1-PHENYL-2-PROPANOL supplier

Name
BENZYLMETHYLCARBINOL
EINECS 211-821-0
CAS No. 698-87-3
Article Data271
CAS DataBase
Density 0.99
Solubility
Melting Point 135-136℃
Formula C9H12 O
Boiling Point 213 °C
Molecular Weight 136.194
Flash Point 85 °C
Transport Information
Appearance
Safety Moderately toxic by intraperitoneal route. When heated to decomposition it emits acrid smoke and irritating vapors.
Risk Codes
Molecular Structure
Hazard Symbols
Synonyms Phenethylalcohol, a-methyl- (7CI,8CI);1-Phenyl-2-propanol;2-Hydroxy-1-phenylpropane;2-Propanol, 1-phenyl-;3-Phenyl-2-hydroxypropane;3-Phenyl-2-propanol;Benzylmethyl carbinol;Benzylethyl alcohol;NSC 53553;a-Methylbenzeneethanol;a-Methylphenethyl alcohol;14898-87-4;
PSA 20.23000
LogP 1.60990

Synthetic route

: 103-79-7
1-phenyl-acetone

: 698-87-3
3-phenyl-2-propanol

Conditions

Conditions	Yield
With diethoxymethylane; cesium fluoride at 25℃; for 5h;	100%
With diethoxymethylane; ethyl laurate; cesium fluoride at 25℃; for 5h;	100%
With C28H18Co(1-)K(1+)2C4H10O2; hydrogen In toluene at 60℃; under 8025.8 Torr; for 24h; chemoselective reaction;	99%

: 243645-11-6
tert-butyl-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluoro-decyloxy)-(1-methyl-2-phenyl-ethoxy)-phenyl-silane

: 698-87-3
3-phenyl-2-propanol

Conditions

Conditions	Yield
With tetrabutyl ammonium fluoride In tetrahydrofuran at 20℃; for 3h; deprotection;	100%

: tert-Butyl-dimethyl-(1-methyl-2-phenyl-ethoxy)-silane

: 698-87-3
3-phenyl-2-propanol

Conditions

Conditions	Yield
With SO3H silica gel at 25℃; for 0.5h;	100%

: 4436-24-2
1,2-epoxy-3-phenylpropane

: 698-87-3
3-phenyl-2-propanol

Conditions

Conditions	Yield
With sodium tetrahydroborate; alpha cyclodextrin In water for 24h; Product distribution; Ambient temperature; presence of β-, and γ-cyclodextrin; kinetic resolution; further epoxides;	98%
Stage #1: 1,2-epoxy-3-phenylpropane With sodium tetrahydroborate; diselenide resin In ethanol Stage #2: With 2,2'-azobis(isobutyronitrile); tris-(trimethylsilyl)silane	97%
With [carbonylchlorohydrido{bis[2-(diphenylphosphinomethyl)ethyl]amino}ethylamino] ruthenium(II); potassium tert-butylate; hydrogen In toluene at 100℃; under 37503.8 Torr; for 24h; regioselective reaction;	95%

: S-methyl O-(1-phenylpropan-2-yl) carbonodithioate

: 698-87-3
3-phenyl-2-propanol

Conditions

Conditions	Yield
With 3-azapentane-1,5-diamine at 160℃; for 0.5h; Reagent/catalyst; Sealed tube; Microwave irradiation;	97%

: 114395-16-3, 121958-40-5, 121958-41-6
(±)-trans-(3-phenyloxiran-2-yl)methyl 4-methylbenzenesulfonate

: 698-87-3
3-phenyl-2-propanol

Conditions

Conditions	Yield
With lithium aluminium tetrahydride In diethyl ether at 0℃;	95%

: 23355-97-7
1-phenylpropylene oxide

: 698-87-3
3-phenyl-2-propanol

Conditions

Conditions	Yield
With palladium 10% on activated carbon; hydrogen In methanol at 20℃; under 760.051 Torr; for 2h; regioselective reaction;	95%
With ammonium formate In ethyl acetate at 25℃; for 12h; Inert atmosphere;	94%
With alkaline hydrogen peroxide; lithium triethylborohydride In tetrahydrofuran for 1h;	93%
With Al-trifluoromethanesulfonyldiisobutylalane In diethyl ether at 25℃; for 0.5h; Meerwein-Ponndorf-Verley reduction; Inert atmosphere; regioselective reaction;
Multi-step reaction with 2 steps 1: dimethyltitanocene / tetrahydrofuran / 18 h / Inert atmosphere; Reflux 2: water; potassium carbonate / tetrahydrofuran; acetone / 16 h / Inert atmosphere View Scheme

: 874960-60-8
(2-phenylpropan-1-yloxy)tetrahydro-2H-pyran

: 698-87-3
3-phenyl-2-propanol

Conditions

Conditions	Yield
With silica triflate In methanol for 0.166667h; Heating;	95%

: (C(Si(CH3)3)3)2In2H3NHCHCH3C6H5

: 103-79-7
1-phenyl-acetone

A: μ4-oxohexa(μ-hydroxy)tetrakis(tris(trimethylsilyl)methylindium)

B: 698-87-3
3-phenyl-2-propanol

Conditions

Conditions	Yield
In tetrahydrofuran A soln. of PhCH2COMe in THF was added to a suspn. of complex in THF at -78°C; 1 h;; evapd., chromy. on silica; eluent - ethyl acetate-light petroleum;;	A n/a B 95%

...Expand

: 100-44-7
benzyl chloride

: 75-07-0
acetaldehyde

: 698-87-3
3-phenyl-2-propanol

Conditions

Conditions	Yield
Stage #1: benzyl chloride With magnesium In diethyl ether Stage #2: acetaldehyde In diethyl ether at 20℃; for 2h; Grignard reaction;	93%

: 75-56-9, 16033-71-9
methyloxirane

: 71-43-2
benzene

: 698-87-3
3-phenyl-2-propanol

Conditions

Conditions	Yield
Stage #1: methyloxirane; benzene With aluminium trichloride at 6 - 7℃; for 4h; Stage #2: With water Further stages.;	93%

: 4436-22-0
1-phenylpropylene oxide

: 698-87-3
3-phenyl-2-propanol

Conditions

Conditions	Yield
With aluminum oxide; sodium tetrahydroborate; palladium dichloride In hexane; water at 30℃; for 1h;	93%
With ammonia borane; C28H28Cl2CoNP2; erbium(III) triflate In tetrahydrofuran at 55℃; for 8h; Reagent/catalyst;	93%
In isopropyl alcohol at 29.84℃; under 760.051 Torr; for 6h; Inert atmosphere; UV-irradiation; Sealed tube;	76%
With cobalt(II) bis[bis((trifluoromethyl)sulfonyl)amide]; hydrogen; zinc trifluoromethanesulfonate In tetrahydrofuran at 80℃; under 30003 Torr; for 16h; Catalytic behavior; Autoclave; regioselective reaction;	85 %Chromat.

: 18052-49-8
trimethyl[(1-phenylpropan-2-yl)oxy]silane

: 698-87-3
3-phenyl-2-propanol

Conditions

Conditions	Yield
With trinitratocerium(IV) bromate at 20℃; for 0.0833333h;	92%
With tris[trinitratocerium(IV)] paraperiodate at 20℃; for 0.0166667h;	90%

: 64-18-6
formic acid

: 42006-80-4
(+/-)-formic acid-(1-methyl-2-phenyl-ethyl ester)

: 698-87-3
3-phenyl-2-propanol

Conditions

Conditions	Yield
Stage #1: formic acid With silica gel at 20℃; for 0.0166667h; Stage #2: (+/-)-formic acid-(1-methyl-2-phenyl-ethyl ester) With silica gel at 110℃; for 0.05h;	92%

: (2-(methoxymethoxy)propyl)benzene

: 698-87-3
3-phenyl-2-propanol

Conditions

Conditions	Yield
With scandium tris(trifluoromethanesulfonate); trimethyleneglycol In acetonitrile for 2h; Heating;	90%
With bismuth(III) chloride; water In acetonitrile at 50℃; for 3h;	78%

: 910660-90-1
bis-(4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluoro-nonyl)-thiocarbamic acid O-(1-methyl-2-phenyl-ethyl) ester

A: N,N-bis-(4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluoro-nonyl)-hydroxylamine

B: 698-87-3
3-phenyl-2-propanol

Conditions

Conditions	Yield
With 3-chloro-benzenecarboperoxoic acid In dichloromethane at -78℃; for 1h;	A n/a B 90%

: 101430-90-4
[2-(benzyloxy)propyl]benzene

: 698-87-3
3-phenyl-2-propanol

Conditions

Conditions	Yield
Stage #1: [2-(benzyloxy)propyl]benzene With isocyanate de chlorosulfonyle; sodium carbonate In dichloromethane for 20h; Heating; Stage #2: With sodium hydroxide In methanol at 20℃; for 1h;	88%

: bis-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,13-heneicosafluoro-tridecyl)-thiocarbamic acid O-(1-methyl-2-phenyl-ethyl) ester

A: N,N-bis-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,13-heneicosafluoro-tridecyl)-hydroxylamine

B: 698-87-3
3-phenyl-2-propanol

Conditions

Conditions	Yield
With 3-chloro-benzenecarboperoxoic acid In dichloromethane at -78℃; for 1h;	A n/a B 88%

: 108-86-1
bromobenzene

: 75-56-9, 16033-71-9
methyloxirane

: 698-87-3
3-phenyl-2-propanol

Conditions

Conditions	Yield
With pyridine; 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone; 4,4'-bipyridine; NiI2*3.9H2O; triethylamine hydrochloride; sodium iodide; zinc at 20℃; for 12h;	87%
Stage #1: bromobenzene With n-butyllithium In tetrahydrofuran; hexane at -70℃; Stage #2: methyloxirane In tetrahydrofuran; hexane at -50 - 20℃;	72%
Stage #1: bromobenzene With n-butyllithium In tetrahydrofuran at -30℃; for 0.5h; Stage #2: methyloxirane In tetrahydrofuran at 20℃; for 1h; Further stages.;	68%

: 4541-87-1
cis-1-phenylpropene oxide

: 698-87-3
3-phenyl-2-propanol

Conditions

Conditions	Yield
With formic acid; triethylamine; Pd0-EnCatTM In ethyl acetate at 23℃; for 3h;	87%

: 637-50-3
1-phenylpropene

: 698-87-3
3-phenyl-2-propanol

Conditions

Conditions	Yield
With water; diphenyldisulfane; 9-(2-mesityl)-10-methylacridinium perchlorate In acetonitrile at 20℃; for 24h; Irradiation; Inert atmosphere; regioselective reaction;	87%

: 910660-89-8
bis-(4,4,5,5,6,6,7,7,7-nonafluoro-heptyl)-thiocarbamic acid O-(1-methyl-2-phenyl-ethyl) ester

A: N,N-bis-(4,4,5,5,6,6,7,7,7-nonafluoro-heptyl)-hydroxylamine

B: 698-87-3
3-phenyl-2-propanol

Conditions

Conditions	Yield
With 3-chloro-benzenecarboperoxoic acid In dichloromethane at -78℃; for 1h;	A n/a B 86%

: bis-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-heptadecafluoro-undecyl)-thiocarbamic acid O-(1-methyl-2-phenyl-ethyl) ester

A: N,N-bis-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-heptadecafluoro-undecyl)-hydroxylamine

B: 698-87-3
3-phenyl-2-propanol

Conditions

Conditions	Yield
With 3-chloro-benzenecarboperoxoic acid In dichloromethane at -78℃; for 1h;	A n/a B 85%

: 2397-68-4
sodium tetraethylaluminate

: 103-79-7
1-phenyl-acetone

A: 698-87-3
3-phenyl-2-propanol

B: 772-46-3
2-methyl-1-phenyl-2-butanol

Conditions

Conditions	Yield
nickel dichloride In pentane at 35℃; for 2h;	A 3% B 82%

...Expand

: 96-09-3
styrene oxide

: 75-16-1
methylmagnesium bromide

: 698-87-3
3-phenyl-2-propanol

Conditions

Conditions	Yield
With titanium(IV) isopropylate In diethyl ether for 6h; Product distribution; Ambient temperature; other Grignard reagents, var. time;	80%
With titanium(IV) isopropylate In diethyl ether for 6h; Ambient temperature;	80%

: 7045-86-5
2-methyl-4,7-dihydro-1,3-dioxepine

: 1589-82-8
phenylmagnesium bromide

A: 698-87-3
3-phenyl-2-propanol

B: 75950-58-2
2-phenylmethyl-but-3-en-1-ol

Conditions

Conditions	Yield
1,2-bis(diphenylphosphino)ethane nickel(II) chloride for 14h; Ambient temperature;	A n/a B 80%

...Expand

: 579-07-7
1-Phenylpropane-1,2-dione

A: 698-87-3
3-phenyl-2-propanol

B: 93-54-9
1-Phenyl-1-propanol

C: 1855-09-0
1-phenyl-1,2-propandiol

D: 93-55-0
1-phenyl-propan-1-one

Conditions

Conditions	Yield
With samarium diiodide; water In tetrahydrofuran at 20℃; for 0.166667h; Further byproducts given;	A 6% B 79% C 3% D 7%

...Expand

: 18006-13-8
methyltriisopropoxytitanium(IV)

: 122-78-1
phenylacetaldehyde

: 698-87-3
3-phenyl-2-propanol

Conditions

Conditions	Yield
In diethyl ether for 2h; -40 deg C to 0 deg C;	74%

: phenyl(1-phenylpropan-2-yl)silane

: 698-87-3
3-phenyl-2-propanol

Conditions

Conditions	Yield
Stage #1: phenyl(1-phenylpropan-2-yl)silane With tetrafluoroboric acid diethyl ether In dichloromethane at 0 - 25℃; for 2h; Schlenk technique; Inert atmosphere; Stage #2: With potassium fluoride; dihydrogen peroxide; potassium hydrogencarbonate In tetrahydrofuran; methanol; dichloromethane; water for 18h; Inert atmosphere; Schlenk technique; Reflux;	72%

: 698-87-3
3-phenyl-2-propanol

: 103-79-7
1-phenyl-acetone

Conditions

Conditions	Yield
With periodic acid; pyridinium chlorochromate In acetonitrile at 0 - 23℃; for 2.08333h; Inert atmosphere;	100%
With periodic acid; pyridinium chlorochromate In acetonitrile at 0 - 23℃; for 2h; Inert atmosphere; Cooling with ice;	100%
With periodic acid; tripropylammonium fluorochromate (VI) In acetonitrile at 0℃; for 2h;	99%

: 698-87-3
3-phenyl-2-propanol

: 1079-66-9
chloro-diphenylphosphine

: 1-phenylpropan-2-yl diphenylphosphinite

Conditions

Conditions	Yield
With dmap; triethylamine In tetrahydrofuran at 20℃; for 2h;	100%
With dmap; triethylamine In tetrahydrofuran at 20℃; for 2h;	100%

: 910660-81-0
C15H12ClF18NS

: 698-87-3
3-phenyl-2-propanol

: 910660-89-8
bis-(4,4,5,5,6,6,7,7,7-nonafluoro-heptyl)-thiocarbamic acid O-(1-methyl-2-phenyl-ethyl) ester

Conditions

Conditions	Yield
With sodium hydride In tetrahydrofuran at 20℃; for 12h;	100%

: 910660-82-1
C19H12ClF26NS

: 698-87-3
3-phenyl-2-propanol

: 910660-90-1
bis-(4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluoro-nonyl)-thiocarbamic acid O-(1-methyl-2-phenyl-ethyl) ester

Conditions

Conditions	Yield
With sodium hydride In tetrahydrofuran at 20℃; for 12h;	100%

: C27H12ClF42NS

: 698-87-3
3-phenyl-2-propanol

: bis-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,13-heneicosafluoro-tridecyl)-thiocarbamic acid O-(1-methyl-2-phenyl-ethyl) ester

Conditions

Conditions	Yield
With sodium hydride In tetrahydrofuran at 20℃; for 12h;	100%

: 698-87-3
3-phenyl-2-propanol

: 824-94-2
p-methoxybenzyl chloride

: 1-methoxy-4-[(2-phenylpropoxy)methyl]benzene

Conditions

Conditions	Yield
With sodium t-butanolate In dimethyl sulfoxide at 20℃; for 3h;	99%
With cesium hydroxide; 4 A molecular sieve In N,N-dimethyl-formamide at 23℃; for 3h;	90%

: 698-87-3
3-phenyl-2-propanol

: 605-65-2
5-(dimethylamino)naphth-1-ylsulfonyl chloride

: 5-dimethylamino-naphthalene-1-sulfonic acid 1-methyl-2-phenyl-ethyl ester

Conditions

Conditions	Yield
With pyridine; dmap In dichloromethane at 20℃; for 49h;	99%

: 698-87-3
3-phenyl-2-propanol

: 100-39-0
benzyl bromide

: 287729-69-5
benzhydryl benzyl carbonate

Conditions

Conditions	Yield
for 120h;	99%

: 698-87-3
3-phenyl-2-propanol

: 7306-46-9
4-chloromethyl-1,2-dimethoxy-benzene

: 1,2-dimethoxy-4-{[(1-phenylpropan-2-yl)oxy]methyl}benzene

Conditions

Conditions	Yield
With sodium t-butanolate In dimethyl sulfoxide at 20℃; for 3h;	99%

: 698-87-3
3-phenyl-2-propanol

: 100-39-0
benzyl bromide

: 101430-90-4
[2-(benzyloxy)propyl]benzene

Conditions

Conditions	Yield
With sodium t-butanolate In dimethyl sulfoxide at 20℃; for 3h;	99%

: 698-87-3
3-phenyl-2-propanol

: 124-38-9
carbon dioxide

: 100-44-7
benzyl chloride

: (+/-)-benzyl 1-methyl-2-phenylethyl carbonate

Conditions

Conditions	Yield
With tetra-(n-butyl)ammonium iodide; caesium carbonate In N,N-dimethyl-formamide at 23℃; for 3h;	98%
Stage #1: 3-phenyl-2-propanol; carbon dioxide With tetra-(n-butyl)ammonium iodide; caesium carbonate In N,N-dimethyl-formamide at 23℃; for 1h; Stage #2: benzyl chloride In N,N-dimethyl-formamide at 23℃; for 3h;	98%

...Expand

: 698-87-3
3-phenyl-2-propanol

: 449813-82-5
3-(diphenylphosphono)-2-(N-cyanoimino)thiazolidine

: diphenyl 1-phenylprop-2-yl phosphate

Conditions

Conditions	Yield
With tert-butylmagnesium chloride In tetrahydrofuran at 20℃; for 0.25h;	98%

: 698-87-3
3-phenyl-2-propanol

: 754-05-2
ethenyltrimethylsilane

: 18052-49-8
trimethyl[(1-phenylpropan-2-yl)oxy]silane

Conditions

Conditions	Yield
With hydrogenchloride; chlorobis(cyclooctene)rhodium(I) dimer In 1,4-dioxane; chloroform at 20℃; for 4h;	98%
Wilkinson's catalyst In toluene at 100℃; for 4h;	97%

: 698-87-3
3-phenyl-2-propanol

: 98-59-9
p-toluenesulfonyl chloride

: 14135-71-8
1-phenyl-2-propyl-4-toluenesulfonate

Conditions

Conditions	Yield
With pyridine; dmap In dichloromethane at 20℃; for 21h;	97%
With pyridine Ambient temperature;	83%

: 698-87-3
3-phenyl-2-propanol

: 449813-84-7
3-(diethylphosphono)-2-(N-cyanoimino)thiazolidine

: diethyl 1-phenylprop-2-yl phosphate

Conditions

Conditions	Yield
With tert-butylmagnesium chloride In tetrahydrofuran at 20℃; for 1.5h;	97%

: 698-87-3
3-phenyl-2-propanol

: 754-05-2
ethenyltrimethylsilane

A: 74-85-1
ethene

B: 18052-49-8
trimethyl[(1-phenylpropan-2-yl)oxy]silane

Conditions

Conditions	Yield
hydrogenchloride; chlorobis(cyclooctene)rhodium(I) dimer In 1,4-dioxane; chloroform for 4h; Product distribution / selectivity;	A n/a B 97%

...Expand

: 698-87-3
3-phenyl-2-propanol

: 42908-73-6
4-fluorophenyl chlorothionoformate

: 1-phenyl-2-propyl 4-fluorophenylthioxocarbonate

Conditions

Conditions	Yield
With pyridine In dichloromethane for 2h;	96%

: 5292-43-3
bromoacetic acid tert-butyl ester

: 698-87-3
3-phenyl-2-propanol

: 124-38-9
carbon dioxide

: (1-methyl-2-phenyl-ethoxycarbonyloxy)-acetic acid tert-butyl ester

Conditions

Conditions	Yield
With tetra-(n-butyl)ammonium iodide; caesium carbonate In N,N-dimethyl-formamide at 23℃; for 5h;	96%
Stage #1: 3-phenyl-2-propanol; carbon dioxide With tetra-(n-butyl)ammonium iodide; caesium carbonate In N,N-dimethyl-formamide at 23℃; for 1h; Stage #2: bromoacetic acid tert-butyl ester In N,N-dimethyl-formamide at 23℃; for 5h;	96%

...Expand

: 108-22-5
Isopropenyl acetate

: 698-87-3
3-phenyl-2-propanol

: 2114-33-2, 29393-15-5, 115630-98-3, 116907-36-9
(R)-1-phenyl-2-acetoxypropane

Conditions

Conditions	Yield
With dicarbonylchlorido(pentabenzylcyclopentadienyl)ruthenium; potassium tert-butylate; sodium carbonate In tetrahydrofuran; toluene at 23℃; for 6h; Inert atmosphere; dynamic kinetic resolution; Enzymatic reaction; optical yield given as %ee; enantioselective reaction;	96%
With Candida antarctica lipase B; C51H41P2Ru(1+)*C32H12BF24(1-); potassium carbonate In toluene at 20℃; for 16h; Glovebox; Enzymatic reaction; enantioselective reaction;	95%
With [(η5-1-methoxy-2,4-di-tert-butyl-3-neopentylcyclopentadienyl)Ru(CO)2(CO2Me)] In toluene at 25℃; for 6h; Schlenk technique; Molecular sieve; Inert atmosphere; Enzymatic reaction; enantioselective reaction;	92%
With air; Novozym-435; silver(l) oxide; (η5-Ph5C5)Ru(CO)(PPh3)Br In toluene at 25℃; for 20h;	93 % Chromat.

: 524-38-9
N-hydroxyphthalimide

: 698-87-3
3-phenyl-2-propanol

: 73771-06-9
2-((1-phenylpropan-2-yl)oxy)isoindoline-1,3-dione

Conditions

Conditions	Yield
With di-isopropyl azodicarboxylate; triphenylphosphine In tetrahydrofuran Inert atmosphere;	96%
With diisopropyl (E)-azodicarboxylate; triphenylphosphine In tetrahydrofuran at 0 - 23℃;	68%
With di-isopropyl azodicarboxylate; triphenylphosphine In tetrahydrofuran at 0 - 20℃; for 3h;

: 64-18-6
formic acid

: 698-87-3
3-phenyl-2-propanol

: 42006-80-4
(+/-)-formic acid-(1-methyl-2-phenyl-ethyl ester)

Conditions

Conditions	Yield
With silica triflate In hexane for 0.183333h; Heating;	95%
With sulfuric acid; silica gel In hexane for 0.25h; Heating;	85%
With magnesium hydrogen sulfate In dichloromethane for 0.5h; Heating;	83%
With zirconium hydrogen sulfate In hexane at 20℃; for 2h;	75%
With copper(II) sulfate

: 698-87-3
3-phenyl-2-propanol

: 10304-81-1
1-phenyl-2-chloropropane

Conditions

Conditions	Yield
With oxalyl dichloride; 1-methyl-3-(2-(3-methyl-2-oxoimidazolidin-1-yl)ethyl)-1H-imidazol-3-ium hexafluorophosphate at 20 - 60℃;	95%
With tetrachlorosilane In tetrachloromethane at 25℃; for 0.5h;	80%
With gallium(III) trichloride; dimethylmonochlorosilane; diethyl (2R,3R)-tartrate In dichloromethane; pentane at 20℃; for 1h; Inert atmosphere;	69%

: 698-87-3
3-phenyl-2-propanol

: 999-97-3
1,1,1,3,3,3-hexamethyl-disilazane

: 18052-49-8
trimethyl[(1-phenylpropan-2-yl)oxy]silane

Conditions

Conditions	Yield
With tetrachlorosilane In dichloromethane for 0.7h; Heating;	95%
With potassium bromide In acetonitrile at 20℃; for 0.0833333h;	92%
With 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione In acetonitrile at 20℃;	92%

1-PHENYL-2-PROPANOL Chemical Properties

The Molecular formula of 1-PHENYL-2-PROPANOL(698-87-3): C₉H₁₂O
The Molar mass of 1-PHENYL-2-PROPANOL(698-87-3): 136.19098
EINECS: 211-821-0
density: 0.99
Boiling point: 213 °C
Flash point: 85 °C
refractive index: n20/D 1.522
Water Solubility: 5840 mg/L 25 °C
Synonyms: 1-Phenyl-2-propanol; 2-Hydroxy-1-phenylpropane; 2-Propanol,1-phenyl-; Benzyl methyl carbinol; alpha-Methyl-phenethyl alcohol; alpha-Methylbenzeneethanol; 1-phenylpropan-2-ol.
The Structure of 1-PHENYL-2-PROPANOL(698-87-3):

1-PHENYL-2-PROPANOL Uses

1-PHENYL-2-PROPANOL(698-87-3) is used as a chemical reagent.

1-PHENYL-2-PROPANOL Toxicity Data With Reference

ipr-mus LD50:520 mg/kg

JPMSAE Journal of Pharmaceutical Sciences. 60 (1971),799.

1-PHENYL-2-PROPANOL Consensus Reports

Reported in EPA TSCA Inventory.

1-PHENYL-2-PROPANOL Safety Profile

Moderately toxic by intraperitoneal route. When heated to decomposition it emits acrid smoke and irritating vapors.
Safety Statements: 23-24/25:
23: Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer)
24/25: Avoid contact with skin and eyes
RTECS: SG8589500

Product Name

BENZYLMETHYLCARBINOL

Synthetic route

1-PHENYL-2-PROPANOL Chemical Properties

1-PHENYL-2-PROPANOL Uses

1-PHENYL-2-PROPANOL Toxicity Data With Reference

1-PHENYL-2-PROPANOL Consensus Reports

1-PHENYL-2-PROPANOL Safety Profile

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