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Shanghai Pinewood Fine Chemical Co., Ltd.

Appearance:YELLOW TO SLIGHT YELLOW CRYSTALLINE POWDER Application:Zuclopenthixol

2-Chlorothioxanthone

Cas:86-39-5

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

2-Chlorothioxanthone

Cas:86-39-5

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 2-Chloro Thioxanthen-9-One supplier in China

Cas:86-39-5

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 2-chlorothioxanthen-9-one

Cas:86-39-5

Min.Order:1

Negotiable

Type:Other

inquiry

Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new ap

2-Chlorothioxanthone

Cas:86-39-5

Min.Order:1 Kilogram

FOB Price: $5.0

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

2-Chlorothioxanthone

Cas:86-39-5

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

2-Chlorothioxanthone Basic information Product Name: 2-Chlorothioxanthone Synonyms: 2-chloro-9h-thioxanthen-9-on;2-chloro-9H-Thioxanthen-9-one;KayacureCTX;NissoCureCTX;QuantacureCTX;Sand

86-39-5

Cas:86-39-5

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. High quality and competitive price: 1) Standard: BP/USP/EP/ enterprise standard 2) All purity ≥99% 3) We are manufacturers and can provide high quality products at factory prices. 2. Fast and safe delivery 1) The package c

2-Chlorothioxanthone CAS: 86-39-5

Cas:86-39-5

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Factory direct supply CAS 86-39-5 with best quality

Cas:86-39-5

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Henan Sinotech Import&Export Corporation

Product name: 2-Chlorothioxanthone CAS No.: 86-39-5 Molecular formula C13H7ClOS Appearance: light yellow crystalline powder Melting point: ≥151℃

2-Chlorothioxanthone

Cas:86-39-5

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

2-Chlorothioxanthone 86-39-5

Cas:86-39-5

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

2-Chlorothioxanthone 99%

Cas:86-39-5

Min.Order:1 Kilogram

FOB Price: $76.0 / 85.0

Type:Trading Company

inquiry

Qingdao Beluga Import and Export Co., LTD

2-Chlorothioxanthone CAS:86-39-5 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic interme

2-Chlorothioxanthone CAS:86-39-5

Cas:86-39-5

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

2-Chlorothioxanthone

Cas:86-39-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We have s

2-Chlorothioxanthone

Cas:86-39-5

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

2-Chlorothioxanthone

Cas:86-39-5

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

2-CHLOROTHIOXANTHEN-9-ONE

Cas:86-39-5

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

2-Chlorothioxanthone

Cas:86-39-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

2-Chlorothioxanthone

Cas:86-39-5

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality 2-Chloro Thioxanthen-9-One

Cas:86-39-5

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Hangzhou Lingrui Chemical Co.,Ltd.

2-ChlorothioxanthoneAppearance:Beige powder Storage:keep in dry and ventilated place Package:according to customers' requirements Application:intermediates Transportation:By air(EMS or EUB or FedEx or TNT ect...) or by sea(FOB or CIF or CNF ect...)or

2-Chlorothioxanthone

Cas:86-39-5

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

supplier in China Appearance:Beige powder Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package: 1g/bag, 5g/bag, 10g/bag, 100g/bag, 1kg/bag or as per your request Application:Used as a drug chloride thiamethoxam ton

2-Chlorothioxanthone-

Cas:86-39-5

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

2-Chlorothioxanthone

Cas:86-39-5

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

2-Chlorothioxanthone

Cas:86-39-5

Min.Order:1 Milligram

Negotiable

Type:Trading Company

inquiry

Shanghai Minstar Chemical Co., Ltd

2-Chlorothioxanthone Basic information Product Name: 2-Chlorothioxanthone Synonyms: 2-chloro-9h-thioxanthen-9-on;2-chloro-9H-Thioxanthen-9-one;2-Chlorothoxanthone;2-CHLOROTHIAXANTHONE;2-CHLOROTHIOXANTHEN-9-ONE;2-CHLOROTHIOXANTHENE-9-ONE;2-CHLO

2-Chlorothioxanthone

Cas:86-39-5

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

2-Chlorothioxanthone

Cas:86-39-5

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Siwei Development Group Ltd.

Product name: 2-Chlorothioxanthen-9-one CAS No,: 86-39-5 Molecule Formula:C13H7ClOS Molecule Weight:246.71 Purity: 99.0% Package: 25kg/drum Description:Ginger yellow powder Manufacture Standards:Enterprise Standard

Best Quality 2-Chlorothioxanthen-9-one

Cas:86-39-5

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Hangzhou Huarong Pharm Co., Ltd.

We Huarong Pharm can provide Customized Synthesis & Process R&D & APIs and intermediates Production & Quality Research & Registration Application, especially our GMP validation service which complies with SFDA, FDA, WHO and EU EMPA. O

2-Chlorothioxanthone

Cas:86-39-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

2-Chlorothioxanthone

Cas:86-39-5

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

2-Chlorothioxanthone

Cas:86-39-5

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Synthetic route

2-chloro-9H-thioxanthene
92-38-6

2-chloro-9H-thioxanthene

2-Chlorothioxanthone
86-39-5

2-Chlorothioxanthone

Conditions
ConditionsYield
With tert.-butylnitrite; oxygen; acetic acid; 2,3-dicyano-5,6-dichloro-p-benzoquinone In 1,2-dichloro-ethane at 20℃; for 12h; Irradiation;98%
With potassium hexafluorophosphate; iron(III) nitrate monohydrate; oxygen In acetonitrile at 80℃; for 12h; Reagent/catalyst; Temperature; Concentration;96%
In 1,2-dichloro-ethane at 20℃; for 4h; UV-irradiation;70%
With air In 1,2-dichloro-ethane at 20℃; for 4h; UV-irradiation;70%
With tert.-butylnitrite; oxygen; acetic acid; 2,3-dicyano-5,6-dichloro-p-benzoquinone In 1,2-dichloro-ethane at 20℃; for 12h; Sealed tube; Irradiation;
(2-bromo-5-chlorophenyl)(2-fluorophenyl)methanone
1449571-63-4

(2-bromo-5-chlorophenyl)(2-fluorophenyl)methanone

2-Chlorothioxanthone
86-39-5

2-Chlorothioxanthone

Conditions
ConditionsYield
With sodiumsulfide nonahydrate In N,N-dimethyl-formamide at 60℃;95%
2-carboxyphenyl 4-chlorophenyl sulphide
6469-85-8

2-carboxyphenyl 4-chlorophenyl sulphide

2-Chlorothioxanthone
86-39-5

2-Chlorothioxanthone

Conditions
ConditionsYield
With sulfuric acid at 60℃; for 3h; Temperature;89.3%
With sulfuric acid Reflux;68%
With sulfuric acid
With sulfuric acid
With sulfuric acid at 100℃; for 12h; Inert atmosphere;8.1mg
Chlorprothixen
4695-61-8

Chlorprothixen

2-Chlorothioxanthone
86-39-5

2-Chlorothioxanthone

Conditions
ConditionsYield
With 1-hydroxy-pyrrolidine-2,5-dione; graphitic carbon nitride; oxygen In acetonitrile at 20℃; Inert atmosphere; Irradiation;62%
9-bromo-2-chloro-9-(1-hydroxy-3-dimethylaminopropyl)thioxanthene
77625-54-8

9-bromo-2-chloro-9-(1-hydroxy-3-dimethylaminopropyl)thioxanthene

A

2-Chlorothioxanthone
86-39-5

2-Chlorothioxanthone

B

1-(2-Chloro-9H-thioxanthen-9-yl)-3-dimethylamino-propan-1-one; hydrobromide
77602-78-9

1-(2-Chloro-9H-thioxanthen-9-yl)-3-dimethylamino-propan-1-one; hydrobromide

C

9-amino-2-chloro-9-(1-hydroxy-3-dimethylaminopropyl)thioxanthene dihydrochloride
77602-80-3

9-amino-2-chloro-9-(1-hydroxy-3-dimethylaminopropyl)thioxanthene dihydrochloride

D

Chlorprothixen
4695-61-8

Chlorprothixen

Conditions
ConditionsYield
at 130℃; for 2h;A 30 mg
B 36%
C 0.66 g
D 0.26 g
2-<5-Chloro-2-(2-fluorophenylthio)phenyl>-5-dimethylaminopentan-2-ol
83986-08-7

2-<5-Chloro-2-(2-fluorophenylthio)phenyl>-5-dimethylaminopentan-2-ol

A

2-Chlorothioxanthone
86-39-5

2-Chlorothioxanthone

B

8-Chloro-6-methyl-6-(3-dimethylaminopropyl)-6H-dibenz-1,4-oxathiepin
83986-07-6

8-Chloro-6-methyl-6-(3-dimethylaminopropyl)-6H-dibenz-1,4-oxathiepin

Conditions
ConditionsYield
With sodium hydride In N,N-dimethyl-formamide at 70℃; for 8h;A 0.17 g
B 35%
5-Chloro-2-(2-fluorophenylthio)acetophenone
73129-22-3

5-Chloro-2-(2-fluorophenylthio)acetophenone

2-Chlorothioxanthone
86-39-5

2-Chlorothioxanthone

Conditions
ConditionsYield
With sodium hydride In N,N-dimethyl-formamide at 70℃; for 8h;12%
Multi-step reaction with 2 steps
1: 1) Mg / 1) THF, reflux, 3 h; 2) THF, reflux, 3 h
2: 1.88 g / NaH / dimethylformamide / 8 h / 70 °C
View Scheme
Multi-step reaction with 2 steps
1: 1) Mg / 1) THF, reflux, 2 h; 2) THF, reflux, 4 h
2: 0.17 g / NaH / dimethylformamide / 8 h / 70 °C
View Scheme
1-[5-Chloro-2-(2-fluoro-phenylsulfanyl)-phenyl]-1-(1-methyl-piperidin-4-yl)-ethanol
83986-13-4

1-[5-Chloro-2-(2-fluoro-phenylsulfanyl)-phenyl]-1-(1-methyl-piperidin-4-yl)-ethanol

A

2-Chlorothioxanthone
86-39-5

2-Chlorothioxanthone

B

8-Chloro-6-methyl-6-(1-methyl-4-piperidyl)-6H-dibenz-1,4-oxathiepin
83986-12-3

8-Chloro-6-methyl-6-(1-methyl-4-piperidyl)-6H-dibenz-1,4-oxathiepin

Conditions
ConditionsYield
With sodium hydride In N,N-dimethyl-formamide at 70℃; for 8h;A 1.88 g
B 8%
2-amino-9H-thioxanthen-9-one
33923-98-7

2-amino-9H-thioxanthen-9-one

2-Chlorothioxanthone
86-39-5

2-Chlorothioxanthone

Conditions
ConditionsYield
ueber die Diazonium-Verbindung;
3-(Dimethylamino)propyl chloride
109-54-6

3-(Dimethylamino)propyl chloride

A

2-Chlorothioxanthone
86-39-5

2-Chlorothioxanthone

B

Dihydrochlorprothixene
28178-78-1

Dihydrochlorprothixene

Conditions
ConditionsYield
With hydrogenchloride; methanol; alkaline aqueous potassium borate solution Vor der Umsetzung mit <3-Chlor-propyl>-dimethyl-amin unter Stickstoff wurde das Reaktionsprodukt mit Butyllithium in Aether behandelt;
Thiosalicylic acid
147-93-3

Thiosalicylic acid

chlorobenzene
108-90-7

chlorobenzene

2-Chlorothioxanthone
86-39-5

2-Chlorothioxanthone

Conditions
ConditionsYield
With sulfuric acid
With sulfuric acid at 75℃; for 2h;
With sulfuric acid at 75℃; for 2h;
With sulfuric acid at 75℃; for 2h;
With sulfuric acid at 75℃; for 2h;
chlorprothixene
4546-35-4

chlorprothixene

2-Chlorothioxanthone
86-39-5

2-Chlorothioxanthone

Conditions
ConditionsYield
With potassium permanganate; 18-crown-6 ether In benzene
2-methyl-1,2,3,4,10,14b-hexahydrodibenzo[c,f]pyrazino[1,2-a]azepine hydrochloride
1229-38-5

2-methyl-1,2,3,4,10,14b-hexahydrodibenzo[c,f]pyrazino[1,2-a]azepine hydrochloride

2-Chlorothioxanthone
86-39-5

2-Chlorothioxanthone

Conditions
ConditionsYield
With potassium permanganate In water
chlorprothixene
4546-35-4

chlorprothixene

A

2-Chlorothioxanthone
86-39-5

2-Chlorothioxanthone

B

other degradation products

other degradation products

Conditions
ConditionsYield
In methanol at 22℃; for 480h; Product distribution; Irradiation; degradation, various conditions;A 32 % Chromat.
B n/a
2-Iodobenzoic acid
88-67-5

2-Iodobenzoic acid

2-Chlorothioxanthone
86-39-5

2-Chlorothioxanthone

Conditions
ConditionsYield
Multi-step reaction with 2 steps
2: H2SO4
View Scheme
Multi-step reaction with 2 steps
1: potassium hydroxide; copper / water / 12 h / Reflux
2: sulfuric acid / Reflux
View Scheme
p-Chlorothiophenol
106-54-7

p-Chlorothiophenol

2-Chlorothioxanthone
86-39-5

2-Chlorothioxanthone

Conditions
ConditionsYield
Multi-step reaction with 2 steps
2: H2SO4
View Scheme
Multi-step reaction with 2 steps
1: potassium hydroxide; copper / water / 12 h / Reflux
2: sulfuric acid / Reflux
View Scheme
2-chlorosulfenylbenzoyl chloride
3950-02-5

2-chlorosulfenylbenzoyl chloride

chlorobenzene
108-90-7

chlorobenzene

A

4-chlorothioxanthen-9-one
21908-85-0

4-chlorothioxanthen-9-one

B

2-Chlorothioxanthone
86-39-5

2-Chlorothioxanthone

Conditions
ConditionsYield
aluminum (III) chloride In 1,2-dichloro-ethane at 40 - 45℃; for 1h; Friedel Crafts Acylation;
benzoic acid methyl ester
93-58-3

benzoic acid methyl ester

2-Chlorothioxanthone
86-39-5

2-Chlorothioxanthone

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: (1,5-cyclooctadiene)(methoxy)iridium(I) dimer / hexane / 14 h / 20 °C / Inert atmosphere
2: copper(II) sulfate; sodium hydrogencarbonate / methanol / 24 h / 20 °C / Inert atmosphere
3: potassium hydroxide; water / methanol / 1 h / 80 °C / Inert atmosphere
4: sulfuric acid / 12 h / 100 °C / Inert atmosphere
View Scheme
4-chlorophenyl 2-methoxycarbonylphenyl sulfide
22096-70-4

4-chlorophenyl 2-methoxycarbonylphenyl sulfide

2-Chlorothioxanthone
86-39-5

2-Chlorothioxanthone

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: potassium hydroxide; water / methanol / 1 h / 80 °C / Inert atmosphere
2: sulfuric acid / 12 h / 100 °C / Inert atmosphere
View Scheme
4,4'-dichlorophenyl thiosulfonate
1146-44-7

4,4'-dichlorophenyl thiosulfonate

2-Chlorothioxanthone
86-39-5

2-Chlorothioxanthone

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: copper(II) sulfate; sodium hydrogencarbonate / methanol / 24 h / 20 °C / Inert atmosphere
2: potassium hydroxide; water / methanol / 1 h / 80 °C / Inert atmosphere
3: sulfuric acid / 12 h / 100 °C / Inert atmosphere
View Scheme
4,4'-dichlorodiphenyl disulfide
1142-19-4

4,4'-dichlorodiphenyl disulfide

2-Chlorothioxanthone
86-39-5

2-Chlorothioxanthone

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: acetic acid; dihydrogen peroxide / water / 50 h / 0 - 20 °C / Inert atmosphere
2: copper(II) sulfate; sodium hydrogencarbonate / methanol / 24 h / 20 °C / Inert atmosphere
3: potassium hydroxide; water / methanol / 1 h / 80 °C / Inert atmosphere
4: sulfuric acid / 12 h / 100 °C / Inert atmosphere
View Scheme
2-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)benzoic acid methyl ester
653589-95-8

2-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)benzoic acid methyl ester

2-Chlorothioxanthone
86-39-5

2-Chlorothioxanthone

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: copper(II) sulfate; sodium hydrogencarbonate / methanol / 24 h / 20 °C / Inert atmosphere
2: potassium hydroxide; water / methanol / 1 h / 80 °C / Inert atmosphere
3: sulfuric acid / 12 h / 100 °C / Inert atmosphere
View Scheme
para-dichlorobenzene
106-46-7

para-dichlorobenzene

2-Chlorothioxanthone
86-39-5

2-Chlorothioxanthone

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: hydrogen sulfide / 300 °C / Flow reactor
2: lithium hydroxide monohydrate; sodium hydroxide / toluene / 12 h / 120 °C
3: sulfuric acid / 3 h / 60 °C
View Scheme
2-Chlorothioxanthone
86-39-5

2-Chlorothioxanthone

benzoic acid
65-85-0

benzoic acid

Conditions
ConditionsYield
In toluene at 25℃; for 42h; Large scale;99%
2-Chlorothioxanthone
86-39-5

2-Chlorothioxanthone

tri(allyl)phenylsilane
2633-57-0

tri(allyl)phenylsilane

2-phenylthioxanthen-9-one

2-phenylthioxanthen-9-one

Conditions
ConditionsYield
Stage #1: triallyl(phenyl)silane With tetrabutyl ammonium fluoride In tetrahydrofuran; water at 20℃; for 1h;
Stage #2: 2-Chlorothioxanthone With XPhos; bis(η3-allyl-μ-chloropalladium(II)) In tetrahydrofuran; water at 80℃; for 12h;
98%
2-Chlorothioxanthone
86-39-5

2-Chlorothioxanthone

2-hydroxy thioxanthone
31696-67-0

2-hydroxy thioxanthone

Conditions
ConditionsYield
With t-BuBrettPhos; C44H62NO5PPdS; water; potassium hydroxide In 1,4-dioxane at 80℃; for 18h; Inert atmosphere;98%
With tris-(dibenzylideneacetone)dipalladium(0); C39H57O3P; potassium hydroxide In 1,4-dioxane at 80℃;98%
With tris-(dibenzylideneacetone)dipalladium(0); potassium hydroxide; tert-butyl XPhos In 1,4-dioxane; water at 100℃; for 16h; Schlenk technique; Inert atmosphere; Reflux;85%
With copper acetylacetonate; N1-(4-hydroxy-2,6-dimethylphenyl)-N2-(4-hydroxy-3,5-dimethylphenyl)oxalamide; water In water; dimethyl sulfoxide at 130℃; for 24h; Schlenk technique; Inert atmosphere;76%
With tris-(dibenzylideneacetone)dipalladium(0); potassium hydroxide; tert-butyl XPhos In 1,4-dioxane; water at 100℃; for 16h; Inert atmosphere;
2-Chlorothioxanthone
86-39-5

2-Chlorothioxanthone

phenylboronic acid
98-80-6

phenylboronic acid

2-phenylthioxanthen-9-one

2-phenylthioxanthen-9-one

Conditions
ConditionsYield
With 4,4'-(phenylphosphinediyl)bis(2,6-dimethylmorpholine); caesium carbonate; tris(dibenzylideneacetone)dipalladium (0) In 1,4-dioxane for 8h; Suzuki-Miyaura coupling; Heating;95%
2-Chlorothioxanthone
86-39-5

2-Chlorothioxanthone

d(4)-methanol
811-98-3

d(4)-methanol

2-trideuteriomethoxy-9H-thioxanthen-9-one
1448366-57-1

2-trideuteriomethoxy-9H-thioxanthen-9-one

Conditions
ConditionsYield
With t-BuBrettPhos; [(2-di-tert-butylphosphino-3,6-dimethoxy-2’,4’,6’-triisopropyl-1,1’-biphenyl)-2-(2’-amino-1,1‘-biphenyl)]palladium(II) methanesulfonate; sodium t-butanolate In 1,4-dioxane at 20℃; for 20h; Sealed tube; Inert atmosphere;94%
2-Chlorothioxanthone
86-39-5

2-Chlorothioxanthone

2-chloro-9H-thioxanthene
92-38-6

2-chloro-9H-thioxanthene

Conditions
ConditionsYield
With dimethylsulfide borane complex In tetrahydrofuran for 2h; Reflux;93%
With borane In tetrahydrofuran 1) 0 - 5 deg C, 0.5 h, 2) 1 h, rt;90%
2-Chlorothioxanthone
86-39-5

2-Chlorothioxanthone

tert-butylamine
75-64-9

tert-butylamine

7-(tert-butylamino)-4aH-thioxanthen-9(9aH)-one

7-(tert-butylamino)-4aH-thioxanthen-9(9aH)-one

Conditions
ConditionsYield
With C26H33N2P; C39H46N3O3PPdS; sodium t-butanolate In 1,4-dioxane at 80℃; for 12h; Inert atmosphere;93%
2-Chlorothioxanthone
86-39-5

2-Chlorothioxanthone

acetone
67-64-1

acetone

2-(2-oxopropyl)-9H-thioxanthen-9-one

2-(2-oxopropyl)-9H-thioxanthen-9-one

Conditions
ConditionsYield
With potassium phosphate; 2-(2,6-dimethoxyphenyl)-1-methyl-3-(diphenylphosphino)-1H-indole; palladium diacetate at 90℃; for 18h; Inert atmosphere; Schlenk technique;88%
With bis[chloro(1,2,3-trihapto-allylbenzene)palladium(II)]; 2-methoxy-6-(N-methyl-N-phenyl-amino)phenyl(dicyclohexyl)phosphine; caesium carbonate at 90℃; for 16h; Inert atmosphere; Schlenk technique; Sealed tube;87%
2-Chlorothioxanthone
86-39-5

2-Chlorothioxanthone

Chloroiodomethane
593-71-5

Chloroiodomethane

2-chloro-9-(chloromethyl)-9H-thioxanthene

2-chloro-9-(chloromethyl)-9H-thioxanthene

Conditions
ConditionsYield
Stage #1: 2-Chlorothioxanthone; Chloroiodomethane With methyllithium lithium bromide In tetrahydrofuran at -78℃; for 0.75h; Inert atmosphere;
Stage #2: With hexylsilane; tris(pentafluorophenyl)borate In dichloromethane at 20℃; for 1h; Inert atmosphere; chemoselective reaction;
87%
3,5,5-Trimethylcyclohex-2-en-1-one
78-59-1

3,5,5-Trimethylcyclohex-2-en-1-one

2-Chlorothioxanthone
86-39-5

2-Chlorothioxanthone

2-((5,5-dimethyl-3-oxocyclohex-1-en-1-yl)methyl)-9H-thioxanthen-9-one

2-((5,5-dimethyl-3-oxocyclohex-1-en-1-yl)methyl)-9H-thioxanthen-9-one

Conditions
ConditionsYield
With 2-(2,6-dimethoxyphenyl)-1-methyl-3-(diphenylphosphino)-1H-indole; palladium diacetate; lithium tert-butoxide In 1,4-dioxane at 100℃; for 1h; Schlenk technique; Inert atmosphere;87%
2-Chlorothioxanthone
86-39-5

2-Chlorothioxanthone

C28H40AgF2N2

C28H40AgF2N2

2-(difluoromethyl)-9H-thioxanthen-9-one

2-(difluoromethyl)-9H-thioxanthen-9-one

Conditions
ConditionsYield
With (2-dicyclohexylphosphino-2’,4’,6’-triisopropyl-1,1'-biphenyl)[2-(2-amino-1,1’-biphenyl)]palladium(II)methanesulfonate; XPhos In toluene at 100℃; Inert atmosphere; Schlenk technique;86%
bromobenzene
108-86-1

bromobenzene

2-Chlorothioxanthone
86-39-5

2-Chlorothioxanthone

2-chloro-9-phenylthioxanthenol
476331-76-7

2-chloro-9-phenylthioxanthenol

Conditions
ConditionsYield
Stage #1: bromobenzene With magnesium; ethylene dibromide In tetrahydrofuran Heating;
Stage #2: 2-Chlorothioxanthone In tetrahydrofuran for 0.5h; Grignard reaction; Further stages.;
83%
2-Chlorothioxanthone
86-39-5

2-Chlorothioxanthone

N-Methyl-N-phenethylamine
589-08-2

N-Methyl-N-phenethylamine

2-(methyl(phenethyl)amino)-9H-thioxanthen-9-one
1501945-26-1

2-(methyl(phenethyl)amino)-9H-thioxanthen-9-one

Conditions
ConditionsYield
With 1,1'-bis-(diphenylphosphino)ferrocene; cis-[1,1'-bis(diphenylphosphino)ferrocene](2-methylphenyl)nickel(II) chloride; acetonitrile; lithium tert-butoxide at 100℃; for 1h; Inert atmosphere;83%
2-Chlorothioxanthone
86-39-5

2-Chlorothioxanthone

2-Bromobiphenyl
2052-07-5

2-Bromobiphenyl

C25H17ClOS

C25H17ClOS

Conditions
ConditionsYield
Stage #1: 2-Bromobiphenyl With n-butyllithium In tetrahydrofuran at -78℃; for 0.5h; Inert atmosphere;
Stage #2: 2-Chlorothioxanthone In tetrahydrofuran at -78 - 20℃; Inert atmosphere;
83%
2-Chlorothioxanthone
86-39-5

2-Chlorothioxanthone

tetramethylammonium trifluoromethylselenate(0)
75264-92-5

tetramethylammonium trifluoromethylselenate(0)

2-((trifluoromethyl)selanyl)-9H-thioxanthen-9-one

2-((trifluoromethyl)selanyl)-9H-thioxanthen-9-one

Conditions
ConditionsYield
With 1,1'-bis-(diphenylphosphino)ferrocene; bis(1,5-cyclooctadiene)nickel (0) In toluene at 50℃; for 12h; Inert atmosphere;82%
2-Chlorothioxanthone
86-39-5

2-Chlorothioxanthone

1-Dimethylaminomethyl-vinylmagnesiumbromid
107123-86-4

1-Dimethylaminomethyl-vinylmagnesiumbromid

2-Chloro-9-(1-dimethylaminomethyl-vinyl)-9H-thioxanthen-9-ol

2-Chloro-9-(1-dimethylaminomethyl-vinyl)-9H-thioxanthen-9-ol

Conditions
ConditionsYield
In tetrahydrofuran80%
2-Chlorothioxanthone
86-39-5

2-Chlorothioxanthone

2-amino-9H-thioxanthen-9-one
33923-98-7

2-amino-9H-thioxanthen-9-one

Conditions
ConditionsYield
With dicyclohexyl(2',4',6'-triisopropyl-5-methoxy-3,4,6-trimethyl-[1,1'-biphenyl]-2-yl)phosphine; C50H70NO4PPdS; C50H70NO4PPdS; dicyclohexyl(2',4',6'-triisopropyl-4-methoxy-3,5,6-trimethyl-[1,1'-biphenyl]-2-yl)phosphine; ammonia; sodium t-butanolate In 1,4-dioxane at 80℃; for 24h; Inert atmosphere;80%
With ammonium hydroxide; potassium phosphate; copper(l) iodide; N1,N2-bis(5-methyl-[1,1'-biphenyl]-2-yl)oxalamide In water; dimethyl sulfoxide at 110℃; for 24h; Inert atmosphere;70%
2-Chlorothioxanthone
86-39-5

2-Chlorothioxanthone

benzylamine
100-46-9

benzylamine

2-benzylaminothioxanthone

2-benzylaminothioxanthone

Conditions
ConditionsYield
With potassium phosphate; copper(l) iodide; N1,N2-bis(2,4,6-trimethoxyphenyl)oxalamide In dimethyl sulfoxide at 120℃; for 24h; Inert atmosphere; Schlenk technique;78%
2-Chlorothioxanthone
86-39-5

2-Chlorothioxanthone

Cyclopropylmethanol
2516-33-8

Cyclopropylmethanol

2-(cyclopropylmethoxy)-9H-thioxanthen-9-one

2-(cyclopropylmethoxy)-9H-thioxanthen-9-one

Conditions
ConditionsYield
With C12H10N(1-)*CH3O3S(1-)*Pd(2+)*C39H57O2P; sodium t-butanolate In 1,4-dioxane at 40℃; for 15h; Reagent/catalyst; Sealed tube; Schlenk technique; Inert atmosphere;78%
2-Chlorothioxanthone
86-39-5

2-Chlorothioxanthone

dimethyl diazomalonate
6773-29-1

dimethyl diazomalonate

2-chlorothioxanthonium bis(carbomethoxy)methylide
76293-15-7

2-chlorothioxanthonium bis(carbomethoxy)methylide

Conditions
ConditionsYield
With copper(II) sulfate In toluene at 95 - 100℃; for 5h;77%
With copper(II) sulfate In toluene Yield given;
2-Chlorothioxanthone
86-39-5

2-Chlorothioxanthone

2-chloro-3-nitrothioxanth-9-one-10,10-dioxide
109702-80-9

2-chloro-3-nitrothioxanth-9-one-10,10-dioxide

Conditions
ConditionsYield
With sulfuric acid; nitric acid at 0℃; for 0.5h;77%
2-Chlorothioxanthone
86-39-5

2-Chlorothioxanthone

sodium methansulfinate
20277-69-4

sodium methansulfinate

2-(methylsulfonyl)-9H-thioxanthen-9-one

2-(methylsulfonyl)-9H-thioxanthen-9-one

Conditions
ConditionsYield
With potassium phosphate; copper(l) iodide; (2S,4R)-4-hydroxy-N-(2-methylnaphthalen-1-yl)pyrrolidine-2-carboxamide In dimethyl sulfoxide at 120℃; Sealed tube; Inert atmosphere;75%
2-Chlorothioxanthone
86-39-5

2-Chlorothioxanthone

diethyl malonate
105-53-3

diethyl malonate

C20H18O5S

C20H18O5S

Conditions
ConditionsYield
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; bis(η3-allyl-μ-chloropalladium(II)) In toluene at 100℃; for 4h;70%
2-Chlorothioxanthone
86-39-5

2-Chlorothioxanthone

2-chlorothioxanthone sulphoxide
7605-18-7

2-chlorothioxanthone sulphoxide

Conditions
ConditionsYield
With ammonium cerium(IV) nitrate In water; acetonitrile at 65℃; for 1.5h;67.3%
N-methylmaleimide
930-88-1

N-methylmaleimide

2-Chlorothioxanthone
86-39-5

2-Chlorothioxanthone

3-(7-chloro-9-oxo-9H-thioxanthen-1-yl)-1-methylpyrrolidine-2,5-dione

3-(7-chloro-9-oxo-9H-thioxanthen-1-yl)-1-methylpyrrolidine-2,5-dione

Conditions
ConditionsYield
With silver hexafluoroantimonate; dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; Trimethylacetic acid In 1,2-dichloro-ethane at 80℃; for 20h; Sealed tube;64%
2-(2-Hydroxyethyl)pyridine
103-74-2

2-(2-Hydroxyethyl)pyridine

2-Chlorothioxanthone
86-39-5

2-Chlorothioxanthone

2-[2-(pyridin-2-yl)ethoxy]-9H-thioxanthen-9-one
1402330-60-2

2-[2-(pyridin-2-yl)ethoxy]-9H-thioxanthen-9-one

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); (R)-(-)-1-[(SP)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine; caesium carbonate In toluene at 80℃; for 16h; Catalytic behavior; Inert atmosphere;58%
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