Conditions | Yield |
---|---|
With hydrogenchloride; oxygen at 379.84℃; Reagent/catalyst; Temperature; | 74.3% |
With chlorine at 379.84℃; Gas phase; chemoselective reaction; | 57.3% |
at 350 - 400℃; bei der Einwirkung von Luft; |
1,1,2,2-tetrachloroethane
A
1,1,2,2-tetrachloroethylene
B
Trichloroethylene
Conditions | Yield |
---|---|
With hydrogenchloride; oxygen at 379.84℃; for 18h; | A 20.8% B 64.3% |
With CuCl2/KCl/attapulgite; chlorine at 379.84℃; Gas phase; chemoselective reaction; | A 16.6% B 45% |
1,1,2,2-tetrachloroethane
A
1,1,2,2-tetrachloroethylene
B
Trichloroethylene
C
pentachloroethane
Conditions | Yield |
---|---|
With hydrogenchloride; oxygen at 379.84℃; | A 20.8% B 64.3% C 6.1% |
1,1,2,2-tetrachloroethylene
A
cis-1,2-Dichloroethylene
B
Trichloroethylene
C
acetylene
Conditions | Yield |
---|---|
With iron sulfide In water for 2922h; pH=8.3; Kinetics; Product distribution; Dehydrochlorination; | A 1% B 1% C 56% |
With iron sulfide; rac-cysteine In water for 2922h; pH=8.3; Kinetics; Product distribution; Dehydrochlorination; | A 1% B 2% C 19% |
N,N-Dichlorobenzenesulfonamide
1,2-Dichloroethylene
A
benzenesulfonamide
B
1,1,2,2-tetrachloroethylene
C
Trichloroethylene
D
N-(2,2,2-trichloroethylidene)benzenesulfonamide
E
N-(2,2-dichloroethylidene)benzenesulfonamide
F
N-{2,2-dichloro-1-[(phenylsulfonyl)amino]ethyl}benzenesulfonamide
Conditions | Yield |
---|---|
at 55℃; for 22h; Product distribution; other time, other temperature, other initiator; | A n/a B n/a C n/a D n/a E n/a F 54.1% |
N,N-Dichlorobenzenesulfonamide
1,2-Dichloroethylene
A
1,1,2,2-tetrachloroethylene
B
Trichloroethylene
C
N-(2,2,2-trichloroethylidene)benzenesulfonamide
D
N-(2,2-dichloroethylidene)benzenesulfonamide
E
N-{2,2-dichloro-1-[(phenylsulfonyl)amino]ethyl}benzenesulfonamide
F
1,1,2,2-tetrachloroethane
Conditions | Yield |
---|---|
at 55℃; for 22h; Product distribution; other time, other temperature, other initiator; | A n/a B n/a C n/a D n/a E 54.1% F n/a |
N,N-dichloro-p-toluenesulfonamide
1,2-Dichloroethylene
A
N-(2,2,2-trichloroethyliden)-p-toluenesulfonamide
B
Trichloroethylene
C
N-(2,2-dichloro-1-{[(4-methylphenyl)sulfonyl]amino}ethyl)-4-methylbenzenesulfonamide
D
toluene-4-sulfonamide
E
N-[2,2-Dichloro-eth-(E)-ylidene]-4-methyl-benzenesulfonamide
F
1,1,2,2-tetrachloroethane
Conditions | Yield |
---|---|
at 55℃; for 22h; Product distribution; other time, other temperature, other initiator; | A n/a B n/a C 44.1% D n/a E n/a F n/a |
1,1,2,2-tetrachloroethylene
A
cis-1,2-Dichloroethylene
B
trans-1,2-dichloroethylene
C
Trichloroethylene
Conditions | Yield |
---|---|
With methanol at 20℃; Inert atmosphere; UV-irradiation; | A n/a B n/a C 43% |
With Desulfomonile tiedjei DCB-1 In water at 35℃; Kinetics; Further Variations:; Reagents; time; concentration; Dehalogenation; |
Conditions | Yield |
---|---|
With hexacarbonyl molybdenum at 140℃; for 3h; further reagent Fe(CO)5; | A 42% B 23% |
With iron pentacarbonyl at 140℃; for 3h; further reagent Mo(CO)6; | A 27% B 23% |
(2,2-dichloro-vinyl)-trimethyl-silane
A
chloro-trimethyl-silane
B
Trichloroethylene
Conditions | Yield |
---|---|
With chlorine for 3h; Further byproducts given; | A 7% B 5% C 30% D 33% |
(2,2-dichloro-vinyl)-trimethyl-silane
A
1,1,2,2-tetrachloroethylene
B
Trichloroethylene
Conditions | Yield |
---|---|
With chlorine for 3h; Further byproducts given; | A 1% B 5% C 30% D 33% |
With chlorine for 3h; Further byproducts given; | A 1% B 7% C 30% D 33% |
(2,2-dichloro-vinyl)-trimethyl-silane
A
Trichloroethylene
B
pentachloroethane
Conditions | Yield |
---|---|
With chlorine for 3h; Further byproducts given; | A 5% B 2% C 30% D 33% |
N,N-dichloro-p-toluenesulfonamide
trans-1,2-dichloroethylene
A
Trichloroethylene
B
N-(2,2,2-trichloro-1-hydroxyethyl)4-methylbenzenesulfonamide
C
N-(2,2-dichloro-1-{[(4-methylphenyl)sulfonyl]amino}ethyl)-4-methylbenzenesulfonamide
Conditions | Yield |
---|---|
at 47℃; for 20h; Further byproducts given. Yields of byproduct given; | A n/a B n/a C 32.5% D n/a |
With water 1.) 47 deg C, 20 h; Yield given. Multistep reaction. Further byproducts given. Yields of byproduct given; |
trans-1,2-dichloroethylene
N,N-dichloro-4-chlorobenzenesulfonamide
A
Trichloroethylene
B
4-chloro-N-(2,2,2-trichloro-1-hydroxyethyl)benzenesulfonamide
D
N-<2,2-dichloro-1-(N-p-chlorobenzenesulfonamido)ethyl>-p-chlorobenzenesulfonamide
Conditions | Yield |
---|---|
at 47℃; for 18h; Further byproducts given. Yields of byproduct given; | A n/a B n/a C n/a D 29.2% |
With water 1.) 47 deg C, 18 h; Yield given. Multistep reaction. Yields of byproduct given; |
piperidine
tetrachloromethane
1,1,2,2-tetrachloroethane
Trichloroethylene
Conditions | Yield |
---|---|
at 20℃; |
quinoline
diphenylether
biphenyl
1,1,2,2-tetrachloroethane
Trichloroethylene
Conditions | Yield |
---|---|
With chlorine; pyrographite at 450℃; |
Conditions | Yield |
---|---|
With oxygen; chlorine; copper(II) oxide at 400℃; | |
With hydrogenchloride; oxygen; copper(II) oxide at 400℃; | |
With hydrogenchloride; iron(III) oxide; air at 490℃; | |
With hydrogenchloride; oxygen; copper(II) oxide at 400℃; | |
With oxygen; chlorine; copper(II) oxide at 400℃; |
Conditions | Yield |
---|---|
With hydrogenchloride; oxygen; copper(II) oxide at 400 - 460℃; |
Conditions | Yield |
---|---|
With oxygen; chlorine; copper(II) oxide at 400℃; | |
With hydrogenchloride; oxygen; copper(II) oxide at 400℃; | |
With hydrogenchloride; oxygen; copper(II) oxide at 400℃; | |
With oxygen; chlorine; copper(II) oxide at 400℃; |
Conditions | Yield |
---|---|
With oxygen; copper(II) oxide at 375 - 525℃; |
Conditions | Yield |
---|---|
chromium(III) oxide In gas at 249.9℃; for 0.000833333h; Thermodynamic data; various temp.; ΔRH0; ΔRG0; | |
at 450℃; | |
With polyethylene glycol; sodium hydroxide at 60 - 110℃; |
Conditions | Yield |
---|---|
With hydrogen; nickel at 300℃; |
Conditions | Yield |
---|---|
With oxygen; chlorine; copper(II) oxide at 400℃; | |
With hydrogenchloride; oxygen; copper(II) oxide at 400℃; | |
With hydrogenchloride; oxygen; copper(II) oxide at 400℃; | |
With oxygen; chlorine; copper(II) oxide at 400℃; |
1,2-dibromo-1,1,2-trichloroethane
Trichloroethylene
Conditions | Yield |
---|---|
With hydrogen; nickel at 300℃; | |
With barium(II) chloride at 400℃; |
Conditions | Yield |
---|---|
With sulfuric acid; zinc |
Conditions | Yield |
---|---|
With tetraphosphorus decasulfide at 160 - 170℃; |
Trichloroethylene
N,N-dichloro-4-chlorobenzenesulfonamide
N-(2,2,2-trichloroethylidene)-4-chlorobenzenesulfonamide
Conditions | Yield |
---|---|
at 90℃; | 100% |
at 87 - 89℃; | 97% |
at 87℃; for 9h; | 95% |
Trichloroethylene
sale sodico del benzen-1,2-ditiolo
2-chloro-1,4-benzodithiin
Conditions | Yield |
---|---|
100% |
N,N,N',N'-tetrachlorobiphenyl-4,4'-disulfonamide
Trichloroethylene
Conditions | Yield |
---|---|
Heating; | 100% |
for 9h; Heating; | 98% |
Trichloroethylene
Conditions | Yield |
---|---|
With caesium carbonate In N,N-dimethyl-formamide at 50℃; for 6h; | 100% |
Conditions | Yield |
---|---|
With chlorine at 10 - 20℃; for 11h; Inert atmosphere; Cooling with ice; | 99% |
With tetrachloromethane; chlorine monoxide at -20℃; | |
With chlorine at 0℃; im Sonnenlicht; |
4-nitro-phenol
Trichloroethylene
(E)-1-(1,2-dichlorovinyloxy)-4-nitrobenzene
Conditions | Yield |
---|---|
With caesium carbonate In dimethyl sulfoxide at 70℃; for 1.5h; Inert atmosphere; | 99% |
With methanol; potassium carbonate In N,N-dimethyl-formamide at 60 - 70℃; Inert atmosphere; | 88% |
With sodium hydroxide; benzyltripropylammonium chloride In cyclohexane for 2h; | 50% |
Conditions | Yield |
---|---|
for 48h; Ambient temperature; in vacuo; | 99% |
Trichloroethylene
4-methoxy-phenol
1-(1,2-dichloroethenyloxy)-4-methoxybenzene
Conditions | Yield |
---|---|
Stage #1: 4-methoxy-phenol With potassium hydride In tetrahydrofuran Inert atmosphere; Stage #2: Trichloroethylene In tetrahydrofuran at 20℃; Inert atmosphere; | 99% |
With sodium hydroxide In dimethyl sulfoxide at 20℃; Inert atmosphere; | 99% |
Stage #1: 4-methoxy-phenol With sodium hydroxide In dimethyl sulfoxide at 20℃; for 2h; Inert atmosphere; Stage #2: Trichloroethylene In dimethyl sulfoxide at 20℃; for 4h; Inert atmosphere; | 98% |
Conditions | Yield |
---|---|
Stage #1: ortho-cresol With potassium hydride In tetrahydrofuran Inert atmosphere; Stage #2: Trichloroethylene In tetrahydrofuran at 20℃; Inert atmosphere; | 99% |
Trichloroethylene
4-cyanophenol
(E)-4-(1,2-dichlorovinyloxy)benzonitrile
Conditions | Yield |
---|---|
With caesium carbonate In dimethyl sulfoxide at 70℃; for 1.5h; Inert atmosphere; | 99% |
With potassium carbonate In N,N-dimethyl-formamide at 60 - 70℃; Inert atmosphere; | 94% |
Trichloroethylene
N-(2,6-di-i-propylphenyl)tosylamide
Conditions | Yield |
---|---|
With caesium carbonate In N,N-dimethyl-formamide at 50℃; | 99% |
Stage #1: N-(2,6-diisopropylphenyl)tosylamide With caesium carbonate In N,N-dimethyl-formamide at 50℃; for 0.166667h; Inert atmosphere; Stage #2: Trichloroethylene In N,N-dimethyl-formamide at 50℃; for 3h; Inert atmosphere; | 94% |
Conditions | Yield |
---|---|
Stage #1: 2,6-di(t-butyl)-4-phenylphenol With sodium hydroxide In dimethyl sulfoxide at 20℃; for 14h; Inert atmosphere; Stage #2: Trichloroethylene In dimethyl sulfoxide at 20℃; for 8h; Inert atmosphere; | 99% |
Conditions | Yield |
---|---|
With caesium carbonate In dimethyl sulfoxide at 20℃; for 1.5h; Inert atmosphere; | 99% |
Trichloroethylene
Conditions | Yield |
---|---|
With caesium carbonate In N,N-dimethyl-formamide at 50℃; for 1.5h; Inert atmosphere; | 99% |
N,N-Dichlorobenzenesulfonamide
Trichloroethylene
N-(2,2,2-trichloro-1-hydroxyethyl)benzenesulfonamide
Conditions | Yield |
---|---|
With water 1) 85 - 90 deg C, 2) 30 deg C.; | 98% |
With tin(IV) chloride at 87℃; for 336h; Yield given; |
Trichloroethylene
sodium thiomethoxide
1,1,2-tris-methylsulfanyl-ethene
Conditions | Yield |
---|---|
In N,N,N,N,N,N-hexamethylphosphoric triamide for 1h; Ambient temperature; | 98% |
In N,N-dimethyl-formamide at 80℃; for 1.5h; | 94% |
Trichloroethylene
3-methyl-phenol
(E)-1-(1,2-dichlorovinyloxy)-3-methylbenzene
Conditions | Yield |
---|---|
Stage #1: 3-methyl-phenol With potassium hydride In tetrahydrofuran Inert atmosphere; Stage #2: Trichloroethylene In tetrahydrofuran at -50 - 20℃; Inert atmosphere; | 98% |
With caesium carbonate In dimethyl sulfoxide at 20℃; for 1.5h; Inert atmosphere; | 91% |
With sodium hydroxide; benzyltripropylammonium chloride In cyclohexane for 2h; | 58% |
Trichloroethylene
N-bromobis(trifluoromethyl)amine
A
Perfluoro-2-azapropen
Conditions | Yield |
---|---|
for 72h; Ambient temperature; in vacuo; | A 2% B 98% |
Conditions | Yield |
---|---|
With potassium hydroxide; 2,3,5,6,8,9,11,12,14,15-decahydro-1,4,7,10,13,16-benzohexaoxacyclooctadecin In diethyl ether; toluene for 3h; | 98% |
With tetrabutylammomium bromide; potassium carbonate In acetonitrile at 82℃; for 2h; | 96% |
With tetrabutylammomium bromide; potassium carbonate In acetonitrile at 80℃; for 3h; Mechanism; other amines, oether bases and catalysts, var. solvent and time; | |
With sodium hydroxide; N-benzyl-N,N,N-triethylammonium chloride In cyclohexane for 3h; Product distribution; other catalysts and PTC systems; |
6-allyl-2,7-dimethyl-hexahydro-1,3,5-trioxa-benzocyclohepten-7-ol
Trichloroethylene
Conditions | Yield |
---|---|
With potassium hydride In tetrahydrofuran at 20℃; for 0.5h; | 98% |
O-methylresorcine
Trichloroethylene
(E)-1-((1,2-dichlorovinyl)oxy)-3-methoxybenzene
Conditions | Yield |
---|---|
Stage #1: O-methylresorcine With potassium hydride In tetrahydrofuran Inert atmosphere; Stage #2: Trichloroethylene In tetrahydrofuran at -50 - 20℃; Inert atmosphere; | 98% |
With sodium hydroxide In dimethyl sulfoxide at 30 - 60℃; | 97% |
With caesium carbonate In dimethyl sulfoxide at 20℃; for 1.5h; Inert atmosphere; | 93% |
Conditions | Yield |
---|---|
Stage #1: Trichloroethylene; salicylic alcohol With sodium hydroxide In dimethyl sulfoxide Stage #2: tert-butyldimethylsilyl chloride With 1H-imidazole In dichloromethane at 20℃; | 98% |
Conditions | Yield |
---|---|
With hydrogen fluoride; antimony pentafluoride at 100℃; for 1h; Temperature; Autoclave; | 97% |
With hydrogen fluoride; tantalum pentafluoride at 0 - 140℃; under 25858.1 Torr; for 10.5h; Product distribution / selectivity; Neat (no solvent); | 90% |
With hydrogen fluoride; tantalum pentafluoride at 100 - 140℃; under 25858.1 Torr; for 6h; | 80% |
N,N-Dichlorobenzenesulfonamide
Trichloroethylene
A
pentachloroethane
B
N-(2,2,2-trichloroethylidene)benzenesulfonamide
Conditions | Yield |
---|---|
at 85 - 90℃; Product distribution; Other temperatures, UV irradiation, presence of azoisobutyronitrile or benzoyl peroxide.; | A n/a B 97% |
at 85 - 90℃; Other temperatures, UV irradiation, presence of azoisobutyronitrile or benzoyl peroxide.; | A n/a B 97% |
N,N-Dichlorobenzenesulfonamide
Trichloroethylene
N-(2,2,2-trichloroethylidene)benzenesulfonamide
Conditions | Yield |
---|---|
at 87 - 89℃; for 8h; | 97% |
at 87 - 89℃; for 8h; Condensation; | 85% |
at 87 - 89℃; for 8h; | 85% |
p-cresol
Trichloroethylene
(E)-1-(1,2-dichlorovinyloxy)-4-methylbenzene
Conditions | Yield |
---|---|
Stage #1: p-cresol With potassium hydride In tetrahydrofuran Inert atmosphere; Stage #2: Trichloroethylene In tetrahydrofuran at -50 - 20℃; Inert atmosphere; | 97% |
With caesium carbonate In dimethyl sulfoxide at 20℃; for 1.5h; Inert atmosphere; | 82% |
With sodium hydroxide; benzyltripropylammonium chloride In cyclohexane for 2h; | 60% |
Conditions | Yield |
---|---|
With hydrogen; palladium/alumina In water at 20℃; under 760 Torr; pH=4 - 6.8; Kinetics; Product distribution; Further Variations:; Catalysts; Dehydrochlorination; | A 97% B n/a |
With iron In water pH=7; Kinetics; Further Variations:; pH-values; Electrochemical reaction; | A 25% B 75% |
With palladium-impregnated γ-alumina; hydrogen at 300℃; under 69.0069 Torr; for 3h; Reagent/catalyst; Inert atmosphere; | |
With Pd1.6Cu1 alloy nanoparticles on γ-alumina; hydrogen at 300℃; under 69.0069 Torr; for 3h; Reagent/catalyst; Inert atmosphere; | |
With hydrogen In water at 25℃; under 760.051 Torr; for 1.5h; Kinetics; Catalytic behavior; |
Conditions | Yield |
---|---|
Stage #1: N,N-Dichlorobenzenesulfonamide; Trichloroethylene at 87℃; for 9h; Stage #2: thiourea at 35℃; | 97% |
Trichloroethylene
4,4'-methylenebis(N,N-dichlorobenzenesulfonamide)
4,4'-methylenebis[N-(2,2,2-trichloroethylidene)benzenesulfonamide]
Conditions | Yield |
---|---|
for 9h; Heating; | 97% |
Trichloroethylene
meta-nitrophenol
(E)-3-(1,2-dichlorovinyloxy)nitrobenzene
Conditions | Yield |
---|---|
Stage #1: meta-nitrophenol With potassium hydride In tetrahydrofuran Inert atmosphere; Stage #2: Trichloroethylene In tetrahydrofuran at -50 - 20℃; Inert atmosphere; | 97% |
Trichloroethylene (CAS NO.79-01-6) was pioneered by Imperial Chemical Industries in Britain, Trichloroethylene's development was hailed as an anesthetic revolution.However,the introduction of halothane in 1956 greatly diminished the use of TCE as a general anesthetic. TCE was still used as an inhalation analgesic in childbirth given by self-administration.Nowadays, Groundwater contamination by TCE has become an important environmental concern.
The Trichloroethylene, with the cas registry number 79-01-6, is a kind of colorless oily liquid with the similar smell with chloroform. This chemical is slight soluble in water and completely soluble in common organic solvent and it is stable chemically while incompatible with oxidizing agents, aluminium, magnesium, strong bases, reducing agents. Besides, it is light-sensitive and then could react violently with many metals, ozone, potassium nitrate, potassium hydroxide, sodium hydroxide. In addition, its product categories are including refrigerants; Organics; Analytical Chemistry; Standard Solution of Volatile Organic Compounds for Water & Soil Analysis; Standard Solutions (VOC).
The physical properties of this chemical are as follows: (1)ACD/LogP: 2.26; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 2.26; (4)ACD/LogD (pH 7.4): 2.26; (5)ACD/BCF (pH 5.5): 30.61; (6)ACD/BCF (pH 7.4): 30.61; (7)ACD/KOC (pH 5.5): 402.89; (8)ACD/KOC (pH 7.4): 402.89; (9)Index of Refraction: 1.489; (10)Molar Refractivity: 25.76 cm3; (11)Molar Volume: 89.1 cm3; (12)Polarizability: 10.21 ×10-24 cm3; (13)Surface Tension: 31 dyne/cm; (14)Density: 1.474 g/cm3; (15)Flash Point: 12.1 °C; (16)Enthalpy of Vaporization: 31.4 kJ/mol; (17)Boiling Point: 87.2 °C at 760 mmHg; (18)Vapour Pressure: 72.4 mmHg at 25°C; (19)Exact Mass: 129.914383; (20)MonoIsotopic Mass: 129.914383; (21)Topological Polar Surface Area: 0; (22)Heavy Atom Count: 5; (23)Formal Charge: 0; (24)Complexity: 42.9.
Use of this chemical: Trichloroethylene could react to produce dichloroethyne, with the following condition: reagent: NaOH; reaction temp.: 260 °C.
As to its usage, it is widely applied in many ways. It could be used in producing indigo and other dye and also could make henchloroacetic acid; It could aslo be used as the metal detergent, dry cleaning agent, agricultural insecticide in the field of industrial solvent; Then it is usually used in many other ways, such as being the noninflammable solvent, analysis reagent, extracting solvent, and also in chemical cleaning, industrial degreasing, and chemical raw materials.
When you are dealing with this kind of chemical, you should be much more careful and then take some measures to protect yourself. For one thing, it is irritating to eyes and skin. For another thing, it is toxic which has the danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed. In addition, it is harmful to aquatic organisms which may cause long-term adverse effects in the aquatic environment. Then it has other hazard. It may cause cancer and will have possible risk of irreversible effects. Therefore, you should wear suitable protective clothing and gloves, and if in case of accident or if you feel unwell, seek medical advice immediately (show label where possible). And then avoid exposure - obtain special instruction before use. Lastly, do remember not to release to the environment, and you could refer to special instructions safety data sheet.
In addition, you could convert the following datas into the molecular structure:
(1)Canonical SMILES: C(=C(Cl)Cl)Cl
(2)InChI: InChI=1S/C2HCl3/c3-1-2(4)5/h1H
(3)InChIKey: XSTXAVWGXDQKEL-UHFFFAOYSA-N
Below are the toxicity information of this chemical:
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
cat | LCLo | inhalation | 32500mg/m3/2H (32500mg/m3) | PERIPHERAL NERVE AND SENSATION: SPASTIC PARALYSIS WITH OR WITHOUT SENSORY CHANGE BEHAVIORAL: GENERAL ANESTHETIC BEHAVIORAL: CHANGES IN MOTOR ACTIVITY (SPECIFIC ASSAY) | Archiv fuer Hygiene und Bakteriologie. Vol. 116, Pg. 131, 1936. |
cat | LDLo | oral | 5864mg/kg (5864mg/kg) | "Handbook of Toxicology," 4 vols., Philadelphia, W.B. Saunders Co., 1956-59Vol. 5, Pg. 76, 1959. | |
dog | LD50 | intraperitoneal | 1900mg/kg (1900mg/kg) | LIVER: LIVER FUNCTION TESTS IMPAIRED | Toxicology and Applied Pharmacology. Vol. 10, Pg. 119, 1967. |
dog | LDLo | intravenous | 150mg/kg (150mg/kg) | Quarterly Journal of Pharmacy & Pharmacology. Vol. 7, Pg. 205, 1934. | |
dog | LDLo | subcutaneous | 150mg/kg (150mg/kg) | "Handbook of Toxicology," 4 vols., Philadelphia, W.B. Saunders Co., 1956-59Vol. 5, Pg. 76, 1959. | |
guinea pig | LCLo | inhalation | 37200ppm/40M (37200ppm) | "Handbook of Toxicology," 4 vols., Philadelphia, W.B. Saunders Co., 1956-59Vol. 5, Pg. 76, 1959. | |
human | LDLo | oral | 7gm/kg (7000mg/kg) | Archives of Toxicology. Vol. 35, Pg. 295, 1976. | |
human | TCLo | inhalation | 160ppm/83M (160ppm) | BEHAVIORAL: "HALLUCINATIONS, DISTORTED PERCEPTIONS" | American Industrial Hygiene Association Journal. Vol. 23, Pg. 167, 1962. |
human | TCLo | inhalation | 500ppm/16.1Y- (500ppm) | KIDNEY, URETER, AND BLADDER: CHANGES IN BOTH TUBULES AND GLOMERULI KIDNEY, URETER, AND BLADDER: PROTEINURIS | Archives of Toxicology. Vol. 73, Pg. 246, 1999. |
human | TCLo | inhalation | 812mg/kg (812mg/kg) | BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) LIVER: "JAUNDICE, OTHER OR UNCLASSIFIED" GASTROINTESTINAL: OTHER CHANGES | British Medical Journal. Vol. 2, Pg. 689, 1945. |
human | TCLo | inhalation | 6900mg/m3/10M (6900mg/m3) | BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) BEHAVIORAL: "HALLUCINATIONS, DISTORTED PERCEPTIONS" | Archiv fuer Hygiene und Bakteriologie. Vol. 116, Pg. 131, 1936. |
man | LCLo | inhalation | 2900ppm (2900ppm) | New Zealand Medical Journal. Vol. 50, Pg. 119, 1951. | |
man | TCLo | inhalation | 110ppm/8H (110ppm) | SENSE ORGANS AND SPECIAL SENSES: OTHER: EYE BEHAVIORAL: "HALLUCINATIONS, DISTORTED PERCEPTIONS" | British Journal of Industrial Medicine. Vol. 28, Pg. 293, 1971. |
man | TDLo | oral | 1mL/kg (1mL/kg) | BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) BEHAVIORAL: TREMOR BEHAVIORAL: COMA | Toxicological Sciences. Vol. 41, Pg. 157, 1998. |
man | TDLo | oral | 2143mg/kg (2143mg/kg) | GASTROINTESTINAL: OTHER CHANGES | "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York, Academic Press, Inc., 1969Vol. -, Pg. 602, 1969. |
mouse | LC50 | inhalation | 8450ppm/4H (8450ppm) | Acta Pharmacologica et Toxicologica. Vol. 9, Pg. 303, 1953. | |
mouse | LD50 | intravenous | 33900ug/kg (33.9mg/kg) | "Summary Tables of Biological Tests," National Research Council Chemical-Biological Coordination Center. Vol. 6, Pg. 141, 1954. | |
mouse | LD50 | oral | 2402mg/kg (2402mg/kg) | BEHAVIORAL: ALTERED SLEEP TIME (INCLUDING CHANGE IN RIGHTING REFLEX) BEHAVIORAL: ATAXIA SKIN AND APPENDAGES (SKIN): HAIR: OTHER | National Technical Information Service. Vol. AD-A080-636, |
mouse | LD50 | subcutaneous | 16gm/kg (16000mg/kg) | BEHAVIORAL: SLEEP BEHAVIORAL: ATAXIA | Journal of Pharmacology and Experimental Therapeutics. Vol. 123, Pg. 224, 1958. |
rabbit | LCLo | inhalation | 11000ppm (11000ppm) | FAO Nutrition Meetings Report Series. Vol. 48A, Pg. 121, 1970. | |
rabbit | LD50 | skin | > 20gm/kg (20000mg/kg) | National Technical Information Service. Vol. AD-A062-138, | |
rabbit | LDLo | oral | 7330mg/kg (7330mg/kg) | "Handbook of Toxicology," 4 vols., Philadelphia, W.B. Saunders Co., 1956-59Vol. 5, Pg. 76, 1959. | |
rabbit | LDLo | subcutaneous | 1800mg/kg (1800mg/kg) | Quarterly Journal of Pharmacy & Pharmacology. Vol. 7, Pg. 205, 1934. | |
rat | LCLo | inhalation | 4800ppm/4H (4800ppm) | AMA Archives of Industrial Hygiene and Occupational Medicine. Vol. 4, Pg. 469, 1951. | |
rat | LD50 | intraperitoneal | 1282mg/kg (1282mg/kg) | Environmental Research. Vol. 40, Pg. 411, 1986. | |
rat | LD50 | oral | 4920mg/kg (4920mg/kg) | Industrial Health. Vol. 32, Pg. 145, 1994. | |
rat | LDLo | intratracheal | 150mg/kg (150mg/kg) | National Technical Information Service. Vol. OTS0520615, |
About|Contact|Cas|Product Name|Molecular|Country|Encyclopedia
Message|New Cas|MSDS|Service|Advertisement|CAS DataBase|Article Data|Manufacturers | Chemical Catalog
©2008 LookChem.com,License: ICP
NO.:Zhejiang16009103
complaints:service@lookchem.com Desktop View