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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

(R)-(+)-Limonene Manufacturer/High quality/Best price/In stock

Cas:5989-27-5

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality D-Limonene supplier in China

Cas:5989-27-5

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Hangzhou Dingyan Chem Co., Ltd

Items Standard Result Assay (Ursolic acid) 98%min 98.22% ----------------------------------------------------------------

High purity 5989-27-5 D-limonene

Cas:5989-27-5

Min.Order:1 Gram

FOB Price: $100.0 / 500.0

Type:Trading Company

inquiry

Hebei yanxi chemical co.,LTD.

Hebei yanxi chemical co., LTD is a professional research, development and production of lead acetate benzene acetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low carb

Top quality d-Limonene with reasonable price on sale!!

Cas:5989-27-5

Min.Order:1 Kilogram

FOB Price: $1.0 / 3.0

Type:Manufacturers

inquiry

Wuhan Fortuna Chemical Co.,Ltd

Unique advantages for (+)-Dipentene Cas 5989-27-5 Guaranteed purity High quality & competitive price Quality control Fast feedback Prompt shipment Appearance:Colorless or light yellow transparent liquid Storage:Store in 2-8℃ Pack

Reliable supplier hot sale (+)-Dipentene Cas 5989-27-5 with high quality and low price

Cas:5989-27-5

Min.Order:180 Kilogram

FOB Price: $13.0 / 15.0

Type:Trading Company

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply (R)-p-mentha-1,8-diene

Cas:5989-27-5

Min.Order:1

Negotiable

Type:Other

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.

Cyclohexene,1-methyl-4-(1-methylethenyl)-, (4R)-,cas:5989-27-5

Cas:5989-27-5

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Antimex Chemical Limied

ProName: (R)-(+)-Limonene Manufacturer/High qua... CasNo: 5989-27-5 Molecular Formula: C10H16 Appearance: colorless oily liquid Application: It is an important raw material and in... DeliveryTime: prompt PackAge: accordin

(R)-(+)-LiMonene

Cas:5989-27-5

Min.Order:1 Metric Ton

FOB Price: $3.6

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

1)quick response within 12 hours; 2)quality guarantee: all products are strictly tested by our qc, confirmed by qa and approved by third party lab in china, usa, canada, germany, uk, italy, france etc. 3) oem/odm available; 4) rea

(+)-DipenteneCAS NO.:5989-27-5

Cas:5989-27-5

Min.Order:1 Gram

FOB Price: $1.0 / 2.0

Type:Lab/Research institutions

inquiry

Lonwin Chemical Group Limited

(+)-Dipentene CAS:5989-27-5 Specification Items Specification Result Assay ≥95% 95.02% Apperance Colorless or light yellow transp

Factory supply (+)-Dipentene

Cas:5989-27-5

Min.Order:1 Kilogram

FOB Price: $100.0 / 150.0

Type:Other

inquiry

Changchun Artel lmport and Export trade company

Price, service, company and transport advantage: 1.place of origin china with super quality by reasonable price. 2. it's customers' right to choose the package (ems, dhl, fedex, ups); 3. it's custo

BEST PRICE/(R)-(+)-Limonene

Cas:5989-27-5

Min.Order:10 Gram

Negotiable

Type:Trading Company

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

(+)-Dipentene

Cas:5989-27-5

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

D(+)-Limonene

Cas:5989-27-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

(R)-(+)-Limone

Cas:5989-27-5

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality D-Limonene

Cas:5989-27-5

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:colourless liquid Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:25kg/drum, or as per your request. Application:Used as Pharmaceutical Intermediat

Cyclohexene,1-methyl-4-(1-methylethenyl)-, (4R)-

Cas:5989-27-5

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

(R)-(+)-Limonene

Cas:5989-27-5

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

D-LiMonene

Cas:5989-27-5

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

(+)-Dipentene

Cas:5989-27-5

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard

factory supply CAS 5989-27-5 with competitive price

Cas:5989-27-5

Min.Order:1 Kilogram

FOB Price: $112.0

Type:Trading Company

inquiry

Xiamen AmoyChem Co.,Ltd

Amoychem is committed to providing the top-quality chemical products and services Internationally. We offer our customers with friendly, professional service and reliable, high performance products that have been manufactured according to the accredi

D-Limonene

Cas:5989-27-5

Min.Order:0

Negotiable

Type:Other

inquiry

Hubei Langyou International Trading Co., Ltd

(R)-(+)-Limonene CAS NO.5989-27-5 Application:(R)-(+)-Limonene CAS NO.5989-27-5

(R)-(+)-Limonene CAS NO.5989-27-5

Cas:5989-27-5

Min.Order:0

Negotiable

Type:Other

inquiry

Luyunjia Chemistry Xiamen Limited

Xiamen Luyunjia Trading Co.,Ltd Package:1kg/bag; 2689kg/drum, or as customer's request. Application:Xiamen Luyunjia Trading Co.,Ltd Transportation:DHL, EMS, FedEx, TNT, AIR, SEA Port:Beijing,Shanghai,Guangzhou ,China main port

d-limonene

Cas:5989-27-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou ZeErRui Chemical Co., Ltd.

Hangzhou ZeErRui Chemical Co., Ltd. located in Lingang industrial areas, our plant covers an area of 6000 square meters.ZeErRui dedicated to the development, production and marketing of chemicals. We have earned ourselves a good reputation at home an

(+)-Dipentene manufacture

Cas:5989-27-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hunan Longxianng Runhui Trading Co.,Ltd

(R)-(+)-Limonene CAS NO.5989-27-5Appearance:ask jude for details Storage:Dry and ventilated Package:in foil bag or customized Application:Pharmaceutical intermediates/Food additive Transportation:By express (Door to door) such as FEDEX, DHL, EMS for

(R)-(+)-Limonene CAS NO.5989-27-5

Cas:5989-27-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Jiangxi LinQ Spices Co.,Ltd.

Raw material ,higher purity, support by origional factory, fully large stock [Physical/Chemical Property] Melting Point -75-73°C Specific optical rotation 112o (10% IN ETHANOL) Boiling point 176-177°C (lit.) Density 0

(+)-Dipentene

Cas:5989-27-5

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Selena Zhou

D-Limonene: is a monoterpene found to prevent mammary cancer by activating hepatic glutathione-S-transferase (GST) and uridine diphosphoglucuronosyl transferase (UGT). D-Limonene is an isoprenylation inhibitor of small G-proteins. Servic

D-Limonene

Cas:5989-27-5

Min.Order:1 Metric Ton

FOB Price: $7000.0 / 7200.0

Type:Trading Company

inquiry

Salus Nutra Inc

Xi’an Salus Nutra Inc Established in 2015 and located in Hi-Tech industrial Zone in xi’an city, which is the most advanced area in northwest china . Salus Nutra is a professional company specialized in natural plant extracts, collagen a

D-limonene

Cas:5989-27-5

Min.Order:1 Kilogram

FOB Price: $60.0 / 80.0

Type:Trading Company

inquiry

SuZhou LaiTeou

1, Quality: Our company is a professional production of intermediates and chemicals for many years, our products have exported to Germany, Spain, UK, USA, Australia, Middle East, and so on other country, and we have got very good feedback fro

(R)-(+)-Limonene

Cas:5989-27-5

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Beijing Top Science biological technology co., LTD

Best service,high quality and reasonable price,COA 1.High quality : the purity is 99% min . through multiple producing procedures. 2.Competitive price : low price because of our skilled production technolpgy ,save the production cost

(+)-Dipentene

Cas:5989-27-5

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

Phosphoric acid diethyl ester (R)-5-isopropenyl-2-methyl-cyclohex-1-enyl ester

Phosphoric acid diethyl ester (R)-5-isopropenyl-2-methyl-cyclohex-1-enyl ester

D-limonene
5989-27-5

D-limonene

Conditions
ConditionsYield
With ammonia; lithium80%
L-carveol
308363-12-4

L-carveol

D-limonene
5989-27-5

D-limonene

Conditions
ConditionsYield
With 2-nitrobenzenesulfonyl hydrazide; triphenylphosphine; diethylazodicarboxylate In various solvent(s) -30 deg, 1 h; 23 deg C 30 min;78%
(+)-trans-carveol
2102-58-1

(+)-trans-carveol

D-limonene
5989-27-5

D-limonene

Conditions
ConditionsYield
With triethylsilane; lithium perchlorate In diethyl ether for 16h; Ambient temperature;68%
1-[2-((R)-4-Methyl-cyclohex-3-enyl)-prop-2-ene-1-sulfonyl]-propan-2-one

1-[2-((R)-4-Methyl-cyclohex-3-enyl)-prop-2-ene-1-sulfonyl]-propan-2-one

D-limonene
5989-27-5

D-limonene

Conditions
ConditionsYield
With aluminum amalgam In tetrahydrofuran; water at 20℃; for 4h;58%
C16H27BO2

C16H27BO2

D-limonene
5989-27-5

D-limonene

Conditions
ConditionsYield
With acetic acid at 120℃;22%
(+)-α-pinene
7785-70-8

(+)-α-pinene

D-limonene
5989-27-5

D-limonene

Conditions
ConditionsYield
With fired clay at 25℃;
With fired clay; acetic anhydride; acetic acid at 10℃;
With fired clay; acetic anhydride; acetic acid at 25℃;
2,4,6-Trinitrophenol
88-89-1

2,4,6-Trinitrophenol

benzene
71-43-2

benzene

A

D-limonene
5989-27-5

D-limonene

B

bornyl-picryl ether

bornyl-picryl ether

C

(+)-camphene
79-92-5

(+)-camphene

D

limonene.
138-86-3

limonene.

Conditions
ConditionsYield
at 120℃; d-α-pinene;
2-Benzoylbenzoic acid
85-52-9

2-Benzoylbenzoic acid

(+)-α-pinene
7785-70-8

(+)-α-pinene

D-limonene
5989-27-5

D-limonene

Conditions
ConditionsYield
at 140℃;
2-Benzoylbenzoic acid
85-52-9

2-Benzoylbenzoic acid

(1R,5R)-(+)-β-pinene
127-91-3

(1R,5R)-(+)-β-pinene

D-limonene
5989-27-5

D-limonene

Conditions
ConditionsYield
at 140℃;
(R)-(+)-binaphthol mononeryl ether
86851-45-8

(R)-(+)-binaphthol mononeryl ether

A

Terpinolene
586-62-9

Terpinolene

B

D-limonene
5989-27-5

D-limonene

C

(-)-(S)-limonene
5989-54-8

(-)-(S)-limonene

Conditions
ConditionsYield
With trifluorormethanesulfonic acid; tri-tert-butylphenol; diisobutylaluminium hydride 2.) 3 h, -130 deg C, CCl3F; Yield given. Multistep reaction. Yields of byproduct given;
(R)-(+)-binaphthol mononeryl ether
86851-45-8

(R)-(+)-binaphthol mononeryl ether

A

D-limonene
5989-27-5

D-limonene

B

(-)-(S)-limonene
5989-54-8

(-)-(S)-limonene

Conditions
ConditionsYield
With (2,4,6-tri-tert-butylphenoxy)-isobutylaluminium trifluormethanesulfonate In trichlorofluoromethane at -130℃; for 3h; further reagents; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
(-)-{1-(R)-[(1E)-2-methylbuta-1,3-dienyloxy]ethyl}benzene
130814-75-4

(-)-{1-(R)-[(1E)-2-methylbuta-1,3-dienyloxy]ethyl}benzene

isoprene
78-79-5

isoprene

A

D-limonene
5989-27-5

D-limonene

B

(-)-trans-carveol
18383-51-2

(-)-trans-carveol

C

(+)-trans-carveol
2102-58-1

(+)-trans-carveol

D

(-)-(S)-limonene
5989-54-8

(-)-(S)-limonene

Conditions
ConditionsYield
at 50℃; under 135011 Torr; for 60h; Product distribution; other conditions; other 1-(1-arylalkoxy)-2-methyl-1,3-butadienes; enantioselectivity of the reaction;
[(S)-2,2-Dimethyl-1-((E)-2-methyl-buta-1,3-dienyloxy)-propyl]-benzene
136476-14-7

[(S)-2,2-Dimethyl-1-((E)-2-methyl-buta-1,3-dienyloxy)-propyl]-benzene

isoprene
78-79-5

isoprene

A

D-limonene
5989-27-5

D-limonene

B

(-)-trans-carveol
18383-51-2

(-)-trans-carveol

C

(+)-trans-carveol
2102-58-1

(+)-trans-carveol

D

(-)-(S)-limonene
5989-54-8

(-)-(S)-limonene

Conditions
ConditionsYield
at 50℃; under 135011 Torr; for 60h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
[(R)-2,2-Dimethyl-1-((E)-2-methyl-buta-1,3-dienyloxy)-propyl]-benzene
175522-76-6

[(R)-2,2-Dimethyl-1-((E)-2-methyl-buta-1,3-dienyloxy)-propyl]-benzene

isoprene
78-79-5

isoprene

A

D-limonene
5989-27-5

D-limonene

B

(-)-trans-carveol
18383-51-2

(-)-trans-carveol

C

(+)-trans-carveol
2102-58-1

(+)-trans-carveol

D

(-)-(S)-limonene
5989-54-8

(-)-(S)-limonene

Conditions
ConditionsYield
at 50℃; under 135011 Torr; for 60h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
[(S)-2-Methyl-1-((E)-2-methyl-buta-1,3-dienyloxy)-propyl]-benzene
136476-12-5

[(S)-2-Methyl-1-((E)-2-methyl-buta-1,3-dienyloxy)-propyl]-benzene

isoprene
78-79-5

isoprene

A

D-limonene
5989-27-5

D-limonene

B

(-)-trans-carveol
18383-51-2

(-)-trans-carveol

C

(+)-trans-carveol
2102-58-1

(+)-trans-carveol

D

(-)-(S)-limonene
5989-54-8

(-)-(S)-limonene

Conditions
ConditionsYield
at 50℃; under 135011 Torr; for 60h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
Benzyl-methyl-[2-((R)-4-methyl-cyclohex-3-enyl)-propyl]-amine

Benzyl-methyl-[2-((R)-4-methyl-cyclohex-3-enyl)-propyl]-amine

D-limonene
5989-27-5

D-limonene

Conditions
ConditionsYield
With dihydrogen peroxide In tert-butyl alcohol 1.) 25 deg C, 110 h, 2.) 150 deg C, 1 torr, 1 h; Yield given;
methanol
67-56-1

methanol

(1R,4R,5R)-4,7,7-trimethyl-6-thiabicyclo[3.2.1]octane
5718-75-2

(1R,4R,5R)-4,7,7-trimethyl-6-thiabicyclo[3.2.1]octane

Raney nickel

Raney nickel

A

trans-1,4-menthane
1678-82-6

trans-1,4-menthane

B

cis-1-isopropyl-4-methyl-cyclohexane
6069-98-3

cis-1-isopropyl-4-methyl-cyclohexane

C

D-limonene
5989-27-5

D-limonene

D

(+)-p-menth-1-ene
1195-31-9

(+)-p-menth-1-ene

linalool
126-91-0

linalool

Japanese acid earth

Japanese acid earth

A

7-methyl-3-methene-1,6-octadiene
123-35-3

7-methyl-3-methene-1,6-octadiene

B

Geraniol
106-24-1

Geraniol

C

terpineol
98-55-5

terpineol

D

D-limonene
5989-27-5

D-limonene

Conditions
ConditionsYield
at 159℃;
formic acid
64-18-6

formic acid

A

Terpinolene
586-62-9

Terpinolene

B

D-limonene
5989-27-5

D-limonene

C

limonene.
138-86-3

limonene.

D

terpinene

terpinene

Conditions
ConditionsYield
d-α-pinene;
diethyl ether
60-29-7

diethyl ether

1,2,8,9-tetrabromo-p-menthane
4764-54-9

1,2,8,9-tetrabromo-p-menthane

iodine
7553-56-2

iodine

magnesium

magnesium

D-limonene
5989-27-5

D-limonene

Conditions
ConditionsYield
at 0℃; d-limonene tetrabromide;
ethanol
64-17-5

ethanol

1,2,8,9-tetrabromo-p-menthane
4764-54-9

1,2,8,9-tetrabromo-p-menthane

zinc dust

zinc dust

D-limonene
5989-27-5

D-limonene

Conditions
ConditionsYield
d-limonene tetrabromide;
(+)-α-pinene
7785-70-8

(+)-α-pinene

aluminium silicate

aluminium silicate

A

D-limonene
5989-27-5

D-limonene

B

(+)-camphene
79-92-5

(+)-camphene

Conditions
ConditionsYield
Mechanism;
(+)-α-pinene
7785-70-8

(+)-α-pinene

titanic acid

titanic acid

A

D-limonene
5989-27-5

D-limonene

B

(+)-camphene
79-92-5

(+)-camphene

Conditions
ConditionsYield
Mechanism;
(+)-α-pinene
7785-70-8

(+)-α-pinene

acetic acid
64-19-7

acetic acid

fired clay

fired clay

A

terpineol
98-55-5

terpineol

B

D-limonene
5989-27-5

D-limonene

rac-endo-borneol
6627-72-1

rac-endo-borneol

D

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol
507-70-0

1,7,7-trimethyl bicyclo[2.2.1]heptan-2-ol

Conditions
ConditionsYield
at 30℃; anschl. Verseifen;
(+)-α-pinene
7785-70-8

(+)-α-pinene

fired clay

fired clay

A

D-limonene
5989-27-5

D-limonene

B

(+)-camphene
79-92-5

(+)-camphene

C

limonene.
138-86-3

limonene.

Conditions
ConditionsYield
at 10℃;
(1S)-endo-fenchylamine
131348-01-1

(1S)-endo-fenchylamine

acetic acid
64-19-7

acetic acid

sodium nitrite

sodium nitrite

A

D-limonene
5989-27-5

D-limonene

B

α-fenchene
116724-26-6

α-fenchene

C

(+)-cyclofenchene
488-97-1

(+)-cyclofenchene

D

(-)-ξ-fenchene

(-)-ξ-fenchene

Conditions
ConditionsYield
Produkt 5: (+)-α-Terpineol, Produkt 6: (-)-α-Fenchol, Produkt 7: (-)-β-Fenchol und Produkt 8: (-)-α-Fenchenhydrat;
phthalic acid mono-((R)-p-menth-1-en-8-yl ester)

phthalic acid mono-((R)-p-menth-1-en-8-yl ester)

aqueous NaOH-solution

aqueous NaOH-solution

A

D-limonene
5989-27-5

D-limonene

B

d-α-terpineol

d-α-terpineol

Conditions
ConditionsYield
bei der Wasserdampfdestillation;
α-terpinyl chloride
39864-10-3

α-terpinyl chloride

A

Terpinolene
586-62-9

Terpinolene

B

D-limonene
5989-27-5

D-limonene

C

(-)-(S)-limonene
5989-54-8

(-)-(S)-limonene

Conditions
ConditionsYield
With 2,4,6-trimethyl-pyridine for 8h; Heating; Title compound not separated from byproducts;
2-Benzyloxy-2'-((Z)-3,7-dimethyl-octa-2,6-dienyloxy)-[1,1']binaphthalenyl

2-Benzyloxy-2'-((Z)-3,7-dimethyl-octa-2,6-dienyloxy)-[1,1']binaphthalenyl

A

1-methyl-4-isopropyl-1,3-cyclohexadiene
99-86-5

1-methyl-4-isopropyl-1,3-cyclohexadiene

B

α-terpinyl chloride
39864-10-3

α-terpinyl chloride

C

D-limonene
5989-27-5

D-limonene

D

(-)-(S)-limonene
5989-54-8

(-)-(S)-limonene

Conditions
ConditionsYield
With tin(IV) chloride In various solvent(s) at -78℃; for 12h; Product distribution; Further Variations:; Solvents; Reagents; Temperatures; time;
2'-((Z)-3,7-Dimethyl-octa-2,6-dienyloxy)-2-(4-trifluoromethyl-benzyloxy)-[1,1']binaphthalenyl

2'-((Z)-3,7-Dimethyl-octa-2,6-dienyloxy)-2-(4-trifluoromethyl-benzyloxy)-[1,1']binaphthalenyl

A

α-terpinyl chloride
39864-10-3

α-terpinyl chloride

B

D-limonene
5989-27-5

D-limonene

C

(-)-(S)-limonene
5989-54-8

(-)-(S)-limonene

Conditions
ConditionsYield
With tin(ll) chloride In dichloromethane at -97℃; for 6h; Product distribution; Further Variations:; Solvents; Temperatures; time;
D-limonene
5989-27-5

D-limonene

(+)-p-menth-1-ene
1195-31-9

(+)-p-menth-1-ene

Conditions
ConditionsYield
With iron(III) chloride; lithium aluminium tetrahydride; hydrogen In tetrahydrofuran at 18℃; under 7500.75 Torr; for 20h; Inert atmosphere; Sealed tube;100%
With ethanol; lithium; nickel dichloride; 4,4'-di-tert-butylbiphenyl In tetrahydrofuran at 20℃; for 22h;99%
With platinum(IV) oxide; hydrogen under 775.743 Torr; regioselective reaction;99%
D-limonene
5989-27-5

D-limonene

(4R)-limonene 1,2-epoxide
1195-92-2

(4R)-limonene 1,2-epoxide

Conditions
ConditionsYield
With urea hydrogen peroxide adduct; methyltrioxorhenium(VII) In dichloromethane at 20℃; for 0.5h;99%
With tert.-butylhydroperoxide In decane at 55℃; for 3h; in air; regioselective reaction;95%
With C15H34N(1+)*H2O4P(1-); Tri(dodecyltrimethylammonium) dodecatungstophosphate; dihydrogen peroxide In water; toluene at 65℃; for 6h; Inert atmosphere;95%
D-limonene
5989-27-5

D-limonene

C37H48N2O4S3

C37H48N2O4S3

C47H64N2O4S3

C47H64N2O4S3

Conditions
ConditionsYield
With fac-tris(2-phenylpyridinato-N,C2')iridium(III) In toluene at 20℃; for 36h; Sealed tube; Irradiation; Inert atmosphere;99%
D-limonene
5989-27-5

D-limonene

cis-(R)-limonene oxide
4680-24-4

cis-(R)-limonene oxide

Conditions
ConditionsYield
With dihydrogen peroxide; polystyrene; {2-(aminomethyl)pyridine}methyl(trioxo)rhenium(VII) In dichloromethane; water; acetonitrile at -10℃; for 2h;98%
With dihydrogen peroxide; divinylbenzene cross-linked poly(4-vinylpyridine); methyltrioxorhenium(VII) In dichloromethane; water; acetonitrile at 25℃; for 1.5h;89%
Multi-step reaction with 2 steps
1: bis[(4R)-2(4-Et-3,4-dihydro-2-oxazolyl)phenolato-N,O]O(O2)Mo; aq. tert-butyl hydroperoxide / toluene / 22 h / 20 °C
2: (μ-O)[MoO2(NCS)-2-(3,4-dihydro-4-MeOMe-oxazolyl-Ph)Py-N,N]2; aq. tert-butyl hydroperoxide / toluene / 22 h / 20 °C
View Scheme
D-limonene
5989-27-5

D-limonene

(R)-5-Isopropenyl-2-methylene-cyclohexyl-hydroperoxide

(R)-5-Isopropenyl-2-methylene-cyclohexyl-hydroperoxide

Conditions
ConditionsYield
With zeolite NaY; oxygen Irradiation; photooxygenation;97%
D-limonene
5989-27-5

D-limonene

diphenylsilane
775-12-2

diphenylsilane

(2-((R)-4-methylcyclohex-3-en-1-yl)propyl)diphenylsilane

(2-((R)-4-methylcyclohex-3-en-1-yl)propyl)diphenylsilane

Conditions
ConditionsYield
Stage #1: diphenylsilane With [(2-dicyclohexylphosphinocyclopentene-1-(2,6-dimethylphenyl)imine)Ni(allyl)]OTf In benzene-d6 at 20℃; for 0.0833333h; Inert atmosphere; Glovebox;
Stage #2: D-limonene In benzene-d6 at 20℃; for 12h; Inert atmosphere; Sealed tube;
97%
With [N,N'-(1,2-dimethyl-1,2-ethanediylidene)bis[3-(diphenylphosphino)-1-propanamine]]Ni In benzene-d6 at 70℃; for 168h; Inert atmosphere;76%
D-limonene
5989-27-5

D-limonene

phenylsilane
694-53-1

phenylsilane

(4R)-1-methyl-4-[(1R,S)-1-methyl-2-(phenylsilyl)ethyl]cyclohex-1-ene

(4R)-1-methyl-4-[(1R,S)-1-methyl-2-(phenylsilyl)ethyl]cyclohex-1-ene

Conditions
ConditionsYield
With n-butyllithium; 2,6-bis-[1-(2,6-diethylphenylimino)ethyl]pyridine iron(II) chloride In hexane; toluene at 20℃; for 1h; Inert atmosphere; regioselective reaction;96%
Stage #1: phenylsilane With (C5Me5)(iPr2MeP)H2FeH(N2); trityl tetrakis(pentafluorophenyl)borate In fluorobenzene at -35 - 20℃;
Stage #2: D-limonene In fluorobenzene at 20℃; for 20h; regioselective reaction;
92%
yttrium(pentamethylcyclopentadienyl)2CH(trimethylsilyl)2 In benzene for 96h; Ambient temperature;61%
(η5-C5Me4(i)Pr)2YMe*THF for 96h; Product distribution; Ambient temperature; other catalysts;
With [(2,6-iPr2PhBDI)Mn(μ-H)]2 In benzene-d6 at 130℃; for 144h; Inert atmosphere;
D-limonene
5989-27-5

D-limonene

A

(R)-8,9-limonene oxide
184488-93-5

(R)-8,9-limonene oxide

(1RS,2SR,4R)-limonene-1,2-epoxide
203719-54-4

(1RS,2SR,4R)-limonene-1,2-epoxide

Conditions
ConditionsYield
With 1H-imidazole; dihydrogen peroxide; sodium N-dodecanoyl-L-proplinate; Mn[5-(4-C6H4CO-(N-L-proline))-10,15,20-Ph3-porphyrinyl]Cl In ethanol; water at 25℃; for 0.166667h; Product distribution; Further Variations:; Catalysts; Reagents;A n/a
B 95%
D-limonene
5989-27-5

D-limonene

1-Chloro-4-(1-chloro-1-methyl-ethyl)-1-methyl-cyclohexane
4497-96-5

1-Chloro-4-(1-chloro-1-methyl-ethyl)-1-methyl-cyclohexane

Conditions
ConditionsYield
With acetyl chloride In ethanol at 30℃; for 0.166667h; Markovnikov hydrochlorination;95%
Multi-step reaction with 2 steps
1: 250 - 270 °C
2: diethyl ether; hydrogen chloride
View Scheme
D-limonene
5989-27-5

D-limonene

A

trans-1,4-menthane
1678-82-6

trans-1,4-menthane

B

cis-1-isopropyl-4-methyl-cyclohexane
6069-98-3

cis-1-isopropyl-4-methyl-cyclohexane

C

(+)-p-menth-1-ene
1195-31-9

(+)-p-menth-1-ene

Conditions
ConditionsYield
With hydrogen; 2 In neat (no solvent)A 2%
B 4%
C 94%
With ruthenium; hydrogen at 30℃; under 900.09 Torr; Reagent/catalyst;
morpholine
110-91-8

morpholine

carbon monoxide
201230-82-2

carbon monoxide

D-limonene
5989-27-5

D-limonene

4-[3-((R)-4-Methyl-cyclohex-3-enyl)-butyl]-morpholine

4-[3-((R)-4-Methyl-cyclohex-3-enyl)-butyl]-morpholine

Conditions
ConditionsYield
With hydrogen; chloro(1,5-cyclooctadiene)rhodium(I) dimer In acetonitrile at 80℃; under 60004.8 Torr; for 20h;93%
Stage #1: morpholine; carbon monoxide; D-limonene With carbonylhydridetris(triphenylphosphine)rhodium(I); hydrogen In tetrahydrofuran at 100℃; Autoclave;
Stage #2: With hydrogen In tetrahydrofuran at 100℃; under 30003 Torr; Autoclave;
79%
D-limonene
5989-27-5

D-limonene

(1S,2R,4R)-1-methyl-4-(prop-1-en-2-yl)cyclohexane-1,2-diol
59121-74-3

(1S,2R,4R)-1-methyl-4-(prop-1-en-2-yl)cyclohexane-1,2-diol

Conditions
ConditionsYield
With oxygen; potassium carbonate In water at 25℃; under 1551.49 Torr; for 72h; enantioselective reaction;92%
D-limonene
5989-27-5

D-limonene

2-bromo-1-hydroxy-p-menth-8-ene
506422-90-8

2-bromo-1-hydroxy-p-menth-8-ene

Conditions
ConditionsYield
With N-Bromosuccinimide In water; acetone at 10℃;91%
D-limonene
5989-27-5

D-limonene

(1S,4R)-2-chloro-4-(1-methylvinyl)-1-methylcyclohexanol
521925-06-4

(1S,4R)-2-chloro-4-(1-methylvinyl)-1-methylcyclohexanol

Conditions
ConditionsYield
With sodium hypochlorite; water; copper(II) acetate monohydrate In 1,2-dichloro-ethane at 60℃; for 9h; Temperature; Solvent;90.2%
D-limonene
5989-27-5

D-limonene

p-menth-1-ene
61585-35-1

p-menth-1-ene

Conditions
ConditionsYield
With hydrogen; platinum on activated charcoal pressure of 60 lb/sq in. to 43.5 lb/sq in.;90%
With copper at 200℃; inactive substances;
With hydrogen; platinum dihydrolimonene;
With sodium tetrahydroborate In methanol at 20℃; Catalytic behavior; Reagent/catalyst; Inert atmosphere;
D-limonene
5989-27-5

D-limonene

4-isopropenyl-1-methylcyclohexane
6252-33-1

4-isopropenyl-1-methylcyclohexane

Conditions
ConditionsYield
Stage #1: D-limonene With 9-bora-bicyclo[3.3.1]nonane In tetrahydrofuran at 0 - 25℃; for 2.5h; Inert atmosphere;
Stage #2: With palladium 10% on activated carbon; hydrogen In tetrahydrofuran under 760.051 Torr; Inert atmosphere;
Stage #3: With 2-methyl-2-nitrosopropane dimer In tetrahydrofuran for 0.75h; regioselective reaction;
90%
ethanol
64-17-5

ethanol

carbon monoxide
201230-82-2

carbon monoxide

D-limonene
5989-27-5

D-limonene

A

(Ξ)-3-((R)-4-methyl-cyclohex-3-enyl)-butyraldehyde diethylacetal

(Ξ)-3-((R)-4-methyl-cyclohex-3-enyl)-butyraldehyde diethylacetal

B

3-(4-methylcyclohex-3-enyl)butanal
199445-85-7

3-(4-methylcyclohex-3-enyl)butanal

Conditions
ConditionsYield
With methoxy(cyclooctadiene)rhodium(I) dimer; tri(o-t-butylphenyl)phosphite; hydrogen at 80℃; under 60804.1 Torr; for 4h; Inert atmosphere; Autoclave;A 90%
B n/a
D-limonene
5989-27-5

D-limonene

(2RS)-2-<(1R)-4-methylcyclohex-3-enyl>propanol
287720-47-2

(2RS)-2-<(1R)-4-methylcyclohex-3-enyl>propanol

Conditions
ConditionsYield
Stage #1: D-limonene With PS-9-BBN In tetrahydrofuran at 40℃; for 24h;
Stage #2: With tetra(n-butyl)ammonium hydroxide; dihydrogen peroxide In tetrahydrofuran; methanol at 0 - 50℃; for 4h;
89%
Stage #1: D-limonene With 9-bora-bicyclo[3.3.1]nonane at 20℃; Inert atmosphere;
Stage #2: With dihydrogen peroxide; sodium hydroxide In ethanol at 50℃; for 2h;
89.6%
Stage #1: D-limonene With 9-bora-bicyclo[3.3.1]nonane In tetrahydrofuran at 20℃; for 2h;
Stage #2: With sodium hydroxide; dihydrogen peroxide In tetrahydrofuran; water temp. < 10 deg C;
Stage #3: In tetrahydrofuran; water at 40℃; for 2h;
80%
D-limonene
5989-27-5

D-limonene

4-methylisopropylbenzene
99-87-6

4-methylisopropylbenzene

Conditions
ConditionsYield
With palladium 10% on activated carbon at 140℃; for 1h;89%
With iodine; 2,3-dicyano-5,6-dichloro-p-benzoquinone In toluene for 0.75h; Reflux;82%
With dodecane; hydrogen at 300℃; under 11251.1 Torr; for 2h; Catalytic behavior; Temperature; Autoclave; Inert atmosphere;57%
piperazine
110-85-0

piperazine

carbon monoxide
201230-82-2

carbon monoxide

D-limonene
5989-27-5

D-limonene

C15H28N2
1098145-03-9

C15H28N2

Conditions
ConditionsYield
Stage #1: piperazine; carbon monoxide; D-limonene With carbonylhydridetris(triphenylphosphine)rhodium(I); hydrogen In tetrahydrofuran at 100℃; Autoclave;
Stage #2: With hydrogen In tetrahydrofuran at 100℃; under 30003 Torr; Autoclave;
89%
D-limonene
5989-27-5

D-limonene

(1S,2S,4R)-2-bromo-1-methyl-4-(prop-1-en-2-yl)cyclohexanol

(1S,2S,4R)-2-bromo-1-methyl-4-(prop-1-en-2-yl)cyclohexanol

Conditions
ConditionsYield
With sodium hypobromide; copper(II) acetate monohydrate In water; 1,2-dichloro-ethane at 80℃; for 6h; Reagent/catalyst; Temperature;88.3%
With N-Bromosuccinimide; water In acetone at 0 - 5℃;85%
With N-Bromosuccinimide; water In acetone at 0 - 25℃; for 1h; Large scale; chemoselective reaction;
With N-Bromosuccinimide In water; acetone at 0 - 25℃; for 1h;
With N-Bromosuccinimide In water; acetone at 0℃; for 0.666667h; Inert atmosphere; Schlenk technique; Glovebox;
Conditions
ConditionsYield
With 2,4,4,6-Tetrabromo-2,5-cyclohexadien-1-one; cetyltrimethylammonim bromide In dichloromethane; chloroform87%
D-limonene
5989-27-5

D-limonene

(R)-4-methyl-3-(3'-oxobutyl)pent-4-enal
7086-79-5, 85031-77-2, 127288-10-2, 136521-14-7

(R)-4-methyl-3-(3'-oxobutyl)pent-4-enal

Conditions
ConditionsYield
Stage #1: D-limonene With pyridine; ozone In methanol at -50℃; for 12h; Inert atmosphere;
Stage #2: With dimethylsulfide In methanol at -50℃;
86%
Stage #1: D-limonene With oxygen; ozone In methanol; dichloromethane at -70℃;
Stage #2: With dimethylsulfide at 20℃; for 5h;
70%
Stage #1: D-limonene With ozone In methanol; dichloromethane at -70℃;
Stage #2: With dimethylsulfide In methanol; dichloromethane at 20℃; for 5h;
70%
D-limonene
5989-27-5

D-limonene

1,3-cylohexanedione
504-02-9

1,3-cylohexanedione

(1'R,2RS)-2-methyl-2-(4'-methylcyclohex-3'-enyl)-2,3,5,6,7-pentahydrobenzo[1,2-b]furan-4-one

(1'R,2RS)-2-methyl-2-(4'-methylcyclohex-3'-enyl)-2,3,5,6,7-pentahydrobenzo[1,2-b]furan-4-one

Conditions
ConditionsYield
With manganese triacetate; acetic acid at 70℃; for 2h;86%
D-limonene
5989-27-5

D-limonene

acetylacetone
123-54-6

acetylacetone

(1'R,5RS)-3-acetyl-2,5-dimethyl-5-(4'-methylcyclohex-3'-enyl)-4,5-dihydrofuran

(1'R,5RS)-3-acetyl-2,5-dimethyl-5-(4'-methylcyclohex-3'-enyl)-4,5-dihydrofuran

Conditions
ConditionsYield
With manganese triacetate; acetic acid at 70℃; for 1.5h;86%
D-limonene
5989-27-5

D-limonene

1-phenylbutan-1,3-dione
93-91-4

1-phenylbutan-1,3-dione

[2,5-Dimethyl-5-((R)-4-methyl-cyclohex-3-enyl)-4,5-dihydro-furan-3-yl]-phenyl-methanone

[2,5-Dimethyl-5-((R)-4-methyl-cyclohex-3-enyl)-4,5-dihydro-furan-3-yl]-phenyl-methanone

Conditions
ConditionsYield
With manganese triacetate; acetic acid at 70℃; for 1.5h;86%
Conditions
ConditionsYield
With platinum(IV) oxide; hydrogen at 20℃; under 760.051 Torr; Overall yield = 16 g;A n/a
B 85%
With (bis-1,2-diphenylphosphinoethane)Co(CH2SiMe3)2; hydrogen In benzene at 25℃; under 3040.2 Torr; for 6h; Time;A 55%
B 42%
With hydrogen; platinum(IV) oxide In methanol under 760 Torr; below 20 deg C; Yield given. Yields of byproduct given;
With platinum(IV) oxide; hydrogen In ethanol at 20℃; under 760.051 Torr; for 5.4h;
D-limonene
5989-27-5

D-limonene

(R)-8,9-limonene oxide
184488-93-5

(R)-8,9-limonene oxide

Conditions
ConditionsYield
With perchloric acid; dihydrogen peroxide In water; acetonitrile; tert-butyl alcohol at 60℃; for 0.166667h; stereoselective reaction;85%
With fluorapatite; dihydrogen peroxide; tris(cetylpyridinium) 12-tungstophosphate In water at 25℃; for 14h;61%
With tert.-butylhydroperoxide In water; acetonitrile at 70℃; for 24h;35%
D-limonene
5989-27-5

D-limonene

O,O-diisopropyl hydrogen phosphorodithioate
107-56-2

O,O-diisopropyl hydrogen phosphorodithioate

O,O-diisopropyl S-[1-methyl-1-(4-methylcyclohex-3-en-1-yl)ethyl]dithiophosphate

O,O-diisopropyl S-[1-methyl-1-(4-methylcyclohex-3-en-1-yl)ethyl]dithiophosphate

Conditions
ConditionsYield
With zinc(II) chloride at 20℃; for 2h;85%
With zinc(II) chloride at 20℃; Inert atmosphere;85%
With zinc(II) chloride
propylamine
107-10-8

propylamine

carbon monoxide
201230-82-2

carbon monoxide

D-limonene
5989-27-5

D-limonene

C14H27N
1098144-84-3

C14H27N

Conditions
ConditionsYield
Stage #1: propylamine; carbon monoxide; D-limonene With carbonylhydridetris(triphenylphosphine)rhodium(I); hydrogen In tetrahydrofuran at 100℃; Autoclave;
Stage #2: With hydrogen In tetrahydrofuran at 100℃; under 30003 Torr; Autoclave;
85%
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