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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

2-(methylthio)benzonitrile

Cas:6609-54-7

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

2-(Methylthio)-benzonitrile

Cas:6609-54-7

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

Benzonitrile,2-(methylthio)-

Cas:6609-54-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

2-(METHYLTHIO)BENZONITRILE CAS:6609-54-7 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic

2-(METHYLTHIO)BENZONITRILE CAS:6609-54-7

Cas:6609-54-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Benzonitrile,2-(methylthio)-

Cas:6609-54-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 2-(Methylthio)benzonitrile

Cas:6609-54-7

Min.Order:0 Metric Ton

Negotiable

Type:Other

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

2-(methylthio)benzonitrile Manufacturer in China

Cas:6609-54-7

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

6609-54-7 supplier in China

Cas:6609-54-7

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

6609-54-7 supplier in China

Cas:6609-54-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

6609-54-7 supplier in China

Cas:6609-54-7

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Suzhou Health Chemicals Co., Ltd.

High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use

6609-54-7

Cas:6609-54-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

6609-54-7 supplier in China

Cas:6609-54-7

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

Hebei Mojin Biotechnology Co.,Ltd

1, High quality with competitive price:2, Fast and safe delivery3.Excellent pre-sales and after-sales service4. Well-trained and professional technologist and sales with rich experience in the field for 5-10 yearsAppearance:see detailed specification

Benzonitrile,2-(methylthio)-

Cas:6609-54-7

Min.Order:0

Negotiable

Type:Trading Company

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:white crystalline powder Storage:Sealed in a cool ,dry and microtherm place , avoid light . Package:100g/bottle,1kg/bottle,25kg/drum or as per your request Application:It is an impo

6609-54-7 supplier in China

Cas:6609-54-7

Min.Order:100 Gram

Negotiable

Type:Trading Company

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

2-(METHYLTHIO)BENZONITRILE

Cas:6609-54-7

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM is one of China's leading providers of integrated fine chemical services including offering, research and development, Custom manufacturing business, as well as other Value-added customer services, for diversified range products of chemicals

2-(METHYLTHIO)BENZONITRILE

Cas:6609-54-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Henan Tianfu Chemical Co., Ltd.

1.Our services:A.Supply sampleB.The packing also can be according the customers` requirmentC.Any inquiries will be replied within 24 hoursD.we provide Commerical Invoice, Packing List, Bill of loading, COA , Health certificate and Origin certificate.

Benzonitrile,2-(methylthio)-

Cas:6609-54-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xian Changyue Biological Technology Co., Ltd.

best seller Application:API

2-(METHYLTHIO)BENZONITRILE

Cas:6609-54-7

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice.pls contact with us freely for getting detailed product spec

2-(METHYLTHIO)BENZONITRILE

Cas:6609-54-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Benzonitrile,2-(methylthio)-

Cas:6609-54-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hubei Langyou International Trading Co., Ltd

6609-54-7 supplier in China Application:6609-54-7 supplier in China

6609-54-7 supplier in China

Cas:6609-54-7

Min.Order:0

Negotiable

Type:Other

inquiry

DB BIOTECH CO., LTD

best seller Application:API

2-(METHYLTHIO)BENZONITRILE

Cas:6609-54-7

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

2-(METHYLTHIO)BENZONITRILE

Cas:6609-54-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

SAGECHEM LIMITED

6609-54-7 Application:intermediate

Benzonitrile, 2-(methylthio)-

Cas:6609-54-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers2. Produce products of different specifications and sizes according to your requirements.3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures sta

2-(METHYLTHIO)BENZONITRILE

Cas:6609-54-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hunan Longxianng Runhui Trading Co.,Ltd

6609-54-7 supplier in ChinaAppearance:white crystalline powder Storage:Sealed in a cool ,dry and microtherm place , avoid light . Package:100g/bottle,1kg/bottle,25kg/drum or as per your request Application:It is an important raw material and medical

6609-54-7 supplier in China

Cas:6609-54-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Chinqesen Biotechnology Co., Ltd.

Good Quality Package:1kg/bag Application:Medical or chemical Transportation:Air/Train/Sea Port:Shenzhen

6609-54-7

Cas:6609-54-7

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hebei Muhuang Technology Co., Ltd

best seller Application:API

2-(METHYLTHIO)BENZONITRILE

Cas:6609-54-7

Min.Order:0

Negotiable

Type:Trading Company

inquiry

ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

2-(METHYLTHIO)BENZONITRILE

Cas:6609-54-7

Min.Order:0

Negotiable

Type:Trading Company

inquiry

LEAP CHEM Co., Ltd.

Best Seller, High Quality, Competitive Price, Fast Delivery, Quick ResponseAppearance:powder, or liquid Storage:Stored in room temperature, ventilated place Package:Bottle, barrel, cargo, container, etc. Application:Pharmaceuticals, intermediates, AP

2-cyanophenyl methyl sulphide

Cas:6609-54-7

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

2-Chlorobenzonitrile
873-32-5

2-Chlorobenzonitrile

sodium thiomethoxide
5188-07-8

sodium thiomethoxide

2-cyanothioanisole
6609-54-7

2-cyanothioanisole

Conditions
ConditionsYield
With tetrabutylammomium bromide In water; chlorobenzene at 60 - 65℃; for 17h; Inert atmosphere;99%
With tetrabutylammomium bromide In water; chlorobenzene at 70 - 75℃; for 15h; Inert atmosphere;98%
2-fluorobenzonitrile
394-47-8

2-fluorobenzonitrile

sodium thiomethoxide
5188-07-8

sodium thiomethoxide

2-cyanothioanisole
6609-54-7

2-cyanothioanisole

Conditions
ConditionsYield
In acetonitrile at 60℃; Inert atmosphere;99%
[(Z)-Hydroxyimino]-(2-methylsulfanyl-phenyl)-acetic acid methyl ester

[(Z)-Hydroxyimino]-(2-methylsulfanyl-phenyl)-acetic acid methyl ester

2-cyanothioanisole
6609-54-7

2-cyanothioanisole

Conditions
ConditionsYield
With acetic anhydride In pyridine for 24h; Heating;83%
N-cyano-N-phenyl-p-toluenesulfonamide
55305-43-6

N-cyano-N-phenyl-p-toluenesulfonamide

2-bromo-1-(methylsulfanyl)benzene
19614-16-5

2-bromo-1-(methylsulfanyl)benzene

2-cyanothioanisole
6609-54-7

2-cyanothioanisole

Conditions
ConditionsYield
Stage #1: 2-bromo-1-(methylsulfanyl)benzene With magnesium; lithium chloride In tetrahydrofuran at 20℃; Inert atmosphere;
Stage #2: N-cyano-N-phenyl-p-toluenesulfonamide In tetrahydrofuran at 0 - 20℃; Inert atmosphere;
75%
sodium cyanide
773837-37-9

sodium cyanide

2-(methylthio)iodobenzene
33775-94-9

2-(methylthio)iodobenzene

2-cyanothioanisole
6609-54-7

2-cyanothioanisole

Conditions
ConditionsYield
With C18H14CuIN4 In acetonitrile at 20℃; for 24h; Inert atmosphere; Sealed tube; UV-irradiation;72%
Dimethyldisulphide
624-92-0

Dimethyldisulphide

1-(methylsulfonyl)-2-(2-cyanophenyl)diazene

1-(methylsulfonyl)-2-(2-cyanophenyl)diazene

2-cyanothioanisole
6609-54-7

2-cyanothioanisole

Conditions
ConditionsYield
In acetonitrile at 20℃; for 12h; UV-irradiation;72%
Dimethyldisulphide
624-92-0

Dimethyldisulphide

2-fluorobenzonitrile
394-47-8

2-fluorobenzonitrile

2-cyanothioanisole
6609-54-7

2-cyanothioanisole

Conditions
ConditionsYield
With potassium tert-butylate In acetonitrile at 50℃; for 6h; Sealed tube;63%
2-fluorobenzonitrile
394-47-8

2-fluorobenzonitrile

dimethyl sulfoxide
67-68-5

dimethyl sulfoxide

2-cyanothioanisole
6609-54-7

2-cyanothioanisole

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine In water at 189℃; for 24h;62%
2-chlorothioanisole
17733-22-1

2-chlorothioanisole

dicyanozinc
557-21-1

dicyanozinc

2-cyanothioanisole
6609-54-7

2-cyanothioanisole

Conditions
ConditionsYield
bis(tri-t-butylphosphine)palladium(0); zinc In N,N-dimethyl acetamide at 95℃; for 5h;56.1%
methyl magnesium iodide
917-64-6

methyl magnesium iodide

diethyl ether
60-29-7

diethyl ether

o-cyanophenyl thiocyanate
34263-66-6

o-cyanophenyl thiocyanate

2-cyanothioanisole
6609-54-7

2-cyanothioanisole

methyl magnesium iodide
917-64-6

methyl magnesium iodide

o-cyanophenyl thiocyanate
34263-66-6

o-cyanophenyl thiocyanate

2-cyanothioanisole
6609-54-7

2-cyanothioanisole

Conditions
ConditionsYield
With diethyl ether
o-cyanophenyl thiocyanate
34263-66-6

o-cyanophenyl thiocyanate

2-cyanothioanisole
6609-54-7

2-cyanothioanisole

Conditions
ConditionsYield
With potassium hydroxide; zinc nachfolgend Behandlung mit Dimethylsulfat;
2-methylsulfanyl-benzamide
54705-16-7

2-methylsulfanyl-benzamide

2-cyanothioanisole
6609-54-7

2-cyanothioanisole

Conditions
ConditionsYield
With diphosphorus pentasulfide; xylene
With phosphorus pentaoxide; xylene
2-(Methylthio)aniline
2987-53-3

2-(Methylthio)aniline

2-cyanothioanisole
6609-54-7

2-cyanothioanisole

Conditions
ConditionsYield
Diazotization.man setzt die Diazoniumsalzloesung bei 60-70grad mit Kaliumkupfercyanuer um;
2-cyanothiophenol
34761-11-0

2-cyanothiophenol

methyl iodide
74-88-4

methyl iodide

2-cyanothioanisole
6609-54-7

2-cyanothioanisole

benzo-[b]thiophene-2,3-dione
493-57-2

benzo-[b]thiophene-2,3-dione

2-cyanothioanisole
6609-54-7

2-cyanothioanisole

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: aq. sodium hydroxide (20percent) / 0.5 h
2: concentrated sulfuric acid / neat (no solvent) / 672 h
3: 90 percent / hydroxylamine hydrochloride / ethanol; pyridine / 4 h / Heating
4: 83 percent / acetic anhydride / pyridine / 24 h / Heating
View Scheme
(2-Methylsulfanyl-phenyl)-oxo-acetic acid

(2-Methylsulfanyl-phenyl)-oxo-acetic acid

2-cyanothioanisole
6609-54-7

2-cyanothioanisole

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: concentrated sulfuric acid / neat (no solvent) / 672 h
2: 90 percent / hydroxylamine hydrochloride / ethanol; pyridine / 4 h / Heating
3: 83 percent / acetic anhydride / pyridine / 24 h / Heating
View Scheme
methyl 2-(2-methylthiophenyl)-2-oxoacetate
117136-70-6

methyl 2-(2-methylthiophenyl)-2-oxoacetate

2-cyanothioanisole
6609-54-7

2-cyanothioanisole

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 90 percent / hydroxylamine hydrochloride / ethanol; pyridine / 4 h / Heating
2: 83 percent / acetic anhydride / pyridine / 24 h / Heating
View Scheme
o-cyanobromobenzene
2042-37-7

o-cyanobromobenzene

2-cyanothioanisole
6609-54-7

2-cyanothioanisole

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 15 percent / potassium tert-butoxide / liquid ammonia / 90 h / Irradiation
View Scheme
Multi-step reaction with 2 steps
1: 100 percent Spectr. / potassium tert-butoxide / liquid ammonia / 60 h / Irradiation
View Scheme
Multi-step reaction with 2 steps
1: 85 percent / potassium tert-butoxide / liquid ammonia / 2 h / Irradiation
View Scheme
methyl 2-nitrophenyl sulfide
3058-47-7

methyl 2-nitrophenyl sulfide

2-cyanothioanisole
6609-54-7

2-cyanothioanisole

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: zinc; concentrated hydrochloric acid
2: Diazotization.man setzt die Diazoniumsalzloesung bei 60-70grad mit Kaliumkupfercyanuer um
View Scheme
2-methylsulfanyl-benzoyl chloride
1442-03-1

2-methylsulfanyl-benzoyl chloride

2-cyanothioanisole
6609-54-7

2-cyanothioanisole

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: diethyl ether; ammonia
2: phosphorus pentoxide; xylene
View Scheme
2-(methylthio)benzoic acid
3724-10-5

2-(methylthio)benzoic acid

2-cyanothioanisole
6609-54-7

2-cyanothioanisole

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: thionyl chloride
2: diethyl ether; ammonia
3: phosphorus pentoxide; xylene
View Scheme
anthranilic acid nitrile
1885-29-6

anthranilic acid nitrile

2-cyanothioanisole
6609-54-7

2-cyanothioanisole

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: Diazotization.Eintragen der Diazoloesung in eine Suspension von Kupfer(I)-rhodanid in Kaliumrhodanid-Loesung
2: alcoholic KOH-solution; zinc dust / nachfolgend Behandlung mit Dimethylsulfat
View Scheme
Multi-step reaction with 2 steps
1: Diazotization.Eintragen der Diazoloesung in eine Suspension von Kupfer(I)-rhodanid in Kaliumrhodanid-Loesung
2: diethyl ether
View Scheme
2-Chlorobenzonitrile
873-32-5

2-Chlorobenzonitrile

methylthiol
74-93-1

methylthiol

chlorobenzene
108-90-7

chlorobenzene

2-cyanothioanisole
6609-54-7

2-cyanothioanisole

Conditions
ConditionsYield
With sodium hydroxide; tetrabutylammomium bromide; sodium In water
2-cyano-benzenediazonium tetrafluoroborate
55165-45-2

2-cyano-benzenediazonium tetrafluoroborate

2-cyanothioanisole
6609-54-7

2-cyanothioanisole

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: dichloromethane / 0 - 20 °C
2: acetonitrile / 12 h / 20 °C / UV-irradiation
View Scheme
methyl-phenyl-thioether
100-68-5

methyl-phenyl-thioether

phthalonitrile
91-15-6

phthalonitrile

A

2-cyanothioanisole
6609-54-7

2-cyanothioanisole

B

benzonitrile
100-47-0

benzonitrile

Conditions
ConditionsYield
With bis(1,5-cyclooctadiene)nickel (0); 1,2-bis-(dicyclohexylphosphino)ethane In o-xylene at 140℃; for 24h;A n/a
B 7 %Chromat.
2-cyanothioanisole
6609-54-7

2-cyanothioanisole

1,2-benzisothiazolin-3-one
2634-33-5

1,2-benzisothiazolin-3-one

Conditions
ConditionsYield
Stage #1: 2-cyanothioanisole With chlorine In water; chlorobenzene at 45 - 70℃; for 5h;
Stage #2: With water; sodium hydroxide In chlorobenzene at 65 - 70℃; Concentration; Time;
99%
Stage #1: 2-cyanothioanisole With hydrogenchloride; water; chlorine In chlorobenzene at 45 - 70℃; for 3h;
Stage #2: With water; sodium hydroxide In chlorobenzene at 65 - 70℃;
98%
Stage #1: 2-cyanothioanisole With chlorine In chlorobenzene at 40 - 80℃;
Stage #2: With sodium hydroxide In water at 60 - 70℃; pH=10 - 12;
Stage #3: With hydrogenchloride In water at 20 - 30℃; for 1h; pH=4 - 6;
90%
With hydrogenchloride; chlorine In water; chlorobenzene at 25 - 65℃; for 1.5h;90.8%
acetic acid tert-butyl ester
540-88-5

acetic acid tert-butyl ester

2-cyanothioanisole
6609-54-7

2-cyanothioanisole

N-tert-butyl-o-(methylthio)benzamide
79054-71-0

N-tert-butyl-o-(methylthio)benzamide

Conditions
ConditionsYield
With sulfuric acid at 42℃; for 6h;90%
2-cyanothioanisole
6609-54-7

2-cyanothioanisole

isopropyl alcohol
67-63-0

isopropyl alcohol

2-isopropoxybenzonitrile
90921-35-0

2-isopropoxybenzonitrile

Conditions
ConditionsYield
With potassium tert-butylate In 1,4-dioxane at 80℃; for 16h; Inert atmosphere; Glovebox;86%
(1S,2R,5S)-(+)-menthol
15356-60-2

(1S,2R,5S)-(+)-menthol

2-cyanothioanisole
6609-54-7

2-cyanothioanisole

2-(((1S,2R,5S)-2-isopropyl-5-methylcyclohexyl)oxy)benzonitrile

2-(((1S,2R,5S)-2-isopropyl-5-methylcyclohexyl)oxy)benzonitrile

Conditions
ConditionsYield
With potassium tert-butylate In 1,4-dioxane at 80℃; for 16h; Inert atmosphere; Glovebox;83%
2-cyanothioanisole
6609-54-7

2-cyanothioanisole

4-phenylcyclohexan-1-d-1-ol
109337-60-2

4-phenylcyclohexan-1-d-1-ol

2-((4-phenylcyclohexyl-1-d)oxy)benzonitrile

2-((4-phenylcyclohexyl-1-d)oxy)benzonitrile

Conditions
ConditionsYield
With potassium tert-butylate In 1,4-dioxane at 80℃; for 16h; Inert atmosphere; Glovebox; Sealed tube;81%
[bis(acetoxy)iodo]benzene
3240-34-4

[bis(acetoxy)iodo]benzene

2-cyanothioanisole
6609-54-7

2-cyanothioanisole

((2-cyanophenyl)thio)methyl acetate

((2-cyanophenyl)thio)methyl acetate

Conditions
ConditionsYield
With (triphenylphosphine)gold(I) chloride In 1,2-dichloro-ethane at 130℃; Schlenk technique;80%
cyclobutanemethanol
4415-82-1

cyclobutanemethanol

2-cyanothioanisole
6609-54-7

2-cyanothioanisole

2-(cyclobutylmethoxy)benzonitrile

2-(cyclobutylmethoxy)benzonitrile

Conditions
ConditionsYield
With potassium tert-butylate In 1,4-dioxane at 80℃; for 16h; Inert atmosphere; Glovebox;78%
n-Pent-4-enyl alcohol
821-09-0

n-Pent-4-enyl alcohol

2-cyanothioanisole
6609-54-7

2-cyanothioanisole

2-(pent-4-en-1-yloxy)benzonitrile

2-(pent-4-en-1-yloxy)benzonitrile

Conditions
ConditionsYield
With potassium tert-butylate In 1,4-dioxane at 80℃; for 16h; Inert atmosphere; Glovebox;77%
2-cyanothioanisole
6609-54-7

2-cyanothioanisole

benzylamine
100-46-9

benzylamine

N-benzyl-2-(methylthio)benzimidamide

N-benzyl-2-(methylthio)benzimidamide

Conditions
ConditionsYield
With bis(trimethylaluminum)–1,4-diazabicyclo[2.2.2]octane adduct In tetrahydrofuran at 130℃; for 0.2h; Microwave irradiation; Inert atmosphere; Sealed tube;76%
4-phenyl-butan-1-ol
3360-41-6

4-phenyl-butan-1-ol

2-cyanothioanisole
6609-54-7

2-cyanothioanisole

2-(4-phenylbutoxy)benzonitrile

2-(4-phenylbutoxy)benzonitrile

Conditions
ConditionsYield
With potassium tert-butylate In 1,4-dioxane at 80℃; for 16h; Inert atmosphere; Glovebox;75%
(2S)-2-methyl-1-butanol
1565-80-6

(2S)-2-methyl-1-butanol

2-cyanothioanisole
6609-54-7

2-cyanothioanisole

(S)-(+)-2-(2-methylbutyloxy)benzonitrile

(S)-(+)-2-(2-methylbutyloxy)benzonitrile

Conditions
ConditionsYield
With potassium tert-butylate In 1,4-dioxane at 80℃; for 16h; Inert atmosphere; Glovebox;71%
2-cyanothioanisole
6609-54-7

2-cyanothioanisole

ethyl acetoacetate
141-97-9

ethyl acetoacetate

ethyl (Z)-2-(amino(2-(methylthio)phenyl)methylene)-3-oxobutanoate

ethyl (Z)-2-(amino(2-(methylthio)phenyl)methylene)-3-oxobutanoate

Conditions
ConditionsYield
With titanium tetrachloride In toluene for 2h; Reflux;70.8%
(S)-valinol
2026-48-4

(S)-valinol

2-cyanothioanisole
6609-54-7

2-cyanothioanisole

(4S)-4-Isopropyl-2-<2-(methylsulfanyl)phenyl>-4,5-dihydro-1,3-oxazole
154132-42-0

(4S)-4-Isopropyl-2-<2-(methylsulfanyl)phenyl>-4,5-dihydro-1,3-oxazole

Conditions
ConditionsYield
zinc(II) chloride In chlorobenzene for 48h; Heating;69%
With zinc(II) chloride In chlorobenzene for 48h; Heating;56%
2-cyanothioanisole
6609-54-7

2-cyanothioanisole

N-Cyanoguanidine
127099-85-8, 780722-26-1

N-Cyanoguanidine

6-(2-(methylthio)phenyl)-1,3,5-triazine-2,4-diamine

6-(2-(methylthio)phenyl)-1,3,5-triazine-2,4-diamine

Conditions
ConditionsYield
With potassium hydroxide In 2-ethoxy-ethanol at 130 - 135℃; for 10h;68%
(S)-Alaninol
2749-11-3

(S)-Alaninol

2-cyanothioanisole
6609-54-7

2-cyanothioanisole

(4S)-2-((2-methylthio)phenyl)-4-methyl-1,3-oxazoline

(4S)-2-((2-methylthio)phenyl)-4-methyl-1,3-oxazoline

Conditions
ConditionsYield
With zinc(II) chloride In chlorobenzene for 48h; Heating;60%
zinc(II) chloride In chlorobenzene for 48h; Heating;60%
2-cyanothioanisole
6609-54-7

2-cyanothioanisole

(2S)-2-phenylglycinol
20989-17-7

(2S)-2-phenylglycinol

(4S)-2-[2-(methylsulfanyl)phenyl]-4-phenyl-4,5-dihydro-1,3-oxazole
154132-43-1

(4S)-2-[2-(methylsulfanyl)phenyl]-4-phenyl-4,5-dihydro-1,3-oxazole

Conditions
ConditionsYield
With zinc(II) chloride In chlorobenzene for 48h; Heating;58%
zinc(II) chloride In chlorobenzene for 48h; Heating;58%
2-cyanothioanisole
6609-54-7

2-cyanothioanisole

(1S,2S)-2-amino-1-phenyl-1,3-diol
28143-91-1

(1S,2S)-2-amino-1-phenyl-1,3-diol

[(4S,5S)-2-(2-Methylsulfanyl-phenyl)-5-phenyl-4,5-dihydro-oxazol-4-yl]-methanol
160246-26-4

[(4S,5S)-2-(2-Methylsulfanyl-phenyl)-5-phenyl-4,5-dihydro-oxazol-4-yl]-methanol

Conditions
ConditionsYield
With potassium carbonate In ethylene glycol; glycerol at 110℃; for 17h;55%
With potassium carbonate In ethylene glycol; glycerol at 115℃; for 18h;47%
2-cyanothioanisole
6609-54-7

2-cyanothioanisole

5-bromo-2-fluorobenzonitrile
391200-05-8

5-bromo-2-fluorobenzonitrile

Conditions
ConditionsYield
With N-Bromosuccinimide; tetrafluoroboric acid dimethyl ether complex In acetonitrile55%
2-cyanothioanisole
6609-54-7

2-cyanothioanisole

(S)-tert-leucinol
112245-13-3

(S)-tert-leucinol

(4S)-4-tert-butyl-2-((2-methylthio)phenyl)-1,3-oxazoline

(4S)-4-tert-butyl-2-((2-methylthio)phenyl)-1,3-oxazoline

Conditions
ConditionsYield
With zinc(II) chloride In chlorobenzene for 48h; Heating;53%
zinc(II) chloride In chlorobenzene for 48h; Heating;53%
4-hexyn-1-ol
928-93-8

4-hexyn-1-ol

2-cyanothioanisole
6609-54-7

2-cyanothioanisole

2-(hex-4-yn-1-yloxy)benzonitrile

2-(hex-4-yn-1-yloxy)benzonitrile

Conditions
ConditionsYield
With potassium tert-butylate In 1,4-dioxane at 80℃; for 16h; Inert atmosphere; Glovebox;50%
2-cyanothioanisole
6609-54-7

2-cyanothioanisole

L-Phenylalaninol
3182-95-4

L-Phenylalaninol

(4S)-4-benzyl-2-((2-methylthio)phenyl)-1,3-oxazoline

(4S)-4-benzyl-2-((2-methylthio)phenyl)-1,3-oxazoline

Conditions
ConditionsYield
With zinc(II) chloride In chlorobenzene for 48h; Heating;42%
zinc(II) chloride In chlorobenzene for 48h; Heating;42%

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