Product Name

  • Name

    9,10-Dibromoanthracene

  • EINECS 208-342-4
  • CAS No. 523-27-3
  • Article Data89
  • CAS DataBase
  • Density 1.768 g/cm3
  • Solubility Soluble in water.
  • Melting Point 220-225 °C
  • Formula C14H8Br2
  • Boiling Point 427.1 °C at 760 mmHg
  • Molecular Weight 336.026
  • Flash Point 248.1 °C
  • Transport Information UN 3077
  • Appearance yellow to yellow-green fluffy powder
  • Safety 37/39-26-61-60-36
  • Risk Codes 36/37/38-50/53
  • Molecular Structure Molecular Structure of 523-27-3 (9,10-Dibromoanthracene)
  • Hazard Symbols IrritantXi,DangerousN
  • Synonyms NSC 6263;
  • PSA 0.00000
  • LogP 5.51800

Synthetic route

anthracene
120-12-7

anthracene

9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

Conditions
ConditionsYield
With N-Bromosuccinimide; lithium perchlorate; silica gel In dichloromethane at 20℃; for 0.0833333h;100%
With oxygen; 1,2-dibromomethane at 20℃; for 2h;99%
With N-Bromosuccinimide; lithium perchlorate; silica gel In dichloromethane for 0.5h;99%
9-Bromoanthracene
1564-64-3

9-Bromoanthracene

9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

Conditions
ConditionsYield
With N-Bromosuccinimide; C5H13NO3S In n-heptane at 25℃; for 19h; Reagent/catalyst; Darkness;85%
With bis(trifluoroacetoxy)iodobencene; trimethylsilyl bromide In dichloromethane at 20℃; Inert atmosphere;83%
With phosphorus pentabromide; benzene
With nitric acid; acetic acid
With 2,6-di-tert-butyl-pyridine; Bromoform In acetonitrile platinum mesh electrodes, H cell containing 0.1 M Bu4NPF6, constant current 10 mA;57 % Chromat.
anthracene
120-12-7

anthracene

A

9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

B

9,10-phenanthrenequinone
84-65-1

9,10-phenanthrenequinone

Conditions
ConditionsYield
With potassium permanganate; hydrogen bromide In acetonitrileA 85%
B 3%
anthracene
120-12-7

anthracene

A

9-Bromoanthracene
1564-64-3

9-Bromoanthracene

B

9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

Conditions
ConditionsYield
With N-Bromosuccinimide; 2,4,6-trimethylaniline In dichloromethane at 0℃; for 8h; Inert atmosphere; regioselective reaction;A 84%
B 7%
With N-Bromosuccinimide; C5H13NO3S In n-heptane at 60℃; for 4.5h; Darkness;A 81%
B 8%
With N-Bromosuccinimide; iodine In tetrachloromethane Bromination; Heating;
methanol
67-56-1

methanol

anthracene
120-12-7

anthracene

A

trans-9,10-dihydro-9,10-dimethoxyanthracene
31750-30-8

trans-9,10-dihydro-9,10-dimethoxyanthracene

B

9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

C

9-methoxyanthracene
2395-96-2

9-methoxyanthracene

D

9,10-dimethoxyanthracene
2395-97-3

9,10-dimethoxyanthracene

Conditions
ConditionsYield
With pyridine; bromine; sodium hydrogencarbonate; water at 20℃; for 0.25h;A 82%
B n/a
C 1%
D 1%
anthracene
120-12-7

anthracene

bromine
7726-95-6

bromine

9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

Conditions
ConditionsYield
In dichloromethane for 24h;75%
9-nitroanthracene
602-60-8

9-nitroanthracene

A

9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

B

bromo-9 nitro-10 anthracene
14789-48-1

bromo-9 nitro-10 anthracene

Conditions
ConditionsYield
With bromine In nitromethane Heating;A 22%
B 44%
9-anthracene aldehyde
642-31-9

9-anthracene aldehyde

A

9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

B

9,10-bromoanthracene-9-carbaldehyde
93496-77-6

9,10-bromoanthracene-9-carbaldehyde

Conditions
ConditionsYield
With bromine In tetrachloromethane at 0 - 5℃; for 20h;A n/a
B 22%
9,10-dihydroanthracene
613-31-0

9,10-dihydroanthracene

A

9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

B

2,9,10-tribromo-anthracene
725744-58-1

2,9,10-tribromo-anthracene

Conditions
ConditionsYield
With carbon disulfide; bromine; iodine Ausschluss von Licht;
9,19-Dibromo-9,10-dihydroanthracene
46491-50-3

9,19-Dibromo-9,10-dihydroanthracene

9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

diethyl ether
60-29-7

diethyl ether

1,2,3,4,9,10-hexabromo-1,2,3,4-tetrahydro-anthracene
860531-60-8

1,2,3,4,9,10-hexabromo-1,2,3,4-tetrahydro-anthracene

9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

Conditions
ConditionsYield
Behandeln mit organischen Magnesiumverbindungen; β-form;
9-nitroanthracene
602-60-8

9-nitroanthracene

9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

Conditions
ConditionsYield
With tetrachloromethane; bromine
triphenylmethane
519-73-3

triphenylmethane

9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

Conditions
ConditionsYield
With bromine
9-benzylanthracene
1498-71-1

9-benzylanthracene

9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

Conditions
ConditionsYield
With carbon disulfide; bromine at 20℃;
1,2,3,4,9,10-hexabromo-1,2,3,4-tetrahydro-anthracene
860531-60-8

1,2,3,4,9,10-hexabromo-1,2,3,4-tetrahydro-anthracene

benzene
71-43-2

benzene

9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

Conditions
ConditionsYield
Einw. von Tageslicht; α-form;
bei Einw. von Sonnenlicht oder Quecksilber-Bogenlicht; α-form;
C19H16Br2O2
113160-97-7

C19H16Br2O2

A

9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

B

ethyl acrylate
140-88-5

ethyl acrylate

Conditions
ConditionsYield
In diphenylether at 200℃; Rate constant;
9,10-dibromoanthracene cation radical
523-27-3

9,10-dibromoanthracene cation radical

9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

Conditions
ConditionsYield
With [76]fullerene In dichloromethane Rate constant; Ambient temperature; also with C78;
9,10-epidioxy-9,10-dihydroanthracene
4741-24-6

9,10-epidioxy-9,10-dihydroanthracene

hydrogen bromide
10035-10-6, 12258-64-9

hydrogen bromide

9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

Conditions
ConditionsYield
Je nach Konzentration;
9,10-dihydroanthracene
613-31-0

9,10-dihydroanthracene

bromine
7726-95-6

bromine

9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

9-nitroanthracene
602-60-8

9-nitroanthracene

hydrogen bromide
10035-10-6, 12258-64-9

hydrogen bromide

9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

Conditions
ConditionsYield
at 260℃;
tetrachloromethane
56-23-5

tetrachloromethane

9-nitroanthracene
602-60-8

9-nitroanthracene

bromine
7726-95-6

bromine

9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

9-nitroanthracene
602-60-8

9-nitroanthracene

bromine
7726-95-6

bromine

CS2

CS2

9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

Conditions
ConditionsYield
at 75℃;
9-Anthracenecarboxylic acid
723-62-6

9-Anthracenecarboxylic acid

bromine
7726-95-6

bromine

A

9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

B

10-bromo-9-anthracenecarboxylic acid
6929-81-3

10-bromo-9-anthracenecarboxylic acid

9-Bromoanthracene
1564-64-3

9-Bromoanthracene

nitric acid
7697-37-2

nitric acid

acetic acid
64-19-7

acetic acid

A

9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

B

9-nitroanthrone
6313-44-6

9-nitroanthrone

chloroform
67-66-3

chloroform

9-Bromoanthracene
1564-64-3

9-Bromoanthracene

nitrogen dioxide

nitrogen dioxide

A

9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

B

9-bromo-9.10-dinitro-dihydroanthracene

9-bromo-9.10-dinitro-dihydroanthracene

α-form of 9.10-dibromo-anthracene tetrabromide-(1.2.3.4)

α-form of 9.10-dibromo-anthracene tetrabromide-(1.2.3.4)

9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

Conditions
ConditionsYield
With acetic acid; zinc
With benzene Irradiation;
With zinc; benzene
With copper; benzene
β-form of 9.10-dibromo-anthracene tetrabromide-(1.2.3.4)

β-form of 9.10-dibromo-anthracene tetrabromide-(1.2.3.4)

9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

Conditions
ConditionsYield
With zinc; benzene
With copper; benzene
With acetic acid; zinc
durch Behandeln mit organischen Magnesiumverbindungen;
1,4-dioxane
123-91-1

1,4-dioxane

anthracene
120-12-7

anthracene

bromine
7726-95-6

bromine

9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

carbon disulfide
75-15-0

carbon disulfide

9-benzylanthracene
1498-71-1

9-benzylanthracene

bromine
7726-95-6

bromine

9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

phenylacetylene
536-74-3

phenylacetylene

9,10-diphenylethynylanthracene
10075-85-1

9,10-diphenylethynylanthracene

Conditions
ConditionsYield
With triethylamine; copper(l) iodide; tetrakis(triphenylphosphine) palladium(0) at 89℃; for 3h;100%
With copper(l) iodide; C44H68N10*PdCl2; caesium carbonate; triphenylphosphine In N,N-dimethyl-formamide at 80℃; for 5h; Sonogashira Cross-Coupling; Inert atmosphere;95%
With potassium phosphate tribasic trihydrate; C50H40N6O2Pd(2+)*2F6P(1-); tetrabutylammomium bromide In 1,4-dioxane; water at 100℃; for 24h; Sonogashira Cross-Coupling;93%
9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

3-chlorophenylboronic acid
63503-60-6

3-chlorophenylboronic acid

9,10-di(3-chlorophenyl)anthracene
1261083-80-0

9,10-di(3-chlorophenyl)anthracene

Conditions
ConditionsYield
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; tetra(n-butyl)ammonium hydroxide In 1,4-dioxane; water at 90℃; for 20h; Suzuki coupling; Inert atmosphere;100%
9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

9,10-di-p-tolyl-anthracene
43217-31-8

9,10-di-p-tolyl-anthracene

Conditions
ConditionsYield
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran; toluene at 85℃; for 3h; Suzuki-Miyaura cross-coupling reaction;99%
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran; toluene at 85℃; for 3h; Suzuki-Miyaura cross-coupling reaction;99%
With tetrakis(triphenylphosphine) palladium(0); tetrabutylammomium bromide; potassium carbonate In water; toluene at 90℃; for 24h; Inert atmosphere;95%
With tetrakis(triphenylphosphine) palladium(0); water; sodium carbonate In ethanol; toluene for 24h; Suzuki Coupling; Inert atmosphere; Reflux;89%
With potassium carbonate; tetrakis(triphenylphosphine) palladium(0) In ethanol; water; toluene for 24h; Suzuki coupling reaction; Heating;81%
9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

9,10-bis-(4-methoxy-phenyl)-anthracene
24672-76-2

9,10-bis-(4-methoxy-phenyl)-anthracene

Conditions
ConditionsYield
With water; palladium diacetate; cesium fluoride; cyclo-octa-1,5-diene; DavePhos In neat (no solvent) for 1.65h; Suzuki-Miyaura Coupling; Milling; Green chemistry;99%
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran; toluene Suzuki-Miyaura cross-coupling reaction; Heating;95%
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran; toluene at 85℃; for 7h; Suzuki-Miyaura cross-coupling reaction;95%
9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

4-fluoroboronic acid
1765-93-1

4-fluoroboronic acid

9,10-bis(4-fluorophenyl)anthracene

9,10-bis(4-fluorophenyl)anthracene

Conditions
ConditionsYield
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran; toluene at 85℃; for 10h; Suzuki-Miyaura cross-coupling reaction;99%
9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

(meta-(trifluoromethyl)phenyl)boronic acid
1423-26-3

(meta-(trifluoromethyl)phenyl)boronic acid

9,10-bis(3-trifluoromethylphenyl)anthracene

9,10-bis(3-trifluoromethylphenyl)anthracene

Conditions
ConditionsYield
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran; toluene at 85℃; for 11h; Suzuki-Miyaura cross-coupling reaction;99%
9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

4,4'-(anthracene-9,10-diyl)dibenzaldehyde
324750-99-4

4,4'-(anthracene-9,10-diyl)dibenzaldehyde

Conditions
ConditionsYield
With dichloro[1,1'-bis(di-t-butylphosphino)ferrocene]palladium(II); triethylamine In water at 20℃; for 0.166667h; Suzuki-Miyaura Coupling; Inert atmosphere;98.1%
With dichloro[1,1′-bis[bis(1,1-dimethylethyl)phosphino]ferrocene-P,P′]palladium; triethylamine In water at 20℃; for 12h; Suzuki-Miyaura Coupling; Green chemistry;95%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; benzene for 48h; Heating;78%
9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

tris-iso-propylsilyl acetylene
89343-06-6

tris-iso-propylsilyl acetylene

9,10-bis[(triisopropylsilanyl)ethynyl]-anthracene
862667-06-9

9,10-bis[(triisopropylsilanyl)ethynyl]-anthracene

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; diethylamine Sonogashira Cross-Coupling; Schlenk technique; Inert atmosphere; Reflux;98%
With diethylamine; copper(l) iodide Sonogashira coupling; Heating;52%
1-(2,6-difluorophenyl)pyrrole-2,5-dione

1-(2,6-difluorophenyl)pyrrole-2,5-dione

9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

(3aR)-5,10-dibromo-2-(2,6-difluorophenyl)-3a,4,11,11a-tetrahydro-1H-4,11-ethenonaphtho[2,3-f]isoindole-1,3(2H)-dione
1617526-39-2

(3aR)-5,10-dibromo-2-(2,6-difluorophenyl)-3a,4,11,11a-tetrahydro-1H-4,11-ethenonaphtho[2,3-f]isoindole-1,3(2H)-dione

Conditions
ConditionsYield
With aluminum (III) chloride In chloroform at 20℃; for 1h; Reagent/catalyst; Diels-Alder Cycloaddition; stereoselective reaction;98%
9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

C39H26N4O

C39H26N4O

C53H33BrN4O

C53H33BrN4O

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); sodium t-butanolate In toluene for 5h; Inert atmosphere; Reflux;98%
(4-(naphthalen-1-yl)phenyl)boronic acid
870774-25-7

(4-(naphthalen-1-yl)phenyl)boronic acid

9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

9-bromo-10-(4-(naphthalene-1-yl)phenyl)anthracene
1092390-01-6

9-bromo-10-(4-(naphthalene-1-yl)phenyl)anthracene

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In ethanol; water; toluene for 1.5h; Inert atmosphere; Reflux;97.5%
Stage #1: (4-(naphthalen-1-yl)phenyl)boronic acid; 9,10-Dibromoanthracene With tetrakis(triphenylphosphine)palladium (0) In tetrahydrofuran for 0.5h; Inert atmosphere;
Stage #2: With potassium carbonate In tetrahydrofuran at 80℃; for 0.333333h; Inert atmosphere;
styrene
292638-84-7

styrene

9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

(E,E)-9,10-Bis(styryl)anthracene
10273-82-2

(E,E)-9,10-Bis(styryl)anthracene

Conditions
ConditionsYield
With tributyl-amine; PdCl2*4P(o-Tol)3; potassium carbonate In water at 100℃; for 3h;97%
With C44H68N10*PdCl2; tetrabutylammomium bromide; potassium carbonate In 1,4-dioxane at 110℃; for 6h; Heck Reaction;95%
With potassium carbonate In N,N-dimethyl-formamide at 110℃; for 6h; Heck Reaction; Green chemistry;90%
With C50H40N6O2Pd(2+)*2F6P(1-); sodium acetate In 1,4-dioxane at 100℃; for 24h; Heck Reaction;86%
styrene
292638-84-7

styrene

9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

A

(E,E)-9,10-Bis(styryl)anthracene
10273-82-2

(E,E)-9,10-Bis(styryl)anthracene

B

(Z,Z)-9,10-Bis(styryl)anthracene
123475-69-4

(Z,Z)-9,10-Bis(styryl)anthracene

Conditions
ConditionsYield
With dichlorobis(tri-O-tolylphosphine)palladium; tributyl-amine; potassium carbonate; tris-(o-tolyl)phosphine In water at 100℃; for 3h;A 97%
B n/a
9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

trimethylsilylacetylene
1066-54-2

trimethylsilylacetylene

9,10-bis(trimethylsilyl)ethynylanthracene
18750-95-3

9,10-bis(trimethylsilyl)ethynylanthracene

Conditions
ConditionsYield
With copper(l) iodide; bis(triphenylphosphine)palladium(II) chloride; diisopropylamine In tetrahydrofuran for 8h; Sonogashira coupling; Reflux;97%
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; diisopropylamine In tetrahydrofuran for 8h; Reflux;97%
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; diethylamine at 70℃; for 22h; Inert atmosphere; Reflux;95%
9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

phenylboronic acid
98-80-6

phenylboronic acid

9,10-diphenylanthracene
1499-10-1

9,10-diphenylanthracene

Conditions
ConditionsYield
With potassium phosphate; dichloro{bis[1-(dicyclohexylphosphanyl)piperidine]}palladium(II) In toluene at 80℃; for 0.0833333h; Suzuki-Miyaura cross-coupling reaction; Air;97%
With potassium carbonate In methanol at 80℃; for 0.5h; Suzuki-Miyaura Coupling; Schlenk technique; Inert atmosphere;97%
With potassium phosphate In ethanol at 80℃; for 2h; Suzuki-Miyaura Coupling; Schlenk technique; Inert atmosphere;97%
4-morpholinecarboxaldehyde
4394-85-8

4-morpholinecarboxaldehyde

9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

9,10-diformylanthracene
7044-91-9

9,10-diformylanthracene

Conditions
ConditionsYield
Stage #1: 9,10-Dibromoanthracene With n-butyllithium In tetrahydrofuran at -78℃;
Stage #2: 4-morpholinecarboxaldehyde In tetrahydrofuran at -78℃;
97%
tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

di-tert-butyl 3,3'-(9,10-anthracenediyl)bis(2-propenoate)
1225023-88-0

di-tert-butyl 3,3'-(9,10-anthracenediyl)bis(2-propenoate)

Conditions
ConditionsYield
With palladium diacetate; triethylamine; tris-(o-tolyl)phosphine In N,N-dimethyl-formamide at 120℃; for 4h;97%
With palladium diacetate; triethylamine; tris-(o-tolyl)phosphine In N,N-dimethyl-formamide at 120℃; for 4h;97%
9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

3-fluorophenylboronic acid
768-35-4

3-fluorophenylboronic acid

9,10-di-(3-fluorophenyl)anthracene
1235890-64-8

9,10-di-(3-fluorophenyl)anthracene

Conditions
ConditionsYield
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; tetra(n-butyl)ammonium hydroxide In 1,4-dioxane; water at 90℃; for 12h; Suzuki coupling; Inert atmosphere;97%
9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

1,1-dimethylethyl 2-ethenyl-1H-pyrrole-1-carboxylate
180283-59-4

1,1-dimethylethyl 2-ethenyl-1H-pyrrole-1-carboxylate

9,10-bis((E)-2-(1H-pyrrol-2-yl)vinyl)anthracene

9,10-bis((E)-2-(1H-pyrrol-2-yl)vinyl)anthracene

Conditions
ConditionsYield
With palladium diacetate; potassium carbonate; acetylacetone In N,N-dimethyl-formamide at 130℃; for 6h; Heck Reaction; Inert atmosphere; Sealed tube;97%
9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

4'-ethynyl-2,2':6',6-terpyridine
149817-60-7

4'-ethynyl-2,2':6',6-terpyridine

C48H28N6

C48H28N6

Conditions
ConditionsYield
With propylamine; tetrakis(triphenylphosphine) palladium(0) at 60℃; for 48h;96%
9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

4-Vinylphenylboronic acid
2156-04-9

4-Vinylphenylboronic acid

9,10-(p,p'-divinyl)-diphenylanthracene
54842-92-1

9,10-(p,p'-divinyl)-diphenylanthracene

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; toluene at 85℃; for 6h; Suzuki-Miyaura Coupling; Inert atmosphere; Schlenk technique;96%
With potassium carbonate; Pd2(dba)3/Pd(PtBu3)2 In toluene at 110℃; for 48h; Suzuki coupling;91%
With potassium carbonate In toluene at 110℃; for 48h; Inert atmosphere;90%
9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

2-isopropyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
76347-13-2

2-isopropyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

2-(10-bromoanthracene-9-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

2-(10-bromoanthracene-9-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Conditions
ConditionsYield
With n-butyllithium In tetrahydrofuran; hexane at -78 - 20℃; for 2.5h; Inert atmosphere; Schlenk technique;96%
9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

ethyl acrylate
140-88-5

ethyl acrylate

diethyl 3,3'-(9,10-anthracenediyl)bisacrylate
108366-06-9

diethyl 3,3'-(9,10-anthracenediyl)bisacrylate

Conditions
ConditionsYield
With triethylamine; tris-(o-tolyl)phosphine; palladium diacetate In N,N-dimethyl-formamide at 120℃; for 48h; Heck reaction;95%
With palladium diacetate; 1,3-bis-(diphenylphosphino)propane; triethylamine In N,N-dimethyl-formamide at 100℃; for 10h; Heck reaction;94%
9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

dodecahedrene
77159-24-1

dodecahedrene

1,22-dibromo-23,24;25,26-dibenzo-tridecacyclo[20.2.2.02,6.02,21.03,13.04,11.05,9.07,20.08,18.010,17.012,16.014,21.015.19]hexacosane

1,22-dibromo-23,24;25,26-dibenzo-tridecacyclo[20.2.2.02,6.02,21.03,13.04,11.05,9.07,20.08,18.010,17.012,16.014,21.015.19]hexacosane

Conditions
ConditionsYield
In benzene at 20℃; for 1h;95%
9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenol
214360-76-6

3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenol

9,10-bis(3-hydroxyphenyl)anthracene

9,10-bis(3-hydroxyphenyl)anthracene

Conditions
ConditionsYield
With potassium hydroxide; bis(dicyclohexylamine)palladium acetate In ethanol at 40℃; for 24h; Suzuki cross-coupling;95%
9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

Chlorodiisopropylphosphane
40244-90-4

Chlorodiisopropylphosphane

9,10-bis(diisopropylphosphanyl)anthracene
1038535-94-2

9,10-bis(diisopropylphosphanyl)anthracene

Conditions
ConditionsYield
Stage #1: 9,10-Dibromoanthracene With n-butyllithium In diethyl ether; hexane at -15 - 20℃; for 1h;
Stage #2: Chlorodiisopropylphosphane In diethyl ether; hexane at 20℃; for 4h; Further stages.;
95%
Stage #1: 9,10-Dibromoanthracene With n-butyllithium In tetrahydrofuran; diethyl ether; hexane at -30℃; Inert atmosphere; Schlenk technique;
Stage #2: Chlorodiisopropylphosphane In tetrahydrofuran; diethyl ether; hexane at 35 - 40℃; Inert atmosphere; Schlenk technique;
20.6%
9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

9,10-dibromo-1,2,3,4-tetrabromo-1,2,3,4-tetrahydroanthracene
402592-29-4

9,10-dibromo-1,2,3,4-tetrabromo-1,2,3,4-tetrahydroanthracene

Conditions
ConditionsYield
With bromine In tetrachloromethane at 25℃; UV-irradiation; stereoselective reaction;95%
With bromine In tetrachloromethane for 48h; Irradiation;71%
With bromine In tetrachloromethane at 25℃; Irradiation;
With bromine In tetrachloromethane Irradiation; stereoselective reaction;
4-Methoxystyrene
637-69-4

4-Methoxystyrene

9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

9,10-bis(4-methoxystyryl)anthracene
60949-09-9

9,10-bis(4-methoxystyryl)anthracene

Conditions
ConditionsYield
With potassium phosphate; palladium diacetate In N,N-dimethyl acetamide at 110℃; for 24h;95%
With potassium phosphate; palladium diacetate In N,N-dimethyl acetamide at 110℃; for 24h;
maleiimide
541-59-3

maleiimide

9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

1,4-dibromodibenzo[e,h]bicyclo[2.2.2]octane-2,3-dicarboximide

1,4-dibromodibenzo[e,h]bicyclo[2.2.2]octane-2,3-dicarboximide

Conditions
ConditionsYield
In toluene at 160℃; for 4h;95%

9,10-Dibromoanthracene Chemical Properties

IUPAC Name: 9,10-Dibromoanthracene
Synonyms of Anthracene, 9,10-dibromo- (CAS NO.523-27-3): 9,10-Dibromoanthracene ; EINECS 208-342-4 ; NSC 6263
CAS NO: 523-27-3
Molecular Formula: C14H8Br2
Molecular Weight: 336.0213
Molecular Structure:

Melting Point: 220-225 °C
ProductCategories: Aromatic Compounds ; Miscellaneous ; Electronic Chemicals ; Anthracenes ; Anthracene series ; Aryl ; C13 to C37+ ; Halogenated Hydrocarbons 
Index of Refraction: 1.748
Molar Refractivity: 77.31 cm3
Molar Volume: 190 cm3
Surface Tension: 54.3 dyne/cm
Density of 1.768 g/cm3
Flash Point: 248.1 °C
Enthalpy of Vaporization: 65.56 kJ/mol
Boiling Point: 427.1 °C at 760 mmHg
Vapour Pressure: 4.19E-07 mmHg at 25°C

9,10-Dibromoanthracene Uses

 Anthracene, 9,10-dibromo- (CAS NO.523-27-3) is used as intermediates in organic synthesis.

9,10-Dibromoanthracene Safety Profile

Hazard Codes of Anthracene, 9,10-dibromo- (CAS NO.523-27-3): IrritantXi,DangerousN
Risk Statements: 36/37/38-50/53 
R36/37/38: Irritating to eyes, respiratory system and skin. 
R50/53: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Statements: 37/39-26-61-60-36 
S37/39: Wear suitable gloves and eye/face protection. 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S61: Avoid release to the environment. Refer to special instructions / safety data sheets. 
S60: This material and its container must be disposed of as hazardous waste. 
S36: Wear suitable protective clothing.
RIDADR UN 3077

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