2,3-Xylidine supplier | CasNO.87-59-2

Name
2,3-Dimethylaniline
EINECS 201-755-0
CAS No. 87-59-2
Article Data59
CAS DataBase
Density 0.975 g/cm³
Solubility 30 g/L (20 °C) in water
Melting Point 2.5 °C(lit.)
Formula C₈H₁₁N
Boiling Point 221.9 °C at 760 mmHg
Molecular Weight 121.182
Flash Point 96.1 °C
Transport Information UN 1711 6.1/PG 2
Appearance brown liquid
Safety 28-36/37-45-61-28A
Risk Codes 23/24/25-33-51/53
Molecular Structure
Hazard Symbols T,N
Synonyms 2,3-Xylidine(8CI);2,3-Xylidine;2,3-Dimethylbenzenamine;2,3-Xylylamine;3-Amino-o-xylene;o-Xylidine;
PSA 26.02000
LogP 2.46680

Synthetic route

: 1321455-35-9
1-tert-butyl-N-(2,3-dimethylphenyl)-1,1-dimethylsilanamine

: 87-59-2
2,3-Dimethylaniline

Conditions

Conditions	Yield
With silica gel In ethanol; water at 20℃; for 2h;	100%

: 83-41-0
2,3-dimethylnitrobenzene

: 87-59-2
2,3-Dimethylaniline

Conditions

Conditions	Yield
With sodium sulfide; tetrabutylammomium bromide In water; toluene at 80℃; for 0.75h; Zinin reduction;	96.8%
Stage #1: 2,3-dimethylnitrobenzene In water at 20℃; for 0.05h; Green chemistry; Stage #2: With glycerol In water at 20℃; for 1.5h; Green chemistry;	95%
With sodium tetrahydroborate In water at 60 - 70℃; for 0.133333h; Green chemistry;	95%

: 18595-13-6
2-amino-6-methylbenzoic acid methyl ester

: 87-59-2
2,3-Dimethylaniline

Conditions

Conditions	Yield
With sodium bis(2-methoxyethoxy)aluminium dihydride In toluene for 3h; Heating;	75%

: 95-47-6
o-xylene

A: 95-64-7
4-amino-o-xylene

B: 87-59-2
2,3-Dimethylaniline

Conditions

Conditions	Yield
With tris-(2-chloro-ethyl)-amine; trifluorormethanesulfonic acid; trifluoroacetic acid In chloroform at 25℃; for 1h;	A 44% B 30%
bei der Nitrierung und Hydrierung des Reaktionsprodukts in Gegenwart von Nickel bei 180-190grad;
With xenon difluoride; trimethylsilyl isocyanate; trifluorormethanesulfonic acid In dichloromethane at -78℃;

: 619-04-5
3,4-dimethylbenzoic acid

A: 95-65-8
3,4-Dimethylphenol

B: 95-64-7
4-amino-o-xylene

C: 87-59-2
2,3-Dimethylaniline

Conditions

Conditions	Yield
With ammonia; water; copper(II) oxide at 220℃; for 0.5h;	A 3.5% B 43.1% C 0.9%

...Expand

: 2,3-dibromo-5,6-dimethyl-aniline

: 87-59-2
2,3-Dimethylaniline

Conditions

Conditions	Yield
With sodium amalgam

: 593-53-3
Methyl fluoride

: 108-44-1
1-amino-3-methylbenzene

A: 95-78-3
2,5-Dimethylaniline

B: 95-64-7
4-amino-o-xylene

C: 87-59-2
2,3-Dimethylaniline

Conditions

Conditions	Yield
With oxygen In gaseous matrix at 80℃; Irradiation;	A 29 % Spectr. B 25 % Spectr. C 46 % Spectr.

...Expand

: 2,3-Dichloro-[1,4]naphthoquinone; compound with 2,3-dimethyl-phenylamine

A: 117-80-6
2,3-Dichloro-1,4-naphthoquinone

B: 87-59-2
2,3-Dimethylaniline

Conditions

Conditions	Yield
In dichloromethane at 21.9℃; Equilibrium constant;

: 2,3-Dichloro-[1,4]naphthoquinone; compound with 2,3-dimethyl-phenylamine

A: 117-80-6
2,3-Dichloro-1,4-naphthoquinone

B: 87-59-2
2,3-Dimethylaniline

Conditions

Conditions	Yield
In dichloromethane at 21.9℃; Equilibrium constant;

3-nitro-o-xylene: 3-nitro-o-xylene

: 87-59-2
2,3-Dimethylaniline

Conditions

Conditions	Yield
With iron; acetic acid

vic nitro-o-xylene: vic nitro-o-xylene

: 87-59-2
2,3-Dimethylaniline

Conditions

Conditions	Yield
With iron; acetic acid

xylidine: xylidine

: 87-59-2
2,3-Dimethylaniline

Conditions

Conditions	Yield
With acetic acid in mehrere Stufen;

: 67-56-1
methanol

: 62-53-3
aniline

A: 87-59-2
2,3-Dimethylaniline

B: 99-97-8
Dimethyl-p-toluidine

C homologous/ues (CH3)2C6H3*N(CH3)2 and (CH3)3C6H2*N(CH3)2: homologous/ues (CH3)2C6H3*N(CH3)2 and (CH3)3C6H2*N(CH3)2

D (CH3)4C6H*N(CH3)2: (CH3)4C6H*N(CH3)2

Conditions

Conditions	Yield
at 280 - 300℃; bei der Einwirkung auf salzsaures Anilin im Autoklaven;

...Expand

: 7647-01-0
hydrogenchloride

: 53877-42-2
4-(2,3-dimethyl-phenylazo)-2,3-dimethyl-aniline

tin: tin

A: 5306-96-7
1,4-diamino-2,3-dimethylbenzene

B: 87-59-2
2,3-Dimethylaniline

...Expand

: 3096-62-6
N-(2,3-dimethylphenyl)hydroxylamine

alcoholic KOH-solution: alcoholic KOH-solution

A: 19618-11-2
bis-(2,3-dimethyl-phenyl)-diazene-N-oxide

B: 87-59-2
2,3-Dimethylaniline

C 3-nitro-o-xylene: 3-nitro-o-xylene

...Expand

: 7664-93-9
sulfuric acid

: 861319-17-7
tetramethyl-[1,4]benzoquinone-(2,3-dimethyl-phenylimine)-imine

A: 527-17-3, 70128-24-4
Duroquinone

B: 87-59-2
2,3-Dimethylaniline

...Expand

: 476170-48-6
2,3-dimethyl-6-(trisopropylsilyl)aniline

: 87-59-2
2,3-Dimethylaniline

Conditions

Conditions	Yield
With trifluoroacetic acid In hexane for 5h; Heating;	0.65 g

: 110036-12-9
2-methoxycarbonyl-3-methyl-6-(trisopropylsilyl)aniline

: 87-59-2
2,3-Dimethylaniline

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: 3.85 g / Red-Al / toluene / 3 h / Heating 2: 0.65 g / trifluoroacetic acid / hexane / 5 h / Heating View Scheme

: 476170-47-5
2-methoxycarbonyl-3-methyl-6,N-bis(trisopropylsilyl)aniline

: 87-59-2
2,3-Dimethylaniline

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: 91 percent / KF; HCl; water / methanol / 2 h / Heating 2: 75 percent / Red-Al / toluene / 3 h / Heating View Scheme
Multi-step reaction with 3 steps 1: 62 percent / KF; HCl; water / methanol / 2 h / Heating 2: 3.85 g / Red-Al / toluene / 3 h / Heating 3: 0.65 g / trifluoroacetic acid / hexane / 5 h / Heating View Scheme

: dimethylaniline oxide

: 82-45-1
1-amino-9,10-anthracenedione

A dianthraquinone-N,N'-dihydroazine: dianthraquinone-N,N'-dihydroazine

B: 87-59-2
2,3-Dimethylaniline

Conditions

Conditions	Yield
With potassium hydroxide; sodium hydroxide

...Expand

: 87-59-2
2,3-Dimethylaniline

: 407-25-0
trifluoroacetic anhydride

: 14719-31-4
N-(2,3-dimethylphenyl)-2,2,2-trifluoroacetamide

Conditions

Conditions	Yield
In dichloromethane for 1h; Further stages;	100%
With triethylamine In dichloromethane for 1h; Ambient temperature;	87%
In diethyl ether
In dichloromethane at 0 - 20℃; for 12h;

: 598-21-0
2-Bromoacetyl bromide

: 87-59-2
2,3-Dimethylaniline

: 349120-89-4
2-bromo-N-(2',3'-dimethylphenyl)acetamide

Conditions

Conditions	Yield
With triethylamine at 0℃; for 1h; Inert atmosphere;	100%
With sodium carbonate In water pH=9 - 10;	99%
With N-ethyl-N,N-diisopropylamine In dichloromethane at 20℃; for 1.5h; bromoacetylation;

: 24424-99-5
di-tert-butyl dicarbonate

: 87-59-2
2,3-Dimethylaniline

: 876353-79-6
N-tert-butyloxycarbonyl-2,3-dimethylaniline

Conditions

Conditions	Yield
With sodium carbonate In methanol at 20℃; for 1.5h;	100%
In neat (no solvent) at 80℃; for 0.166667h; Green chemistry; chemoselective reaction;	98%
at 20℃; for 0.0833333h; Green chemistry;	95%
With pyridinium trifluroacetate In neat (no solvent) at 20℃; for 0.3h; Green chemistry;	93%
In tetrahydrofuran for 12h; Reflux;

: 102-71-6
triethanolamine

: 87-59-2
2,3-Dimethylaniline

: 55199-24-1
6,7-dimethyl-1H-indole

Conditions

Conditions	Yield
With tin(ll) chloride; ruthenium trichloride; triphenylphosphine In 1,4-dioxane at 180℃; for 20h;	99%

: 87-59-2
2,3-Dimethylaniline

: 57-27-2
MORPHIN

: 76-57-3
codeine

Conditions

Conditions	Yield
With potassium carbonate In 5,5-dimethyl-1,3-cyclohexadiene	99%

: 13139-15-6
N-tert-butoxycarbonyl-L-leucine

: 87-59-2
2,3-Dimethylaniline

: (S)-Boc-L-Leu-N'-(2,3-dimethylphenyl)amide

Conditions

Conditions	Yield
Stage #1: N-tert-butoxycarbonyl-L-leucine With 4-methyl-morpholine; isobutyl chloroformate In tetrahydrofuran at 0℃; for 0.5h; Inert atmosphere; Schlenk technique; Stage #2: 2,3-Dimethylaniline In tetrahydrofuran at 0 - 20℃; Inert atmosphere; Schlenk technique;	99%

: 108-24-7
acetic anhydride

: 87-59-2
2,3-Dimethylaniline

: 134-98-5
N-(2,3-dimethylphenyl)acetamide

Conditions

Conditions	Yield
With Ni2B-Cu2O nanocomposite In neat (no solvent) at 40℃; for 0.0166667h; Reagent/catalyst;	98%
In chloroform at 20℃; for 2h;	88%
With pyridine at 0 - 20℃;	80%

: 532-55-8
Benzoyl isothiocyanate

: 87-59-2
2,3-Dimethylaniline

: 83697-76-1
1-benzoyl-3-(2,3-dimethylphenyl)thiourea

Conditions

Conditions	Yield
In acetone at 20℃; for 1h;	98%
In tetrahydrofuran at 60 - 65℃; for 0.166667h; Microwave irradiation;	92%
In acetone	85%

: 16937-99-8
N-Boc-D-Leu

: 87-59-2
2,3-Dimethylaniline

: N-Boc-D-Leu-N'-(2,3-dimethylphenyl)amide

Conditions

Conditions	Yield
Stage #1: N-Boc-D-Leu With 4-methyl-morpholine; isobutyl chloroformate In tetrahydrofuran at 0℃; for 0.5h; Inert atmosphere; Schlenk technique; Stage #2: 2,3-Dimethylaniline In tetrahydrofuran at 0 - 20℃; Inert atmosphere; Schlenk technique;	98%

: 623-12-1
4-chloromethoxybenzene

: 87-59-2
2,3-Dimethylaniline

: C15H17NO

Conditions

Conditions	Yield
With 2'-dicyclohexylphosphanyl-6-hydroxy-biphenyl-3-sulfonic acid; palladium diacetate; sodium t-butanolate In diethylene glycol dimethyl ether at 120℃; for 14h; Buchwald-Hartwig Coupling; Inert atmosphere;	98%

: 98-09-9
benzenesulfonyl chloride

: 87-59-2
2,3-Dimethylaniline

: 126494-77-7
2,3-dimethyl-N-(phenylsulfonyl)aniline

Conditions

Conditions	Yield
With pyridine In dichloromethane	97%

: 845870-02-2
C10H14O5

: 87-59-2
2,3-Dimethylaniline

: 1254946-88-7
dimethyl (1S,2S,4S,5S)-4-(2,3-dimethylphenylamino)-5-hydroxycyclohexane-1,2-dicarboxylate

Conditions

Conditions	Yield
With indium(III) bromide In dichloromethane at 20℃; for 15h;	97%

: 16714-25-3
2-azidobenzaldehyde

: 87-59-2
2,3-Dimethylaniline

: C15H14N2

Conditions

Conditions	Yield
at 100℃; under 10343.2 Torr; Microwave irradiation;	97%

: 93-56-1
phenylethane 1,2-diol

: 87-59-2
2,3-Dimethylaniline

: 33555-28-1
6,7-dimethyl-2-phenyl-1H-indole

Conditions

Conditions	Yield
With tetrafluoroboric acid diethyl ether; {[(PCy3)(CO)RuH]4(μ-O)(μ-OH)2}; cyclopentene In 1,4-dioxane at 120℃; for 14h; Sealed tube; Schlenk technique; Inert atmosphere; regioselective reaction;	97%

: 577-56-0
2-acetyl-benzoic acid

: 87-59-2
2,3-Dimethylaniline

: 2-(2,3-dimethylphenyl)-3-methyleneisoindolin-1-one

Conditions

Conditions	Yield
With 3-(1,1-dioxido-4-(3-(3-(3-sulfopropyl)-1H-imidazol-3-ium-1-yl)propyl)thiomorpholino-4-ium)propane-1-sulfonate trifluoromethanesulfonate In acetic acid butyl ester at 100℃; for 8h; Green chemistry;	97%

: 79-04-9
chloroacetyl chloride

: 87-59-2
2,3-Dimethylaniline

: 2564-07-0
2-chloro-N-(2, 3-dimethylphenyl)acetamide

Conditions

Conditions	Yield
With sodium hydroxide In dichloromethane; water for 18h;	96%
With potassium carbonate In acetone at 20℃;	83%
In benzene for 5h; Heating;	60%

: 87-59-2
2,3-Dimethylaniline

: 2564-07-0
2-chloro-N-(2, 3-dimethylphenyl)acetamide

Conditions

Conditions	Yield
	96%

: 106-39-8
bromochlorobenzene

: 87-59-2
2,3-Dimethylaniline

: 1616092-86-4
2,3-dimethyl-4',4"-dichlorotriphenylamine

Conditions

Conditions	Yield
With bis-triphenylphosphine-palladium(II) chloride; triphenylphosphine; sodium t-butanolate In o-xylene for 12h; Inert atmosphere; Reflux; Schlenk technique;	96%

: 66090-36-6
3-chlorobenzoyl isothiocyanate

: 87-59-2
2,3-Dimethylaniline

: 1-(3-chlorobenzoyl)-3-(2,3-dimethylphenyl)thiourea

Conditions

Conditions	Yield
In tetrahydrofuran at 60 - 65℃; under 760.051 Torr; for 0.025h; Microwave irradiation;	96%

: 26385-24-0
potassium methanethiolate

: 87-59-2
2,3-Dimethylaniline

: 66794-10-3
1,2-dimethyl-3-(methylsulfanyl)benzene

Conditions

Conditions	Yield
Stage #1: 2,3-Dimethylaniline With sulfuric acid at 50℃; for 0.5h; Stage #2: With sodium nitrite In water at -10 - -5℃; for 1h; Stage #3: potassium methanethiolate In water at 20 - 35℃; for 4h;	95.8%

: 87-59-2
2,3-Dimethylaniline

: 5188-07-8
sodium thiomethoxide

: 66794-10-3
1,2-dimethyl-3-(methylsulfanyl)benzene

Conditions

Conditions	Yield
Stage #1: 2,3-Dimethylaniline With hydrogenchloride In water at 50℃; for 0.5h; Stage #2: With sodium nitrite In water at -5 - 0℃; for 1h; Stage #3: sodium thiomethoxide In water at 35℃; for 2h;	95.5%

: 87-59-2
2,3-Dimethylaniline

: 121-51-7
3-nitrobenzenesulphonyl chloride

: 250697-59-7
3-nitro-N-(2,3-dimethylphenyl)benzenesulfonamide

Conditions

Conditions	Yield
With 4-methyl-morpholine In dichloromethane at 0℃;	95%
With 4-methyl-morpholine In dichloromethane at 0℃; for 12h; Acylation;	95%
With 4-methyl-morpholine In dichloromethane at 0 - 20℃; Substitution;

: 18162-48-6
tert-butyldimethylsilyl chloride

: 87-59-2
2,3-Dimethylaniline

: 1321455-35-9
1-tert-butyl-N-(2,3-dimethylphenyl)-1,1-dimethylsilanamine

Conditions

Conditions	Yield
Stage #1: 2,3-Dimethylaniline With methyllithium In 2-methyltetrahydrofuran; diethyl ether at 0℃; Inert atmosphere; Stage #2: tert-butyldimethylsilyl chloride In 2-methyltetrahydrofuran; diethyl ether at 0 - 20℃; Inert atmosphere;	95%

: 536-74-3
phenylacetylene

: 87-59-2
2,3-Dimethylaniline

: 1272320-35-0
2,3-dimethyl-N-(1-phenylethylidene)benzenamine

Conditions

Conditions	Yield
With silver trifluoromethanesulfonate; C17H25Cl2N3OPtS In toluene at 120℃; for 12h; Reagent/catalyst;	95%
With trifluorormethanesulfonic acid; [(S(CH2CH2C3H2N2(Bn))2-κ3C,C',S)PdBr]Br In toluene at 100℃; for 12h;	48 %Chromat.

: 106-38-7
para-bromotoluene

: 87-59-2
2,3-Dimethylaniline

: 1616092-85-3
2,3,4’,4’’-tetramethyltriphenylamine

Conditions

Conditions	Yield
With bis-triphenylphosphine-palladium(II) chloride; triphenylphosphine; sodium t-butanolate In o-xylene for 12h; Inert atmosphere; Reflux; Schlenk technique;	95%

: 578-57-4
2-bromoanisole

: 87-59-2
2,3-Dimethylaniline

: (2,3-dimethyl-phenyl)-(2-methoxyphenyl)-amine

Conditions

Conditions	Yield
With tris-(dibenzylideneacetone)dipalladium(0); (RSp,SRp)-tert-butyl([2.2]paracyclophan-4-yl)phosphine oxide; sodium t-butanolate In toluene at 105℃; Buchwald-Hartwig Coupling;	95%
With 2'-dicyclohexylphosphanyl-6-methoxy-biphenyl-3-sulfonic acid; palladium diacetate; sodium t-butanolate In diethylene glycol dimethyl ether at 120℃; for 48h; Buchwald-Hartwig Coupling; Inert atmosphere;	27%

: 580-13-2
2-bromonaphthalene

: 87-59-2
2,3-Dimethylaniline

: (2,3-dimethylphenyl)(2-naphthyl)amine

Conditions

Conditions	Yield
With 2'-dicyclohexylphosphanyl-6-methoxy-biphenyl-3-sulfonic acid; palladium diacetate; sodium t-butanolate In diethylene glycol dimethyl ether at 120℃; for 96h; Buchwald-Hartwig Coupling; Inert atmosphere;	95%

: 87-59-2
2,3-Dimethylaniline

: 118-91-2
ortho-chlorobenzoic acid

: 61-68-7
mefenamic Acid

Conditions

Conditions	Yield
Stage #1: ortho-chlorobenzoic acid With sodium carbonate In N,N-dimethyl-formamide at 80℃; for 0.5h; Stage #2: 2,3-Dimethylaniline With manganese(II) acetate In water; N,N-dimethyl-formamide; toluene at 120 - 130℃; Reagent/catalyst;	94.8%
Stage #1: ortho-chlorobenzoic acid With sodium carbonate In N,N-dimethyl-formamide at 80℃; for 1.16667h; Stage #2: 2,3-Dimethylaniline With copper In water; N,N-dimethyl-formamide; toluene at 104 - 123℃;	91.3%
With copper; sodium carbonate In N,N-dimethyl-formamide at 140℃; for 2h;	90%

2,3-Xylidine Chemical Properties

Chemical Name: 2,3-Dimethylaniline
IUPAC NAME: 2,3-Dimethylaniline
CAS No.: 87-59-2
EINECS: 201-755-0
RTECS: ZE8750000
RTECS Class: Mutagen
EC Class: toxic, dangerous for the environment
Molecular Formula: C₈H₁₁N
Molecular Weight: 121.18 g/mol
Polar Surface Area: 26.02 Å²
Index of Refraction: 1.559
Molar Refractivity: 40.13 cm³
Molar Volume: 124.2 cm³
Surface Tension: 37.9 dyne/cm
Density: 0.975 g/cm³
Flash Point: 96.1 °C
Enthalpy of Vaporization: 45.84 kJ/mol
Boiling Point: 221.9 °C at 760 mmHg Vapour Pressure: 0.105 mmHg at 25°C
2,3-Xylidine (87-59-2) is stable under normal temperatures and pressures.but incompatible with Strong oxidizing agents, acids, acid chlorides, halogens, acid anhydrides, hypochlorite, chloroformates.The pale yellow liquid with special smell is slightly soluble in water and the water solubility is equal to 30 g/L (20 °C), it is miscible in ethanol, ethyl ether.
Following is the structure of 2,3-Xylidine (CAS NO.87-59-2):

The chemical synonymous of 2,3-Xylidine (CAS NO.87-59-2) are 2,3-Dimethylaniline ; 2,3-Dimethylbenzenamine ; 2,3-Dimethylphenylamine ; 2,3-Xylylamine ; 3-Amino-o-xylene ; 4-12-00-02497 (Beilstein Handbook Reference) ; BRN 0742174 ; Benzenamine, 2,3-dimethyl- ; Benzene, 1-amino-2,3-dimethyl- ; CCRIS 4739 ; EINECS 201-755-0 ; HSDB 2091 ; o-Xylidine ; ortho-Xylidine

2,3-Xylidine Uses

2,3-Xylidine (CAS NO.87-59-2) is mainly used in organic synthesis and used an the main raw material of mefenamic acid.

2,3-Xylidine Production

Product Categories about 2,3-Xylidine (CAS NO.87-59-2) are Intermediates of Dyes and Pigments;Intermediates.

2,3-Xylidine Toxicity Data With Reference

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
mouse	LD50	oral	836mg/kg (836mg/kg)	BEHAVIORAL: COMA LUNGS, THORAX, OR RESPIRATION: DYSPNEA	Proceedings of the Western Pharmacology Society. Vol. 6, Pg. 11, 1963.
rat	LD50	oral	933mg/kg (933mg/kg)		National Technical Information Service. Vol. PB214-270,

2,3-Xylidine Consensus Reports

Reported in EPA TSCA Inventory.

2,3-Xylidine Safety Profile

Hazard Codes: Toxic T, Dangerous N
Risk Statements: 23/24/25-33-51/53
R23/24/25: Toxic by inhalation, in contact with skin and if swallowed.
R33: Danger of cumulative effects.
R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Statements: 28-36/37-45-61
S28: After contact with skin, wash immediately with plenty of soap-suds.
S36/37: Wear suitable protective clothing and gloves.
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S61: Avoid release to the environment. Refer to special instructions / safety data sheets.
RIDADR: UN 1711 6.1/PG 2
WGK Germany: 2
RTECS: ZE8750000
HazardClass: 6.1
PackingGroup: II
HS Code: 29214910
A poison. Moderately toxic by ingestion. Mutation data reported. When heated to decomposition it emits toxic fumes of NO_x. See also XYLIDINE; 2,4-XYLIDINE; 2,5-XYLIDINE; 2,6-XYLIDINE; 3,4-XYLIDINE; 3,5-XYLIDINE; 2,4-XYLIDINE HYDROCHLORIDE; 2,5-XYLIDINE HYDROCHLORIDE.

2,3-Xylidine Standards and Recommendations

DFG MAK: (all isomers except 2,4-xylidene) 5 ppm (25 mg/m³)

2,3-Xylidine Specification

1. Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
2. Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.
3. Personal Protection: Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
4. Fire Fighting: Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. To extinguish fire, use water fog, dry chemical, carbon dioxide, or regular foam. Do NOT get water inside containers.
5. Reactivity Profile 2,3-Dimethylaniline reacts with strong oxidizing agents and hypochlorite bleaches . Neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.

Product Name

2,3-Dimethylaniline

Synthetic route

2,3-Xylidine Chemical Properties

2,3-Xylidine Uses

2,3-Xylidine Production

2,3-Xylidine Toxicity Data With Reference

2,3-Xylidine Consensus Reports

2,3-Xylidine Safety Profile

2,3-Xylidine Standards and Recommendations

2,3-Xylidine Specification

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