1-Chloro-1-fluoroethylene supplier

Name
1-Chloro-1-fluoroethylene
EINECS 219-027-6
CAS No. 2317-91-1
Article Data27
CAS DataBase
Density 1.098 g/cm³
Solubility negligible
Melting Point -169°C
Formula C₂H₂ClF
Boiling Point -24°C
Molecular Weight 80.4893
Flash Point
Transport Information
Appearance colourless gas
Safety 9-16-23
Risk Codes 11
Molecular Structure
Hazard Symbols F
Synonyms Ethylene,1-chloro-1-fluoro- (6CI,7CI,8CI);1-Chloro-1-fluoroethene;1-Chloro-1-fluoroethylene;1-Fluoro-1-chloroethylene;F 1131a;HCFC 1131a;R1131a;
PSA 0.00000
LogP 1.66590

Synthetic route

: 75-68-3
1-Chloro-1,1-difluoroethane

A: 420-46-2
2,2,2-trifluoroethanol

B: 2317-91-1
1-chloro-1-fluoroethane

Conditions

Conditions	Yield
With aluminum(III) fluoride at 325℃;
With aluminum(III) fluoride at 300 - 400℃;

: 811-95-0
1,1,2-trichloro-1-fluoroethane

: 2317-91-1
1-chloro-1-fluoroethane

Conditions

Conditions	Yield
With sodium amalgam; ethanol
With water; zinc
With chromium(III) oxide at -28.15℃;

: 463-97-8
1-bromo-2,2-dichloro-2-fluoroethane

: 2317-91-1
1-chloro-1-fluoroethane

Conditions

Conditions	Yield
With ethanol; zinc
With ethanol; zinc

: 430-57-9
1,2-dichloro-1-fluoroethane

A: 2268-31-7
cis-1-Chloro-2-fluoroethylene

B: 2268-32-8
trans-1-chloro-2-fluoroethylene

C: 2713-09-9
fluoroethyne

D: 593-63-5
chloroacetylene

E: 2317-91-1
1-chloro-1-fluoroethane

F: 74-86-2
acetylene

Conditions

Conditions	Yield
Mechanism; Irradiation;

...Expand

: 13245-54-0
1,2-dichlorofluoroethylene

A: 7572-29-4
dichloroethyne

B: 2268-31-7
cis-1-Chloro-2-fluoroethylene

C: 2713-09-9
fluoroethyne

D: 593-63-5
chloroacetylene

E: 2317-91-1
1-chloro-1-fluoroethane

F: 74-86-2
acetylene

Conditions

Conditions	Yield
Product distribution; infrared multiphoton decomposition;

...Expand

: 2834-23-3
chlorodifluoroacetic anhydride

: 74-88-4
methyl iodide

A: 116-14-3
polytetrafluoroethylene

B: 75-68-3
1-Chloro-1,1-difluoroethane

C: 75-38-7
Vinylidene fluoride

D: 2317-91-1
1-chloro-1-fluoroethane

E: 76-14-2
1,2-dichloro-1,1,2,2-tetrafluoroethane

F: 79-35-6
1,1'-dichloro-2,2'-difluoroethene

Conditions

Conditions	Yield
With mercury(I) iodide at 26.9℃; for 0.166667h; Rate constant; Thermodynamic data; Irradiation; E0, , var. pressure;

...Expand

: 67-66-3
chloroform

A: 354-58-5
1,1,1-Trichloro-2,2,2-trifluoroethane

B: 75-72-9
chlorotrifluoromethane

C: 2317-91-1
1-chloro-1-fluoroethane

D: 76-13-1
1,1,2-Trichloro-1,2,2-trifluoroethane

Conditions

Conditions	Yield
With fluorinated Co3O4 for 2h; Ambient temperature; Yields of byproduct given. Title compound not separated from byproducts;

...Expand

: 67-66-3
chloroform

A: 75-72-9
chlorotrifluoromethane

B: 75-69-4
trichlorofluoromethane

C: 2317-91-1
1-chloro-1-fluoroethane

Conditions

Conditions	Yield
With fluorinated Fe3O4 for 2h; Ambient temperature; Yields of byproduct given. Title compound not separated from byproducts;

...Expand

: 75-68-3
1-Chloro-1,1-difluoroethane

A: 420-46-2
2,2,2-trifluoroethanol

B: 75-38-7
Vinylidene fluoride

C: 2317-91-1
1-chloro-1-fluoroethane

D: 75-35-4
1,1-Dichloroethylene

E: 64-19-7
acetic acid

Conditions

Conditions	Yield
With hydrogen fluoride; fluorinated γ-alumina at 300℃; Product distribution; other temperatures; also with HCl as a reagent;

...Expand

: 1717-00-6
HCFC-141b

A: 420-46-2
2,2,2-trifluoroethanol

B: 75-68-3
1-Chloro-1,1-difluoroethane

C: 2317-91-1
1-chloro-1-fluoroethane

D: 75-35-4
1,1-Dichloroethylene

E: 64-19-7
acetic acid

Conditions

Conditions	Yield
fluorinated γ-alumina at 300℃; Product distribution; other temperatures; also with HCl or HF as reagents;

...Expand

: 79-51-6
1,1,3,3-tetrachloro-1,3-difluoro-2-propanone

: 67-64-1
acetone

A: 75-43-4
Dichlorofluoromethane

B: 1717-00-6
HCFC-141b

C: 75-69-4
trichlorofluoromethane

D: 2317-91-1
1-chloro-1-fluoroethane

E: 75-35-4
1,1-Dichloroethylene

F: 76-12-0
CFC-112a

Conditions

Conditions	Yield
With propene; sulphur hexafluoride for 0.5h; Rate constant; Ambient temperature; Irradiation; also with acetone-d6;

...Expand

: 64-17-5
ethanol

: 463-97-8
1-bromo-2,2-dichloro-2-fluoroethane

zinc: zinc

CuCl: CuCl

: 2317-91-1
1-chloro-1-fluoroethane

...Expand

: 75-68-3
1-Chloro-1,1-difluoroethane

aluminium fluoride: aluminium fluoride

A: 420-46-2
2,2,2-trifluoroethanol

B: 2317-91-1
1-chloro-1-fluoroethane

Conditions

Conditions	Yield
at 325℃;

...Expand

: 430-57-9
1,2-dichloro-1-fluoroethane

A: 156-59-2
cis-1,2-Dichloroethylene

B: 2268-31-7
cis-1-Chloro-2-fluoroethylene

C: 2268-32-8
trans-1-chloro-2-fluoroethylene

D: 2713-09-9
fluoroethyne

E: 593-63-5
chloroacetylene

F: 2317-91-1
1-chloro-1-fluoroethane

G HCl, HF: HCl, HF

Conditions

Conditions	Yield
under 30 Torr; Product distribution; Thermodynamic data; Mechanism; Irradiation; heats of reaction, influence of pressure, additive gas pressure, pulse number, pulse energy and pulse duration;	A .491 % Chromat. B 9.28 % Chromat. C 5.86 % Chromat. D .984 % Chromat. E 1.87 % Chromat. F 3.77 % Chromat. G n/a

...Expand

: 1717-00-6
HCFC-141b

: 2317-91-1
1-chloro-1-fluoroethane

Conditions

Conditions	Yield
at 336.85 - 426.85℃; under 14 - 120 Torr; Kinetics; Activation energy; Further Variations:; Reagents;

: 75-34-3
1,1-dichloroethane

A: 75-37-6
1,1-difluoroethane

B: 74-85-1
ethene

C: 1615-75-4
1-chloro-1-fluoroethane

D: 75-02-5
1-fluoroethylene

E: 75-01-4
chloroethylene

F: 2317-91-1
1-chloro-1-fluoroethane

G: 75-35-4
1,1-Dichloroethylene

Conditions

Conditions	Yield
With hydrogen fluoride at 200 - 250℃;

...Expand

: 111-34-2
-butyl vinyl ether

: 79-38-9
Chlorotrifluoroethylene

A: 75-38-7
Vinylidene fluoride

B: 2317-91-1
1-chloro-1-fluoroethane

C: butyl (2,2-difluorovinyl) ether

D: butyl (2-chloro-2-fluorovinyl) ether

Conditions

Conditions	Yield
With UmicoreM73SIPr In benzene-d6 at 60℃; for 1h; Inert atmosphere; Molecular sieve;
With bis[1,1-di(trifluoromethyl)ethoxy][(2,6-diisopropylphenyl)imino](2-methyl-2-phenylpropylidene)molybdenum In benzene-d6 at 60℃; for 1h; Reagent/catalyst; Inert atmosphere;

...Expand

: 75-68-3
1-Chloro-1,1-difluoroethane

A: 75-38-7
Vinylidene fluoride

B: 2317-91-1
1-chloro-1-fluoroethane

Conditions

Conditions	Yield
With SrF2 calcined at 500 °C at 450℃; under 750.075 Torr; Temperature; Flow reactor; Inert atmosphere;

: 616-45-5
2-pyrrolidinon

: 2317-91-1
1-chloro-1-fluoroethane

: 1-(1-fluorovinyl)pyrrolidin-2-one

Conditions

Conditions	Yield
With tris-(dibenzylideneacetone)dipalladium(0); t-BuBrettPhos; caesium carbonate In 1,2-dimethoxyethane at -78 - 110℃; for 18h; Sealed tube;	98%

: 67-56-1
methanol

: 2317-91-1
1-chloro-1-fluoroethane

: 201230-82-2
carbon monoxide

: 2343-89-7
methyl 2-fluoroprop-2-enoate

Conditions

Conditions	Yield
With dichloro[ferrocene-1,1'-diylbis(diisopropylphosphine-P)]palladium(II); triethylamine at 100℃; under 5250.53 Torr; for 8h; Reagent/catalyst; Autoclave;	91.8%
With bis(tri-t-butylphosphine)palladium(0) at 100℃; for 18h; Reagent/catalyst; Time; Autoclave;	77.4%

...Expand

: 497-25-6
dimethylenecyclourethane

: 2317-91-1
1-chloro-1-fluoroethane

: 3-(1-fluorovinyl)oxazolidin-2-one

Conditions

Conditions	Yield
With tris-(dibenzylideneacetone)dipalladium(0); t-BuBrettPhos; caesium carbonate In 1,2-dimethoxyethane at -78 - 110℃; for 18h; Sealed tube;	91%

: 623-73-4
diazoacetic acid ethyl ester

dirhodium (II) tetrakis(N-(3,6-dichlorophthaloyl)-L-phenylalanine): dirhodium (II) tetrakis(N-(3,6-dichlorophthaloyl)-L-phenylalanine)

: 2317-91-1
1-chloro-1-fluoroethane

: 155051-93-7
2-chloro-2-fluorocyclopropanecarboxylic acid ethyl ester

Conditions

Conditions	Yield
In dichloromethane	86%

...Expand

: 480-91-1
oxisoindole

: 2317-91-1
1-chloro-1-fluoroethane

: 2-(1-fluorovinyl)isoindoline-1-one

Conditions

Conditions	Yield
With tris-(dibenzylideneacetone)dipalladium(0); t-BuBrettPhos; caesium carbonate In 1,2-dimethoxyethane at -78 - 110℃; for 18h;	76%

: 623-73-4
diazoacetic acid ethyl ester

tetrakis(N-benzyloxycarbonyl-L-proline) dirhodium: tetrakis(N-benzyloxycarbonyl-L-proline) dirhodium

: 2317-91-1
1-chloro-1-fluoroethane

: 177933-51-6
(1S,2S)-2-Fluorocyclopropanecarboxylic Acid Ethyl Ester

: 155051-93-7
2-chloro-2-fluorocyclopropanecarboxylic acid ethyl ester

Conditions

Conditions	Yield
In dichloromethane	73%

...Expand

: 623-73-4
diazoacetic acid ethyl ester

tetrakis[(-)-cis-2-benzamidecyclohexanecarboxylate] dirhodium: tetrakis[(-)-cis-2-benzamidecyclohexanecarboxylate] dirhodium

: 2317-91-1
1-chloro-1-fluoroethane

: 177933-51-6
(1S,2S)-2-Fluorocyclopropanecarboxylic Acid Ethyl Ester

: 155051-93-7
2-chloro-2-fluorocyclopropanecarboxylic acid ethyl ester

Conditions

Conditions	Yield
In dichloromethane	71%

...Expand

: 2317-91-1
1-chloro-1-fluoroethane

: C2H2BrClF6S

Conditions

Conditions	Yield
With pentafluorosulfanyl bromide at 25 - 50℃; for 144h;	51%

: 675-20-7
piperidin-2-one

: 2317-91-1
1-chloro-1-fluoroethane

: 1-(1-fluorovinyl)piperidin-2-one

Conditions

Conditions	Yield
With tris-(dibenzylideneacetone)dipalladium(0); t-BuBrettPhos; caesium carbonate In 1,2-dimethoxyethane at -78 - 110℃; for 18h; Sealed tube;	48%

: 88070-48-8
N-methylbenzamide

: 2317-91-1
1-chloro-1-fluoroethane

: N-(1-fluorovinyl)-N-methylbenzamide

Conditions

Conditions	Yield
With tris-(dibenzylideneacetone)dipalladium(0); t-BuBrettPhos; caesium carbonate In 1,2-dimethoxyethane at -78 - 110℃; for 18h; Sealed tube;	27%

: 2317-91-1
1-chloro-1-fluoroethane

: 354-61-0
1,2-dichloro-1,2,2-trifluoro-1-iodoethane

: 380-62-1
1,2,4-trichloro-1,1,2,4-tetrafluoro-4-iodo-butane

Conditions

Conditions	Yield
With dibenzoyl peroxide

: 2317-91-1
1-chloro-1-fluoroethane

: 3294-60-8
phenyl(tribromomethyl)mercury(II)

: 24071-57-6
1,1-Dibrom-2-chlor-2-fluor-cyclopropan

: 428-59-1
Hexafluoropropene oxide

: 2317-91-1
1-chloro-1-fluoroethane

: 51326-67-1
1,1,2-trifluoro-2-chlorocyclopropane

Conditions

Conditions	Yield
In gas at 195℃;

: 2317-91-1
1-chloro-1-fluoroethane

A: 2713-09-9
fluoroethyne

B: 593-63-5
chloroacetylene

Conditions

Conditions	Yield
under 0.5 Torr; Product distribution; Rate constant; Irradiation; effect of laser pulse energy;

: 2317-91-1
1-chloro-1-fluoroethane

: 144092-38-6
(difluoroamino)chlorofluoroacetonitrile

Conditions

Conditions	Yield
With potassium fluoride; tetrafluorohydrazine at 160℃; for 40h;

: 2317-91-1
1-chloro-1-fluoroethane

A: 420-46-2
2,2,2-trifluoroethanol

B: 75-68-3
1-Chloro-1,1-difluoroethane

C: 75-38-7
Vinylidene fluoride

D: 64-19-7
acetic acid

Conditions

Conditions	Yield
fluorinated γ-alumina at 300℃; Product distribution; other temperatures;

...Expand

: 2317-91-1
1-chloro-1-fluoroethane

A: 420-46-2
2,2,2-trifluoroethanol

B: 75-68-3
1-Chloro-1,1-difluoroethane

C: 75-38-7
Vinylidene fluoride

D: 75-35-4
1,1-Dichloroethylene

E: 64-19-7
acetic acid

Conditions

Conditions	Yield
With hydrogenchloride; fluorinated γ-alumina at 300℃; Product distribution; other temperatures;

...Expand

: 2317-91-1
1-chloro-1-fluoroethane

A: 75-35-4
1,1-Dichloroethylene

B: 64-19-7
acetic acid

Conditions

Conditions	Yield
With hydrogenchloride; fluorinated γ-alumina at 200℃; Product distribution; other temperatures;

1-Chloro-1-fluoroethylene Specification

The 1-Chloro-1-fluoroethylene with the CAS number 2317-91-1 is also called Ethene,1-chloro-1-fluoro- (9CI). Its EINECS registry number is 219-027-6. The molecular formula is C₂H₂ClF. This chemical is highly flammable. While using this chemical, you should be very cautious.

The properties of the chemical are: (1)ACD/LogP: 1.51; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 1.51; (4)ACD/LogD (pH 7.4): 1.51; (5)ACD/BCF (pH 5.5): 8.29; (6)ACD/BCF (pH 7.4): 8.29; (7)ACD/KOC (pH 5.5): 158.16; (8)ACD/KOC (pH 7.4): 158.16; (9)#H bond acceptors: 0; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 0; (12)Polar Surface Area: 0 Å²; (13)Index of Refraction: 1.353; (14)Molar Refractivity: 15.89 cm³; (15)Molar Volume: 73.2 cm³; (16)Polarizability: 6.3×10^-24cm³; (17)Surface Tension: 15.2 dyne/cm; (18)Enthalpy of Vaporization: 22.13 kJ/mol; (19)Vapour Pressure: 3720 mmHg at 25°C.

You can still convert the following datas into molecular structure:
(1)SMILES: Cl/C(F)=C
(2)InChI: InChI=1/C2H2ClF/c1-2(3)4/h1H2
(3)InChIKey: FPBWSPZHCJXUBL-UHFFFAOYAV

Product Name

1-Chloro-1-fluoroethylene

Synthetic route

1-Chloro-1-fluoroethylene Specification

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