Product Name

  • Name

    1-Hexadecene

  • EINECS 248-131-4
  • CAS No. 629-73-2
  • Article Data90
  • CAS DataBase
  • Density 0.779 g/cm3
  • Solubility
  • Melting Point 3-5 °C(lit.)
  • Formula C16H32
  • Boiling Point 284.8 °C at 760 mmHg
  • Molecular Weight 224.43
  • Flash Point 132.2 °C
  • Transport Information
  • Appearance clear colorless liquid
  • Safety 23-24/25
  • Risk Codes 38
  • Molecular Structure Molecular Structure of 629-73-2 (1-Hexadecene)
  • Hazard Symbols IrritantXi
  • Synonyms 1-Cetene;1-n-Hexadecene;Cetene;Dialen 16;LAO-C 16;Linealene 16;NSC 60602;NeoSolv6;Neodene 16;n-Hexadec-1-ene;a-Hexadecene;
  • PSA 0.00000
  • LogP 6.26360

Synthetic route

1-iodohexadecane
544-77-4

1-iodohexadecane

1-Hexadecene
629-73-2

1-Hexadecene

Conditions
ConditionsYield
With potassium tert-butylate In tetrahydrofuran at 20℃;96%
With sodium t-butanolate In water at 50℃; for 4h; Sealed tube; UV-irradiation;50 %Spectr.
pentadecyl bromide
629-72-1

pentadecyl bromide

trimethylsulphonium iodide
2181-42-2

trimethylsulphonium iodide

1-Hexadecene
629-73-2

1-Hexadecene

Conditions
ConditionsYield
With n-butyllithium; lithium iodide In tetrahydrofuran; hexane Ambient temperature;92%
2-pentadecyl-1,3-dioxolane
4360-57-0

2-pentadecyl-1,3-dioxolane

A

1-Hexadecene
629-73-2

1-Hexadecene

B

(1R,6S,7R)-7-(4-Chloro-phenyl)-bicyclo[4.1.0]heptane

(1R,6S,7R)-7-(4-Chloro-phenyl)-bicyclo[4.1.0]heptane

Conditions
ConditionsYield
With chloro-trimethyl-silane; mercury; zinc In diethyl ether for 17h; Heating; Yields of byproduct given;A 86%
B n/a
hexadec-1-yne
629-74-3

hexadec-1-yne

1-Hexadecene
629-73-2

1-Hexadecene

Conditions
ConditionsYield
With [CuCl(ClIPr)]; sodium t-butanolate; tert-butyl alcohol In tetrahydrofuran; hexane at 40℃; for 20h; Inert atmosphere; chemoselective reaction;86%
heptadecanoic acid
506-12-7

heptadecanoic acid

1-Hexadecene
629-73-2

1-Hexadecene

Conditions
ConditionsYield
With bis(triphenylphosphine)iridium(I) carbonyl chloride; acetic anhydride; potassium iodide at 160℃; for 5h; Inert atmosphere;84%
With carbon monoxide; 1,5-bis-(diphenylphosphino)pentane; acetic anhydride; potassium iodide; iron(II) chloride at 240℃; under 15201 Torr; for 3h;76%
1,2-dibromohexadecane
63758-87-2

1,2-dibromohexadecane

1-Hexadecene
629-73-2

1-Hexadecene

Conditions
ConditionsYield
With disodium telluride In ethanol Product distribution; Ambient temperature; study of the stereoselective debromination of various vicinal dibromoalkanes with sodium telluride, prepared from tellurium and Rongalite in aq. alkaline medium;82%
With bis(4-methoxyphenyl)telluride In benzene Product distribution; Irradiation;70 (unit not given)
hexadecanyl bromide
112-82-3

hexadecanyl bromide

B

1-Hexadecene
629-73-2

1-Hexadecene

Conditions
ConditionsYield
With bis(triphenylphosphine)nickel(II) chloride; n-butyllithium; 1,8-diazabicyclo[5.4.0]undec-7-ene; triphenylphosphine In tetrahydrofuran; hexane Ambient temperature;A 20%
B 77%
cetyladehyde dimethyl acetal
2791-29-9

cetyladehyde dimethyl acetal

A

1-Hexadecene
629-73-2

1-Hexadecene

B

(1R,6S,7R)-7-(4-Chloro-phenyl)-bicyclo[4.1.0]heptane

(1R,6S,7R)-7-(4-Chloro-phenyl)-bicyclo[4.1.0]heptane

Conditions
ConditionsYield
With chloro-trimethyl-silane; mercury; zinc In diethyl ether for 20h; Heating; Yields of byproduct given;A 62%
B n/a
1-iodohexadecane
544-77-4

1-iodohexadecane

A

Hexadecane
544-76-3

Hexadecane

B

1-Hexadecene
629-73-2

1-Hexadecene

C

n-dotriacontane
544-85-4

n-dotriacontane

Conditions
ConditionsYield
With tetrabutylammonium tetrafluoroborate In N,N-dimethyl-formamide Electrochemical reaction; Inert atmosphere;A 27%
B 42%
C 27%
1-Hexadecanol
36653-82-4

1-Hexadecanol

A

dihexadecyl sulfide
3312-77-4

dihexadecyl sulfide

B

16-mercaptohexadecanoate
2917-26-2

16-mercaptohexadecanoate

C

1-Hexadecene
629-73-2

1-Hexadecene

Conditions
ConditionsYield
With P, S at 171 - 180℃; for 6h; Product distribution;A 26.6%
B 24.5%
C 39.2%
heptadecanenitrile
5399-02-0

heptadecanenitrile

1-Hexadecene
629-73-2

1-Hexadecene

Conditions
ConditionsYield
With [1,1'-bis(diphenylphosphino)ferrocene]nickel(II) chloride; ethanol; potassium hexamethylsilazane In toluene at 150℃; for 8h; Inert atmosphere; Molecular sieve;35%
5,5-Dimethyl-2-pentadecyl-[1,3]dioxane

5,5-Dimethyl-2-pentadecyl-[1,3]dioxane

A

1-Hexadecene
629-73-2

1-Hexadecene

B

(1R,6S,7R)-7-(4-Chloro-phenyl)-bicyclo[4.1.0]heptane

(1R,6S,7R)-7-(4-Chloro-phenyl)-bicyclo[4.1.0]heptane

Conditions
ConditionsYield
With chloro-trimethyl-silane; mercury; zinc In diethyl ether for 60h; Heating; Yields of byproduct given;A 14%
B n/a
1,3-Propandiol-hexadecanal-acetal
17352-27-1

1,3-Propandiol-hexadecanal-acetal

A

1-Hexadecene
629-73-2

1-Hexadecene

B

(1R,6S,7R)-7-(4-Chloro-phenyl)-bicyclo[4.1.0]heptane

(1R,6S,7R)-7-(4-Chloro-phenyl)-bicyclo[4.1.0]heptane

Conditions
ConditionsYield
With chloro-trimethyl-silane; mercury; zinc In diethyl ether for 36h; Heating; Yields of byproduct given;A 6%
B n/a
2-ethoxy-1-bromo-hexadecane
412014-27-8

2-ethoxy-1-bromo-hexadecane

1-Hexadecene
629-73-2

1-Hexadecene

Conditions
ConditionsYield
With zinc; butan-1-ol
stearic acid-(1-methyl-pentadecyl ester)

stearic acid-(1-methyl-pentadecyl ester)

B

1-Hexadecene
629-73-2

1-Hexadecene

Conditions
ConditionsYield
under 300 Torr;
1-Hexadecanol
36653-82-4

1-Hexadecanol

1-Hexadecene
629-73-2

1-Hexadecene

Conditions
ConditionsYield
With aluminum oxide at 340 - 355℃; bei der Dehydratisierung entsteht wohl im Gemisch mit Isomeren;
With aluminum oxide at 340 - 355℃; bei der Dehydratisierung;
With phosphoric acid; pyrographite bei der Dehydratisierung;
1-Chlorohexadecan
4860-03-1

1-Chlorohexadecan

1-Hexadecene
629-73-2

1-Hexadecene

hexadecyl stearate
1190-63-2

hexadecyl stearate

A

1-Hexadecene
629-73-2

1-Hexadecene

B

stearic acid
57-11-4

stearic acid

Conditions
ConditionsYield
at 330 - 360℃; under 300 Torr;
hexadecyl acetate
629-70-9

hexadecyl acetate

acetic acid
64-19-7

acetic acid

1-Hexadecene
629-73-2

1-Hexadecene

Conditions
ConditionsYield
at 450 - 550℃;
tridecylmagnesium bromide
117711-00-9

tridecylmagnesium bromide

allyl bromide
106-95-6

allyl bromide

1-Hexadecene
629-73-2

1-Hexadecene

Conditions
ConditionsYield
With diethyl ether
hexadecan-2-ol
14852-31-4

hexadecan-2-ol

Stearoyl chloride
112-76-5

Stearoyl chloride

B

1-Hexadecene
629-73-2

1-Hexadecene

Conditions
ConditionsYield
folgenden thermischen Zersetzung bei 320grad und 300 mm;
hexadecanyl bromide
112-82-3

hexadecanyl bromide

1-Hexadecene
629-73-2

1-Hexadecene

Conditions
ConditionsYield
With anion-exchanger at 160℃; under 16 Torr;
Multi-step reaction with 2 steps
1: 36 percent / NaBH4 / ethanol / 8 h / Heating
2: 33 percent Chromat. / 30percent H2O2 / tetrahydrofuran / 2 h / 25 °C
View Scheme
nonadecan-2-one
629-66-3

nonadecan-2-one

A

1-Hexadecene
629-73-2

1-Hexadecene

(1R,2R)-1-Methyl-2-tetradecyl-cyclobutanol
102396-71-4, 102396-72-5

(1R,2R)-1-Methyl-2-tetradecyl-cyclobutanol

(1R,2S)-1-Methyl-2-tetradecyl-cyclobutanol
102396-71-4, 102396-72-5

(1R,2S)-1-Methyl-2-tetradecyl-cyclobutanol

D

acetone
67-64-1

acetone

Conditions
ConditionsYield
With n-butyl stearate In tert-butyl alcohol Product distribution; Irradiation; various temperatures;
ethene
74-85-1

ethene

1-Hexadecene
629-73-2

1-Hexadecene

1-bromo-hexane
111-25-1

1-bromo-hexane

10-bromodec-1-ene
62871-09-4

10-bromodec-1-ene

A

dodecane
112-40-3

dodecane

B

eicosa-1,19-diene
14811-95-1

eicosa-1,19-diene

C

1-Decene
872-05-9

1-Decene

D

1-Hexadecene
629-73-2

1-Hexadecene

Conditions
ConditionsYield
With hydrogenchloride; sodium peroxide; magnesium 1.) 22 deg C, 30 min, diethyl ether; Multistep reaction. Further byproducts given;
With hydrogenchloride; sodium peroxide; magnesium 1.) 22 deg C, 30 min, diethyl ether; Multistep reaction. Further byproducts given;
1-bromo-hexane
111-25-1

1-bromo-hexane

10-bromodec-1-ene
62871-09-4

10-bromodec-1-ene

A

dodecane
112-40-3

dodecane

B

hexane
110-54-3

hexane

C

1-Hexadecene
629-73-2

1-Hexadecene

Conditions
ConditionsYield
With hydrogenchloride; sodium peroxide; magnesium 1.) 22 deg C, 30 min, diethyl ether; Yield given. Multistep reaction;
pentadecyl bromide
629-72-1

pentadecyl bromide

trimethylsulphonium iodide
2181-42-2

trimethylsulphonium iodide

A

1-pentadecene
13360-61-7

1-pentadecene

B

1-Hexadecene
629-73-2

1-Hexadecene

Conditions
ConditionsYield
With n-butyllithium In tetrahydrofuran; hexane Ambient temperature; Yield given. Yields of byproduct given;
hexadecyl acetate
629-70-9

hexadecyl acetate

1-Hexadecene
629-73-2

1-Hexadecene

Conditions
ConditionsYield
In methanol for 24h; Irradiation;
Methyl stearate
112-61-8

Methyl stearate

1-Hexadecene
629-73-2

1-Hexadecene

Conditions
ConditionsYield
In methanol for 24h; Irradiation;
1-Hexadecene
629-73-2

1-Hexadecene

Hexadecane
544-76-3

Hexadecane

Conditions
ConditionsYield
With fac-[Mn(1,2-bis(di-isopropylphosphino)ethane)(CO)3(CH2CH2CH3)]; hydrogen In diethyl ether at 25℃; under 37503.8 Torr; for 18h;99%
With methanol; C30H30FeN6O9(3+)*3Cl(1-) at 90℃; under 11251.1 Torr; for 24h; Ionic liquid;81%
With diethyl ether; nickel under 19000 Torr; Hydrogenation;
1-Hexadecene
629-73-2

1-Hexadecene

(+)-2-[(1R)-(hydroxymethyl)prop-2-enyl]-1H-isoindole-1,3-(2H)-dione
174810-06-1

(+)-2-[(1R)-(hydroxymethyl)prop-2-enyl]-1H-isoindole-1,3-(2H)-dione

(2R)-(3E)-2-phthalimido-3-octadecen-1-ol
1094213-76-9

(2R)-(3E)-2-phthalimido-3-octadecen-1-ol

Conditions
ConditionsYield
With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride In dichloromethane at 20℃; for 12h; Reflux; Inert atmosphere;99%
With tri(cycloxexyl)phosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene][benzylidene]ruthenium(IV) dichloride In dichloromethane Reflux; stereoselective reaction;99%
triethylsilane
617-86-7

triethylsilane

1-Hexadecene
629-73-2

1-Hexadecene

Triethyl-hexadecylsilan

Triethyl-hexadecylsilan

Conditions
ConditionsYield
With [Rh(OH)cod]2 and diethylaminopropyltrimethoxysilane immobilized on SiO2 In neat (no solvent) at 40℃; for 0.25h;99%
With C77H70N2OPtSi2 In toluene at 80℃; for 24h; Catalytic behavior; Reagent/catalyst; Inert atmosphere; Sealed tube; regioselective reaction;89 %Chromat.
1-Hexadecene
629-73-2

1-Hexadecene

2,4,6,8-tetramethylcyclotetrasiloxane
2370-88-9

2,4,6,8-tetramethylcyclotetrasiloxane

2,4,6,8-tetramethyltetrahexadecylcyclotetrasiloxane

2,4,6,8-tetramethyltetrahexadecylcyclotetrasiloxane

Conditions
ConditionsYield
With platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex at 80℃;99%
4-bromo-1H-pyrazole
2075-45-8

4-bromo-1H-pyrazole

1-Hexadecene
629-73-2

1-Hexadecene

(S)-4-bromo-1-(hexadec-1-en-3-yl)-1H-pyrazole

(S)-4-bromo-1-(hexadec-1-en-3-yl)-1H-pyrazole

Conditions
ConditionsYield
With chloro(1,5-cyclooctadiene)rhodium(I) dimer; JoSPOPhos SL-J688-2; pyridinium p-toluenesulfonate In toluene at 80℃; for 16h; Inert atmosphere; Schlenk technique; Sealed tube; enantioselective reaction;98%
1-Hexadecene
629-73-2

1-Hexadecene

C42H63O7PS

C42H63O7PS

Hexadecyl-phosphonothioic acid O-{(R)-1-hexadecyloxymethyl-2-[tris-(4-methoxy-phenyl)-methoxy]-ethyl} ester O-methyl ester

Hexadecyl-phosphonothioic acid O-{(R)-1-hexadecyloxymethyl-2-[tris-(4-methoxy-phenyl)-methoxy]-ethyl} ester O-methyl ester

Conditions
ConditionsYield
2,2'-azobis(isobutyronitrile) at 100 - 105℃; for 1.66667h;97%
1-Hexadecene
629-73-2

1-Hexadecene

C32H63O2P

C32H63O2P

Conditions
ConditionsYield
With potassium hypophosphite; acetic acid; dibenzoyl peroxide at 40 - 50℃; under 8250.83 Torr; for 30h;96.52%
1-iodoheptadecafluorooctane
507-63-1

1-iodoheptadecafluorooctane

1-Hexadecene
629-73-2

1-Hexadecene

1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-heptadecafluoro-10-iodotetracosane

1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-heptadecafluoro-10-iodotetracosane

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile) at 80℃; Inert atmosphere;96%
With 2,2'-azobis(isobutyronitrile) at 100℃; for 0.25h;
1-Hexadecene
629-73-2

1-Hexadecene

phosphonic acid diethyl ester
762-04-9

phosphonic acid diethyl ester

hexadecanphosphonic acid diethyl ester
16165-71-2

hexadecanphosphonic acid diethyl ester

Conditions
ConditionsYield
With di-tert-butyl peroxide at 135℃; for 8h;96%
1,1,1,3,5,5,5-heptamethyltrisiloxan
1873-88-7

1,1,1,3,5,5,5-heptamethyltrisiloxan

1-Hexadecene
629-73-2

1-Hexadecene

C23H54O2Si3
286938-67-8

C23H54O2Si3

Conditions
ConditionsYield
With [Rh(OH)cod]2 and diethylaminopropyltrimethoxysilane immobilized on SiO2 In neat (no solvent) at 40℃; for 0.25h; Catalytic behavior; Reagent/catalyst;96%
(1,5-cyclooctadiene)rhodium/Aerosil 200 at 100℃; for 1h;98 % Chromat.
With C77H70N2OPtSi2 In toluene at 80℃; for 24h; Catalytic behavior; Reagent/catalyst; Inert atmosphere; Schlenk technique; regioselective reaction;91 %Chromat.
tributylsilane
998-41-4

tributylsilane

1-Hexadecene
629-73-2

1-Hexadecene

tributyl-hexadecyl-silane
18767-76-5

tributyl-hexadecyl-silane

Conditions
ConditionsYield
With [Rh(OH)cod]2 and diethylaminopropyltrimethoxysilane immobilized on SiO2 In neat (no solvent) at 40℃; for 0.25h;96%
1-Hexadecene
629-73-2

1-Hexadecene

N-(9-fluorenylmethoxycarbonyl)-S-trityl-L-cysteine
103213-32-7

N-(9-fluorenylmethoxycarbonyl)-S-trityl-L-cysteine

(L)-2-(9H-fluoren-9-ylmethoxycarbonylamino)-3-hexadecylsulfanyl-propionic acid
876312-48-0

(L)-2-(9H-fluoren-9-ylmethoxycarbonylamino)-3-hexadecylsulfanyl-propionic acid

Conditions
ConditionsYield
Stage #1: N-(9-fluorenylmethoxycarbonyl)-S-trityl-L-cysteine With triethylsilane; trifluoroacetic acid In dichloromethane at 20℃; for 3h;
Stage #2: 1-Hexadecene With 2,2'-azobis(isobutyronitrile) In 1,2-dichloro-ethane at 90℃; for 3h;
96%
1-Hexadecene
629-73-2

1-Hexadecene

1,2-epoxyhexadecane
7320-37-8

1,2-epoxyhexadecane

Conditions
ConditionsYield
With 3-chloro-benzenecarboperoxoic acid In dichloromethane at 0℃; for 1h;95%
With maleic anhydride; urea hydrogen peroxide adduct In dichloromethane at 18 - 20℃; for 20h; Inert atmosphere;93%
With [2,2']bipyridinyl 1,1'-dioxide; dihydrogen peroxide; methyltrioxorhenium(VII) In dichloromethane; water for 24h; Ambient temperature;91%
1-Hexadecene
629-73-2

1-Hexadecene

1,2-dibromohexadecane
63758-87-2

1,2-dibromohexadecane

Conditions
ConditionsYield
With bromine In dichloromethane at 20℃; for 0.5h;95%
With carbon disulfide; bromine
With bromine
With bromine In tetrachloromethane
Dichloromethylsilane
75-54-7

Dichloromethylsilane

1-Hexadecene
629-73-2

1-Hexadecene

Dichlorohexadecylmethylsilane
59086-81-6

Dichlorohexadecylmethylsilane

Conditions
ConditionsYield
Stage #1: 1-Hexadecene With diethylenetriaminepentaacetic acid (DTPA)-functionalized silica supported Pt at 60℃; for 0.5h;
Stage #2: Dichloromethylsilane at 60℃; for 4h; Reagent/catalyst;
95%
With dihydrogen hexachloroplatinate
1-Hexadecene
629-73-2

1-Hexadecene

(2R)-(+)-1,2-hexadecanediol
61490-71-9

(2R)-(+)-1,2-hexadecanediol

Conditions
ConditionsYield
With AD-mix-β In water; tert-butyl alcohol at 0℃; dihydroxylation;95%
Multi-step reaction with 2 steps
1: 3-chloro-benzenecarboperoxoic acid / dichloromethane; water / 16 h / 0 - 20 °C / Inert atmosphere
2: acetic acid; water; [(S,S)-N,N’-bis(3,5-di-tertbutylsalicylidene)-1,2-cyclohexanediaminato(2-)]cobalt(II) / toluene / 12 h / 20 °C
View Scheme
1-Hexadecene
629-73-2

1-Hexadecene

(2S)-(-)-1,2-hexadecanediol
61490-70-8

(2S)-(-)-1,2-hexadecanediol

Conditions
ConditionsYield
With AD-mix-α In water; tert-butyl alcohol at 0℃; dihydroxylation;95%
Multi-step reaction with 2 steps
1: urea hydrogen peroxide adduct; maleic anhydride / dichloromethane / 20 h / 18 - 20 °C / Inert atmosphere
2: [InCl3(Co((R,R)-C6H10(NCHC6H2O(tert-butyl)2)2))2]; water / tetrahydrofuran / 24 h / 25 °C / Inert atmosphere; Sealed tube; Resolution of racemate
View Scheme
1-Hexadecene
629-73-2

1-Hexadecene

Dimethyl phosphite
868-85-9

Dimethyl phosphite

hexadecylphosphonate de dimethyle
33447-06-2

hexadecylphosphonate de dimethyle

Conditions
ConditionsYield
With di-tert-butyl peroxide at 135℃; for 8h;95%
With dibenzoyl peroxide at 130℃; for 0.333333h;
1-Hexadecene
629-73-2

1-Hexadecene

1-Iodo-perfluorodecane
423-62-1

1-Iodo-perfluorodecane

1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10-henicosafluoro-12-iodohexacosane
1257261-91-8

1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10-henicosafluoro-12-iodohexacosane

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile) at 80℃; Inert atmosphere;95%
1-Hexadecene
629-73-2

1-Hexadecene

Diphenyliodonium triflate
66003-76-7

Diphenyliodonium triflate

(E)-hexadec-1-enylbenzene
1446341-35-0

(E)-hexadec-1-enylbenzene

Conditions
ConditionsYield
With palladium diacetate In N,N-dimethyl-formamide at 130℃; for 0.0333333h; Schlenk technique; Microwave irradiation; regioselective reaction;95%
1-Hexadecene
629-73-2

1-Hexadecene

1-Hexadecanol
36653-82-4

1-Hexadecanol

Conditions
ConditionsYield
With titanium(III) tetrahydroborate In dichloromethane at -20℃; for 0.3h;94%
Multi-step reaction with 2 steps
1: chloroplatinic acid / 46 h / Heating
2: 1.) m-chloroperbenzoic acid, disodium hydrogen phosphate, 2.) water / 1.) methanol, RT, 24 h
View Scheme
1-Hexadecene
629-73-2

1-Hexadecene

2,4-Xylenol
105-67-9

2,4-Xylenol

2,4-dimethyl-6-(1-methyl-pentadecyl)phenol
134701-20-5

2,4-dimethyl-6-(1-methyl-pentadecyl)phenol

Conditions
ConditionsYield
at 130℃; for 20h; Temperature; Inert atmosphere;91.4%
1-Hexadecene
629-73-2

1-Hexadecene

L-cysteine methyl ester hydrochloride
18598-63-5

L-cysteine methyl ester hydrochloride

(L)-2-amino-3-hexadecylsulfanyl-propionic acid methyl ester
262596-88-3

(L)-2-amino-3-hexadecylsulfanyl-propionic acid methyl ester

Conditions
ConditionsYield
In 1,2-dichloro-ethane at 90℃; for 3h;91%
1-Hexadecene
629-73-2

1-Hexadecene

hexadecylphosphonous acid
2629-28-9

hexadecylphosphonous acid

Conditions
ConditionsYield
With sodium hypophosphite; 2,2'-azobis(isobutyronitrile); sulfuric acid In ethanol for 26h; Inert atmosphere; Reflux;91%
With hypophosphorous acid In 1,4-dioxane; water at 180℃; for 1h; Microwave irradiation; Sealed tube;83%
octasilsesquioxane
281-50-5

octasilsesquioxane

1-Hexadecene
629-73-2

1-Hexadecene

C128H264O12Si8
1421920-81-1

C128H264O12Si8

Conditions
ConditionsYield
With dihydrogen hexachloroplatinate In isopropyl alcohol at 80℃; for 3h;91%
1-Hexadecene
629-73-2

1-Hexadecene

trifluoromethane sulfonyl chloride
421-83-0

trifluoromethane sulfonyl chloride

C17H32ClF3

C17H32ClF3

Conditions
ConditionsYield
With 2,4,6-trimethyl-pyridine; [Hf6(μ3-O)4(mu3-OH)4(formato)5.9(eosinato Y)0.1(4'-(4-carboxylatophenyl)[2,2':6',2''-terpyridine]-5,5''-dicarboxylato-Fe(OTf)2)2] In acetonitrile at 20℃; for 2h; Catalytic behavior; Inert atmosphere; Schlenk technique; Irradiation;90%
1-Hexadecene
629-73-2

1-Hexadecene

(R)-2-(1-((tert-butyldimethylsilyl)oxy)but-3-en-2-yl)isoindoline-1,3-dione
1300026-35-0

(R)-2-(1-((tert-butyldimethylsilyl)oxy)but-3-en-2-yl)isoindoline-1,3-dione

(R,Z)-2-(1-((tert-butyldimethylsilyl)oxy)octadec-3-en-2-yl)isoindoline-1,3-dione
1300026-36-1

(R,Z)-2-(1-((tert-butyldimethylsilyl)oxy)octadec-3-en-2-yl)isoindoline-1,3-dione

Conditions
ConditionsYield
With [Mo(adamantylimido)(CHC(CH3)2(phenyl))(C4H2N(CH3)2)(OC10H9BrC10H9(Br)O(tert-butyldimethylsilyl))] In benzene at 22℃; under 7 Torr; for 5h; Inert atmosphere; optical yield given as %de; stereoselective reaction;88%
1-Hexadecene
629-73-2

1-Hexadecene

phenylsilane
694-53-1

phenylsilane

C22H40Si

C22H40Si

Conditions
ConditionsYield
With C10H14CoO5; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In tetrahydrofuran at 20℃; for 3h; regioselective reaction;88%

1-Hexadecene Chemical Properties

IUPAC Name: Hexadec-1-ene 
Following is the structure of 1-Hexadecene (CAS NO.629-73-2):
                        
Empirical Formula: C16H32
Molecular Weight: 224.4253 g/mol
EINECS: 208-878-9
Index of Refraction: 1.44
Molar Refractivity: 75.9 cm3
Molar Volume: 287.7 cm3
Density: 0.779 g/cm3
Flash Point: 132.2 °C
Melting point: 3-5 °C(lit.)
Surface Tension: 27.2 dyne/cm
Enthalpy of Vaporization: 50.28 kJ/mol
Boiling Point: 284.8 °C at 760 mmHg
Vapour Pressure: 0.00499 mmHg at 25 °C
Product Categories of 1-Hexadecene (CAS NO.629-73-2): 1-Olefins (GC Standard);Analytical Chemistry; Standard Materials for GC
Water Solubility of 1-Hexadecene (CAS NO.629-73-2): 1.23E-03 mg/L at 25 °C
Appearance of 1-Hexadecene (CAS NO.629-73-2): clear colorless liquid
Canonical SMILES: CCCCCCCCCCCCCCC=C
InChI: InChI=1S/C16H32/c1-3-5-7-9-11-13-15-16-14-12-10-8-6-4-2/h3H,1,4-16H2,2H3
InChIKey: GQEZCXVZFLOKMC-UHFFFAOYSA-N

1-Hexadecene Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
rabbit LD skin > 10gm/kg (10000mg/kg) SKIN AND APPENDAGES (SKIN): HAIR: OTHER National Technical Information Service. Vol. OTS0535205,
rat LC inhalation > 8500mg/m3/1H (8500mg/m3)   National Technical Information Service. Vol. OTS0535205,
rat LD oral > 10gm/kg (10000mg/kg)   National Technical Information Service. Vol. OTS0535205,
 1-Hexadecene (CAS NO.629-73-2) hasn't been listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65. And the toxicological properties have not been fully investigated. You can see actual entry in RTECS for complete information.

1-Hexadecene Safety Profile

Hazard Codes: IrritantXi
Risk Statements: 38 
R38:Irritating to skin.
Safety Statements: 23-24/25 
S23:Do not breathe vapour. 
S24/25:Avoid contact with skin and eyes.
WGK Germany: 3
RTECS: MM0479000

1-Hexadecene Specification

 1-Hexadecene , its cas register number is 629-73-2. It also can be called (5-Aminobenzo[d]isoxazol-3-yl)carbamic acid tert-butyl ester ;  1-Cetene ; 1-n-Hexadecene ; Cetene ; Cetylene ; Dialene 16 ; Gulftene 16 ; Hexadecylene-1 ; alpha-Hexadecene ; alpha-Hexadecylene ; and n-Hexadec-1-ene .
 1-Hexadecene (CAS NO.629-73-2) is hazardous, so the first aid measures and others should be known. Such as: When on the skin: first, should flush skin with plenty of water immediately for at least 15 minutes while removing contaminated clothing. Secondly, get medical aid. Or in the eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Then get medical aid soon. While, it's inhaled: Remove from exposure and move to fresh air immediately. Give artificial respiration while not breathing. When breathing is difficult, give oxygen. And as soon as to get medical aid. Then you have the ingesting of the product : Wash mouth out with water, and get medical aid immediately.
 1-Hexadecene (CAS NO.629-73-2) could be stable under normal temperatures and pressures. It should avoid the condition like incompatible materials. It is not compatible with strong oxidizing agents, chlorates, nitrates, peroxides. And also prevent it to broken down into hazardous decomposition products: carbon monoxide, carbon dioxide. However, its hazardous polymerization will not occur. In addition, it should be stored in a cool, dry place, or stored in a tightly closed container.

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