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Henan Allgreen Chemical Co.,Ltd

TRIETHYLGALLIUM Basic information Product Name: TRIETHYLGALLIUM Synonyms: triethyl-galliu;GALLIUM TRIETHYL;TRIETHYLGALLIUM;Triethylgalliumcolorlessliq;Triethylgalli

TRIETHYLGALLIUM

Cas:1115-99-7

Min.Order:1 Gram

Negotiable

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Triethylgallium

Cas:1115-99-7

Min.Order:1

Negotiable

Type:Other

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COLORCOM LTD.

Colorcom is a global leader in industrial chemical manufacturing and is continuously innovating and transforming to exceed client expectations and industry standards. Colorcom prides itself on superior customer and technical focus, while focusing on

Triethylgallium

Cas:1115-99-7

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem’s R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis

Triethylgallium

Cas:1115-99-7

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. High quality and competitive price: 1) Standard: BP/USP/EP/ enterprise standard 2) All purity ≥99% 3) We are manufacturers and can provide high quality products at factory prices. 2. Fast and safe delivery 1) The package c

TRIETHYLGALLIUM.CAS: 1115-99-7

Cas:1115-99-7

Min.Order:1 Kilogram

FOB Price: $245.0 / 255.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Discount price CAS 1115-99-7 with best quality

Cas:1115-99-7

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

Gallium, triethyl-

Cas:1115-99-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Qingdao Beluga Import and Export Co., LTD

TRIETHYLGALLIUM CAS:1115-99-7 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermedia

TRIETHYLGALLIUM CAS:1115-99-7

Cas:1115-99-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Gallium, triethyl-

Cas:1115-99-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Changchun Artel lmport and Export trade company

Minimum Order Qty. 10 Gram Supply Ability 500 Kilograms/Month Storage store in cool, dry, ventilated place 20℃ Delivery Time 3 business days after payment Payment Term TT,western union,Paypal,MoneyGram Package 10g,20g,50g,100g,500g,1KGS,

Triethylgallium CAS NO.1115-99-7

Cas:1115-99-7

Min.Order:10 Gram

Negotiable

Type:Trading Company

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Gallium, triethyl-

Cas:1115-99-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Gallium, triethyl-

Cas:1115-99-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

Triethylgallium

Cas:1115-99-7

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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Hebei yanxi chemical co.,LTD.

Hebei Yanxi Chemical Co., Ltd. is a professional research, development and production of lead acetate benzene acetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low car

Triethylgallium

Cas:1115-99-7

Min.Order:1 Metric Ton

FOB Price: $1.0 / 2.0

Type:Trading Company

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Shanghai Minstar Chemical Co., Ltd

Product Name: TRIETHYLGALLIUM CAS: 1115-99-7 MF: C6H15Ga MW: 156.91 EINECS: 214-232-7 Product Categories: metal alkyl Mol File: 1115-99-7.mol TRIETHYLGALLIUM Structure TRIETHYLGALLIUM Chemical Properties Melting point -82,3&

TRIETHYLGALLIUM

Cas:1115-99-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

Hot Sales Triethylgallium CAS NO.1115-99-7

Cas:1115-99-7

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

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TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

TRIETHYLGALLIUM

Cas:1115-99-7

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

Hot Sales Triethylgallium CAS NO.1115-99-7

Cas:1115-99-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

Hot Sales Triethylgallium CAS NO.1115-99-7

Cas:1115-99-7

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

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Suzhou Health Chemicals Co., Ltd.

High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use

1115-99-7

Cas:1115-99-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

Hot Sales Triethylgallium CAS NO.1115-99-7

Cas:1115-99-7

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Hunan chemfish Pharmaceutical co.,Ltd.located in Lugu High-tech industral park ,Hunan province . with its own R&D center and more than 10000㎡manufacture plant . Chemfish owns 40 reactors from 1000L to 8000L. With complete auxiliary equipment as

TRIETHYLGALLIUM

Cas:1115-99-7

Min.Order:1 Gram

Negotiable

Type:Manufacturers

inquiry

Hangzhou Ocean Chemical Co., Ltd.

Ocean inorganic department is a professional supplier and exporter engaging in inorganic chemical materials and metal organic compounds. Over the past years, our company is committed to improving the product quality and developing new products, in

Triethylgallium

Cas:1115-99-7

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

Triethylgallium, elec. gr., 99.9998%

Cas:1115-99-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

Triethylgallium

Cas:1115-99-7

Min.Order:0

Negotiable

Type:Other

inquiry

Xi`an Eastling Biotech Co., Ltd.

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:Beijing or Guangzhou

TRIETHYLGALLIUM

Cas:1115-99-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Henan Tianfu Chemical Co., Ltd.

1.Our services:A.Supply sampleB.The packing also can be according the customers` requirmentC.Any inquiries will be replied within 24 hoursD.we provide Commerical Invoice, Packing List, Bill of loading, COA , Health certificate and Origin certificate.

Gallium, triethyl-

Cas:1115-99-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Xian Changyue Biological Technology Co., Ltd.

best seller Application:API

TRIETHYLGALLIUM

Cas:1115-99-7

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hangzhou Fandachem Co.,Ltd

FandaChem (, a China-based chemical company, specialize in exporting Triethylgallium / C6H15Ga cas 1115-99-7, Please contact us by email freely. Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG dru

Triethylgallium cas 1115-99-7

Cas:1115-99-7

Min.Order:1 Kilogram

Negotiable

Type:Other

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Gallium, triethyl-

Cas:1115-99-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

(CH2)3(P(C6H5)2Ga(C2H5)3)2

(CH2)3(P(C6H5)2Ga(C2H5)3)2

triethyl gallium
1115-99-7

triethyl gallium

Conditions
ConditionsYield
In neat (no solvent) metal complex decomposed at 120-143°C for 2-3 h;93%
gallium(III) trichloride

gallium(III) trichloride

triethylaluminum
97-93-8

triethylaluminum

triethyl gallium
1115-99-7

triethyl gallium

Conditions
ConditionsYield
Stage #1: triethylaluminum With tri-n-propylamine at 20℃;
Stage #2: gallium(III) trichloride at 100℃; for 2h; Neat (no solvent);
92%
In hexane at 70℃; Glovebox; Inert atmosphere;
(CH2)5(P(C6H5)2Ga(C2H5)3)2

(CH2)5(P(C6H5)2Ga(C2H5)3)2

triethyl gallium
1115-99-7

triethyl gallium

Conditions
ConditionsYield
In neat (no solvent) metal complex decomposed at 120-143°C for 2-3 h;92%
(triphenylphosphine)triethylgallium

(triphenylphosphine)triethylgallium

triethyl gallium
1115-99-7

triethyl gallium

Conditions
ConditionsYield
In neat (no solvent) metal complex decomposed at 120-125°C for 2-3 h;90%
gallium(III) trichloride

gallium(III) trichloride

sesquiethylaluminum chloride dimer

sesquiethylaluminum chloride dimer

A

triethyl gallium
1115-99-7

triethyl gallium

B

diethylgallium chloride
30914-08-0

diethylgallium chloride

Conditions
ConditionsYield
With potassium chloride; sodium chloride at 120 - 130℃; under 225.023 Torr; Pressure; Concentration; Temperature; Inert atmosphere;A 75.9%
B n/a
With potassium chloride; sodium chloride at 120℃; under 225.023 Torr; Inert atmosphere;A 75.9%
B 19%
(Et3Ga)2*diphos

(Et3Ga)2*diphos

triethyl gallium
1115-99-7

triethyl gallium

Conditions
ConditionsYield
In neat (no solvent) heated slowly under 1E-2 mmHg in a trap-to-trap distillation apparatus (receiver flask at -196 °C), liberation of Et3Ga started at 80 °C, the rate was more satisfactory at 120-125 °C;;66%
gallium
7440-55-3

gallium

magnesium
7439-95-4

magnesium

ethyl iodide
75-03-6

ethyl iodide

A

triethyl gallium
1115-99-7

triethyl gallium

B

magnesium chloride
7786-30-3

magnesium chloride

Conditions
ConditionsYield
In hexane inert condition; addn. of hexane to mixt. of Mg and Ga (vac.), addn. of hexane, dropwise addn. of EtI (boiling hexane); distillation;A 65%
B n/a
gallium
7440-55-3

gallium

iodine
7553-56-2

iodine

magnesium
7439-95-4

magnesium

ethyl iodide
75-03-6

ethyl iodide

A

triethyl gallium
1115-99-7

triethyl gallium

B

magnesium chloride
7786-30-3

magnesium chloride

Conditions
ConditionsYield
In neat (no solvent) inert condition; addn. of I2 to mixt. of Mg and Ga, heating in vac. (150°C), chilling, addn. of EtI (50 - 70°C, 1 h), heating (90 °C, 4 h); distillation;A 61%
B n/a
Ga(35),Mg(65) (X%)

Ga(35),Mg(65) (X%)

iodine
7553-56-2

iodine

ethyl iodide
75-03-6

ethyl iodide

A

triethyl gallium
1115-99-7

triethyl gallium

B

magnesium chloride
7786-30-3

magnesium chloride

Conditions
ConditionsYield
In neat (no solvent) inert condition; addn. of I2 to alloy Mg-Ga, heating in vac. (150 °C), chilling, addn. of EtI), heating (85°C, 4 h); distillation;A 57%
B n/a
Ga(35),Mg(65) (X%)

Ga(35),Mg(65) (X%)

ethyl iodide
75-03-6

ethyl iodide

triethyl gallium
1115-99-7

triethyl gallium

Conditions
ConditionsYield
With iodine; magnesium In neat (no solvent) byproducts: MgI2; inert atm.; heating (85°C); distn.;57%
1,3,5-tris(3,3-dimethyl-1-butynyl)benzene
851961-39-2

1,3,5-tris(3,3-dimethyl-1-butynyl)benzene

diethylgallium hydride
93481-56-2

diethylgallium hydride

A

(C2H5)3Ga3(C6H3(CCHC(CH3)3)3)2

(C2H5)3Ga3(C6H3(CCHC(CH3)3)3)2

B

triethyl gallium
1115-99-7

triethyl gallium

Conditions
ConditionsYield
In hexane under Ar; soln. of Et2GaH in n-hexane added to soln. of C6H3(C2CMe3)3 inn-hexane at room temp.; heated under reflux for 16 h; filtered; filtrate concd. under vac. at room temp.; ppt. collected;A 44%
B n/a
triethylaluminum
97-93-8

triethylaluminum

triethyl gallium
1115-99-7

triethyl gallium

Conditions
ConditionsYield
With gallium(III) trichloride; sodium chloride
diethylmercury
627-44-1

diethylmercury

triethyl gallium
1115-99-7

triethyl gallium

Conditions
ConditionsYield
With gallium at 165℃;
diethylmercury
627-44-1

diethylmercury

gallium

gallium

nitrogen

nitrogen

triethyl gallium
1115-99-7

triethyl gallium

Conditions
ConditionsYield
at 165℃;
triethyl borane
97-94-9

triethyl borane

triethyl gallium
1115-99-7

triethyl gallium

Conditions
ConditionsYield
With gallium(III) trichloride at 50 - 100℃; for 1 - 3h; Heating / reflux;
gallium
7440-55-3

gallium

ethyl iodide
75-03-6

ethyl iodide

triethyl gallium
1115-99-7

triethyl gallium

Conditions
ConditionsYield
With iodine; magnesium In hexane byproducts: MgI2; inert atm.; boiling; distn.;
With magnesium In neat (no solvent) byproducts: MgI2; inert atm.; heating (90°C, 4 h); distn.;
gallium
7440-55-3

gallium

diethylmercury
627-44-1

diethylmercury

triethyl gallium
1115-99-7

triethyl gallium

Et2Ga(NH[C6H2(2,4,6-t-Bu)3])
230310-74-4

Et2Ga(NH[C6H2(2,4,6-t-Bu)3])

A

(EtGaNH[C6H2(4,6-t-Bu)2CMe2CH2-2])2

(EtGaNH[C6H2(4,6-t-Bu)2CMe2CH2-2])2

B

triethyl gallium
1115-99-7

triethyl gallium

Conditions
ConditionsYield
In neat (no solvent) byproducts: H2N[C6H2(t-Bu)3]; Ar-atmosphere; heating at 65°C for 12 h; distillation off of GaEt3 (vac., room temp.), sublimation off of amine, recrystn. (pentane); elem. anal.;
ethyl bromide
74-96-4

ethyl bromide

Gallium trichloride
13450-90-3

Gallium trichloride

triethyl gallium
1115-99-7

triethyl gallium

Conditions
ConditionsYield
With Mg In diethyl ether (N2), EtBr added dropwise to mixt. of Mg and abs.Et2O, boiled under stirring for 2 h, treated dropwise with GaCl3 in Et2O, boiled under stirringfor 1 h; evapd. at 45°C, condensed into liquid N2, separated (refluxer), recruficated;
(C6H3-2,6-(C6H2-2,4,6-(CH3)3)2)2Sn(Et)GaEt2

(C6H3-2,6-(C6H2-2,4,6-(CH3)3)2)2Sn(Et)GaEt2

A

Sn(C6H3-2,6-(C6H2-2,4,6-(CH3)3)2)2
188685-27-0

Sn(C6H3-2,6-(C6H2-2,4,6-(CH3)3)2)2

B

triethyl gallium
1115-99-7

triethyl gallium

Conditions
ConditionsYield
In toluene at 20℃;
ethylmagnesium iodide
10467-10-4

ethylmagnesium iodide

gallium(III) iodide

gallium(III) iodide

triethyl gallium
1115-99-7

triethyl gallium

Conditions
ConditionsYield
In diethyl ether
ethyl bromide
74-96-4

ethyl bromide

gallium(III) fluoride

gallium(III) fluoride

triethyl gallium
1115-99-7

triethyl gallium

Conditions
ConditionsYield
Stage #1: ethyl bromide With magnesium
Stage #2: gallium(III) fluoride In diethyl ether for 48h; Reflux;
triisopropylbismuthine
85824-61-9

triisopropylbismuthine

triethyl gallium
1115-99-7

triethyl gallium

((CH3)2CH)3BiGa(C2H5)3

((CH3)2CH)3BiGa(C2H5)3

Conditions
ConditionsYield
In neat (no solvent) all manipulations under N2 atm.; mixed equimolar amts. of Ga and Bi compds. at ambient temp.; elem. anal.;100%
triethyl gallium
1115-99-7

triethyl gallium

tetraethyldistibine
4669-92-5

tetraethyldistibine

[Et4Sb2][GaEt3]2

[Et4Sb2][GaEt3]2

Conditions
ConditionsYield
In neat (no solvent) under N2 atm. react. Et3Ga and Et4Sb2; elem. anal.;100%
all-cis-1,3,5-triethynyl-1,3,5-trimethyl-1,3,5-trisilacyclohexane

all-cis-1,3,5-triethynyl-1,3,5-trimethyl-1,3,5-trisilacyclohexane

triethyl gallium
1115-99-7

triethyl gallium

1,3,5-tris(diethylgallanylethynyl)-1,3,5-trimethyl-1,3,5-trisilacyclohexane

1,3,5-tris(diethylgallanylethynyl)-1,3,5-trimethyl-1,3,5-trisilacyclohexane

Conditions
ConditionsYield
In neat (no solvent) at 20℃; for 24h; Temperature; Schlenk technique; Inert atmosphere;100%
tris[(ethynyl)dimethylsilyl](trimethylsilyl)methane

tris[(ethynyl)dimethylsilyl](trimethylsilyl)methane

triethyl gallium
1115-99-7

triethyl gallium

tris[(diethylgallanylethynyl)dimethylsilyl](trimethylsilyl)methane

tris[(diethylgallanylethynyl)dimethylsilyl](trimethylsilyl)methane

Conditions
ConditionsYield
In neat (no solvent) at 20℃; for 24h;100%
bis(1,5-cyclooctadiene)nickel (0)
1295-35-8

bis(1,5-cyclooctadiene)nickel (0)

triethylaluminum
97-93-8

triethylaluminum

triethyl gallium
1115-99-7

triethyl gallium

NiAl#dotGa

NiAl#dotGa

Conditions
ConditionsYield
With hydrogen In toluene High Pressure; a solns. mixed under inert atm., stirred at 130°C for 16 h under H2 pressure (5 MPa), solvent removed, ppt. dried (high vac.), hydrogenated for 24 h at 390°C; elem. anal.;99.7%
Gallium trichloride
13450-90-3

Gallium trichloride

triethyl gallium
1115-99-7

triethyl gallium

diethylgallium chloride
30914-08-0

diethylgallium chloride

Conditions
ConditionsYield
In pentane Ar-atmosphere; GaEt3:GaCl3 2:1 molar ratio; evapn. (0°C), distillation (60°C, ;99%
2/1 comproportionation of Et3Ga and CaCl3;
aluminum ethoxide
555-75-9

aluminum ethoxide

triethyl gallium
1115-99-7

triethyl gallium

toluene
108-88-3

toluene

[Al((μ-OEt)2GaEt2)3]

[Al((μ-OEt)2GaEt2)3]

Conditions
ConditionsYield
In toluene inert atmosphere; GaEt3 addn. to susp. of Al-ethoxide (3:2 molar ratio);reflux (4 h); cooling; filtration; filtrate evapn. (vac.); elem. anal.;98%
triethyl gallium
1115-99-7

triethyl gallium

(2-pyridylmethyl)(tert-butyldimethylsilyl)amine
338963-61-4

(2-pyridylmethyl)(tert-butyldimethylsilyl)amine

[(2-pyridylmethyl)(tert-butyldimethylsilyl)amino]triethylgallane

[(2-pyridylmethyl)(tert-butyldimethylsilyl)amino]triethylgallane

Conditions
ConditionsYield
In toluene All manipulations under Ar atm.; soln. of org. compd. added dropwise at 0°C to soln. of GaEt3, stirred at room temp. for 12 h; solvent removed. at room temp. in vac.; elem. anal.;98%
[(calix[4]arene monomethyl ether)nitridomolybdenum(VI)]-diethyl ether (1:1.5)

[(calix[4]arene monomethyl ether)nitridomolybdenum(VI)]-diethyl ether (1:1.5)

triethyl gallium
1115-99-7

triethyl gallium

[(calix[4]arene monomethyl ether)(triethyl(nitrido)gallium(III))molybdenum(VI)]
869318-27-4

[(calix[4]arene monomethyl ether)(triethyl(nitrido)gallium(III))molybdenum(VI)]

Conditions
ConditionsYield
In toluene N2, a soln. of Ga compd. (0.52 equiv.) slowly added to a soln. of Mo compd. (0.52 equiv.) at room temp., stirred for 1 h; solvent removed (vac.); elem. anal.;98%
1,3-bis-(dimethylamino)propan-2-ol
5966-51-8

1,3-bis-(dimethylamino)propan-2-ol

triethyl gallium
1115-99-7

triethyl gallium

[(C2H5)2Ga(OCH(CH2N(CH3)2)2)]2
811786-06-8

[(C2H5)2Ga(OCH(CH2N(CH3)2)2)]2

Conditions
ConditionsYield
In dichloromethane (N2); using Schlenk techniques; addn. dropwise of HOCH(CH2NMe2)2 (1 equiv.) to soln. of Et3Ga (1 equiv.) in CH2Cl2 at -78°C with stirringfor 0.5 h; slow warming to room temp., stirring for 5 h; removal of solvent in vac., redissolving in toluene and cooling to -20°C; crystn. for 2 days; elem. anal.;98%
In hexane (N2); using Schlenk techniques; treatment of HOCH(CH2NMe2)2 (1 equiv.) with Et3Ga (1 equiv.) in hexane at room temp.;
Gallium trichloride
13450-90-3

Gallium trichloride

triethyl gallium
1115-99-7

triethyl gallium

ethylgallium dichloride
6917-79-9

ethylgallium dichloride

Conditions
ConditionsYield
In pentane Ar-atmosphere; GaEt3:GaCl3 1:2 molar ratio; sublimation (room temp.); elem. anal.;97.3%
1-Methoxy-2-methylpropan-2-ol
3587-64-2

1-Methoxy-2-methylpropan-2-ol

triethyl gallium
1115-99-7

triethyl gallium

((C2H5)2Ga(OC(CH3)2CH2OCH3))2
811786-09-1

((C2H5)2Ga(OC(CH3)2CH2OCH3))2

Conditions
ConditionsYield
In toluene byproducts: ethane; under N2; ligand added dropwise to soln. of Et3Ga (molar ratio 1:1) in toluene at -78°C with stirring over 0.5 h; warmed slowly to room temp.; stirred for 24 h; solvent removed in vac.; redissolved in toluene; cooled to -20°C;crystd. for several d; elem. anal.;96%
triethyl gallium
1115-99-7

triethyl gallium

1-heptynyllithium
42017-07-2

1-heptynyllithium

lithium triethylheptynylgallate
80359-11-1

lithium triethylheptynylgallate

Conditions
ConditionsYield
In benzene Ar; heated at 60°C; solvent removed (vac., 1 Torr, 50°C); elem. anal.;95%
In neat (no solvent) Ar; heated at 50°C; elem. anal.;
N,N'-bis(o-hydroxybenzyl)-1,2-diamino-(4,5-dimethyl)benzene
163122-31-4

N,N'-bis(o-hydroxybenzyl)-1,2-diamino-(4,5-dimethyl)benzene

triethyl gallium
1115-99-7

triethyl gallium

((OC6H4CH2N)2C6H2(CH3)2)Ga(C2H5)(Ga(C2H5)2)2
166542-84-3

((OC6H4CH2N)2C6H2(CH3)2)Ga(C2H5)(Ga(C2H5)2)2

Conditions
ConditionsYield
In toluene byproducts: CH4; stirring (25°C, 15 min), refluxing (8 h); evapn. (vac.); elem. anal.;95%
triethyl gallium
1115-99-7

triethyl gallium

N,N′-bis(3,5-di-t-butylsalicylidene)-ethylenediamine

N,N′-bis(3,5-di-t-butylsalicylidene)-ethylenediamine

Ga2(C2H5)4((CH2NCHC6H2(C(CH3)3)2O)2)
207676-24-2

Ga2(C2H5)4((CH2NCHC6H2(C(CH3)3)2O)2)

Conditions
ConditionsYield
In toluene stirring (room temp., 24 h); evapn., recrystn. (toluene, -30°C);95%
1-methyl-2-N,N-dimethylaminoethanol
108-16-7

1-methyl-2-N,N-dimethylaminoethanol

triethyl gallium
1115-99-7

triethyl gallium

[(C2H5)2Ga(OCH(CH3)CH2N(CH3)2)]2
811786-08-0

[(C2H5)2Ga(OCH(CH3)CH2N(CH3)2)]2

Conditions
ConditionsYield
In dichloromethane (N2); using Schlenk techniques; addn. dropwise of HOCH(CH3)CH2NMe2 (1 equiv.) to soln. of Et3Ga (1 equiv.) in CH2Cl2 at -78°C with stirring for 0.5 h; slow warming to room temp., stirring for 5 h; removal of solvent in vac., redissolving in toluene and cooling to -20°C; as solid; elem. anal.;95%
In hexane (N2); using Schlenk techniques; treatment of HOCH(CH3)CH2NMe2 (1 equiv.)with Et3Ga (1 equiv.) in hexane at room temp.;
2-(N,N-dimethylamino)ethanol
108-01-0

2-(N,N-dimethylamino)ethanol

triethyl gallium
1115-99-7

triethyl gallium

((C2H5)2Ga(OCH2CH2N(CH3)2))2
552851-83-9

((C2H5)2Ga(OCH2CH2N(CH3)2))2

Conditions
ConditionsYield
In toluene byproducts: ethane; under N2; ligand added dropwise to soln. of Et3Ga (molar ratio 1:1) in toluene at -78°C with stirring over 0.5 h; warmed slowly to room temp.; stirred for 24 h; solvent removed in vac.; crystd. by standing at room temp. for several d; elem. anal.;95%
1,1,1,5,5,5-hexafluoroacetylacetone
1522-22-1

1,1,1,5,5,5-hexafluoroacetylacetone

triethyl gallium
1115-99-7

triethyl gallium

Et2Ga(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato)
203209-46-5

Et2Ga(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato)

Conditions
ConditionsYield
In pentane byproducts: CH4; Ar-atmosphere; stirring (-196°C to room temp., room temp., 12 h); distg. (vac., -20°C), fractional distg.; elem. anal.;94.9%
tris(trimethylsilyl)bismuthane
81183-20-2

tris(trimethylsilyl)bismuthane

triethyl gallium
1115-99-7

triethyl gallium

(C2H5)3GaBi(Si(CH3)3)3

(C2H5)3GaBi(Si(CH3)3)3

Conditions
ConditionsYield
In neat (no solvent) all manipulations under N2 atm.; mixed equimolar amts. of Ga and Bi compds. at ambient temp.; dissolved in pentane and storred at -30°C., elem. anal.;94%
triethyl gallium
1115-99-7

triethyl gallium

(Di-iso-propylsilandiyl)diphosphan
89332-24-1

(Di-iso-propylsilandiyl)diphosphan

[[CH(CH3)2]2Si(PHGa(C2H5)2)2]2

[[CH(CH3)2]2Si(PHGa(C2H5)2)2]2

Conditions
ConditionsYield
In n-heptane byproducts: ethane; (N2), metal complex added to a stirred soln. of ligand in heptane, reacted for 20 min; warmed, crystd. for 3 days at 6°C, elem. anal.;94%
triethyl gallium
1115-99-7

triethyl gallium

(2-pyridylmethyl)(tert-butyldimethylsilyl)amine
338963-61-4

(2-pyridylmethyl)(tert-butyldimethylsilyl)amine

[(2-pyridylmethyl)di(tert-butylsilyl)amido]diethylgallane

[(2-pyridylmethyl)di(tert-butylsilyl)amido]diethylgallane

Conditions
ConditionsYield
In neat (no solvent) byproducts: C2H6; All manipulations under Ar atm.; mixt. of org. compd. and GaEt3 heated at 120°C for 20 h; volatiles removed in vac.; elem. anal.;94%
(2-pyridylmethyl)di(tert-butylsilyl)amine
852471-37-5

(2-pyridylmethyl)di(tert-butylsilyl)amine

triethyl gallium
1115-99-7

triethyl gallium

[(2-pyridylmethyl)di(tert-butylsilyl)amino]triethylgallane

[(2-pyridylmethyl)di(tert-butylsilyl)amino]triethylgallane

Conditions
ConditionsYield
In tetrahydrofuran All manipulations under Ar atm.; GaEt3 added dropwise at 0°C to soln. of org. compd., stirred at room temp. for 12 h; solvent removed at room temp. in vac.; elem. anal.;94%
[Li(thf)Sn(2-C5H3N-5-Me)3]

[Li(thf)Sn(2-C5H3N-5-Me)3]

triethyl gallium
1115-99-7

triethyl gallium

[{LiSn(2-C5H3N-5-Me)3}GaEt3]n

[{LiSn(2-C5H3N-5-Me)3}GaEt3]n

Conditions
ConditionsYield
In toluene at 20℃; Inert atmosphere;94%
[LiPb(2-py6OtBu)3]

[LiPb(2-py6OtBu)3]

triethyl gallium
1115-99-7

triethyl gallium

[LiGaEt2(2-py6OtBu)2]2

[LiGaEt2(2-py6OtBu)2]2

Conditions
ConditionsYield
In toluene at 20℃; Schlenk technique; Inert atmosphere;94%
[Ga(C5H4CH3)3]

[Ga(C5H4CH3)3]

triethyl gallium
1115-99-7

triethyl gallium

[(C2H5)2Ga(C5H4CH3)]

[(C2H5)2Ga(C5H4CH3)]

Conditions
ConditionsYield
In pentane (Ar); standard vac. line technique; soln. of GaEt3 and Ga(C5H4Me)3 in pentane stirred overnight at room temp.; pentane was removed by vac. distn.; residue was vac. distd.; elem. anal.;93.1%
N,N'-bis(2-hydroxybenzyl)ethylenediamine
18653-98-0

N,N'-bis(2-hydroxybenzyl)ethylenediamine

triethyl gallium
1115-99-7

triethyl gallium

((OC6H4CH2NCH2)2)Ga(C2H5)(Ga(C2H5)2)2

((OC6H4CH2NCH2)2)Ga(C2H5)(Ga(C2H5)2)2

Conditions
ConditionsYield
In toluene byproducts: CH4; stirring (25°C, 15 min), refluxing (8 h); evapn. (vac.); elem. anal.;93%
N,N'-bis(2-hydroxybenzyl)-1,3-diaminopropane
2287-28-7

N,N'-bis(2-hydroxybenzyl)-1,3-diaminopropane

triethyl gallium
1115-99-7

triethyl gallium

((OC6H4CH2NCH2)2CH2)Ga(C2H5)(Ga(C2H5)2)2
166542-82-1

((OC6H4CH2NCH2)2CH2)Ga(C2H5)(Ga(C2H5)2)2

Conditions
ConditionsYield
In toluene byproducts: CH4; stirring (25°C, 15 min), refluxing (8 h); evapn. (vac.); elem. anal.;93%
triethyl gallium
1115-99-7

triethyl gallium

(2-pyridylmethyl)(tert-butyldimethylsilyl)amine
338963-61-4

(2-pyridylmethyl)(tert-butyldimethylsilyl)amine

[(2-pyridylmethyl)(tert-butyldimethylsilyl)amido]diethylgallane

[(2-pyridylmethyl)(tert-butyldimethylsilyl)amido]diethylgallane

Conditions
ConditionsYield
In toluene byproducts: C2H6; All manipulations under Ar atm.; mixt. of org. compd. and GaEt3 in toluene refluxed for 20 h; volatiles removed at room temp. in vac.; elem. anal.;93%
2-methoxy-ethanol
109-86-4

2-methoxy-ethanol

triethyl gallium
1115-99-7

triethyl gallium

[(C2H5)2Ga(OCH2CH2OCH3)]2
811786-07-9

[(C2H5)2Ga(OCH2CH2OCH3)]2

Conditions
ConditionsYield
In dichloromethane (N2); using Schlenk techniques; addn. dropwise of HOCH2CH2OMe (1 equiv.)to soln. of Et3Ga (1 equiv.) in CH2Cl2 at -78°C with stirring fo r 0.5 h; slow warming to room temp., stirring for 5 h; removal of solvent in vac., redissolving in toluene and cooling to -20°C; as oil;93%
In hexane (N2); using Schlenk techniques; treatment of HOCH2CH2OMe (1 equiv.) withEt3Ga (1 equiv.) in hexane at room temp.; as oil;
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