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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

2,3-Xylidine Manufacturer/High quality/Best price/In stock

Cas:87-59-2

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 2,3-Dimethylaniline supplier in China

Cas:87-59-2

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Jinan Finer Chemical Co., Ltd

Product Description Product website: http://www.finerchem.com Product Name 2,3-Dimethylphenylamine CAS No. 87-59-2 Appearance

2,3-Dimethylaniline

Cas:87-59-2

Min.Order:1 Gram

FOB Price: $8.0

Type:Lab/Research institutions

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Henan Allgreen Chemical Co.,Ltd

high quality Appearance:White or off white powder Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai

2,3-Dimethylaniline

Cas:87-59-2

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 2,3-xylidine

Cas:87-59-2

Min.Order:1

Negotiable

Type:Other

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Chemwill Asia Co., Ltd.

CHemwill -- 2,3-Dimethylaniline

Cas:87-59-2

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Manufacturers

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Hebei yanxi chemical co.,LTD.

Hebei Yanxi Chemical Co., Ltd. is a professional research, development and production of lead acetate benzene acetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low car

2,3-Dimethylaniline

Cas:87-59-2

Min.Order:1 Metric Ton

FOB Price: $1.0 / 2.0

Type:Trading Company

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Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

top 2,3-Dimethylaniline

Cas:87-59-2

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

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Henan Sinotech Import&Export Corporation

2,3-Dimethylaniline(2,3-Xylidine) CAS No.: 87-59-2 UN No.:1711 Appearance: Colorless or light brown liquid Assay: ≥99.0% Water (by K Fisher): ≤0.2% [Packing&Storage] 2,3-Dimethylaniline stores in a w

2,3-Dimethylaniline(2,3-Xylidine)

Cas:87-59-2

Min.Order:1600 Kilogram

FOB Price: $1.0

Type:Other

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:87-59-2

Cas:87-59-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Lonwin Chemical Group Limited

2,3-Dimethylaniline CAS: 87-59-2 Superiority Item Standard Appearance Light yellow or light brown liquid Purity,% 99min Moisture, % 0.2max

Factory supply 2,3-Dimethylaniline

Cas:87-59-2

Min.Order:1 Kilogram

Negotiable

Type:Other

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

2,3-Dimethylaniline

Cas:87-59-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality 2,3-Dimethylaniline

Cas:87-59-2

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:Brown liquid Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:25kg/drum, or as per your request. Application:Used as Pharmaceutical Intermediates Tr

2,3-Xylidine

Cas:87-59-2

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Siwei Development Group Ltd.

Product name: 2,3-Dimethylaniline CAS No.:87-59-2 Molecule Formula:C8H11N Molecule Weight:121.98 Purity: 99.0% Package: 200kg/drum Description:Colorless to dark red liquid Manufacture Standards:Enterprise Standard

Best Quality 2,3-Dimethylaniline

Cas:87-59-2

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

2,3-Xylidine Manufacturer/High quality/Best price/In stock

Cas:87-59-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou ZeErRui Chemical Co., Ltd.

ProductName:2,3-Dimethylaniline CAS:87-59-2 Molecular Formula:C8H11N Molecular Weight:121.18000 Appearance:Colorless or light brown liquid Assay:≥99.0% Water content:≤0.20% Appearance:Colorless transparent liquid Storage:keep

2,3-Dimethylaniline

Cas:87-59-2

Min.Order:10 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

2,3-Xylidine

Cas:87-59-2

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

SAGECHEM LIMITED

SAGECHEM is a chemical R&D, manufacturing and distribution company in China since 2009, including pharmaceutical intermediates, agrochemical, dyestuff intermediates, organosilicone, API and etc. We also offer a full range of services in custom synthe

SAGECHEM/2,3-Dimethyianiline

Cas:87-59-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Beijing Greenchem Technology Co.,Ltd. ( Panjin Greenchem Technology Co.Ltd .)

Capability on chemical synthesis1. Beijing High-Tech Enterprises2. Strong R&D Team3. 8 years of experiences in R & D of high-tech Catalyst;4. 5000 production techniques, 69 items of national patents, and 360 kinds of products on sales;5. The producti

2,3-Dimethyianiline

Cas:87-59-2

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

GIHI CHEMICALS CO.,LIMITED

high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,Pharmaceutical intermediates Transportation:air,sea,courier

2,3-Dimethylaniline

Cas:87-59-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Fortuna Chemical Co.,Ltd

1.High quality : the purity is 99% min . through multiple producing procedures. 2.Competitive price : low price because of our skilled production technolpgy ,save the production cost at most , and give big profit room to our customers325.Safe and fa

2,3-Dimethylaniline

Cas:87-59-2

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

2,3-Dimethylaniline

Cas:87-59-2

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard

factory supply CAS 87-59-2 with competitive price

Cas:87-59-2

Min.Order:1 Kilogram

FOB Price: $112.0

Type:Trading Company

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Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

2,3-Xylidine

Cas:87-59-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Ocean Chemical Co., Ltd.

★.Best quality according to requirement ★.Competitive price in China market ★.Mature Technical support ★.Professional logistic support

2,3-Dimethylaniline

Cas:87-59-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen AmoyChem Co.,Ltd

Amoychem is committed to providing the top-quality chemical products and services Internationally. We offer our customers with friendly, professional service and reliable, high performance products that have been manufactured according to the accredi

2,3-Dimethylaniline

Cas:87-59-2

Min.Order:0

Negotiable

Type:Other

inquiry

Hubei Langyou International Trading Co., Ltd

2,3-Dimethylaniline Application:2,3-Dimethylaniline

2,3-Dimethylaniline

Cas:87-59-2

Min.Order:0

Negotiable

Type:Other

inquiry

Wuhan ZeShanCheng Biomedical Technology Co., Ltd.

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highl

2,3-Xylidine

Cas:87-59-2

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hunan Longxianng Runhui Trading Co.,Ltd

2,3-DimethylanilineAppearance:White powder Storage:Shading, sealed and preserved. Package:25 kg/barrels Application:An organic synthetic intermediate used in the synthesis of medicine. Transportation:By express (Door to door) such as FEDEX, DHL, EMS

2,3-Dimethylaniline

Cas:87-59-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

1-tert-butyl-N-(2,3-dimethylphenyl)-1,1-dimethylsilanamine
1321455-35-9

1-tert-butyl-N-(2,3-dimethylphenyl)-1,1-dimethylsilanamine

2,3-Dimethylaniline
87-59-2

2,3-Dimethylaniline

Conditions
ConditionsYield
With silica gel In ethanol; water at 20℃; for 2h;100%
2,3-dimethylnitrobenzene
83-41-0

2,3-dimethylnitrobenzene

2,3-Dimethylaniline
87-59-2

2,3-Dimethylaniline

Conditions
ConditionsYield
With sodium sulfide; tetrabutylammomium bromide In water; toluene at 80℃; for 0.75h; Zinin reduction;96.8%
Stage #1: 2,3-dimethylnitrobenzene In water at 20℃; for 0.05h; Green chemistry;
Stage #2: With glycerol In water at 20℃; for 1.5h; Green chemistry;
95%
With sodium tetrahydroborate In water at 60 - 70℃; for 0.133333h; Green chemistry;95%
2-amino-6-methylbenzoic acid methyl ester
18595-13-6

2-amino-6-methylbenzoic acid methyl ester

2,3-Dimethylaniline
87-59-2

2,3-Dimethylaniline

Conditions
ConditionsYield
With sodium bis(2-methoxyethoxy)aluminium dihydride In toluene for 3h; Heating;75%
o-xylene
95-47-6

o-xylene

A

4-amino-o-xylene
95-64-7

4-amino-o-xylene

B

2,3-Dimethylaniline
87-59-2

2,3-Dimethylaniline

Conditions
ConditionsYield
With tris-(2-chloro-ethyl)-amine; trifluorormethanesulfonic acid; trifluoroacetic acid In chloroform at 25℃; for 1h;A 44%
B 30%
bei der Nitrierung und Hydrierung des Reaktionsprodukts in Gegenwart von Nickel bei 180-190grad;
With xenon difluoride; trimethylsilyl isocyanate; trifluorormethanesulfonic acid In dichloromethane at -78℃;
3,4-dimethylbenzoic acid
619-04-5

3,4-dimethylbenzoic acid

A

3,4-Dimethylphenol
95-65-8

3,4-Dimethylphenol

B

4-amino-o-xylene
95-64-7

4-amino-o-xylene

C

2,3-Dimethylaniline
87-59-2

2,3-Dimethylaniline

Conditions
ConditionsYield
With ammonia; water; copper(II) oxide at 220℃; for 0.5h;A 3.5%
B 43.1%
C 0.9%
2,3-dibromo-5,6-dimethyl-aniline

2,3-dibromo-5,6-dimethyl-aniline

2,3-Dimethylaniline
87-59-2

2,3-Dimethylaniline

Conditions
ConditionsYield
With sodium amalgam
Methyl fluoride
593-53-3

Methyl fluoride

1-amino-3-methylbenzene
108-44-1

1-amino-3-methylbenzene

A

2,5-Dimethylaniline
95-78-3

2,5-Dimethylaniline

B

4-amino-o-xylene
95-64-7

4-amino-o-xylene

C

2,3-Dimethylaniline
87-59-2

2,3-Dimethylaniline

Conditions
ConditionsYield
With oxygen In gaseous matrix at 80℃; Irradiation;A 29 % Spectr.
B 25 % Spectr.
C 46 % Spectr.
2,3-Dichloro-[1,4]naphthoquinone; compound with 2,3-dimethyl-phenylamine

2,3-Dichloro-[1,4]naphthoquinone; compound with 2,3-dimethyl-phenylamine

A

2,3-Dichloro-1,4-naphthoquinone
117-80-6

2,3-Dichloro-1,4-naphthoquinone

B

2,3-Dimethylaniline
87-59-2

2,3-Dimethylaniline

Conditions
ConditionsYield
In dichloromethane at 21.9℃; Equilibrium constant;
2,3-Dichloro-[1,4]naphthoquinone; compound with 2,3-dimethyl-phenylamine

2,3-Dichloro-[1,4]naphthoquinone; compound with 2,3-dimethyl-phenylamine

A

2,3-Dichloro-1,4-naphthoquinone
117-80-6

2,3-Dichloro-1,4-naphthoquinone

B

2,3-Dimethylaniline
87-59-2

2,3-Dimethylaniline

Conditions
ConditionsYield
In dichloromethane at 21.9℃; Equilibrium constant;
3-nitro-o-xylene

3-nitro-o-xylene

2,3-Dimethylaniline
87-59-2

2,3-Dimethylaniline

Conditions
ConditionsYield
With iron; acetic acid
vic nitro-o-xylene

vic nitro-o-xylene

2,3-Dimethylaniline
87-59-2

2,3-Dimethylaniline

Conditions
ConditionsYield
With iron; acetic acid
xylidine

xylidine

2,3-Dimethylaniline
87-59-2

2,3-Dimethylaniline

Conditions
ConditionsYield
With acetic acid in mehrere Stufen;
methanol
67-56-1

methanol

aniline
62-53-3

aniline

A

2,3-Dimethylaniline
87-59-2

2,3-Dimethylaniline

B

Dimethyl-p-toluidine
99-97-8

Dimethyl-p-toluidine

C

homologous/ues (CH3)2C6H3*N(CH3)2 and (CH3)3C6H2*N(CH3)2

homologous/ues (CH3)2C6H3*N(CH3)2 and (CH3)3C6H2*N(CH3)2

D

(CH3)4C6H*N(CH3)2

(CH3)4C6H*N(CH3)2

Conditions
ConditionsYield
at 280 - 300℃; bei der Einwirkung auf salzsaures Anilin im Autoklaven;
hydrogenchloride
7647-01-0

hydrogenchloride

4-(2,3-dimethyl-phenylazo)-2,3-dimethyl-aniline
53877-42-2

4-(2,3-dimethyl-phenylazo)-2,3-dimethyl-aniline

tin

tin

A

1,4-diamino-2,3-dimethylbenzene
5306-96-7

1,4-diamino-2,3-dimethylbenzene

B

2,3-Dimethylaniline
87-59-2

2,3-Dimethylaniline

N-(2,3-dimethylphenyl)hydroxylamine
3096-62-6

N-(2,3-dimethylphenyl)hydroxylamine

alcoholic KOH-solution

alcoholic KOH-solution

A

bis-(2,3-dimethyl-phenyl)-diazene-N-oxide
19618-11-2

bis-(2,3-dimethyl-phenyl)-diazene-N-oxide

B

2,3-Dimethylaniline
87-59-2

2,3-Dimethylaniline

C

3-nitro-o-xylene

3-nitro-o-xylene

sulfuric acid
7664-93-9

sulfuric acid

tetramethyl-[1,4]benzoquinone-(2,3-dimethyl-phenylimine)-imine
861319-17-7

tetramethyl-[1,4]benzoquinone-(2,3-dimethyl-phenylimine)-imine

A

Duroquinone
527-17-3, 70128-24-4

Duroquinone

B

2,3-Dimethylaniline
87-59-2

2,3-Dimethylaniline

2,3-dimethyl-6-(trisopropylsilyl)aniline
476170-48-6

2,3-dimethyl-6-(trisopropylsilyl)aniline

2,3-Dimethylaniline
87-59-2

2,3-Dimethylaniline

Conditions
ConditionsYield
With trifluoroacetic acid In hexane for 5h; Heating;0.65 g
2-methoxycarbonyl-3-methyl-6-(trisopropylsilyl)aniline
110036-12-9

2-methoxycarbonyl-3-methyl-6-(trisopropylsilyl)aniline

2,3-Dimethylaniline
87-59-2

2,3-Dimethylaniline

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 3.85 g / Red-Al / toluene / 3 h / Heating
2: 0.65 g / trifluoroacetic acid / hexane / 5 h / Heating
View Scheme
2-methoxycarbonyl-3-methyl-6,N-bis(trisopropylsilyl)aniline
476170-47-5

2-methoxycarbonyl-3-methyl-6,N-bis(trisopropylsilyl)aniline

2,3-Dimethylaniline
87-59-2

2,3-Dimethylaniline

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 91 percent / KF; HCl; water / methanol / 2 h / Heating
2: 75 percent / Red-Al / toluene / 3 h / Heating
View Scheme
Multi-step reaction with 3 steps
1: 62 percent / KF; HCl; water / methanol / 2 h / Heating
2: 3.85 g / Red-Al / toluene / 3 h / Heating
3: 0.65 g / trifluoroacetic acid / hexane / 5 h / Heating
View Scheme
dimethylaniline oxide

dimethylaniline oxide

1-amino-9,10-anthracenedione
82-45-1

1-amino-9,10-anthracenedione

A

dianthraquinone-N,N'-dihydroazine

dianthraquinone-N,N'-dihydroazine

B

2,3-Dimethylaniline
87-59-2

2,3-Dimethylaniline

Conditions
ConditionsYield
With potassium hydroxide; sodium hydroxide
2,3-Dimethylaniline
87-59-2

2,3-Dimethylaniline

trifluoroacetic anhydride
407-25-0

trifluoroacetic anhydride

N-(2,3-dimethylphenyl)-2,2,2-trifluoroacetamide
14719-31-4

N-(2,3-dimethylphenyl)-2,2,2-trifluoroacetamide

Conditions
ConditionsYield
In dichloromethane for 1h; Further stages;100%
With triethylamine In dichloromethane for 1h; Ambient temperature;87%
In diethyl ether
In dichloromethane at 0 - 20℃; for 12h;
2-Bromoacetyl bromide
598-21-0

2-Bromoacetyl bromide

2,3-Dimethylaniline
87-59-2

2,3-Dimethylaniline

2-bromo-N-(2',3'-dimethylphenyl)acetamide
349120-89-4

2-bromo-N-(2',3'-dimethylphenyl)acetamide

Conditions
ConditionsYield
With triethylamine at 0℃; for 1h; Inert atmosphere;100%
With sodium carbonate In water pH=9 - 10;99%
With N-ethyl-N,N-diisopropylamine In dichloromethane at 20℃; for 1.5h; bromoacetylation;
di-tert-butyl dicarbonate
24424-99-5

di-tert-butyl dicarbonate

2,3-Dimethylaniline
87-59-2

2,3-Dimethylaniline

N-tert-butyloxycarbonyl-2,3-dimethylaniline
876353-79-6

N-tert-butyloxycarbonyl-2,3-dimethylaniline

Conditions
ConditionsYield
With sodium carbonate In methanol at 20℃; for 1.5h;100%
In neat (no solvent) at 80℃; for 0.166667h; Green chemistry; chemoselective reaction;98%
at 20℃; for 0.0833333h; Green chemistry;95%
With pyridinium trifluroacetate In neat (no solvent) at 20℃; for 0.3h; Green chemistry;93%
In tetrahydrofuran for 12h; Reflux;
triethanolamine
102-71-6

triethanolamine

2,3-Dimethylaniline
87-59-2

2,3-Dimethylaniline

6,7-dimethyl-1H-indole
55199-24-1

6,7-dimethyl-1H-indole

Conditions
ConditionsYield
With tin(ll) chloride; ruthenium trichloride; triphenylphosphine In 1,4-dioxane at 180℃; for 20h;99%
2,3-Dimethylaniline
87-59-2

2,3-Dimethylaniline

MORPHIN
57-27-2

MORPHIN

codeine
76-57-3

codeine

Conditions
ConditionsYield
With potassium carbonate In 5,5-dimethyl-1,3-cyclohexadiene99%
N-tert-butoxycarbonyl-L-leucine
13139-15-6

N-tert-butoxycarbonyl-L-leucine

2,3-Dimethylaniline
87-59-2

2,3-Dimethylaniline

(S)-Boc-L-Leu-N'-(2,3-dimethylphenyl)amide

(S)-Boc-L-Leu-N'-(2,3-dimethylphenyl)amide

Conditions
ConditionsYield
Stage #1: N-tert-butoxycarbonyl-L-leucine With 4-methyl-morpholine; isobutyl chloroformate In tetrahydrofuran at 0℃; for 0.5h; Inert atmosphere; Schlenk technique;
Stage #2: 2,3-Dimethylaniline In tetrahydrofuran at 0 - 20℃; Inert atmosphere; Schlenk technique;
99%
acetic anhydride
108-24-7

acetic anhydride

2,3-Dimethylaniline
87-59-2

2,3-Dimethylaniline

N-(2,3-dimethylphenyl)acetamide
134-98-5

N-(2,3-dimethylphenyl)acetamide

Conditions
ConditionsYield
With Ni2B-Cu2O nanocomposite In neat (no solvent) at 40℃; for 0.0166667h; Reagent/catalyst;98%
In chloroform at 20℃; for 2h;88%
With pyridine at 0 - 20℃;80%
Benzoyl isothiocyanate
532-55-8

Benzoyl isothiocyanate

2,3-Dimethylaniline
87-59-2

2,3-Dimethylaniline

1-benzoyl-3-(2,3-dimethylphenyl)thiourea
83697-76-1

1-benzoyl-3-(2,3-dimethylphenyl)thiourea

Conditions
ConditionsYield
In acetone at 20℃; for 1h;98%
In tetrahydrofuran at 60 - 65℃; for 0.166667h; Microwave irradiation;92%
In acetone85%
N-Boc-D-Leu
16937-99-8

N-Boc-D-Leu

2,3-Dimethylaniline
87-59-2

2,3-Dimethylaniline

N-Boc-D-Leu-N'-(2,3-dimethylphenyl)amide

N-Boc-D-Leu-N'-(2,3-dimethylphenyl)amide

Conditions
ConditionsYield
Stage #1: N-Boc-D-Leu With 4-methyl-morpholine; isobutyl chloroformate In tetrahydrofuran at 0℃; for 0.5h; Inert atmosphere; Schlenk technique;
Stage #2: 2,3-Dimethylaniline In tetrahydrofuran at 0 - 20℃; Inert atmosphere; Schlenk technique;
98%
4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

2,3-Dimethylaniline
87-59-2

2,3-Dimethylaniline

C15H17NO

C15H17NO

Conditions
ConditionsYield
With 2'-dicyclohexylphosphanyl-6-hydroxy-biphenyl-3-sulfonic acid; palladium diacetate; sodium t-butanolate In diethylene glycol dimethyl ether at 120℃; for 14h; Buchwald-Hartwig Coupling; Inert atmosphere;98%
benzenesulfonyl chloride
98-09-9

benzenesulfonyl chloride

2,3-Dimethylaniline
87-59-2

2,3-Dimethylaniline

2,3-dimethyl-N-(phenylsulfonyl)aniline
126494-77-7

2,3-dimethyl-N-(phenylsulfonyl)aniline

Conditions
ConditionsYield
With pyridine In dichloromethane97%
C10H14O5
845870-02-2

C10H14O5

2,3-Dimethylaniline
87-59-2

2,3-Dimethylaniline

dimethyl (1S,2S,4S,5S)-4-(2,3-dimethylphenylamino)-5-hydroxycyclohexane-1,2-dicarboxylate
1254946-88-7

dimethyl (1S,2S,4S,5S)-4-(2,3-dimethylphenylamino)-5-hydroxycyclohexane-1,2-dicarboxylate

Conditions
ConditionsYield
With indium(III) bromide In dichloromethane at 20℃; for 15h;97%
2-azidobenzaldehyde
16714-25-3

2-azidobenzaldehyde

2,3-Dimethylaniline
87-59-2

2,3-Dimethylaniline

C15H14N2

C15H14N2

Conditions
ConditionsYield
at 100℃; under 10343.2 Torr; Microwave irradiation;97%
phenylethane 1,2-diol
93-56-1

phenylethane 1,2-diol

2,3-Dimethylaniline
87-59-2

2,3-Dimethylaniline

6,7-dimethyl-2-phenyl-1H-indole
33555-28-1

6,7-dimethyl-2-phenyl-1H-indole

Conditions
ConditionsYield
With tetrafluoroboric acid diethyl ether; {[(PCy3)(CO)RuH]4(μ-O)(μ-OH)2}; cyclopentene In 1,4-dioxane at 120℃; for 14h; Sealed tube; Schlenk technique; Inert atmosphere; regioselective reaction;97%
2-acetyl-benzoic acid
577-56-0

2-acetyl-benzoic acid

2,3-Dimethylaniline
87-59-2

2,3-Dimethylaniline

2-(2,3-dimethylphenyl)-3-methyleneisoindolin-1-one

2-(2,3-dimethylphenyl)-3-methyleneisoindolin-1-one

Conditions
ConditionsYield
With 3-(1,1-dioxido-4-(3-(3-(3-sulfopropyl)-1H-imidazol-3-ium-1-yl)propyl)thiomorpholino-4-ium)propane-1-sulfonate trifluoromethanesulfonate In acetic acid butyl ester at 100℃; for 8h; Green chemistry;97%
chloroacetyl chloride
79-04-9

chloroacetyl chloride

2,3-Dimethylaniline
87-59-2

2,3-Dimethylaniline

2-chloro-N-(2, 3-dimethylphenyl)acetamide
2564-07-0

2-chloro-N-(2, 3-dimethylphenyl)acetamide

Conditions
ConditionsYield
With sodium hydroxide In dichloromethane; water for 18h;96%
With potassium carbonate In acetone at 20℃;83%
In benzene for 5h; Heating;60%
2,3-Dimethylaniline
87-59-2

2,3-Dimethylaniline

2-chloro-N-(2, 3-dimethylphenyl)acetamide
2564-07-0

2-chloro-N-(2, 3-dimethylphenyl)acetamide

Conditions
ConditionsYield
96%
bromochlorobenzene
106-39-8

bromochlorobenzene

2,3-Dimethylaniline
87-59-2

2,3-Dimethylaniline

2,3-dimethyl-4',4"-dichlorotriphenylamine
1616092-86-4

2,3-dimethyl-4',4"-dichlorotriphenylamine

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; triphenylphosphine; sodium t-butanolate In o-xylene for 12h; Inert atmosphere; Reflux; Schlenk technique;96%
3-chlorobenzoyl isothiocyanate
66090-36-6

3-chlorobenzoyl isothiocyanate

2,3-Dimethylaniline
87-59-2

2,3-Dimethylaniline

1-(3-chlorobenzoyl)-3-(2,3-dimethylphenyl)thiourea

1-(3-chlorobenzoyl)-3-(2,3-dimethylphenyl)thiourea

Conditions
ConditionsYield
In tetrahydrofuran at 60 - 65℃; under 760.051 Torr; for 0.025h; Microwave irradiation;96%
potassium methanethiolate
26385-24-0

potassium methanethiolate

2,3-Dimethylaniline
87-59-2

2,3-Dimethylaniline

1,2-dimethyl-3-(methylsulfanyl)benzene
66794-10-3

1,2-dimethyl-3-(methylsulfanyl)benzene

Conditions
ConditionsYield
Stage #1: 2,3-Dimethylaniline With sulfuric acid at 50℃; for 0.5h;
Stage #2: With sodium nitrite In water at -10 - -5℃; for 1h;
Stage #3: potassium methanethiolate In water at 20 - 35℃; for 4h;
95.8%
2,3-Dimethylaniline
87-59-2

2,3-Dimethylaniline

sodium thiomethoxide
5188-07-8

sodium thiomethoxide

1,2-dimethyl-3-(methylsulfanyl)benzene
66794-10-3

1,2-dimethyl-3-(methylsulfanyl)benzene

Conditions
ConditionsYield
Stage #1: 2,3-Dimethylaniline With hydrogenchloride In water at 50℃; for 0.5h;
Stage #2: With sodium nitrite In water at -5 - 0℃; for 1h;
Stage #3: sodium thiomethoxide In water at 35℃; for 2h;
95.5%
2,3-Dimethylaniline
87-59-2

2,3-Dimethylaniline

3-nitrobenzenesulphonyl chloride
121-51-7

3-nitrobenzenesulphonyl chloride

3-nitro-N-(2,3-dimethylphenyl)benzenesulfonamide
250697-59-7

3-nitro-N-(2,3-dimethylphenyl)benzenesulfonamide

Conditions
ConditionsYield
With 4-methyl-morpholine In dichloromethane at 0℃;95%
With 4-methyl-morpholine In dichloromethane at 0℃; for 12h; Acylation;95%
With 4-methyl-morpholine In dichloromethane at 0 - 20℃; Substitution;
tert-butyldimethylsilyl chloride
18162-48-6

tert-butyldimethylsilyl chloride

2,3-Dimethylaniline
87-59-2

2,3-Dimethylaniline

1-tert-butyl-N-(2,3-dimethylphenyl)-1,1-dimethylsilanamine
1321455-35-9

1-tert-butyl-N-(2,3-dimethylphenyl)-1,1-dimethylsilanamine

Conditions
ConditionsYield
Stage #1: 2,3-Dimethylaniline With methyllithium In 2-methyltetrahydrofuran; diethyl ether at 0℃; Inert atmosphere;
Stage #2: tert-butyldimethylsilyl chloride In 2-methyltetrahydrofuran; diethyl ether at 0 - 20℃; Inert atmosphere;
95%
phenylacetylene
536-74-3

phenylacetylene

2,3-Dimethylaniline
87-59-2

2,3-Dimethylaniline

2,3-dimethyl-N-(1-phenylethylidene)benzenamine
1272320-35-0

2,3-dimethyl-N-(1-phenylethylidene)benzenamine

Conditions
ConditionsYield
With silver trifluoromethanesulfonate; C17H25Cl2N3OPtS In toluene at 120℃; for 12h; Reagent/catalyst;95%
With trifluorormethanesulfonic acid; [(S(CH2CH2C3H2N2(Bn))2-κ3C,C',S)PdBr]Br In toluene at 100℃; for 12h;48 %Chromat.
para-bromotoluene
106-38-7

para-bromotoluene

2,3-Dimethylaniline
87-59-2

2,3-Dimethylaniline

2,3,4’,4’’-tetramethyltriphenylamine
1616092-85-3

2,3,4’,4’’-tetramethyltriphenylamine

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; triphenylphosphine; sodium t-butanolate In o-xylene for 12h; Inert atmosphere; Reflux; Schlenk technique;95%
2-bromoanisole
578-57-4

2-bromoanisole

2,3-Dimethylaniline
87-59-2

2,3-Dimethylaniline

(2,3-dimethyl-phenyl)-(2-methoxyphenyl)-amine

(2,3-dimethyl-phenyl)-(2-methoxyphenyl)-amine

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); (RSp,SRp)-tert-butyl([2.2]paracyclophan-4-yl)phosphine oxide; sodium t-butanolate In toluene at 105℃; Buchwald-Hartwig Coupling;95%
With 2'-dicyclohexylphosphanyl-6-methoxy-biphenyl-3-sulfonic acid; palladium diacetate; sodium t-butanolate In diethylene glycol dimethyl ether at 120℃; for 48h; Buchwald-Hartwig Coupling; Inert atmosphere;27%
2-bromonaphthalene
580-13-2

2-bromonaphthalene

2,3-Dimethylaniline
87-59-2

2,3-Dimethylaniline

(2,3-dimethylphenyl)(2-naphthyl)amine

(2,3-dimethylphenyl)(2-naphthyl)amine

Conditions
ConditionsYield
With 2'-dicyclohexylphosphanyl-6-methoxy-biphenyl-3-sulfonic acid; palladium diacetate; sodium t-butanolate In diethylene glycol dimethyl ether at 120℃; for 96h; Buchwald-Hartwig Coupling; Inert atmosphere;95%
2,3-Dimethylaniline
87-59-2

2,3-Dimethylaniline

ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

mefenamic Acid
61-68-7

mefenamic Acid

Conditions
ConditionsYield
Stage #1: ortho-chlorobenzoic acid With sodium carbonate In N,N-dimethyl-formamide at 80℃; for 0.5h;
Stage #2: 2,3-Dimethylaniline With manganese(II) acetate In water; N,N-dimethyl-formamide; toluene at 120 - 130℃; Reagent/catalyst;
94.8%
Stage #1: ortho-chlorobenzoic acid With sodium carbonate In N,N-dimethyl-formamide at 80℃; for 1.16667h;
Stage #2: 2,3-Dimethylaniline With copper In water; N,N-dimethyl-formamide; toluene at 104 - 123℃;
91.3%
With copper; sodium carbonate In N,N-dimethyl-formamide at 140℃; for 2h;90%
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