Hexachloroethane supplier

Name
Perchloroethane
EINECS 200-666-4
CAS No. 67-72-1
Article Data390
CAS DataBase
Density 1.821 g/cm³
Solubility 0.05 g/L (22 °C) in water
Melting Point 184 °C
Formula C₂Cl₆
Boiling Point 186.8 °C at 760 mmHg
Molecular Weight 236.74
Flash Point 61.3 °C
Transport Information UN 9037
Appearance white crystalline powder
Safety 36/37-61-45-36/37/39-26-24-16-7
Risk Codes 40-51/53-36/37/38-39/23/24/25-36/38-23/24/25-11
Molecular Structure
Hazard Symbols Xn, N, T, F
Synonyms Phenohep;Ethane,hexachloro- (8CI,9CI);1,1,1,2,2,2-Hexachloroethane;1,2-Dichloro-1,1,2,2-tetrachloroethane;Avlothane;Distokal;Distopan;Distopin;Egitol;Ethane hexachloride;Falkitol;Fasciolin;Fron 110;Hexachlorethane;Mottenhexe;NSC 9224;Perchloroethane;
PSA 0.00000
LogP 3.72680

Synthetic route

: 10170-69-1
dimanganese decacarbonyl

A: 14100-30-2
pentacarbonylchloromanganese(I)

B: 67-72-1
hexachloroethane

Conditions

Conditions	Yield
With tetrachloromethane In tetrachloromethane byproducts: CCl3; Irradiation (UV/VIS); Irradiation λ >350 nm, CCl4, Ar atm.;; detected by IR spectra and GCA;;	A n/a B 100%

: hexacarbonyl-bis(η5-methylcyclopentadienyl)dimolybdenum

A: MoCl(CO)3(η5-C5H4CH3)

B: 67-72-1
hexachloroethane

Conditions

Conditions	Yield
With tetrachloromethane In tetrachloromethane Irradiation (UV/VIS); Irradiation λ >490 nm, CCl4, Ar atm.;; detected by IR spectra and GCA;;	A n/a B 100%
With tetrachloromethane In tetrachloromethane; acetone Irradiation (UV/VIS); Irradiation λ >490 nm, acetone:CCl4=3:1, Ar atm.;; detected by IR spectra and GCA;;	A >99 B 70%

: perchloro-1,3-butanediol

: 67-72-1
hexachloroethane

Conditions

Conditions	Yield
With 2,2'-azobis(isobutyronitrile); chlorine at 130℃; under 11251.1 Torr; Reagent/catalyst; Temperature; Pressure;	99%

: C21H14N2O2

A: 119-61-9
benzophenone

B: 67-72-1
hexachloroethane

C: 1885-81-0
p-chlorophenyl isocyanide

D: 983-79-9
benzophenone azine

Conditions

Conditions	Yield
With tetrachloromethane Ambient temperature; Irradiation; Yields of byproduct given;	A n/a B n/a C 98% D n/a

...Expand

: Cp(CO)2Re(CH3)2

: 75-62-7
Bromotrichloromethane

A: 74-83-9
methyl bromide

B: tricarbonylcyclopentadienylrhenium

C: C5H5(CO)2Re(CH3)Br

D: C5H5Re(CO)2(CH3)Cl

E: 67-72-1
hexachloroethane

Conditions

Conditions	Yield
With carbon monoxide In further solvent(s) Irradiation (UV/VIS); Irradiation of complex at 350-380 nm under 20 atm of CO in CBrCl3;;	A 81-87 B 97% C 78-85 D <4 E >65

...Expand

: 56-23-5
tetrachloromethane

: 118334-80-8
N-acyloxyphthalimide

A: 136918-14-4
phthalimide

B: 67-72-1
hexachloroethane

C: 1-(tert-butyl)-4-(3-chloropropyl)benzene

D CO2: CO2

Conditions

Conditions	Yield
With 1,4-diaza-bicyclo[2.2.2]octane In water; tert-butyl alcohol for 3h; Product distribution; Quantum yield; Irradiation; ratio, without DABCO;	A 95% B 70% C 74% D n/a

...Expand

: 77743-10-3
(2,5,6-trimethylbenzyl)bis(dimethylglyoximato)pyridinecobalt(III)

: 75-62-7
Bromotrichloromethane

A: bromo Co(III)(dmgH)2py

B: 67-72-1
hexachloroethane

C: 54757-29-8
2-(Bromomethyl)-1,3,4-trimethylbenzene

D: 1,2,4-Trimethyl-3-(2,2,2-trichloro-ethyl)-benzene

Conditions

Conditions	Yield
In chloroform Excess of CHCl3, 50°C for 5 h;; detected by NMR spectra and GLC;;	A n/a B n/a C 5% D 95%

...Expand

: 56-23-5
tetrachloromethane

: 84784-54-3
1,4-diphenyl-2,3-benzo-7,7,8,8-tetramethyl-7,8-digermabicyclo<2,2,2>octadiene

A: 67-72-1
hexachloroethane

B: 796-30-5
1,4-diphenylnaphthalene

C: 22702-77-8
1,2-dichlorotetramethyldigermane

D: 1529-48-2
dichlorodimethylgermanium

Conditions

Conditions	Yield
In benzene Irradiation (UV/VIS); UV irradn. of a soln. of germanium compd. and CCl4 in C6H6 in a degassed sealed Pyrex tube for 3 h at room temp.; not isolated, detected by NMR, analyzed by GC and GC-MS;	A 38% B 95% C 71% D 27%

...Expand

: 115975-16-1
C24H22N2O3

A: 119-61-9
benzophenone

B: 67-72-1
hexachloroethane

C: 84967-87-3
N-(β-Chlor-isopropyl)benzamid

D: 983-79-9
benzophenone azine

Conditions

Conditions	Yield
With tetrachloromethane Ambient temperature; Irradiation; Yields of byproduct given;	A n/a B n/a C 92% D n/a

...Expand

: 93845-09-1
C26H19NO2

A: 119-61-9
benzophenone

B: 67-72-1
hexachloroethane

C: 983-79-9
benzophenone azine

D: 2051-62-9
4'-biphenyl chloride

Conditions

Conditions	Yield
With tetrachloromethane Ambient temperature; Irradiation; Yields of byproduct given;	A n/a B n/a C n/a D 88%

...Expand

: 115975-21-8
C24H17NO2

A: 119-61-9
benzophenone

B: 67-72-1
hexachloroethane

C: 91-58-7
2-chloronaphthalene

D: 983-79-9
benzophenone azine

Conditions

Conditions	Yield
With tetrachloromethane Ambient temperature; Irradiation; Yields of byproduct given;	A n/a B n/a C 87% D n/a

...Expand

: 56-23-5
tetrachloromethane

: 595-90-4
tetraphenyltin(IV)

: 94-36-0
dibenzoyl peroxide

A: 67-72-1
hexachloroethane

B: 7646-78-8
tin(IV) chloride

C: 108-90-7
chlorobenzene

D: 88-99-3
benzene-1,2-dicarboxylic acid

E: 65-85-0
benzoic acid

Conditions

Conditions	Yield
50h boiling;	A n/a B 84.1% C n/a D n/a E n/a

...Expand

: 56-23-5
tetrachloromethane

A: 67-66-3
chloroform

B: 67-72-1
hexachloroethane

Conditions

Conditions	Yield
With photoreduced H2W10O324- In acetonitrile at 60℃; for 24h; Product distribution; Mechanism; other halocarbons, other redox-active polyoxotungstate complexes; other temperature, also with irradiation; other solvents;	A 82% B 2%
With pentaerythritol tetracaproate; dibenzoyl peroxide at 99.9℃; Product distribution; Rate constant; effect of concentration of pentaerythritol tetracaproate; dependence of rate constant from the number of (CH2) fragments in the molecule of esters;

: 115975-11-6
diphenylmethanone O-(4-phenylbutanoyl) oxime

A: 119-61-9
benzophenone

B: 67-72-1
hexachloroethane

C: 104-52-9
phenylpropyl chloride

D: 983-79-9
benzophenone azine

Conditions

Conditions	Yield
With tetrachloromethane Ambient temperature; Irradiation; Yields of byproduct given;	A n/a B n/a C 82% D n/a

...Expand

: 107264-20-0
diphenylmethanone O-(adamantane-1-carbonyl) oxime

A: 119-61-9
benzophenone

B: 67-72-1
hexachloroethane

C: 935-56-8
1-chloroadamantane

D: 983-79-9
benzophenone azine

Conditions

Conditions	Yield
With tetrachloromethane Ambient temperature; Irradiation; Yields of byproduct given;	A n/a B n/a C 82% D n/a

...Expand

: 120569-16-6
C31H45NO2

A: 119-61-9
benzophenone

B: 67-72-1
hexachloroethane

C: 62016-75-5
1-chloroheptadecane

D: 983-79-9
benzophenone azine

Conditions

Conditions	Yield
With tetrachloromethane Ambient temperature; Irradiation; Yields of byproduct given;	A n/a B n/a C 82% D n/a

...Expand

: 30435-62-2
C19H14N2O2

A: 626-60-8
3-Chloropyridine

B: 119-61-9
benzophenone

C: 67-72-1
hexachloroethane

D: 983-79-9
benzophenone azine

Conditions

Conditions	Yield
With tetrachloromethane Ambient temperature; Irradiation; Yields of byproduct given;	A 82% B n/a C n/a D n/a

...Expand

: 120569-19-9
C37H49NO3

A: 119-61-9
benzophenone

B: 67-72-1
hexachloroethane

C: 120577-31-3
(3R,5S,8R,9S,10S,13R,14S,17R)-17-((R)-3-Chloro-1-methyl-propyl)-10,13-dimethyl-hexadecahydro-cyclopenta[a]phenanthren-3-ol

D: 983-79-9
benzophenone azine

Conditions

Conditions	Yield
With tetrachloromethane Ambient temperature; Irradiation; Yields of byproduct given;	A n/a B n/a C 81% D n/a

...Expand

: 14688-34-7
Benzophenon-O-(p-chlorbenzoyl)-oxim

A: 119-61-9
benzophenone

B: 106-46-7
para-dichlorobenzene

C: 67-72-1
hexachloroethane

D: 983-79-9
benzophenone azine

Conditions

Conditions	Yield
With tetrachloromethane Ambient temperature; Irradiation; Yields of byproduct given;	A n/a B 80% C n/a D n/a

...Expand

: 115975-20-7
C24H17NO2

A: 119-61-9
benzophenone

B: 67-72-1
hexachloroethane

C: 983-79-9
benzophenone azine

D: 90-13-1
1-Chloronaphthalene

Conditions

Conditions	Yield
With tetrachloromethane Ambient temperature; Irradiation; Yields of byproduct given;	A n/a B n/a C n/a D 80%

...Expand

: 115993-91-4
C23H16N2O2

A: 611-35-8
4-chloroquinoline

B: 119-61-9
benzophenone

C: 67-72-1
hexachloroethane

D: 983-79-9
benzophenone azine

Conditions

Conditions	Yield
With tetrachloromethane Ambient temperature; Irradiation; Yields of byproduct given;	A 80% B n/a C n/a D n/a

...Expand

: 120569-17-7
C35H53NO2

A: 119-61-9
benzophenone

B: 67-72-1
hexachloroethane

C: 66326-16-7
1-chloroheneicosane

D: 983-79-9
benzophenone azine

Conditions

Conditions	Yield
With tetrachloromethane Ambient temperature; Irradiation; Yields of byproduct given;	A n/a B n/a C 80% D n/a

...Expand

: 93845-11-5
C19H14N2O2

A: 109-09-1
2-chloropyridine

B: 119-61-9
benzophenone

C: 67-72-1
hexachloroethane

D: 983-79-9
benzophenone azine

Conditions

Conditions	Yield
With tetrachloromethane Ambient temperature; Irradiation; Yields of byproduct given;	A 80% B n/a C n/a D n/a

...Expand

: 6430-25-7
acetyl-triphenylgermane

A: 67-72-1
hexachloroethane

B: 918-00-3
1,1,1-trichloroacetone

C: 1626-24-0
chlorotriphenylgermane

D: 75-36-5
acetyl chloride

Conditions

Conditions	Yield
With tetrachloromethane In tetrachloromethane Irradiation (UV/VIS); Ph3GeCOMe photolyzed in CCl4;	A 53% B 10% C 78% D 74%

...Expand

: 120569-14-4
C23H16N2O2

A: 1532-91-8
4-chloroisoquinoline

B: 119-61-9
benzophenone

C: 67-72-1
hexachloroethane

D: 983-79-9
benzophenone azine

Conditions

Conditions	Yield
With tetrachloromethane Ambient temperature; Irradiation; Yields of byproduct given;	A 77% B n/a C n/a D n/a

...Expand

: 93845-12-6
C19H14N2O2

A: 626-61-9
4-Chloropyridine

B: 119-61-9
benzophenone

C: 67-72-1
hexachloroethane

D: 983-79-9
benzophenone azine

Conditions

Conditions	Yield
With tetrachloromethane Ambient temperature; Irradiation; Yields of byproduct given;	A 77% B n/a C n/a D n/a

...Expand

: 115975-18-3
C23H16N2O2

A: 612-62-4
2-Chloroquinoline

B: 119-61-9
benzophenone

C: 67-72-1
hexachloroethane

D: 983-79-9
benzophenone azine

Conditions

Conditions	Yield
With tetrachloromethane Ambient temperature; Irradiation; Yields of byproduct given;	A 76% B n/a C n/a D n/a

...Expand

: 107264-22-2
C26H24N2O3

A: 119-61-9
benzophenone

B: 67-72-1
hexachloroethane

C: 90670-04-5
(4-chloropiperidin-1-yl)(phenyl)methanone

D: 983-79-9
benzophenone azine

Conditions

Conditions	Yield
With tetrachloromethane Ambient temperature; Irradiation; Yields of byproduct given;	A n/a B n/a C 76% D n/a

...Expand

: 120569-15-5
C22H15N3O2

A: 1448-87-9
2-chloroquinoxaline

B: 119-61-9
benzophenone

C: 67-72-1
hexachloroethane

D: 983-79-9
benzophenone azine

Conditions

Conditions	Yield
With tetrachloromethane Ambient temperature; Irradiation; Yields of byproduct given;	A 74% B n/a C n/a D n/a

...Expand

: 107264-24-4
C27H25NO3

A: 119-61-9
benzophenone

B: 67-72-1
hexachloroethane

C: 107774-09-4
(2-chloro-cyclohexyl)-phenyl ketone

D: 983-79-9
benzophenone azine

Conditions

Conditions	Yield
With tetrachloromethane Ambient temperature; Irradiation; Yields of byproduct given;	A n/a B n/a C 74% D n/a

...Expand

: 676491-10-4
4-(1-Phenyl-1-hydrazinocarbonyl-methylene)piperidine-1-carboxylic acid tert-butyl ester

: 67-72-1
hexachloroethane

: 1538-75-6
2,2-dimethylpropanoic anhydride

: 4-[1-Phenyl-1-(5-tert-butyl-1,3,4-oxadiazol-2-yl)-methylene]-piperidine-1-carboxylic acid tert-butyl ester

Conditions

Conditions	Yield
With IPr2NEt; triphenylphosphine In acetonitrile	100%

...Expand

: 67-72-1
hexachloroethane

: C5(CH3)5Ru(C5H4CH2C4H7NCH2OCH3)

: (Sp)-Cp*Ru[1-Cl-2-(CH2NC4H7CH2OCH3)C5H3]

Conditions

Conditions	Yield
With LisBu In diethyl ether; cyclohexane (inert atm.); Ru complex in Et2O cooled to -78°C, treated with LisBu in cyclohexane (1:1.70) at -78°C within 20-30 s, stirred at -78°C for 3.5 h, treated with suspn. of ligand in Et2O, warmed to room temp. within 2.5 h, stirred for; evapd.(vac.), extd.(pentane), filtered (kieselghur), freed of volatiles,elem. anal.;	100%

: 67-72-1
hexachloroethane

: 124-38-9
carbon dioxide

Conditions

Conditions	Yield
With Oxone; II(H2O)2(Me2SO)4>(BF4)2; Hexadecyltrimethylammonium hydrogen sulfate In water at 20℃; Product distribution; other chloro- and bromoolefins;	99%

: 109-99-9
tetrahydrofuran

: 7440-19-9
samarium

: 67-72-1
hexachloroethane

: SmCl3(tetrahydrofuran)2

Conditions

Conditions	Yield
In tetrahydrofuran byproducts: C2Cl4; Sonication; inert atmosphere; mass ratio metal : C2Cl6 = 1 : 3, 30 h; pptn. on pentane addn., decantation, washing (pentane), drying (room temp., dry box); elem. anal.;	99%

...Expand

: 67-72-1
hexachloroethane

: 214750-14-8
Co(C5H4B(N(CH3)2)2)2

: 214750-16-0
Co(C5H4B(N(CH3)2)2)2(1+)*Cl(1-)=[Co(C5H4B(N(CH3)2)2)2]Cl

Conditions

Conditions	Yield
In toluene N2-atmosphere; stirring (4 h); filtering, drying (vac.), crystn. (CH2Cl2 / hexane = 1 : 1); elem. anal.;	99%

: 67-72-1
hexachloroethane

: 219944-90-8
5-(trimethylsilyl)-methyl-2,2′-bipyridine

: 219944-93-1
5-chloromethyl-2,2'-bipyridine

Conditions

Conditions	Yield
With cesium fluoride In acetonitrile at 60℃; for 4h;	98%

: W(O)(neopentylidene)(PEt3)2Cl2

: 67-72-1
hexachloroethane

: 594-09-2
trimethylphosphane

: 78251-18-0
W(CC(CH3)3)Cl3(P(CH3)3)3

Conditions

Conditions	Yield
In tetrahydrofuran; diethyl ether byproducts: PEt3HCl, Et3PO; under N2 for 12 h, filtration, adding of PMe3; react. time 10 min; filtration; elem. anal.;	98%

...Expand

: W(O)(neopentylidene)(PEt3)2Cl2

: 67-72-1
hexachloroethane

: 78251-21-5
W(6+)*CC(CH3)3(3-)*3Cl(1-)*OP(C2H5)3 = [W(CC(CH3)3)Cl3(PO(C2H5)3)]

Conditions

Conditions	Yield
In tetrahydrofuran byproducts: PEt3HCl; under N2 for 10 h; filtration, pptn. of PEt3HCl with pentane, filtration, evapn.;	98%

: 67-72-1
hexachloroethane

: 214750-15-9
Co(C5H4B(N(C2H5)2)2)2

: 214750-17-1
Co(C5H4B(N(C2H5)2)2)2(1+)*Cl(1-)=[Co(C5H4B(N(C2H5)2)2)2]Cl

Conditions

Conditions	Yield
In toluene N2-atmosphere; stirring (4 h); filtering, drying (vac.), crystn. (CH2Cl2 / hexane = 1 : 1); elem. anal.;	98%

: 110-00-9
furan

: 67-72-1
hexachloroethane

: 3187-94-8
2-chlorofuran

Conditions

Conditions	Yield
With n-butyllithium; sodium hydrogencarbonate In diethyl ether; water	97.6%

: 67-72-1
hexachloroethane

: 76-13-1
1,1,2-Trichloro-1,2,2-trifluoroethane

Conditions

Conditions	Yield
With aluminum(III) fluoride; hydrogen fluoride at 120℃; under 11251.1 Torr; for 10h; Reagent/catalyst; Temperature; Autoclave;	97.06%
With CFC-112a; antimonypentachloride; fluorine at 32℃; unter vermindertem Druck;
With antimonypentachloride; antimony(III) fluoride at 48℃;

: 67-72-1
hexachloroethane

: 127-18-4
1,1,2,2-tetrachloroethylene

Conditions

Conditions	Yield
In tetrachloromethane at 300℃; for 0.000555556h; Temperature; Flow reactor; Pyrolysis;	97%
at 600℃;
With pyrographite at 700℃;

: 109-99-9
tetrahydrofuran

: holmium

: 67-72-1
hexachloroethane

: HoCl3(tetrahydrofuran)2.5

Conditions

Conditions	Yield
In tetrahydrofuran byproducts: C2Cl4; Sonication; inert atmosphere; mass ratio metal : C2Cl6 = 1 : 3, 6 h; solvent evapn. (vac.), pentane addn., filtration, washing (pentane), drying (vac., 70 - 80°C, 10 - 15 min); elem. anal.;	97%

...Expand

: 109-99-9
tetrahydrofuran

: 67-72-1
hexachloroethane

: ytterbium

: 14782-79-7, 152006-21-8
YbCl3(tetrahydrofuran)3

Conditions

Conditions	Yield
In tetrahydrofuran byproducts: C2Cl4; Sonication; inert atmosphere; mass ratio metal : C2Cl6 = 1 : 3, 45 h; pptn. on pentane addn., decantation, washing (pentane), drying (room temp., dry box); elem. anal.;	96%

...Expand

: 109-99-9
tetrahydrofuran

: terbium

: 67-72-1
hexachloroethane

: TbCl3(tetrahydrofuran)2.5

Conditions

Conditions	Yield
In tetrahydrofuran byproducts: C2Cl4; Sonication; inert atmosphere; mass ratio metal : C2Cl6 = 1 : 3, 12 h; solvent evapn. (vac.), pentane addn., filtration, washing (pentane), drying (vac., 70 - 80°C, 10 - 15 min); elem. anal.;	96%

...Expand

: 67-72-1
hexachloroethane

: 1261240-33-8
Rh((P(C6H5)2CH2)4N2)(1+)*BF4(1-)=[Rh((P(C6H5)2CH2)4N2)]BF4

: 1261240-39-4
RhCl2((P(C6H5)2CH2)4N2)(1+)*BF4(1-)=[RhCl2((P(C6H5)2CH2)4N2)]BF4

Conditions

Conditions	Yield
In dichloromethane under N2 or Ar; C2Cl6 added to soln. of rhodium complex in CH2Cl2, mixt. stirred at room temp. for 3 h; evapn. under vac., residue washed with hexanes; elem. anal.;	96%

: 67-72-1
hexachloroethane

: 3348-44-5
bis(N,N-dimethylamino)chlorophosphine

A: 683-85-2
N,N-dimethylaminodichlorophosphane

B: 5574-93-6
chlorotris(dimethylamino)phosphonium chloride

Conditions

Conditions	Yield
In diethyl ether for 480h;	A 90% B 95%

...Expand

: 67-72-1
hexachloroethane

: 219944-91-9
6’-[(trimethylsilyl)methyl]-2’,2-bipyridine

: 82740-65-6
6-(chloromethyl)-2,2’-bipyridine

Conditions

Conditions	Yield
With cesium fluoride In acetonitrile at 60℃; for 4h;	95%

: 67-72-1
hexachloroethane

: 302320-86-1
η6-(4-triisopropylsiloxymethyl-1-methoxymethoxybenzene)tricarbonylchromium(0)

: 410083-62-4, 409359-96-2, 410083-63-5
(+)-(S)-η6-(2-chloro-4-triisopropylsiloxymethyl-1-methoxymethoxybenzene)tricarbonylchromium(0)

Conditions

Conditions	Yield
With (-)-sparteine; n-butyllithium In diethyl ether N2; soln. of Cr-contg. compd. (4.3 mmol) in ether at -78°C was added to soln. of (-)-sparteine (3 equiv.) and n-BuLi (1.1 equiv.) in ether at the same temp.; stirring for 1 h and quenching with C2Cl6 (8.6 mmol); warming to -10°C overnight; treatment with water; the org. layer was washed twice with water and once with brine, dried (MgSO4) and concd. under reduced pressure; flash column chromy. (Sorbisil C-60; eluant: 10% ether-hexane);	95%

Yield

With (-)-sparteine; n-butyllithium In diethyl ether N2; soln. of Cr-contg. compd. (4.3 mmol) in ether at -78°C was added to soln. of (-)-sparteine (3 equiv.) and n-BuLi (1.1 equiv.) in ether at the same temp.; stirring for 1 h and quenching with C2Cl6 (8.6 mmol); warming to -10°C overnight; treatment with water; the org. layer was washed twice with water and once with brine, dried (MgSO4) and concd. under reduced pressure; flash column chromy. (Sorbisil C-60; eluant: 10% ether-hexane);

95%

: 67-72-1
hexachloroethane

: C29H36ClIrP2S2

: C29H36Cl3IrP2S2

Conditions

Conditions	Yield
In dichloromethane at 50℃; for 1h; Solvent;	95%

: 67-72-1
hexachloroethane

: 219944-89-5
4-(trimethylsilyl)-methyl-2,2'-bipyridine

: 219944-92-0
4-chloromethyl-2,2'-bipyridine

Conditions

Conditions	Yield
With cesium fluoride In acetonitrile at 60℃; for 4h;	94%

: 154671-38-2
bis[N,N-bistrimethylsilylamido]bis(tetrahydrofuran)ytterbium(II)

: 67-72-1
hexachloroethane

: Yb[bis(trimethylsilyl)amide]2Cl(tetrahydrofuran)2

Conditions

Conditions	Yield
In tetrahydrofuran at 20℃; for 18h; Inert atmosphere; Glovebox;	93%

Hexachloroethane Chemical Properties

Molecular structure of Hexachloroethane (CAS NO.67-72-1) is:

Product Name: Hexachloroethane
CAS Registry Number: 67-72-1
IUPAC Name: 1,1,1,2,2,2-hexachloroethane
Molecular Weight: 236.7394 [g/mol]
Molecular Formula: C₂Cl₆
XLogP3: 4.1
EINECS: 200-666-4
Melting Point: 184 °C
Storage temp.: 2-8 °C
Water Solubility: 0.05 g/L (22 °C)
Surface Tension: 42.8 dyne/cm
Density: 1.821 g/cm³
Flash Point: 61.3 °C
Enthalpy of Vaporization: 40.57 kJ/mol
Boiling Point: 186.8 °C at 760 mmHg
Vapour Pressure: 0.895 mmHg at 25°C
Stability: Stable. Non-combustible. May react with hot metals, strong oxidizing agents.
Product Categories: refrigerants;Organics;Alpha Sort;E-LAlphabetic;H;HA -HT;Volatiles/ Semivolatiles

Hexachloroethane Uses

Hexachloroethane (CAS NO.67-72-1) is comonly used as raw materials for organic synthesis,and it also can be used as degassing agents of aluminum and its alloy.Also, it can be used in most aluminium foundries around the world to remove hydrogen.

Hexachloroethane Toxicity Data With Reference

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
dog	LDLo	intravenous	325mg/kg (325mg/kg)		Quarterly Journal of Pharmacy & Pharmacology. Vol. 7, Pg. 205, 1934.
guinea pig	LD50	oral	4970mg/kg (4970mg/kg)		American Industrial Hygiene Association Journal. Vol. 40, Pg. 187, 1979.
mouse	LD50	intraperitoneal	4500mg/kg (4500mg/kg)		Arzneimittel-Forschung. Drug Research. Vol. 11, Pg. 902, 1961.
rabbit	LD	oral	> 1gm/kg (1000mg/kg)		American Industrial Hygiene Association Journal. Vol. 40, Pg. 187, 1979.
rabbit	LD50	skin	32gm/kg (32000mg/kg)		American Industrial Hygiene Association Journal. Vol. 40, Pg. 187, 1979.
rabbit	LDLo	subcutaneous	4gm/kg (4000mg/kg)		Quarterly Journal of Pharmacy & Pharmacology. Vol. 7, Pg. 205, 1934.
rat	LCLo	inhalation	5900ppm/8H (5900ppm)	BEHAVIORAL: MUSCLE WEAKNESS	American Industrial Hygiene Association Journal. Vol. 40, Pg. 187, 1979.
rat	LD50	oral	4460mg/kg (4460mg/kg)		American Industrial Hygiene Association Journal. Vol. 40, Pg. 187, 1979.
rat	LDLo	intraperitoneal	2900mg/kg (2900mg/kg)		American Industrial Hygiene Association Journal. Vol. 40, Pg. 187, 1979.

Hexachloroethane Safety Profile

Confirmed carcinogen with experimental carcinogenic data. A poison by intravenous route. Moderately toxic by intraperitoneal route. Mildly toxic by ingestion. Experimental reproductive effects. Mutation data reported. Liver injury has resulted from exposure to this material. An insecticide. Slightly explosive by spontaneous chemical reaction. Dehalogenation of this material by reaction with alkalies, metals, etc., will produce spontaneously explosive chloroacetylenes. When heated to decomposition it emits highly toxic fumes of Cl⁻ and phosgene.
Hazard Codes: Harmful Xn, Dangerous N, Toxic T, Flammable F
Risk Statements: 40-51/53-36/37/38-39/23/24/25-36/38-23/24/25-11
R40:Limited evidence of a carcinogenic effect.
R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R36/37/38:Irritating to eyes, respiratory system and skin.
R39/23/24/25:Danger of very serious irreversible effects and Toxic by inhalation, in contact with skin and if swallowed.
R36/38:Irritating to eyes and skin.
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed.
R12:Extremely flammable.
Safety Statements: 36/37-61-45-36/37/39-26-24-16-7
S36/37:Wear suitable protective clothing and gloves.
S61:Avoid release to the environment. Refer to special instructions / safety data sheets.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S24:Avoid contact with skin.
S16:Keep away from sources of ignition.
S7:Keep container tightly closed.
RIDADR: UN 9037
WGK Germany: 3
RTECS: KI4025000
HazardClass: 9
PackingGroup: III

Hexachloroethane Specification

Hexachloroethane , its cas register number is 67-72-1. It also can be called 1,1,1,2,2,2-Hexachloroethane ; Avlothane ; Distokal ; Egitol ; Ethane hexachloride ; Ethane, hexachloro- ; Ethylene hexachloride ; Falkitol ; Hexachlor-aethan ; Mottenhexe ; Perchloroethane ; Phenohep ; Ethane, 1,1,1,2,2,2-hexachloro- .It is a colorless, crystalline solid with a camphor-like odor.It may cause illness from inhalation or ingestion and may irritate skin, eyes and mucous membranes. When heated to high temperatures it may emit toxic fumes. The primary hazard is the threat to the environment. Immediate steps should be taken to limit its spread to the environment. It insoluble in water.It can react with hot iron, zinc and aluminum.

Product Name

Perchloroethane

Synthetic route

Hexachloroethane Chemical Properties

Hexachloroethane Uses

Hexachloroethane Toxicity Data With Reference

Hexachloroethane Safety Profile

Hexachloroethane Specification

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