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Hangzhou Dingyan Chem Co., Ltd

Items Standard Result Appearance Yellow transparent oily liquid Conform Identification P

Top purity 4-methoxyphenylacetone with high quality and best price cas:122-84-9

Cas:122-84-9

Min.Order:1 Kilogram

FOB Price: $50.0 / 140.0

Type:Manufacturers

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Jinan Finer Chemical Co., Ltd

Product description: Product name 4-Methoxyphenylacetone CAS number 122-84-9 Assay ≥99% Appearance Yellowish liquid Capacity 100mt/year Application Pharmaceutical intermediat

4-Methoxyphenylacetone

Cas:122-84-9

Min.Order:1 Kilogram

FOB Price: $12.0

Type:Lab/Research institutions

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 4-methoxyphenylacetone

Cas:122-84-9

Min.Order:1

Negotiable

Type:Other

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

(4-Methoxyphenyl)-acetone

Cas:122-84-9

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

4-Methoxyphenylacetone

Cas:122-84-9

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

New production CAS 122-84-9 with best quality

Cas:122-84-9

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Hebei yanxi chemical co.,LTD.

hebei yanxi chemical co., LTD who registered capital of 10 million yuan, nearly to $2 million, we have a pharmaceutical raw materials factory production of pharmaceutical raw materials, and a reagent r&d center, and we do research and developmen

4-Methoxyphenylacetone CAS NO.122-84-9

Cas:122-84-9

Min.Order:1 Kilogram

FOB Price: $2.0 / 6.0

Type:Trading Company

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Hot Sell Factory Supply Raw Material 4-Methoxyphenylacetone CAS 122-84-9

Cas:122-84-9

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

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Hangzhou Sartort Biopharma Co., Ltd

Appearance:pale yellow liquid Storage:room temperature Package:200kg/drum Application:A volatile compound released by flowering plants to attractant insects Transportation:Express/Sea/Air Port:Shanghai

4-Methoxyphenylacetone with high quality

Cas:122-84-9

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Lab/Research institutions

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HANWAYS CHEMPHARM CO.,LIMITED

Hanways chempharm is a specialized company concentrating on the R&D, production, marketing and technical service of APIs and pharmaceutical intermediates. The marketing department is located in Wuhan. We have two GMP facilities in Hubei Pr

4-Methoxyphenylacetone / CAS 122-84-9 Liquid Anesthetic Pass Customs Whole Sale High Purity in Stock

Cas:122-84-9

Min.Order:1 Kilogram

FOB Price: $200.0 / 400.0

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

2-Propanone,1-(4-methoxyphenyl)- 122-84-9

Cas:122-84-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hangzhou Fonlynn Health Technology Co., Ltd.

Packing: According to customer requirements Delivery time: In stock or depands Port of shipment: Ningbo/Shanghai/Qingdao OEM/ODM:Welcome Sample:We can offer our existing samples at once Appearance:Clear colorless liquid Storage:Refer to COA / M

4-Methoxyphenylacetone 99% Ready stock cas 122-84-9

Cas:122-84-9

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Baoji Guokang Healthchem co.,ltd

Medical intermediates. Appearance:Pale Yellow Liquid Storage:2-8°C Package: according to customers' requirements Application:Medical intermediates. Transportation:Air, sea, land transport Port: China main port

Anisicketone,4-Methoxyphenylacetone,cas:122-84-9

Cas:122-84-9

Min.Order:1 Kilogram

FOB Price: $230.0 / 250.0

Type:Trading Company

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

2-Propanone,1-(4-methoxyphenyl)-

Cas:122-84-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Changchun Artel lmport and Export trade company

Minimum Order Qty. 10 Gram Supply Ability 500 Kilograms/Month Storage store in cool, dry, ventilated place 20℃ Delivery Time 3 business days after payment Payment Term TT,western union,Paypal,MoneyGram Package 10g,20g,50g,100g,500g,1KGS,

4-Methoxyphenylacetone CAS NO.122-84-9

Cas:122-84-9

Min.Order:10 Gram

Negotiable

Type:Trading Company

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

2-Propanone,1-(4-methoxyphenyl)-

Cas:122-84-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Triumph International Development Limilted

Appearance:white powder Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Used for research and industrial manufacture. Transportation:Common products:Sea/Air/Courie

4-Methoxyphenylacetone

Cas:122-84-9

Min.Order:100 Metric Ton

Negotiable

Type:Lab/Research institutions

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Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures

4-Methoxyphenylacetone

Cas:122-84-9

Min.Order:1 Kilogram

FOB Price: $30.0 / 50.0

Type:Lab/Research institutions

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

4-Methoxyphenylacetone

Cas:122-84-9

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

4-Methoxyphenylacetone

Cas:122-84-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Afine Chemicals Limited

Our Services 1. New Molecules R&D 2. Own test center HPLC NMR GC LC-MS 3. API and Intermediates from China reputed manufacturers 4. Documents support COA MOA MSDS DMF open part Our advantages 1. Government awarded company. Top 100 enter

4-METHOXYPHENYLACETONE

Cas:122-84-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Chemlyte Solutions

Chemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff

Featured products 4-Methoxyphenylacetone

Cas:122-84-9

Min.Order:100 Gram

Negotiable

Type:Other

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Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

4-Methoxyphenylacetone

Cas:122-84-9

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

4-Methoxyphenylacetone

Cas:122-84-9

Min.Order:10 Gram

Negotiable

Type:Lab/Research institutions

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Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

2-Propanone,1-(4-methoxyphenyl)-

Cas:122-84-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Siwei Development Group Ltd.

Product name: 4-Methoxyphenylacetone CAS No.:122-84-9 Molecule Formula:C10H12O2 Molecule Weight:164.20 Purity: 98.0% Package: 25kg/drum Description:Light yellow liquid Manufacture Standards:Enterprise Standard TESTING ITEMS

Best Quality 4-Methoxyphenylacetone

Cas:122-84-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Jiangsu Qianyu Molecular Technology Co., LTD.

Our Advantages A. International Top level TechnologyOur company owned biomedicine experts are famous at home and abroad with rich experience in research and development in the field of efficient chiral functional molecules research and development an

Best Offer4-Methoxyphenylacetone

Cas:122-84-9

Min.Order:0

Negotiable

Type:Trading Company

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Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

4-Methoxyphenylacetone

Cas:122-84-9

Min.Order:1 Milligram

Negotiable

Type:Trading Company

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Shanghai Minstar Chemical Co., Ltd

4-Methoxyphenylacetone Basic information Product Name: 4-Methoxyphenylacetone Synonyms: 4-ANISYL ACETONE;4-METHOXYBENZYL METHYL KETONE;4-METHOXYPHENYLACETONE;4-ACETONYLANISOLE;1-(P-METHOXYPHENYL)-2-PROPANONE;3-(4-METHOXYPHENYL)-2-PROPANONE;1-(

4-Methoxyphenylacetone

Cas:122-84-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

4-Methoxyphenylacetone 122-84-9

Cas:122-84-9

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Synthetic route

para-iodoanisole
696-62-8

para-iodoanisole

acetone
67-64-1

acetone

4-methoxybenzyl methyl ketone
122-84-9

4-methoxybenzyl methyl ketone

Conditions
ConditionsYield
With bis[chloro(1,2,3-trihapto-allylbenzene)palladium(II)]; N-[2-(di(1-adamantyl)phosphino)phenyl]morpholine; caesium carbonate at 90℃; for 16h; Inert atmosphere; sealed vial;98%
With (R)-1-[(SP)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine; [Pd(π-cinnamyl)Cl]2; caesium carbonate at 25℃; for 48h; Sealed tube; Inert atmosphere; Glovebox;76%
1-bromo-2-(4-methoxyphenyl)propan-2-ol
98815-48-6

1-bromo-2-(4-methoxyphenyl)propan-2-ol

4-methoxybenzyl methyl ketone
122-84-9

4-methoxybenzyl methyl ketone

Conditions
ConditionsYield
With diethylzinc In dichloromethane at 20℃; for 2h;95%
1-isopropenyl-4-methoxybenzene
1712-69-2

1-isopropenyl-4-methoxybenzene

4-methoxybenzyl methyl ketone
122-84-9

4-methoxybenzyl methyl ketone

Conditions
ConditionsYield
With [hydroxy(tosyloxy)iodo]benzene In methanol at 20℃; for 0.333333h;92%
With oxone; sodium iodide In water; acetonitrile at 20℃; for 15h; Green chemistry;85%
Stage #1: 1-isopropenyl-4-methoxybenzene With 2-Iodo-5-methylbenzenesulfonic acid In tert-butyl methyl ether; water; isopropyl alcohol at 22℃; for 0.0833333h; Inert atmosphere;
Stage #2: With Oxone In tert-butyl methyl ether; water; isopropyl alcohol at 22℃; for 4h; Inert atmosphere; Further stages;
68%
With iodine; mercury(II) oxide Man laesst auf das entstandene Jodhydrin AgNO3 oder HgO einwirken;
Estragole
140-67-0

Estragole

4-methoxybenzyl methyl ketone
122-84-9

4-methoxybenzyl methyl ketone

Conditions
ConditionsYield
With iron(III) chloride; palladium(II) trifluoroacetate; sodium 2,2,2-trifluoroacetate In water; acetonitrile at 30℃; Temperature; Wacker-Tsuji Olefin Oxidation; Inert atmosphere; Darkness;92%
Multi-step reaction with 2 steps
1: yellow HgO; absolute methanol; iodine
2: alcoholic potash / Durch Einw. von 20prozentiger Schwefelsaeure das Reaktionsprodukt
View Scheme
Multi-step reaction with 2 steps
1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 3 h / 0 - 20 °C / Inert atmosphere; Schlenk technique
2: Rh((1,8-bis(imidazolin-2-ylidene)-3,6-di(tert-butyl)carbazolide)homoallyl) / benzene-d6 / 2 h / 20 °C / Inert atmosphere; Schlenk technique
View Scheme
1-(2,2-dimethoxypropyl)-4-methoxybenzene

1-(2,2-dimethoxypropyl)-4-methoxybenzene

4-methoxybenzyl methyl ketone
122-84-9

4-methoxybenzyl methyl ketone

Conditions
ConditionsYield
With SO3H silica gel In methanol at 50℃; for 2h; Inert atmosphere;92%
1-(2-Iodo-1-methoxy-1-methyl-ethyl)-4-methoxy-benzene
98236-12-5

1-(2-Iodo-1-methoxy-1-methyl-ethyl)-4-methoxy-benzene

4-methoxybenzyl methyl ketone
122-84-9

4-methoxybenzyl methyl ketone

Conditions
ConditionsYield
With 3-chloro-benzenecarboperoxoic acid In dichloromethane at 0℃; for 1h;90%
1-(4-Methoxy-phenyl)-propan-2-one O-methyl-oxime
94169-18-3

1-(4-Methoxy-phenyl)-propan-2-one O-methyl-oxime

4-methoxybenzyl methyl ketone
122-84-9

4-methoxybenzyl methyl ketone

Conditions
ConditionsYield
With hydrogenchloride In methanol at 65℃; for 10h;90%
para-iodoanisole
696-62-8

para-iodoanisole

acetylacetone
123-54-6

acetylacetone

4-methoxybenzyl methyl ketone
122-84-9

4-methoxybenzyl methyl ketone

Conditions
ConditionsYield
With copper(l) iodide; potassium phosphate tribasic trihydrate In dimethyl sulfoxide at 90℃; for 20h; Inert atmosphere;89%
1-(4-methoxyphenyl)-2-methyl-3-phenylpropan-2-ol
65739-10-8

1-(4-methoxyphenyl)-2-methyl-3-phenylpropan-2-ol

A

4-methoxybenzyl methyl ketone
122-84-9

4-methoxybenzyl methyl ketone

B

1-phenyl-acetone
103-79-7

1-phenyl-acetone

Conditions
ConditionsYield
With 2,3,5-trimethyl-pyridine; [Ir(2-(2,4-difluorophenyl)-5-(trifluoromethyl)pyridine)2(5,5'-bis(trifluoromethyl)-2,2'-bipyridyl)](PF6); thiophenol In dichloromethane at 20℃; Sealed tube; Inert atmosphere; Irradiation;A 5%
B 89%
4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

acetone
67-64-1

acetone

4-methoxybenzyl methyl ketone
122-84-9

4-methoxybenzyl methyl ketone

Conditions
ConditionsYield
With potassium phosphate; 2-(2,6-dimethoxyphenyl)-1-methyl-3-(diphenylphosphino)-1H-indole; palladium diacetate at 90℃; for 18h; Inert atmosphere; Schlenk technique;88%
With bis[chloro(1,2,3-trihapto-allylbenzene)palladium(II)]; 2-methoxy-6-(N-methyl-N-phenyl-amino)phenyl(dicyclohexyl)phosphine; caesium carbonate at 90℃; for 24h; Kinetics; Reagent/catalyst; Inert atmosphere; Schlenk technique; Sealed tube;84%
With 2-methoxy-6-(N-methyl-N-phenyl-amino)phenyl(dicyclohexyl)phosphine; palladium cinnamyl chloride; caesium carbonate at 90℃; for 12h; Schlenk technique; Inert atmosphere;84%
1-methoxy-4-(2-nitro-1(Z)-propenyl)benzene
207511-16-8

1-methoxy-4-(2-nitro-1(Z)-propenyl)benzene

4-methoxybenzyl methyl ketone
122-84-9

4-methoxybenzyl methyl ketone

Conditions
ConditionsYield
With formaldehyd In 1,4-dioxane; perchloric acid; dichloromethane for 0.333333h; Ambient temperature;87%
With hydrogenchloride; iron In methanol; water for 0.5h; Heating;80%
With aluminium; nickel dichloride In tetrahydrofuran Substitution;79%
methyl magnesium iodide
917-64-6

methyl magnesium iodide

2-chloro-1-(4-methoxyphenyl)ethanone
2196-99-8

2-chloro-1-(4-methoxyphenyl)ethanone

A

1-(4-methoxyphenyl)-2-methylpropan-2-ol
35144-39-9

1-(4-methoxyphenyl)-2-methylpropan-2-ol

B

4-methoxybenzyl methyl ketone
122-84-9

4-methoxybenzyl methyl ketone

Conditions
ConditionsYield
In tetrahydrofuran for 16h; Ambient temperature;A 85%
B 10%
In tetrahydrofuran at 20℃; for 16h;A 85%
B 10%
(E)-3-(4-methoxyphenyl)-2-methylacrylic acid
13048-81-2, 40527-52-4, 13048-80-1

(E)-3-(4-methoxyphenyl)-2-methylacrylic acid

4-methoxybenzyl methyl ketone
122-84-9

4-methoxybenzyl methyl ketone

Conditions
ConditionsYield
With diphenyl phosphoryl azide; triethylamine In toluene at 25 - 110℃; for 2h;85%
Multi-step reaction with 2 steps
1: thionyl chloride / tetrachloromethane / 0.5 h / 35 °C
2: sodium azide; tetrabutylammomium bromide; water / tetrachloromethane / 1.5 h / Reflux
View Scheme
4-methoxyphenyl 1H-imidazole-1-sulfonate
1139705-25-1

4-methoxyphenyl 1H-imidazole-1-sulfonate

acetone
67-64-1

acetone

4-methoxybenzyl methyl ketone
122-84-9

4-methoxybenzyl methyl ketone

Conditions
ConditionsYield
With palladium diacetate; caesium carbonate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In 1,4-dioxane at 80℃; for 16h; Inert atmosphere; chemoselective reaction;84%
With 4-fluorophenyl tosylate; palladium diacetate; caesium carbonate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In 1,4-dioxane at 80℃; for 10h; Inert atmosphere;84%
2-nitro-1-(4-methoxylphenyl) propane
29865-49-4

2-nitro-1-(4-methoxylphenyl) propane

4-methoxybenzyl methyl ketone
122-84-9

4-methoxybenzyl methyl ketone

Conditions
ConditionsYield
With hydrogenchloride; iron In methanol; water for 0.5h; Heating;82%
With chloro-trimethyl-silane; 1,8-diazabicyclo[5.4.0]undec-7-ene; 3-chloro-benzenecarboperoxoic acid 1.) dichloromethane, 30 min, 0 degC; 2.) dichloromethane, 30 min, room temperature; Yield given. Multistep reaction;
4-(4'-methoxyphenyl)-2,5-dimethyl-1,3-dioxolane

4-(4'-methoxyphenyl)-2,5-dimethyl-1,3-dioxolane

A

1-chloro-2-hydroxy-1-(4'-methoxyphenyl)propane
1227753-59-4

1-chloro-2-hydroxy-1-(4'-methoxyphenyl)propane

B

4-methoxybenzyl methyl ketone
122-84-9

4-methoxybenzyl methyl ketone

Conditions
ConditionsYield
With titanium tetrachloride In dichloromethane at 0℃; for 0.5h; Mukaiyama reaction; Inert atmosphere;A 16%
B 80%
With titanium tetrachloride In dichloromethane at -30℃; for 0.5h; Mukaiyama reaction; Inert atmosphere;A 66%
B 30%
methanol
67-56-1

methanol

1-methoxy-4-(2-nitro-1(Z)-propenyl)benzene
207511-16-8

1-methoxy-4-(2-nitro-1(Z)-propenyl)benzene

A

4-methoxybenzyl methyl ketone
122-84-9

4-methoxybenzyl methyl ketone

B

1-methoxy-1-(4-methoxy-phenyl)-propan-2-one oxime

1-methoxy-1-(4-methoxy-phenyl)-propan-2-one oxime

Conditions
ConditionsYield
With indium; chloro-trimethyl-silane at 25℃; for 5.5h; Reduction; Addition;A n/a
B 78%
1-methoxy-4-((E)-2-nitroprop-1-enyl)benzene
37629-51-9

1-methoxy-4-((E)-2-nitroprop-1-enyl)benzene

4-methoxybenzyl methyl ketone
122-84-9

4-methoxybenzyl methyl ketone

Conditions
ConditionsYield
With trifluoroacetic acid; zinc In N,N-dimethyl-formamide for 0.25h;75%
1-bromo-4-methoxy-benzene
104-92-7

1-bromo-4-methoxy-benzene

acetone
67-64-1

acetone

4-methoxybenzyl methyl ketone
122-84-9

4-methoxybenzyl methyl ketone

Conditions
ConditionsYield
With potassium phosphate; C37H56ClPPd at 50℃; for 21h; Sealed tube; Inert atmosphere;70%
With (R)-1-[(SP)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine; [Pd(π-cinnamyl)Cl]2; caesium carbonate at 25℃; for 48h; Sealed tube; Inert atmosphere; Glovebox;64%
trans-2-(p-methoxyphenyl)-3-methyloxirane

trans-2-(p-methoxyphenyl)-3-methyloxirane

2-fluoro-4,4,5,5-tetramethyl-1,3-dioxa-2-boracyclopentane

2-fluoro-4,4,5,5-tetramethyl-1,3-dioxa-2-boracyclopentane

4-methoxybenzyl methyl ketone
122-84-9

4-methoxybenzyl methyl ketone

Conditions
ConditionsYield
In dichloromethane at 20℃; Inert atmosphere;69%
1-bromo-4-methoxy-benzene
104-92-7

1-bromo-4-methoxy-benzene

sodium acetylacetonate
15435-71-9, 1118-67-8

sodium acetylacetonate

A

4-methoxybenzyl methyl ketone
122-84-9

4-methoxybenzyl methyl ketone

B

1-(4-methoxyphenyl)pentane-2,4-dione
210168-09-5

1-(4-methoxyphenyl)pentane-2,4-dione

Conditions
ConditionsYield
copper(l) iodide In N,N-dimethyl-formamide at 100 - 120℃; for 23h;A 67%
B 23%
copper(l) iodide In N,N-dimethyl-formamide at 100 - 120℃; for 23h;A 67%
B 26%
1-(4-methoxybenzyl)-2,4,6-triphenylpyridin-1-ium tetrafluoroborate salt
71017-75-9

1-(4-methoxybenzyl)-2,4,6-triphenylpyridin-1-ium tetrafluoroborate salt

acetyl chloride
75-36-5

acetyl chloride

4-methoxybenzyl methyl ketone
122-84-9

4-methoxybenzyl methyl ketone

Conditions
ConditionsYield
With manganese; (2,2'-bipyridine)nickel(II) dibromide In N,N-dimethyl acetamide; acetonitrile at 20℃; for 6h; Inert atmosphere; Schlenk technique;67%
4-(2-nitro-propenyl)-anisole
17354-63-1

4-(2-nitro-propenyl)-anisole

A

4-methoxybenzyl methyl ketone
122-84-9

4-methoxybenzyl methyl ketone

B

4-methoxyphenylacetone oxime
52271-41-7

4-methoxyphenylacetone oxime

Conditions
ConditionsYield
With sulfuric acid; toluene-4-sulfonic acid In methanol at 0 - 5℃; ceramic diaphragm, carbon-rod anode, platinum cathode, 4.5 F/mol, 0.1A, cathode potential -1.45 to -1.65V vs. SCE;A 6%
B 65%
para-iodoanisole
696-62-8

para-iodoanisole

chloroacetone
78-95-5

chloroacetone

4-methoxybenzyl methyl ketone
122-84-9

4-methoxybenzyl methyl ketone

Conditions
ConditionsYield
With (2,2'-bipyridine)nickel(II) dibromide; tetrabutylammonium tetrafluoroborate Ambient temperature; Al rod/nickel-sponge;65%
With (2,2'-bipyridine)nickel(II) dibromide; tetrabutylammonium tetrafluoroborate In N,N-dimethyl-formamide Ambient temperature; i = 250 mA, nickel-sponge cathode;65%
4-(4'-methoxyphenyl)-2,5-dimethyl-1,3-dioxolane

4-(4'-methoxyphenyl)-2,5-dimethyl-1,3-dioxolane

A

1-chloro-2-hydroxy-1-(4'-methoxyphenyl)propane
1227753-59-4

1-chloro-2-hydroxy-1-(4'-methoxyphenyl)propane

B

4-methoxybenzyl methyl ketone
122-84-9

4-methoxybenzyl methyl ketone

C

2-hydroxy-1-methoxy-1-(4'-methoxyphenyl)propane
21712-86-7

2-hydroxy-1-methoxy-1-(4'-methoxyphenyl)propane

Conditions
ConditionsYield
With titanium tetrachloride In dichloromethane at -78℃; for 0.5h; Mukaiyama reaction; Inert atmosphere;A 64%
B 16%
C 16%
2-(4-methoxyphenyl)-3-methyloxirane
51410-46-9

2-(4-methoxyphenyl)-3-methyloxirane

4-methoxybenzyl methyl ketone
122-84-9

4-methoxybenzyl methyl ketone

Conditions
ConditionsYield
With clay; potassium bromide In benzene for 0.25h; Ambient temperature;61%
1-(1-phenylethyl)-2-methyleneaziridine

1-(1-phenylethyl)-2-methyleneaziridine

CH3OC6H4MgX

CH3OC6H4MgX

4-methoxybenzyl methyl ketone
122-84-9

4-methoxybenzyl methyl ketone

Conditions
ConditionsYield
Stage #1: N-(1-Phenylethyl)-2-methyleneaziridine; CH3OC6H4MgX With copper(l) iodide; boron trifluoride diethyl etherate In tetrahydrofuran at -30 - 0℃; Ring cleavage;
Stage #2: In tetrahydrofuran Hydrolysis; Further stages.;
60%
4-methoxybenzyl methyl ketone
122-84-9

4-methoxybenzyl methyl ketone

2-methoxy-5-(2-oxopropyl)benzenesulfonyl chloride
80223-79-6

2-methoxy-5-(2-oxopropyl)benzenesulfonyl chloride

Conditions
ConditionsYield
With chlorosulfonic acid at 0 - 20℃; for 2h;100%
With chlorosulfonic acid40%
With chlorosulfonic acid for 2h; Ambient temperature;11.4 g
4-methoxybenzyl methyl ketone
122-84-9

4-methoxybenzyl methyl ketone

2-Pentanone
107-87-9

2-Pentanone

B

(R)-(-)-p-methoxyamphetamine
58993-79-6

(R)-(-)-p-methoxyamphetamine

Conditions
ConditionsYield
With Candida boidinii formate dehydrogenase; pyridoxal 5'-phosphate; Aspergillus terreus ω-trans aminase; Lysinibacillus fusiformis leucine dehydrogenase; ammonium formate; nicotinamide adenine dinucleotide In aq. buffer at 30℃; for 24h; pH=8.8; Catalytic behavior; Green chemistry; Enzymatic reaction;A 99.7%
B 99.4%
4-methoxybenzyl methyl ketone
122-84-9

4-methoxybenzyl methyl ketone

toluene-4-sulfonic acid hydrazide
1576-35-8

toluene-4-sulfonic acid hydrazide

N'-(1-(4-methoxyphenyl)propan-2-ylidene)-4-methylbenzenesulfonohydrazide
1379610-69-1

N'-(1-(4-methoxyphenyl)propan-2-ylidene)-4-methylbenzenesulfonohydrazide

Conditions
ConditionsYield
In methanol at 20℃; Inert atmosphere;99.5%
In methanol at 70℃; Inert atmosphere;
In methanol Reflux;
4-methoxybenzyl methyl ketone
122-84-9

4-methoxybenzyl methyl ketone

1-(4-methoxyphenyl)propan-2-ol
131029-01-1, 30314-64-8

1-(4-methoxyphenyl)propan-2-ol

Conditions
ConditionsYield
With sodium tetrahydroborate In methanol at 20℃; for 0.166667h; Inert atmosphere; Schlenk technique;99%
With methanol; sodium tetrahydroborate at 0℃; for 2h; Inert atmosphere;99%
With IrH2Cl[(iPr2PC2H4)2NH]; potassium tert-butylate; hydrogen In methanol at 20℃; under 7600.51 Torr; for 1h;98%
4-methoxybenzyl methyl ketone
122-84-9

4-methoxybenzyl methyl ketone

benzylamine
100-46-9

benzylamine

[2-(4-methoxyphenyl)-1-methylethyl](phenylmethyl)amine
43229-65-8

[2-(4-methoxyphenyl)-1-methylethyl](phenylmethyl)amine

Conditions
ConditionsYield
With hydrogen; platinum on activated charcoal In ethanol99%
With platinum on carbon; hydrogen In methanol at 20℃; under 2327.23 - 2844.39 Torr; Inert atmosphere;99%
With sodium tris(acetoxy)borohydride; acetic acid In dichloromethane at 0 - 20℃;97%
trimethylsilyl cyanide
7677-24-9

trimethylsilyl cyanide

4-methoxybenzyl methyl ketone
122-84-9

4-methoxybenzyl methyl ketone

3-(4'-methoxyphenyl)-2-methyl-2-trimethylsilyloxypropanenitrile

3-(4'-methoxyphenyl)-2-methyl-2-trimethylsilyloxypropanenitrile

Conditions
ConditionsYield
With 4-methylmorpholine N-oxide In dichloromethane at 20℃; for 5h;99%
With cesium fluoride In acetonitrile at 20℃; for 0.8h;97%
With montmorillonite K10 In acetone at 20℃; for 0.166667h; Catalytic behavior; Green chemistry;96%
4-methoxybenzyl methyl ketone
122-84-9

4-methoxybenzyl methyl ketone

(R)-(-)-p-methoxyamphetamine
58993-79-6

(R)-(-)-p-methoxyamphetamine

Conditions
ConditionsYield
With glucose dehydrogenase; D-Alanine; D-glucose; ω-transaminase ATA-117; pyridoxal 5'-phosphate; nicotinamide adenine dinucleotide; lactate dehydrogenase In dimethyl sulfoxide at 30℃; for 24h; pH=7; aq. phosphate buffer; Enzymatic reaction; optical yield given as %ee; stereoselective reaction;99%
With pyridoxal 5'-phosphate; amine transaminase TA-P2-B01; isopropylamine In aq. phosphate buffer at 30℃; for 24h; pH=7.5; Reagent/catalyst; Enzymatic reaction; enantioselective reaction;86%
With Cb-FDH formate dehydrogenase (variant) from Candida boidinii; Rs-PhAmDH amine dehydrogenase variant from the phenylalanine dehydrogenase from Rhodoccoccus species; NAD; ammonium formate In water at 30℃; for 24h; pH=8.5; Reagent/catalyst; Enzymatic reaction; stereoselective reaction;82%
4-methoxybenzyl methyl ketone
122-84-9

4-methoxybenzyl methyl ketone

N,N-dimethyl-formamide dimethyl acetal
4637-24-5

N,N-dimethyl-formamide dimethyl acetal

4-dimethylamino-3-(4-methoxyphenyl)-but-3-en-2-one

4-dimethylamino-3-(4-methoxyphenyl)-but-3-en-2-one

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 100℃; for 2h; Microwave irradiation;99%
4-methoxybenzyl methyl ketone
122-84-9

4-methoxybenzyl methyl ketone

malononitrile
109-77-3

malononitrile

2-(1-(4-methoxyphenyl)propan-2-ylidene)malononitrile
69358-84-5

2-(1-(4-methoxyphenyl)propan-2-ylidene)malononitrile

Conditions
ConditionsYield
With ammonium acetate; acetic acid In benzene at 120℃; Knoevenagel Condensation; Dean-Stark;98%
With ammonium acetate In acetic acid; benzene
4-methoxybenzyl methyl ketone
122-84-9

4-methoxybenzyl methyl ketone

(S)-(+)-1-(4-methoxyphenyl)propan-2-ol
131029-01-1

(S)-(+)-1-(4-methoxyphenyl)propan-2-ol

Conditions
ConditionsYield
With Rhodococcus ruber alcohol dehydrogenase; NAD; isopropyl alcohol; magnesium chloride In aq. phosphate buffer at 30℃; pH=7; Catalytic behavior; Reagent/catalyst; Time; Inert atmosphere; Schlenk technique; Enzymatic reaction; enantioselective reaction;98%
With D-glucose; Zygosaccharomyces rouxii cells In water at 28℃; for 1h;82%
With bakers' yeast at 30℃; for 120h; Product distribution; further aryl ketones investigated;80%
4-methoxybenzyl methyl ketone
122-84-9

4-methoxybenzyl methyl ketone

(S)-2-(4-methoxy-phenyl)-1-methyl-ethylamine
58993-78-5

(S)-2-(4-methoxy-phenyl)-1-methyl-ethylamine

Conditions
ConditionsYield
With L-alanin; Bacillus subtilis L-alanine dehydrogenase; NAD-specific formate dehydrogenase; ω-transaminase ATA-113; pyridoxal 5'-phosphate; ammonium formate; nicotiamide adenine dinucleotide In dimethyl sulfoxide at 30℃; for 24h; pH=7; aq. phosphate buffer; optical yield given as %ee; enantioselective reaction;98%
With pyridoxal 5'-phosphate; amine transaminase TA-P1-G05; isopropylamine In aq. phosphate buffer at 30℃; for 24h; pH=7.5; Reagent/catalyst; Enzymatic reaction; enantioselective reaction;84%
Multi-step reaction with 2 steps
1: 79 percent / ammonium formate / Pd/C / methanol / 20 °C
2: Candida antarctica lipase B / 22 h / 28 °C
View Scheme
4-methoxybenzyl methyl ketone
122-84-9

4-methoxybenzyl methyl ketone

methylmagnesium bromide
75-16-1

methylmagnesium bromide

1-(4-methoxyphenyl)-2-methylpropan-2-ol
35144-39-9

1-(4-methoxyphenyl)-2-methylpropan-2-ol

Conditions
ConditionsYield
Stage #1: 4-methoxybenzyl methyl ketone; methylmagnesium bromide In diethyl ether; benzene at 100℃; for 3h;
Stage #2: With water; ammonium chloride In diethyl ether; benzene at 0℃;
98%
In tetrahydrofuran at 0 - 20℃; Inert atmosphere; Schlenk technique;
4-methoxybenzyl methyl ketone
122-84-9

4-methoxybenzyl methyl ketone

2-chloro-1,2-bis(4-methylphenyl)ethanone
71193-32-3

2-chloro-1,2-bis(4-methylphenyl)ethanone

3-(4-methoxyphenyl)-1,2-di-p-tolylpentane-1,4-dione
1333377-93-7

3-(4-methoxyphenyl)-1,2-di-p-tolylpentane-1,4-dione

Conditions
ConditionsYield
Stage #1: 4-methoxybenzyl methyl ketone With sodium hexamethyldisilazane In tetrahydrofuran at 0℃; Inert atmosphere;
Stage #2: With zinc(II) chloride In tetrahydrofuran for 0.166667h; Inert atmosphere;
Stage #3: 2-chloro-1,2-bis(4-methylphenyl)ethanone With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride In tetrahydrofuran at 45℃; Inert atmosphere; optical yield given as %de;
98%
4-methoxybenzyl methyl ketone
122-84-9

4-methoxybenzyl methyl ketone

4-methoxybenzonitrile
874-90-8

4-methoxybenzonitrile

Conditions
ConditionsYield
With aluminum (III) chloride; sodium nitrite In N,N-dimethyl-formamide at 90℃; for 4h; Schlenk technique;98%
With oxygen; copper diacetate; ammonium carbonate; tetra-(n-butyl)ammonium iodide In dimethyl sulfoxide at 120℃; for 5h; Schlenk technique;59%
2-(2-bromophenyl)-1,3-dioxolan
34824-58-3

2-(2-bromophenyl)-1,3-dioxolan

4-methoxybenzyl methyl ketone
122-84-9

4-methoxybenzyl methyl ketone

1-(2-(1,3-dioxolan-2-yl)phenyl)-1-(4-methoxyphenyl)propan-2-one

1-(2-(1,3-dioxolan-2-yl)phenyl)-1-(4-methoxyphenyl)propan-2-one

Conditions
ConditionsYield
With dichloro[1,1'-bis(di-t-butylphosphino)ferrocene]palladium(II); caesium carbonate at 70℃; for 18h; Inert atmosphere;98%
4-methoxybenzyl methyl ketone
122-84-9

4-methoxybenzyl methyl ketone

tert-butyldimethylsilyl chloride
18162-48-6

tert-butyldimethylsilyl chloride

tert-Butyl-[(Z)-2-(4-methoxy-phenyl)-1-methyl-vinyloxy]-dimethyl-silane
82700-20-7

tert-Butyl-[(Z)-2-(4-methoxy-phenyl)-1-methyl-vinyloxy]-dimethyl-silane

Conditions
ConditionsYield
With sodium hydride In tetrahydrofuran Ambient temperature;97%
4-methoxybenzyl methyl ketone
122-84-9

4-methoxybenzyl methyl ketone

(R)-1-phenyl-ethyl-amine
3886-69-9

(R)-1-phenyl-ethyl-amine

(R)-1-(4-methoxyphenyl)-N-((R)-1-phenylethyl)propan-2-amine
140173-30-4

(R)-1-(4-methoxyphenyl)-N-((R)-1-phenylethyl)propan-2-amine

Conditions
ConditionsYield
With hydrogen; titanium(IV)isopropoxide In 1,2-dichloro-ethane at 20 - 45℃; under 7600.51 Torr; for 1.25h; Reagent/catalyst; Autoclave;96%
(i) benzene, (ii) H2, Raney-Ni, EtOH; Multistep reaction;
With hydrogen; platinum(IV) oxide In methanol at 50℃; under 1500.15 Torr; for 12h;
With platinum on carbon; hydrogen In methanol at 60℃; for 24h;
Multi-step reaction with 2 steps
1: hydrogen; platinum on activated charcoal
2: L-Tartaric acid / ethanol
View Scheme
trimethylsilyl cyanide
7677-24-9

trimethylsilyl cyanide

4-methoxybenzyl methyl ketone
122-84-9

4-methoxybenzyl methyl ketone

C14H21NO2Si

C14H21NO2Si

Conditions
ConditionsYield
Stage #1: 4-methoxybenzyl methyl ketone With (R,R)-N,N′-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminum(III) chloride; (tert-Butoxycarbonylmethylene)triphenylphosphorane; Triphenylphosphine oxide In dichloromethane at -40℃; for 0.5h; Inert atmosphere;
Stage #2: trimethylsilyl cyanide In dichloromethane at -40℃; for 10h; Inert atmosphere;
96%
4-methoxybenzyl methyl ketone
122-84-9

4-methoxybenzyl methyl ketone

2,2-dihydroxy-1-phenyl-ethanone
1075-06-5

2,2-dihydroxy-1-phenyl-ethanone

2-hydroxy-3-(4-methoxyphenyl)-1-phenylpentane-1,4-dione

2-hydroxy-3-(4-methoxyphenyl)-1-phenylpentane-1,4-dione

Conditions
ConditionsYield
With 1,4-diaza-bicyclo[2.2.2]octane In water at 20℃; for 24h; Reagent/catalyst; Aldol Condensation; Green chemistry; diastereoselective reaction;95%
4-methoxybenzyl methyl ketone
122-84-9

4-methoxybenzyl methyl ketone

(R)-1-phenyl-ethyl-amine
3886-69-9

(R)-1-phenyl-ethyl-amine

C18H23NO*ClH

C18H23NO*ClH

Conditions
ConditionsYield
Stage #1: 4-methoxybenzyl methyl ketone; (R)-1-phenyl-ethyl-amine With 2 % platinum on carbon; hydrogen In methanol for 3h;
Stage #2: With hydrogenchloride In acetone for 2h; pH=2 - 3; Reagent/catalyst; Solvent;
95%
4-methoxybenzyl methyl ketone
122-84-9

4-methoxybenzyl methyl ketone

potassium cyanide
151-50-8

potassium cyanide

5-(4-methoxybenzyl)-5-methylimidazolidine-2,4-dione
13500-24-8

5-(4-methoxybenzyl)-5-methylimidazolidine-2,4-dione

Conditions
ConditionsYield
With ammonium carbonate In ethanol; water at 80℃; for 18h;93%
5-fluoro-1H-indole-2,3-dione
443-69-6

5-fluoro-1H-indole-2,3-dione

4-methoxybenzyl methyl ketone
122-84-9

4-methoxybenzyl methyl ketone

6-fluoro-3-(4-methoxyphenyl)-2-methylquinoline-4-carboxylic acid
1609013-04-8

6-fluoro-3-(4-methoxyphenyl)-2-methylquinoline-4-carboxylic acid

Conditions
ConditionsYield
With potassium hydroxide In ethanol at 80℃; for 48h; Pfitzinger Quinoline Synthesis;93%
With potassium hydroxide In ethanol for 48h; Pfitzinger Quinoline Synthesis; Reflux;93%
2-methyl-3-bromo-1-propene
1458-98-6

2-methyl-3-bromo-1-propene

4-methoxybenzyl methyl ketone
122-84-9

4-methoxybenzyl methyl ketone

C14H18O2

C14H18O2

Conditions
ConditionsYield
Stage #1: 4-methoxybenzyl methyl ketone With sodium hydride In N,N-dimethyl-formamide; mineral oil at -20℃; for 0.5h; Inert atmosphere;
Stage #2: 2-methyl-3-bromo-1-propene In N,N-dimethyl-formamide; mineral oil at -20 - 20℃; for 0.5h; Inert atmosphere;
93%
4-methoxybenzyl methyl ketone
122-84-9

4-methoxybenzyl methyl ketone

Benzhydrylamine
91-00-9

Benzhydrylamine

N-diphenylmethyl-1-(4-methyloxyphenyl)propan-2-amine

N-diphenylmethyl-1-(4-methyloxyphenyl)propan-2-amine

Conditions
ConditionsYield
Stage #1: 4-methoxybenzyl methyl ketone; Benzhydrylamine With titanium(IV) isopropylate; trifluoroacetic acid In dichloromethane for 2h; Molecular sieve;
Stage #2: With hydrogen under 38002.6 Torr; for 14h;
93%
4-methoxybenzyl methyl ketone
122-84-9

4-methoxybenzyl methyl ketone

methylmagnesium chloride
676-58-4

methylmagnesium chloride

1-(4-methoxyphenyl)-2-methylpropan-2-ol
35144-39-9

1-(4-methoxyphenyl)-2-methylpropan-2-ol

Conditions
ConditionsYield
In tetrahydrofuran; toluene at 8 - 12℃; for 1.75h;93%
4-methoxybenzyl methyl ketone
122-84-9

4-methoxybenzyl methyl ketone

trimethylsulfoxonium iodide
1774-47-6

trimethylsulfoxonium iodide

2-(4-methoxybenzyl)-2-methyloxirane

2-(4-methoxybenzyl)-2-methyloxirane

Conditions
ConditionsYield
Stage #1: trimethylsulfoxonium iodide With sodium hydride In dimethyl sulfoxide; mineral oil at 20℃; for 0.5h; Inert atmosphere; Sealed tube;
Stage #2: 4-methoxybenzyl methyl ketone In dimethyl sulfoxide; mineral oil at 20℃; for 5h; Sealed tube; Inert atmosphere;
93%
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