4-Phenylphenol supplier | CasNO.92-69-3

Name
4-Phenylphenol
EINECS 202-179-2
CAS No. 92-69-3
Article Data489
CAS DataBase
Density 1.111 g/cm³
Solubility 0.7 g/L (20 °C) in water
Melting Point 164-166 °C(lit.)
Formula C₁₂H₁₀O
Boiling Point 306.387 °C at 760 mmHg
Molecular Weight 170.211
Flash Point 147.175 °C
Transport Information UN 3077
Appearance Light tan solid (odour threshold detection limit 0.7 ppm)
Safety 26-36/37-61-36
Risk Codes 36/37/38-51/53-38
Molecular Structure
Hazard Symbols Xi, N
Synonyms 4-Biphenylol(8CI);4-Diphenylol;4-Hydroxy-1,1'-biphenyl;4-Hydroxybiphenyl;4-Hydroxydiphenyl;[1,1'-Biphenyl]-4-ol;MK 1100;NSC 1858;P-PP;Paraxenol;TetrosinP 300;p-Biphenylol;p-Hydroxybiphenyl;p-Hydroxydiphenyl;p-Phenylphenol;p-Xenol;
PSA 20.23000
LogP 3.05920

Synthetic route

: 212687-68-8
2-(phenylethynyl)-3-vinyloxirane

: 92-69-3
4-Phenylphenol

Conditions

Conditions	Yield
In tetrachloromethane at 160℃; for 1h; Mechanism; sealed tube;	100%

: 72536-28-8
2-ethynyl-1-formyl-2-phenylcyclopropane

: 92-69-3
4-Phenylphenol

Conditions

Conditions	Yield
In tetrachloromethane at 130℃; for 1h; Mechanism; sealed tube;	100%

: 106-41-2
4-bromo-phenol

: 98-80-6
phenylboronic acid

: 92-69-3
4-Phenylphenol

Conditions

Conditions	Yield
With potassium carbonate In water at 70℃; for 1h; Suzuki-Miyaura Coupling;	100%
With [{PdCl(2-(2-thiophenyl)-4,4-dimethyloxazoline)}2]; potassium carbonate In water at 90℃; for 2h; Catalytic behavior; Reagent/catalyst; Suzuki-Miyaura Coupling;	100%
With potassium carbonate; Pd/PS-co-PAEMA-co-PMAA In water at 90℃; for 1h; Suzuki reaction;	99%

: 129236-45-9
[1,1′-biphenyl]-4-yl methanesulfonate

: 92-69-3
4-Phenylphenol

Conditions

Conditions	Yield
With sodium phosphate In aq. phosphate buffer; water; dimethyl sulfoxide at 25℃; for 0.333333h; pH=7.5; Enzymatic reaction;	100%
In cyclohexane Kinetics; Solvent; Photolysis; Inert atmosphere;

: 540-38-5
4-Iodophenol

: 98-80-6
phenylboronic acid

: 92-69-3
4-Phenylphenol

Conditions

Conditions	Yield
With caesium carbonate; polymer-supported PEG-N-heterocyclic carbene Pd In water at 50℃; for 12h; Suzuki reaction;	99%
With potassium carbonate; [PS-PEG-adppp-Pd(η3-C3H5)]Cl In water at 50℃; for 12h; Suzuki-Miyaura coupling;	99%
With potassium carbonate; 10percent Pd/C In water at 20℃; for 12h; Suzuki-Miyaura coupling reaction;	99%

: 106-41-2
4-bromo-phenol

: 143-66-8
sodium tetraphenyl borate

: 92-69-3
4-Phenylphenol

Conditions

Conditions	Yield
With air; Pd-sepiolite; sodium carbonate; palladium In water at 20℃; for 5h; Product distribution; Further Variations:; Reagents; Reaction partners;	99%
With palladium diacetate; sodium carbonate In water for 0.5h; Ambient temperature;	98%
With sodium carbonate at 80℃; for 0.666667h; Green chemistry;	98%

: 106-41-2
4-bromo-phenol

: potassium phenyltrifluoborate

: 92-69-3
4-Phenylphenol

Conditions

Conditions	Yield
With water; palladium diacetate; sodium carbonate at 80℃; for 4h; Suzuki Coupling; Green chemistry;	99%
With palladium diacetate; sodium carbonate; 3-butyl-1-methyl-1H-imidazol-3-ium hexafluorophosphate In water at 80℃; for 6h; Suzuki-Miyaura Coupling;	92%
With 5%-palladium/activated carbon; oxygen; potassium carbonate In ethanol; water at 80℃; for 0.5h; Suzuki-Miyaura Coupling;	91%

: 106-48-9
4-chloro-phenol

: 98-80-6
phenylboronic acid

: 92-69-3
4-Phenylphenol

Conditions

Conditions	Yield
With potassium carbonate In water at 25℃; for 10h; Suzuki-Miyaura Coupling;	99%
With potassium phosphate; tetrabutylammomium bromide In water at 95℃; for 20h; Suzuki Coupling;	95%
With tetrabutyl ammonium fluoride; potassium carbonate In water at 100℃; for 9h; Suzuki-Miyaura coupling;	94%

: 540-38-5
4-Iodophenol

: 5720-05-8
4-methylphenylboronic acid

: 92-69-3
4-Phenylphenol

Conditions

Conditions	Yield
With sodium hydroxide; tetrabutylammomium bromide; palladium on activated charcoal at 100℃; for 2h; Suzuki-Miyaura cross-coupling;	99%

: 84954-30-3
4-benzyloxybiphenyl

: 92-69-3
4-Phenylphenol

Conditions

Conditions	Yield
With 1-n-butyl-3-methylimidazolim bromide at 200 - 220℃; for 0.0416667h; Temperature; Time; Microwave irradiation; Inert atmosphere;	99%
With pyridine hydrochloride at 200℃; for 0.333333h; Microwave irradiation; Ionic liquid;	91%
With cyclohexa-1,4-diene; 3,6-bis(dimethylamino)-9H-carbazole; caesium carbonate In dimethyl sulfoxide at 23℃; for 48h; Inert atmosphere; Schlenk technique; Irradiation;	70%
With triethylsilane; bis(1,5-cyclooctadiene)nickel (0); C28H41N2(1+)*Cl(1-); sodium t-butanolate In toluene at 140℃; for 3h; Reagent/catalyst; Temperature; Glovebox; chemoselective reaction;	99 %Spectr.

: 1591-31-7
4-iodo-biphenyl

: 92-69-3
4-Phenylphenol

Conditions

Conditions	Yield
With water; ethylene glycol; potassium hydroxide; copper dichloride In dimethyl sulfoxide at 120℃; for 24h; Reagent/catalyst; Temperature; Inert atmosphere;	99%
Stage #1: 4-iodo-biphenyl With copper(l) iodide; cesiumhydroxide monohydrate; 1,3-diphenylpropanedione In water; dimethyl sulfoxide at 130℃; for 24h; Inert atmosphere; Stage #2: With hydrogenchloride In dichloromethane; water; dimethyl sulfoxide at 20℃; Inert atmosphere; chemoselective reaction;	95%
Stage #1: 4-iodo-biphenyl With copper(l) iodide; 8-Hydroxyquinoline-N-oxide In dimethyl sulfoxide at 20℃; for 0.166667h; Inert atmosphere; Stage #2: With cesiumhydroxide monohydrate In water; dimethyl sulfoxide at 100℃; for 36h; Inert atmosphere;	93%

: 447464-29-1
[1,1'-biphenyl]-4-yl tert-butyl carbonate

: 92-69-3
4-Phenylphenol

Conditions

Conditions	Yield
With 1,1,3,3-Tetramethyldisiloxane; pyrographite; palladium dichloride In 1,2-dimethoxyethane at 25 - 40℃; for 6h;	99%
Stage #1: tert-butyl 4-biphenylcarbonate With (μ3,η2,η3,η5-acenaphthylene)Ru3(CO)7; Dimethylphenylsilane In 1,2-dimethoxyethane at 40℃; for 7h; Inert atmosphere; Stage #2: With tetrabutyl ammonium fluoride In diethyl ether at 20℃; for 1h; Inert atmosphere;	93%

: 5122-94-1
4-biphenylboronic acid

: 92-69-3
4-Phenylphenol

Conditions

Conditions	Yield
With [Rh2(bpy)2(μ-OAc)2(OAc)2]; oxygen; N-ethyl-N,N-diisopropylamine In N,N-dimethyl-formamide under 760.051 Torr; for 18h; Catalytic behavior; Reagent/catalyst; Solvent; Irradiation;	99%
With oxygen; triethylamine In acetonitrile at 20℃; under 760.051 Torr; for 4h; Reagent/catalyst; Irradiation;	99%
With dihydrogen peroxide In acetonitrile at 30 - 35℃; for 0.0833333h; Schlenk technique;	98%

: 6734-90-3
biphenyl-4-yl-propyl ether

: 92-69-3
4-Phenylphenol

Conditions

Conditions	Yield
With 1-n-butyl-3-methylimidazolim bromide at 200 - 220℃; for 0.5h; Microwave irradiation; Inert atmosphere;	99%

: 19070-95-2
2-(4-phenylphenoxy)-ethanol

: 92-69-3
4-Phenylphenol

Conditions

Conditions	Yield
With potassium hydroxide In dimethyl sulfoxide at 100℃; for 3h; Schlenk technique;	99%

: 613-37-6
4-methoxylbiphenyl

: 92-69-3
4-Phenylphenol

Conditions

Conditions	Yield
With 1-n-butyl-3-methylimidazolim bromide at 220℃; for 0.666667h; Inert atmosphere; Microwave irradiation;	98%
With pyridine hydrochloride at 200℃; for 0.916667h; Microwave irradiation; Ionic liquid;	97%
With 1-n-butyl-3-methylimidazolim bromide; toluene-4-sulfonic acid; 1-butyl-3-methylimidazolium Tetrafluoroborate at 115℃; for 20h;	95%

: ([1,1′-biphenyl]-4-yloxy)(tert-butyl)dimethylsilane

: 92-69-3
4-Phenylphenol

Conditions

Conditions	Yield
With copper(ll) bromide In acetonitrile at 20℃; for 5h;	98%
With aluminum oxide; potassium fluoride In 1,2-dimethoxyethane at 25℃; for 4h;	95%

: 115298-64-1
tert-butyl 4-biphenyl ether

: 92-69-3
4-Phenylphenol

Conditions

Conditions	Yield
With 1,1,3,3-Tetramethyldisiloxane; pyrographite; palladium dichloride In 1,2-dimethoxyethane at 25 - 40℃; for 20h;	98%
Stage #1: tert-butyl 4-biphenyl ether With (μ3,η2,η3,η5-acenaphthylene)Ru3(CO)7; Dimethylphenylsilane In 1,2-dimethoxyethane at 40℃; for 20h; Inert atmosphere; Stage #2: With tetrabutyl ammonium fluoride In diethyl ether at 20℃; for 1h; Inert atmosphere;	95%

: 106-41-2
4-bromo-phenol

: 639-58-7
triphenyltin chloride

: 92-69-3
4-Phenylphenol

Conditions

Conditions	Yield
With potassium carbonate for 0.66h; Stille Cross Coupling;	98%
With sodium carbonate at 80℃; for 0.75h; Catalytic behavior; Stille Cross Coupling;	97%
With sodium carbonate at 80℃; for 0.833333h; Catalytic behavior; Stille Cross Coupling;	95%

: 15231-91-1
6-bromo-naphthalen-2-ol

: 98-80-6
phenylboronic acid

: 92-69-3
4-Phenylphenol

Conditions

Conditions	Yield
With C29H25N6O2Pd(1+)*BF4(1-); potassium carbonate In N,N-dimethyl-formamide at 120℃; for 20h; Suzuki-Miyaura Coupling;	98%

: p-biphenyl allyl carbonate

: 92-69-3
4-Phenylphenol

Conditions

Conditions	Yield
With trisodium tris(3-sulfophenyl)phosphine; water; diethylamine; palladium diacetate; heptakis(2,6-di-O-methyl)cyclomaltoheptaose In toluene at 20℃; for 0.5h; Substitution;	97%

: 108-86-1
bromobenzene

: 71597-85-8
(p-hydroxyphenyl)boronic acid

: 92-69-3
4-Phenylphenol

Conditions

Conditions	Yield
With potassium carbonate In ethanol; water at 80℃; for 10h; Catalytic behavior; Suzuki Coupling;	96.4%
With potassium carbonate In water at 20℃; for 0.5h; Suzuki-Miyaura Coupling;	95%
With trans-[PdBr2(1-(3-triethylammonium)propyl-4-mesityl-1,2,4-triazolin-5-ylidene)2]Br2; potassium carbonate In water; isopropyl alcohol at 80℃; for 2h; Catalytic behavior; Suzuki-Miyaura Coupling;	94%

: 20281-44-1
4-allyloxy-biphenyl

: 92-69-3
4-Phenylphenol

Conditions

Conditions	Yield
With trisodium tris(3-sulfophenyl)phosphine; water; diethylamine; palladium diacetate; heptakis(2,6-di-O-methyl)cyclomaltoheptaose In toluene at 20℃; for 100h; Substitution;	96%
Stage #1: 4-allyloxy-biphenyl With C12H37NiP4(1+)*C2F6NO4S2(1-) In tetrahydrofuran at 20℃; for 0.5h; Glovebox; Schlenk technique; Inert atmosphere; Stage #2: With toluene-4-sulfonic acid In tetrahydrofuran for 10h; Glovebox; Schlenk technique; Reflux; Inert atmosphere;	85%
With titanium(III) chloride; iodine; lithium In tetrahydrofuran at -10℃; for 1h;	83%
With titanium(III) chloride; lithium In tetrahydrofuran Product distribution; effects of I2 addition and temperature;

: 540-38-5
4-Iodophenol

: phenylmagnesium bromide

: 92-69-3
4-Phenylphenol

Conditions

Conditions	Yield
With tris(dibenzylideneacetone)dipalladium (0); N,N′-bis(2,6-diisopropylphenyl)imidazol-2-ylidene hydrochloride In tetrahydrofuran; 1,4-dioxane at 80℃; for 3h; Phenylation;	96%
With 1,3-bis[(diphenylphosphino)propane]dichloronickel(II) In diethyl ether; benzene for 30h; Substitution; Wuertz-Grignard reaction; Heating;	65%

: 106-41-2
4-bromo-phenol

: 540-38-5
4-Iodophenol

(C6H5)4BNa: (C6H5)4BNa

: 92-69-3
4-Phenylphenol

Conditions

Conditions	Yield
With palladium diacetate; sodium carbonate In water at 20℃; for 3h;	96%

...Expand

: 591-50-4
iodobenzene

: 71597-85-8
(p-hydroxyphenyl)boronic acid

: 92-69-3
4-Phenylphenol

Conditions

Conditions	Yield
With 2,2′-(1,2-phenylene)bis(4,4-di-methyl-4,5-dihydrooxazole)-N,N′-dichloridopalladium(II); potassium carbonate In water; N,N-dimethyl-formamide at 20℃; for 0.3h; Suzuki-Miyaura Coupling;	96%
With potassium carbonate In water at 20℃; for 0.5h; Suzuki-Miyaura Coupling;	95%
With sodium carbonate In N,N-dimethyl-formamide at 110℃; for 24h; Suzuki Coupling;	94%

: 106-41-2
4-bromo-phenol

: 1078-58-6
diphenylzinc

: 92-69-3
4-Phenylphenol

Conditions

Conditions	Yield
With dichloro{bis[1-(dicyclohexylphosphanyl)piperidine]}palladium(II) In tetrahydrofuran; 1-methyl-pyrrolidin-2-one at 100℃; for 0.25h; Negishi cross-coupling reaction; In air;	96%
With catalyst 1 (aliphatic, phosphine based pincer complex of palladium) In 1,4-dioxane; 1-methyl-pyrrolidin-2-one at 100℃; for 0.5h; Negishi cross-coupling reaction;	89%

: 106-41-2
4-bromo-phenol

: 960-16-7
tributylphenylstannane

: 92-69-3
4-Phenylphenol

Conditions

Conditions	Yield
With 4,4’‐bis(trimethylammoniummethyl)‐2,2’‐bipyridine; diamminedichloropalladium(II); sodium hydrogencarbonate In water at 110℃; for 12h; Catalytic behavior; Stille Cross Coupling; Sealed tube;	96%
With [Zn4O(2-aminoterephthalate)2.79(2-pyridyl-imine terephthalate-PdCl2)0.21]; lithium chloride In ethanol at 80℃; for 3h; Stille Cross Coupling;	82%
With dmap; palladium dichloride for 0.333333h; Stille Cross Coupling; Microwave irradiation;	57%

: 71597-85-8
(p-hydroxyphenyl)boronic acid

: 215438-84-9
(ethyl)diphenylsulfonium triflate

: 92-69-3
4-Phenylphenol

Conditions

Conditions	Yield
With bis(tri-t-butylphosphine)palladium(0); sodium hydrogencarbonate In N,N-dimethyl-formamide at 60℃; for 6h; Suzuki-Miyaura Coupling; Inert atmosphere; Glovebox; Sealed tube;	96%

: 92-69-3
4-Phenylphenol

: 124-63-0
methanesulfonyl chloride

: 129236-45-9
[1,1′-biphenyl]-4-yl methanesulfonate

Conditions

Conditions	Yield
With pyridine In dichloromethane Acylation;	100%
With triethylamine In dichloromethane at 0℃; for 0.283333h; Inert atmosphere; Schlenk technique;	99%
With triethylamine In dichloromethane at 0℃; for 0.5h;	97%

: 92-69-3
4-Phenylphenol

: 109-70-6
1,3-chlorobromopropane

: 99472-05-6
4-(3-chloropropoxy)-1,1'-biphenyl

Conditions

Conditions	Yield
With potassium carbonate In acetone for 24h; Williamson Ether Synthesis; Reflux;	100%
With potassium carbonate In acetone for 24h; Heating;	71%
With potassium carbonate In acetone for 24h; Heating;	70%

: 92-69-3
4-Phenylphenol

: 4091-39-8
3-chloro-2-butanone

: 28089-74-9
3-(4-phenylphenoxy)butan-2-one

Conditions

Conditions	Yield
Stage #1: 4-Phenylphenol With 18-crown-6 ether; potassium carbonate In butanone at 20℃; for 0.5h; Inert atmosphere; Stage #2: 3-chloro-2-butanone In butanone at 20℃; for 23h; Inert atmosphere;	100%
With potassium carbonate In acetone
With potassium carbonate; potassium iodide In butanone at 20℃; for 12h;

: 92-69-3
4-Phenylphenol

: C12H9(2)HO

Conditions

Conditions	Yield
With sulfuric acid-d2 In acetic acid for 3h; Heating;	100%

: 92-69-3
4-Phenylphenol

: 79-22-1
methyl chloroformate

: 17175-08-5
biphenyl-4-yl methyl carbonate

Conditions

Conditions	Yield
With pyridine In dichloromethane Acylation;	100%
With triethylamine In tert-butyl methyl ether at 23℃; for 1h;	92%

: 92-69-3
4-Phenylphenol

: 75-36-5
acetyl chloride

: 148-86-7
4-acetoxybiphenyl

Conditions

Conditions	Yield
With pyridine In dichloromethane for 3h;	100%
With triethylamine In 1,2-dichloro-ethane at 20 - 70℃; for 0.5h;	100%
Stage #1: 4-Phenylphenol With pyridine In dichloromethane for 0.166667h; Stage #2: acetyl chloride In dichloromethane at 20℃; for 4h;	95.9%

: 92-69-3
4-Phenylphenol

: 13139-14-5
Boc-Trp-OH

: (S)-biphenyl-4-yl 2-(tert-butoxycarbonylamino)-3-(1H-indol-3-yl)propanoate

Conditions

Conditions	Yield
With dmap; 2-chloro-1-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)pyridinium trifluoromethanesulfonate; triethylamine In dichloromethane at 20℃; for 1h;	100%
With N-(methylpolystyrene)-4-(methylamino)pyridine; TEA; (2-chloro-1-pyridinio)-(Wang resin) triflate In dichloromethane for 2h;

: 92-69-3
4-Phenylphenol

: 5241-64-5, 13139-14-5, 112525-72-1
BOC-tryptophane

: C28H28N2O4

Conditions

Conditions	Yield
With dmap; triethylamine In dichloromethane at 20℃; for 1h;	100%

: 1450-14-2
1,1,1,2,2,2-hexamethyldisilane

: 92-69-3
4-Phenylphenol

: 1023-13-8
4-phenylphenol trimethylsilyl ether

Conditions

Conditions	Yield
In pyridine at 115℃; for 3h;	100%

: 760-93-0
methacryloyl anhydride

: 92-69-3
4-Phenylphenol

: 46904-74-9
[1,1'-biphenyl]-4-ylmethacrylate

Conditions

Conditions	Yield
With dmap; 2,6-di-tert-butyl-4-methyl-phenol In toluene at 80℃; for 40h;	100%

: 92-69-3
4-Phenylphenol

: C15H15BrN3Pol

: C27H24N3OPol

Conditions

Conditions	Yield
With pyridine; copper(I) bromide dimethylsulfide complex; sodium carbonate In acetonitrile at 75℃; for 48h; Inert atmosphere; solid phase reaction;	100%

: 92-69-3
4-Phenylphenol

: 40400-13-3
2-Iodobenzyl bromide

: 1332326-18-7
4-(2-iodobenzyloxy)-1-phenylbenzene

Conditions

Conditions	Yield
With potassium carbonate In acetone at 50℃;	100%

: 92-69-3
4-Phenylphenol

: ethyl 1-[1-(3-hydroxypropyl)-7-methoxy-1H-pyrazolo[4,3-d]pyrimidin-5-yl]-1H-pyrazole-4-carboxylate

: ethyl 1-{1-[3-(biphenyl-4-yloxy)propyl]-7-methoxy-1H-pyrazolo[4,3-d]pyrimidin-5-yl}-1H-pyrazole-4-carboxylate

Conditions

Conditions	Yield
With di-isopropyl azodicarboxylate; triphenylphosphine In tetrahydrofuran; toluene	100%

: 92-69-3
4-Phenylphenol

: 885-82-5
4-phenyl-2-nitrophenol

Conditions

Conditions	Yield
With tetrachlorosilane; silica gel; sodium nitrite In dichloromethane at 20℃; for 2h;	99%
With silica gel; citric acid; sodium nitrite In hexane at 20℃; for 3h;	99%
With nitric acid In acetic acid	99%

: 92-69-3
4-Phenylphenol

: 3282-30-2
pivaloyl chloride

: 188114-77-4
(1,1'-biphenyl)-4-yl pivalate

Conditions

Conditions	Yield
With dmap; triethylamine In dichloromethane at 0℃; for 0.3h; Inert atmosphere;	99%
With dmap; triethylamine Sealed tube; Inert atmosphere;	85%
With triethylamine In dichloromethane at 0 - 20℃; Inert atmosphere; Sealed tube;	79%

: 92-69-3
4-Phenylphenol

: 98-88-4
benzoyl chloride

: 2170-13-0
biphenyl 4-yl benzoate

Conditions

Conditions	Yield
With pyridine for 0.5h; Heating;	99%
With triethylamine In tetrahydrofuran at 0 - 20℃; for 24h;	93%
In pyridine for 1.16667h; Cooling with ice;	92%

: 92-69-3
4-Phenylphenol

: 108-90-7
chlorobenzene

: 3933-94-6
4-Phenoxybiphenyl

Conditions

Conditions	Yield
With potassium carbonate In N,N-dimethyl-formamide at 110℃; for 12h;	99%
With potassium hydroxide; copper at 375 - 400℃;

: 92-69-3
4-Phenylphenol

: 74-88-4
methyl iodide

: 613-37-6
4-methoxylbiphenyl

Conditions

Conditions	Yield
With potassium carbonate Sealed tube; Inert atmosphere;	99%
With sodium hydroxide; acetone

: 50-00-0
formaldehyd

: 92-69-3
4-Phenylphenol

: 109-89-7
diethylamine

: 123380-99-4
2,6-Bis<(diethylamino)methyl>-4-phenylphenol

Conditions

Conditions	Yield
With sodium hydroxide In ethanol; water for 30h; Heating;	99%

...Expand

: 92-69-3
4-Phenylphenol

: 35787-71-4
thianthrene cation radical perchlorate

: 5-(4-Hydroxy-biphenyl-3-yl)-thianthren-5-ium; perchlorate

Conditions

Conditions	Yield
In acetonitrile for 3h;	99%

: 92-69-3
4-Phenylphenol

: 159405-16-0
(R)-2-Fluoropropanoic acid chloride

: (R)-2-Fluoro-propionic acid biphenyl-4-yl ester

Conditions

Conditions	Yield
With pyridine In dichloromethane Esterification;	99%

4-Phenylphenol Chemical Properties

Molecular Formula: C₁₂H₁₀O
Molecular Weight: 170.21
EINECS: 202-179-2
Melting point: 164-166 °C(lit.)
Boiling Point: 306.4 °C at 760 mmHg
Flash Point: 147.2 °C
Index of Refraction: 1.604
Molar Refractivity: 52.72 cm³
Molar Volume: 153.1 cm³
Surface Tension: 44.5 dyne/cm
Density: 1.111 g/cm³
Storage temp.: 0-6 °C
Water Solubility: 0.7 g/L (20 °C)
Enthalpy of Vaporization: 56.87 kJ/mol
Vapour Pressure: 0.000428 mmHg at 25 °C
Stability: Stable. Incompatible with strong oxidizing agents, strong bases, halogens. Combustible.
Structure of 4-Phenylphenol (CAS NO.92-69-3):

IUPAC Name: 4-Phenylphenol
Canonical SMILES: C1=CC=C(C=C1)C2=CC=C(C=C2)O
InChI: InChI=1S/C12H10O/c13-12-8-6-11(7-9-12)10-4-2-1-3-5-10/h1-9,13H
InChIKey: YXVFYQXJAXKLAK-UHFFFAOYSA-N
Product Category of 4-Phenylphenol (CAS NO.92-69-3): Industrial/Fine Chemicals;Organics;Phenoles and thiophenoles;Color Former & Related Compounds;Developer;Functional Materials

4-Phenylphenol Uses

4-Phenylphenol (CAS NO.92-69-3) is used for dyes, resins and rubber intermediates.

4-Phenylphenol Toxicity Data With Reference

ipr-mus LD50:150 mg/kg

NTIS** National Technical Information Service. (Springfield, VA 22161) (Formerly U.S. Clearinghouse for Scientific and Technical Information) AD691-490 .

4-Phenylphenol Consensus Reports

Reported in EPA TSCA Inventory.

4-Phenylphenol Safety Profile

Acute poison by intraperitoneal route. Questionable carcinogen with experimental carcinogenic and tumorigenic data. When heated to decomposition it emits acrid, irritating fumes.
The Hazard Codes: Xi, N
HazardClass: 9
The Risk Statements:
38: Irritating to the skin
51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
36/37/38: Irritating to eyes, respiratory system and skin
The Safety Statements:
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36: Wear suitable protective clothing
61: Avoid release to the environment. Refer to special instructions safety data sheet
36/37: Wear suitable protective clothing and gloves
RIDADR: UN3077
WGK Germany: 2
RTECS: DV5850000
PackingGroup: III
HS Code: 29071900

4-Phenylphenol Specification

4-Phenylphenol , its cas register number is 92-69-3. It also can be called 4-Biphenylol ; 4-Hydroxybiphenyl ; and 1-Hydroxy-4-phenylbenzene . It is hazardous, so the first aid measures and others should be known. Such as: When on the skin: first, should flush skin with plenty of water immediately for at least 15 minutes while removing contaminated clothing. Secondly, get medical aid. Or in the eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Then get medical aid soon. While, it's inhaled: Remove from exposure and move to fresh air immediately. Give artificial respiration while not breathing. When breathing is difficult, give oxygen. And as soon as to get medical aid. Then you have the ingesting of the product: Wash mouth out with water, and get medical aid immediately. Notes to physician: Treat supportively and symptomatically.
In addition, 4-Phenylphenol (CAS NO.92-69-3) could be stable under normal temperatures and pressures. It is not compatible with strong oxidizing agents, and you must not take it with incompatible materials. And also prevent it to broken down into hazardous decomposition products: Carbon monoxide, carbon dioxide.

Product Name

4-Phenylphenol

Synthetic route

4-Phenylphenol Chemical Properties

4-Phenylphenol Uses

4-Phenylphenol Toxicity Data With Reference

4-Phenylphenol Consensus Reports

4-Phenylphenol Safety Profile

4-Phenylphenol Specification

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