Items Standard Result Appearance Yellow transparent oily liquid Conform Identification P
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inquiryProduct description: Product name 4-Methoxyphenylacetone CAS number 122-84-9 Assay ≥99% Appearance Yellowish liquid Capacity 100mt/year Application Pharmaceutical intermediat
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inquiryAppearance:pale yellow liquid Storage:room temperature Package:200kg/drum Application:A volatile compound released by flowering plants to attractant insects Transportation:Express/Sea/Air Port:Shanghai
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Cas:122-84-9
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inquiryProduct name: 4-Methoxyphenylacetone CAS No.:122-84-9 Molecule Formula:C10H12O2 Molecule Weight:164.20 Purity: 98.0% Package: 25kg/drum Description:Light yellow liquid Manufacture Standards:Enterprise Standard TESTING ITEMS
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4-Methoxyphenylacetone Basic information Product Name: 4-Methoxyphenylacetone Synonyms: 4-ANISYL ACETONE;4-METHOXYBENZYL METHYL KETONE;4-METHOXYPHENYLACETONE;4-ACETONYLANISOLE;1-(P-METHOXYPHENYL)-2-PROPANONE;3-(4-METHOXYPHENYL)-2-PROPANONE;1-(
Cas:122-84-9
Min.Order:1 Gram
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inquiryfactory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B
Cas:122-84-9
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inquiryConditions | Yield |
---|---|
With bis[chloro(1,2,3-trihapto-allylbenzene)palladium(II)]; N-[2-(di(1-adamantyl)phosphino)phenyl]morpholine; caesium carbonate at 90℃; for 16h; Inert atmosphere; sealed vial; | 98% |
With (R)-1-[(SP)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine; [Pd(π-cinnamyl)Cl]2; caesium carbonate at 25℃; for 48h; Sealed tube; Inert atmosphere; Glovebox; | 76% |
1-bromo-2-(4-methoxyphenyl)propan-2-ol
4-methoxybenzyl methyl ketone
Conditions | Yield |
---|---|
With diethylzinc In dichloromethane at 20℃; for 2h; | 95% |
Conditions | Yield |
---|---|
With [hydroxy(tosyloxy)iodo]benzene In methanol at 20℃; for 0.333333h; | 92% |
With oxone; sodium iodide In water; acetonitrile at 20℃; for 15h; Green chemistry; | 85% |
Stage #1: 1-isopropenyl-4-methoxybenzene With 2-Iodo-5-methylbenzenesulfonic acid In tert-butyl methyl ether; water; isopropyl alcohol at 22℃; for 0.0833333h; Inert atmosphere; Stage #2: With Oxone In tert-butyl methyl ether; water; isopropyl alcohol at 22℃; for 4h; Inert atmosphere; Further stages; | 68% |
With iodine; mercury(II) oxide Man laesst auf das entstandene Jodhydrin AgNO3 oder HgO einwirken; |
Conditions | Yield |
---|---|
With iron(III) chloride; palladium(II) trifluoroacetate; sodium 2,2,2-trifluoroacetate In water; acetonitrile at 30℃; Temperature; Wacker-Tsuji Olefin Oxidation; Inert atmosphere; Darkness; | 92% |
Multi-step reaction with 2 steps 1: yellow HgO; absolute methanol; iodine 2: alcoholic potash / Durch Einw. von 20prozentiger Schwefelsaeure das Reaktionsprodukt View Scheme | |
Multi-step reaction with 2 steps 1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 3 h / 0 - 20 °C / Inert atmosphere; Schlenk technique 2: Rh((1,8-bis(imidazolin-2-ylidene)-3,6-di(tert-butyl)carbazolide)homoallyl) / benzene-d6 / 2 h / 20 °C / Inert atmosphere; Schlenk technique View Scheme |
4-methoxybenzyl methyl ketone
Conditions | Yield |
---|---|
With SO3H silica gel In methanol at 50℃; for 2h; Inert atmosphere; | 92% |
1-(2-Iodo-1-methoxy-1-methyl-ethyl)-4-methoxy-benzene
4-methoxybenzyl methyl ketone
Conditions | Yield |
---|---|
With 3-chloro-benzenecarboperoxoic acid In dichloromethane at 0℃; for 1h; | 90% |
1-(4-Methoxy-phenyl)-propan-2-one O-methyl-oxime
4-methoxybenzyl methyl ketone
Conditions | Yield |
---|---|
With hydrogenchloride In methanol at 65℃; for 10h; | 90% |
Conditions | Yield |
---|---|
With copper(l) iodide; potassium phosphate tribasic trihydrate In dimethyl sulfoxide at 90℃; for 20h; Inert atmosphere; | 89% |
1-(4-methoxyphenyl)-2-methyl-3-phenylpropan-2-ol
A
4-methoxybenzyl methyl ketone
B
1-phenyl-acetone
Conditions | Yield |
---|---|
With 2,3,5-trimethyl-pyridine; [Ir(2-(2,4-difluorophenyl)-5-(trifluoromethyl)pyridine)2(5,5'-bis(trifluoromethyl)-2,2'-bipyridyl)](PF6); thiophenol In dichloromethane at 20℃; Sealed tube; Inert atmosphere; Irradiation; | A 5% B 89% |
Conditions | Yield |
---|---|
With potassium phosphate; 2-(2,6-dimethoxyphenyl)-1-methyl-3-(diphenylphosphino)-1H-indole; palladium diacetate at 90℃; for 18h; Inert atmosphere; Schlenk technique; | 88% |
With bis[chloro(1,2,3-trihapto-allylbenzene)palladium(II)]; 2-methoxy-6-(N-methyl-N-phenyl-amino)phenyl(dicyclohexyl)phosphine; caesium carbonate at 90℃; for 24h; Kinetics; Reagent/catalyst; Inert atmosphere; Schlenk technique; Sealed tube; | 84% |
With 2-methoxy-6-(N-methyl-N-phenyl-amino)phenyl(dicyclohexyl)phosphine; palladium cinnamyl chloride; caesium carbonate at 90℃; for 12h; Schlenk technique; Inert atmosphere; | 84% |
1-methoxy-4-(2-nitro-1(Z)-propenyl)benzene
4-methoxybenzyl methyl ketone
Conditions | Yield |
---|---|
With formaldehyd In 1,4-dioxane; perchloric acid; dichloromethane for 0.333333h; Ambient temperature; | 87% |
With hydrogenchloride; iron In methanol; water for 0.5h; Heating; | 80% |
With aluminium; nickel dichloride In tetrahydrofuran Substitution; | 79% |
methyl magnesium iodide
2-chloro-1-(4-methoxyphenyl)ethanone
A
1-(4-methoxyphenyl)-2-methylpropan-2-ol
B
4-methoxybenzyl methyl ketone
Conditions | Yield |
---|---|
In tetrahydrofuran for 16h; Ambient temperature; | A 85% B 10% |
In tetrahydrofuran at 20℃; for 16h; | A 85% B 10% |
(E)-3-(4-methoxyphenyl)-2-methylacrylic acid
4-methoxybenzyl methyl ketone
Conditions | Yield |
---|---|
With diphenyl phosphoryl azide; triethylamine In toluene at 25 - 110℃; for 2h; | 85% |
Multi-step reaction with 2 steps 1: thionyl chloride / tetrachloromethane / 0.5 h / 35 °C 2: sodium azide; tetrabutylammomium bromide; water / tetrachloromethane / 1.5 h / Reflux View Scheme |
4-methoxyphenyl 1H-imidazole-1-sulfonate
acetone
4-methoxybenzyl methyl ketone
Conditions | Yield |
---|---|
With palladium diacetate; caesium carbonate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In 1,4-dioxane at 80℃; for 16h; Inert atmosphere; chemoselective reaction; | 84% |
With 4-fluorophenyl tosylate; palladium diacetate; caesium carbonate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In 1,4-dioxane at 80℃; for 10h; Inert atmosphere; | 84% |
2-nitro-1-(4-methoxylphenyl) propane
4-methoxybenzyl methyl ketone
Conditions | Yield |
---|---|
With hydrogenchloride; iron In methanol; water for 0.5h; Heating; | 82% |
With chloro-trimethyl-silane; 1,8-diazabicyclo[5.4.0]undec-7-ene; 3-chloro-benzenecarboperoxoic acid 1.) dichloromethane, 30 min, 0 degC; 2.) dichloromethane, 30 min, room temperature; Yield given. Multistep reaction; |
A
1-chloro-2-hydroxy-1-(4'-methoxyphenyl)propane
B
4-methoxybenzyl methyl ketone
Conditions | Yield |
---|---|
With titanium tetrachloride In dichloromethane at 0℃; for 0.5h; Mukaiyama reaction; Inert atmosphere; | A 16% B 80% |
With titanium tetrachloride In dichloromethane at -30℃; for 0.5h; Mukaiyama reaction; Inert atmosphere; | A 66% B 30% |
methanol
1-methoxy-4-(2-nitro-1(Z)-propenyl)benzene
A
4-methoxybenzyl methyl ketone
Conditions | Yield |
---|---|
With indium; chloro-trimethyl-silane at 25℃; for 5.5h; Reduction; Addition; | A n/a B 78% |
1-methoxy-4-((E)-2-nitroprop-1-enyl)benzene
4-methoxybenzyl methyl ketone
Conditions | Yield |
---|---|
With trifluoroacetic acid; zinc In N,N-dimethyl-formamide for 0.25h; | 75% |
Conditions | Yield |
---|---|
With potassium phosphate; C37H56ClPPd at 50℃; for 21h; Sealed tube; Inert atmosphere; | 70% |
With (R)-1-[(SP)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine; [Pd(π-cinnamyl)Cl]2; caesium carbonate at 25℃; for 48h; Sealed tube; Inert atmosphere; Glovebox; | 64% |
4-methoxybenzyl methyl ketone
Conditions | Yield |
---|---|
In dichloromethane at 20℃; Inert atmosphere; | 69% |
1-bromo-4-methoxy-benzene
sodium acetylacetonate
A
4-methoxybenzyl methyl ketone
B
1-(4-methoxyphenyl)pentane-2,4-dione
Conditions | Yield |
---|---|
copper(l) iodide In N,N-dimethyl-formamide at 100 - 120℃; for 23h; | A 67% B 23% |
copper(l) iodide In N,N-dimethyl-formamide at 100 - 120℃; for 23h; | A 67% B 26% |
1-(4-methoxybenzyl)-2,4,6-triphenylpyridin-1-ium tetrafluoroborate salt
acetyl chloride
4-methoxybenzyl methyl ketone
Conditions | Yield |
---|---|
With manganese; (2,2'-bipyridine)nickel(II) dibromide In N,N-dimethyl acetamide; acetonitrile at 20℃; for 6h; Inert atmosphere; Schlenk technique; | 67% |
4-(2-nitro-propenyl)-anisole
A
4-methoxybenzyl methyl ketone
B
4-methoxyphenylacetone oxime
Conditions | Yield |
---|---|
With sulfuric acid; toluene-4-sulfonic acid In methanol at 0 - 5℃; ceramic diaphragm, carbon-rod anode, platinum cathode, 4.5 F/mol, 0.1A, cathode potential -1.45 to -1.65V vs. SCE; | A 6% B 65% |
Conditions | Yield |
---|---|
With (2,2'-bipyridine)nickel(II) dibromide; tetrabutylammonium tetrafluoroborate Ambient temperature; Al rod/nickel-sponge; | 65% |
With (2,2'-bipyridine)nickel(II) dibromide; tetrabutylammonium tetrafluoroborate In N,N-dimethyl-formamide Ambient temperature; i = 250 mA, nickel-sponge cathode; | 65% |
A
1-chloro-2-hydroxy-1-(4'-methoxyphenyl)propane
B
4-methoxybenzyl methyl ketone
C
2-hydroxy-1-methoxy-1-(4'-methoxyphenyl)propane
Conditions | Yield |
---|---|
With titanium tetrachloride In dichloromethane at -78℃; for 0.5h; Mukaiyama reaction; Inert atmosphere; | A 64% B 16% C 16% |
2-(4-methoxyphenyl)-3-methyloxirane
4-methoxybenzyl methyl ketone
Conditions | Yield |
---|---|
With clay; potassium bromide In benzene for 0.25h; Ambient temperature; | 61% |
4-methoxybenzyl methyl ketone
Conditions | Yield |
---|---|
Stage #1: N-(1-Phenylethyl)-2-methyleneaziridine; CH3OC6H4MgX With copper(l) iodide; boron trifluoride diethyl etherate In tetrahydrofuran at -30 - 0℃; Ring cleavage; Stage #2: In tetrahydrofuran Hydrolysis; Further stages.; | 60% |
4-methoxybenzyl methyl ketone
2-methoxy-5-(2-oxopropyl)benzenesulfonyl chloride
Conditions | Yield |
---|---|
With chlorosulfonic acid at 0 - 20℃; for 2h; | 100% |
With chlorosulfonic acid | 40% |
With chlorosulfonic acid for 2h; Ambient temperature; | 11.4 g |
4-methoxybenzyl methyl ketone
2-Pentanone
A
(R)‐2‐aminopentane
B
(R)-(-)-p-methoxyamphetamine
Conditions | Yield |
---|---|
With Candida boidinii formate dehydrogenase; pyridoxal 5'-phosphate; Aspergillus terreus ω-trans aminase; Lysinibacillus fusiformis leucine dehydrogenase; ammonium formate; nicotinamide adenine dinucleotide In aq. buffer at 30℃; for 24h; pH=8.8; Catalytic behavior; Green chemistry; Enzymatic reaction; | A 99.7% B 99.4% |
4-methoxybenzyl methyl ketone
toluene-4-sulfonic acid hydrazide
N'-(1-(4-methoxyphenyl)propan-2-ylidene)-4-methylbenzenesulfonohydrazide
Conditions | Yield |
---|---|
In methanol at 20℃; Inert atmosphere; | 99.5% |
In methanol at 70℃; Inert atmosphere; | |
In methanol Reflux; |
4-methoxybenzyl methyl ketone
1-(4-methoxyphenyl)propan-2-ol
Conditions | Yield |
---|---|
With sodium tetrahydroborate In methanol at 20℃; for 0.166667h; Inert atmosphere; Schlenk technique; | 99% |
With methanol; sodium tetrahydroborate at 0℃; for 2h; Inert atmosphere; | 99% |
With IrH2Cl[(iPr2PC2H4)2NH]; potassium tert-butylate; hydrogen In methanol at 20℃; under 7600.51 Torr; for 1h; | 98% |
4-methoxybenzyl methyl ketone
benzylamine
[2-(4-methoxyphenyl)-1-methylethyl](phenylmethyl)amine
Conditions | Yield |
---|---|
With hydrogen; platinum on activated charcoal In ethanol | 99% |
With platinum on carbon; hydrogen In methanol at 20℃; under 2327.23 - 2844.39 Torr; Inert atmosphere; | 99% |
With sodium tris(acetoxy)borohydride; acetic acid In dichloromethane at 0 - 20℃; | 97% |
Conditions | Yield |
---|---|
With 4-methylmorpholine N-oxide In dichloromethane at 20℃; for 5h; | 99% |
With cesium fluoride In acetonitrile at 20℃; for 0.8h; | 97% |
With montmorillonite K10 In acetone at 20℃; for 0.166667h; Catalytic behavior; Green chemistry; | 96% |
4-methoxybenzyl methyl ketone
(R)-(-)-p-methoxyamphetamine
Conditions | Yield |
---|---|
With glucose dehydrogenase; D-Alanine; D-glucose; ω-transaminase ATA-117; pyridoxal 5'-phosphate; nicotinamide adenine dinucleotide; lactate dehydrogenase In dimethyl sulfoxide at 30℃; for 24h; pH=7; aq. phosphate buffer; Enzymatic reaction; optical yield given as %ee; stereoselective reaction; | 99% |
With pyridoxal 5'-phosphate; amine transaminase TA-P2-B01; isopropylamine In aq. phosphate buffer at 30℃; for 24h; pH=7.5; Reagent/catalyst; Enzymatic reaction; enantioselective reaction; | 86% |
With Cb-FDH formate dehydrogenase (variant) from Candida boidinii; Rs-PhAmDH amine dehydrogenase variant from the phenylalanine dehydrogenase from Rhodoccoccus species; NAD; ammonium formate In water at 30℃; for 24h; pH=8.5; Reagent/catalyst; Enzymatic reaction; stereoselective reaction; | 82% |
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide at 100℃; for 2h; Microwave irradiation; | 99% |
4-methoxybenzyl methyl ketone
malononitrile
2-(1-(4-methoxyphenyl)propan-2-ylidene)malononitrile
Conditions | Yield |
---|---|
With ammonium acetate; acetic acid In benzene at 120℃; Knoevenagel Condensation; Dean-Stark; | 98% |
With ammonium acetate In acetic acid; benzene |
4-methoxybenzyl methyl ketone
(S)-(+)-1-(4-methoxyphenyl)propan-2-ol
Conditions | Yield |
---|---|
With Rhodococcus ruber alcohol dehydrogenase; NAD; isopropyl alcohol; magnesium chloride In aq. phosphate buffer at 30℃; pH=7; Catalytic behavior; Reagent/catalyst; Time; Inert atmosphere; Schlenk technique; Enzymatic reaction; enantioselective reaction; | 98% |
With D-glucose; Zygosaccharomyces rouxii cells In water at 28℃; for 1h; | 82% |
With bakers' yeast at 30℃; for 120h; Product distribution; further aryl ketones investigated; | 80% |
4-methoxybenzyl methyl ketone
(S)-2-(4-methoxy-phenyl)-1-methyl-ethylamine
Conditions | Yield |
---|---|
With L-alanin; Bacillus subtilis L-alanine dehydrogenase; NAD-specific formate dehydrogenase; ω-transaminase ATA-113; pyridoxal 5'-phosphate; ammonium formate; nicotiamide adenine dinucleotide In dimethyl sulfoxide at 30℃; for 24h; pH=7; aq. phosphate buffer; optical yield given as %ee; enantioselective reaction; | 98% |
With pyridoxal 5'-phosphate; amine transaminase TA-P1-G05; isopropylamine In aq. phosphate buffer at 30℃; for 24h; pH=7.5; Reagent/catalyst; Enzymatic reaction; enantioselective reaction; | 84% |
Multi-step reaction with 2 steps 1: 79 percent / ammonium formate / Pd/C / methanol / 20 °C 2: Candida antarctica lipase B / 22 h / 28 °C View Scheme |
4-methoxybenzyl methyl ketone
methylmagnesium bromide
1-(4-methoxyphenyl)-2-methylpropan-2-ol
Conditions | Yield |
---|---|
Stage #1: 4-methoxybenzyl methyl ketone; methylmagnesium bromide In diethyl ether; benzene at 100℃; for 3h; Stage #2: With water; ammonium chloride In diethyl ether; benzene at 0℃; | 98% |
In tetrahydrofuran at 0 - 20℃; Inert atmosphere; Schlenk technique; |
4-methoxybenzyl methyl ketone
2-chloro-1,2-bis(4-methylphenyl)ethanone
3-(4-methoxyphenyl)-1,2-di-p-tolylpentane-1,4-dione
Conditions | Yield |
---|---|
Stage #1: 4-methoxybenzyl methyl ketone With sodium hexamethyldisilazane In tetrahydrofuran at 0℃; Inert atmosphere; Stage #2: With zinc(II) chloride In tetrahydrofuran for 0.166667h; Inert atmosphere; Stage #3: 2-chloro-1,2-bis(4-methylphenyl)ethanone With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride In tetrahydrofuran at 45℃; Inert atmosphere; optical yield given as %de; | 98% |
Conditions | Yield |
---|---|
With aluminum (III) chloride; sodium nitrite In N,N-dimethyl-formamide at 90℃; for 4h; Schlenk technique; | 98% |
With oxygen; copper diacetate; ammonium carbonate; tetra-(n-butyl)ammonium iodide In dimethyl sulfoxide at 120℃; for 5h; Schlenk technique; | 59% |
2-(2-bromophenyl)-1,3-dioxolan
4-methoxybenzyl methyl ketone
Conditions | Yield |
---|---|
With dichloro[1,1'-bis(di-t-butylphosphino)ferrocene]palladium(II); caesium carbonate at 70℃; for 18h; Inert atmosphere; | 98% |
4-methoxybenzyl methyl ketone
tert-butyldimethylsilyl chloride
tert-Butyl-[(Z)-2-(4-methoxy-phenyl)-1-methyl-vinyloxy]-dimethyl-silane
Conditions | Yield |
---|---|
With sodium hydride In tetrahydrofuran Ambient temperature; | 97% |
4-methoxybenzyl methyl ketone
(R)-1-phenyl-ethyl-amine
(R)-1-(4-methoxyphenyl)-N-((R)-1-phenylethyl)propan-2-amine
Conditions | Yield |
---|---|
With hydrogen; titanium(IV)isopropoxide In 1,2-dichloro-ethane at 20 - 45℃; under 7600.51 Torr; for 1.25h; Reagent/catalyst; Autoclave; | 96% |
(i) benzene, (ii) H2, Raney-Ni, EtOH; Multistep reaction; | |
With hydrogen; platinum(IV) oxide In methanol at 50℃; under 1500.15 Torr; for 12h; | |
With platinum on carbon; hydrogen In methanol at 60℃; for 24h; | |
Multi-step reaction with 2 steps 1: hydrogen; platinum on activated charcoal 2: L-Tartaric acid / ethanol View Scheme |
Conditions | Yield |
---|---|
Stage #1: 4-methoxybenzyl methyl ketone With (R,R)-N,N′-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminum(III) chloride; (tert-Butoxycarbonylmethylene)triphenylphosphorane; Triphenylphosphine oxide In dichloromethane at -40℃; for 0.5h; Inert atmosphere; Stage #2: trimethylsilyl cyanide In dichloromethane at -40℃; for 10h; Inert atmosphere; | 96% |
Conditions | Yield |
---|---|
With 1,4-diaza-bicyclo[2.2.2]octane In water at 20℃; for 24h; Reagent/catalyst; Aldol Condensation; Green chemistry; diastereoselective reaction; | 95% |
Conditions | Yield |
---|---|
Stage #1: 4-methoxybenzyl methyl ketone; (R)-1-phenyl-ethyl-amine With 2 % platinum on carbon; hydrogen In methanol for 3h; Stage #2: With hydrogenchloride In acetone for 2h; pH=2 - 3; Reagent/catalyst; Solvent; | 95% |
4-methoxybenzyl methyl ketone
potassium cyanide
5-(4-methoxybenzyl)-5-methylimidazolidine-2,4-dione
Conditions | Yield |
---|---|
With ammonium carbonate In ethanol; water at 80℃; for 18h; | 93% |
5-fluoro-1H-indole-2,3-dione
4-methoxybenzyl methyl ketone
6-fluoro-3-(4-methoxyphenyl)-2-methylquinoline-4-carboxylic acid
Conditions | Yield |
---|---|
With potassium hydroxide In ethanol at 80℃; for 48h; Pfitzinger Quinoline Synthesis; | 93% |
With potassium hydroxide In ethanol for 48h; Pfitzinger Quinoline Synthesis; Reflux; | 93% |
Conditions | Yield |
---|---|
Stage #1: 4-methoxybenzyl methyl ketone With sodium hydride In N,N-dimethyl-formamide; mineral oil at -20℃; for 0.5h; Inert atmosphere; Stage #2: 2-methyl-3-bromo-1-propene In N,N-dimethyl-formamide; mineral oil at -20 - 20℃; for 0.5h; Inert atmosphere; | 93% |
Conditions | Yield |
---|---|
Stage #1: 4-methoxybenzyl methyl ketone; Benzhydrylamine With titanium(IV) isopropylate; trifluoroacetic acid In dichloromethane for 2h; Molecular sieve; Stage #2: With hydrogen under 38002.6 Torr; for 14h; | 93% |
4-methoxybenzyl methyl ketone
methylmagnesium chloride
1-(4-methoxyphenyl)-2-methylpropan-2-ol
Conditions | Yield |
---|---|
In tetrahydrofuran; toluene at 8 - 12℃; for 1.75h; | 93% |
Conditions | Yield |
---|---|
Stage #1: trimethylsulfoxonium iodide With sodium hydride In dimethyl sulfoxide; mineral oil at 20℃; for 0.5h; Inert atmosphere; Sealed tube; Stage #2: 4-methoxybenzyl methyl ketone In dimethyl sulfoxide; mineral oil at 20℃; for 5h; Sealed tube; Inert atmosphere; | 93% |
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