As a leading and professional manufacturer of APIs and API intermediates in China,Anhui Dexinjia Biopharm Co., Ltd founded in 2006, Except for the R&D center, our company has built a close cooperation relation with Chinese Academy of Sciences,
Cas:5470-70-2
Min.Order:1 Gram
Negotiable
Type:Manufacturers
inquiryChemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff
Cas:5470-70-2
Min.Order:100 Gram
Negotiable
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inquiryAs a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch
Cas:5470-70-2
Min.Order:1 Kilogram
FOB Price: $3.0
Type:Lab/Research institutions
inquiryWelcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our
Cas:5470-70-2
Min.Order:0 Metric Ton
Negotiable
Type:Manufacturers
inquiryUnique advantages Guaranteed purity High quality & competitive price Quality control Fast feedback Prompt shipment Appearance:Clear colorless to light yellow liquid Storage:Cool dry place Package:25kg/drum,200kg/drum Applic
Cas:5470-70-2
Min.Order:1 Kilogram
Negotiable
Type:Trading Company
inquiryThe above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi
Cas:5470-70-2
Min.Order:1
Negotiable
Type:Other
inquiryHebei yanxi chemical co., LTD is a professional research, development and production 2-phenylacetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low carbon environ
Cas:5470-70-2
Min.Order:5 Gram
FOB Price: $100.0
Type:Trading Company
inquiryOur main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block
Cas:5470-70-2
Min.Order:5 Kiloliter
FOB Price: $1.2 / 5.0
Type:Manufacturers
inquiryOur company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung, LG, Merck, Thermo Fisher Scientific and so o
Cas:5470-70-2
Min.Order:1 Metric Ton
Negotiable
Type:Lab/Research institutions
inquiryWith our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin
Cas:5470-70-2
Min.Order:1 Gram
FOB Price: $6.0 / 9.0
Type:Trading Company
inquiryWITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et
Cas:5470-70-2
Min.Order:1 Kilogram
FOB Price: $139.0 / 210.0
Type:Trading Company
inquiryName: Methyl-6-methylnicotinate Synonyms: Methyl 6-methylpyridine-3-carboxylate CAS: 5470-70-2 MF: C8H9NO2 Appearance: white powder Storage:Store in cool and dry place, away from sun light. Package: 25kgs/drum Application:Organic synthesis Trans
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Cas:5470-70-2
Min.Order:0 Metric Ton
Negotiable
Type:Trading Company
inquiryAppearance:White crystalline powder Storage:R.T Package:25kg/drum Application:Intermediate Transportation:Express/Sea/Air Port:Any port in China
Cas:5470-70-2
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
inquiry1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized
Cas:5470-70-2
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
inquiryAdvantage : LIDE PHARMACEUTICALS LTD. is a mid-small manufacturing-type enterprise, engaged in pharmaceutical intermediates of R&D, custom-made and production, and also involving trading chemicals for export. We have established the
Cas:5470-70-2
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
inquiryOur company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese
Cas:5470-70-2
Min.Order:1 Kilogram
FOB Price: $89.0 / 98.0
Type:Trading Company
inquiryMethyl 6-methylnicotinate CAS:5470-70-2 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic
Cas:5470-70-2
Min.Order:1 Gram
Negotiable
Type:Lab/Research institutions
inquiryHello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai
Cas:5470-70-2
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
inquiry1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualifie
Cas:5470-70-2
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
inquiryProduct Description Product website: http://www.finerchem.com/pro01en/id/1290.html Product Name Methyl 6-methylnicotinate CAS No. 5470-70-2
Cas:5470-70-2
Min.Order:1 Gram
FOB Price: $11.0
Type:Lab/Research institutions
inquiryMethyl 6-methylnicotinate CAS: 5470-70-2 Specification mp 34-37 °c(lit.) bp 160 °c106 mm hg(lit.) fp 218 °f storage temp. refri
Cas:5470-70-2
Min.Order:1 Kilogram
Negotiable
Type:Other
inquiryProduct Name: Methyl 6-methylnicotinate Synonyms: LABOTEST-BB LT00847843;METHYL 6-METHYLPYRIDINE-3-CARBOXYLATE;METHYL 6-METHYLNICOTINATE;3-PYRIDINECARBOXYLIC ACID, 6-METHYL-, METHYL ESTER;6-METHYL PYRIDINE-3-CARBOXYLIC ACID METHYL ESTER;6-METHYL
Cas:5470-70-2
Min.Order:100 Gram
Negotiable
Type:Lab/Research institutions
inquiryBest quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia
Cas:5470-70-2
Min.Order:0
Negotiable
Type:Manufacturers
inquiryOur Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We
Cas:5470-70-2
Min.Order:10 Kilogram
Negotiable
Type:Trading Company
inquiryAppearance:white or light yellow crystalline powder Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Used for research and industrial manufacture. Transportation:By
Cas:5470-70-2
Min.Order:100 Gram
Negotiable
Type:Lab/Research institutions
inquiryCompany Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments
Cas:5470-70-2
Min.Order:1 Gram
Negotiable
Type:Lab/Research institutions
inquiryJ&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia
Cas:5470-70-2
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiryA substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc
Cas:5470-70-2
Min.Order:4 Kilogram
Negotiable
Type:Lab/Research institutions
inquiryWhy Choose Us: 1. Factory direct sales, so we can provide the competitive price and high quality product base on 8 years of production and R&D experience. 2. It is available in stock for quick shipment.Products could be packaged according to cu
5-(methoxycarbonyl)-2-methylpyridine 1-oxide
Methyl 6-methylnicotinate
Conditions | Yield |
---|---|
With indium; cobalt(II) chloride In methanol at 20℃; for 2h; sonication; | 80% |
Conditions | Yield |
---|---|
With sulfuric acid for 17h; Reflux; | 75% |
With sulfuric acid for 21h; Heating; Yield given; | |
With sulfuryl dichloride |
Conditions | Yield |
---|---|
In benzene for 5h; Heating; | 41% |
1,3-DIOXOLANE
methyl 3-pyridinecarboxylate
A
Methyl 6-methylnicotinate
B
Methyl 4,6-Dimethylnicotinate
Conditions | Yield |
---|---|
With sulfuric acid for 7h; Irradiation; | A 21% B 5% |
(+/-)-(E)-methyl 3-(but-3-yn-2-yloxy)acrylate
N-methoxylamine hydrochloride
Methyl 6-methylnicotinate
Conditions | Yield |
---|---|
With sodium acetate In ethanol at 150℃; for 3h; Inert atmosphere; Microwave irradiation; | 14% |
methanol
methyl 3-pyridinecarboxylate
A
4-methylnicotinic acid methyl ester
B
Methyl 6-methylnicotinate
C
2-methoxynicotinic acid methyl ester
D
6-methoxy-nicotinic acid methyl ester
Conditions | Yield |
---|---|
With sulfuric acid for 1h; Product distribution; Mechanism; Irradiation; effect of additives; variation of temp., acid concn.; further alcohol; | A 7.1% B 9.5% C 8.8% D 3.8% |
With sulfuric acid for 1h; Irradiation; | A 7.1% B 9.5% C 8.8% D 3.8% |
With sulfuric acid at 32℃; for 0.833333h; Product distribution; Mechanism; Irradiation; var. reagent, acid concentration and time; |
Conditions | Yield |
---|---|
In dichloromethane Ambient temperature; | |
With triethylamine for 3h; |
methyl 3-pyridinecarboxylate
methylmagnesium chloride
phenyl chloroformate
A
4-methylnicotinic acid methyl ester
B
Methyl 6-methylnicotinate
Conditions | Yield |
---|---|
With sulfur Yield given. Multistep reaction; | |
With sulfur Yield given. Multistep reaction; |
Methyl 6-methylnicotinate
Conditions | Yield |
---|---|
With hydrogenchloride |
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: SOCl2 / 2 h / Heating 2: CH2Cl2 / Ambient temperature View Scheme | |
Multi-step reaction with 2 steps 1: oxalyl dichloride; N,N-dimethyl-formamide / dichloromethane / 3 h / 0 - 20 °C / Inert atmosphere 2: triethylamine / 3 h View Scheme |
6-methylnicotinic acid
sodium hydrogencarbonate
Methyl 6-methylnicotinate
Conditions | Yield |
---|---|
In methanol |
Conditions | Yield |
---|---|
With oxygen; potassium carbonate at 60℃; under 750.075 Torr; for 24h; Schlenk technique; Green chemistry; | 92%Chromat. |
Conditions | Yield |
---|---|
With sulfuric acid; nitric acid at 150℃; |
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: fluorosulfonyl fluoride; triethylamine / dichloromethane / 24 h / 20 °C / 760.05 Torr 2: bis(triphenylphosphine)nickel(II) chloride; 2.9-dimethyl-1,10-phenanthroline; manganese / N,N-dimethyl-formamide / 20 h / 20 °C / 760.05 Torr / Schlenk technique; Inert atmosphere; Glovebox 3: methanol View Scheme |
diazomethane
6-methylnicotinic acid
Methyl 6-methylnicotinate
Conditions | Yield |
---|---|
In methanol | 54.2 mg |
Methyl 6-methylnicotinate
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: bis(triphenylphosphine)nickel(II) chloride; 2.9-dimethyl-1,10-phenanthroline; manganese / N,N-dimethyl-formamide / 20 h / 20 °C / 760.05 Torr / Schlenk technique; Inert atmosphere; Glovebox 2: methanol View Scheme |
Methyl 6-methylnicotinate
6-methyl-3-pyridinemethanol
Conditions | Yield |
---|---|
With lithium aluminium tetrahydride In tetrahydrofuran at -5 - 23℃; for 2h; | 100% |
With lithium aluminium tetrahydride In tetrahydrofuran at 0℃; for 3h; | 98% |
Stage #1: Methyl 6-methylnicotinate With lithium aluminium tetrahydride In diethyl ether at 55℃; for 1.5h; Heating / reflux; Stage #2: With water In diethyl ether at 0℃; for 1h; | 97% |
Methyl 6-methylnicotinate
5-(methoxycarbonyl)-2-methylpyridine 1-oxide
Conditions | Yield |
---|---|
With 3-chloro-benzenecarboperoxoic acid In dichloromethane at 20℃; Inert atmosphere; | 100% |
With dihydrogen peroxide; sodium tungstate In water at 60 - 80℃; for 5.66667h; | 98% |
Stage #1: Methyl 6-methylnicotinate With dihydrogen peroxide; methyltrioxorhenium(VII) In dichloromethane; water at 24℃; for 6h; Stage #2: manganese(IV) oxide In dichloromethane; water | 91% |
Methyl 6-methylnicotinate
methyl 6-methylpiperidine-3-carboxylate.hydrochloride
Conditions | Yield |
---|---|
With hydrogenchloride; hydrogen; palladium 10% on activated carbon In methanol; water at 80℃; under 3102.97 Torr; for 21h; | 100% |
With hydrogenchloride; palladium 10% on activated carbon; hydrogen In methanol at 75℃; under 2844.39 Torr; | 100% |
Conditions | Yield |
---|---|
100% |
Methyl 6-methylnicotinate
6-methyl-3-piperidinecarboxylic acid methyl ester
Conditions | Yield |
---|---|
With hydrogenchloride; hydrogen; 1% Pd/C In methanol; water at 80℃; under 3102.97 Torr; for 21h; Inert atmosphere; | 100% |
With hydrogenchloride; platinum(IV) oxide; hydrogen In methanol; water at 50℃; under 2585.81 Torr; for 15h; | 96.15% |
With hydrogenchloride; hydrogen; palladium 10% on activated carbon In methanol; water under 2534.09 Torr; for 24h; |
Conditions | Yield |
---|---|
With platinum(IV) oxide; hydrogen at 60℃; under 7500.75 Torr; Autoclave; | 100% |
Methyl 6-methylnicotinate
6-methylpyridine-3-carbohydrazide
Conditions | Yield |
---|---|
With hydrazine In methanol at 20℃; for 2h; | 98% |
With hydrazine hydrate In ethanol for 2h; Reflux; | 90% |
With hydrazine hydrate In ethanol at 20℃; for 2h; | 90% |
Methyl 6-methylnicotinate
sodium tungstate (VI) dihydrate
5-(methoxycarbonyl)-2-methylpyridine 1-oxide
Conditions | Yield |
---|---|
With dihydrogen peroxide In methanol; water | 98% |
Conditions | Yield |
---|---|
With 1,3-di-tert-butyl-2-(neopentyloxy)-2,3-dihydro-1H-1,3,2-diazaphosphole In diethyl ether at 20℃; for 12h; | 96% |
Methyl 6-methylnicotinate
N,0-dimethylhydroxylamine
N-methoxy-N-methyl-6-methylnicotinamide
Conditions | Yield |
---|---|
With isopropylmagnesium chloride In tetrahydrofuran at -10 - 5℃; for 2.5h; | 94.3% |
With isopropylmagnesium chloride In tetrahydrofuran; toluene at -10℃; for 0.5h; |
Methyl 6-methylnicotinate
1-bromoacetone
methyl 2-methyl-indolizine-6-carboxylate
Conditions | Yield |
---|---|
Stage #1: Methyl 6-methylnicotinate; 1-bromoacetone In acetone Heating; Stage #2: With sodium carbonate In ethanol for 3h; Heating; | 93% |
Conditions | Yield |
---|---|
With ammonia In ethanol at 80℃; for 72h; | 91% |
With ammonia; water at 20℃; for 4h; | 72% |
Methyl 6-methylnicotinate
1-(6-methyl-3-pyridinyl)-2-[4-(methyl sulfide)phenyl]ethanone
Conditions | Yield |
---|---|
With tert-butylmagnesium chloride In tetrahydrofuran at 65 - 70℃; for 1h; Reagent/catalyst; Temperature; | 87.7% |
Methyl 6-methylnicotinate
trifluoromethylsulfonic anhydride
triphenylphosphine
Conditions | Yield |
---|---|
Stage #1: Methyl 6-methylnicotinate; trifluoromethylsulfonic anhydride In dichloromethane at -78℃; for 1h; Inert atmosphere; Stage #2: triphenylphosphine With 1,8-diazabicyclo[5.4.0]undec-7-ene In dichloromethane at -78 - 20℃; | 83% |
at -78 - 20℃; Alkaline conditions; | 83% |
Conditions | Yield |
---|---|
With Ethyl 2-mercaptopropionate; (4,4'-di-tert-butyl-2,2'-dipyridyl)-bis-(2-phenylpyridine(-1H))-iridium(III) hexafluorophosphate; toluene-4-sulfonic acid In dimethyl sulfoxide at 23℃; UV-irradiation; | 82% |
Methyl 6-methylnicotinate
isoxazolidine hydrochloride
Conditions | Yield |
---|---|
With isopropylmagnesium chloride In tetrahydrofuran; toluene at -20 - -10℃; for 0.5h; Reagent/catalyst; Inert atmosphere; | 80% |
Conditions | Yield |
---|---|
With lithium hexamethyldisilazane In tetrahydrofuran at 20℃; | 80% |
Methyl 6-methylnicotinate
methylmagnesium chloride
2-(6-methylpyridin-3-yl)propan-2-ol
Conditions | Yield |
---|---|
In tetrahydrofuran at -78℃; for 12h; | 80% |
Methyl 6-methylnicotinate
1-(6-methyl-3-pyridinyl)-2-[4-(methyl sulfide)phenyl]ethanone
Conditions | Yield |
---|---|
With tert-butylmagnesium chloride In tetrahydrofuran at 65 - 70℃; for 1h; | 78.5% |
Methyl 6-methylnicotinate
lithium (4-methylsulfonylphenyl)acetate
A
1-(6-methylpyridin-3-yl)-2-({4-[2-(6-methylpyridin-3-yl)-2-oxoethyl]phenyl}sulfonyl)ethanone
B
1-(6-methyl-3-pyridinyl)-2-[4-(methylsulfonyl)phenyl]ethanone
Conditions | Yield |
---|---|
With tert-butylmagnesium chloride In tetrahydrofuran at 65 - 70℃; for 1.5h; | A n/a B 78% |
Methyl 6-methylnicotinate
ethyl acetate
ethyl 3-(2-methyl-5-pyridinyl)-3-oxopropanoate
Conditions | Yield |
---|---|
With lithium hexamethyldisilazane In tetrahydrofuran at -50℃; for 0.5h; | 76% |
With sodium hydride In N,N-dimethyl-formamide; toluene at 80℃; for 2.5h; |
Conditions | Yield |
---|---|
With zinc(II) chloride In acetic anhydride at 140℃; for 12h; | 76% |
Methyl 6-methylnicotinate
Conditions | Yield |
---|---|
at 120℃; for 4h; | 75.9% |
Methyl 6-methylnicotinate
methyl 6-(dibromomethyl)pyridine-3-carboxylate
Conditions | Yield |
---|---|
With N-Bromosuccinimide; dibenzoyl peroxide In tetrachloromethane Heating; | 75% |
With N-Bromosuccinimide; dibenzoyl peroxide In tetrachloromethane Heating; | 75% |
With N-Bromosuccinimide; dibenzoyl peroxide In tetrachloromethane Heating / reflux; | 19.4% |
Methyl 6-methylnicotinate
4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane
methyl 1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-6-methyl-1,2-dihydropyridine-3-carboxylate
Conditions | Yield |
---|---|
With chloro(1,5-cyclooctadiene)rhodium(I) dimer; tricyclohexylphosphine In benzene-d6 at 50℃; for 24h; Inert atmosphere; regioselective reaction; | 75% |
With P(C6H11)3; chloro(1,5-cyclooctadiene)rhodium(I) dimer In benzene-d6 ligand reacted with pinacolborane in C6D6 at 50°C for 24 h in presence of (Rh(C8H12)Cl)2 and P(C6H11)3; distilled; | 75% |
Conditions | Yield |
---|---|
With piperidine; acetic acid In toluene for 72h; Knoevenagel reaction; Heating; | 74% |
glyoxylic acid ethyl ester
Methyl 6-methylnicotinate
(E)-methyl 6-(3-ethoxy-3-oxoprop-1-en-1-yl)nicotinate
Conditions | Yield |
---|---|
In acetic anhydride at 130℃; for 48h; | 73% |
With acetic anhydride at 130℃; for 48h; Reflux; | 73% |
In acetic anhydride at 130℃; for 48h; | 73% |
With acetic anhydride at 130℃; for 48h; | 57 g |
Methyl 6-methylnicotinate
2-(4-(methylthio)phenyl)acetic acid
1-(6-methyl-3-pyridinyl)-2-[4-(methyl sulfide)phenyl]ethanone
Conditions | Yield |
---|---|
With tert-butylmagnesium chloride In tetrahydrofuran at 65 - 70℃; for 1h; | 72% |
Stage #1: 2-(4-(methylthio)phenyl)acetic acid With tert-butylmagnesium chloride In tetrahydrofuran at 60℃; for 1h; Flow reactor; Stage #2: Methyl 6-methylnicotinate In tetrahydrofuran at 60℃; for 1h; Flow reactor; Stage #3: With hydrogenchloride In water; toluene Temperature; Flow reactor; |
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