L-Lyxose supplier | CasNO.1949-78-6

Name
L-Lyxose
EINECS 255-277-2
CAS No. 1949-78-6
Article Data24
CAS DataBase
Density 1.757 g/cm³
Solubility Very soluble (586 g/L) (25°C) in water.
Melting Point 108-112 °C(lit.)
Formula C₅H₁₀O₅
Boiling Point 333.2 °C at 760 mmHg
Molecular Weight 150.131
Flash Point 155.3 °C
Transport Information
Appearance white fine crystalline powder
Safety 24/25-36/37/39-26
Risk Codes 36/37/38
Molecular Structure
Hazard Symbols Xi
Synonyms D-aldotriose;aldehydo-L-Lyxose;rechtsdrehende Lyxose;D-glyceraldehyde;D-glycerose;L-lyxo-2,3,4,5-Tetrahydroxy-valeraldehyd;L-(+)-Lyxose;L-LYXOSE;Triose;
PSA 90.15000
LogP -2.58230

Synthetic route

: 4099-88-1, 67814-68-0, 70266-87-4, 76249-50-8, 76249-51-9, 93451-15-1
2,3-O-isopropylidene-L-lyxofuranose

: 1949-78-6
L-lyxose

Conditions

Conditions	Yield
With water at 20℃;	95%

: 5328-37-0
L-arabinose

A: 609-06-3
L-xylose

B: 1949-78-6
L-lyxose

C: 24259-59-4
L-ribose

Conditions

Conditions	Yield
With molybdenum(VI) oxide In water at 90℃; for 9h; Bilik reaction;	A n/a B n/a C 19%

...Expand

calcium salt of/the/ L-galactonic acid: calcium salt of/the/ L-galactonic acid

: 1949-78-6
L-lyxose

Conditions

Conditions	Yield
With dihydrogen peroxide; iron(III) acetate

: 133-42-6, 488-33-5, 526-95-4, 526-97-6, 576-36-3, 642-99-9, 1114-17-6, 3956-93-2, 6906-37-2, 7760-07-8, 13382-27-9, 20246-33-7, 20246-35-9, 20246-52-0, 20246-53-1, 21675-42-3, 22430-69-9, 24871-35-0, 28223-42-9, 51547-37-6, 28278-17-3
L-galactonic acid

: 7722-84-1
dihydrogen peroxide

ferriacetate: ferriacetate

: 1949-78-6
L-lyxose

Conditions

Conditions	Yield
das Calciumsalz reagiert;

...Expand

l-galactonate calcium: l-galactonate calcium

: 1949-78-6
L-lyxose

Conditions

Conditions	Yield
With ferriacetate; dihydrogen peroxide

: 78008-36-3, 92822-62-3, 99744-77-1
(S)-cyclohexylidene glyceraldehyde

polymer bonded 2-phenyl-1,3,2-dioxaborole: polymer bonded 2-phenyl-1,3,2-dioxaborole

A: 609-06-3
L-xylose

B: 1949-78-6
L-lyxose

C: 24259-59-4
L-ribose

D: 5328-37-0
L-arabinose

Conditions

Conditions	Yield
In dichloromethane Ambient temperature; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
In dichloromethane Ambient temperature; Yield given. Yields of byproduct given;

...Expand

: 78008-36-3, 92822-62-3, 99744-77-1
(S)-cyclohexylidene glyceraldehyde

polymer bound 1,3,2-dioxaborole: polymer bound 1,3,2-dioxaborole

A: 609-06-3
L-xylose

B: 1949-78-6
L-lyxose

C: 24259-59-4
L-ribose

D: 5328-37-0
L-arabinose

Conditions

Conditions	Yield
Yield given. Multistep reaction. Yields of byproduct given;

...Expand

: 888487-02-3
(4R,5S)-4-((R)-1-hydroxy-2,2-dimethoxyethyl)-2,2-dimethyl-1,3-dioxan-5-ol

: 1949-78-6
L-lyxose

Conditions

Conditions	Yield
With Dowex 50W2-100 In water at 20℃; for 6.5h;

: 850252-47-0
(4S,1'R)-4-(1'-hydroxy-2',2'-dimethoxyethyl)-2,2-dimethyl-1,3-dioxan-5-one

: 1949-78-6
L-lyxose

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: NaBH(OAc)3; AcOH / CH2Cl2 / 5 h / -20 °C 2: Dowex 50W2-100 / H2O / 6.5 h / 20 °C View Scheme

: (4R)-4-((R)-1-(tert-butyldimethylsilyloxy)-2,2-dimethoxyethyl)-2,2-dimethyl-1,3-dioxan-5-ol

: 1949-78-6
L-lyxose

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: TBAF / tetrahydrofuran 2: Dowex 50W2-100 / H2O / 6.5 h / 20 °C View Scheme

: 488-82-4
D-Arabitol

A: 488-84-6
D-ribulose

B: 527-50-4
L-xylulose

C: 10323-20-3
D-Arabinose

D: 1949-78-6
L-lyxose

Conditions

Conditions	Yield
With sulfuric acid; platinum on activated charcoal Electrochemical reaction; Inert atmosphere;

...Expand

: 488-82-4
D-Arabitol

A: 64-18-6
formic acid

B: 10323-20-3
D-Arabinose

C: 1949-78-6
L-lyxose

Conditions

Conditions	Yield
With sulfuric acid; platinum on activated charcoal Electrochemical reaction; Inert atmosphere;

...Expand

: 1949-78-6
L-lyxose

: 75-08-1
ethanethiol

: 22249-18-9
L-Lyxose diethyl dithioacetal

Conditions

Conditions	Yield
With hydrogenchloride In water at 0℃; for 2h; Inert atmosphere;	95%

: 1949-78-6
L-lyxose

: 98-01-1
furfural

Conditions

Conditions	Yield
With 1-methyl-3-(4-sulfobutyl)-1H-imidazol-3-ium hydrogensulfate; 4-methyl-2-pentanone In water at 150℃; under 760.051 Torr; for 0.416667h; Autoclave;	91.4%

: 1949-78-6
L-lyxose

: L-xylulose 1-phosphate

Conditions

Conditions	Yield
With ATP multistep reaction, enzymatic conversion of aldoses to ketose 1-phosphates (KM and Vmax for most of the steps given);	78%
With ATP 1) L-rhamnose isomerase, tris buffer pH 8.0, mercaptoethanol, MgCl2, ATP (cat.), 2) L-rhamnulose kinase, PEP/pyruvate kinase; Yield given. Multistep reaction;

: 1949-78-6
L-lyxose

: 108-24-7
acetic anhydride

: 106-95-6
allyl bromide

A: 4,5,6,7,8-penta-O-acetyl-1,2,3-trideoxy-L-galacto-oct-1-enitol

B: C18H26O10

Conditions

Conditions	Yield
Stage #1: L-lyxose; allyl bromide With indium In ethanol at 20℃; for 3h; sonication; Stage #2: acetic anhydride With pyridine; dmap at 20℃; for 18h; Further stages.;	A 75% B n/a

...Expand

: 67-56-1
methanol

: 1949-78-6
L-lyxose

: 36793-06-3
Methyl α-L-lyxopyranoside

Conditions

Conditions	Yield
Stage #1: methanol With acetyl chloride at 0℃; for 0.5h; Stage #2: L-lyxose at 0 - 20℃; for 12h; Stage #3: With pyridine at 20℃; for 3h;	68%

: 1949-78-6
L-lyxose

: 75-09-2
dichloromethane

: 101752-05-0
methanol hydrochloride

: 75-36-5
acetyl chloride

: 36793-06-3
Methyl α-L-lyxopyranoside

Conditions

Conditions	Yield
In methanol; ethyl acetate	67%

...Expand

: 53008-62-1, 53008-61-0
2,3,4,6-tetra-O-benzyl-α-D-galactopyranosyl iodide

: 1949-78-6
L-lyxose

: 7087-68-5
N-ethyl-N,N-diisopropylamine

: 2,3-O-isopropylidene-5-O-(2,3,4,6-tetra-O-benzyl-α-D-galactopyranosyl)-D-lyxofuranose

Conditions

Conditions	Yield
Stage #1: L-lyxose With sulfuric acid In acetone at 20℃; for 4h; Inert atmosphere; Stage #2: 2,3,4,6-tetra-O-benzyl-α-D-galactopyranosyl iodide; N-ethyl-N,N-diisopropylamine With tetra-(n-butyl)ammonium iodide In acetone; toluene at 65℃; for 1.16667h; Inert atmosphere; Molecular sieve; regioselective reaction;	63%

...Expand

: 1949-78-6
L-lyxose

: 1114-34-7
D-lyxose

: 50-69-1, 58-86-6, 65-42-9, 147-81-9, 609-06-3, 1114-34-7, 1949-78-6, 5328-37-0, 10323-20-3, 20235-19-2, 24259-59-4, 25990-60-7, 34466-20-1, 41247-05-6, 53106-52-8, 55058-43-0, 80952-57-4
rac-lyxose

Conditions

Conditions	Yield
With water

: 1949-78-6
L-lyxose

: 873389-62-9
(2-amino-4,5-dimethyl-phenyl)-carbamic acid ethyl ester

: 1-(6-ethoxycarbonylamino-3.4-dimethyl-anilino)-1-deoxy-L-lyxitol

Conditions

Conditions	Yield
With methanol anschliessendes Hydrieren an Nickel oder Palladium;

: 1949-78-6
L-lyxose

: 4172-43-4
L-lyxonic acid

Conditions

Conditions	Yield
With methanol; potassium hydroxide; iodine

: 1949-78-6
L-lyxose

: 95-64-7
4-amino-o-xylene

: 906331-23-5
5-(3,4-dimethyl-anilino)-5-deoxy-L-arabitol

Conditions

Conditions	Yield
With methanol; Raney. nickel at 100℃; under 73550.8 Torr; Hydrogenation;
With hydrogenchloride; Raney. nickel at 80℃; under 44130.5 Torr; Hydrogenation;

: 1949-78-6
L-lyxose

: 589-21-9
(4-bromophenyl)hydrazine

: 10018-08-3, 18841-81-1, 20603-24-1, 20664-64-6, 72748-84-6, 78039-46-0, 100016-91-9
lyxose-(4-bromo-phenylhydrazone)

Conditions

Conditions	Yield
With ethanol -<4-bromo-phenylhydrazone>;

: 1949-78-6
L-lyxose

: 2627-86-3
L-(-)-α-methylbenzylamine

: 108-24-7
acetic anhydride

: 79526-48-0, 79549-54-5, 79549-55-6, 79549-57-8, 79549-58-9, 79549-59-0, 79549-60-3, 79549-61-4, 83680-88-0
Acetic acid (1S,2S,3S)-2,3,4-triacetoxy-1-{[acetyl-(1-phenyl-ethyl)-amino]-methyl}-butyl ester

Conditions

Conditions	Yield
With pyridine; sodium cyanoborohydride 1.) methanol-water 2.) 100 deg C, 1 h; Multistep reaction;

...Expand

: 1949-78-6
L-lyxose

: 2627-86-3
(-)-α-methylbenzylamine

: 108-24-7
acetic anhydride

: 79526-48-0, 79549-54-5, 79549-55-6, 79549-57-8, 79549-58-9, 79549-59-0, 79549-60-3, 79549-61-4, 83680-88-0
Acetic acid (1S,2S,3S)-2,3,4-triacetoxy-1-{[acetyl-((S)-1-phenyl-ethyl)-amino]-methyl}-butyl ester

Conditions

Conditions	Yield
With pyridine; sodium cyanoborohydride 1.)Methanol, water, room temp. 2.)100 deg C, 1 hour; Multistep reaction;

...Expand

: 1949-78-6
L-lyxose

: 104196-15-8
lyxonic acid-1,4-lactone

Conditions

Conditions	Yield
With hypoiodous acid

: 67-56-1
methanol

: 1949-78-6
L-lyxose

: 98-88-4
benzoyl chloride

: 169529-25-3
1-O-methyl-2,3,5-tri-O-benzoyl-L-lyxofuranose

Conditions

Conditions	Yield
With pyridine; sulfuric acid

...Expand

: 1949-78-6
L-lyxose

: 7643-75-6
L-(-)-arabitol

Conditions

Conditions	Yield
With monospecific xylose reductase from yeast Candida intermedia; NADPH In phosphate buffer at 25℃; pH=7.0; Enzyme kinetics; Further Variations:; Reagents;

: 1949-78-6
L-lyxose

: 107-18-6
allyl alcohol

: allyl α/β-L-lyxofuranoside

Conditions

Conditions	Yield
With sulfuric acid; sodium sulfate at 25℃;

: 1949-78-6
L-lyxose

: 2687-43-6
O-benzylhydoxylamine hydrochloride

: (2S,3S,4S,E)-2,3,4,5-tetrahydroxypentanal O-benzyl oxime

Conditions

Conditions	Yield
With pyridine In ethanol for 24h;

L-Lyxose Specification

The L-Lyxose, with the CAS registry number 1949-78-6, is also known as beta-L-lyxopyranose. It belongs to the product categories of Carbohydrate; 13C & 2H Sugars; Basic Sugars (Mono & Oligosaccharides); Biochemistry; Lyxose; Sugars; Aldehydes; Carbohydrates & Derivatives. Its EINECS registry number is 217-763-2. This chemical's molecular formula is C₅H₁₀O₅ and molecular weight is 150.1299. Its IUPAC name is called (2S,3R,4R,5S)-oxane-2,3,4,5-tetrol. This chemical is an aldopentose — a monosaccharide containing five carbon atoms, and including an aldehyde functional group. This chemical is white fine crystalline powder.

Physical properties of L-Lyxose: (1)ACD/LogP: -0.83; (2)ACD/LogD (pH 5.5): -0.83; (3)ACD/LogD (pH 7.4): -0.83; (4)ACD/BCF (pH 5.5): 1; (5)ACD/BCF (pH 7.4): 1; (6)ACD/KOC (pH 5.5): 8.46; (7)ACD/KOC (pH 7.4): 8.46; (8)#H bond acceptors: 5; (9)#H bond donors: 4; (10)#Freely Rotating Bonds: 4; (11)Index of Refraction: 1.646; (12)Molar Refractivity: 31.02 cm³; (13)Molar Volume: 85.4 cm³; (14)Surface Tension: 75.3 dyne/cm; (15)Density: 1.757 g/cm³; (16)Flash Point: 155.3 °C; (17)Enthalpy of Vaporization: 66.74 kJ/mol; (18)Boiling Point: 333.2 °C at 760 mmHg; (19)Vapour Pressure: 9.92E-06 mmHg at 25°C.

When you are using this chemical, please be cautious about it as the following:
This chemical may cause inflammation to the skin or other mucous membranes. It is irritating to eyes, respiratory system and skin. You must avoid contacting it with skin and eyes. In case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice. Whenever you will contact it, please wear suitable protective clothing, gloves and eye/face protection.

You can still convert the following datas into molecular structure:
(1)Canonical SMILES: C1C(C(C(C(O1)O)O)O)O
(2)Isomeric SMILES: C1[C@@H]([C@H]([C@H]([C@H](O1)O)O)O)O
(3)InChI: InChI=1S/C5H10O5/c6-2-1-10-5(9)4(8)3(2)7/h2-9H,1H2/t2-,3+,4+,5-/m0/s1
(4)InChIKey: SRBFZHDQGSBBOR-RSJOWCBRSA-N

Product Name

L-Lyxose

Synthetic route

L-Lyxose Specification

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