2-Vinylpyridine supplier | CasNO.100-69-6

Name
2-Vinylpyridine
EINECS 202-879-8
CAS No. 100-69-6
Article Data103
CAS DataBase
Density 0.968 g/cm³
Solubility 2.5 g/100 mL (20 °C) in water
Melting Point -50 °C
Formula C₇H₇N
Boiling Point 160.3 °C at 760 mmHg
Molecular Weight 105.139
Flash Point 46.7 °C
Transport Information UN 3073 6.1/PG 2
Appearance dark brown liquid with an unpleasant odour
Safety 16-23-26-36/37/39-45-28A
Risk Codes 10-20-25-34-42/43
Molecular Structure
Hazard Symbols T,C,F
Synonyms Pyridine,2-vinyl- (8CI);2-Ethenylpyridine;2-Pyridylethylene;NSC18255;a-Vinylpyridine;
PSA 12.89000
LogP 1.72460

Synthetic route

: 1945-84-2
2-ethynylpyridine

: 100-69-6
2-vinylpyridine

Conditions

Conditions	Yield
With hydrogen In toluene at 20℃; under 22801.5 Torr; for 12h; Autoclave; chemoselective reaction;	99%
With hydrogen In toluene at 110℃; under 760.051 Torr; for 24h; Schlenk technique;	87%
With ammonium formate In N,N-dimethyl-formamide at 80℃; Green chemistry;	76%

: 25877-30-9
diethyl-(2-pyridin-2-yl-ethyl)-amine

: 100-69-6
2-vinylpyridine

Conditions

Conditions	Yield
	92.3%

: 1121-60-4
pyridine-2-carbaldehyde

: 18107-18-1
diazomethyl-trimethyl-silane

: 100-69-6
2-vinylpyridine

Conditions

Conditions	Yield
With (IMes)CuCl; triphenylphosphine; isopropyl alcohol In 1,4-dioxane; diethyl ether at 60℃; for 16h;	86%

: 109-09-1
2-chloropyridine

: 7486-35-3
tri-n-butyl(vinyl)tin

: 100-69-6
2-vinylpyridine

Conditions

Conditions	Yield
With cesium fluoride In ethanol; water at 50℃; for 5h; Stille coupling; Inert atmosphere;	82%

: 138428-37-2
2-(pyridin-2-yl)ethyl methanesulfonate

: 100-69-6
2-vinylpyridine

Conditions

Conditions	Yield
With N-benzyl-N,N,N-triethylammonium chloride; sodium hydroxide In water at 40℃; for 2h;	80%
With sodium carbonate

: 593-60-2
Vinyl bromide

: 81745-83-7
pyridin-2-ylzinc(ll) bromide

: 100-69-6
2-vinylpyridine

Conditions

Conditions	Yield
With tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran for 6h; Ambient temperature;	73%

: 103-74-2
2-(2-Hydroxyethyl)pyridine

: 100-69-6
2-vinylpyridine

Conditions

Conditions	Yield
With acetic acid for 12h; Heating;	70%
With sodium tetrafluoroborate; acetic acid In N,N-dimethyl acetamide at 150℃; for 24h; Reagent/catalyst;	64%
With tris(triphenylphosphine)ruthenium(II) chloride; 1,3-bis-(diphenylphosphino)propane; sodium t-butanolate In toluene at 111℃; for 24h; Inert atmosphere;	41%

: 107-13-1
acrylonitrile

: 74-86-2
acetylene

: 100-69-6
2-vinylpyridine

Conditions

Conditions	Yield
borininato-cobalt-COD catalyst at 120℃; under 38253.1 Torr; for 2h;	62%
With (η-1,5-cyclooctadien(<1-6-η-(1-phenylborinato)>cobalt at 120℃; under 38253.1 Torr; for 2.08333h;	61.5%

: 103-74-2
2-(2-Hydroxyethyl)pyridine

: 501-65-5
diphenyl acetylene

A: 100-69-6
2-vinylpyridine

B: 3,4-diphenylquinolizin-5-ium tetrafluoroborate

Conditions

Conditions	Yield
With sodium tetrafluoroborate; dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; copper diacetate; acetic acid In N,N-dimethyl acetamide at 150℃; for 24h; Time;	A 26% B 53%

...Expand

: 4833-24-3
2-ethylpyridine 1-oxide

: 100-69-6
2-vinylpyridine

Conditions

Conditions	Yield
at 800℃; under 0.1 Torr;	45%

: 82198-70-7
1,2-bis(2-pyridyl)ethane N-oxide

A: 110-86-1
pyridine

B: 100-69-6
2-vinylpyridine

C: 109-06-8
α-picoline

D: 4916-40-9
1,2-bis(pyridin-2-yl)ethane

E: 1437-15-6
1,2-bis(2-pyridyl)ethylene

Conditions

Conditions	Yield
at 800℃; under 0.05 - 0.2 Torr; Product distribution; Mechanism;	A 11% B 39% C 11% D 7% E 20%

...Expand

: 56983-98-3
(2-pyridyl)acetaldoxime

A: 110-86-1
pyridine

B: 100-69-6
2-vinylpyridine

C: 109-06-8
α-picoline

D: 100-71-0
2-Ethylpyridine

E: 73177-35-2
2-methyl-1H-pyrrolo<3,2-b>pyridine

F: 4916-40-9
1,2-bis(pyridin-2-yl)ethane

Conditions

Conditions	Yield
at 800℃; under 0.001 - 0.01 Torr; approximate contact time: 0.002-0.03 s;	A 18% B 5% C 32% D 11% E 4% F 32%

...Expand

: 109-06-8
α-picoline

: 67-56-1
methanol

A: 100-69-6
2-vinylpyridine

B: 108-48-5
2,6-dimethylpyridine

C: 100-71-0
2-Ethylpyridine

D: 108-47-4
2,4-lutidine

Conditions

Conditions	Yield
Cs exchanged zeolite at 450℃; Product distribution; investigation of the heterogeneous vapor-phase alkylation of α-picoline with methanol over Na+, K+, Rb+, or Cs+ exchanged X- or Y-type zeolite in an atmosphere of nitrogen;	A 3.1% B 7.3% C 30.2% D 3.6%

...Expand

: 931-19-1
2-methylpyridine N-oxide

A: 110-86-1
pyridine

B: 100-69-6
2-vinylpyridine

C: 109-06-8
α-picoline

D: 1132-37-2
bis(2-pyridyl)methane

E: 4916-40-9
1,2-bis(pyridin-2-yl)ethane

F: 1437-15-6
1,2-bis(2-pyridyl)ethylene

Conditions

Conditions	Yield
at 800℃; under 0.1 - 1 Torr; Product distribution; Mechanism; other temperatures; other pressure; different carriers; various alkyl derivatives of pyridine N-oxides;	A 24% B 7% C 17% D 8% E 26% F 11%

...Expand

: 54856-82-5
3-methyl-[1,2,3]triazolo[1,5-a]pyridine

: 100-69-6
2-vinylpyridine

Conditions

Conditions	Yield
With palladium on activated charcoal In ethanol at 150℃; for 24h; Autoclave;	23%

: 110-86-1
pyridine

: 67-56-1
methanol

A: 100-69-6
2-vinylpyridine

B: 109-06-8
α-picoline

C: 108-89-4
picoline

D: 100-71-0
2-Ethylpyridine

E: 536-75-4
4-Ethylpyridine

F: 108-99-6
3-Methylpyridine

Conditions

Conditions	Yield
Cs exchanged zeolite at 450℃; Product distribution; investigation of the heterogeneous vapor-phase alkylation of pyridine with methanol over Na+, K+, Rb+, or Cs+ exchanged X- or Y-type zeolite in an atmosphere of nitrogen;	A 5.5% B 6.5% C 5% D 22.2% E 5.3% F 3.1%

...Expand

: 54856-82-5
3-methyl-[1,2,3]triazolo[1,5-a]pyridine

: 98-09-9
benzenesulfonyl chloride

: 67-64-1
acetone

A: 100-69-6
2-vinylpyridine

B: 10445-92-8
2-(1-chloroethyl)pyridine

C: 127-63-9
diphenyl sulphone

D: 2116-62-3
2-(2-phenylethyl)pyridine

E: 882-33-7
diphenyldisulfane

F: 103-79-7
1-phenyl-acetone

Conditions

Conditions	Yield
for 80h; Mechanism; Heating;	A n/a B 4% C 6% D n/a E 1% F 3%

...Expand

: 110-86-1
pyridine

: 64-17-5
ethanol

A: 100-69-6
2-vinylpyridine

B: 108-48-5
2,6-dimethylpyridine

C: 536-78-7
3-ethylpyridine

D: 100-71-0
2-Ethylpyridine

E: 536-75-4
4-Ethylpyridine

Conditions

Conditions	Yield
Cs exchanged zeolite at 450℃; Product distribution; investigation of the heterogeneous vapor-phase alkylation of pyridine with ethanol over Na+, K+, Rb+, or Cs+ exchanged X- or Y-type zeolite in an atmosphere of nitrogen;	A 1.3% B 1.1% C 1.1% D 5.9% E 3.2%

...Expand

: 931-19-1
2-methylpyridine N-oxide

A: 110-86-1
pyridine

B: 100-69-6
2-vinylpyridine

C: 109-06-8
α-picoline

D: 4916-40-9
1,2-bis(pyridin-2-yl)ethane

Conditions

Conditions	Yield
at 800℃; under 1 - 5 Torr;	A n/a B 5% C n/a D n/a

...Expand

: 109-06-8
α-picoline

: 50-00-0
formaldehyd

A: 100-69-6
2-vinylpyridine

B: 100-71-0
2-Ethylpyridine

Conditions

Conditions	Yield
With water at 275℃; beim Leiten ueber mit Zinkfluorid impraegniertes Al2O3;
K-ZSM-5 at 300℃; Conversion of starting material;

...Expand

: 109-06-8
α-picoline

: 50-00-0
formaldehyd

A: 100-69-6
2-vinylpyridine

B: 103-74-2
2-(2-Hydroxyethyl)pyridine

Conditions

Conditions	Yield
With sulfuric acid; water; hydrogen at 160℃;

...Expand

: 100-71-0
2-Ethylpyridine

: 100-69-6
2-vinylpyridine

Conditions

Conditions	Yield
With chromium(III) oxide; iron(III) oxide; potassium hydroxide at 700℃; mit Wasserdampf;
With nitrogen; iodine; oxygen at 700℃; beim Leiten ueber Quarz;
With binary vanadium-magnesium catalyst; water; oxygen at 480℃; Product distribution; oxidative dehydrogenation; other alkylpyridines, also in the presence sulfur dioxide, variously modified catalysts, var. temp.;

: 109-04-6
2-bromo-pyridine

: 754-05-2
ethenyltrimethylsilane

A: 100-69-6
2-vinylpyridine

B: 2857-97-8
trimethylsilyl bromide

C: 107-46-0
Hexamethyldisiloxane

D: 106-99-0
buta-1,3-diene

Conditions

Conditions	Yield
bis(η3-allyl-μ-chloropalladium(II)) In tetralin; water; N,N-dimethyl-formamide at 100℃; for 5h; other catalysts: (Ph3P)4Pd, LiPdCl3, (PhCN)2PdCl2, (MeCN)2PdCl2, Pd/C; Et3N presence; Further byproducts given;	A 30 % Chromat. B n/a C n/a D n/a

...Expand

: 5029-67-4
2-iodopyridine

: 754-05-2
ethenyltrimethylsilane

A: 100-69-6
2-vinylpyridine

B: 16029-98-4
trimethylsilyl iodide

C: 107-46-0
Hexamethyldisiloxane

D: 106-99-0
buta-1,3-diene

Conditions

Conditions	Yield
bis(η3-allyl-μ-chloropalladium(II)) In tetralin; water; N,N-dimethyl-formamide at 100℃; for 5h; other catalysts: (Ph3P)4Pd, LiPdCl3, (PhCN)2PdCl2, (MeCN)2PdCl2, Pd/C; Et3N presence; Further byproducts given;	A 23 % Chromat. B n/a C n/a D n/a

...Expand

: 931-19-1
2-methylpyridine N-oxide

A: 110-86-1
pyridine

B: 100-69-6
2-vinylpyridine

C: 109-06-8
α-picoline

D: 1132-37-2
bis(2-pyridyl)methane

E: 4916-40-9
1,2-bis(pyridin-2-yl)ethane

Conditions

Conditions	Yield
at 550 - 800℃; Product distribution; flash vacuum pyrolysis;

...Expand

: 931-19-1
2-methylpyridine N-oxide

A: 100-69-6
2-vinylpyridine

B: 100-71-0
2-Ethylpyridine

C: 586-98-1
2-Hydroxymethylpyridine

D: 1132-37-2
bis(2-pyridyl)methane

E: 4916-40-9
1,2-bis(pyridin-2-yl)ethane

F: 1437-15-6
1,2-bis(2-pyridyl)ethylene

Conditions

Conditions	Yield
at 500 - 800℃; under 0.01 - 0.1 Torr; Product distribution; other pyridine and pyridazine N-oxides;

...Expand

: 107-13-1
acrylonitrile

: 74-86-2
acetylene

A: 100-69-6
2-vinylpyridine

B: 71-43-2
benzene

Conditions

Conditions	Yield
With η6-borinato cobalt complexes at 120 - 160℃; under 37503 Torr; Product distribution;

...Expand

: 110232-64-9
2-[2-([1,3,2]Dioxaphospholan-2-yloxy)-ethyl]-pyridine

: 100-69-6
2-vinylpyridine

Conditions

Conditions	Yield
at 800℃;
at 700℃; under 0.001 Torr;

: 31656-92-5
1-azido-2-methyl-benzene

A: 100-69-6
2-vinylpyridine

B: 16118-22-2
benzylidenamine

C: 64372-87-8
6-Methylene-2,4-cyclohexadien-1-imine

D: 100-47-0
benzonitrile

Conditions

Conditions	Yield
at 800℃;

...Expand

: 100-69-6
2-vinylpyridine

: 108-98-5
thiophenol

: 21070-71-3
phenyl 2-(2-pyridyl)ethyl sulfide

Conditions

Conditions	Yield
at 60℃; for 2.5h; Alkylation;	100%
With zinc(II) nitrate hexahydrate In acetonitrile at 25℃; for 0.166667h; Sealed tube; Green chemistry;	92%
In water at 20℃;	84%
With benzene
unter Zusatz von wenig wss. Benzyl-trimethyl-ammonium-hydroxid-Loesung auf 100grad;

: 100-69-6
2-vinylpyridine

: 100-71-0
2-Ethylpyridine

Conditions

Conditions	Yield
With 5% Pd/C; hydrogen In ethanol at 20℃; for 0.5h; chemoselective reaction;	100%
With 6C53H32O8(4-)13Zr(4+)18O(2-)8Co(2+)8H(1-); hydrogen In tetrahydrofuran at 20℃; under 30003 Torr; for 36h; Catalytic behavior;	99%
With cobalt In tetrahydrofuran Heating; High pressure; chemoselective reaction;	99%

: 100-69-6
2-vinylpyridine

: 956472-60-9
2-(4′-vinylbiphenyl-4-yl)pyridine

poly(2-(4'-vinylbiphenyl-4-yl)pyridine-co-2-vinylpyridine): poly(2-(4'-vinylbiphenyl-4-yl)pyridine-co-2-vinylpyridine)

Conditions

Conditions	Yield
Stage #1: 2-vinylpyridine With (diphenylmethyl)potassium Stage #2: 2-(4′-vinylbiphenyl-4-yl)pyridine at -78℃;	100%

: 100-69-6
2-vinylpyridine

: tris(pentafluorophenyl)aluminum*(toluene)0.5

: 1632067-27-6
(2-vinylpyridine)Al(C6F5)3

Conditions

Conditions	Yield
In toluene at 25℃;	100%

: 100-69-6
2-vinylpyridine

: 5747-23-9
2-phenyl-1,3,2-benzodioxaborole

: 100-71-0
2-Ethylpyridine

Conditions

Conditions	Yield
With oxygen; hydrazine hydrate In acetonitrile at 32℃; under 760.051 Torr; for 3h; Schlenk technique;	100%

: 100-69-6
2-vinylpyridine

: 75-15-0
carbon disulfide

: 109-73-9
N-butylamine

: 2-(pyridin-2-yl)ethyl butylcarbamodithioate

Conditions

Conditions	Yield
In neat (no solvent) at 20℃; for 6h; Green chemistry; regioselective reaction;	100%

...Expand

: 100-69-6
2-vinylpyridine

: 75-15-0
carbon disulfide

: 124-02-7
diallylamine

: 2-(pyridin-2-yl)ethyl diallylcarbamodithioate

Conditions

Conditions	Yield
In neat (no solvent) at 20℃; for 6h; Green chemistry; regioselective reaction;	100%

...Expand

: 100-69-6
2-vinylpyridine

: 75-15-0
carbon disulfide

: 156-87-6
propan-1-ol-3-amine

: 2-(pyridin-2-yl)ethyl 3-hydroxypropylcarbamodithioate

Conditions

Conditions	Yield
In neat (no solvent) at 20℃; for 6h; Green chemistry; regioselective reaction;	100%

...Expand

: 100-69-6
2-vinylpyridine

: 75-15-0
carbon disulfide

: 2393-23-9
4-methoxy-benzylamine

: 2-(pyridin-2-yl)ethyl 4-methoxybenzylcarbamodithioate

Conditions

Conditions	Yield
In neat (no solvent) at 20℃; for 6h; Green chemistry; regioselective reaction;	100%

...Expand

: 100-69-6
2-vinylpyridine

: 75-15-0
carbon disulfide

: 3886-69-9
(R)-1-phenyl-ethyl-amine

: 2-(pyridin-2-yl)ethyl (R)-1-phenylethylcarbamodithioate

Conditions

Conditions	Yield
In neat (no solvent) at 20℃; for 6h; Green chemistry; regioselective reaction;	100%

...Expand

: 100-69-6
2-vinylpyridine

: 75-15-0
carbon disulfide

: 109-89-7
diethylamine

: 2-(pyridin-2-yl)ethyl diethylcarbamodithioate

Conditions

Conditions	Yield
In neat (no solvent) at 20℃; for 6h; Green chemistry; regioselective reaction;	100%

...Expand

: 110-89-4
piperidine

: 100-69-6
2-vinylpyridine

: 75-15-0
carbon disulfide

: 2-(pyridin-2-yl)ethyl piperidine-1-carbodithioate

Conditions

Conditions	Yield
In neat (no solvent) at 20℃; for 6h; Green chemistry; regioselective reaction;	100%

...Expand

: 123-75-1
pyrrolidine

: 100-69-6
2-vinylpyridine

: 75-15-0
carbon disulfide

: 2-(pyridin-2-yl)ethyl pyrrolidine-1-carbodithioate

Conditions

Conditions	Yield
In neat (no solvent) at 20℃; for 6h; Green chemistry; regioselective reaction;	100%

...Expand

: 100-69-6
2-vinylpyridine

: 75-15-0
carbon disulfide

: 107-11-9
1-amino-2-propene

: 2-(pyridin-2-yl)ethyl allylcarbamodithioate

Conditions

Conditions	Yield
In neat (no solvent) at 20℃; for 6h; Green chemistry; regioselective reaction;	100%

...Expand

: 100-69-6
2-vinylpyridine

: 75-15-0
carbon disulfide

: 75-04-7
ethylamine

: 2-(pyridin-2-yl)ethyl ethylcarbamodithioate

Conditions

Conditions	Yield
In neat (no solvent) at 20℃; for 6h; Green chemistry; regioselective reaction;	100%

...Expand

: 100-69-6
2-vinylpyridine

: 75-15-0
carbon disulfide

: 75-31-0
isopropylamine

: 2-(pyridin-2-yl)ethyl isopropylcarbamodithioate

Conditions

Conditions	Yield
In neat (no solvent) at 20℃; for 6h; Green chemistry; regioselective reaction;	100%

...Expand

: 100-69-6
2-vinylpyridine

: 75-15-0
carbon disulfide

: 78-81-9
isobutylamine

: 2-(pyridin-2-yl)ethyl isobutylcarbamodithioate

Conditions

Conditions	Yield
In neat (no solvent) at 20℃; for 6h; Green chemistry; regioselective reaction;	100%

...Expand

: 100-69-6
2-vinylpyridine

: 696-62-8
para-iodoanisole

: 19036-99-8
2-(4-Methoxy-styryl)-pyridin

Conditions

Conditions	Yield
With potassium phosphate; sodium chloride In water; N,N-dimethyl-formamide at 45℃; for 16h; Catalytic behavior; Reagent/catalyst; Micellar solution;	99%
With potassium carbonate; palladium on activated charcoal In N,N-dimethyl-formamide at 100℃;	44%

: 100-69-6
2-vinylpyridine

Reaxys ID: 15741156: Reaxys ID: 15741156

Conditions

Conditions	Yield
With ethyl 2-methyl-2-methyl tellurium propionate; 2,2'-azobis(isobutyronitrile) at 60℃; for 3h; Product distribution / selectivity;	99%

: 100-69-6
2-vinylpyridine

: 626-55-1
3-Bromopyridine

: 13362-75-9
trans-1-(2-pyridyl)-2-(3-pyridyl)ethylene

Conditions

Conditions	Yield
With dicyclohexyl(2',4',6'-triisopropyl-[1,1':3',1''-terphenyl]-2-yl)phosphane; palladium diacetate; sodium hydrogencarbonate In N,N-dimethyl-formamide at 120℃; for 8h; Sealed tube; Inert atmosphere; Glovebox; Schlenk technique;	99%
With monophosphine 1,2,3,4,5-pentaphenyl-1'-(di-tert-butylphosphino)ferrocene; palladium diacetate; sodium hydrogencarbonate In N,N-dimethyl-formamide at 120℃; for 4h; Reagent/catalyst; Heck Reaction; Inert atmosphere;	99%
With C18H21N3O2Pd; tetrabutylammomium bromide; caesium carbonate In N,N-dimethyl acetamide at 150℃; for 15h; Heck Reaction; Sealed tube;	60%

: 100-69-6
2-vinylpyridine

: (E)-1-(pyridin-2-yl)-N-(4-styrylbenzyl)methanamine

: (E)-2-(pyridin-2-yl)-N-(pyridin-2-ylmethyl)-N-(4-styrylbenzyl)-ethanamine

Conditions

Conditions	Yield
With acetic acid In ethanol for 36h; Reflux;	99%

: 100-69-6
2-vinylpyridine

: 23516-84-9
2,2,2-trifluoro-1-(4-iodophenyl)ethan-1-one

: 1,1,1-trifluoro-2-(4-iodophenyl)-4-(pyridin-2-yl)butan-2-ol

Conditions

Conditions	Yield
With diphenyl hydrogen phosphate; diethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate In dichloromethane at 20℃; Irradiation; Inert atmosphere;	99%

: 100-69-6
2-vinylpyridine

: 4559-70-0
Diphenylphosphine oxide

: 25898-97-9
α-<2-(diphenylphosphinyl)ethyl>pyridine

Conditions

Conditions	Yield
With pyridine; lanthanum tris(N,N-dimethylbenzylamine) at 80℃; for 16h; Glovebox; regioselective reaction;	98%
at 120℃; for 1h; microwave irradiation;	88%
With silver fluoride In N,N-dimethyl-formamide at 110℃; for 24h;	80%
In benzene at 140℃; for 3.5h;	78%
With oxygen at 80℃; for 12h;	95 % Spectr.

: 100-69-6
2-vinylpyridine

: 696-63-9
4-Methoxybenzenethiol

: 4-methoxyphenyl 2-(2-pyridyl)ethyl sulfide

Conditions

Conditions	Yield
at 60℃; for 2.5h; Alkylation;	98%

: 100-69-6
2-vinylpyridine

: 106-54-7
p-Chlorothiophenol

: 2-(2-((4-chlorophenyl)thio)ethyl)pyridine

Conditions

Conditions	Yield
In neat (no solvent) at 40℃; for 0.5h;	98%
at 60℃; for 2.5h; Alkylation;	93%

: 100-69-6
2-vinylpyridine

: 75-15-0
carbon disulfide

: 100-46-9
benzylamine

: 21172-92-9
2-(pyridin-2-yl)ethyl benzylcarbamodithioate

Conditions

Conditions	Yield
In neat (no solvent) at 20℃; for 6h; Green chemistry; regioselective reaction;	98%

...Expand

: 100-69-6
2-vinylpyridine

: C17H16BN2(1+)*C24BF20(1-)

: C24H23BN3(1+)*C24BF20(1-)

Conditions

Conditions	Yield
In chloroform Inert atmosphere; Schlenk technique;	98%

: 100-69-6
2-vinylpyridine

: 254454-54-1
tert-butyl-3-iodoazetidine-1-carboxylate

: tert-butyl 3-(2-(pyridin-2-yl)ethyl)azetidine-1-carboxylate

Conditions

Conditions	Yield
With triethylamine In water; acetonitrile at 20℃; for 16h; Irradiation; chemoselective reaction;	98%

: 123-75-1
pyrrolidine

: 100-69-6
2-vinylpyridine

: 6311-90-6
2-[2-(pyrrolidin-1-yl)ethyl]pyridine

Conditions

Conditions	Yield
With (dpp-BIAN)Mg(THF)3 In benzene-d6 at 20℃; for 4.1h; Reagent/catalyst; Time; Inert atmosphere; Schlenk technique;	97%
With NPs-Fe3O4-DE-bmim3PW In dichloromethane at 20℃; for 2h;	90%
With ferrocene; C42H48N2Si2Y(1-)*C16H32LiO4(1+) In benzene-d6 at 130℃; for 0.08h; Inert atmosphere; Glovebox;	84%

2-Vinylpyridine Consensus Reports

Reported in EPA TSCA Inventory.

2-Vinylpyridine Specification

The 2-Vinylpyridine, with the CAS registry number 100-69-6, is also known as 2VP. It belongs to the product categories of Pyridines Derivates; Monomers; Polymer Science; Vinyl Halides, Amines, Amides, and Other Vinyl Monomers; C7 and C8; Heterocyclic Building Blocks; Pyridines. Its EINECS registry number is 202-879-8. This chemical's molecular formula is C₇H₇N and molecular weight is 105.13718. Its IUPAC name is called 2-ethenylpyridine. The product can be used to prepare modification latex of vinyl pyridine with butadiene or styrene copolymerization. In addition, it also can be used for binder. 2-Vinylpyridine is a useful intermediate for the production of polymers.

Physical properties of 2-Vinylpyridine: (1)ACD/LogP: 1.34; (2)ACD/LogD (pH 5.5): 1.23; (3)ACD/LogD (pH 7.4): 1.34; (4)ACD/BCF (pH 5.5): 4.78; (5)ACD/BCF (pH 7.4): 6.1; (6)ACD/KOC (pH 5.5): 99.31; (7)ACD/KOC (pH 7.4): 126.9; (8)#H bond acceptors: 1; (9)#Freely Rotating Bonds: 1; (10)Index of Refraction: 1.562; (11)Molar Refractivity: 35.26 cm³; (12)Molar Volume: 108.6 cm³; (13)Surface Tension: 36.1 dyne/cm; (14)Density: 0.968 g/cm³; (15)Flash Point: 46.7 °C; (16)Enthalpy of Vaporization: 38.05 kJ/mol; (17)Boiling Point: 160.3 °C at 760 mmHg; (18)Vapour Pressure: 3.13 mmHg at 25°C.

Preparation of 2-Vinylpyridine: this chemical can be obtained from 2-hydroxyethyl pyridine by dehydration.

2-Vinylpyridine can be obtained from 2-hydroxyethyl pyridine by dehydration

Uses of 2-Vinylpyridine: it can be used to produce 4-chlorophenyl 2-(2-pyridyl)ethyl sulfide at temperature of 60 °C. This reaction is a kind of Alkylation. It will need 2.5 hours. The yield is about 93%.

2-Vinylpyridine can be used to produce 4-chlorophenyl 2-(2-pyridyl)ethyl sulfide

When you are using this chemical, please be cautious about it as the following:
This chemical may destroy living tissue on contact and may cause burns. In case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice. Whenever you will contact it, please wear suitable protective clothing, gloves and eye/face protection.

You can still convert the following datas into molecular structure:
(1)Canonical SMILES: C=CC1=CC=CC=N1
(2)InChI: InChI=1S/C7H7N/c1-2-7-5-3-4-6-8-7/h2-6H,1H2
(3)InChIKey: KGIGUEBEKRSTEW-UHFFFAOYSA-N

The toxicity data is as follows:

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Source
guinea pig	LDLo	skin	500mg/kg (500mg/kg)	"Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986Vol. -, Pg. 845, 1986.
mammal (species unspecified)	LD50	oral	415mg/kg (415mg/kg)	Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 39(4), Pg. 86, 1974.
mouse	LC50	inhalation	460mg/m³ (460mg/m³)	Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 10(3), Pg. 9, 1966.
mouse	LD50	oral	420mg/kg (420mg/kg)	Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 10(3), Pg. 9, 1966.
rat	LC50	inhalation	610mg/m³ (610mg/m³)	Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 57(9-10), Pg. 64, 1992.
rat	LD50	oral	100mg/kg (100mg/kg)	"Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986Vol. -, Pg. 845, 1986.

Product Name

2-Vinylpyridine

Synthetic route

2-Vinylpyridine Consensus Reports

2-Vinylpyridine Specification

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