Product Name

  • Name

    Tetrafluoroethylene

  • EINECS 204-126-9
  • CAS No. 116-14-3
  • Article Data301
  • CAS DataBase
  • Density 1.306 g/cm3
  • Solubility 110mg/L at 28℃
  • Melting Point -142 °C
  • Formula C2F4
  • Boiling Point -76.301 °C at 760 mmHg
  • Molecular Weight 100.016
  • Flash Point -119.677 °C
  • Transport Information
  • Appearance colourless gas
  • Safety 16-36/37/39-45
  • Risk Codes 11
  • Molecular Structure Molecular Structure of 116-14-3 (Tetrafluoroethylene)
  • Hazard Symbols CorrosiveC,FlammableF
  • Synonyms Ethene,tetrafluoro- (9CI);Ethylene, tetrafluoro- (6CI,8CI);1,1,2,2-Tetrafluoroethylene;Ethylene tetrafluoride;Lubron 5;PFC 1114;Perfluoroethene;Perfluoroethylene;R 1114;TFE;Teflon 851K02730;Tetrafluoroethene;Tetrafluoroethylene;
  • PSA 0.00000
  • LogP 1.99100

Synthetic route

propene
187737-37-7

propene

1,1,2,2,3,3-Hexafluoro-cyclopropane
931-91-9

1,1,2,2,3,3-Hexafluoro-cyclopropane

A

polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

B

1,1-difluoro-2-methylcyclopropane
373-94-4

1,1-difluoro-2-methylcyclopropane

C

Octafluorocyclobutane
115-25-3

Octafluorocyclobutane

D

1,1,2,2-tetrafluoro-3-methylcyclobutane
374-30-1

1,1,2,2-tetrafluoro-3-methylcyclobutane

Conditions
ConditionsYield
at 296℃; for 1h; sealed tube in vacuo;A 16%
B 100%
C 9%
D 21%
at 296℃; sealed tube in vacuo;A 16%
B 100%
C 9%
D 21%
1,2,2,3,3-pentafluoro-1-difluoromethylcyclopropane
379-14-6

1,2,2,3,3-pentafluoro-1-difluoromethylcyclopropane

A

polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

B

pentafloropropylene
433-66-9

pentafloropropylene

C

1,1,2,2,3,3-Hexafluoro-cyclopropane
931-91-9

1,1,2,2,3,3-Hexafluoro-cyclopropane

D

Octafluorocyclobutane
115-25-3

Octafluorocyclobutane

Conditions
ConditionsYield
at 300℃; for 160h; Further byproducts given;A 28%
B 100%
C 6%
D 12%
Hexafluoroethane
76-16-4

Hexafluoroethane

polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

Conditions
ConditionsYield
With hydrogen at 336.84 - 736.84℃; Product distribution / selectivity; Gas phase; Inert atmosphere;100%
1,2,2,3,3-pentafluoro-1-difluoromethylcyclopropane
379-14-6

1,2,2,3,3-pentafluoro-1-difluoromethylcyclopropane

cyclohexene
110-83-8

cyclohexene

A

polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

B

pentafloropropylene
433-66-9

pentafloropropylene

C

Octafluorocyclobutane
115-25-3

Octafluorocyclobutane

D

7,7-difluoronorcarane
823-70-1

7,7-difluoronorcarane

Conditions
ConditionsYield
at 200℃; for 320h; Further byproducts given;A 14%
B 99%
C n/a
D 47%
1,2,2,3,3-pentafluoro-1-difluoromethylcyclopropane
379-14-6

1,2,2,3,3-pentafluoro-1-difluoromethylcyclopropane

cyclohexene
110-83-8

cyclohexene

A

polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

B

pentafloropropylene
433-66-9

pentafloropropylene

C

carbon monoxide
201230-82-2

carbon monoxide

D

Octafluorocyclobutane
115-25-3

Octafluorocyclobutane

E

7,7-difluoronorcarane
823-70-1

7,7-difluoronorcarane

F

silicon tetrafluoride
7783-61-1

silicon tetrafluoride

Conditions
ConditionsYield
With Pyrex tube at 200℃; for 320h; Product distribution; Mechanism; further periods of contact time, other temperatures;A 14%
B 99%
C 11%
D n/a
E 47%
F 13%
Potassium pentafluoropropionate
378-76-7

Potassium pentafluoropropionate

polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

Conditions
ConditionsYield
at 300℃; Pyrolysis;98%
difluorodiiodomethane
1184-76-5

difluorodiiodomethane

polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

Conditions
ConditionsYield
With sodium dithionite; Allyl ether; sodium hydrogencarbonate In water; acetonitrile at 20℃; for 0.0833333h;97%
polytetrafluoroethylene (1)

polytetrafluoroethylene (1)

polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

Conditions
ConditionsYield
at 630 - 650℃; under 0.6 - 2 Torr; for 0.5h;96%
Chlorodifluoromethane
75-45-6

Chlorodifluoromethane

polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

Conditions
ConditionsYield
With high nickel alloy at 420 - 955℃; for 6.94444E-05h; Temperature;95.2%
In gas Product distribution; Irradiation; dependence on pressure and light intensity;
Pyrolysis;
sodium pentafluoropropionate
378-77-8

sodium pentafluoropropionate

polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

Conditions
ConditionsYield
at 300℃; Pyrolysis;91.3%
1-chloro-1,1,2,2-tetrafluoro-2-iodo-ethane
421-78-3

1-chloro-1,1,2,2-tetrafluoro-2-iodo-ethane

polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

Conditions
ConditionsYield
With sodium; ethyl acetoacetate In ethanol; N,N-dimethyl-formamide at 60℃; for 5h;91.2%
chloroethylene
75-01-4

chloroethylene

1,1,2,2,3,3-Hexafluoro-cyclopropane
931-91-9

1,1,2,2,3,3-Hexafluoro-cyclopropane

A

polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

B

Octafluorocyclobutane
115-25-3

Octafluorocyclobutane

C

1,1-difluoro-2-chlorocyclopropane
54944-21-7

1,1-difluoro-2-chlorocyclopropane

Conditions
ConditionsYield
at 294℃; for 1h; sealed tube in vacuo;A 91%
B 19%
C 55%
1,2-dibromo-1,1,2,2-tetrafluoroethane
124-73-2

1,2-dibromo-1,1,2,2-tetrafluoroethane

polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

Conditions
ConditionsYield
In methanol at 50℃;91%
With triethylchlorogermane; hexaethylphosphoric triamide In dichloromethane at -50 - 20℃;85%
With zinc In ethanol
(CF3)2Cd*(CH3OCH2)2

(CF3)2Cd*(CH3OCH2)2

A

polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

B

acetyl fluoride
557-99-3

acetyl fluoride

Conditions
ConditionsYield
With Acetyl bromide for 0.0833333h;A 64%
B 91%
1,2-diiodotetrafluoroethane
354-65-4

1,2-diiodotetrafluoroethane

polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

Conditions
ConditionsYield
With Allyl ether; sodium; ethyl acetoacetate In ethanol; N,N-dimethyl-formamide at 60℃; for 5h;90.5%
With cadmium In acetonitrile for 2h;
at 0℃; Mechanism; Irradiation; other temperatures, other excitation energies;
pyrographite
7440-44-0

pyrographite

trifluorophosphane
7783-55-3

trifluorophosphane

A

polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

B

carbon tetrafluoride
75-73-0

carbon tetrafluoride

Conditions
ConditionsYield
In neat (no solvent) react. of C with PF3 in a Ni-tube at 1100°C;;A 90%
B 9%
difluoro diazomethane
814-73-3

difluoro diazomethane

polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

Conditions
ConditionsYield
byproducts: N2; Irradiation (UV/VIS); irradn. with UV lamp at 25°C (2.5 h);90%
1-dichloromethylene-2,2-difluoro-3,3-bis(trifluoromethyl)cyclopropane
83933-48-6

1-dichloromethylene-2,2-difluoro-3,3-bis(trifluoromethyl)cyclopropane

A

polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

B

1,1-dichloro-4,4,4-trifluoro-3-trifluoromethylbuta-1,2-diene
83933-47-5

1,1-dichloro-4,4,4-trifluoro-3-trifluoromethylbuta-1,2-diene

Conditions
ConditionsYield
at 550℃; under 2 Torr; Yields of byproduct given;A n/a
B 87%
benzoyl chloride
98-88-4

benzoyl chloride

(CF3)2Cd*(CH3OCH2)2

(CF3)2Cd*(CH3OCH2)2

A

polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

B

benzoyl fluoride
455-32-3

benzoyl fluoride

Conditions
ConditionsYield
In dichloromethaneA 50%
B 86%
1-Chloro-2,2-difluoroethene
359-10-4

1-Chloro-2,2-difluoroethene

A

polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

B

Vinylidene fluoride
75-38-7

Vinylidene fluoride

C

1,1,2-trifluoroethylene
359-11-5

1,1,2-trifluoroethylene

Conditions
ConditionsYield
With hydrogen sulfide Product distribution; Irradiation; added CH3OH or alone;A 6%
B 82%
C 12%
(trifluoro methyl) magnesiumiodide
334-98-5

(trifluoro methyl) magnesiumiodide

A

polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

B

difluoro-methylene
2154-59-8

difluoro-methylene

C

trifluoromethan
75-46-7

trifluoromethan

Conditions
ConditionsYield
In diethyl ether decomposition under reflux in ether;;A 6%
B n/a
C 81%
In diethyl ether decomposition under reflux in ether;;A 6%
B n/a
C 81%
Tris(trifluormethyl)-difluorphosphoran
661-45-0, 79549-41-0

Tris(trifluormethyl)-difluorphosphoran

A

polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

B

difluoro-methylene
2154-59-8

difluoro-methylene

C

1,1,2,2,3,3-Hexafluoro-cyclopropane
931-91-9

1,1,2,2,3,3-Hexafluoro-cyclopropane

Conditions
ConditionsYield
120°C (24 h);A 10%
B 10%
C 80%
200°C (10 min);A 80%
B 10%
C 10%
120°C (24 h);A 10%
B 10%
C 80%
200°C (10 min);A 80%
B 10%
C 10%
1,2-dibromo-1,1,2,2-tetrafluoroethane
124-73-2

1,2-dibromo-1,1,2,2-tetrafluoroethane

diethylamine
109-89-7

diethylamine

phosphonic acid diethyl ester
762-04-9

phosphonic acid diethyl ester

A

polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

B

diethyl-amidophosphoric acid diethyl ester
3167-69-9

diethyl-amidophosphoric acid diethyl ester

Conditions
ConditionsYield
at 0 - 20℃; Todd-Atterton reaction;A n/a
B 73%
ethene
74-85-1

ethene

1,1,2,2,3,3-Hexafluoro-cyclopropane
931-91-9

1,1,2,2,3,3-Hexafluoro-cyclopropane

A

polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

B

2,2-difluorocyclopropane
558-29-2

2,2-difluorocyclopropane

C

1,1,2,2-tetrafluorocyclobutane
374-12-9

1,1,2,2-tetrafluorocyclobutane

D

Octafluorocyclobutane
115-25-3

Octafluorocyclobutane

Conditions
ConditionsYield
at 300℃; for 4h; sealed tube in vacuo;A 16%
B 68%
C 63%
D 15%
trifluoromethyltrimethylsilane
335-06-8

trifluoromethyltrimethylsilane

A

polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

B

(difluoromethyl)fluorosilane
129452-95-5

(difluoromethyl)fluorosilane

Conditions
ConditionsYield
With fluorosilane at 102℃; for 2h;A n/a
B 67%
1-bromo-2-iodo-1,1,2,2-tetrafluoroethane
421-70-5

1-bromo-2-iodo-1,1,2,2-tetrafluoroethane

polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

Conditions
ConditionsYield
With dibromodifluoromethane; triphenylphosphine; zinc In N,N-dimethyl-formamide at 20℃;67%
1,2-dibromo-1,1,2,2-tetrafluoroethane
124-73-2

1,2-dibromo-1,1,2,2-tetrafluoroethane

phosphonic acid bis-(2,2,3,3-tetrafluoro-propyl) ester
65611-25-8

phosphonic acid bis-(2,2,3,3-tetrafluoro-propyl) ester

diethylamine
109-89-7

diethylamine

A

polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

B

bis(1,1,3-trihydroperfluoropropyl) (diethylamido)phosphate

bis(1,1,3-trihydroperfluoropropyl) (diethylamido)phosphate

Conditions
ConditionsYield
at 0 - 20℃; Todd-Atterton reaction;A n/a
B 65.3%
bis(trifluoromethyl)cadmium*glyme

bis(trifluoromethyl)cadmium*glyme

polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

Conditions
ConditionsYield
With Acetyl bromide In various solvent(s) Ambient temperature;64%
1-chloro-1,1,2,2-tetrafluoro-2-iodo-ethane
421-78-3

1-chloro-1,1,2,2-tetrafluoro-2-iodo-ethane

Allyl ether
557-40-4

Allyl ether

ethyl acetoacetate
141-97-9

ethyl acetoacetate

A

polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

B

3-(3-Chloro-2,2,3,3-tetrafluoro-propyl)-4-iodomethyl-tetrahydro-furan

3-(3-Chloro-2,2,3,3-tetrafluoro-propyl)-4-iodomethyl-tetrahydro-furan

Conditions
ConditionsYield
With sodium In ethanol; N,N-dimethyl-formamide at 60℃; for 5h;A 63.7%
B 19.1%
perfluorocetane
355-49-7

perfluorocetane

A

polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

B

perfluoropropylene
116-15-4

perfluoropropylene

C

octafluoro-1-butene
357-26-6

octafluoro-1-butene

Conditions
ConditionsYield
at 195 - 500℃; under 75.7576 Torr; Temperature; Pressure; Pyrolysis;A 62.4%
B 24.3%
C 6.2%
polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

(1,1,2,2-tetrafluoroethyl)trifluorosilane
4168-07-4

(1,1,2,2-tetrafluoroethyl)trifluorosilane

A

pentafloropropylene
433-66-9

pentafloropropylene

B

1,1,2,2,3,3-Hexafluoro-cyclopropane
931-91-9

1,1,2,2,3,3-Hexafluoro-cyclopropane

C

1,2,2,3,3-pentafluoro-1-difluoromethylcyclopropane
379-14-6

1,2,2,3,3-pentafluoro-1-difluoromethylcyclopropane

D

silicon tetrafluoride
7783-61-1

silicon tetrafluoride

Conditions
ConditionsYield
at 150℃; for 18h; Further byproducts given;A 5%
B n/a
C 74%
D 100%
at 200℃; for 10h; Further byproducts given;A 19%
B n/a
C 71%
D 98%
polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

Carbonyl fluoride
353-50-4

Carbonyl fluoride

Conditions
ConditionsYield
With oxygen at 200 - 370℃; for 0.00166667h; Product distribution / selectivity;100%
With triplet molecular oxygen; sulphur hexafluoride under 202.5 - 525.04 Torr; Product distribution; Mechanism; Irradiation; various ratio of all the components;
polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

perfluoropropylene
116-15-4

perfluoropropylene

copolymer; monomers: tetrafluoroethylene; hexafluoropropylene

copolymer; monomers: tetrafluoroethylene; hexafluoropropylene

Conditions
ConditionsYield
With ozone at -33.15 - 16.85℃;100%
polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

allyl(cyclopentadiene)palladium(II)
1271-03-0

allyl(cyclopentadiene)palladium(II)

1,4-bis(dicyclohexylphosphino)butane
65038-36-0

1,4-bis(dicyclohexylphosphino)butane

(η2-tetrafluoroethylene)Pd(1,4-bis(dicyclohexylphosphino)butane)
1445270-22-3

(η2-tetrafluoroethylene)Pd(1,4-bis(dicyclohexylphosphino)butane)

Conditions
ConditionsYield
In toluene at 20℃; under 760.051 Torr; for 3h; Inert atmosphere;100%
polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

bis(1,5-cyclooctadiene)nickel (0)
1295-35-8

bis(1,5-cyclooctadiene)nickel (0)

1,4-bis(dicyclohexylphosphino)butane
65038-36-0

1,4-bis(dicyclohexylphosphino)butane

(η2-tetrafluoroethylene)Ni(1,4-bis(dicyclohexylphosphino)butane)
1445270-35-8

(η2-tetrafluoroethylene)Ni(1,4-bis(dicyclohexylphosphino)butane)

Conditions
ConditionsYield
In toluene at 20℃; under 760.051 Torr; for 4.5h; Inert atmosphere;100%
polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

bis(1,5-cyclooctadiene)nickel (0)
1295-35-8

bis(1,5-cyclooctadiene)nickel (0)

ethene
74-85-1

ethene

C40H34F4NiP2

C40H34F4NiP2

Conditions
ConditionsYield
With triphenylphosphine In toluene at 20℃; for 0.5h; Autoclave; Inert atmosphere;100%
polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

bis(1,5-cyclooctadiene)nickel (0)
1295-35-8

bis(1,5-cyclooctadiene)nickel (0)

ethene
74-85-1

ethene

C40H30F8NiP2
27661-80-9

C40H30F8NiP2

Conditions
ConditionsYield
With triphenylphosphine In toluene at 20℃; for 0.25h; Autoclave; Inert atmosphere;100%
polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

bis(1,5-cyclooctadiene)nickel (0)
1295-35-8

bis(1,5-cyclooctadiene)nickel (0)

ethene
74-85-1

ethene

triphenylphosphine
603-35-0

triphenylphosphine

(CF2CF2CH2CH2)Ni(PPh3)2

(CF2CF2CH2CH2)Ni(PPh3)2

Conditions
ConditionsYield
In benzene-d6 at 20℃; under 1875.19 Torr; Glovebox;100%
polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

ethene
74-85-1

ethene

5,5,6,6-tetrafluoro-1-hexene

5,5,6,6-tetrafluoro-1-hexene

Conditions
ConditionsYield
With bis(1,5-cyclooctadiene)nickel (0); tricyclohexylphosphine In benzene-d6 at 20℃; under 1875.19 - 3750.38 Torr; for 10h; Glovebox;100%
polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

2,2,3,3,3-pentafluoropropyl alcohol
422-05-9

2,2,3,3,3-pentafluoropropyl alcohol

1,1,1,2,2-pentafluoro-3-(1,1,2,2-tetrafluoroethoxy)propane
50807-74-4

1,1,1,2,2-pentafluoro-3-(1,1,2,2-tetrafluoroethoxy)propane

Conditions
ConditionsYield
With potassium hydroxide In water at 75 - 85℃; under 5250.53 - 6000.6 Torr; Inert atmosphere; Autoclave;99.8%
polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

fluorosulfonyl fluoride
640723-20-2, 2699-79-8, 12769-73-2

fluorosulfonyl fluoride

Se8(AsF6)2

Se8(AsF6)2

A

bis(pentafluoroethyl)diselane
6123-49-5

bis(pentafluoroethyl)diselane

B

bis(pentafluoroethyl) triselenide
51684-79-8

bis(pentafluoroethyl) triselenide

Conditions
ConditionsYield
20 atm, 100°C, 3 d;A 99%
B <1
polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

Se8(Sb2F11)2

Se8(Sb2F11)2

A

bis(pentafluoroethyl)diselane
6123-49-5

bis(pentafluoroethyl)diselane

B

bis(pentafluoroethyl) triselenide
51684-79-8

bis(pentafluoroethyl) triselenide

Conditions
ConditionsYield
10 atm, 100°C, 3 d;A 99%
B <1
polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

osmium(VIII) oxide
20816-12-0

osmium(VIII) oxide

(C5H5N)2Os(O)2OCF2CF2O
143492-97-1

(C5H5N)2Os(O)2OCF2CF2O

Conditions
ConditionsYield
With pyridine In toluene poured through a soln. of OsO4 in toluene and pyridine at 25°C, few minutes; pptd., solvent removed, dried in vacuo, elem. anal.;99%
With pyridine In pyridine; toluene passing olefine through reagent soln. from toluene, OsO4 and pyridine to olefine, room temp., 2h; pptn.; evapn.; recrystn. (toluene/dichlormethane); elem. anal.;>99
polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

allyl(cyclopentadiene)palladium(II)
1271-03-0

allyl(cyclopentadiene)palladium(II)

1,2-bis-(dicyclohexylphosphino)ethane
23743-26-2

1,2-bis-(dicyclohexylphosphino)ethane

(η2-tetrafluoroethylene)Pd(1,2-bis(dicyclohexylphosphino)ethane)
1445269-18-0

(η2-tetrafluoroethylene)Pd(1,2-bis(dicyclohexylphosphino)ethane)

Conditions
ConditionsYield
In toluene at 20℃; under 760.051 Torr; for 3h; Inert atmosphere;99%
polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

bis(1,5-cyclooctadiene)nickel (0)
1295-35-8

bis(1,5-cyclooctadiene)nickel (0)

tris(1-methylethyl)phosphine
6476-36-4

tris(1-methylethyl)phosphine

(η2-tetrafluoroethylene)Ni(triisopropylphosphine)2
1250264-09-5

(η2-tetrafluoroethylene)Ni(triisopropylphosphine)2

Conditions
ConditionsYield
In toluene at 20℃; under 760.051 Torr; for 16h; Inert atmosphere;99%
polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

ethene
74-85-1

ethene

4-Octyne
1942-45-6

4-Octyne

(Z)-7,7,8,8-tetrafluoro-3,4-dipropyl-1,3-octadiene

(Z)-7,7,8,8-tetrafluoro-3,4-dipropyl-1,3-octadiene

Conditions
ConditionsYield
With bis(1,5-cyclooctadiene)nickel (0); tricyclohexylphosphine In toluene at 40℃; under 2280.15 Torr; for 1h; Catalytic behavior; Solvent; Reagent/catalyst; Time; Autoclave;99%
polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

3-mercaptophenol
40248-84-8

3-mercaptophenol

C10H6F8OS

C10H6F8OS

Conditions
ConditionsYield
With potassium hydroxide In N,N-dimethyl-formamide at 20℃; under 1520.1 Torr; for 1h; Inert atmosphere;99%
propan-1-ol
71-23-8

propan-1-ol

polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

1,1,2,2-tetrafluoroethyl propyl ether
380-48-3

1,1,2,2-tetrafluoroethyl propyl ether

Conditions
ConditionsYield
With 1,4-diaza-bicyclo[2.2.2]octane; dmap; DBN; 1,8-diazabicyclo[5.4.0]undec-7-ene at 50 - 70℃; for 0.005h;98.9%
With sodium n-propoxide
polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

2,2,3,3-tetrafluoropropanol
76-37-9

2,2,3,3-tetrafluoropropanol

1,1,2,2-tetrafluoro-3-(1,1,2,2-tetrafluoroethoxy)propane
16627-68-2

1,1,2,2-tetrafluoro-3-(1,1,2,2-tetrafluoroethoxy)propane

Conditions
ConditionsYield
With potassium hydroxide In water at 75 - 95℃; under 5625.56 - 6000.6 Torr; for 8.5h; Product distribution / selectivity; Inert atmosphere; Autoclave;98.5%
With sodium In 1,4-dioxane
With potassium hydroxide In N,N-dimethyl-formamide
With potassium hydroxide In water at 20 - 95℃; under 750.075 - 6000.6 Torr; Product distribution / selectivity; Inert atmosphere; Industry scale; Autoclave;
polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

1,1,2,2-Tetrafluoro-1-(2,2,2-trifluoroethoxy)-ethane
406-78-0

1,1,2,2-Tetrafluoro-1-(2,2,2-trifluoroethoxy)-ethane

Conditions
ConditionsYield
potassium hydroxide In diethylene glycol dimethyl ether; water at 50℃; under 1500.15 Torr; for 4.8h; Product distribution / selectivity; Cooling with liquid nitrogen;98%
potassium hydroxide In Tetraethylene glycol dimethyl ether; water at 50℃; under 1500.15 Torr; for 0.33 - 1.25h; Product distribution / selectivity; Cooling with liquid nitrogen;97%
potassium hydroxide In Tetraethylene glycol dimethyl ether; water at 60℃; under 3750.38 Torr; for 10h; Product distribution / selectivity;94%
polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

dimethyl amine
124-40-3

dimethyl amine

1,1,2,2-tetrafluoro-N,N-dimethylethan-1-amine
1550-50-1

1,1,2,2-tetrafluoro-N,N-dimethylethan-1-amine

Conditions
ConditionsYield
at 20℃; for 12h;98%
at -70℃;
polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

bis(trifluoromethyl)phosphine
460-96-8

bis(trifluoromethyl)phosphine

Tetrafluorethylbis-trifluormethyl-phosphin
25196-27-4

Tetrafluorethylbis-trifluormethyl-phosphin

Conditions
ConditionsYield
Irradiation (UV/VIS); time of irradiation:1 h;98%
Irradiation (UV/VIS); time of irradiation:1 h;98%
Irradiation (UV/VIS); time of irradiation:20 h;83%
Irradiation (UV/VIS); time of irradiation:20 h;83%
Irradiation;
polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

(1,1,2,2-tetrafluoroethyl)trifluorosilane
4168-07-4

(1,1,2,2-tetrafluoroethyl)trifluorosilane

A

pentafloropropylene
433-66-9

pentafloropropylene

B

1,2,2,3,3-pentafluoro-1-difluoromethylcyclopropane
379-14-6

1,2,2,3,3-pentafluoro-1-difluoromethylcyclopropane

C

silicon tetrafluoride
7783-61-1

silicon tetrafluoride

D

1,1,2-trifluoroethylene
359-11-5

1,1,2-trifluoroethylene

Conditions
ConditionsYield
at 200℃; for 10h; Further byproducts given;A 19%
B 71%
C 98%
D 8%
polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

1,10-Phenanthroline
66-71-7

1,10-Phenanthroline

2-methoxy-4-nitrophenol
3251-56-7

2-methoxy-4-nitrophenol

mesitylcopper(I)
75732-01-3

mesitylcopper(I)

C21H14CuF4N3O4

C21H14CuF4N3O4

Conditions
ConditionsYield
Stage #1: 1,10-Phenanthroline; 2-methoxy-4-nitrophenol; mesitylcopper(I) In tetrahydrofuran at 20℃; Autoclave; Inert atmosphere;
Stage #2: polytetrafluoroethylene In tetrahydrofuran at 40℃; under 2660.18 Torr; for 24h; Inert atmosphere;
98%

TETRAFLUOROETHYLENE Chemical Properties

Molecular Formula: C2F4
Formula Weight: 100.02
mp of TETRAFLUOROETHYLENE (116-14-3): -142°C
bp of TETRAFLUOROETHYLENE (116-14-3): -76.3°C
Density: 1.519 g/cm
Vapour Pressure: 20000 mmHg at 25°C
Index of Refraction: 1.241
VAPOR DENSITY (air=1): 3.9
SOLUBILITY: TETRAFLUOROETHYLENE (116-14-3) do not dissolve in water.
Appearance: TETRAFLUOROETHYLENE (116-14-3) is an odorless and colorless gas.

TETRAFLUOROETHYLENE Uses

TETRAFLUOROETHYLENE (116-14-3) is used as a monomer for manufacturing polyfluortetraethylene, other fluoroplastic, fluorubber and perfluoro propylene. TETRAFLUOROETHYLENE (116-14-3) is also used in the preparation of numerous copolymers that also include hydrogen and/or oxygen, including both fluoroplastics and fluoroelastomers.

TETRAFLUOROETHYLENE Production

TETRAFLUOROETHYLENE (116-14-3) is manufactured from chloroform.
CHCl3 + 2HF → CHClF2 + 2HCl
2CHClF2 → C2F4 + 2HCl

TETRAFLUOROETHYLENE Toxicity Data With Reference

1.   

ihl-rat LC50:40,000 ppm/4H

   JOCMA7    Journal of Occupational Medicine. 4 (1962),262.
2.   

ihl-mus LC50:143 g/m3/kg

   GTPZAB    Gigiena Truda i Professionalnye Zabolevaniia. Labor Hygiene and Occupational Diseases. 21 (5)(1977),36.
3.   

ihl-gpg LC50:116 g/m3/kg

   GTPZAB    Gigiena Truda i Professionalnye Zabolevaniia. Labor Hygiene and Occupational Diseases. 21 (5)(1977),36.

TETRAFLUOROETHYLENE Consensus Reports

NTP 10th Report on Carcinogens. IARC Cancer Review: Group 3 IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 7 ,1987,p. 56.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) . Reported in EPA TSCA Inventory.

TETRAFLUOROETHYLENE Safety Profile

Safety: WARNING: Irreversible damage risk, protect skin/eyes/lungs; Safety glasses, adequate ventilation.
Hazard Codes : C: Corrosive
F: Highly Flammable
Risk Statements : 11: Highly Flammable
Safety Statements : 16: Keep away from sources of ignition - No smoking
36/37/39: Wear suitable protective clothing, gloves and eye/face protection
45: In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
RIDADR : 1081
Hazard Note : Corrosive/Flammable
HazardClass : 2.1
Confirmed carcinogen. Mildly toxic by inhalation. Can act as an asphyxiant and may have other toxic properties. The gas is flammable when exposed to heat or flame. The inhibited monomer will explode if ignited. Explosive in the form of vapor when exposed to heat or flame. Will explode at pressures above 2.7 bar if limonene inhibitor is not added. Iodine pentafluoride depletes the limonene inhibitor and then causes explosive polymerization of the monomer. Mixtures with hexafluoropropene and air form an explosive peroxide. Reacts violently with SO3; air; difluoromethylene dihypofluorite; dioxygen difluoride; iodine pentafluoride; oxygen. When heated to decomposition it emits highly toxic fumes of F. See also FLUORIDES.

TETRAFLUOROETHYLENE Standards and Recommendations

ACGIH TLV: TWA 2 ppm; Confirmed Animal Carcinogen with Unknown Relevance to Humans
DOT Classification:  2.1; Label: Flammable Gas

TETRAFLUOROETHYLENE Specification

STORAGE: Store and handle in accordance with all current regulations and standards. Store outside or in a detached building. Store in a well-ventilated area. Avoid contact with light. Keep separated from incompatible substances. Protect from physical damage. Provide fire protection and spill control systems suitable for the hazards of the material.
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