5-Hexen-1-ol supplier | CasNO.821-41-0

Name
5-Hexen-1-ol
EINECS 212-477-4
CAS No. 821-41-0
Article Data103
CAS DataBase
Density 0.833 g/cm³
Solubility Miscible with water.
Melting Point <-20 °C
Formula C₆H₁₂O
Boiling Point 149.9 °C at 760 mmHg
Molecular Weight 100.161
Flash Point 47.2 °C
Transport Information UN 1987 3/PG 3
Appearance clear colourless liquid
Safety 16
Risk Codes 10
Molecular Structure
Hazard Symbols F
Synonyms 1-Hexen-6-ol;5-Hexene-1-ol;6-Hydroxy-1-hexene;5-Hexenol;
PSA 20.23000
LogP 1.33500

Synthetic route

: 43216-12-2
2-iodomethyltetrahydropyran

: 821-41-0
5-Hexen-1-ol

Conditions

Conditions	Yield
With indium In methanol for 4.5h; sonication;	95%
With dimethylboron bromide; tetra-(n-butyl)ammonium iodide; triethylamine In dichloromethane at 0℃; for 0.5h;	82%

: 127102-60-7
(S)-4-(but-3-enyl)-2,2-dimethyl-1,3-dioxolane

: 821-41-0
5-Hexen-1-ol

Conditions

Conditions	Yield
With water; acetic acid	95%

: 928-90-5
5-hexyl-1-ol

: 821-41-0
5-Hexen-1-ol

Conditions

Conditions	Yield
With dimethylamine borane In ethanol at 25℃; for 0.5h; Reagent/catalyst; Time;	95%
With palladium on activated charcoal; hydrogen In water at 25℃; under 760.051 Torr; for 1.5h;	68%
With quinoline; hydrogen In methanol; water at 20℃; under 760.051 Torr; for 0.433333h; chemoselective reaction;
With hydrogen In ethanol at 20℃; under 760.051 Torr; for 3.4h; Schlenk technique; Sealed tube; chemoselective reaction;	> 99 %Chromat.
With Dimethylphenylsilane; water In dimethyl sulfoxide at 70℃; for 0.333333h; Inert atmosphere; stereoselective reaction;

: 54653-25-7
ethyl hex-5-enoate

: 821-41-0
5-Hexen-1-ol

Conditions

Conditions	Yield
With lithium aluminium tetrahydride In diethyl ether	93%

: 106-69-4
hexane-1,2,6-triol

: 821-41-0
5-Hexen-1-ol

Conditions

Conditions	Yield
With rhenium(VII) oxide; triphenylphosphine at 165℃; for 1h; Reagent/catalyst; Concentration; Temperature;	91%
With rac-3-octanol at 170℃; for 1h;	38%

: 2009-83-8
6-chloro-1-hexanol

: 821-41-0
5-Hexen-1-ol

Conditions

Conditions	Yield
at 700℃; for 2h;	87%
With tert-butoxide; 18-crown-6 ether In tetrahydrofuran for 1.85h; Heating;	72%

: 34723-82-5, 130233-15-7, 130233-16-8
2-(bromomethyl)tetrahydro-2H-pyran

: 821-41-0
5-Hexen-1-ol

Conditions

Conditions	Yield
Stage #1: 2-(bromomethyl)tetrahydro-2H-pyran With sodium In diethyl ether for 2h; Metallation; Heating; Stage #2: With water Hydrolysis;	87%
With sodium	76%
With Na; pyridinium p-toluenesulfonate 1.) MeOH; 2.) CDCl3; Multistep reaction;

: 6-(allyloxy)hex-1-ene

: 821-41-0
5-Hexen-1-ol

Conditions

Conditions	Yield
With 2,3-dicyano-5,6-dichloro-p-benzoquinone In dichloromethane; water for 18h; Ambient temperature;	85%

: 18420-41-2, 130233-13-5, 130233-14-6
2-(chloromethyl)tetrahydropyran

: 821-41-0
5-Hexen-1-ol

Conditions

Conditions	Yield
With sodium In diethyl ether for 16h;	83.5%
With diethyl ether; sodium

: 77022-44-7
6-(tetrahydropyran-2-yloxy)hex-1-ene

: 821-41-0
5-Hexen-1-ol

Conditions

Conditions	Yield
With toluene-4-sulfonic acid In methanol for 4h; Ambient temperature;	82%
With ammonium chloride at 20℃; for 0.166667h; Yield given;

: 1315481-26-5
2,6-diphenylphenyl hex-5-enyl ether

: 821-41-0
5-Hexen-1-ol

Conditions

Conditions	Yield
Stage #1: 2,6-diphenylphenyl hex-5-enyl ether With sodium In tetrahydrofuran at 20℃; for 24h; Inert atmosphere; Stage #2: With water In tetrahydrofuran at 0 - 20℃; Inert atmosphere; regioselective reaction;	81%

: 49639-25-0
phenyl(6-hexanol)sulfoxide

: 821-41-0
5-Hexen-1-ol

Conditions

Conditions	Yield
In various solvent(s) for 0.0166667h; Irradiation;	80%

: 207795-48-0
1-((hex-5-en-1-yloxy)methyl)-4-methoxybenzene

: 821-41-0
5-Hexen-1-ol

Conditions

Conditions	Yield
With montmorillonite K 10 supported ammonium nitrate In neat (no solvent) for 0.05h; Irradiation;	80%

: potassium trifluoro(hex-5-en-1-yl)borate

: 821-41-0
5-Hexen-1-ol

Conditions

Conditions	Yield
With rose bengal; triethylamine In ethanol at 25℃; for 12h; Schlenk technique; Irradiation;	78%

: 627-32-7
1-iodopropan-3-ol

: 106-95-6
allyl bromide

: 821-41-0
5-Hexen-1-ol

Conditions

Conditions	Yield
With palladium diacetate; copper(II) acetate monohydrate; ammonium bromide; lithium chloride In water; N,N-dimethyl-formamide at 0℃; for 12h; Electrochemical reaction;	73%

: 629-11-8
1,6-hexanediol

: 821-41-0
5-Hexen-1-ol

Conditions

Conditions	Yield
With 1-hexadecylcarboxylic acid at 330 - 350℃; under 760 Torr; for 24h;	71%

: 1577-22-6
5-hexenoic acid

: 821-41-0
5-Hexen-1-ol

Conditions

Conditions	Yield
With lithium aluminium tetrahydride	71%
With hydrogen In aq. phosphate buffer at 50℃; under 1500.15 Torr; for 48h; pH=7; Autoclave;
With lithium aluminium tetrahydride In tetrahydrofuran at 0 - 20℃; Inert atmosphere;

: 63974-05-0
(E)-hex-2-ene-1,6-diol

: 821-41-0
5-Hexen-1-ol

Conditions

Conditions	Yield
With lithium aluminium tetrahydride In 1,2-dimethoxyethane for 120h; Heating;	70%

: 627-32-7
1-iodopropan-3-ol

: 107-05-1
3-chloroprop-1-ene

: 821-41-0
5-Hexen-1-ol

Conditions

Conditions	Yield
With palladium diacetate; copper(II) acetate monohydrate; ammonium bromide; lithium chloride In water; N,N-dimethyl-formamide at 0℃; for 12h; Electrochemical reaction;	70%

: 503-30-0
trimethylene oxide

: 762-72-1
allyl-trimethyl-silane

: 821-41-0
5-Hexen-1-ol

Conditions

Conditions	Yield
With titanium tetrachloride In dichloromethane at -100 - 20℃;	69%

: 86692-87-7
hex-5-enyl hydroperoxide

A: 821-41-0
5-Hexen-1-ol

B: 6032-29-7
(+/-)-2-pentanol

C: 764-59-0
hex-5-en-1-al

Conditions

Conditions	Yield
In pentane for 48h; Irradiation;	A 60% B 10% C 30%

...Expand

: 86692-87-7
hex-5-enyl hydroperoxide

A: 821-41-0
5-Hexen-1-ol

B: 764-59-0
hex-5-en-1-al

C: 5048-26-0
5-hexenyl acetate

Conditions

Conditions	Yield
With titanium(III) chloride; acetic acid In water for 2h;	A 56% B 27% C 17%

...Expand

: 2396-80-7
methyl 5-hexenoate

A: 821-41-0
5-Hexen-1-ol

: 25144-04-1
trans-2-methylcyclopentanol

Conditions

Conditions	Yield
With sodium In tetrahydrofuran; ammonia at -78 - -33℃; Cyclization; Bouveault-Blanc reduction;	A 36% B 54%

: 2396-80-7
methyl 5-hexenoate

: 821-41-0
5-Hexen-1-ol

Conditions

Conditions	Yield
With ethanol; [bis({2‐[bis(propan‐2‐yl)phosphanyl]ethyl})amine](borohydride)(carbonyl)(hydride)iron(II) at 100℃; for 24h; Inert atmosphere; Sealed tube; Darkness;	53%

: 629-03-8
1 ,6-dibromohexane

A: 592-41-6
1-hexene

B: 821-41-0
5-Hexen-1-ol

C: 110-54-3
hexane

D: 592-42-7
1,5-Hexadien

Conditions

Conditions	Yield
With tetramethylammonium perchlorate In water-d2; N,N-dimethyl-formamide Solvent; Electrolysis; Overall yield = 90 %;	A 22% B 9% C 50% D 16%
With tetramethylammonium perchlorate In N,N-dimethyl-formamide Electrolysis;	A 22% B 7% C 39% D 18%

...Expand

: 27925-22-0
6,8-dioxa-bicyclo[3.2.1]oct-2-ene

A: 821-41-0
5-Hexen-1-ol

B: 63974-05-0
(E)-hex-2-ene-1,6-diol

C: 6126-50-7, 928-91-6, 928-92-7
hex-4-en-1-ol

Conditions

Conditions	Yield
With lithium aluminium tetrahydride In 1,2-dimethoxyethane for 150h; Heating;	A 23% B 5% C 46%
With lithium aluminium tetrahydride In 1,2-dimethoxyethane for 150h; Product distribution; Heating; also with various other allylic ethers and allylic alcohols;	A 23% B 5% C 46%

...Expand

: 86692-87-7
hex-5-enyl hydroperoxide

A: 821-41-0
5-Hexen-1-ol

B: 764-59-0
hex-5-en-1-al

C: 108-95-2
phenol

Conditions

Conditions	Yield
In benzene for 48h; Irradiation;	A 44% B 43% C 13%

...Expand

: 592-42-7
1,5-Hexadien

: 821-41-0
5-Hexen-1-ol

Conditions

Conditions	Yield
With tetrahydrofuran; alkaline aqueous hydrogen peroxide; diborane
With sodium hydroxide; 9-borabicyclo[3.3.1]nonane dimer; dihydrogen peroxide 1) 2h, THF; 2) 0 deg C; 3) 50 deg C; Yield given. Multistep reaction;
With sodium tetrahydroborate; 18-crown-6 ether; dihydrogen peroxide; sodium methylate; titanium(III) chloride 1.) THF, 30 deg C, 5 h, 2.) THF, methanol, 40 deg C; Yield given. Multistep reaction;
Multi-step reaction with 3 steps 1: hydrogen bromide 2: acetic acid 3: ethanolic KOH-solution View Scheme

: 5048-26-0
5-hexenyl acetate

: 821-41-0
5-Hexen-1-ol

Conditions

Conditions	Yield
With potassium hydroxide
Saponification;

: 109-99-9
tetrahydrofuran

: 107671-69-2
Peroxyde de t-butyle et d'hex-5-enyle

A: 3208-31-9
2-pentyl-tetrahydro-furan

B: 821-41-0
5-Hexen-1-ol

C: 134141-96-1
(tetrahydrofuryl-2 methyl)-2 tetrahydropyranne

D: 6-(tetrahydrofuran-2-yl)hexan-1-ol

E: 6-(Tetrahydro-furan-2-yl)-hexanal

F: C14H26O3

Conditions

Conditions	Yield
at 140℃; for 10h; Mechanism; Product distribution;	A 6 % Chromat. B 5 % Chromat. C 20 % Chromat. D 15 % Chromat. E 12 % Chromat. F 8 % Chromat.

...Expand

: 821-41-0
5-Hexen-1-ol

: 764-59-0
hex-5-en-1-al

Conditions

Conditions	Yield
Stage #1: 5-Hexen-1-ol With oxalyl dichloride; dimethyl sulfoxide In dichloromethane at -78℃; for 1h; Swern oxidation; Inert atmosphere; Stage #2: With triethylamine In dichloromethane at -78 - 0℃; Swern oxidation; Inert atmosphere;	100%
Stage #1: 5-Hexen-1-ol With oxalyl dichloride; dimethyl sulfoxide at -78℃; for 1h; Stage #2: With triethylamine	100%
With (NH4)4[CuMo6O18(OH)6]·5H2O; oxygen; sodium sulfite In water; acetonitrile at 60℃; under 760.051 Torr; for 6h;	95%

: 821-41-0
5-Hexen-1-ol

: 98-88-4
benzoyl chloride

: 41795-26-0
benzoic acid hex-5-enyl ester

Conditions

Conditions	Yield
With dmap; triethylamine In dichloromethane at 0 - 20℃;	100%
With dmap; triethylamine In dichloromethane at 0 - 20℃; Inert atmosphere;	98%
With triethylamine In tetrahydrofuran at 20℃;	93%

: 821-41-0
5-Hexen-1-ol

: 124-63-0
methanesulfonyl chloride

: 64818-36-6
5-hexenyl methanesulfonate

Conditions

Conditions	Yield
With triethylamine In dichloromethane at 20℃; for 1h;	100%
With triethylamine In dichloromethane at -15℃; for 1h; Green chemistry;	100%
With triethylamine In dichloromethane at -15℃; for 1.5h;	100%

: 821-41-0
5-Hexen-1-ol

: 5707-04-0
Phenylselenyl chloride

: 75526-73-7
(2-(phenylselanylmethyl)oxane)

Conditions

Conditions	Yield
With pyridine In dichloromethane at 20℃;	100%
With zinc(II) chloride In dichloromethane at 20℃;	100%
With silver(l) oxide In dichloromethane at 20℃;	100%

: 821-41-0
5-Hexen-1-ol

: 133708-80-2
benzeneselenenyl m-nitrobenzenesulfonate

: 75526-73-7
(2-(phenylselanylmethyl)oxane)

Conditions

Conditions	Yield
In acetonitrile at 0℃; for 2h;	100%

: 821-41-0
5-Hexen-1-ol

: 18162-48-6
tert-butyldimethylsilyl chloride

: 85807-84-7
tert-butyl(5-hexenyloxy)dimethylsilane

Conditions

Conditions	Yield
With 1H-imidazole In N,N-dimethyl-formamide	100%
With 1H-imidazole In tetrahydrofuran at 20℃;	100%
With 1H-imidazole In dichloromethane at 20℃; for 19h;	100%

: 821-41-0
5-Hexen-1-ol

: 98-59-9
p-toluenesulfonyl chloride

: 18922-06-0
hex-5-enyl 4-methylbenzenesulfonate

Conditions

Conditions	Yield
With pyridine at 0 - 5℃; for 3h;	100%
With triethylamine In dichloromethane at 0 - 20℃; for 12h;	100%
With dmap; triethylamine In dichloromethane at 0 - 20℃; for 13h; Inert atmosphere;	98%

: 821-41-0
5-Hexen-1-ol

: 75-11-6
diiodomethane

: 5687-83-2
4-cyclopropylbutan-1-ol

Conditions

Conditions	Yield
With trimethylaluminum In dichloromethane for 10h; Heating;	100%
With diethylzinc In 1,2-dichloro-ethane; toluene at 20℃;	40%
Stage #1: diiodomethane With diethylzinc; trifluoroacetic acid In n-heptane; dichloromethane at -10 - 10℃; for 1h; Stage #2: 5-Hexen-1-ol In n-heptane; dichloromethane at 0 - 20℃; for 1.5h;
With diethylzinc; trifluoroacetic acid In hexane; dichloromethane at 0 - 20℃; for 24h; Inert atmosphere;
With trimethylaluminum In hexane; dichloromethane at 20 - 40℃;

: 821-41-0
5-Hexen-1-ol

: 58479-61-1
tert-butylchlorodiphenylsilane

: 185999-07-9
tert-butyl(hex-5-enyloxy)diphenylsilane

Conditions

Conditions	Yield
With 1H-imidazole In dichloromethane at 0 - 20℃; for 5h;	100%
With 1H-imidazole In N,N-dimethyl-formamide at 20℃;	99%
With 1H-imidazole In dichloromethane at 23℃; for 2h;	99%

: 821-41-0
5-Hexen-1-ol

: 34837-55-3
Phenylselenyl bromide

: 75526-73-7
(2-(phenylselanylmethyl)oxane)

Conditions

Conditions	Yield
With pyridine In dichloromethane at 20℃;	100%
With zinc(II) chloride In dichloromethane at 20℃;	100%
With silver(l) oxide In dichloromethane at 20℃;	98%
With pyridine In dichloromethane at 20℃; Product distribution; Further Variations:; Reagents; Reaction partners;	90%

: 136918-14-4
phthalimide

: 821-41-0
5-Hexen-1-ol

: 52898-33-6
N-(5-hexenyl)phthalimide

Conditions

Conditions	Yield
With di-isopropyl azodicarboxylate; triphenylphosphine In tetrahydrofuran at -20℃; for 0.166667h; Inert atmosphere;	100%
With di-isopropyl azodicarboxylate; triphenylphosphine In tetrahydrofuran at 0 - 23℃; Mitsunobu reaction; Inert atmosphere;	95%
With di-isopropyl azodicarboxylate; triphenylphosphine In tetrahydrofuran at 0 - 20℃; for 24h; Cooling with ice; Inert atmosphere;	84%
With di-isopropyl azodicarboxylate; triphenylphosphine In tetrahydrofuran at 20℃;

: 821-41-0
5-Hexen-1-ol

: 65118-17-4
N-allyl-o-nitrobenzenesulfonamide

: 1018389-28-0
N-allyl-N-(hex-5-enyl)-2'-nitrobenzenesulfonamide

Conditions

Conditions	Yield
With triphenylphosphine; diethylazodicarboxylate In tetrahydrofuran at 0 - 20℃; for 1h;	100%
With di-isopropyl azodicarboxylate; triphenylphosphine In tetrahydrofuran at 20℃; for 1h; Fukuyama-Mitsunobu reaction;	98%

: 821-41-0
5-Hexen-1-ol

: 1711-05-3
m-anisoyl chloride

: hex-5-en-1-yl 3-methoxybenzoate

Conditions

Conditions	Yield
With dmap; triethylamine In dichloromethane at 0 - 20℃; Inert atmosphere;	100%

: 123-73-9
trans-Crotonaldehyde

: 821-41-0
5-Hexen-1-ol

: 1100136-96-6
(E)-7-hydroxyhept-2-enal

Conditions

Conditions	Yield
With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride In dichloromethane for 2h; Reflux; Inert atmosphere;	100%

: 821-41-0
5-Hexen-1-ol

: 1950-78-3
p-toluenesulfonyl iodide

: 141246-59-5
5-iodo-6-(para-toluenesulfonyl)hexan-1-ol

Conditions

Conditions	Yield
In acetonitrile Ambient temperature;	99%
In acetonitrile Mechanism; Ambient temperature; other alkenols;

: 821-41-0
5-Hexen-1-ol

: 21915-57-1
4-(oxiran-2-yl)butyl acetate

Conditions

Conditions	Yield
With [2-percarboxyethyl] functionalized silica In dichloromethane at 20℃; for 1h;	99%
With 3-chloro-benzenecarboperoxoic acid In dichloromethane at 0 - 20℃;	86%
With 3-chloro-benzenecarboperoxoic acid In water for 2h; pH=7.0;	85%

: 821-41-0
5-Hexen-1-ol

: 999-97-3
1,1,1,3,3,3-hexamethyl-disilazane

: 71138-63-1
(5-hexenyloxy)trimethylsilane

Conditions

Conditions	Yield
With N-Bromosuccinimide In neat (no solvent) at 50℃; for 1.5h;	99%
at 20℃; immediate distillation; Yield given;

: 821-41-0
5-Hexen-1-ol

: 507-63-1
1-iodoheptadecafluorooctane

: rac-7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,14-Heptadecafluoro-3-iodotetradecanol

Conditions

Conditions	Yield
With C30H26N6Ru(2+)*2Cl(1-); sodium L-ascorbate In methanol; acetonitrile for 0.5h; Inert atmosphere; Irradiation;	99%
With 2,6-dimethylpyridine In acetonitrile at 20℃; for 12h; Catalytic behavior; Reagent/catalyst; Wavelength; Irradiation; Inert atmosphere; Sealed tube;	93%
With copper diacetate; Piperonyl butoxide In methanol for 48h; Ambient temperature;	90%

: 821-41-0
5-Hexen-1-ol

: 246540-39-6
allyl bromomethanesulfonamide

: 246540-42-1
N-allyl-C-bromo-N-hex-5-enyl-methanesulfonamide

Conditions

Conditions	Yield
With triphenylphosphine; diethylazodicarboxylate In tetrahydrofuran; toluene for 0.5h; Alkylation; Mitsunobu reaction;	99%
With triphenylphosphine; diethylazodicarboxylate In tetrahydrofuran; toluene Alkylation;	99%

: 821-41-0
5-Hexen-1-ol

: 3619-91-8
1,3-bisphosphinopropane

: 288145-88-0
1,3-bis[di(6-hydroxyhexyl)phosphino]propane

Conditions

Conditions	Yield
at 20℃; for 10h; Addition; Irradiation;	99%

: 821-41-0
5-Hexen-1-ol

: 6522-02-7
3-(4-(allyloxy)phenyl)propanoic acid

: 515835-01-5
3-(4-allyloxy-phenyl)-propionic acid hex-5-enyl ester

Conditions

Conditions	Yield
With dmap; dicyclohexyl-carbodiimide In dichloromethane at 0℃;	99%

: 821-41-0
5-Hexen-1-ol

: 110-66-7
n-pentanethiol

: 6-(pentylsulfanyl)hexan-1-ol

Conditions

Conditions	Yield
With 9-borabicyclo[3.3.1]nonane dimer In tetrahydrofuran at 20℃; for 3h;	99%

: 821-41-0
5-Hexen-1-ol

: (R)-1-(trimethylsilyl)-4-methyl-5-(tert-butyldiphenylsilyloxy)-1-pentyne

: (E)-(R)-10-(Diphenyl-trimethylsilanyl-methoxy)-9-methyl-7-[1-trimethylsilanyl-meth-(Z)-ylidene]-dec-4-en-1-ol

Conditions

Conditions	Yield
cyclopentadienylruthenium(II) trisacetonitrile hexafluorophosphate In acetone at 20℃; for 4h; Alder-ene reaction;	99%

: 821-41-0
5-Hexen-1-ol

: 13154-24-0
triisopropylsilyl chloride

: 173470-74-1
(hex-5-en-1-yloxy)triisopropylsilane

Conditions

Conditions	Yield
With 1H-imidazole In dichloromethane at 20℃; for 1h;	99%
With 1H-imidazole In dichloromethane at 0 - 20℃; Inert atmosphere;	94%
With dmap; triethylamine In tetrahydrofuran at 20℃;	90%
Stage #1: 5-Hexen-1-ol With 1H-imidazole; dmap In dichloromethane at 0℃; for 0.0833333h; Inert atmosphere; Stage #2: triisopropylsilyl chloride In dichloromethane at 0 - 20℃; for 3h; Inert atmosphere;	87%
With dmap; triethylamine for 72h;	83%

: 821-41-0
5-Hexen-1-ol

: 122-04-3
4-nitro-benzoyl chloride

: 6835-50-3
hex-5-enyl 4-nitrobenzoate

Conditions

Conditions	Yield
With triethylamine In dichloromethane at 0 - 20℃; for 21h;	99%
With triethylamine In dichloromethane at 0 - 20℃; for 21h;	99%
With triethylamine In dichloromethane at 0 - 20℃; for 21h;	99%

: 821-41-0
5-Hexen-1-ol

: 1873-77-4
tris-(trimethylsilyl)silane

: 1001067-36-2
6-[tris(trimethylsilyl)]-1-hexanol

Conditions

Conditions	Yield
With 1,1'-azobis(1-cyanocyclohexanenitrile) In water at 100℃; for 4h;	99%

: 821-41-0
5-Hexen-1-ol

: 146176-60-5
2,2,4,4-tetramethyl-1,3-oxazolidine-3-carbonyl chloride

: 152857-60-8
hex-5-enyl 2,2,4,4-tetramethyl-1,3-oxazolidine-3-carboxylate

Conditions

Conditions	Yield
Stage #1: 5-Hexen-1-ol With sodium hydride In tetrahydrofuran; mineral oil at 20℃; for 0.5h; Stage #2: 2,2,4,4-tetramethyl-1,3-oxazolidine-3-carbonyl chloride In tetrahydrofuran; mineral oil at 80℃;	99%

: 821-41-0
5-Hexen-1-ol

: 401-55-8
ethyl bromofluoroacetate

: 1277181-09-5
ethyl 4-bromo-2-fluoro-8-hydroxyoctanoate

Conditions

Conditions	Yield
With Ir[(dF(CF3)ppy)2(dtbbpy)]PF6; lithium bromide In water; N,N-dimethyl-formamide for 24h; Visible-light irradiation; Inert atmosphere;	99%
With C30H26N6Ru(2+)*2Cl(1-); lithium bromide In dimethyl sulfoxide for 24h; Inert atmosphere; Irradiation;	99%
With 2,6-diiodo-4,4-difluoro-1,3,5,7-tetramethyl-8-phenyl-4-bora-3a,4a-diaza-s-indacene; sodium L-ascorbate; lithium bromide In water; N,N-dimethyl-formamide at 20℃; for 20h; Inert atmosphere; Schlenk technique; Irradiation;	89%
With 7-(diethylamino)-3-(thiophen-2-yl)-2H-chromen-2-one In ethanol; water at 20℃; for 36h; Schlenk technique; Inert atmosphere; Irradiation;	65%
With 2,6-dimethylpyridine; 4-methoxy-benzaldehyde In acetonitrile at 25℃; for 48h; Schlenk technique; Inert atmosphere; Sealed tube; Irradiation;	60%

: 821-41-0
5-Hexen-1-ol

: 685-87-0
Diethyl 2-bromomalonate

: 1277180-98-9
diethyl 2-(2-bromo-6-hydroxyhexyl)malonate

Conditions

Conditions	Yield
With Ir[(dF(CF3)ppy)2(dtbbpy)]PF6; lithium bromide In water; N,N-dimethyl-formamide for 24h; Visible-light irradiation; Inert atmosphere;	99%
With [4,4’-bis(1,1-dimethylethyl)-2,2’-bipyridine-N1,N1‘]bis [3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-N]phenyl-C]iridium(III) hexafluorophosphate; lithium bromide In water; N,N-dimethyl-formamide Inert atmosphere; Irradiation;	99%
With 2,6-dimethylpyridine; 4-methoxy-benzaldehyde In acetonitrile at 25℃; for 26h; Schlenk technique; Inert atmosphere; Sealed tube; Irradiation;	99%

: 821-41-0
5-Hexen-1-ol

: 75-36-5
acetyl chloride

: 18719-24-9
oct-7-enoic acid

Conditions

Conditions	Yield
With triethylamine In dichloromethane at 20℃; for 18h;	99%

5-Hexen-1-ol Specification

The CAS register number of 5-Hexen-1-ol is 821-41-0. It also can be called as Hex-5-en-1-ol and the IUPAC name about this chemical is hex-5-en-1-ol. It belongs to the following product categories, such as omega-Functional Alkanols, Carboxylic Acids, Amines & Halides, omega-Unsaturated Alkanols and so on. This chemical is flammable. When you are using it, please keep away from sources of ignition.

Physical properties about 5-Hexen-1-ol are: (1)ACD/LogP: 1.50; (2)ACD/LogD (pH 5.5): 1.5; (3)ACD/LogD (pH 7.4): 1.5; (4)ACD/BCF (pH 5.5): 8.08; (5)ACD/BCF (pH 7.4): 8.08; (6)ACD/KOC (pH 5.5): 155.3; (7)ACD/KOC (pH 7.4): 155.3; (8)#H bond acceptors: 1; (9)#H bond donors: 1; (10)#Freely Rotating Bonds: 5; (11)Polar Surface Area: 9.23Å²; (12)Index of Refraction: 1.43; (13)Molar Refractivity: 31.1 cm³; (14)Molar Volume: 120.1 cm³; (15)Polarizability: 12.33x10^-24cm³; (16)Surface Tension: 28 dyne/cm; (17)Enthalpy of Vaporization: 45.06 kJ/mol; (18)Vapour Pressure: 1.5 mmHg at 25°C.

Preparation: this chemical can be prepared by 2-chloromethyl-tetrahydro-pyran. This reaction will need reagent Na and solvent diethyl ether. The reaction time is 16 hour(s). The yield is about 83.5%.

Uses of hex-5-en-1-ol: it can be used to produce 6-bromo-hex-1-ene at Heating. This reaction will need reagent phosphorus tribromide, pyridine and solvent diethyl ether with reaction time of 3 hours. The yield is about 75%.

You can still convert the following datas into molecular structure:
(1)SMILES: OCCCC\C=C
(2)InChI: InChI=1/C6H12O/c1-2-3-4-5-6-7/h2,7H,1,3-6H2
(3)InChIKey: UIZVMOZAXAMASY-UHFFFAOYAD
(4)Std. InChI: InChI=1S/C6H12O/c1-2-3-4-5-6-7/h2,7H,1,3-6H2
(5)Std. InChIKey: UIZVMOZAXAMASY-UHFFFAOYSA-N

Product Name

5-Hexen-1-ol

Synthetic route

5-Hexen-1-ol Specification

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