Conditions | Yield |
---|---|
With iron; trimethyl orthoformate at 100℃; under 1500.15 Torr; for 1h; | 98.1% |
With iron(III) chloride; phosphoric acid tributyl ester; iron at 110℃; under 5931.67 Torr; Reagent/catalyst; Pressure; Flow reactor; Large scale; | 96% |
iron(III) chloride; triethyl phosphate; iron at 110 - 134℃; under 1875.19 - 6000.6 Torr; Autoclave; Inert atmosphere; | 91% |
Conditions | Yield |
---|---|
With benzene; dibenzoyl peroxide at 70℃; under 20594.2 Torr; |
Conditions | Yield |
---|---|
beim Chlorieren; zunaechst im Sonnenlicht in der Dampfphase, dann in fluessiger Phase unter Kuehlung; |
tetrachloromethane
ethene
A
1,1,1,5-tetrachloropentane
B
1,1,5-trichloro-pent-1-ene
C
1,1,1,3-tetrachloropropane
D
1,1,1,3-tetrachlorobutane
Conditions | Yield |
---|---|
With diethyl amine hydrochloride; 2-hydroxy-2-phenylacetophenone; iron(III) chloride In isopropyl alcohol Further byproducts given; |
tetrachloromethane
ethene
A
1,1,1,5-tetrachloropentane
B
1,1,5-trichloro-pent-1-ene
C
1,1,1,3-tetrachloropropane
D
1,3,5-trichloro-2-pentene
Conditions | Yield |
---|---|
With diethyl amine hydrochloride; 2-hydroxy-2-phenylacetophenone In isopropyl alcohol Further byproducts given; |
tetrachloromethane
ethene
A
1,1,1,5-tetrachloropentane
B
1,1,1,3-tetrachloropropane
C
1,1,1,3-tetrachlorobutane
D
1,3,3,5-tetrachloropentane
Conditions | Yield |
---|---|
With 2-hydroxy-2-phenylacetophenone; diethylamine; iron(III) chloride In isopropyl alcohol Further byproducts given; |
tetrachloromethane
ethene
A
1,1,1,5-tetrachloropentane
B
1,1,1,3-tetrachloropropane
C
1,3,3,5-tetrachloropentane
D
1,3,5-trichloro-2-pentene
Conditions | Yield |
---|---|
With diethyl amine hydrochloride; 2-hydroxy-2-phenylacetophenone; iron(III) chloride Further byproducts given; |
tetrachloromethane
propene
ethene
A
1,1,1,5-tetrachloropentane
B
1,1,1,5-tetrachloro-3-methylhexane
C
1,1,1,3-tetrachloropropane
D
1,1,1,3-tetrachlorobutane
E
1,1,1,7-tetrachloroheptane
F
1,1,1,7-tetrachloro-3,5-dimethyl-octane
Conditions | Yield |
---|---|
With dibenzoyl peroxide at 90℃; for 3h; Product distribution; variation of the reactant ratio; |
tetrachloromethane
ethene
A
1,1,1,5-tetrachloropentane
B
1,1,1,3-tetrachloropropane
Conditions | Yield |
---|---|
FeIIFe2IIICl8(CH3CN)6 In N,N-dimethyl acetamide; acetonitrile at 130℃; under 15200 Torr; for 4h; Product distribution; Mechanism; other concentrations of CH3CN, DMA; other catalyst; | A 1.6 % Turnov. B 98.4 % Turnov. |
FeIIFe2IIICl8(CH3CN)6 In N,N-dimethyl acetamide; acetonitrile at 130℃; under 15200 Torr; for 4h; | A 1.6 % Turnov. B 98.4 % Turnov. |
tetrachloromethane
ethene
A
1,1,1,5-tetrachloropentane
B
1,1,1,3-tetrachloropropane
C
1,1,1,7-tetrachloroheptane
D
1,1,1,9-tetrachloro-nonane
E
1,1,1,11-tetrachloro-undecane
Conditions | Yield |
---|---|
With chromium(0) hexacarbonyl at 120℃; Product distribution; relative rate of telomerization initiated by Cr(CO)6 and further initiator; partial chain-transfer constants; |
tetrachloromethane
ethene
A
1,1,1,5-tetrachloropentane
B
1,1,1,3-tetrachloropropane
C
1,1,1,7-tetrachloroheptane
D
1,3,3,5-tetrachloropentane
Conditions | Yield |
---|---|
With dimanganese decacarbonyl; isopropyl alcohol at 120℃; for 2h; Product distribution; other reagents, reagents ratios; |
tetrachloromethane
3,3,3-trichloro-propyl
A
trichloromethyl radical
B
1,1,1,3-tetrachloropropane
Conditions | Yield |
---|---|
at 39.9℃; Rate constant; |
chloroform
1,3,3,3-tetrachloro-propyl
A
trichloromethyl radical
B
1,1,1,3-tetrachloropropane
Conditions | Yield |
---|---|
at 21.9℃; Rate constant; |
Conditions | Yield |
---|---|
With tetrachloromethane at 40℃; Rate constant; |
tetrachloromethane
acetyl propionyl peroxide
A
methylene chloride
B
methane
C
chloroethane
D
1,1,1,3-tetrachloropropane
E
acetic acid
F
ethyl acetate
Conditions | Yield |
---|---|
at 59.9 - 99.9℃; for 150h; Product distribution; Kinetics; Rate constant; |
tetrachloromethane
ethene
water
dibenzoyl peroxide
A
1,1,1,5-tetrachloropentane
B
1,1,1,3-tetrachloropropane
C
1,1,1,7-tetrachloroheptane
D
1,1,1,9-tetrachloro-nonane
Conditions | Yield |
---|---|
at 95℃; under 73550.8 Torr; | |
at 95℃; under 73550.8 Torr; bei der Reaktion koennen Explosionen auftreten; | |
at 95℃; under 73550.8 Torr; analoge Reaktionen mit Propen, Octen-(1) und Hexadien-(2.5) bezw. mit Vinylacetat; | |
at 95℃; under 73550.8 Torr; | |
at 95℃; under 73550.8 Torr; analoge Reaktionen mit Propen, Octen-(1) und Hexadien-(2.5) bezw. mit Vinylacetat; |
tetrachloromethane
2,2'-azobis(isobutyronitrile)
ethene
A
1,1,1,3-tetrachloropropane
Conditions | Yield |
---|---|
at 90 - 110℃; under 73550.8 - 110326 Torr; |
tetrachloromethane
ethene
dibenzoyl peroxide
A
1,1,1,3-tetrachloropropane
Conditions | Yield |
---|---|
at 90 - 95℃; unter Druck; |
Conditions | Yield |
---|---|
at 95 - 100℃; under 58840.6 Torr; |
tetrachloromethane
acetyl propionyl peroxide
A
methylene chloride
B
chloroethane
C
1,1,1,3-tetrachloropropane
D
1-chloroethyl acetate
E
acetic acid
F
ethyl acetate
Conditions | Yield |
---|---|
at 69.9℃; Product distribution; other temperature; thermolysis and photolysis in CCl4 and or in MeOH+CCl4 at different temperatures; lifetime of acyloxy radicals produces by decomposition of APP; decarboxylation rate constants of acyloxy radicals; |
tetrachloromethane
ethene
A
1,1,2,2-tetrachloroethylene
B
1,1,1,3-tetrachloropropane
C
3,3,3-trichloro-1-propene
D
hexachloroethane
Conditions | Yield |
---|---|
In tetrachloromethane other Radiation; γ-radiation of C2H4 in CCl4;; yields given;; |
tetraethyltin
A
chloroethane
B
1,1,1,3-tetrachloropropane
C
hexachloroethane
D
dichlorodiethylstannane
Conditions | Yield |
---|---|
With tetrachloromethane byproducts: C4H10, C2H6, C2H4; Irradiation (UV/VIS); for 120 h; further byproduct: CHCl3; |
Conditions | Yield |
---|---|
Stage #1: 1,1,1,3-tetrachloropropane With iron at 115℃; for 3h; Stage #2: With tetradecafluorohexane; fluorine at -60℃; Inert atmosphere; Stage #3: With hydrogen fluoride at 300℃; under 3000.3 Torr; Pressure; Temperature; Concentration; Reagent/catalyst; | 99.7% |
Stage #1: 1,1,1,3-tetrachloropropane With tetrabutylammomium bromide; sodium hydroxide In water at 32 - 35℃; under 760.051 Torr; for 17h; Stage #2: With fluorine In hydrogen fluoride at -60℃; under 760.051 Torr; Inert atmosphere; liquid HF; Stage #3: With hydrogen fluoride at 220 - 250℃; under 760.051 Torr; |
1,1,1,3-tetrachloropropane
1,1,1,2,3-pentachloro-propane
Conditions | Yield |
---|---|
Stage #1: 1,1,1,3-tetrachloropropane With iron(III) chloride at 85℃; under 1005.1 Torr; Industrial scale; Stage #2: With chlorine at 30℃; Temperature; Industrial scale; | 96% |
Stage #1: 1,1,1,3-tetrachloropropane With aluminum (III) chloride In N,N-dimethyl acetamide at 25℃; for 0.166667h; Stage #2: With chlorine In N,N-dimethyl acetamide at 25℃; for 1.5h; | 95% |
Stage #1: 1,1,1,3-tetrachloropropane With potassium hydroxide; Aliquat 336 In water at 80℃; for 3h; Stage #2: With chlorine at 0℃; for 3h; UV-irradiation; |
Conditions | Yield |
---|---|
With iron(II) chloride tetrahydrate at 90 - 100℃; | 95% |
With iron(II) chloride at 95℃; for 8h; | 95% |
at 450℃; |
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide at 130 - 150℃; for 6h; | 95% |
Conditions | Yield |
---|---|
With hydrogen fluoride at 225 - 250℃; | 90% |
With hydrogen fluoride; activated by HF amorphous Zn/chromia catalyst at 200℃; under 760.051 Torr; for 15h; Inert atmosphere; | 100 %Chromat. |
With hydrogen fluoride; activated by HF amorphous Zn/chromia catalyst at 200℃; under 760.051 Torr; for 15h; Inert atmosphere; | 100 %Chromat. |
1,1,1,3-tetrachloropropane
ethenyltrimethylsilane
A
Trimethyl-((Z)-1,3,5-trichloro-pent-3-enyl)-silane
B
Trimethyl-((Z)-1,3,5-trichloro-pent-2-enyl)-silane
C
Trimethyl-(1,3,3,5-tetrachloro-pentyl)-silane
Conditions | Yield |
---|---|
With iron pentacarbonyl; triphenylphosphine at 130℃; for 3h; further reagents DMFA, HMPTA, 2-propanol; Yield given. Yields of byproduct given. Title compound not separated from byproducts; | A n/a B n/a C 88% |
With iron pentacarbonyl; triphenylphosphine at 130℃; for 3h; further reagents DMFA, HMPTA, 2-propanol; Yields of byproduct given; | A n/a B n/a C 88% |
Conditions | Yield |
---|---|
With iron pentacarbonyl In N,N-dimethyl-formamide at 105℃; for 3h; | 85% |
With iron pentacarbonyl; N,N-dichloro-4-chlorobenzenesulfonamide In N,N,N,N,N,N-hexamethylphosphoric triamide at 105℃; |
1,1,1,3-tetrachloropropane
potassium propionate
3,3-Dichloroallylpropionate
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide at 130 - 150℃; for 6h; | 85% |
1,1,1,3-tetrachloropropane
A
1,1,1,2,3-pentachloro-propane
B
3,3-dichloroallyl chloride
C
1,1,2,3-Tetrachloropropene
Conditions | Yield |
---|---|
With iron(III) chloride; chlorine at 82℃; under 1277.21 Torr; for 15.33h; Product distribution / selectivity; | A 82.9% B 3.4% C 8.1% |
1,1,1,3-tetrachloropropane
1,1,3-trichloropropane
Conditions | Yield |
---|---|
With trans-Mo2(μ-N,N′-bis(4-methoxyphenyl)formamidinato-κ2N:N′)2(OOCCH3)2; 1-methyl-3,6-bis(trimethylsilyl)-1,4-cyclohexadiene; tetrabutyl-ammonium chloride In [D3]acetonitrile at 80℃; for 3h; Catalytic behavior; Reagent/catalyst; Solvent; | 73% |
With iron pentacarbonyl; cyclohexanol at 130 - 140℃; for 3.5h; Product distribution; further reagents, percent of conversion; | 60% |
With lithium aluminium tetrahydride; Trichlorbutylstannan In diethyl ether | |
With bis(cyclopentadienyl)dihydrozirconium In toluene at 20℃; further reagents; Yield given; | |
With trans-Mo2(μ-N,N′-bis(4-methoxyphenyl)formamidinato-κ2N:N′)2(OOCCH3)2; 1-methyl-3,6-bis(trimethylsilyl)-1,4-cyclohexadiene In [D3]acetonitrile at 80℃; for 3h; Kinetics; Catalytic behavior; Concentration; Reagent/catalyst; | 85 %Spectr. |
1,3-dioxolane-4-methanol
1,1,1,3-tetrachloropropane
4-(3,3,3-Trichloro-propoxymethyl)-[1,3]dioxolane
Conditions | Yield |
---|---|
With potassium hydroxide; 18-crown-6 ether for 4h; Ambient temperature; | 60% |
2-chloropropene
1,1,1,3-tetrachloropropane
1,3,3,5,5-pentachlorohexane
Conditions | Yield |
---|---|
N,N,N,N,N,N-hexamethylphosphoric triamide; iron pentacarbonyl at 130 - 135℃; for 2h; | 60% |
With trans-bisdinitrogenbis(1,2-diphenylphosphinoethane)molybdenum(0) In acetonitrile at 140℃; for 3h; further reagents Mo(CO)6, Mo(CO)5PPh3, cis-Mo(CO)4(PPh3)2, cis-Mo(CO)4(dppe), cis-Mo(CO)2(dppe)2, MoH4(dppe)2; | 75 % Chromat. |
Conditions | Yield |
---|---|
With antimonypentachloride; antimony(III) fluoride In 1,2-dichloro-ethane Ambient temperature; | 57% |
With antimony dichloride trifluoride; antimony(III) fluoride; 1,2-dichloro-ethane | |
With antimony dichloride trifluoride; dichloromethane; antimony(III) fluoride |
Conditions | Yield |
---|---|
iron pentacarbonyl; N,N-dimethyl-formamide at 105℃; for 3h; | 52% |
1,1,1,3-tetrachloropropane
A
1,1-difluoro-1,3-dichloropropane
B
1-fluoro-1,1,3-trichloropropane
C
1,1-Dichloro-1,3-difluoro-propane
Conditions | Yield |
---|---|
With bromine trifluoride; tin(IV) chloride In 1,1,2-Trichloro-1,2,2-trifluoroethane at 20 - 25℃; | A 11% B 51% C 10% |
Conditions | Yield |
---|---|
With sulfuric acid |
1,1,1,3-tetrachloropropane
1,3,3,4,4,6-hexachloro-hexane
Conditions | Yield |
---|---|
With water; iron |
1,1,1,3-tetrachloropropane
A
1,3,3,4,4,6-hexachloro-hexane
B
1,3,4,6-tetrachloro-hex-3-ene
Conditions | Yield |
---|---|
With ammonia; platinum Hydrogenation; |
1,1,1,3-tetrachloropropane
1,3,4,6-tetrachloro-hex-3t-ene
Conditions | Yield |
---|---|
With ammonia; platinum Hydrogenation; |
1,1,1,3-tetrachloropropane
A
3-chloro-1,1,1-trifluoropropane
B
1,1-difluoro-1,3-dichloropropane
Conditions | Yield |
---|---|
With antimony dichloride trifluoride; α,α,α-trifluorotoluene; antimony(III) fluoride |
1,1,1,3-tetrachloropropane
A
1,1,1,2,3-pentachloro-propane
B
1,1,1,3,3-pentachloropropane
Conditions | Yield |
---|---|
With chlorine at 100℃; Irradiation.mit UV-Licht; | |
With chlorine; triphenylbismuthane at 140 - 150℃; under 2585.81 Torr; for 2h; Sealed tube; Inert atmosphere; | |
With chlorine at 130 - 150℃; under 2585.81 Torr; for 2h; Sealed tube; Inert atmosphere; | |
With iron(III) chloride at 41.2℃; Temperature; Reagent/catalyst; |
1,1,1,3-tetrachloropropane
A
3,3-dichloroallyl chloride
B
3,3,3-trichloro-1-propene
Conditions | Yield |
---|---|
With 2-ethoxy-ethanol; potassium hydroxide at 80℃; | |
With potassium hydroxide at 0 - 5℃; | |
With potassium hydroxide; Aliquat 336 In water at 80℃; for 3h; |
1,1,1,3-tetrachloropropane
N-methylaniline
N-methyl-N-(3,3,3-trichloro-propyl)-aniline
Conditions | Yield |
---|---|
With antimonypentachloride |
IUPAC Name: 1,1,1,3-Tetrachloro-propane
The MF of 1,1,1,3-Tetrachloro-propane (CAS NO.1070-78-6) is C3H4Cl4.
The MW of 1,1,1,3-Tetrachloro-propane (CAS NO.1070-78-6) is 181.88.
Synonyms of 1,1,1,3-Tetrachloro-propane (CAS NO.1070-78-6): 1,1,1,3-Tetrachloro-propan ; Propane,1,1,1,3-tetrachloro- ; Tetrachloropropane
Index of Refraction: 1.482
EINECS: 213-981-7
Density: 1.471 g/ml
Flash Point: 51.4 °C
Boiling Point: 161.3 °C
Melting Point: -35 °C
1,1,1,3-Tetrachloro-propane (CAS NO.1070-78-6) is used for the preparation of three allyl chloride, trifluoro-propylene, also as solvent.
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
mouse | LDLo | oral | 1mL/kg (1mL/kg) | National Technical Information Service. Vol. OTS0520626, | |
rabbit | LD50 | skin | > 2mL/kg (2mL/kg) | National Technical Information Service. Vol. OTS0520626, | |
rat | LCLo | inhalation | 4700ppm/6H (4700ppm) | BEHAVIORAL: ATAXIA | National Technical Information Service. Vol. OTS0520625, |
rat | LD50 | oral | 490mg/kg (490mg/kg) | Office of Toxic Substances Report. Vol. OTS0515505, |
Reported in EPA TSCA Inventory.
Moderately toxic by ingestion. When heated to decomposition it emits toxic fumes of Cl−. See also CHLORINATED HYDROCARBONS, ALIPHATIC.Safety information of 1,1,1,3-Tetrachloro-propane (CAS NO.1070-78-6):
Hazard Codes Xi
RTECS TZ7000000
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