Boron tribromide supplier | CasNO.10294-33-4

Name
Boron tribromide
EINECS 233-657-9
CAS No. 10294-33-4
Article Data109
CAS DataBase
Density 2.782 g/cm³
Solubility Reacts with water.
Melting Point -46 °C(lit.)
Formula BBr₃
Boiling Point 91.3 °C at 760 mmHg
Molecular Weight 250.523
Flash Point 30°F
Transport Information UN 3390 6.1/PG 1
Appearance clear to amber liquid with a pungent odour
Safety 9-26-28-36/37/39-45-23-33-16-62-61-60
Risk Codes 14-26/28-35-40-62-11-67-65-50/53
Molecular Structure
Hazard Symbols T+, C, F, N
Synonyms Boronbromide (BBr3) (8CI);Boron bromide;Boron(III) bromide;Tribromoborane;Tribromoboron;Borane, tribromo-;
PSA 0.00000
LogP 2.15600

Synthetic route

: pentaborane(9)

: 14355-29-4
diboron tetrabromide

A: 1-(dibromoboryl)pentaborane

B: 10294-33-4
boron tribromide

C: 13709-65-4
dibromoborane

Conditions

Conditions	Yield
In neat (no solvent) Teflon-valve-equipped standard vacuum line or a nitrogen-filled glovebox;excess B5H9;pentaborane, B2Br4 separately condensed in the reactor, after 20 min at room temp., vessel cooled to -10 ° C,; over course of the following 10 h,all volatile material removed,reactor warmed to room temp.,all volatile material at room temp. were removed,BBr2B5H8 extd. with CH2Cl2, yield:80% on basis of amt. of B2Br4 employed, 86% on basis of unrecovered B5H9;	A 80% B n/a C n/a

Yield

In neat (no solvent) Teflon-valve-equipped standard vacuum line or a nitrogen-filled glovebox;excess B5H9;pentaborane, B2Br4 separately condensed in the reactor, after 20 min at room temp., vessel cooled to -10 ° C,; over course of the following 10 h,all volatile material removed,reactor warmed to room temp.,all volatile material at room temp. were removed,BBr2B5H8 extd. with CH2Cl2, yield:80% on basis of amt. of B2Br4 employed, 86% on basis of unrecovered B5H9;

A 80%
B n/a
C n/a

...Expand

: boron

: 7726-95-6
bromine

: 10294-33-4
boron tribromide

Conditions

Conditions	Yield
boron is mixed with ca. 9 w % Mg, in H2 atmosphere;	70%
In not given kept over liq. Hg for 48 h; distd. (vac., room temp.);	57.6%
at red heat; in H2 atmosphere;	40%

: 7637-07-2
boron trifluoride

: 7727-15-3
aluminium bromide

: 10294-33-4
boron tribromide

Conditions

Conditions	Yield
with excess of BF3; addn. of Al to depress formation of Br2; addn. of Hg to get rid of Br2;	70%
with excess of BF3; addn. of Al to depress formation of Br2; addn. of Hg to get rid of Br2;	70%

: BBr3*2(o-nitrotoluene)

: 10294-33-4
boron tribromide

Conditions

Conditions	Yield
In neat (no solvent) byproducts: o-CH3C6H4NO2; decompn. reaction immediately;	50%

: BBr3*3C6H5NO2

: 10294-33-4
boron tribromide

Conditions

Conditions	Yield
In neat (no solvent) byproducts: C6H5NO2; decompn. reaction immediately;	50%

: 14355-29-4
diboron tetrabromide

: 353-54-8
tribromofluoromethane

A: 12589-31-0
closo-B9Br9

B: 7637-07-2
boron trifluoride

C: 10294-33-4
boron tribromide

D: 13965-73-6
diboron tetrafluoride

Conditions

Conditions	Yield
B2Br4 and CFBr3 were reacted in a NMR-tube at ambient temp. for 3,75 h; products detected by (19)F- and (11)B-NMR, CBr4 by (13)C-NMR;	A 2% B 7% C 2% D 39%

...Expand

: 7727-15-3
aluminium bromide

: 14075-53-7
potassium tetrafluoroborate

: 10294-33-4
boron tribromide

Conditions

Conditions	Yield
	30%
	30%

: 856317-96-9
BBr3*Cl3CCOOC2H5

: 10294-33-4
boron tribromide

Conditions

Conditions	Yield
In neat (no solvent) byproducts: Cl3CCOOC2H5; decompn. reaction immediately;	25%

: 14355-29-4
diboron tetrabromide

: 558-13-4
carbon tetrabromide

: 10294-33-4
boron tribromide

Conditions

Conditions	Yield
Vac.-distn. of B2Br4 to CBr4, heating in an oil-bath (96°C, 5.75 h).; Monitored by (11)B-NMR.;	8.6%

: boron(III) sulfide

: 7726-95-6
bromine

: 10294-33-4
boron tribromide

Conditions

Conditions	Yield
heating of B2S3 in Br2 vapour;

: boron

: 96-11-7
1,2,3-tribromopropane

: 10294-33-4
boron tribromide

Conditions

Conditions	Yield
250 °C in reaction tube;
at 250°C in sealed tube;
at 250°C in sealed tube;

: boron trioxide

: 13510-40-2
phosphorus trichloride dibromide

: 10294-33-4
boron tribromide

: boron trioxide

: 7726-95-6
bromine

: 10294-33-4
boron tribromide

Conditions

Conditions	Yield
With coal 250°C; fractionated distn.;

: boron trioxide

: 7726-95-6
bromine

: 7440-44-0
pyrographite

: 10294-33-4
boron tribromide

Conditions

Conditions	Yield
byproducts: CO; glowed B2O3-C mixt. is treated with Br2;

...Expand

: boron trioxide

: 7647-15-6
sodium bromide

: 10294-33-4
boron tribromide

Conditions

Conditions	Yield
800-1000°C;

: boron trioxide

: 7789-69-7
phosphorus pentabromide

: 10294-33-4
boron tribromide

Conditions

Conditions	Yield
140 °C, reaction tube;

: boron

: 7726-95-6
bromine

: 7782-50-5
chlorine

A: 10294-34-5
boron trichloride

B: 10294-33-4
boron tribromide

...Expand

: iron boride

: 7726-95-6
bromine

: 10294-33-4
boron tribromide

Conditions

Conditions	Yield
	0%

: 19287-45-7
diborane

A: 23834-96-0
bromodiborane

B: 10294-33-4
boron tribromide

Conditions

Conditions	Yield
With bromine at 100°C in light;	A >99 B n/a
With bromine at room temperature in light;
With hydrogen bromide; aluminium bromide at 80-90 °C;

: boron

: 7439-95-4
magnesium

: 10294-33-4
boron tribromide

Conditions

Conditions	Yield
With bromine at moderate temp.;

: boron

: 10294-33-4
boron tribromide

Conditions

Conditions	Yield
With C2H4Br2 at 250°C in sealed tube;
With bromine at 700°C, or at red heat;
With C2H4Br2 at 250°C in sealed tube;

: boron

: 106-93-4
ethylene dibromide

: 10294-33-4
boron tribromide

Conditions

Conditions	Yield
250 °C in reaction tube;

: hydrogen cyanide; compound with boron bromide

A: 74-90-8
hydrogen cyanide

B: 10294-33-4
boron tribromide

Conditions

Conditions	Yield
decompn. by moisture of air;
decompn. by moisture of air;

: 4262-75-3
chloroseleniumtetrabromoborate

A: 7782-49-2
selenium

B: 10294-33-4
boron tribromide

Conditions

Conditions	Yield
byproducts: CH3Br; decompn. above 66°C;

: 21259-75-6
mercury bis(trifluoromethanethiolate)

: 10294-33-4
boron tribromide

: 36884-78-3
tris(trifluoromethylsulfanyl)borane

Conditions

Conditions	Yield
In further solvent(s) in 2-methylbutane, -196 to +25°C;	100%
	95%
	95%

: 1291-32-3
zirconocene dichloride

: 10294-33-4
boron tribromide

: bis(cyclopentadienyl)dibromozirconium

Conditions

Conditions	Yield
In diethyl ether (π-C5H5)2ZrCl2/BBr3 (molar ratio: 3:2);;	100%
In diethyl ether (π-C5H5)2ZrCl2/BBr3 (molar ratio: 3:2);;	100%

: 158789-52-7
nitrido(tetra-tert-butylphthalocyaninato)rhenium(V)

: 10294-33-4
boron tribromide

: Re(tetra-tert-butylphthalocyaninato)(NBBr3)

Conditions

Conditions	Yield
In dichloromethane addn. of BBr3 to soln. of rhenium complex at 0°C, 0°C (6 h); removement of solvent (vacuum);	100%

: nitrido(octa-n-pentylphthalocyaninato)rhenium(V)

: 10294-33-4
boron tribromide

: Re(octa-n-pentylphthalocyaninato)(NBBr3)

Conditions

Conditions	Yield
In dichloromethane addn. of BBr3 to soln. of rhenium complex at 0°C, 0°C (6 h); removement of solvent (vacuum);	100%

: 745811-87-4
(C5Me5)Fe(CO)2SiMe2Ph

: 10294-33-4
boron tribromide

: 745811-89-6
(C5Me5)Fe(CO)2SiBrMePh

Conditions

Conditions	Yield
In toluene byproducts: MeBBr2; under inert atm.; BBr3 was added dropwise to a toluene soln. of Fe-complex at room temp., the mixt. was stirred at room temp. for 6 h; evapd., hexane was added, filtd., filtrate evapd.; elem. anal.;	100%
In benzene-d6 byproducts: MeBBr2; 1 equiv. of BBr3, 20°C, 1 h, inert atm.; not isolated; detd. by (1)H NMR spectroscopy;

: 745811-87-4
(C5Me5)Fe(CO)2SiMe2Ph

: 10294-33-4
boron tribromide

: 745811-92-1
(C5Me5)Fe(CO)2SiBr2Ph

Conditions

Conditions	Yield
In toluene byproducts: MeBBr2; under inert atm.; BBr3 was added dropwise to a toluene soln. of Fe-complex at room temp., the mixt. was stirred for 24 h at 80°C; evapd., tolyene was added, filtd., filtrate evapd.; elem. anal.;	100%

: 6-methoxy-1-phenyl-1H-indazole

: 10294-33-4
boron tribromide

: 1-phenyl-1H-indazol-6-ol

Conditions

Conditions	Yield
In dichloromethane at 20℃; for 16h; Cooling with ice;	100%

: 5624-60-2
1,3,5-tris(trimethylsilyl)benzene

: 7732-18-5
water

: 10294-33-4
boron tribromide

: benzene-1,3,5-triyltriboronic acid

Conditions

Conditions	Yield
Stage #1: 1,3,5-tris(trimethylsilyl)benzene; boron tribromide at 100℃; for 4h; Inert atmosphere; Stage #2: water In hexane at 0℃;	100%
Stage #1: 1,3,5-tris(trimethylsilyl)benzene; boron tribromide at 100℃; for 4h; Inert atmosphere; Stage #2: water In hexane at 0℃;	99%

...Expand

: C16H14S2Si

: 10294-33-4
boron tribromide

: C14H8BBrS2

Conditions

Conditions	Yield
In dichloromethane at -40 - 20℃;	100%

: 4375-83-1
tris(dimethylamino)borane

: 10294-33-4
boron tribromide

: 6990-27-8
bromobis(dimethylamino)borane

Conditions

Conditions	Yield
In pentane at -40 - 20℃; for 2h; Inert atmosphere;	99%
In pentane at -40°C to -50°C;	85%
In pentane at -40°C to -50°C;	85%
In pentane -50 - -40°C, 2 mol BBr3;
80°C;	>99

: 7443-22-3
2,4,6-triethyl-borazine

: 10294-33-4
boron tribromide

A: 13703-88-3
2,4,6-tribromo-cyclotriborazane

B: 136237-57-5
Br2(CH3CH2)B3N3H3

Conditions

Conditions	Yield
In dichloromethane addn. of BBr3 to a stirred soln. of the borazine in CH2Cl2 at -10°C over 1 h, warming to room temp., refluxing for 1 h; filtn., evapn. of volatiles under reduced pressure, sublimation under vacuum (40-50°C bath temp.), elem. anal.;	A n/a B 99%

...Expand

: 177187-93-8, 90026-95-2, 76126-80-2
tricarbonyl(η6-α-methylbenzyl methyl ether) chromium(0)

: 10294-33-4
boron tribromide

: 191352-86-0
(OC)3CrC6H5CH(CH3)Br

Conditions

Conditions	Yield
In dichloromethane stirring at -78°C for 1 h, quenching (satd. aq. NaHCO3), warming to room temp.; addn. of H2O, extn. (Et2O), drying (MgSO4), filtration, concn.;	99%

: 106367-62-8
bis(benzyl-tert-butylamino)boron fluoride

: 10294-33-4
boron tribromide

: 106542-71-6
{bis(benzyl-tert-butylamino)boron}tetrabromo borate

Conditions

Conditions	Yield
In dichloromethane react. in dry N2 or in vac. with exclosure of moisture; BBr3 was added to a soln. of the B-compound in CH2Cl2 with stirring at -50°C; the soln. was allowed to warm to 0°C; it was stirred for 15 min at this temp.;; evapd. in vac., volatiles condensed at -196°C; product remains as the residue; elem. anal.;;	99%

: 10294-33-4
boron tribromide

: 124-40-3
dimethyl amine

: 14215-61-3
(bisdimethylamine)dibromoboronium(+1) bromide

Conditions

Conditions	Yield
In chloroform reaction at -70°C;;	99%
In chloroform reaction at -70°C;;	99%
In chloroform	>99
In chloroform	>99

: 15696-40-9
dodecacarbonyl triosmium

: 10294-33-4
boron tribromide

: 2Os(2+)*6CO*4Br(1-)=Os2(CO)6Br4

Conditions

Conditions	Yield
With carbon monoxide; hydrogen In neat (no solvent) A sealed tube contained Os3(CO)12, BBr3 and 630 torr (at -196°C)of 3:1 H2:CO gas mixt. was heated at 150°C for 1 h, cooled;; purified by sublimation at 190°C or by treatment with H2O-CH2Cl2and recrystn. from CH2Cl2; elem. anal.;;	99%

: 12116-45-9
(benzyl alcohol)tricarbonylchromium(0)

: 10294-33-4
boron tribromide

: 191352-85-9
[Cr(η6-C6H5CH2Br)(CO)3]

Conditions

Conditions	Yield
In dichloromethane stirring at -78°C for 1 h, quenching (satd. aq. NaHCO3), warming to room temp.; addn. of H2O, extn. (Et2O), drying (MgSO4), filtration, concn.;	99%
In dichloromethane BBr3 in CH2Cl2 was added to a soln. of complex in CH2Cl2 under N2 at -78°C, stirred for 1.5-3 h; satd. aq. NaHCO3 was added, warmed to room temp., H2O was added, the organic layer was sepd., dried over MgSO4, filtered, the solvent was removed under reduced pressure;	70%

: (η5-C5Me5)Fe(CO)2SiMe3

: 10294-33-4
boron tribromide

: 745811-88-5
(C5Me5)Fe(CO)2SiBrMe2

Conditions

Conditions	Yield
In hexane byproducts: MeBBr2; under inert atm.; BBr3 was added dropwise to a hexane soln. of Fe-complex at room temp., the mixt. was stirred vigorously for 1 h; evapd., hexane was added, filtd., filtrate evapd.; elem. anal.;	99%
In benzene-d6 byproducts: MeBBr2; 1 equiv. of BBr3, 20°C, 0,5 h, inert atm.; not isolated; detd. by (1)H NMR spectroscopy;

: [CH3(C6H4)BBr(4,4'-bis(but-3''-enyl)-2,2'-bipyridyl)]Br

: 617-86-7
triethylsilane

: 10294-33-4
boron tribromide

: [CH3(C6H4)BBr(((C5H3N)(CH2)4BBr2)2)](1+)*BBr4(1-) = [CH3(C6H4)BBr(((C5H3N)(CH2)4BBr2)2)]BBr4

Conditions

Conditions	Yield
In dichloromethane under O2-free Ar; soln. of boronium bromide complex (0.75 mmol) and Et3SiH (2.25 mmol) in CH2Cl2 (5 ml) added dropwise to BBr3 (2.25 mmol) in CH2Cl2 (5 ml) (-78°C); warmed to room temp.; pptd. with n-hexane (5 ml);	99%

...Expand

: 67-56-1
methanol

: N,N-diethyl 10-trimethylsilylphenanthren-9-yl-O-carbamate

: 10294-33-4
boron tribromide

: 9-(N,N-diethyl-O-carbamato)-phenanthren-10-yl-boronic acid

Conditions

Conditions	Yield
In dichloromethane (Ar or N2); addn. of BBr3 to soln of N,N-diethyl 10-trimethylsilylphenanthren-9-yl-O-carbamate in CH2Cl2 at -78°C, stirring at room temp. overnight, addn. of MeOH;	99%

...Expand

: (C6F5)2(CH3)2C3HN2Si(CH3)3

: 10294-33-4
boron tribromide

: (C6F5)2N2(CH3)2C3HBBr2

Conditions

Conditions	Yield
In hexane; toluene (under Ar, Schlenk); soln. of BBr3 in hexane added to soln. of ligand intoluene at ambient temp., stirred overnight; solvent removed under reduced pressure;	99%

: 2,6-diethyl-4,4-difluoro-1,3,5,7-tetramethyl-8H-4-bora-3a,4a-diaza-s-indacene

: 10294-33-4
boron tribromide

: 4,4-dibromo-2,6-diethyl-1,3,5,7-tetramethyl-8H-4-bora-3a,4a-diaza-s-indacene

Conditions

Conditions	Yield
In tetrachloromethane Inert atmosphere;	99%

: C12H9BrFN

: 7732-18-5
water

: 10294-33-4
boron tribromide

: C12H8BBrFNO

Conditions

Conditions	Yield
Stage #1: C12H9BrFN; boron tribromide In dichloromethane at 20℃; Stage #2: water	99%

...Expand

: C17H16B2N2O4

: 10294-33-4
boron tribromide

: C11H12B2Br2N2O2

Conditions

Conditions	Yield
In hexane; toluene at -30 - 20℃; for 3h;	99%

: 76822-32-7
tetraphenylarsonium tetrachloronitridorhenate

: 10294-33-4
boron tribromide

: As(C6H5)4(1+)*Br4ReNBBr3(1-) = As(C6H5)4{Br4ReNBBr3}

Conditions

Conditions	Yield
In neat (no solvent) byproducts: BCl3; condensing BBr3 onto the Re-complex in vac.; refluxing for 7 h; evapn. of excess BBr3; drying in vac.; elem. anal.;	98.5%

: 371-76-6
bis(trifluoromethyl)mercury

: 10294-33-4
boron tribromide

: 7637-07-2
boron trifluoride

Conditions

Conditions	Yield
In neat (no solvent) (N2); BBr3 was condensed above Hg compd. in an evacuated tube, mixt. was warmed up to room temp. and stirred for 60 min; identified by (19)F- and (11)B-NMR;	98%

: 135952-85-1
1,4,6,9-tetraisopropyl-3,8-diethyl-2,7-bis(diethylboryl)-5-stannaspiro[4.4]nona-1,3,6,8-tetraene

: 10294-33-4
boron tribromide

: 172166-31-3
3,4-diethyl-2,5-diisopropyl-1,6-dibromo-2,3,4,5-tetracarba-nido-hexaborane(6)

Conditions

Conditions	Yield
In hexane byproducts: EtBBr2, SnBr4; N2-atmosphere; addn. of excess BBr3 to Sn-compd. at -78°C, warming to room temp., stirring for 3 h; filtration, removal of volatiles (vac.), fractional distn.;	98%

: 12116-66-4
bis(cyclopentadienyl)hafnium dichloride

: 10294-33-4
boron tribromide

: bis(cyclopentadienyl)hafnium dibromide

Conditions

Conditions	Yield
In dichloromethane (π-C5H5)2HfCl2/BBr3 (molar ratio 3:2); inert atm.; 5 min. in CH2Cl2;;	98%
In dichloromethane (π-C5H5)2HfCl2/BBr3 (molar ratio 3:2); inert atm.; 5 min. in CH2Cl2;;	98%

: 768-32-1
trimethylphenylsilane

: 10294-33-4
boron tribromide

: 4151-77-3
dibromo(phenyl)borane

Conditions

Conditions	Yield
In neat (no solvent) byproducts: BrSi(CH3)3; BBr3 and C6H5Si(CH3)3 mixed under stirring and cooling (room temp.), 60°C, 1h;	98%
In dichloromethane byproducts: BrSi(CH3)3; in inert atmosphere, dropwise addn. of trimethylphenylsilane to a stirred soln. of BBr3 at -78°C, stirring (-78°C, 1 h), slow warming to room temp.; evapn. in vac. at 30°C.;	94%
In neat (no solvent) (N2); neat BBr3 added by pipette to neat PhSiMe3 in a Schenk flask; placed in 60 °C oil bath for 4.5 h; volatile components removed by vacuum distillation at room temp.;	94%

: 1314-86-9
tetraphosphorus triselenide

: 10294-33-4
boron tribromide

: 366837-16-3
P4Se3BBr3

Conditions

Conditions	Yield
In carbon disulfide (N2); P4Se3 in CS2 was added to soln. of BBr3 in CS2 at room temp.; cooled to -78°C; filtered; dried in vac. at room temp.;	98%

: 135952-86-2
1,4,6,9-tetrabutyl-3,8-diethyl-2,7-bis(diethylboryl)-5-stannaspiro[4.4]nona-1,3,6,8-tetraene

: 10294-33-4
boron tribromide

: 172166-32-4
1,6-dibromo-2,5-dibutyl-3,4-diethyl-2,3,4,5-tetracarba-nido-hexaborane(6)

Conditions

Conditions	Yield
In hexane byproducts: EtBBr2, SnBr4; N2-atmosphere; addn. of excess BBr3 to Sn-compd. at -78°C, warming to room temp., stirring for 3 h; filtration, removal of volatiles (vac.), fractional distn.;	98%

Boron tribromide Chemical Properties

MF: BBr₃
MW: 250.52
mp : -46 °C(lit.)
bp : -90 °C
density : 2.60 g/mL at 20 °C(lit.)
vapor density : 8.6 (vs air)
vapor pressure : 40 mm Hg ( 14 °C)
Fp : 30 °F
storage temp. : Poison room
color : colorless
Sensitive : Moisture Sensitive
IUPAC Name: tribromoborane
Storage temp: Poison room
Sensitive: Moisture Sensitive
Stability: Stable, but reacts violently with water
Appearance: clear to amber liquid with a pungent odour
Product Categories: Inorganics;Piperazine derivates;Deprotecting Reagents;Others;Protection and Derivatization
Synonyms of Boron tribromide (10294-33-4): BBr3 ; Borane,tribromo- ; Boron,tribromo- ; boronbromide(bbr3) ; tribromo-boran ; tribromoborane ; tribromoboron ; tribromo-Boron
Molecular Structure of Boron tribromide (10294-33-4):

Boron tribromide (10294-33-4) is commercially available and is a strong Lewis acid. It is an excellent demethylating or dealkylating agent for ethers, often in the production of pharmaceuticals. Additionally, it also finds applications in olefin polymerization and in Friedel-Crafts chemistry as a Lewis acid catalyst. The electronics industry uses boron tribromide as a boron source in pre-deposition processes for doping in the manufacture of semiconductors.

Boron tribromide Uses

Boron tribromide (10294-33-4) is used as intermingle source in semiconductor silicon; extracting high-purity boron and organic boron compound; a source in optical fibre.

Boron tribromide Production

The first synthesis was done by M. Poggiale in 1846 by reacting boron trioxide with carbon and bromine at high temperatures:
B₂O₃ + 3 C + 3 Br₂ → 2 BBr₃ + 3 CO
An improvement of this method was developed by F. W?hler and Deville in 1857. By starting from amorphous boron the reaction temperatures are lower and no carbon monoxide is produced
2 B + 3 Br₂ → 2 BBr₃

Boron tribromide Toxicity Data With Reference

RTECS#: CAS# 142-82-5: MI7700000
CAS# 10294-33-4: ED7400000
LD50/LC50: RTECS:
CAS# 142-82-5: Inhalation, rat: LC50 = 103 gm/m3/4H;
RTECS:
CAS# 10294-33-4:.
Carcinogenicity: Heptane (n-) - Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65.
Boron tribromide (10294-33-4) - Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65.
Other: See actual entry in RTECS for complete information.

Boron tribromide Safety Profile

Hazard Codes: Very T+ Corrosive C Flammable F Dangerous N
Risk Statements: 14-26/28-35-40-62-11-67-65-50/53
R14: Reacts violently with water
R26/28: Very toxic by inhalation and if swallowed
R35: Causes severe burns
R40: Limited evidence of a carcinogenic effect
R62: Risk of impaired fertility
R11: Highly flammable
R67: Vapours may cause drowsiness and dizziness
R65: Harmful: may cause lung damage if swallowed
R50/53: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Safety Statements: 9-26-28-36/37/39-45-23-33-16-62-61-60
S9: Keep container in a well-ventilated place
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S28: After contact with skin, wash immediately with plenty of soap-suds
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S23: Do not breathe vapour
S33: Take precautionary measures against static discharges
S16: Keep away from sources of ignition
S62: If swallowed, do not induce vomitting; seek medical advice immediately and show this container or label
S61: Avoid release to the environment. Refer to special instructions / safety data sheets
S60: This material and its container must be disposed of as hazardous waste
RIDADR: UN 3390 6.1/PG 1
WGK Germany: 3
RTECS: ED7400000
F: 10-21
HazardClass: 8
PackingGroup: I

Product Name

Boron tribromide

Synthetic route

Boron tribromide Chemical Properties

Boron tribromide Uses

Boron tribromide Production

Boron tribromide Toxicity Data With Reference

Boron tribromide Safety Profile

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