Product Name

  • Name

    1,1-Difluoroethane

  • EINECS 200-866-1
  • CAS No. 75-37-6
  • Article Data68
  • CAS DataBase
  • Density 0.907 g/cm3
  • Solubility
  • Melting Point -117 °C
  • Formula C2H4 F2
  • Boiling Point -25 °C
  • Molecular Weight 66.0506
  • Flash Point
  • Transport Information UN 1030 2.1
  • Appearance liquefied colourless gas under pressure
  • Safety 16-33-36-38
  • Risk Codes 11
  • Molecular Structure Molecular Structure of 75-37-6 (1,1-Difluoroethane)
  • Hazard Symbols FlammableF
  • Synonyms Propellant 152A;R 152a;Solkane 152a;TG 152a;1,1-Difluoroethane;Algofrene 67;Dymel 152;Dymel 152A;Ethylidene fluoride;F 152A;FC 152a;FKW152a;Formacel Z 2;Fron 152a;Genetron 152A;HCFC 152a;HFA 152a;HFC 152a;
  • PSA 0.00000
  • LogP 1.27140

Synthetic route

1,1-dichloroethane
75-34-3

1,1-dichloroethane

1,1-difluoroethane
75-37-6

1,1-difluoroethane

Conditions
ConditionsYield
With hydrogen fluoride; chromium(III) oxide at 200℃; under 1500.15 Torr; for 10 - 200h; Product distribution / selectivity; Molecular sieve MS-13X;96.2%
With hydrogen fluoride; chromium(III) oxide at 200℃; under 1500.15 Torr; for 3 - 100h; Product distribution / selectivity;62%
With hydrogen fluoride; antimonypentachloride at 50℃; im Autoklaven;
ethene
74-85-1

ethene

A

1,1-difluoroethane
75-37-6

1,1-difluoroethane

B

1,2-difluoroethane
624-72-6

1,2-difluoroethane

C

1,1,2-Trifluoroethan
430-66-0

1,1,2-Trifluoroethan

Conditions
ConditionsYield
With xenon difluoride; silicon tetrafluoride at 20℃; for 24h; Fluorination;A 25%
B 63%
C 9%
1,2-dichloro-ethane
107-06-2

1,2-dichloro-ethane

1,1-difluoroethane
75-37-6

1,1-difluoroethane

Conditions
ConditionsYield
With hydrogen fluoride; iron(III) chloride; titanium tetrachloride at 90 - 120℃; under 7500.75 - 15001.5 Torr; for 1.5 - 30h; Product distribution / selectivity;46%
With hydrogen fluoride; titanium tetrachloride at 95 - 120℃; under 7500.75 Torr; for 3.5 - 29h; Product distribution / selectivity;21%
Ethyl trifluorovinyl ether
1763-27-5

Ethyl trifluorovinyl ether

A

1,1-difluoroethane
75-37-6

1,1-difluoroethane

B

1-fluoroethane
353-36-6

1-fluoroethane

C

perfluoroethyl ethyl ether
22052-81-9

perfluoroethyl ethyl ether

D

1,1,1,2,2-pentafluoro-2-(1-fluoro-ethoxy)-ethane

1,1,1,2,2-pentafluoro-2-(1-fluoro-ethoxy)-ethane

Conditions
ConditionsYield
With cobalt (III) fluoride at -196 - 20℃; for 0.5h; Fluorination;A 5%
B 2%
C 45%
D 2%
1,1-dichloroethane
75-34-3

1,1-dichloroethane

A

1,1-difluoroethane
75-37-6

1,1-difluoroethane

B

1-chloro-1-fluoroethane
1615-75-4

1-chloro-1-fluoroethane

Conditions
ConditionsYield
With hydrogen fluoride; tin(ll) chloride at 60℃; under 1064 - 2660 Torr;
With hydrogen fluoride; tin(ll) chloride at 60℃; under 1064 - 2660 Torr;
With hydrogen fluoride; tin(ll) chloride at 60℃; under 1064 - 2660 Torr;
1,1-Dibromoethane
557-91-5

1,1-Dibromoethane

1,1-difluoroethane
75-37-6

1,1-difluoroethane

Conditions
ConditionsYield
With mercury(II) fluoride
With mercury monofluoride; iodine
1-fluoroethane
353-36-6

1-fluoroethane

1,1-difluoroethane
75-37-6

1,1-difluoroethane

Conditions
ConditionsYield
With hydrogen fluoride; lead dioxide at 100℃; unter Druck;
Vinylidene fluoride
75-38-7

Vinylidene fluoride

1,1-difluoroethane
75-37-6

1,1-difluoroethane

Conditions
ConditionsYield
With palladium on activated charcoal at 120℃; Hydrogenation;
1,1'-dichloro-2,2'-difluoroethene
79-35-6

1,1'-dichloro-2,2'-difluoroethene

1,1-difluoroethane
75-37-6

1,1-difluoroethane

Conditions
ConditionsYield
With palladium on activated charcoal at 120℃; Hydrogenation;
acetylene
74-86-2

acetylene

1,1-difluoroethane
75-37-6

1,1-difluoroethane

Conditions
ConditionsYield
With hydrogen fluoride; boron trifluoride at 0 - 30℃; unter Druck;
With hydrogen fluoride; pyrographite; mercury(II) oxide at 20 - 40℃;
With aluminum(III) fluoride; hydrogen fluoride at 300℃;
With hydrogen fluoride; fluorosulphonic acid at 0℃;
Hexafluorobenzene
392-56-3

Hexafluorobenzene

2,2-difluoropropionyl peroxide
83698-72-0

2,2-difluoropropionyl peroxide

A

1,1-difluoroethane
75-37-6

1,1-difluoroethane

B

carbon dioxide
124-38-9

carbon dioxide

Conditions
ConditionsYield
In n-heptane at 50℃; for 0.333333h; Product distribution; relative rate const. of CH3CF2 radical to heptane;
n-heptane
142-82-5

n-heptane

2,2-difluoropropionyl peroxide
83698-72-0

2,2-difluoropropionyl peroxide

A

1,1-difluoroethane
75-37-6

1,1-difluoroethane

B

carbon dioxide
124-38-9

carbon dioxide

Conditions
ConditionsYield
at 50℃; for 0.333333h; Product distribution; relative rate const. of CF3 radical to hexafluorobenzene, octafluorotoluene, 1,4-bis(pentafluorophenoxy)perfluorobutane, and benzene;
1,4-bis(trifluoromethyl)benzene
433-19-2

1,4-bis(trifluoromethyl)benzene

2,2-difluoropropionyl peroxide
83698-72-0

2,2-difluoropropionyl peroxide

A

1,1-difluoroethane
75-37-6

1,1-difluoroethane

B

carbon dioxide
124-38-9

carbon dioxide

Conditions
ConditionsYield
In n-heptane at 50℃; for 0.333333h; Product distribution; relative rate const. of CH3CF2 radical to heptane and to hexafluorobenzene;
perfluorotoluene
434-64-0

perfluorotoluene

2,2-difluoropropionyl peroxide
83698-72-0

2,2-difluoropropionyl peroxide

A

1,1-difluoroethane
75-37-6

1,1-difluoroethane

B

carbon dioxide
124-38-9

carbon dioxide

Conditions
ConditionsYield
In n-heptane at 50℃; for 0.333333h; Product distribution; relative rate const. of CH3CF2 radical to heptane;
2,2-difluoropropionyl peroxide
83698-72-0

2,2-difluoropropionyl peroxide

1,4-bis(pentafluorophenoxy)perfluorobutane
88388-83-4

1,4-bis(pentafluorophenoxy)perfluorobutane

A

1,1-difluoroethane
75-37-6

1,1-difluoroethane

B

carbon dioxide
124-38-9

carbon dioxide

Conditions
ConditionsYield
In n-heptane at 50℃; for 0.333333h; Product distribution; relative rate const. of CH3CF2 radical to heptane and to hexafluorobenzene;
2,2-difluoropropionyl peroxide
83698-72-0

2,2-difluoropropionyl peroxide

A

1,1-difluoroethane
75-37-6

1,1-difluoroethane

B

Vinylidene fluoride
75-38-7

Vinylidene fluoride

C

2,2,3,3-tetrafluorobutane
421-74-9

2,2,3,3-tetrafluorobutane

Conditions
ConditionsYield
In n-heptane at 50℃; Kinetics; Product distribution; Mechanism; thermal decomposition, other temperatures, other solvents;
methylenesulfurtetrafluoride
66793-25-7

methylenesulfurtetrafluoride

acetaldehyde
75-07-0

acetaldehyde

A

1,1-difluoroethane
75-37-6

1,1-difluoroethane

B

ethene
74-85-1

ethene

trifluoroacetic anhydride
407-25-0

trifluoroacetic anhydride

A

1,1-difluoroethane
75-37-6

1,1-difluoroethane

B

Carbonyl fluoride
353-50-4

Carbonyl fluoride

C

trifluoroacetyl fluoride
354-34-7

trifluoroacetyl fluoride

D

2,2-difluorocyclopropane
558-29-2

2,2-difluorocyclopropane

E

carbon monoxide
201230-82-2

carbon monoxide

F

γ-lactone 2,2-difluorobutyric acid

γ-lactone 2,2-difluorobutyric acid

Conditions
ConditionsYield
With ethane; sulphur hexafluoride for 0.0833333h; Product distribution; Mechanism; Irradiation; other perfluoro acid anhydride;
2,2-difluoropropionyl peroxide
83698-72-0

2,2-difluoropropionyl peroxide

benzene
71-43-2

benzene

A

1,1-difluoroethane
75-37-6

1,1-difluoroethane

B

carbon dioxide
124-38-9

carbon dioxide

Conditions
ConditionsYield
In n-heptane at 50℃; for 0.333333h; Product distribution; relative rate const. of CH3CF2 radical to heptane and to hexafluorobenzene;
ethene
74-85-1

ethene

A

1,1-difluoroethane
75-37-6

1,1-difluoroethane

B

1,2-difluoroethane
624-72-6

1,2-difluoroethane

C

2,2,2-trifluoroethanol
420-46-2

2,2,2-trifluoroethanol

D

1,1,2-Trifluoroethan
430-66-0

1,1,2-Trifluoroethan

E

1,1,1,2-tetrafluoroethane
811-97-2

1,1,1,2-tetrafluoroethane

F

1,1,2,2-tetrafluoroethane
359-35-3

1,1,2,2-tetrafluoroethane

Conditions
ConditionsYield
With cobalt (III) fluoride at 95℃; Product distribution; Mechanism; var. temp. and metal fluorides;
chloroethylene
75-01-4

chloroethylene

1,1-difluoroethane
75-37-6

1,1-difluoroethane

Conditions
ConditionsYield
With hydrogen fluoride Heating;
hydrogen fluoride
7664-39-3

hydrogen fluoride

acetylene
74-86-2

acetylene

1,1-difluoroethane
75-37-6

1,1-difluoroethane

Conditions
ConditionsYield
Leiten ueber quecksilberhaltige Katalysatoren;
Leiten ueber quecksilberhaltige Katalysatoren;
hydrogen fluoride
7664-39-3

hydrogen fluoride

boron trifluoride
7637-07-2

boron trifluoride

acetylene
74-86-2

acetylene

1,1-difluoroethane
75-37-6

1,1-difluoroethane

Conditions
ConditionsYield
at 0 - 30℃;
hydrogen fluoride
7664-39-3

hydrogen fluoride

fluorosulphonic acid
7789-21-1

fluorosulphonic acid

acetylene
74-86-2

acetylene

1,1-difluoroethane
75-37-6

1,1-difluoroethane

Conditions
ConditionsYield
at 0℃;
at 0℃;
hydrogen fluoride
7664-39-3

hydrogen fluoride

acetylene
74-86-2

acetylene

AlF3-graphite

AlF3-graphite

1,1-difluoroethane
75-37-6

1,1-difluoroethane

Conditions
ConditionsYield
at 260 - 320℃;
at 260 - 320℃;
butanone
78-93-3

butanone

nitrogen

nitrogen

cobalt (III)-fluoride

cobalt (III)-fluoride

A

1,1-difluoroethane
75-37-6

1,1-difluoroethane

B

1,1,2-Trifluoroethan
430-66-0

1,1,2-Trifluoroethan

C

1,1,2,2-tetrafluoroethane
359-35-3

1,1,2,2-tetrafluoroethane

D

fluoroacetyl fluoride
1514-42-7

fluoroacetyl fluoride

Conditions
ConditionsYield
at 80℃; Produkt5:Difluormethan, Produkt6:Trifluormethan, Produkt7:Carbonylfluorid;
1,1-dichloroethane
75-34-3

1,1-dichloroethane

hydrogen fluoride
7664-39-3

hydrogen fluoride

1,1-difluoroethane
75-37-6

1,1-difluoroethane

Conditions
ConditionsYield
at 150℃; unter Druck;
1,1-dichloroethane
75-34-3

1,1-dichloroethane

hydrogen fluoride
7664-39-3

hydrogen fluoride

antimonypentachloride
7647-18-9

antimonypentachloride

1,1-difluoroethane
75-37-6

1,1-difluoroethane

Conditions
ConditionsYield
at 50℃; im Autoklaven;
(pentamethylcyclopentadienyl)2ZrH2
61396-34-7

(pentamethylcyclopentadienyl)2ZrH2

1,1-difluoroethane
75-37-6

1,1-difluoroethane

[(η(5)-pentamethylcyclopentadienyl)2ZrHF]
87985-79-3

[(η(5)-pentamethylcyclopentadienyl)2ZrHF]

Conditions
ConditionsYield
With hydrogen In not given byproducts: ethane; treating 1,1-difluoroethane with zirconium complex at 150°C for 1 d under H2;90%
1,1-difluoroethane
75-37-6

1,1-difluoroethane

Difluoroacetic acid
381-73-7

Difluoroacetic acid

Conditions
ConditionsYield
With dihydrogen peroxide at 140℃; Catalytic behavior; Reagent/catalyst; Temperature; Inert atmosphere;88%
1,1-difluoroethane
75-37-6

1,1-difluoroethane

bis-trifluoromethyl-aminooxyl
2154-71-4

bis-trifluoromethyl-aminooxyl

A

N,N-bis(trifluoromethyl)hydroxylamine
359-63-7

N,N-bis(trifluoromethyl)hydroxylamine

B

1,2-Bis-(di-trifluormethyl-aminooxy)-1,1-difluor-ethan
24616-12-4

1,2-Bis-(di-trifluormethyl-aminooxy)-1,1-difluor-ethan

C

O-(1,1-Difluoro-ethyl)-N,N-bis-trifluoromethyl-hydroxylamine

O-(1,1-Difluoro-ethyl)-N,N-bis-trifluoromethyl-hydroxylamine

Conditions
ConditionsYield
at 80℃; for 240h;A 81%
B 5%
C 76%
1,1-difluoroethane
75-37-6

1,1-difluoroethane

acetylene
74-86-2

acetylene

1-fluoroethylene
75-02-5

1-fluoroethylene

Conditions
ConditionsYield
at 340℃; other temperatures, other catalysts;77.5%
1,1-difluoroethane
75-37-6

1,1-difluoroethane

perfluoropropylene
116-15-4

perfluoropropylene

1,1,1,2,3,3,4,4-Octafluoropentan
58705-98-9

1,1,1,2,3,3,4,4-Octafluoropentan

Conditions
ConditionsYield
at 290℃; for 96h;65%
1,1-difluoroethane
75-37-6

1,1-difluoroethane

(E)-1,3-diethyl-7-methyl-8-(4-(piperidin-4-yloxy)styryl)-1H-purine-2,6-(3H,7H)-dione

(E)-1,3-diethyl-7-methyl-8-(4-(piperidin-4-yloxy)styryl)-1H-purine-2,6-(3H,7H)-dione

(E)-8-(4-((1-(2,2-difluoroethyl)piperidin-4-yl)oxy)styryl)-1,3-diethyl-7-methyl-1H-purine-2,6-(3H,7H)-dione

(E)-8-(4-((1-(2,2-difluoroethyl)piperidin-4-yl)oxy)styryl)-1,3-diethyl-7-methyl-1H-purine-2,6-(3H,7H)-dione

Conditions
ConditionsYield
With potassium carbonate; methyl p-toluene sulfonate; sodium iodide In acetonitrile at 90℃; for 20h;60.8%
1,1-difluoroethane
75-37-6

1,1-difluoroethane

1-fluoroethylene
75-02-5

1-fluoroethylene

Conditions
ConditionsYield
With hydrogen fluoride; Alpha-chromium oxide obtained from the pyrolysis of ammonium dichromate, treated with HF for 9 - 162h;29.8%
With hydrogen fluoride; chromium(III) oxide at 245 - 275℃; for 5 - 49h; Catalys was activated in a stream of HF up to 350 C;13.2%
With hydrogen fluoride; Alpha-chromium oxide obtained from the pyrolysis of ammonium dichromate, treated with HF at 200 - 245℃; for 15 - 47.5h;6%
1,1-difluoroethane
75-37-6

1,1-difluoroethane

A

ethene
74-85-1

ethene

B

1-fluoroethylene
75-02-5

1-fluoroethylene

C

acetylene
74-86-2

acetylene

Conditions
ConditionsYield
With hydrogen fluoride; Guingnet's green at 250 - 400℃; for 10 - 129h;A 0%
B 19.6%
C 0%
With hydrogen fluoride; Alpha-chromium oxide obtained from the pyrolysis of ammonium dichromate, treated with HF at 250 - 350℃;A 0%
B 19.3%
C 0%
With hydrogen fluoride; Alpha-chromium oxide prepared by the precipitation of chromium hydroxide from chromium nitrate followed by calcination in air at 500 C for 72 hours, treated with HF at 250 - 350℃;A 0%
B 19.9%
C 0%
1,1-difluoroethane
75-37-6

1,1-difluoroethane

1,1-difluorotetrachloroethane
76-11-9

1,1-difluorotetrachloroethane

Conditions
ConditionsYield
at 450 - 475℃; durch photochemische Chlorierung;
With chlorine; pyrographite at 300℃;
1,1-difluoroethane
75-37-6

1,1-difluoroethane

2,2,2-trifluoroethanol
420-46-2

2,2,2-trifluoroethanol

Conditions
ConditionsYield
With manganese(IV) oxide; hydrogen fluoride at 125℃;
With chromium(III) oxide; hydrogen fluoride at 50℃; unter Druck;
With hydrogen fluoride; lead dioxide at 125℃;
1,1-difluoroethane
75-37-6

1,1-difluoroethane

1-Chloro-1,1-difluoroethane
75-68-3

1-Chloro-1,1-difluoroethane

Conditions
ConditionsYield
With chlorine In gas at 21.9℃; under 760 Torr; for 0.000666667h; Irradiation; time history of ignition;
bei der Photochlorierung;
beim Chlorieren im Sonnenlicht;
1,1-difluoroethane
75-37-6

1,1-difluoroethane

A

1-Chloro-1,1-difluoroethane
75-68-3

1-Chloro-1,1-difluoroethane

B

1,2-dichloro-1,1-difluoroethane
1649-08-7

1,2-dichloro-1,1-difluoroethane

Conditions
ConditionsYield
beim Chlorieren im Sonennlicht;
1,1-difluoroethane
75-37-6

1,1-difluoroethane

Dichlorodifluoromethane
75-71-8

Dichlorodifluoromethane

Conditions
ConditionsYield
With chlorine at 700℃;
With chlorine at 800℃;
1,1-difluoroethane
75-37-6

1,1-difluoroethane

1,2-dichloro-1,1-difluoroethane
1649-08-7

1,2-dichloro-1,1-difluoroethane

Conditions
ConditionsYield
beim Chlorieren im Sonnenlicht;
1,1-difluoroethane
75-37-6

1,1-difluoroethane

1,1-dichloro-2,2-difluoroethane
471-43-2

1,1-dichloro-2,2-difluoroethane

Conditions
ConditionsYield
at 200℃; bei der Photochlorierung;
1,1-difluoroethane
75-37-6

1,1-difluoroethane

Vinylidene fluoride
75-38-7

Vinylidene fluoride

Conditions
ConditionsYield
With Dichlorodifluoromethane; chlorine at 650℃;
With chlorine at 610℃;
1,1-difluoroethane
75-37-6

1,1-difluoroethane

1,1,2-trichloro-2,2-difluoroethane
354-21-2

1,1,2-trichloro-2,2-difluoroethane

Conditions
ConditionsYield
With chlorine at 200℃; unter Belichtung;
1,1-difluoroethane
75-37-6

1,1-difluoroethane

1,1'-dichloro-2,2'-difluoroethene
79-35-6

1,1'-dichloro-2,2'-difluoroethene

Conditions
ConditionsYield
With Dichlorodifluoromethane; chlorine at 610 - 680℃;
With chlorine at 610 - 680℃;
1,1-difluoroethane
75-37-6

1,1-difluoroethane

trichlorofluoroethene
359-29-5

trichlorofluoroethene

Conditions
ConditionsYield
With chlorine at 800℃;

Difluoroethane Consensus Reports

Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program.

Difluoroethane Specification

The Ethylidene difluoride, with the 75-37-6, has the IUPAC name of 1,1-difluoroethane. This is a kind of colourless liquid with the odour of ether, and its product categories are including Industrial/Fine Chemicals; refrigerants; Organics; Refrigerant. Besides, it is incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides. If contacting with the liquid, it can cause frostbite, and it is easily ignited.

The physical properties of this chemical are as follows: (1)ACD/LogP: 0.65; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 0.65; (4)ACD/LogD (pH 7.4): 0.65; (5)ACD/BCF (pH 5.5): 1.84; (6)ACD/BCF (pH 7.4): 1.84; (7)ACD/KOC (pH 5.5): 53.85; (8)ACD/KOC (pH 7.4): 53.85; (9)#H bond acceptors: 0; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 0; (12)Polar Surface Area: 0; (13)Index of Refraction: 1.252; (14)Molar Refractivity: 11.6 cm3; (15)Molar Volume: 72.8 cm3; (16)Polarizability: 4.59 ×10-24 cm3; (17)Surface Tension: 9.5 dyne/cm; (18)Density: 0.907 g/cm3; (19)Enthalpy of Vaporization: 21.89 kJ/mol; (20)Vapour Pressure: 4100 mmHg at 25°C; (21)Exact Mass: 66.028107; (22)MonoIsotopic Mass: 66.028107; (23)Topological Polar Surface Area: 0; (24)Heavy Atom Count: 4; (25)Formal Charge: 0; (26)Complexity: 11.5.

The production method of this chemical is as below: Firstly. calcium carbide could react with water in the acetylene reactor to produce acetylene, and then go through washing, impurity by the sodium hypochlorite; Secondly, the purified acetylene has the complete drying and then put into the fluorination reactor; Thirdly, with the existence of sulfuryl fluoride, acetylene could react with hydrogen fluoride to produce crude Ethylidene difluoride; Lastly, go through the process of condensation, fractionation to get the products.

As to its usage, it is widely applied in many ways. It could be used as the Freon substitute, refrigerant, aerosol and so on; It could also be used as the important raw material of vinyl fluoride. Besides, it is also commonly found in electronic cleaning products, and many consumer aerosol products that must meet stringent VOC requirements.

When you are dealing with this chemical, please be more cautious. It is a kind of highly flammable chemicals which may catch fire in contact with air, only needing brief contact with an ignition source. And it has a very low flash point or evolve highly flammable gases in contact with water. Therefore, you should take the following instructions. Wear suitable protective clothing and then take precautionary measures against static discharges. Besides, keep away from sources of ignition - No smoking, and if in case of insufficient ventilation, wear suitable respiratory equipment. In addition, there is one hidden danger that is if under prolonged exposure to fire or heat, the containers may rupture violently and rocket, so you should be very careful while keeping this chemical. 
 
In addition, you could convert the following datas into the molecular structure:
(1)Canonical SMILES: CC(F)F
(2)InChI: InChI=1S/C2H4F2/c1-2(3)4/h2H,1H3
(3)InChIKey: NPNPZTNLOVBDOC-UHFFFAOYSA-N 

Below are the toxicity information of this chemical:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LC50 inhalation 977gm/m3/2H (977000mg/m3)   "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 54, 1982.
rat LCLo inhalation 64000ppm/4H (64000ppm)   Journal of Industrial Hygiene and Toxicology. Vol. 31, Pg. 343, 1949.
 
rat LDLo oral > 1500mg/kg (1500mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) National Technical Information Service. Vol. OTS0530083,

 

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