-trifluoroacetoacetate In chloroform for 5h; Reflux;
99%
ethanol
64-17-5

ethanol

4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

C9H10ClN
1538636-70-2

C9H10ClN

Conditions
ConditionsYield
With potassium hydroxide at 30℃; for 3h; Green chemistry;99%
S-methylthiouronium iodide
4338-95-8

S-methylthiouronium iodide

4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

4-chlorobenzylguanidine hydroiodide

4-chlorobenzylguanidine hydroiodide

Conditions
ConditionsYield
In tetrahydrofuran at 25℃; for 12h;99%
carbon dioxide
124-38-9

carbon dioxide

4-chlorobenzylamine
104-86-9

4-chlorobenzylamine

N-(4-chlorobenzyl)formamide
86386-67-6

N-(4-chlorobenzyl)formamide

Conditions
ConditionsYield
With phenylsilane; C14H24N4Si*HI In benzene-d6 at 40℃; Inert atmosphere; Schlenk technique;99%
With Au-TiO2; hydrogen In N,N-dimethyl acetamide at 120℃; for 5h;94%
With tris(2-diphenylphosphinoethyl)phosphine; hydrogen; potassium carbonate; cobalt(II) perchlorate hexahydrate In ethanol at 140℃; under 45004.5 Torr; for 24h; Autoclave; Green chemistry;90%

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