cyclohexa-1,3-diene
cyclohexane
Conditions | Yield |
---|---|
With Pd/C; hydrogen In chloroform at 20℃; under 760.051 Torr; for 2h; Catalytic behavior; | 100% |
With hydrogen; HRh(CO)3 at 79.9℃; under 3750.3 Torr; for 1.66667h; | 63% |
With hydrogen In tetrahydrofuran at 20℃; under 760.051 Torr; for 10h; | 50% |
Conditions | Yield |
---|---|
With hydrogen; mer-Os(PPh3)3HBr(CO) at 150℃; under 3800 Torr; for 1h; Product distribution; | 100% |
With hydrogen; decacarbonyldirhenium(0) at 230℃; under 37503 Torr; for 0.25h; | 100% |
With {(η6-C6H6)Ru(NCCH3)3}{BF4}2; water; hydrogen In benzene at 90℃; under 30400 Torr; for 4h; | 100% |
Conditions | Yield |
---|---|
With hydrogen; [(norbornadiene)rhodium(I)chloride]2; polydiacetylene In n-heptane at 30℃; under 60800 Torr; for 0.9h; Product distribution; various aromatic compounds and other catalyst also investigated; | 100% |
With hydrogen; Ni-Tc on γ-Al2O3 at 175 - 250℃; under 760 Torr; Product distribution; dependence of catalytic activity on the reduction temperature; enhanced activity of bimetallic catalysts; | 100% |
With hydrogen; decacarbonyldirhenium(0) at 230℃; under 75005.9 Torr; for 0.25h; | 100% |
Conditions | Yield |
---|---|
With 9-borabicyclo[3.3.1]nonane dimer; triphenylstannane In toluene at 0℃; | 100% |
With triethylsilane; aluminium trichloride In dichloromethane at 18 - 20℃; for 0.25h; | 95% |
With water; sodium iodide; nickel dichloride; zinc; sonication In N,N,N,N,N,N-hexamethylphosphoric triamide at 60℃; for 1h; Product distribution; | 82% |
Conditions | Yield |
---|---|
With hydrogen; Leuna-Kontakt 6525 at 150℃; Product distribution; other halogen organic compounds, var. catalysts; | 100% |
With hydrogen; platinum at 120℃; under 16501.7 Torr; for 1.66667h; Autoclave; Inert atmosphere; | 12.8% |
With dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; hydrogen; triethylamine In isopropyl alcohol at 75℃; under 31028.9 Torr; for 4h; other chloroaromatics; var. reaction time; catalytic hydrodechlorination; |
Conditions | Yield |
---|---|
With C53H82ClN3P2Ru In dichloromethane-d2 at 50℃; under 3040.2 Torr; for 3h; Reagent/catalyst; Time; | 100% |
at 25℃; Catalytic behavior; | |
With ReH(NO)2(P(CH(CH3)2)3)2; Dimethylphenylsilane; tris(pentafluorophenyl)borate at 100℃; under 30003 Torr; for 1h; Catalytic behavior; Autoclave; | |
With [ReH(NO)2(P(C6H11)3)2]; Dimethylphenylsilane; tris(pentafluorophenyl)borate at 100℃; under 30003 Torr; for 1h; Catalytic behavior; Autoclave; | |
at 80℃; under 30003 Torr; for 24h; |
Conditions | Yield |
---|---|
With isopropyl alcohol at 150℃; under 7500.75 Torr; for 12h; Inert atmosphere; Autoclave; | A 25.1% B 100% C 74.9% |
With isopropyl alcohol at 160℃; for 15h; Autoclave; Inert atmosphere; | |
With isopropyl alcohol at 150℃; for 10h; Catalytic behavior; Reagent/catalyst; Temperature; Sealed tube; | A 24.6 %Chromat. B 47.8 %Chromat. C 24.3 %Chromat. |
With isopropyl alcohol at 150℃; for 6h; Temperature; Sealed tube; | A 15.2 %Chromat. B 17.7 %Chromat. C 5.8 %Chromat. |
Conditions | Yield |
---|---|
With hydrogen In dodecane at 200℃; under 15001.5 Torr; for 8h; | 99.9% |
bei der katalytischen Hyrierung; | |
With phosphoric acid; 5% Pd(II)/C(eggshell); hydrogen In water at 249.84℃; under 37503.8 Torr; for 0.5h; Autoclave; | 87 %Chromat. |
Conditions | Yield |
---|---|
With hydrogen In dodecane at 200℃; under 15001.5 Torr; for 2h; | 99.9% |
With rhodium contaminated with carbon; N-methyldiethanolamine trifluoromethanesulfonate; hydrogen at 120℃; under 30003 Torr; for 6h; Autoclave; | 91.5% |
With carbon nanotubes-supported ruthenium; hydrogen In dodecane; water at 220℃; under 37503.8 Torr; for 3h; Autoclave; | 64 %Chromat. |
With hydrogen at 130℃; under 15001.5 Torr; for 6h; Ionic liquid; Autoclave; Schlenk technique; | 99.4 %Chromat. |
Conditions | Yield |
---|---|
With hydrogen In dodecane at 200℃; under 15001.5 Torr; for 12h; | 99.9% |
Multi-step reaction with 2 steps 1: hydrogen / water / 8 h / 200 °C / 30003 Torr / Autoclave 2: hydrogen / water / 4 h / 200 °C / 30003 Torr View Scheme | |
With palladium on activated charcoal; hydrogen In water at 150℃; under 30003 Torr; for 4h; Reagent/catalyst; Autoclave; |
Conditions | Yield |
---|---|
With hydrogen In dodecane at 200℃; under 15001.5 Torr; for 2h; | 99.6% |
With rhodium contaminated with carbon; N-methyldiethanolamine trifluoromethanesulfonate; hydrogen at 120℃; under 30003 Torr; for 6h; Autoclave; | 93.5% |
With Ni-doped silica; hydrogen In decalin at 140℃; under 22502.3 Torr; for 5h; Reagent/catalyst; Autoclave; | 91.7% |
Conditions | Yield |
---|---|
With hydrogen In dodecane at 300℃; under 45004.5 Torr; for 1h; Autoclave; | 99.3% |
With hafnium tetrakis(trifluoromethanesulfonate); Ru/Al2O3; hydrogen In octane at 250℃; under 30003 Torr; for 2h; Sealed tube; | 94.3% |
With hydrogen In dodecane at 200℃; under 15001.5 Torr; for 2h; | 92% |
Conditions | Yield |
---|---|
With hydrogen; aluminum oxide; nickel at 180℃; | 99% |
With platinum on activated charcoal; N-methyldiethanolamine trifluoromethanesulfonate; hydrogen at 120℃; under 30003 Torr; for 2h; Autoclave; | 93.5% |
at 300℃; Leiten ueber Aktivkohle; |
Conditions | Yield |
---|---|
With tris-(trimethylsilyl)silane; 2,2'-azobis(isobutyronitrile) In toluene at 80℃; for 0.666667h; | 99% |
Conditions | Yield |
---|---|
With bis(acetylacetonate)nickel(II); cetyltrimethylammonim bromide; lithium tri-t-butoxyaluminum hydride; sodium t-butanolate; tricyclohexylphosphine In toluene at 70℃; for 5h; Micellar solution; | A 99% B 99% |
With Ru0.6Ni0.4; hydrogen In water at 95℃; under 760.051 Torr; for 16h; Reagent/catalyst; | A 92% B 96% |
With hydrogen In water at 110℃; under 7500.75 Torr; for 1h; Autoclave; |
Conditions | Yield |
---|---|
With gold on titanium oxide In decane at 299.84℃; under 22502.3 Torr; for 12h; Temperature; High pressure; Inert atmosphere; Autoclave; | 98.7% |
With hydrogen In water at 200℃; under 37503.8 Torr; for 2h; Autoclave; Green chemistry; | |
With hydrogen In dodecane at 224.84℃; under 30003 Torr; for 2h; Autoclave; | |
With carbon nanotubes-supported ruthenium; hydrogen In dodecane; water at 220℃; under 37503.8 Torr; for 3h; Autoclave; | 90 %Chromat. |
Conditions | Yield |
---|---|
With hydrogen In dodecane at 200℃; under 15001.5 Torr; for 8h; | 98.6% |
With dihydrogen hexachloroplatinate; hydrogen; 3-butyl-1-methyl-1H-imidazol-3-ium hexafluorophosphate; 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide at 60℃; under 7500.75 Torr; for 15h; Autoclave; |
aniline
A
cyclohexane
B
cyclohexylamine
C
N-cyclohexyl-cyclohexanamine
D
cyclohexene
Conditions | Yield |
---|---|
With ammonia; hydrogen at 180 - 200℃; | A n/a B 98.4% C 0.08% D n/a |
With hydrogen at 160 - 200℃; under 150015 Torr; | A n/a B 95.9% C 0.45% D n/a |
Conditions | Yield |
---|---|
With gold on titanium oxide In decane at 299.84℃; under 22502.3 Torr; for 12h; Time; High pressure; Inert atmosphere; Autoclave; | 98.2% |
Conditions | Yield |
---|---|
With hydrogen In water at 130℃; for 20h; Reagent/catalyst; Inert atmosphere; Autoclave; Heating; stereoselective reaction; | 97.9% |
With rhodium contaminated with carbon; N-methyldiethanolamine trifluoromethanesulfonate; hydrogen at 120℃; under 30003 Torr; for 24h; Reagent/catalyst; Autoclave; | 97.3% |
With hydrogen In water at 249.84℃; under 30003 Torr; | 93.7% |
Conditions | Yield |
---|---|
With hydrogen In neat (no solvent) at 200℃; under 37503.8 Torr; for 24h; Autoclave; | 97% |
With hydrogen; aluminum oxide; nickel at 190℃; | 90% |
With hydrogen; K-10 montmorillonite; platinum In diethylene glycol dimethyl ether under 37503 Torr; for 30h; Reduction; | 82% |
Conditions | Yield |
---|---|
With hydrogen; palladium dichloride In N,N-dimethyl-formamide under 18751.5 Torr; for 0.333333h; Product distribution; Ambient temperature; various time; | A 0.05% B 95.6% |
With ammonium acetate In methanol Electrochemical reaction; | A 88% B 12% |
With hydrogen; (η3-C3H5)Co[P(OMe)3]3 for 24h; Ambient temperature; | A 7.6% B 48.3% |
Conditions | Yield |
---|---|
With hydrogen In decalin at 20 - 220℃; under 37503.8 - 45004.5 Torr; Reagent/catalyst; Inert atmosphere; Autoclave; | 95% |
With ruthenium-carbon composite; N-methyldiethanolamine trifluoromethanesulfonate; hydrogen at 150℃; under 7500.75 Torr; for 6h; Autoclave; | 91.2% |
With hydrogen; platinum unter geringem Ueberdruck; |
triethylsilane
fluorocyclohexane
A
triethylsilyl fluoride
B
cyclohexane
Conditions | Yield |
---|---|
With C21H16N3P(2+) In dichloromethane at 25℃; for 4h; Reagent/catalyst; | A 95% B n/a |
With [(SIMes)PFMe2][B(C6F5)4]2 In dichloromethane-d2 for 1h; Catalytic behavior; Inert atmosphere; |
Conditions | Yield |
---|---|
With hydrogen In dodecane at 200℃; under 15001.5 Torr; for 2h; | 95% |
Conditions | Yield |
---|---|
With tris-(trimethylsilyl)silane; 2,2'-azobis(isobutyronitrile) at 70℃; | A 4.1% B 93% C 2% |
With tri-n-butyl-tin hydride; 2,2'-azobis(isobutyronitrile) at 70℃; | A 15% B 83% C 1.2% |
With 9-borabicyclo[3.3.1]nonane dimer; tribenzyltin hydride In toluene at 0℃; Product distribution; variation of reagent; | A 29% B 68% C 3% |
Conditions | Yield |
---|---|
With rhodium contaminated with carbon; N-methyldiethanolamine trifluoromethanesulfonate; hydrogen at 150℃; under 7500.75 Torr; for 6h; Autoclave; | 92.3% |
With hydrogen In dodecane at 224.84℃; under 30003 Torr; for 2h; Autoclave; |
1-methoxy-3-phenoxybenzene
A
3-methoxycyclohexan-1-ol
B
cyclohexane
Conditions | Yield |
---|---|
With bis(acetylacetonate)nickel(II); cetyltrimethylammonim bromide; lithium tri-t-butoxyaluminum hydride; sodium t-butanolate; tricyclohexylphosphine In toluene at 70℃; for 5h; Micellar solution; | A 92% B 89% |
Conditions | Yield |
---|---|
With palladium on activated charcoal; N-methyldiethanolamine trifluoromethanesulfonate; hydrogen at 150℃; under 7500.75 Torr; for 6h; Autoclave; | A 91.5% B 90.3% |
With carbon nanotubes-supported ruthenium; hydrogen In dodecane; water at 220℃; under 37503.8 Torr; for 3h; Autoclave; | A 95 %Chromat. B 44 %Chromat. |
With hydrogen at 130℃; under 15001.5 Torr; for 6h; Ionic liquid; Autoclave; Schlenk technique; |
Conditions | Yield |
---|---|
With hydrogen In dodecane at 300℃; under 45004.5 Torr; for 1h; Autoclave; | A 6.08% B 90.52% |
With hydrogen at 320℃; under 127513 Torr; for 1h; Reagent/catalyst; Autoclave; | A 6.8 %Chromat. B 67 %Chromat. |
Conditions | Yield |
---|---|
With bromine; aluminum tri-bromide; Acetyl bromide In dichloromethane at -20℃; for 3h; | 100% |
With bromine; sodium t-butanolate In cyclohexane at 40℃; for 15h; | 100% |
With manganese(IV) oxide; bromine at 80℃; for 0.166667h; Product distribution; Further Variations:; Reagents; reagent ratios, reaction time; | 99% |
Conditions | Yield |
---|---|
cobalt (III) fluoride at 360℃; for 3h; | 100% |
With fluorine Product distribution; Irradiation; | 30% |
With lead(IV) fluoride at 200℃; zuletzt bei 400grad; |
Conditions | Yield |
---|---|
With Fe2(4,4″-dioxido-[1,1′:4′,1″-terphenyl]-3,3″-dicarboxylate); 1-(tert-butylsulfonyl)-2-iodosylbenzene In [D3]acetonitrile at 20℃; for 1.5h; | A 100% B 100% |
With 3-chloro-benzenecarboperoxoic acid; [Ni2(L2H2)(OAc)2] at 20℃; for 1h; | A 7% B 93% |
With 3-chloro-benzenecarboperoxoic acid; (5,10,15,20-tetrakis(pentafluorophenyl)porphyrinato)iron(III) chloride In dichloromethane; acetonitrile for 1h; Product distribution; Ambient temperature; other catalysts; kinetic isotope effect; | A 2% B 89% |
Conditions | Yield |
---|---|
With 4-tert-butylpyridine; hydrogen sulfide; oxygen; iron(II) chloride In acetonitrile for 4h; Ambient temperature; | 100% |
With 4-tert-butylpyridine; 2-Picolinic acid; dihydrogen peroxide; triphenylphosphine; iron(II) chloride In acetonitrile at 0℃; | 99% |
With di-tert-butyl peroxide at 120℃; for 18h; Reagent/catalyst; | 96% |
cyclohexane
N,O-bistrimethylsilyl-N-(ethoxycarbonyl)hydroxylamine
A
Hexamethyldisiloxane
B
ethyl N-cyclohexylcarbamate
C
urethane
Conditions | Yield |
---|---|
at 100℃; for 25h; | A 100% B 80% C 8% |
at 45℃; for 58h; Irradiation; | A 75% B 45% C 55% |
cyclohexane
perpentene-4 oate de tertiobutyle
A
cyclohexylcyclohexane
B
butylcyclohexane
C
cyclohexyl-5 pentanolide-4
D
acetone
E
5-methyl-dihydro-furan-2-one
F
tert-butyl alcohol
Conditions | Yield |
---|---|
at 120℃; for 4h; Product distribution; Mechanism; different ratios of reactant, reactants, reaction times and temperatures; | A 5% B 5% C 35% D n/a E 1% F 100% |
cyclohexane
1,1,3,3-tetramethyl-2,3-dihydro-1H-isoindol-2-yloxoyl radical
2-(t-butylazo)prop-2-yl hydroperoxide
A
2-cyclohexyloxy-1,1,3,3-tetramethyl-2,3-dihydro-1H-isoindole
B
2-tert-butoxy-1,1,3,3-tetramethylisoindoline
C
acetone
D
isobutene
Conditions | Yield |
---|---|
at 70℃; for 17h; Mechanism; Rate constant; Thermodynamic data; var. of nitroxide, solvent, temp., EA, ΔH(excit.), ΔS(excit.); | A 96% B 82% C 100% D 15% |
Conditions | Yield |
---|---|
cobalt (III) fluoride at 360℃; for 3h; Product distribution; | A n/a B 100% |
Conditions | Yield |
---|---|
With 4-tert-butylpyridine; hydrogen sulfide; oxygen; iron(II) chloride In acetonitrile for 4h; Ambient temperature; | 100% |
cyclohexane
2,2,2-trichloroethyl sulfamate
Conditions | Yield |
---|---|
With [bis(acetoxy)iodo]benzene; C32H44ClN4O4Rh2*3CH2Cl2 at 20℃; for 3h; Inert atmosphere; | 100% |
With bis(tertbutylcarbonyloxy)iodobenzene; Rh2(esp)2 In benzene at 23℃; | 95% |
With bis{rhodium[3,3'-(1,3-phenylene)bis(2,2-dimethylpropanoic acid)]}; [bis(acetoxy)iodo]benzene In water at 4℃; for 24h; | 64% |
With [p-(trifluoromethyl)phenyl](diacetoxy)-λ3-bromane at 0 - 15℃; for 3h; Inert atmosphere; | 18% |
Conditions | Yield |
---|---|
In gas reaction in a mass spectrometer; total pressure: 4E-6 Torr; | A 100% B 100% |
nonafluoro-tert-butanesulfenyl chloride
cyclohexane
A
nonafluoro-tert-butanethiol
B
cyclohexyl chloride
Conditions | Yield |
---|---|
A 100% B 100% | |
A 100% B 100% |
Conditions | Yield |
---|---|
In benzene at 80℃; for 4h; Inert atmosphere; | 100% |
Conditions | Yield |
---|---|
With MCM-41 silicate; hydrogen; di(rhodium)tetracarbonyl dichloride at 100℃; under 21001.7 Torr; for 20h; | 99.4% |
With Rh; benzaldehyde In benzene Mechanism; Irradiation; other d8 metal carbonyls, other aromatic ketones and aldehydes; relative quantum yields; |
Conditions | Yield |
---|---|
With C28H6Ag2Au2F24N2 In cyclohexane for 12h; Inert atmosphere; | 99% |
With C56H82Cl2Cu2N4O2P2; sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate In dichloromethane at 20℃; for 12h; Inert atmosphere; Schlenk technique; | 98% |
With C4H11B22Br12IN2(2-)*2Li(1+); copper dichloride In tetrahydrofuran at 90℃; for 3h; Reagent/catalyst; Inert atmosphere; Reflux; | 92.6% |
Conditions | Yield |
---|---|
With nitric acid; trifluoroacetic acid; N-hydroxy-5-carboxy-phthalimide at 23℃; for 18h; Reagent/catalyst; | 99% |
With 2-pyrazylcarboxylic acid; FeCl2(κ3-HC(C3H3N2)3); ozone at 20℃; for 6h; Catalytic behavior; Time; Reagent/catalyst; Schlenk technique; Green chemistry; | 96% |
In acetic acid at 115℃; under 22502.3 Torr; for 5h; Reagent/catalyst; Pressure; | 95% |
Conditions | Yield |
---|---|
With dibenzoyl peroxide for 14h; Product distribution; Heating; further educts and peroxides; | 99% |
With dilauryl peroxide for 14h; Heating; | 99% |
With dibenzoyl peroxide at 80℃; Yield given; |
Unlike compounds like benzene, Cyclohexane (CAS NO.110-82-7) cannot easily be obtained from natural resources such as coal. Towards the end of the nineteenth century early chemical investigators had to depend on organic synthesis. It took them 30 years to flesh out the details.
In 1867 Marcellin Berthelot reduced benzene with hydroiodic acid at elevated temperatures. He incorrectly identified the reaction product as n-hexane not only because of the convenient match in boiling point (69°C) but also because he did not believe benzene was a cyclic molecule but rather some sort of association of acetylene.
In 1870 one of his sceptics Adolf von Baeyer repeated the reaction and pronounced the same reaction product hexahydrobenzene and in 1890 Vladimir Markovnikov believed he was able to distill the same compound from Caucasus petroleum calling his concoction hexanaphtene.
In 1894 Baeyer synthesized Cyclohexane (CAS NO.110-82-7) starting with a Dieckmann condensation of pimelic acid, and in the same year E. Haworth and W.H. Perkin Jr. (1860 - 1929) did the same in a Wurtz reaction of 1,6-dibromohexane.
Surprisingly their cyclohexanes(110-82-7) boiled higher by 10°C than either hexahydrobenzene or hexanaphtene but this riddle was solved in 1895 by Markovnikov, N.M. Kishner and Nikolay Zelinsky when they re-diagnosed hexahydrobenzene and hexanaphtene as methylcyclopentane, the result of an unexpected rearrangement reaction.
Community Right-To-Know List.
OSHA PEL: TWA 300 ppm
ACGIH TLV: TWA 100 ppm
DFG MAK: 200 ppm (720 mg/m3)
DOT Classification: 3; Label: Flammable Liquid
For occupational chemical analysis use NIOSH: Hydrocarbons.
The Cyclohexane is an organic compound with the formula C6H12. The IUPAC name of this chemical is cyclohexane. With the CAS registry number 110-82-7, the product's categories are Analytical Chemistry; Solvents for HPLC & Spectrophotometry; Solvents for Spectrophotometry; HPLC Solvents; Aluminum Bottles; Solvent Bottles; Solvents; Alpha Sort; C; CAlphabetic; CO - CZ; Volatiles/Semivolatiles; CO - CZChemical Class; Chemical Class; Hydrocarbons; NeatsAnalytical Standards ;C-D, Puriss p.a. ACS; Analytical Reagents for General Use; Puriss p.a. ACS; Amber Glass Bottles; Spectrophotometric Grade Solvents; Spectrophotometric GradeSolvents; Anhydrous Grade SolventsSolvents; AnhydrousSolvents; Returnable Container Solvents; Carbon Steel Cans with NPT Threads; ReagentPlus(R) Solvent Grade Products; ReagentPlus(R)Semi-Bulk Solvents; ReagentPlus(R)Solvents; Pesticide Residue Analysis (PRA) Solvents Solvent Bottles; PRA; ACS Grade Solvents; ACS GradeSemi-Bulk Solvents; ACS GradeSolvents; Chromatography/CE Reagents; Pestanal/Residue Analysis; Solvents - GC/SH; LC-MS Plus and Gradient; Spectroscopy; UV/Vis Solvents; UV/Visible (UV/VIS) Spectroscopy. Besides, it is colorless liquid, which should be stored in in a cool and well-ventilated place.
Physical properties about Cyclohexane are: (1)ACD/LogP: 3.16; (2)ACD/LogD (pH 5.5): 3.163; (3)ACD/LogD (pH 7.4): 3.163; (4)ACD/BCF (pH 5.5): 149.118; (5)ACD/BCF (pH 7.4): 149.118; (6)ACD/KOC (pH 5.5): 1251.474; (7)ACD/KOC (pH 7.4): 1251.474; (8)Index of Refraction: 1.433; (9)Molar Refractivity: 27.67 cm3; (10)Molar Volume: 106.454 cm3; (11)Polarizability: 10.969×10-24cm3; (12)Surface Tension: 25.943 dyne/cm; (13)Density: 0.791 g/cm3; (14)Enthalpy of Vaporization: 29.97 kJ/mol; (15)Boiling Point: 80.719 °C at 760 mmHg; (16)Vapour Pressure: 93.669 mmHg at 25°C.
Preparation: this chemical can be quantitatively produced from benzene by hydrogenation over either a nickel or a platinum catalyst at 210 °C and 350 to 500 psi hydrogen. Several reactors may be used in series and the yield is over 99 percent.
C6H6 + 3H2 → C6H12
Uses of Cyclohexane: commercially most of cyclohexane produced is converted into cyclohexanone-cyclohexanol mixture (or "KA oil") by catalytic oxidation. KA oil is then used as a raw material for adipic acid and caprolactam. Practically, if the cyclohexanol content of KA oil is higher than cyclohexanone, it is more likely(economical) to be converted into adipic acid, and the reverse case, caprolactam production is more likely. Such ratio in KA oil can be controlled by selecting suitable oxidation catalyst. Some of cyclohexane is used as an organic solvent. Cyclohexane is also used for calibration of Differential scanning calorimetry (DSC) instruments, because of a convenient crystal-crystal transition at -87.1 C.
When you are using this chemical, please be cautious about it as the following:
It is highly flammable and toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Please keep away from sources of ignition - No smoking and take precautionary measures against static discharges. Besides, this chemical is irritating to skin and may cause lung damage if swallowed. When you are using it, avoid contact with eyes and avoid release to the environment. Refer to special instructions/safety data sheet. This material and its container must be disposed of as hazardous waste.
You can still convert the following datas into molecular structure:
(1)SMILES: C1CCCCC1
(2)InChI: InChI=1/C6H12/c1-2-4-6-5-3-1/h1-6H2
(3)InChIKey: XDTMQSROBMDMFD-UHFFFAOYAZ
(4)Std. InChI: InChI=1S/C6H12/c1-2-4-6-5-3-1/h1-6H2
(5)Std. InChIKey: XDTMQSROBMDMFD-UHFFFAOYSA-N
The toxicity data is as follows:
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
mammal (species unspecified) | LC50 | inhalation | 70gm/m3 (70000mg/m3) | Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 32(10), Pg. 25, 1988. | |
mouse | LCLo | inhalation | 70gm/m3/2H (70000mg/m3) | "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 41, 1982. | |
mouse | LD50 | oral | 813mg/kg (813mg/kg) | Raw Material Data Handbook, Vol.1: Organic Solvents, 1974. Vol. 1, Pg. 17, 1974. | |
rabbit | LCLo | inhalation | 89600mg/m3/1H (89600mg/m3) | BEHAVIORAL: GENERAL ANESTHETIC BEHAVIORAL: TREMOR BEHAVIORAL: MUSCLE CONTRACTION OR SPASTICITY) | Journal of Industrial Hygiene and Toxicology. Vol. 25, Pg. 323, 1943. |
rabbit | LD | skin | > 180gm/kg (180000mg/kg) | Journal of Industrial Hygiene and Toxicology. Vol. 25, Pg. 199, 1943. | |
rabbit | LDLo | oral | 5500mg/kg (5500mg/kg) | GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA" | Journal of Industrial Hygiene and Toxicology. Vol. 25, Pg. 199, 1943. |
rat | LD50 | oral | 12705mg/kg (12705mg/kg) | Toxicology and Applied Pharmacology. Vol. 19, Pg. 699, 1971. |
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