1-Nitropropane supplier | CasNO.108-03-2

Name
1-Nitropropane
EINECS 203-544-9
CAS No. 108-03-2
Article Data53
CAS DataBase
Density 0.981 g/cm³
Solubility 1.40 g/100 mL in water
Melting Point -108 °C
Formula C₃H₇NO₂
Boiling Point 131.714 °C at 760 mmHg
Molecular Weight 89.0941
Flash Point 42.337 °C
Transport Information UN 2608 3/PG 3
Appearance liquid
Safety 9
Risk Codes 10-20/21/22
Molecular Structure
Hazard Symbols Xn
Synonyms NSC 6363;
PSA 45.82000
LogP 1.19630

Synthetic route

: 627-39-4
propionaldehyde oxime

: 108-03-2
1-Nitropropane

Conditions

Conditions	Yield
With magnesium hydroxide; dihydrogen peroxide In propan-1-ol; water at 80℃; under 5250.53 Torr;	95.5%
With ammonium hydroxide; dihydrogen peroxide In methanol at 70℃; under 760.051 Torr; Green chemistry; chemoselective reaction;	97 %Chromat.

: 75-52-5
nitromethane

: 557-20-0
diethylzinc

: 108-03-2
1-Nitropropane

Conditions

Conditions	Yield
With diethyl ether anschliessend Behandeln mit Wasser;

: 543-67-9
n-propyl nitrite

: 108-03-2
1-Nitropropane

Conditions

Conditions	Yield
at 125 - 130℃;
beim Erhitzen;

: 74-98-6
propane

: 108-03-2
1-Nitropropane

Conditions

Conditions	Yield
With oxygen; nitric acid in der Gasphase;
With nitric acid; chlorine in der Gasphase;
With bromine; oxygen; nitric acid in der Gasphase;
With oxygen; nitric acid; chlorine in der Gasphase;

: 74-98-6
propane

A: 79-46-9
2-nitropropane

B: 108-03-2
1-Nitropropane

Conditions

Conditions	Yield
With nitric acid at 400℃;
With Nitrogen dioxide at 250 - 795℃;
With Nitrogen dioxide at 250℃;
With nitric acid In water at 285℃; under 72402.6 Torr; Product distribution / selectivity;

: 106-94-5
propyl bromide

A: 543-67-9
n-propyl nitrite

B: 108-03-2
1-Nitropropane

Conditions

Conditions	Yield
With silver(I) nitrite

: 107-08-4
1-iodo-propane

: 108-03-2
1-Nitropropane

Conditions

Conditions	Yield
With silver(I) nitrite
With poly(N-ethyl-4-vinylpyridinium)nitrite In hexane at 20℃; for 43h;

: 107-08-4
1-iodo-propane

A: 543-67-9
n-propyl nitrite

B: 108-03-2
1-Nitropropane

Conditions

Conditions	Yield
With silver(I) nitrite

: 3156-70-5
1-Nitropropen

: 108-03-2
1-Nitropropane

Conditions

Conditions	Yield
With tetrahydrofuran; diethyl ether; Trimethyl borate; sodium at -70℃;

: 106-97-8
n-butane

: 108-03-2
1-Nitropropane

Conditions

Conditions	Yield
With nitric acid at 375℃;

: 589-57-1
diethyl phosphorylchloridite

: 12384-98-4
aci-1-nitropropane sodium salt

A: 90050-32-1
(1-nitro-propyl)-phosphonous acid diethyl ester

B: 108-03-2
1-Nitropropane

Conditions

Conditions	Yield
In diethyl ether

...Expand

: 74-98-6
propane

A: 541-42-4
i-propyl nitrite

B: 543-67-9
n-propyl nitrite

C: 1712-64-7
isopropyl nitrate

D: 627-13-4
propyl nitrate

E: 79-46-9
2-nitropropane

F: 108-03-2
1-Nitropropane

Conditions

Conditions	Yield
With dihydrogen peroxide; Nitrogen dioxide at 24.9℃; under 300.02 Torr; Rate constant; Product distribution; Mechanism; boric-acid-coated surface; various pressure and carrier-gas composition;	A 12 % Chromat. B 7 % Chromat. C 16 % Chromat. D 5 % Chromat. E 46 % Chromat. F 14 % Chromat.

...Expand

: 74-98-6
propane

A: 541-42-4
i-propyl nitrite

B: 1712-64-7
isopropyl nitrate

C: 627-13-4
propyl nitrate

D: 79-46-9
2-nitropropane

E: 108-03-2
1-Nitropropane

F: 67-64-1
acetone

Conditions

Conditions	Yield
With dihydrogen peroxide; oxygen; Nitrogen dioxide at 24.9℃; under 300.02 Torr; Rate constant; Product distribution; Mechanism; boric-acid-coated surface; various O2 concn.;

...Expand

: 287-92-3
Cyclopentane

A: 64-18-6
formic acid

B: 74-85-1
ethene

C: 627-05-4
1-nitrobutane

D: 108-03-2
1-Nitropropane

E: 2562-38-1
nitrocyclopentane

Conditions

Conditions	Yield
With Nitrogen dioxide; sulphur hexafluoride for 0.0166667h; Product distribution; Irradiation; CO2 laser irradiation; products investigated on different reaction conditions; products identified with IR and MS spectra; further cycloalkanes measured;

...Expand

: 1000-56-2
sodium propylthiosulfate

: 108-03-2
1-Nitropropane

Conditions

Conditions	Yield
With potassium nitrate; sodium nitrite at 150℃; Yield given;
With potassium nitrate; sodium nitrite Thermodynamic data; Heating; E;

α-bromo-n-butyric acid: α-bromo-n-butyric acid

: 108-03-2
1-Nitropropane

Conditions

Conditions	Yield
With sodium nitrite

potassium propyl sulfate: potassium propyl sulfate

A: 543-67-9
n-propyl nitrite

B: 108-03-2
1-Nitropropane

Conditions

Conditions	Yield
With alkali nitrite
With alkaline earth nitrite

: 106-94-5
propyl bromide

silver nitrite: silver nitrite

A: 543-67-9
n-propyl nitrite

B: 108-03-2
1-Nitropropane

Conditions

Conditions	Yield
Product distribution;

...Expand

: 107-08-4
1-iodo-propane

silver nitrite: silver nitrite

A: 543-67-9
n-propyl nitrite

B: 108-03-2
1-Nitropropane

Conditions

Conditions	Yield
Product distribution;

...Expand

: 107-92-6
butyric acid

NaNO3: NaNO3

KHCO3: KHCO3

A: 1712-64-7
isopropyl nitrate

B: 110-54-3
hexane

C: 638-11-9
isopropyl butyrate

D: 108-03-2
1-Nitropropane

Conditions

Conditions	Yield
Elektrolyse von Natriumbutyrat; Produkt5: Essigsaeure; Produkt6: Propionsaeure; Produkt7: Glycerin-nitrat(?); und andere Produkten;

...Expand

: 7697-37-2
nitric acid

: 106-97-8
n-butane

A: 79-24-3
Nitroethane

B: 75-52-5
nitromethane

C: 627-05-4
1-nitrobutane

D: 108-03-2
1-Nitropropane

Conditions

Conditions	Yield
at 370 - 450℃; in der Gasphase;

...Expand

: 7697-37-2
nitric acid

: 109-66-0
pentane

A: 79-24-3
Nitroethane

B: 75-52-5
nitromethane

C: 627-05-4
1-nitrobutane

D: 108-03-2
1-Nitropropane

Conditions

Conditions	Yield
at 400℃; bei der Nitrierung enstehen noch: 1-Nitro-pentan,2-Nitro-pentan,3-Nitro-pentan und Aethylen,Propylen und Buten-(1);
at 400℃; bei der Nitrierung enstehen noch: 1-Nitro-pentan,2-Nitro-pentan,3-Nitro-pentan;

...Expand

: 109-99-9
tetrahydrofuran

: 17082-05-2
(E)-1-nitroprop-1-ene

: 60-29-7
diethyl ether

lithium borate: lithium borate

A: 99115-57-8
2-methyl-1,3-dinitro-pentane

B: 108-03-2
1-Nitropropane

Conditions

Conditions	Yield
at -70℃;

...Expand

: 109-99-9
tetrahydrofuran

: 17082-05-2
(E)-1-nitroprop-1-ene

: 60-29-7
diethyl ether

sodium-: sodium-

A: 99115-57-8
2-methyl-1,3-dinitro-pentane

B: 108-03-2
1-Nitropropane

Conditions

Conditions	Yield
at -70℃;

...Expand

: 111-43-3
Dipropyl ether

: 7697-37-2
nitric acid

A: 79-24-3
Nitroethane

B: 75-52-5
nitromethane

C: 108-03-2
1-Nitropropane

Conditions

Conditions	Yield
at 400℃;

...Expand

: 627-39-4
propionaldehyde oxime

sulfomonoperoxoic acid: sulfomonoperoxoic acid

A: 2580-63-4, 875452-10-1, 875452-12-3
propionohydroxamic acid

B: 108-03-2
1-Nitropropane

...Expand

: 74-98-6
propane

: 7697-37-2
nitric acid

A: 79-24-3
Nitroethane

B: 75-52-5
nitromethane

C: 79-46-9
2-nitropropane

D: 108-03-2
1-Nitropropane

Conditions

Conditions	Yield
at 250 - 795℃; in der Gasphase meist bei ca.400grad; weitere Produkte: Aethylen und Propylen;
at 250 - 795℃; in der Gasphase meist bei ca.400grad;
at 250 - 795℃; in der Gasphase meist bei ca.400grad; weitere Produkte: Propylalkohol und Isopropylalkohol;
at 410℃; under 5884.06 - 8826.09 Torr;

...Expand

: 74-98-6
propane

NO2: NO2

A: 79-24-3
Nitroethane

B: 75-52-5
nitromethane

C: 79-46-9
2-nitropropane

D: 108-03-2
1-Nitropropane

Conditions

Conditions	Yield
at 250 - 795℃; in der Gasphase meist bei ca.400grad;
at 250 - 795℃; in der Gasphase meist bei ca.400grad; weitere Produkte: Aethylen und Propylen;
at 250 - 795℃; in der Gasphase meist bei ca.400grad; weitere Produkte: Propylalkohol und Isopropylalkohol;

...Expand

: 142-96-1
dibutyl ether

: 7697-37-2
nitric acid

A: 79-24-3
Nitroethane

B: 75-52-5
nitromethane

C: 627-05-4
1-nitrobutane

D: 108-03-2
1-Nitropropane

Conditions

Conditions	Yield
at 400℃; durch ein Glasrohr;Produkt 5:Butyl-nitrobutyl-aether;

...Expand

: 111-71-7
heptanal

: 108-03-2
1-Nitropropane

: 93297-82-6
3-nitro-decan-4-ol

Conditions

Conditions	Yield
With P(i-PrNCH2CH2)3N; magnesium sulfate for 1.25h; Ambient temperature;	99%
With tetrabutyl ammonium fluoride; tert-butyldimethylsilyl chloride; triethylamine In tetrahydrofuran for 0.0833333h;	92%
With Amberlyst A-21 for 10h;	84%
Yield given. Multistep reaction;
With potassium hydrogencarbonate

: 108-03-2
1-Nitropropane

: 479423-39-7
4-methylbenzaldehyde N-(tert-butoxycarbonyl)imine

: 1039201-63-2
tert-butyl (1R,2S)-2-nitro-1-p-tolylpropylcarbamate

Conditions

Conditions	Yield
With N-((1R,2R)-2-(3-((1R,2R)-2-(dimethylamino)cyclohexyl)thioureido)-1,2-diphenylethyl)-3,5-bis(trifluoromethyl)benzenesulfonamide In acetonitrile at -20℃; Mannich reaction; Molecular sieve;	99%

: 100-52-7
benzaldehyde

: 108-03-2
1-Nitropropane

: (1R,2S)-2-nitro-1-phenylbutan-1-ol

Conditions

Conditions	Yield
Stage #1: 1-Nitropropane With C19H20F2N2O4; Nd5O(OiPr)13; water; sodium hexamethyldisilazane In tetrahydrofuran at 0 - 20℃; Inert atmosphere; Stage #2: benzaldehyde In tetrahydrofuran at -40℃; for 20h; Inert atmosphere; optical yield given as %ee; diastereoselective reaction;	99%

: 4122-56-9
methyl o-formylbenzoate

: 108-03-2
1-Nitropropane

: 79017-07-5, 115912-82-8, 115912-83-9
3-(1-nitropropyl)-1(3H)-isobenzofuranone

Conditions

Conditions	Yield
With potassium carbonate at 20℃; for 8h; Neat (no solvent);	99%

: 108-03-2
1-Nitropropane

: 155396-71-7
tert-butyl N-(phenyl(phenylsulfonyl)methyl)carbamate

: (1S,2R)-2-nitro-1-phenylbutylcarbamic acid tert-butyl ester

Conditions

Conditions	Yield
With (S)-N-benzyl-2-(3-((S)-1-hydroxy-3-phenylpropan-2-yl)ureido)-N,N,3,3-tetramethylbutan-1-aminium bromide; potassium hydroxide In chloroform at -20℃; for 12h; Mannich Aminomethylation; stereoselective reaction;	99%
With C36H41N4O3(1+)*Br(1-); potassium hydroxide In chloroform at -20℃; for 12h; Mannich Aminomethylation; stereoselective reaction;	95%

: 108-03-2
1-Nitropropane

12percent nickel/Al-SBA-15 fiber: 12percent nickel/Al-SBA-15 fiber

: 107-10-8
propylamine

Conditions

Conditions	Yield
With hydrogen In ethanol at 109.84℃; under 18751.9 Torr; for 7.5h; Autoclave; Green chemistry; chemoselective reaction;	99%

: 99-61-6
3-nitro-benzaldehyde

: 108-03-2
1-Nitropropane

: 14438-60-9
2-nitro-1-(3-nitro-phenyl)-butan-1-ol

Conditions

Conditions	Yield
With N-benzyl-trimethylammonium hydroxide In tetrahydrofuran; water at 20℃; for 0.1h;	98%
With diethyl ether; sodium methylate
With triethylamine

: 37605-69-9
3-ethoxy-2-methyl-but-3-en-2-ol

: 108-03-2
1-Nitropropane

: 86905-39-7
2-(5-Ethoxy-3-ethyl-4,5-dihydro-isoxazol-5-yl)-propan-2-ol

Conditions

Conditions	Yield
With phenyl isocyanate; triethylamine In benzene	98%

: 98993-72-7
1-methyl-3,6,8-trinitro-2-quinolone

: 108-03-2
1-Nitropropane

: 1203492-12-9
6,8-dinitro-1-methyl-4(1-nitropropyl)-2-quinolone

Conditions

Conditions	Yield
With triethylamine In acetonitrile at 80℃; for 3h; regioselective reaction;	98%

: 3157-65-1
N-(p-chlorobenzylidene)-p-toluenesulfonamide

: 108-03-2
1-Nitropropane

: 1359755-97-7
C17H19ClN2O4S

Conditions

Conditions	Yield
With nanocrystalline magnesium oxide In N,N-dimethyl-formamide at 20℃; for 0.25h; aza-Henry reaction;	98%

: 4-chloro-N-[2,2,2-trifluoro-1-methylethylidene]aniline

: 108-03-2
1-Nitropropane

: 4-chloro-N-[1-methyl-2-nitro-1-(trifluoromethyl)butyl]aniline

Conditions

Conditions	Yield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In toluene Aza-Henry Reaction;	98%

: 108-03-2
1-Nitropropane

: 107-10-8
propylamine

Conditions

Conditions	Yield
With hydrogen at 100℃; under 7500.75 Torr; for 12h; Sealed tube; Autoclave;	97%
With sodium tetrahydroborate; nickel(II) chloride hexahydrate In water at 20℃; for 3h; Inert atmosphere; Green chemistry;	96%
Stage #1: 1-Nitropropane In water at 20℃; for 0.0166667h; Stage #2: With sodium tetrahydroborate In water at 50℃; for 0.133333h;	95%

: 100-52-7
benzaldehyde

: 108-03-2
1-Nitropropane

: 7248-39-7
2-nitro-1-phenylbutyl alcohol

Conditions

Conditions	Yield
With P(i-PrNCH2CH2)3N; magnesium sulfate for 2.25h; Ambient temperature;	97%
With P(i-BuNCH2CH2)3N; magnesium sulfate at 25℃; for 2h; Henry reaction;	96%
With tetrabutyl ammonium fluoride; tert-butyldimethylsilyl chloride; triethylamine In tetrahydrofuran for 0.0833333h;	90%

: 108-03-2
1-Nitropropane

: 140-88-5
ethyl acrylate

: 59925-14-3
4-nitro-hexanoic acid ethyl ester

Conditions

Conditions	Yield
With aluminum oxide; potassium fluoride In tetrahydrofuran for 2h;	97%

: 14003-18-0, 14003-19-1, 59225-18-2
ethyl 2-(2-oxoindolin-3-ylidene)cyanoacetate

: 108-03-2
1-Nitropropane

A: ethyl (2R,3S)-2-cyano-2-(-3-(1-nitropropyl)-2-oxoindolin-3-yl)acetate

: ethyl 2-cyano-2-(-3-(1-nitropropyl)-2-oxoindolin-3-yl)acetate

Conditions

Conditions	Yield
With C26H36N4OS at -10℃; for 3h; Michael condensation; Neat (no solvent); optical yield given as %ee; enantioselective reaction;	A 97% B n/a

...Expand

: 4217-54-3
9,10-dihydro-10-methylacridine

: 108-03-2
1-Nitropropane

: 10-methyl-9-(1-nitropropyl)-9,10-dihydroacridine

Conditions

Conditions	Yield
With 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; oxygen at 60℃; under 760.051 Torr; for 27h;	97%

: 100-52-7
benzaldehyde

: 108-03-2
1-Nitropropane

: 5-ethyl-4-phenyl-1H-1,2,3-triazole

Conditions

Conditions	Yield
With sodium azide; ammonium acetate; acetic acid In N,N-dimethyl-formamide at 100℃;	97%
Stage #1: benzaldehyde With sodium azide; sodium hydrogen sulphite; sodium sulfite In dimethyl sulfoxide at 110℃; Inert atmosphere; Stage #2: 1-Nitropropane In dimethyl sulfoxide Inert atmosphere;	50%

: 108-03-2
1-Nitropropane

: lithium propylideneazinate

Conditions

Conditions	Yield
With lithium methanolate In ethanol at 0 - 20℃; Inert atmosphere;	97%

: 15793-77-8
2-hydrazinoquinoline

: 108-03-2
1-Nitropropane

: 29005-32-1
1-ethyl-[1,2,4]triazolo[4,3-a]quinoline

Conditions

Conditions	Yield
Stage #1: 1-Nitropropane With polyphosphoric acid at 130℃; Stage #2: 2-hydrazinoquinoline at 130℃;	97%

: 623-43-8, 4358-59-2, 18707-60-3, 130981-57-6
methyl crotonate

: 108-03-2
1-Nitropropane

: 16507-08-7
methyl 3-methyl-4-nitrohexanoate

Conditions

Conditions	Yield
With tetrabutyl ammonium fluoride In tetrahydrofuran at 30℃; under 10000 Torr; for 120h;	96%
With triethylamine In dichloromethane under 11250900 Torr; for 48h; Ambient temperature;	95%

: 108-03-2
1-Nitropropane

: 94-41-7
benzalacetophenone

: 80460-05-5
4-Nitro-1,3-diphenyl-1-hexanone

Conditions

Conditions	Yield
With aluminum oxide; potassium fluoride In tetrahydrofuran for 2h;	96%
With 1,8-diazabicyclo[5.4.0]undec-7-ene In acetonitrile Ambient temperature;	77%
With sodium methylate In methanol Heating;	46%

: 555-16-8
4-nitrobenzaldehdye

: 108-03-2
1-Nitropropane

: 222025-81-2
2-nitro-1-(4-nitrophenyl)butan-1-ol

Conditions

Conditions	Yield
With polymer supported 4-DMAP at 20℃; for 0.5h; Henry Nitro Aldol Condensation;	96%
With Streptorerticillium griseoverticillatum protein-glutamine γ-glutamyltransferase In dichloromethane; water at 30℃; for 72h; Henry reaction; Enzymatic reaction; optical yield given as %de;	94%
With polystyryl-diphenylphosphine-ethyl acrylate complex In neat (no solvent) at 20℃; for 3h; Henry Nitro Aldol Condensation; Green chemistry;	94%

: 26805-54-9, 61784-44-9, 19530-68-8
dimethyl (Z)-2-(bromomethyl)fumarate

: 108-03-2
1-Nitropropane

: 409060-84-0
(E)-1-ethyl-2,3-dimethoxycarbonyl buta-1,3-diene

Conditions

Conditions	Yield
With sodium hydroxide In tetrahydrofuran at 20℃; for 4h;	96%
With sodium hydroxide In tetrahydrofuran at 20℃; for 2h;	96%

: 108-03-2
1-Nitropropane

: 13707-47-6
2-furaldehyde tosylimine

: 1359755-95-5
C15H18N2O5S

Conditions

Conditions	Yield
With nanocrystalline magnesium oxide In N,N-dimethyl-formamide at 20℃; for 0.25h; aza-Henry reaction;	96%

: 100-52-7
benzaldehyde

: 108-03-2
1-Nitropropane

: (1R,2R)-2-nitro-1-phenyl-1-butanol

Conditions

Conditions	Yield
With copper(I) trifluoromethanesolfonate toluene complex; (+)-6,6'-(((1R,2R,4R,5R)-bicyclo[2.2.2]octane-2,5-diylbis(azanediyl))bis(methylene))bis(2,4-di-tert-butylphenol) In methanol at 40℃; for 24h; Henry Nitro Aldol Condensation; Molecular sieve; enantioselective reaction;	96%

: 15206-55-0
methyl 2-oxo-2-phenylacetate

: 108-03-2
1-Nitropropane

: methyl (2R,3S)-2-hydroxy-3-nitro-2-phenylpentanoate

Conditions

Conditions	Yield
With tetrahydrofuran; 2-methyltetrahydrofuran; Nitroethane; neodymium(III) chloride hexahydrate; (S)-2-fluoro-N-(1-((4-fluoro-2-hydroxyphenyl)amino)-3,3-dimethyl-1-oxobutan-2-yl)-5-hydroxybenzamide; sodium t-butanolate at -78℃; for 48h; Kinetics; Reagent/catalyst; Aldol Addition; Inert atmosphere; stereoselective reaction;	96%

: 108-03-2
1-Nitropropane

: 802294-64-0
propionic acid

Conditions

Conditions	Yield
With acetic acid; zinc(II) iodide In toluene at 110℃; for 24h; Catalytic behavior; Reagent/catalyst; Solvent;	95%
With sulfuric acid
With water; benzenesulfonic acid

: 104-87-0
4-methyl-benzaldehyde

: 108-03-2
1-Nitropropane

: erythro-2-nitro-1-(p-tolyl)-1-butanol

: threo-2-nitro-1-(p-tolyl)-1-butanol

Conditions

Conditions	Yield
In aq. phosphate buffer at 20℃; for 72h; pH=7.0; Henry Nitro Aldol Condensation; Overall yield = 70%; Overall yield = 36.6 mg; diastereoselective reaction;	A n/a B 95%
With n-butyllithium; acetic acid THF-DMPU-hexane, 1.) a.) -88 to -60 deg C, 75 min; b.) -70 to -60 deg C, 1.5 h; 2.) -90 to -85 deg C; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;

...Expand

: 555-16-8
4-nitrobenzaldehdye

: 108-03-2
1-Nitropropane

: 82945-24-2, 118869-06-0, 118890-28-1, 130711-68-1
2-nitro-1-(4-nitrophenyl)butan-1-ol

: 82945-24-2, 118869-06-0, 118890-28-1, 130711-68-1
2-nitro-1-(4-nitrophenyl)butan-1-ol

Conditions

Conditions	Yield
In aq. phosphate buffer at 20℃; for 50h; pH=7.0; Henry Nitro Aldol Condensation; Overall yield = 87%; Overall yield = 52.2 mg; diastereoselective reaction;	A n/a B 95%
Product distribution; var. ratio of educts, var. nitroalkanes, var. aldehydes;	A 60% B n/a
Yield given. Multistep reaction. Yields of byproduct given;

...Expand

1-Nitropropane Chemical Properties

IUPAC Name: 1-Nitropropane
Product Name: 1-Nitropropane
The MF of 1-Nitropropane (CAS NO.108-03-2) is C₃H₇NO₂.

The MW of 1-Nitropropane (CAS NO.108-03-2) is 89.09.
Synonyms of 1-Nitropropane (CAS NO.108-03-2): 1-Nitropane ; 1-Nitropan ; 1-Nitro-propan ; 1-NP ; Ai3-02264 ; N-C3H7NO2 ; NiPar S-10 ; Nitropropane(non-specificname)
Product Categories: Industrial/Fine Chemicals;Organics;Nitro Compounds;Nitrogen Compounds;Organic Building Blocks;Alpha Sort;Chemical Class
Appearance: Colorless liquid with a somewhat disagreeable odor
Stability: Stable. Flammable. Incompatible with strong bases, strong oxidizing agents
Index of Refraction: 1.398
EINECS: 203-544-9
Density: 0.98 g/ml
Flash Point: 42.3 °C
Boiling Point: 131.7 °C
Melting Point: -108 °C
Storage temp: Flammables area
Water Solubility: 1.40 g/100 mL
Merck: 14,6627
BRN: 506236

1-Nitropropane Uses

1-Nitropropane (CAS NO.108-03-2) is used as primarily as solvents and intermediates, jet engine fuel, sprays and so on.

1-Nitropropane Production

Preparation Products: Isobutyric acid-->Nitroethane-->2-Nitropropane
Raw materials: Nitric acid-->Nitromethane-->Nitroethane-->2-Nitropropane

1-Nitropropane Toxicity Data With Reference

1.	eye-hmn 150 ppm/15M	JIHTAB Journal of Industrial Hygiene and Toxicology. 28 (1946),262.
2.	dns-rat:lvr 1 µmol/L	MUREAV Mutation Research. 221 (1989),263.
3.	ihl-hmn TCLo:150 ppm:EYE	JIHTAB Journal of Industrial Hygiene and Toxicology. 28 (1946),262.
4.	orl-rat LD50:455 mg/kg	NPIRI* Raw Material Data Handbook, Vol.1: Organic Solvents, 1974. 1 (1974),91.
5.	ihl-rat LC50:3100 ppm/8H	NPIRI* Raw Material Data Handbook, Vol.1: Organic Solvents, 1974. 1 (1974),91.
6.	orl-mus LD50:800 mg/kg	GISAAA Gigiena i Sanitariya. 32 (9)(1967),9.
7.	ipr-mus LD50:250 mg/kg	KHFZAN Khimiko-Farmatsevticheskii Zhurnal. Chemical Pharmaceutical Journal. 10 (6)(1976),53.
8.	orl-rbt LDLo:250 mg/kg	JIHTAB Journal of Industrial Hygiene and Toxicology. 22 (1940),315.

1-Nitropropane Consensus Reports

Reported in EPA TSCA Inventory.

1-Nitropropane Safety Profile

Poison by ingestion and intraperitoneal routes. Mildly toxic by inhalation. A human eye irritant. Human systemic effects by inhalation: conjunctiva irritation. Mutation data reported. Very dangerous fire hazard when exposed to heat, open flame, or oxidizers. Reacts violently with Ca(OH)₂, hydrocarbons, hydroxides, inorganic bases. May explode on heating. Metal oxides increase its sensitivity to thermal ignition. To fight fire, use alcohol foam, CO₂, dry chemical, water spray. When heated to decomposition it emits toxic fumes of NO_x. See also 2-NITROPROPANE, NITROALKANES, and NITRO COMPOUNDS.Safety information of 1-Nitropropane (CAS NO.108-03-2):
Hazard Codes Harmful Xn
Risk Statements
10 Flammable
20/21/22 Harmful by inhalation, in contact with skin and if swallowed
Safety Statements
9 Keep container in a well-ventilated place
RIDADR UN 2608 3/PG 3
WGK Germany 1
RTECS TZ5075000
HazardClass 3
PackingGroup III
HS Code 29042000

1-Nitropropane Standards and Recommendations

OSHA PEL: TWA 25 ppm
ACGIH TLV: TWA 25 ppm; Not Classifiable as a Human Carcinogen
DFG MAK: 25 ppm (92 mg/m³)

1-Nitropropane Analytical Methods

For occupational chemical analysis use OSHA: #46.

Product Name

1-Nitropropane

Synthetic route

1-Nitropropane Chemical Properties

1-Nitropropane Uses

1-Nitropropane Production

1-Nitropropane Toxicity Data With Reference

1-Nitropropane Consensus Reports

1-Nitropropane Safety Profile

1-Nitropropane Standards and Recommendations

1-Nitropropane Analytical Methods

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