propene
1,1,2,2,3,3-Hexafluoro-cyclopropane
A
polytetrafluoroethylene
B
1,1-difluoro-2-methylcyclopropane
C
Octafluorocyclobutane
D
1,1,2,2-tetrafluoro-3-methylcyclobutane
Conditions | Yield |
---|---|
at 296℃; for 1h; sealed tube in vacuo; | A 16% B 100% C 9% D 21% |
at 296℃; sealed tube in vacuo; | A 16% B 100% C 9% D 21% |
1,2,2,3,3-pentafluoro-1-difluoromethylcyclopropane
A
polytetrafluoroethylene
B
pentafloropropylene
C
1,1,2,2,3,3-Hexafluoro-cyclopropane
D
Octafluorocyclobutane
Conditions | Yield |
---|---|
at 300℃; for 160h; Further byproducts given; | A 28% B 100% C 6% D 12% |
Conditions | Yield |
---|---|
With hydrogen at 336.84 - 736.84℃; Product distribution / selectivity; Gas phase; Inert atmosphere; | 100% |
1,2,2,3,3-pentafluoro-1-difluoromethylcyclopropane
cyclohexene
A
polytetrafluoroethylene
B
pentafloropropylene
C
Octafluorocyclobutane
D
7,7-difluoronorcarane
Conditions | Yield |
---|---|
at 200℃; for 320h; Further byproducts given; | A 14% B 99% C n/a D 47% |
1,2,2,3,3-pentafluoro-1-difluoromethylcyclopropane
cyclohexene
A
polytetrafluoroethylene
B
pentafloropropylene
C
carbon monoxide
D
Octafluorocyclobutane
E
7,7-difluoronorcarane
F
silicon tetrafluoride
Conditions | Yield |
---|---|
With Pyrex tube at 200℃; for 320h; Product distribution; Mechanism; further periods of contact time, other temperatures; | A 14% B 99% C 11% D n/a E 47% F 13% |
Conditions | Yield |
---|---|
at 300℃; Pyrolysis; | 98% |
Conditions | Yield |
---|---|
With sodium dithionite; Allyl ether; sodium hydrogencarbonate In water; acetonitrile at 20℃; for 0.0833333h; | 97% |
polytetrafluoroethylene
Conditions | Yield |
---|---|
at 630 - 650℃; under 0.6 - 2 Torr; for 0.5h; | 96% |
Conditions | Yield |
---|---|
With high nickel alloy at 420 - 955℃; for 6.94444E-05h; Temperature; | 95.2% |
In gas Product distribution; Irradiation; dependence on pressure and light intensity; | |
Pyrolysis; |
Conditions | Yield |
---|---|
at 300℃; Pyrolysis; | 91.3% |
Conditions | Yield |
---|---|
With sodium; ethyl acetoacetate In ethanol; N,N-dimethyl-formamide at 60℃; for 5h; | 91.2% |
chloroethylene
1,1,2,2,3,3-Hexafluoro-cyclopropane
A
polytetrafluoroethylene
B
Octafluorocyclobutane
C
1,1-difluoro-2-chlorocyclopropane
Conditions | Yield |
---|---|
at 294℃; for 1h; sealed tube in vacuo; | A 91% B 19% C 55% |
Conditions | Yield |
---|---|
In methanol at 50℃; | 91% |
With triethylchlorogermane; hexaethylphosphoric triamide In dichloromethane at -50 - 20℃; | 85% |
With zinc In ethanol |
Conditions | Yield |
---|---|
With Acetyl bromide for 0.0833333h; | A 64% B 91% |
Conditions | Yield |
---|---|
With Allyl ether; sodium; ethyl acetoacetate In ethanol; N,N-dimethyl-formamide at 60℃; for 5h; | 90.5% |
With cadmium In acetonitrile for 2h; | |
at 0℃; Mechanism; Irradiation; other temperatures, other excitation energies; |
pyrographite
trifluorophosphane
A
polytetrafluoroethylene
B
carbon tetrafluoride
Conditions | Yield |
---|---|
In neat (no solvent) react. of C with PF3 in a Ni-tube at 1100°C;; | A 90% B 9% |
Conditions | Yield |
---|---|
byproducts: N2; Irradiation (UV/VIS); irradn. with UV lamp at 25°C (2.5 h); | 90% |
1-dichloromethylene-2,2-difluoro-3,3-bis(trifluoromethyl)cyclopropane
A
polytetrafluoroethylene
B
1,1-dichloro-4,4,4-trifluoro-3-trifluoromethylbuta-1,2-diene
Conditions | Yield |
---|---|
at 550℃; under 2 Torr; Yields of byproduct given; | A n/a B 87% |
Conditions | Yield |
---|---|
In dichloromethane | A 50% B 86% |
1-Chloro-2,2-difluoroethene
A
polytetrafluoroethylene
B
Vinylidene fluoride
C
1,1,2-trifluoroethylene
Conditions | Yield |
---|---|
With hydrogen sulfide Product distribution; Irradiation; added CH3OH or alone; | A 6% B 82% C 12% |
(trifluoro methyl) magnesiumiodide
A
polytetrafluoroethylene
B
difluoro-methylene
C
trifluoromethan
Conditions | Yield |
---|---|
In diethyl ether decomposition under reflux in ether;; | A 6% B n/a C 81% |
In diethyl ether decomposition under reflux in ether;; | A 6% B n/a C 81% |
Tris(trifluormethyl)-difluorphosphoran
A
polytetrafluoroethylene
B
difluoro-methylene
C
1,1,2,2,3,3-Hexafluoro-cyclopropane
Conditions | Yield |
---|---|
120°C (24 h); | A 10% B 10% C 80% |
200°C (10 min); | A 80% B 10% C 10% |
120°C (24 h); | A 10% B 10% C 80% |
200°C (10 min); | A 80% B 10% C 10% |
1,2-dibromo-1,1,2,2-tetrafluoroethane
diethylamine
phosphonic acid diethyl ester
A
polytetrafluoroethylene
B
diethyl-amidophosphoric acid diethyl ester
Conditions | Yield |
---|---|
at 0 - 20℃; Todd-Atterton reaction; | A n/a B 73% |
ethene
1,1,2,2,3,3-Hexafluoro-cyclopropane
A
polytetrafluoroethylene
B
2,2-difluorocyclopropane
C
1,1,2,2-tetrafluorocyclobutane
D
Octafluorocyclobutane
Conditions | Yield |
---|---|
at 300℃; for 4h; sealed tube in vacuo; | A 16% B 68% C 63% D 15% |
trifluoromethyltrimethylsilane
A
polytetrafluoroethylene
B
(difluoromethyl)fluorosilane
Conditions | Yield |
---|---|
With fluorosilane at 102℃; for 2h; | A n/a B 67% |
Conditions | Yield |
---|---|
With dibromodifluoromethane; triphenylphosphine; zinc In N,N-dimethyl-formamide at 20℃; | 67% |
1,2-dibromo-1,1,2,2-tetrafluoroethane
phosphonic acid bis-(2,2,3,3-tetrafluoro-propyl) ester
diethylamine
A
polytetrafluoroethylene
Conditions | Yield |
---|---|
at 0 - 20℃; Todd-Atterton reaction; | A n/a B 65.3% |
polytetrafluoroethylene
Conditions | Yield |
---|---|
With Acetyl bromide In various solvent(s) Ambient temperature; | 64% |
1-chloro-1,1,2,2-tetrafluoro-2-iodo-ethane
Allyl ether
ethyl acetoacetate
A
polytetrafluoroethylene
Conditions | Yield |
---|---|
With sodium In ethanol; N,N-dimethyl-formamide at 60℃; for 5h; | A 63.7% B 19.1% |
perfluorocetane
A
polytetrafluoroethylene
B
perfluoropropylene
C
octafluoro-1-butene
Conditions | Yield |
---|---|
at 195 - 500℃; under 75.7576 Torr; Temperature; Pressure; Pyrolysis; | A 62.4% B 24.3% C 6.2% |
polytetrafluoroethylene
(1,1,2,2-tetrafluoroethyl)trifluorosilane
A
pentafloropropylene
B
1,1,2,2,3,3-Hexafluoro-cyclopropane
C
1,2,2,3,3-pentafluoro-1-difluoromethylcyclopropane
D
silicon tetrafluoride
Conditions | Yield |
---|---|
at 150℃; for 18h; Further byproducts given; | A 5% B n/a C 74% D 100% |
at 200℃; for 10h; Further byproducts given; | A 19% B n/a C 71% D 98% |
Conditions | Yield |
---|---|
With oxygen at 200 - 370℃; for 0.00166667h; Product distribution / selectivity; | 100% |
With triplet molecular oxygen; sulphur hexafluoride under 202.5 - 525.04 Torr; Product distribution; Mechanism; Irradiation; various ratio of all the components; |
Conditions | Yield |
---|---|
With ozone at -33.15 - 16.85℃; | 100% |
polytetrafluoroethylene
allyl(cyclopentadiene)palladium(II)
1,4-bis(dicyclohexylphosphino)butane
(η2-tetrafluoroethylene)Pd(1,4-bis(dicyclohexylphosphino)butane)
Conditions | Yield |
---|---|
In toluene at 20℃; under 760.051 Torr; for 3h; Inert atmosphere; | 100% |
polytetrafluoroethylene
bis(1,5-cyclooctadiene)nickel (0)
1,4-bis(dicyclohexylphosphino)butane
(η2-tetrafluoroethylene)Ni(1,4-bis(dicyclohexylphosphino)butane)
Conditions | Yield |
---|---|
In toluene at 20℃; under 760.051 Torr; for 4.5h; Inert atmosphere; | 100% |
Conditions | Yield |
---|---|
With triphenylphosphine In toluene at 20℃; for 0.5h; Autoclave; Inert atmosphere; | 100% |
polytetrafluoroethylene
bis(1,5-cyclooctadiene)nickel (0)
ethene
C40H30F8NiP2
Conditions | Yield |
---|---|
With triphenylphosphine In toluene at 20℃; for 0.25h; Autoclave; Inert atmosphere; | 100% |
polytetrafluoroethylene
bis(1,5-cyclooctadiene)nickel (0)
ethene
triphenylphosphine
Conditions | Yield |
---|---|
In benzene-d6 at 20℃; under 1875.19 Torr; Glovebox; | 100% |
Conditions | Yield |
---|---|
With bis(1,5-cyclooctadiene)nickel (0); tricyclohexylphosphine In benzene-d6 at 20℃; under 1875.19 - 3750.38 Torr; for 10h; Glovebox; | 100% |
polytetrafluoroethylene
2,2,3,3,3-pentafluoropropyl alcohol
1,1,1,2,2-pentafluoro-3-(1,1,2,2-tetrafluoroethoxy)propane
Conditions | Yield |
---|---|
With potassium hydroxide In water at 75 - 85℃; under 5250.53 - 6000.6 Torr; Inert atmosphere; Autoclave; | 99.8% |
polytetrafluoroethylene
fluorosulfonyl fluoride
A
bis(pentafluoroethyl)diselane
B
bis(pentafluoroethyl) triselenide
Conditions | Yield |
---|---|
20 atm, 100°C, 3 d; | A 99% B <1 |
polytetrafluoroethylene
A
bis(pentafluoroethyl)diselane
B
bis(pentafluoroethyl) triselenide
Conditions | Yield |
---|---|
10 atm, 100°C, 3 d; | A 99% B <1 |
Conditions | Yield |
---|---|
With pyridine In toluene poured through a soln. of OsO4 in toluene and pyridine at 25°C, few minutes; pptd., solvent removed, dried in vacuo, elem. anal.; | 99% |
With pyridine In pyridine; toluene passing olefine through reagent soln. from toluene, OsO4 and pyridine to olefine, room temp., 2h; pptn.; evapn.; recrystn. (toluene/dichlormethane); elem. anal.; | >99 |
polytetrafluoroethylene
allyl(cyclopentadiene)palladium(II)
1,2-bis-(dicyclohexylphosphino)ethane
(η2-tetrafluoroethylene)Pd(1,2-bis(dicyclohexylphosphino)ethane)
Conditions | Yield |
---|---|
In toluene at 20℃; under 760.051 Torr; for 3h; Inert atmosphere; | 99% |
polytetrafluoroethylene
bis(1,5-cyclooctadiene)nickel (0)
tris(1-methylethyl)phosphine
(η2-tetrafluoroethylene)Ni(triisopropylphosphine)2
Conditions | Yield |
---|---|
In toluene at 20℃; under 760.051 Torr; for 16h; Inert atmosphere; | 99% |
Conditions | Yield |
---|---|
With bis(1,5-cyclooctadiene)nickel (0); tricyclohexylphosphine In toluene at 40℃; under 2280.15 Torr; for 1h; Catalytic behavior; Solvent; Reagent/catalyst; Time; Autoclave; | 99% |
Conditions | Yield |
---|---|
With potassium hydroxide In N,N-dimethyl-formamide at 20℃; under 1520.1 Torr; for 1h; Inert atmosphere; | 99% |
Conditions | Yield |
---|---|
With 1,4-diaza-bicyclo[2.2.2]octane; dmap; DBN; 1,8-diazabicyclo[5.4.0]undec-7-ene at 50 - 70℃; for 0.005h; | 98.9% |
With sodium n-propoxide |
polytetrafluoroethylene
2,2,3,3-tetrafluoropropanol
1,1,2,2-tetrafluoro-3-(1,1,2,2-tetrafluoroethoxy)propane
Conditions | Yield |
---|---|
With potassium hydroxide In water at 75 - 95℃; under 5625.56 - 6000.6 Torr; for 8.5h; Product distribution / selectivity; Inert atmosphere; Autoclave; | 98.5% |
With sodium In 1,4-dioxane | |
With potassium hydroxide In N,N-dimethyl-formamide | |
With potassium hydroxide In water at 20 - 95℃; under 750.075 - 6000.6 Torr; Product distribution / selectivity; Inert atmosphere; Industry scale; Autoclave; |
polytetrafluoroethylene
2,2,2-trifluoroethanol
1,1,2,2-Tetrafluoro-1-(2,2,2-trifluoroethoxy)-ethane
Conditions | Yield |
---|---|
potassium hydroxide In diethylene glycol dimethyl ether; water at 50℃; under 1500.15 Torr; for 4.8h; Product distribution / selectivity; Cooling with liquid nitrogen; | 98% |
potassium hydroxide In Tetraethylene glycol dimethyl ether; water at 50℃; under 1500.15 Torr; for 0.33 - 1.25h; Product distribution / selectivity; Cooling with liquid nitrogen; | 97% |
potassium hydroxide In Tetraethylene glycol dimethyl ether; water at 60℃; under 3750.38 Torr; for 10h; Product distribution / selectivity; | 94% |
polytetrafluoroethylene
dimethyl amine
1,1,2,2-tetrafluoro-N,N-dimethylethan-1-amine
Conditions | Yield |
---|---|
at 20℃; for 12h; | 98% |
at -70℃; |
polytetrafluoroethylene
bis(trifluoromethyl)phosphine
Tetrafluorethylbis-trifluormethyl-phosphin
Conditions | Yield |
---|---|
Irradiation (UV/VIS); time of irradiation:1 h; | 98% |
Irradiation (UV/VIS); time of irradiation:1 h; | 98% |
Irradiation (UV/VIS); time of irradiation:20 h; | 83% |
Irradiation (UV/VIS); time of irradiation:20 h; | 83% |
Irradiation; |
polytetrafluoroethylene
(1,1,2,2-tetrafluoroethyl)trifluorosilane
A
pentafloropropylene
B
1,2,2,3,3-pentafluoro-1-difluoromethylcyclopropane
C
silicon tetrafluoride
D
1,1,2-trifluoroethylene
Conditions | Yield |
---|---|
at 200℃; for 10h; Further byproducts given; | A 19% B 71% C 98% D 8% |
polytetrafluoroethylene
1,10-Phenanthroline
2-methoxy-4-nitrophenol
mesitylcopper(I)
Conditions | Yield |
---|---|
Stage #1: 1,10-Phenanthroline; 2-methoxy-4-nitrophenol; mesitylcopper(I) In tetrahydrofuran at 20℃; Autoclave; Inert atmosphere; Stage #2: polytetrafluoroethylene In tetrahydrofuran at 40℃; under 2660.18 Torr; for 24h; Inert atmosphere; | 98% |
1. | ihl-rat LC50:40,000 ppm/4H | JOCMA7 Journal of Occupational Medicine. 4 (1962),262. | ||
2. | ihl-mus LC50:143 g/m3/kg | GTPZAB Gigiena Truda i Professionalnye Zabolevaniia. Labor Hygiene and Occupational Diseases. 21 (5)(1977),36. | ||
3. | ihl-gpg LC50:116 g/m3/kg | GTPZAB Gigiena Truda i Professionalnye Zabolevaniia. Labor Hygiene and Occupational Diseases. 21 (5)(1977),36. |
About|Contact|Cas|Product Name|Molecular|Country|Encyclopedia
Message|New Cas|MSDS|Service|Advertisement|CAS DataBase|Article Data|Manufacturers | Chemical Catalog
©2008 LookChem.com,License: ICP
NO.:Zhejiang16009103
complaints:service@lookchem.com Desktop View