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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

Methyl 4-formylbenzoate Manufacturer/High quality/Best price/In stock

Cas:1571-08-0

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Methyl 4-formylbenzoate

Cas:1571-08-0

Min.Order:1

Negotiable

Type:Other

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Terephthalaldehydic acid methyl ester

Cas:1571-08-0

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

Tianfu Chemical, built in 2009, is a professional supplier for API materials in China. With 10 years development, we have bulit our own factory and lab to produce a certain of products. And we have established stable business relationship

TIANFU 1571-08-0 Methyl 4-formylbenzoate

Cas:1571-08-0

Min.Order:1 Kilogram

FOB Price: $200.0

Type:Lab/Research institutions

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

HotCAS 1571-08-0 with best price

Cas:1571-08-0

Min.Order:10 Gram

FOB Price: $146.0 / 176.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Product name: Methyl p-formylbenzoate Category: Pharmaceutical intermediates CAS NO.: 1571-08-0 Molecular formula: C9H7

Methyl 4-formylbenzoate

Cas:1571-08-0

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

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Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

Methyl 4-formylbenzoate CAS:1571-08-0

Cas:1571-08-0

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Methyl 4-formylbenzoate 1571-08-0

Cas:1571-08-0

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Shanghai Minstar Chemical Co., Ltd

Product Name: Methyl 4-formylbenzoate CAS: 1571-08-0 MF: C9H8O3 MW: 164.16 EINECS: 216-385-5 Mol File: 1571-08-0.mol Methyl 4-formylbenzoate Structure Methyl 4-formylbenzoate Chemical Properties Melting point 59-63 °C (lit

Methyl 4-formylbenzoate

Cas:1571-08-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Qingdao Beluga Import and Export Co., LTD

Methyl 4-formylbenzoate CAS:1571-08-0 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic in

Methyl 4-formylbenzoate CAS:1571-08-0

Cas:1571-08-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Methyl 4-formylbenzoate

Cas:1571-08-0

Min.Order:1 Kilogram

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Wuhan Kemi-Works Chemical Co., Ltd

1.Product name: Methyl 4-formylbenzoate 2.CAS No. 1571-08-0 3.Assay:99% min 4.Appearance: White crystal ISO9001 Appearance:White crystals Storage:store in dry and cool place Package:25KG/fibre drum Application:Pharmaceutical Intermediat

Methyl 4-formylbenzoate

Cas:1571-08-0

Min.Order:1 Kilogram

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Type:Other

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Methyl 4-formylbenzoate

Cas:1571-08-0

Min.Order:0

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Type:Lab/Research institutions

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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

Methyl-4-Formyl Benzoate

Cas:1571-08-0

Min.Order:0

Negotiable

Type:Manufacturers

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Methyl 4-formylbenzoate CAS NO.1571-08-0

Cas:1571-08-0

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Methyl 4-formylbenzoate

Cas:1571-08-0

Min.Order:0

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Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

Methyl 4-formylbenzoate

Cas:1571-08-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality methyl 4-formylbenzoate

Cas:1571-08-0

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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Siwei Development Group Ltd.

Product name: Ethyl P-Formylbenzoate CAS No.:1571-08-0 Molecule Formula:C9H7O3 Molecule Weight:163.15 Purity: 99.0% Package: 25kg/drum Description:White crystalline powder Manufacture Standards:Enterprise Standard

Best Quality Ethyl P-Formylbenzoate

Cas:1571-08-0

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

Methyl 4-formylbenzoate Manufacturer

Cas:1571-08-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

Methyl 4-formylbenzoate CAS NO.1571-08-0

Cas:1571-08-0

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

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Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

Methyl 4-formylbenzoate CAS NO.1571-08-0

Cas:1571-08-0

Min.Order:1 Gram

Negotiable

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KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

Methyl 4-formylbenzoate CAS NO.1571-08-0

Cas:1571-08-0

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

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Hangzhou Zhongqi chem Co.,Ltd.

Located in Hangzhou National Hi-Tech Industrial Development Zone, zhongqichem is a technical company mainly focus on the Custom synthesis, manufacturing, sales of chemicals to various industries. Benefiting from the outstanding customer service and h

Methyl 4-formylbenzoate

Cas:1571-08-0

Min.Order:0

Negotiable

Type:Other

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HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:white crystalline powder Storage:stored in a cool, dry and ventilated place to provent sun and rain Package:25kg/drum, or as per your request. Application:Used as Pharmaceutical

Methyl 4-formylbenzoate

Cas:1571-08-0

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

Methyl 4-formylbenzoate CAS NO.1571-08-0

Cas:1571-08-0

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

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Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

Methyl 4-Formylbenzoate cas no. 1571-08-0 98%

Cas:1571-08-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Suzhou Sibian Chemical Technology Co., Ltd

The process is mature and can be mass produced to 100 kg, with good quality and purity up to 99%.The product has a large stock and can be supplied stably. Package:bottle Application:Drug R&D Transportation:Sealed drying(25℃) Port:ShangHai

Methyl 4-formylbenzoate

Cas:1571-08-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

Methyl p-formylbenzoate

Cas:1571-08-0

Min.Order:0

Negotiable

Type:Other

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Wuxi TAA Chemical Industry Co.,LTD.

1.A strong technical force and advanced processing equipments. The quality of the products has been strictly inspected and all kinds of index have reached or exceeded domestic and international standards.2. Now we have established long-term stable re

1571-08-0 Methyl 4-formylbenzoate

Cas:1571-08-0

Min.Order:0

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Type:Other

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Synthetic route

4-(methoxycarbonyl)benzyl alcohol
6908-41-4

4-(methoxycarbonyl)benzyl alcohol

methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

Conditions
ConditionsYield
With air; poly-alkylated (nitrosyl)Ru(salen) In toluene at 20℃; for 24h; Irradiation;100%
With dmap; tetrakis(actonitrile)copper(I) hexafluorophosphate; N,N'-di-tert-butylethylenediamine; oxygen In dichloromethane at 20℃; under 760.051 Torr; for 3h; Schlenk technique; Molecular sieve; Sealed tube;99%
With fluorosulfonyl fluoride; potassium carbonate; dimethyl sulfoxide at 20℃; for 12h; chemoselective reaction;99%
methyl 4-(diethoxymethyl)benzenecarboxylate
101403-69-4

methyl 4-(diethoxymethyl)benzenecarboxylate

methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

Conditions
ConditionsYield
sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate In water at 30℃; for 3h;100%
4-Carboxybenzaldehyde
619-66-9

4-Carboxybenzaldehyde

methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

Conditions
ConditionsYield
In methanol100%
In dichloromethane
In dichloromethane
Multi-step reaction with 2 steps
1: O-(benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium tetrafluoroborate; N-ethyl-N,N-diisopropylamine / dichloromethane / 20 °C
2: copper(II) bis(trifluoromethanesulfonate) / 16 h / 20 °C
View Scheme
4-(hydroxyiminomethyl)benzoic acid methyl ester
53148-13-3

4-(hydroxyiminomethyl)benzoic acid methyl ester

methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

Conditions
ConditionsYield
With hydrogenchloride In water; toluene at 20℃; for 4h; Reflux; Large scale;98%
methyl 4-(dimethoxymethyl)benzoate
42228-16-0

methyl 4-(dimethoxymethyl)benzoate

methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

Conditions
ConditionsYield
With toluene-4-sulfonic acid In acetone at 20℃; for 20h;98%
methyl 4-[2-(methylthio)-1,3-dithian-2-yl]benzoate
176208-43-8

methyl 4-[2-(methylthio)-1,3-dithian-2-yl]benzoate

methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

Conditions
ConditionsYield
With water; 2,3-dicyano-5,6-dichloro-p-benzoquinone In acetonitrile for 3h; Ambient temperature;97%
With p-benzoquinone; sodium iodide In water; acetonitrile at 100℃; for 31h;86 %Spectr.
4-Carboxybenzaldehyde
619-66-9

4-Carboxybenzaldehyde

dimethyl dicarbonate
4525-33-1

dimethyl dicarbonate

methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

Conditions
ConditionsYield
magnesium(II) perchlorate In nitromethane at 40℃; for 16h;97%
di(p-tolyl) sulfoxide
1774-35-2

di(p-tolyl) sulfoxide

4-(methoxycarbonyl)benzyl alcohol
6908-41-4

4-(methoxycarbonyl)benzyl alcohol

A

di-(p-tolyl)sulfane
620-94-0

di-(p-tolyl)sulfane

B

methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

Conditions
ConditionsYield
With per-rhenic acid In toluene for 24h; Reflux;A 97%
B 85%
methanol
67-56-1

methanol

4-Carboxybenzaldehyde
619-66-9

4-Carboxybenzaldehyde

methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

Conditions
ConditionsYield
With acetyl chloride at 0 - 20℃;96%
With thionyl chloride Ambient temperature;95%
With thionyl chloride at 0 - 20℃;93%
4-quinolynylmethyl 4-formylbenzoate
274250-98-5

4-quinolynylmethyl 4-formylbenzoate

methyl iodide
74-88-4

methyl iodide

methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

Conditions
ConditionsYield
Stage #1: 4-quinolynylmethyl 4-formylbenzoate With ammonium formate; 1,2-bis-(diphenylphosphino)ethane; bis(dibenzylideneacetone)-palladium(0) In dimethyl sulfoxide at 50℃; for 12h; Reduction; Deprotection;
Stage #2: methyl iodide With sodium carbonate In water; dimethyl sulfoxide at 20℃; for 12h; Methylation;
96%
methanol
67-56-1

methanol

4-formylphenyl 2,3,4,5,6-pentafluorobenzenesulfonate

4-formylphenyl 2,3,4,5,6-pentafluorobenzenesulfonate

methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

Conditions
ConditionsYield
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; potassium acetate at 20℃; for 16h; Schlenk technique; Inert atmosphere; chemoselective reaction;96%
Methyl 4-(bromomethyl)benzoate
2417-72-3

Methyl 4-(bromomethyl)benzoate

methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

Conditions
ConditionsYield
With potassium hydrogencarbonate; dimethyl sulfoxide for 0.05h; Microwave irradiation;95%
With pyridine N-oxide; silver(l) oxide In acetonitrile at 25℃;81%
With ethanol; sodium 2-nitropropane
With methanol; hexamethylenetetramine
With 4-methylmorpholine N-oxide In acetonitrile at 0℃; Inert atmosphere; Molecular sieve;
(4-(methoxycarbonyl)phenyl)methylene diacetate
59153-68-3

(4-(methoxycarbonyl)phenyl)methylene diacetate

methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

Conditions
ConditionsYield
With potassium tert-butylate; 3-Dimethylaminophenol In tetrahydrofuran for 0.0833333h;92%
With zirconium(IV) chloride In methanol at 20℃; for 0.1h;89%
4-(diethylaminocarbonyl)benzoic acid methyl ester
122357-96-4

4-(diethylaminocarbonyl)benzoic acid methyl ester

methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

Conditions
ConditionsYield
With Schwartz's reagent In tetrahydrofuran at 20℃; for 0.416667h; Inert atmosphere;92%
With Schwartz's reagent In tetrahydrofuran at 20℃; for 0.5h;73%
methyl 4-[(hydroxy)(1,2,3,4,5-pentamethyl-2,4-cyclopentadienyl)methyl]benzoate
862387-17-5

methyl 4-[(hydroxy)(1,2,3,4,5-pentamethyl-2,4-cyclopentadienyl)methyl]benzoate

A

1,2,3,4,5-pentamethylcyclopentadiene
4045-44-7

1,2,3,4,5-pentamethylcyclopentadiene

B

methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

Conditions
ConditionsYield
With trichloroacetic acid In dichloromethane at 28℃; for 1.5h;A n/a
B 91%
methanol
67-56-1

methanol

4-formyl-N,N-bis(pyridin-2-ylmethyl)benzamide
1314659-42-1

4-formyl-N,N-bis(pyridin-2-ylmethyl)benzamide

methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

Conditions
ConditionsYield
With copper(II) bis(trifluoromethanesulfonate) at 20℃; for 16h;91%
formic acid
64-18-6

formic acid

methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

Conditions
ConditionsYield
With palladium diacetate; triethylamine; dicyclohexyl-carbodiimide; tricyclohexylphosphine In N,N-dimethyl-formamide at 60℃; for 10h; Inert atmosphere; Sealed tube;91%
Stage #1: formic acid; methyl 4-iodobenzoate With palladium diacetate; acetic anhydride; tricyclohexylphosphine In N,N-dimethyl-formamide at 30℃; for 1h; Inert atmosphere; Green chemistry;
Stage #2: With triethylamine In N,N-dimethyl-formamide at 80℃; for 6h; Inert atmosphere; Green chemistry;
79%
With iodine; triethylamine; triphenylphosphine In toluene at 80℃; Inert atmosphere; Sealed tube;71%
4-methoxycarbonylphenyl bromide
619-42-1

4-methoxycarbonylphenyl bromide

methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

Conditions
ConditionsYield
With triethylsilane; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; sodium acetate In acetonitrile at 60℃; for 16h; Schlenk technique; Inert atmosphere;91%
4-carbomethoxyphenyl triflate
17763-71-2

4-carbomethoxyphenyl triflate

methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

Conditions
ConditionsYield
With triethylsilane; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; sodium acetate In acetonitrile at 25℃; for 16h; Schlenk technique; Inert atmosphere;91%
carbon monoxide
201230-82-2

carbon monoxide

methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

A

benzoic acid methyl ester
93-58-3

benzoic acid methyl ester

B

methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

Conditions
ConditionsYield
With tri-n-butyl-tin hydride; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran at 50℃; under 2280 Torr;A 8%
B 90%
With hydrogen; potassium carbonate In 1,4-dioxane at 120 - 140℃; under 30003 Torr; for 20h; Autoclave;A 45%
B 8%
carbon monoxide
201230-82-2

carbon monoxide

methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

Conditions
ConditionsYield
With sodium formate In N,N-dimethyl-formamide at 110℃; under 760.051 Torr; for 4h;90%
With sodium formate In N,N-dimethyl-formamide at 100℃; under 760.051 Torr; for 6h;89%
With triethylsilane; palladium diacetate; sodium hydrogencarbonate; sodium carbonate at 20℃; under 760.051 Torr; for 24h;83%
With poly-γ-(p-diphenylphosphinophenyl)propylsiloxane Pd; sodium acetate In N,N-dimethyl-formamide at 90℃; for 8h;81%
N-cyclohexyl-4-(methoxycarbonyl)benzamide

N-cyclohexyl-4-(methoxycarbonyl)benzamide

methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

Conditions
ConditionsYield
Stage #1: N-cyclohexyl-4-(methoxycarbonyl)benzamide With 2-fluoropyridine; trifluoromethylsulfonic anhydride In dichloromethane at -78 - 0℃; Inert atmosphere;
Stage #2: With triethylsilane In dichloromethane at 0 - 25℃; Inert atmosphere;
Stage #3: With citric acid In tetrahydrofuran; dichloromethane; water at 45℃; for 2h; chemoselective reaction;
90%
methyl 4-(isopropylcarbamoyl)benzoate
229648-45-7

methyl 4-(isopropylcarbamoyl)benzoate

methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

Conditions
ConditionsYield
Stage #1: methyl 4-(isopropylcarbamoyl)benzoate With 2-fluoropyridine; trifluoromethylsulfonic anhydride In dichloromethane at 0℃; for 0.333333h; Inert atmosphere;
Stage #2: With 1,1,3,3-Tetramethyldisiloxane In dichloromethane at 0 - 20℃; for 6.16667h; Inert atmosphere;
Stage #3: With hydrogenchloride In dichloromethane; water at 20℃; Inert atmosphere;
90%
Multi-step reaction with 3 steps
1: phosphorus pentachloride / dichloromethane / 20 °C / Schlenk technique
2: Dimethylphenylsilane; CpRu(PiPr3)(CH3CN)2PF6; tert-butyl isocyanide / dichloromethane-d2 / 0.5 h / 20 °C / Schlenk technique
3: hydrogenchloride; water / hexane
View Scheme
methyl 4-(aminomethyl)benzoate
18469-52-8

methyl 4-(aminomethyl)benzoate

methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

Conditions
ConditionsYield
With copper(I) 2-hydroxy-3-methylbenzoate; oxygen; ascorbic acid In N,N-dimethyl acetamide at 40℃; for 2h; chemoselective reaction;89%
With N-chloro-succinimide In water at 24.9℃; Kinetics; Thermodynamic data; pH 10.6; ΔH(excit.), ΔS(excit.);
With N-bromoacetamide In water at 14.9 - 34.9℃; Kinetics; Thermodynamic data; ΔH(excit.), ΔS(excit.);
Monomethyl terephthalate
1679-64-7

Monomethyl terephthalate

methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

Conditions
ConditionsYield
With P(p-CH3OC6H4)3; methylphenylsilane; 2,2-dimethylpropanoic anhydride; bis(dibenzylideneacetone)-palladium(0) In toluene at 80℃; for 20h; Schlenk technique; Inert atmosphere;89%
With bis-triphenylphosphine-palladium(II) chloride; 2-chloro-4,6-dimethoxy-1 ,3,5-triazine; Dimethylphenylsilane In toluene at 80℃; for 7h; Inert atmosphere; Sealed tube;89%
With palladium(II) acetylacetonate; hydrogen; 2,2-dimethylpropanoic anhydride; dicyclohexylphenylphosphine In tetrahydrofuran at 80℃; under 3750.38 Torr; for 20h; Inert atmosphere;80%
4-Carboxybenzaldehyde
619-66-9

4-Carboxybenzaldehyde

carbonic acid dimethyl ester
616-38-6

carbonic acid dimethyl ester

methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

Conditions
ConditionsYield
With potassium carbonate In dimethyl sulfoxide at 90℃; for 16h; Inert atmosphere; Green chemistry;89%
4-Carboxybenzaldehyde
619-66-9

4-Carboxybenzaldehyde

methyl salicylate
119-36-8

methyl salicylate

A

salicylic acid
69-72-7

salicylic acid

B

methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

Conditions
ConditionsYield
Stage #1: 4-Carboxybenzaldehyde With potassium carbonate In N,N-dimethyl acetamide at 110℃; for 0.5h;
Stage #2: methyl salicylate at 110℃; for 24h;
A n/a
B 89%
4-Carboxybenzaldehyde
619-66-9

4-Carboxybenzaldehyde

methyl iodide
74-88-4

methyl iodide

methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In acetonitrile at 20℃; for 1h;88%
With 1,8-diazabicyclo[5.4.0]undec-7-ene In acetonitrile at 20℃; for 2h;71%
With potassium carbonate In N-methyl-acetamide; water4.7 g (84%)
With potassium carbonate In N,N-dimethyl-formamide at 60℃; Darkness;
methanol
67-56-1

methanol

4-(trifluormethanesulfonyloxy)benzaldehyde
17763-69-8

4-(trifluormethanesulfonyloxy)benzaldehyde

methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

Conditions
ConditionsYield
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; potassium acetate at 20℃; for 16h; Schlenk technique; Inert atmosphere; chemoselective reaction;88%
methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

Monomethyl terephthalate
1679-64-7

Monomethyl terephthalate

Conditions
ConditionsYield
With phosphate-buffered silica gel supported KMnO4 In cyclohexane at 65℃;100%
With chromium(VI) oxide; sulfuric acid In water; acetone at 0℃; Jones Oxidation;97%
With selenium(IV) oxide; dihydrogen peroxide In tetrahydrofuran for 5h; Heating;95%
2,2-Dimethyl-1,3-propanediol
126-30-7

2,2-Dimethyl-1,3-propanediol

methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

4-(5,5-Dimethyl-[1,3]dioxan-2-yl)-benzoic acid methyl ester
138536-73-9

4-(5,5-Dimethyl-[1,3]dioxan-2-yl)-benzoic acid methyl ester

Conditions
ConditionsYield
With toluene-4-sulfonic acid In benzene for 2h; Heating;100%
With toluene-4-sulfonic acid In toluene for 24h; Reflux;66%
trimethylsilyl cyanide
7677-24-9

trimethylsilyl cyanide

methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

methyl 4-(cyano(trimethylsilyloxy)methyl)benzoate
93555-00-1

methyl 4-(cyano(trimethylsilyloxy)methyl)benzoate

Conditions
ConditionsYield
In diethyl ether at 0℃; for 1h;100%
With Al(3+)*C36H48NO3(3-) In acetonitrile at 20℃; for 9.5h; Inert atmosphere; Schlenk techniques;92%
With iodine In dichloromethane at 20℃; for 0.05h;90%
benzyl 2-bromopropionate
3017-53-6

benzyl 2-bromopropionate

methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

benzyl 2-methyl-3-hydroxy-p-carbomethoxyhydrocinnamate
122594-12-1

benzyl 2-methyl-3-hydroxy-p-carbomethoxyhydrocinnamate

Conditions
ConditionsYield
With iodine; zinc In benzene for 18h; Heating;100%
2-bromobutyric acid benzyl ester
42115-51-5

2-bromobutyric acid benzyl ester

methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

4-(2-Benzyloxycarbonyl-1-hydroxy-butyl)-benzoic acid methyl ester
122594-13-2

4-(2-Benzyloxycarbonyl-1-hydroxy-butyl)-benzoic acid methyl ester

Conditions
ConditionsYield
With iodine; zinc In benzene Heating;100%
(Z)-2-(1-methoxyethyl)-2,4-pentadienyltrimethyltin

(Z)-2-(1-methoxyethyl)-2,4-pentadienyltrimethyltin

methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

4-((1S,2R,4R)-1-Hydroxy-4-methoxy-3-methylene-2-vinyl-pentyl)-benzoic acid methyl ester

4-((1S,2R,4R)-1-Hydroxy-4-methoxy-3-methylene-2-vinyl-pentyl)-benzoic acid methyl ester

Conditions
ConditionsYield
With TiCl4*Et2O In dichloromethane at -78℃; for 2h;100%
methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

4-(methoxycarbonyl)benzyl alcohol
6908-41-4

4-(methoxycarbonyl)benzyl alcohol

Conditions
ConditionsYield
With sodium tetrahydroborate In ethanol at 5℃; for 0.5h;100%
With zirconium dioxide hydrate; isopropyl alcohol at 60℃; for 0.133333h; Meerwein-Ponndorf-Verley Reduction;100%
Stage #1: methyl 4-formylbenzoate With polymethylhydrosiloxane; iron(II) acetate; tricyclohexylphosphine In tetrahydrofuran at 65℃; for 16h;
Stage #2: With sodium hydrogencarbonate In tetrahydrofuran; methanol at 0 - 20℃; Further stages.;
99%
malonic acid
141-82-2

malonic acid

methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

4-(2-carboxyvinyl)benzoic acid methyl ester
19473-96-2

4-(2-carboxyvinyl)benzoic acid methyl ester

Conditions
ConditionsYield
With piperidine; pyridine at 120℃; for 12h;100%
With piperidine In pyridine at 100 - 120℃; for 19h;99.39%
With piperidine; pyridine at 80 - 100℃; for 4h;91.6%
With piperidine; pyridine at 110℃; for 2h;75%
With piperidine; pyridine for 5h; Reflux;36%
3-acetyl-2,4-dihydroxyquinoline
26138-64-7

3-acetyl-2,4-dihydroxyquinoline

methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

4-[(E)-3-(2,4-Dihydroxy-quinolin-3-yl)-3-oxo-propenyl]-benzoic acid methyl ester

4-[(E)-3-(2,4-Dihydroxy-quinolin-3-yl)-3-oxo-propenyl]-benzoic acid methyl ester

Conditions
ConditionsYield
100%
benzylamine
100-46-9

benzylamine

methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

N-benzyl-(4-methoxycarbonylphenyl)methanimine
193821-09-9

N-benzyl-(4-methoxycarbonylphenyl)methanimine

Conditions
ConditionsYield
In toluene for 15.5h; Heating;100%
With 4 A molecular sieve In methanol for 4h; Heating;96%
In methanol
methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

methyl 4-[(1E)-(hydroxyimino)methyl]benzoate
168699-41-0

methyl 4-[(1E)-(hydroxyimino)methyl]benzoate

Conditions
ConditionsYield
With hydroxylamine hydrochloride; sodium acetate In methanol; water Reflux;100%
With hydroxylamine hydrochloride; sodium acetate In methanol; water for 0.5h; Reflux;79%
With hydroxylamine hydrochloride; sodium hydrogencarbonate In methanol at 20℃; for 4h;60%
1-benzoyl-1H-benzotriazole
4231-62-3

1-benzoyl-1H-benzotriazole

methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

methyl 4-<1H-1,2,3-benzotriazol-1-yl(benzoyloxy)methyl> benzoate

methyl 4-<1H-1,2,3-benzotriazol-1-yl(benzoyloxy)methyl> benzoate

Conditions
ConditionsYield
With potassium carbonate In acetonitrile at 20℃; for 10h;100%
1,6-Hexanediamine
124-09-4

1,6-Hexanediamine

methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

1,6-bis(4-methoxycarbonylbenzylidene)hexanediamine
106872-64-4

1,6-bis(4-methoxycarbonylbenzylidene)hexanediamine

Conditions
ConditionsYield
In toluene for 0.5h; Condensation; Heating;100%
In toluene for 1h; Reflux; Dean-Stark trap;100%
1H-indene-1,3(2H)-dione
606-23-5

1H-indene-1,3(2H)-dione

(E)-benzalacetone
1896-62-4

(E)-benzalacetone

methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

2-[4-(methoxycarbonyl)phenyl]-6-phenylspiro[cyclohexane-1,2'-indan]-1',3',4-trione

2-[4-(methoxycarbonyl)phenyl]-6-phenylspiro[cyclohexane-1,2'-indan]-1',3',4-trione

Conditions
ConditionsYield
Stage #1: 1H-indene-1,3(2H)-dione; methyl 4-formylbenzoate With L-proline In methanol at 20℃; for 0.5h; organocatalytic Knoevenagel condensation;
Stage #2: (E)-benzalacetone In methanol at 25℃; for 96h; Diels-Alder/epimerization reaction;
100%
(E)-3-methyl-4-methoxy-2-[(trimethylsilyl)oxy]-1,3-butadiene
72476-03-0

(E)-3-methyl-4-methoxy-2-[(trimethylsilyl)oxy]-1,3-butadiene

methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

4-(5-methyl-4-oxo-3,4-dihydro-2H-pyran-2-yl)-benzoic acid methyl ester

4-(5-methyl-4-oxo-3,4-dihydro-2H-pyran-2-yl)-benzoic acid methyl ester

Conditions
ConditionsYield
Stage #1: (E)-3-methyl-4-methoxy-2-[(trimethylsilyl)oxy]-1,3-butadiene; methyl 4-formylbenzoate With lithium methanolate In N,N-dimethyl-formamide at 0℃; Mukaiyama aldol addition;
Stage #2: With trifluoroacetic acid In N,N-dimethyl-formamide at 0℃;
100%
(1H,1H,2H,2H-perfluorooctyl)triphenylphosphonium iodide
94190-73-5

(1H,1H,2H,2H-perfluorooctyl)triphenylphosphonium iodide

methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

C17H11F13O2
944720-88-1

C17H11F13O2

Conditions
ConditionsYield
With potassium carbonate In 1,4-dioxane; water Wittig reaction; Heating;100%
2-(5-fluoro-2-methoxyphenyl)ethanamine
1000533-03-8

2-(5-fluoro-2-methoxyphenyl)ethanamine

methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

4-({[2-(5-fluoro-2-methoxyphenyl)ethyl]imino}methyl)benzoic acid methyl ester

4-({[2-(5-fluoro-2-methoxyphenyl)ethyl]imino}methyl)benzoic acid methyl ester

Conditions
ConditionsYield
In ethanol for 2h; Heating / reflux;100%
p-Trifluoromethylbenzylamine
3300-51-4

p-Trifluoromethylbenzylamine

methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

N-(4-(methylcarboxy)benzylidene)-p-trifluoromethylbenzylamine
1276692-13-7

N-(4-(methylcarboxy)benzylidene)-p-trifluoromethylbenzylamine

Conditions
ConditionsYield
In toluene Reflux;100%
tert-butyl 1-(2-bromobenzyl)hydrazine-1-carboxylate

tert-butyl 1-(2-bromobenzyl)hydrazine-1-carboxylate

methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

C21H23BrN2O4

C21H23BrN2O4

Conditions
ConditionsYield
In ethanol at 20℃;100%
2,4-Dimethoxybenzylamine
20781-20-8

2,4-Dimethoxybenzylamine

methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

methyl (E)-4-(2,4-dimethoxybenzyliminomethyl)benzoate

methyl (E)-4-(2,4-dimethoxybenzyliminomethyl)benzoate

Conditions
ConditionsYield
With magnesium sulfate In dichloromethane at 20℃; for 12h; Inert atmosphere;100%
trimethylsilyl cyanide
7677-24-9

trimethylsilyl cyanide

3-Phenylpropan-1-amine
2038-57-5

3-Phenylpropan-1-amine

methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

methyl 4-[cyano(3-phenylpropylamino)methyl]benzoate
1108730-71-7

methyl 4-[cyano(3-phenylpropylamino)methyl]benzoate

Conditions
ConditionsYield
With polymer-supported scandium(III) bis(trifluoromethanesulfonate) In acetonitrile at 20℃; for 1h; Strecker reaction; Combinatorial reaction / High throughput screening (HTS); chemoselective reaction;99.9%
trimethylsilyl cyanide
7677-24-9

trimethylsilyl cyanide

phenethylamine
64-04-0

phenethylamine

methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

methyl 4-[cyano(phenethylamino)methyl]benzoate
1108730-70-6

methyl 4-[cyano(phenethylamino)methyl]benzoate

Conditions
ConditionsYield
With polymer-supported scandium(III) bis(trifluoromethanesulfonate) In acetonitrile at 20℃; for 1h; Strecker reaction; Combinatorial reaction / High throughput screening (HTS); chemoselective reaction;99.9%
trimethylsilyl cyanide
7677-24-9

trimethylsilyl cyanide

aniline
62-53-3

aniline

methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

methyl 4-[cyano(phenylamino)methyl]benzoate
1108730-68-2

methyl 4-[cyano(phenylamino)methyl]benzoate

Conditions
ConditionsYield
With polymer-supported scandium(III) bis(trifluoromethanesulfonate) In acetonitrile at 20℃; for 1h; Strecker reaction; Combinatorial reaction / High throughput screening (HTS); chemoselective reaction;99.8%
With polymer-supported gallium(III) bis(trifluoromethanesulfonate) In dichloromethane at 40℃; under 15001.5 Torr; for 1h; Strecker reaction; Microreactor;99.9%
trimethylsilyl cyanide
7677-24-9

trimethylsilyl cyanide

benzylamine
100-46-9

benzylamine

methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

methyl 4-((benzylamino)(cyano)methyl)benzoate
1108730-69-3

methyl 4-((benzylamino)(cyano)methyl)benzoate

Conditions
ConditionsYield
With polymer-supported scandium(III) bis(trifluoromethanesulfonate) In acetonitrile at 20℃; for 1h; Strecker reaction; Combinatorial reaction / High throughput screening (HTS); chemoselective reaction;99.9%
ethyl 2-cyanoacetate
105-56-6

ethyl 2-cyanoacetate

methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

C14H13NO4

C14H13NO4

Conditions
ConditionsYield
With piperazine In acetonitrile for 1h; Knoevenagel condensation; electroosmos;99.8%
methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

4-(hydroxyiminomethyl)benzoic acid methyl ester
53148-13-3

4-(hydroxyiminomethyl)benzoic acid methyl ester

Conditions
ConditionsYield
Stage #1: methyl 4-formylbenzoate With hydroxylamine hydrochloride In methanol; water at 25 - 35℃; for 2h;
Stage #2: With sodium hydroxide In methanol; water pH=7.5 - 8;
99.5%
Stage #1: methyl 4-formylbenzoate With hydroxylamine hydrochloride; 5%-palladium/activated carbon In methanol; water at 25 - 35℃; for 2h;
Stage #2: With sodium hydroxide In methanol; water pH=7.5 - 8; Product distribution / selectivity;
99.5%
With hydroxylamine hydrochloride In methanol; water at 20℃; for 6h; Large scale;95%
methyl 4-formylbenzoate
1571-08-0

methyl 4-formylbenzoate

trimethyl orthoformate
149-73-5

trimethyl orthoformate

methyl 4-(dimethoxymethyl)benzoate
42228-16-0

methyl 4-(dimethoxymethyl)benzoate

Conditions
ConditionsYield
With *OTf3 In methanol for 5h; Ambient temperature;99%
With amberlyst-15 In acetonitrile for 1h; electroosmos;99.4%
With amberlyst-15 In acetonitrile for 0.166667h;95.3%
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