In the present study, a series of 4-(1-aryl-5-chloro-2-oxo-1,2-dihydro-indol-3-ylideneamino)-N-substituted benzene sulfonamides (1–20) was synthesized and screened for their in vitro antimicrobial activity against Gram positive, Gram negative bacterial and fungal strains indicating that compoun...
The intermediate in the reaction catalysed by 4-chlorobenzoate dehalogenase from Pseudomonas sp. CBS3 was identified as 4-chlorobenzoyl-CoA. One component of 4-chlorobenzoate debalogenase worked as a a 4-chlorobenzoyl-CoA ligase catalysing the formation of 4-chlorobenzoyl-CoA from 4-chlorobenzoa...
Allosteric enhancers for the A1 adenosine receptor represent a novel and unique drug design strategy to augment the response to endogenous adenosine in a site- and event-specific manner. We have previously investigated a detailed structure–activity relationship study around a wide series of 2-a...
The structure of the N-4-chlorobenzoyl–N′-4-methoxylphenylthiourea (C15H13N2OClS, Mr=320.79) derived from X-ray diffraction on single crystal has been presented. The crystals are monoclinic, space group: P21/n (#14), a=12.125(2), b=6.3650(6), c=19.755(3) Å, β=76.800(6)°, V=1484.3(3) Å3, Z=4....
The preparation, spectroscopic and magnetic properties of ML2Cl2 (M=Cu(II), Mn(II), Ni(II)) and [ML3]Cl3 (M=Fe(III), Cr(III)), L=N-4-methoxyphenyl-N-4-chlorobenzoyl hydrazide are reported. In all the studied complexes the N-4-methoxyphenyl-N-4-chlorobenzoyl hydrazide acts as a neutral bidentate ...
The cis-[Ru(bpy)2(clbzpy)(Cl)](PF6) complex (I), where clbzpy = 4-(4-chlorobenzoyl)pyridine and bpy = 2,2′-bipyridine, was prepared and fully characterized. Blue light photolysis (453 nm) of this compound in aqueous solution led to release of clbzpy and formation of the cis-[Ru(bpy)2(H2O)Cl]+ i...
A new dianionic ligand, 1-(4-chlorobenzoyl)-3-[2-(2-{2-[3-(4-chlorobenzoyl)-thioureido]-ethoxy}ethoxy)ethyl]-thiourea(CBEDEA), and its Ni(II) and Cu(II) complexes have been synthesized. X-ray single crystal analysis of CBEDEA shows that the molecule crystallized in the triclinic crystal system, ...
The condensation reaction of biphenyl-4-carbonyl isothiocyanate/4-chlorobenzoyl isothiocyanate with diphenylamine yielded two new compounds; N-diphenyl-N'-(biphenyl-4-carbonyl) thiocarbamide (1) and N, N-diphenyl-N'-(4-chlorobenzoyl) thiocarbamide (2). Structure of the compounds were d...
This contribution describes the facile preparation of functional yolk–shell nanoparticles (YSNs) made up of different compositions confined within a hollow porous carbon shell ([email protected], M = multiple Cu, NiO nanoparticles or ZnO nanowires). These new yolk–shell hybrid materials have b...
Berberine hydrochloride (Brb) is a well-known herbal drug that holds a great promise in the recent years thanks to its various pharmacological actions. Currently, Brb is extensively researched as a natural surrogate with evidenced potentiality against numerous types of skin diseases including sk...
The efficient separation of pentlandite from serpentine remains a challenging issue in the processing of nickel sulfide ores. In this study, selective magnetic coating-magnetic separation was employed to separate the pentlandite from serpentine with adding NaOL as a coagulant, which is different...
The effect of calcium ions on the adsorption of sodium oleate on the mineral surfaces and flotation separation of cassiterite from quartz were studied in this work through micro-flotation tests, zeta potential measurements, solution chemistry calculation, surface adsorption experiments, and X-ra...
The effects of Pb(II) ions on the flotation of hemimorphite was investigated by micro-flotation tests, zeta-potential measurements, solution chemistry and Fourier transform infrared spectroscopy. The micro-flotation results indicated that the Pb(II) effectively improved the flotation of hemimorp...
The flotation of pyrochlore using two common oxide collectors, octyl hydroxamic acid (OHA) and sodium oleate (NaOl), was studied by microflotation tests on high purity pyrochlore sample and batch flotation tests on a pyrochlore ore sample. The high purity pyrochlore sample was screened into diff...
We report the successful fabrication of copper (II) oleate [Cu(C18H33O2)2, Cu-oleate] microspheres as novel targets for laser fusion. Cu-oleate microspheres were prepared using emulsion method with Cu-oleate dissolved in an organic solvent. The fabricated microspheres exhibit a uniform radius of...
The aim of the study is to explore the effect of nanobubbles on the adsorption capacity of surfactants on mineral surfaces. Firstly, nanobubbles were imaged under the condition that the solution had a dissolved oxygen difference (DOD) by atomic force microscope (AFM). Subsequently, the calcite p...
This paper proposed the surface modification of hemimorphite using lead ions as a promising method for increasing its flotation recovery with sodium oleate as collector. The floatability of lead-modified hemimorphite was significantly improved and the flotation recovery of hemimorphite in the pr...
Froth flotation plays a significant role in the beneficiation of rare earth elements (REE) minerals from differing ores. Monazite has been identified as one of the principal REE minerals in most iron oxide silicate rich tailings generated in Australia from the extraction of primary commodities s...
Synthetic efforts to overcome the metabolic oxidative degradation of the HIV protease inhibitory cyclic urea DMP323, a benzyl alcohol, have led to the discovery of a tertiary carbinol with superior affinity for the viral protease and more potent inhibitory activity against viral replication. Syn...
Various pyridylseleniums and their hydrochloride salts have been synthesized and evaluated for their antibacterial activities. SEM, TEM and enzyme profiling techniques have been used to investigate the mode of action of these compounds as antibiotics. Single crystal X-ray study of bis(3-bromo-2-...
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