3-Fluorotoluene supplier | CasNO.352-70-5

Name
3-Fluorotoluene
EINECS 206-524-8
CAS No. 352-70-5
Article Data76
CAS DataBase
Density 1.001 g/cm³
Solubility immiscible with water
Melting Point -87 °C
Formula C₇H₇F
Boiling Point 118.2 °C at 760 mmHg
Molecular Weight 110.131
Flash Point 9.4 °C
Transport Information UN 2388 3/PG 2
Appearance clear colorless to light yellow liquid
Safety 16-26-36-37/39
Risk Codes 11-36/37/38
Molecular Structure
Hazard Symbols F, Xi
Synonyms Toluene, m-fluoro- (8CI);m-Fluorotoluene;Toluene, m-fluoro-;1-chloro-4-fluoro-benzene;1-Fluoro-3-methylbenzene;1-Methyl-3-fluorobenzene;Benzene, 1-fluoro-3-methyl-;m-Fluorotoluene [UN2388] [Flammable liquid];
PSA 0.00000
LogP 2.13410

Synthetic route

: 108-44-1
1-amino-3-methylbenzene

: 352-70-5
m-Fluorotoluene

Conditions

Conditions	Yield
With pyridine hydrogenfluoride; sodium nitrite 1.) O deg C, 20 min, 2.) 70 deg C, 1 h;	98%
Stage #1: 1-amino-3-methylbenzene With hydrogen fluoride at -5 - 0.5℃; Flow reactor; Large scale; Stage #2: With nitrosylsulfuric acid at 0.5 - 2℃; Flow reactor; Large scale;	98.3%
Stage #1: 1-amino-3-methylbenzene With hydrogen fluoride at 0℃; for 3h; Stage #2: With sodium nitrite at -5 - 35℃; for 4h;	90.1%

: 1202873-16-2
3-fluoro-1-methyl-2,5-cyclohexadiene-1-carboxylic acid

: 352-70-5
m-Fluorotoluene

Conditions

Conditions	Yield
With chlorosulfonic acid In dichloromethane at 0℃; for 0.166667h;	82%

: 1493-13-6
trifluorormethanesulfonic acid

: 1422-76-0
3-methylbenzenediazonium tetrafluoroborate

A: 352-70-5
m-Fluorotoluene

B: 32578-31-7
3-tolyl triflate

Conditions

Conditions	Yield
at 90℃; for 1h;	A n/a B 75%

...Expand

: 106-43-4
para-chlorotoluene

A: 352-32-9
p-fluorotoluene

B: 95-52-3
2-Fluorotoluene

C: 352-70-5
m-Fluorotoluene

Conditions

Conditions	Yield
With Al2CuF8 Gas phase; Inert atmosphere;	A 71% B 5% C 10%
With silver fluoride at 350℃; Product distribution / selectivity; Gas phase;	A 20.8% B 0.6% C 35.8%

...Expand

: 456-41-7
1-(Bromomethyl)-3-fluorobenzene

A: 352-70-5
m-Fluorotoluene

B: 351-22-4
1,2-bis(3-fluorophenyl)ethane

Conditions

Conditions	Yield
With magnesium at 600℃;	A 12% B 67%

: potassium trifluoro(3-methylphenyl)borate

: 352-70-5
m-Fluorotoluene

Conditions

Conditions	Yield
With lithium hydroxide monohydrate; silver trifluoromethanesulfonate; Selectfluor In ethyl acetate at 55℃; Sealed tube;	66%
With copper(I) trifluoromethanesulfonate bis(trimethylacetonitrile) complex; 1-fluoro-2,4,6-trimethylpyridinium trifluoromethanesulfonate In ethyl acetate at 40℃; for 12h; Inert atmosphere; Glovebox;	67 %Spectr.

: C7H7N2(1+)*F6P(1-)

: 352-70-5
m-Fluorotoluene

Conditions

Conditions	Yield
With boron trifluoride diethyl etherate at 120 - 125℃; for 1h;	65%

: 108-41-8
1-chloro-3-methylbenzene

: 352-70-5
m-Fluorotoluene

Conditions

Conditions	Yield
With Al2CuF8 Gas phase; Inert atmosphere;	61%

: 95-49-8
2-methylchlorobenzene

A: 95-52-3
2-Fluorotoluene

B: 352-70-5
m-Fluorotoluene

Conditions

Conditions	Yield
With Al2CuF8 Gas phase; Inert atmosphere;	A 60% B 7%

: 99-04-7
m-Toluic acid

: 352-70-5
m-Fluorotoluene

Conditions

Conditions	Yield
Stage #1: m-Toluic acid With tetrakis(acetonitrile)copper(I)tetrafluoroborate; tetrabutylammonium tetra(tert-butyl alcohol) coordinate fluoride; copper(II) bis(trifluoromethanesulfonate) In acetonitrile at 23℃; for 0.5h; Sealed tube; Inert atmosphere; Stage #2: In acetonitrile at 35℃; Irradiation; Sealed tube; Inert atmosphere;	57%

: 546-67-8
lead(IV) tetraacetate

: 109-63-7
trifluoroborane diethyl ether

: 108-88-3
toluene

A: 352-32-9
p-fluorotoluene

B: 95-52-3
2-Fluorotoluene

C: 352-70-5
m-Fluorotoluene

Conditions

Conditions	Yield
mercury(II) diacetate Stirring of toluene in BF3*Et2O contg. Pb(OAc)4 and overnight at room temp.; GC anal. 13% recovery of toluene.;	A 43% B 12% C 4%

...Expand

: 108-41-8
1-chloro-3-methylbenzene

A: 352-32-9
p-fluorotoluene

B: 95-52-3
2-Fluorotoluene

C: 352-70-5
m-Fluorotoluene

Conditions

Conditions	Yield
With silver fluoride at 350℃; Product distribution / selectivity; Gas phase;	A 15% B 6.7% C 25.7%

...Expand

: 920-66-1
1,1,1,3',3',3'-hexafluoro-propanol

: 1422-76-0
3-methylbenzenediazonium tetrafluoroborate

A: 352-70-5
m-Fluorotoluene

B: 1,1,1,3,3,3-hexafluoro-2-propyl 3-methylphenyl ether

Conditions

Conditions	Yield
at 20℃; Irradiation;	A 15% B 85 % Chromat.

...Expand

: 95-49-8
2-methylchlorobenzene

A: 352-32-9
p-fluorotoluene

B: 95-52-3
2-Fluorotoluene

C: 352-70-5
m-Fluorotoluene

Conditions

Conditions	Yield
With silver fluoride at 350℃; Product distribution / selectivity; Gas phase;	A 0.5% B 13.9% C 14.4%

...Expand

: 462-06-6
fluorobenzene

: 593-53-3
Methyl fluoride

A: 352-32-9
p-fluorotoluene

B: 95-52-3
2-Fluorotoluene

C: 352-70-5
m-Fluorotoluene

Conditions

Conditions	Yield
at 37.5℃; Product distribution; Irradiation; various fluorobenzenes, other conditions;

...Expand

: 75-45-6
Chlorodifluoromethane

A: 462-06-6
fluorobenzene

B: 352-32-9
p-fluorotoluene

C: 95-52-3
2-Fluorotoluene

D: 352-70-5
m-Fluorotoluene

E: 71-43-2
benzene

Conditions

Conditions	Yield
With methylcyclopentadiene at 650.9℃; Product distribution; Mechanism; conditions of pulse gas compression, other temperatures;

...Expand

: 624-31-7
4-tolyl iodide

A: 352-70-5
m-Fluorotoluene

B: 108-41-8
1-chloro-3-methylbenzene

C: 591-17-3
meta-bromotoluene

D: 106-43-4
para-chlorotoluene

E: 106-38-7
para-bromotoluene

F: 108-39-4
3-methyl-phenol

Conditions

Conditions	Yield
With potassium hydroxide; potassium chloride; sodium fluoride; potassium bromide In water at 308℃; Mechanism; Product distribution;	A 1.37 % Chromat. B 1.67 % Chromat. C 2.66 % Chromat. D 1.44 % Chromat. E 2.22 % Chromat. F 2.88 % Chromat.

...Expand

: 624-31-7
4-tolyl iodide

A: 106-44-5
p-cresol

B: 352-32-9
p-fluorotoluene

C: 352-70-5
m-Fluorotoluene

D: 108-41-8
1-chloro-3-methylbenzene

E: 108-39-4
3-methyl-phenol

F: 108-95-2
phenol

Conditions

Conditions	Yield
With potassium hydroxide; potassium chloride; sodium fluoride In water at 312℃; Mechanism; Product distribution;	A 13.0 % Chromat. B 5.01 % Chromat. C 5.97 % Chromat. D 3.0 % Chromat. E 18.6 % Chromat. F 2.6 % Chromat.

...Expand

: 28490-56-4
1-fluoro-3-(iodomethyl)benzene

: 352-70-5
m-Fluorotoluene

Conditions

Conditions	Yield
With Perbenzoic acid; tri-n-butyl-tin hydride In benzene at 90℃; for 12h; Mechanism; in the presence of α-iodotoluene (competitor), relative reactivity;

: C7H8F(1+)

: 108-88-3
toluene

A: 352-70-5
m-Fluorotoluene

B: 52809-63-9
C7H8*H(1+)

Conditions

Conditions	Yield
Thermodynamic data;

...Expand

: 1-Fluoro-3-methyl-benzene; compound with GENERIC INORGANIC NEUTRAL COMPONENT

: 108-88-3
toluene

A: 352-70-5
m-Fluorotoluene

B: 77406-15-6
Toluene; compound with GENERIC INORGANIC NEUTRAL COMPONENT

Conditions

Conditions	Yield
Thermodynamic data;

...Expand

: 108-88-3
toluene

A: 352-32-9
p-fluorotoluene

B: 95-52-3
2-Fluorotoluene

C: 352-70-5
m-Fluorotoluene

Conditions

Conditions	Yield
With fluorine In trichlorofluoromethane at -78℃; for 1h; Rate constant; Product distribution; competitive reaction with benzene, other solvent;	A 29 % Chromat. B 60 % Chromat. C 11 % Chromat.
With lead(IV) acetate; boron trifluoride diethyl etherate; mercury(II) diacetate Ambient temperature;	A 43 % Chromat. B 12 % Chromat. C 4 % Chromat.
With caesium fluoroxysulphate; trifluorormethanesulfonic acid In acetonitrile Ambient temperature; Yield given;

...Expand

: 108-88-3
toluene

A: 352-32-9
p-fluorotoluene

B: 95-52-3
2-Fluorotoluene

C: 352-70-5
m-Fluorotoluene

D: 350-50-5
benzyl fluoride

Conditions

Conditions	Yield
With acetyl hypofluorite In acetic acid for 0.0833333h; Ambient temperature; Yield given. Yields of byproduct given;
With fluorine In acetonitrile at 0℃; Flow reactor;

...Expand

: 108-88-3
toluene

A: 352-32-9
p-fluorotoluene

B: 95-52-3
2-Fluorotoluene

C: 352-70-5
m-Fluorotoluene

D: 452-76-6
2,4-difluorotoluene

Conditions

Conditions	Yield
With tetrafluoroammonium tetrafluoroborate In hydrogen fluoride at 0℃; Further byproducts given. Title compound not separated from byproducts;	A 15 % Spectr. B 15 % Spectr. C 8 % Spectr. D 30 % Spectr.

...Expand

: 108-88-3
toluene

A: 352-32-9
p-fluorotoluene

B: 95-52-3
2-Fluorotoluene

C: 352-70-5
m-Fluorotoluene

D: 452-76-6
2,4-difluorotoluene

E: 2,3,4,6-tetrafluorotoluene

Conditions

Conditions	Yield
With tetrafluoroammonium tetrafluoroborate In hydrogen fluoride at 0℃; Product distribution;	A 15 % Spectr. B 15 % Spectr. C 8 % Spectr. D 30 % Spectr. E 7 % Spectr.

...Expand

: 108-88-3
toluene

A: 352-32-9
p-fluorotoluene

B: 95-52-3
2-Fluorotoluene

C: 352-70-5
m-Fluorotoluene

D: 2,3,4,6-tetrafluorotoluene

Conditions

Conditions	Yield
With tetrafluoroammonium tetrafluoroborate In hydrogen fluoride at 0℃; Further byproducts given. Title compound not separated from byproducts;	A 15 % Spectr. B 15 % Spectr. C 8 % Spectr. D 7 % Spectr.

...Expand

: 456-41-7
1-(Bromomethyl)-3-fluorobenzene

: 352-70-5
m-Fluorotoluene

Conditions

Conditions	Yield
With Perbenzoic acid; tri-n-butyl-tin hydride In benzene at 90℃; for 12h; Mechanism; in the presence of α-bromotoluene, α-iodotoluene, or α,3-dichlorotoluene (20 h) (competitors), relative reactivities;

: 456-42-8
m-fluorobenzyl chloride

: 352-70-5
m-Fluorotoluene

Conditions

Conditions	Yield
With Perbenzoic acid; tri-n-butyl-tin hydride In benzene at 90℃; for 12h; Mechanism; in the presence of α-chlorotoluene (competitor), relative reactivity;

: 1-Fluoro-3-methyl-benzene; compound with GENERIC INORGANIC NEUTRAL COMPONENT

: 71-43-2
benzene

A: 352-70-5
m-Fluorotoluene

B: Benzene; compound with GENERIC INORGANIC NEUTRAL COMPONENT

Conditions

Conditions	Yield
Thermodynamic data;

...Expand

: 352-70-5
m-Fluorotoluene

: 455-38-9
3-fluorobenzoic acid

Conditions

Conditions	Yield
With oxygen; pyridinium chlorochromate In water at 120℃; under 45004.5 Torr; for 2h;	95%
With copper(l) iodide; oxygen; nitric acid at 160℃; under 11251.1 - 18751.9 Torr; for 4.7h; Autoclave;	84.7%
With cerium(III) chloride; 1,1,1-trichloroethanol; oxygen In acetonitrile at 60℃; Irradiation;	83%

: 352-70-5
m-Fluorotoluene

: 199620-14-9, 13007-92-6
chromium(0) hexacarbonyl

: 33411-10-8
(η6-1-fluoro-3-methylbenzene)tricarbonylchromium(0)

Conditions

Conditions	Yield
In tetrahydrofuran; dibutyl ether heating, 8d; filtration; evapn.; chromy. (silica, ether/petroleum ether); recrystn. (petroleum ether/ether); elem. anal.;	95%
In tetrahydrofuran; dibutyl ether at 160℃;	80%
In tetrahydrofuran; dibutyl ether Cr(CO)6 and arene were heated under reflux in a mixt. of n-Bu2O and THFfor 42 h under N2 atmosphere; soln. was cooled, filtered, evapd. under reduced pressure, residue was dissolved in ether, refiltered, light petroleum was added to the filtrate, ppt. collected, recrystd. from ether-light petroleum; elem. anal.;	49%
In tetrahydrofuran; dibutyl ether reflux for 48 h; filtration through Celite, evapn. under reduced pressure, recrystn. from ether/petroleum ether;	42%

: 51-17-2
benzoimidazole

: 352-70-5
m-Fluorotoluene

: 93716-66-6
N-(3-methyl-1-phenyl)-1H-benzimidazole

Conditions

Conditions	Yield
With caesium carbonate In N,N-dimethyl acetamide at 210℃; for 12h; Microwave irradiation;	92%

: 352-70-5
m-Fluorotoluene

: 556-96-7
5-bromo-1,3-xylene

: 1453806-84-2
C15H15F

Conditions

Conditions	Yield
With dichloro bis(acetonitrile) palladium(II); potassium carbonate; Trimethylacetic acid In N,N-dimethyl acetamide at 120℃; for 3h; regioselective reaction;	92%

: 352-70-5
m-Fluorotoluene

: 108-98-5
thiophenol

: 1312161-82-2
1-fluoro-3-(phenylsulfinylmethyl)benzene

Conditions

Conditions	Yield
With copper diacetate; 1,8-diazabicyclo[5.4.0]undec-7-ene In 1,4-dioxane at 80℃; for 10h;	91%

: 124-38-9
carbon dioxide

: 352-70-5
m-Fluorotoluene

: 99-04-7
m-Toluic acid

Conditions

Conditions	Yield
Stage #1: m-Fluorotoluene With C78H70Al2Cl4N6P4Rh2; magnesium; ethylene dibromide In tetrahydrofuran at -30℃; for 22h; Inert atmosphere; Glovebox; Stage #2: carbon dioxide In tetrahydrofuran at 20℃; under 760.051 Torr; for 0.5h;	90%

: 100-02-7
4-nitro-phenol

: 352-70-5
m-Fluorotoluene

: C13H10FNO2

Conditions

Conditions	Yield
With di-tert-butyl peroxide; 1,3-di-tert-butylimidazolium at 130℃; for 24h; Green chemistry;	90%

: 100-02-7
4-nitro-phenol

: 352-70-5
m-Fluorotoluene

: 630412-56-5
1-fluoro-3-((4-nitrophenoxy)methyl)benzene

Conditions

Conditions	Yield
With di-tert-butyl peroxide; 1,3-di-tert-butylimidazolium at 130℃; for 24h;	90%

: 110-91-8
morpholine

: 352-70-5
m-Fluorotoluene

: 7025-91-4
4-m-tolylmorpholine

Conditions

Conditions	Yield
With silver(I) hexafluorophosphate; [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; C17H21O3P In tetrahydrofuran at 120℃; for 20h; Inert atmosphere; Molecular sieve;	89%
With dichloro(benzene)ruthenium(II) dimer; silver trifluoromethanesulfonate; P(p-C6H4F)3 In 1,4-dioxane for 24h; Inert atmosphere; Molecular sieve; Reflux;	83%
With triethylsilane; [bis(2-methylallyl)cycloocta-1,5-diene]ruthenium(II); trifluorormethanesulfonic acid; 1,5-bis-(diphenylphosphino)pentane; triethylamine In 1,4-dioxane for 24h; Inert atmosphere; Reflux;	79%

: 23866-67-3
9-(2-pyridyl)carbazole

: 352-70-5
m-Fluorotoluene

: (3-fluorophenyl)(9-(pyridin-2-yl)-9H-carbazol-1-yl)methanone

Conditions

Conditions	Yield
With N-hydroxyphthalimide; oxygen; palladium diacetate at 80℃; under 760.051 Torr; for 24h; Schlenk technique; regioselective reaction;	89%

: 352-70-5
m-Fluorotoluene

: 200001-73-6
7-chloro-7-(4-nitrophenyl)norbornane

: 200001-80-5
NO2/Me-FDPN

Conditions

Conditions	Yield
With aluminium trichloride at 25℃; for 2h;	88%

: 352-70-5
m-Fluorotoluene

: 74483-52-6
4-fluoro-3-methylbenzotrifluoride

Conditions

Conditions	Yield
	87%

: 352-70-5
m-Fluorotoluene

: C25H38O3Si2

: C20H16O3

Conditions

Conditions	Yield
Stage #1: C25H38O3Si2 With lithium diisopropyl amide In tetrahydrofuran at 0 - 3℃; for 2h; Stage #2: m-Fluorotoluene In tetrahydrofuran at 20℃; for 24h;	87%

: 95-16-9
1,3-Benzothiazole

: 352-70-5
m-Fluorotoluene

: benzo[d]thiazol-2-yl(3-fluorophenyl)methanone

Conditions

Conditions	Yield
With Selectfluor; trifluoroacetic acid In acetonitrile at 80℃; for 12h;	86%
With dipotassium peroxodisulfate at 110℃; for 12h; Schlenk technique;	75%
With Selectfluor; trifluoroacetic acid In acetonitrile at 80℃; for 10h;	61%

: 352-70-5
m-Fluorotoluene

: 446-33-3
3-fluoro-6-nitrotoluene

Conditions

Conditions	Yield
With nitric acid at -15 - 55℃; for 8.5h; Inert atmosphere;	85%
With nitric acid In water at 0 - 5℃; for 0.5h;	38%
With nitric acid

: 352-70-5
m-Fluorotoluene

: 124-41-4
sodium methylate

: 95-92-1
oxalic acid diethyl ester

: 3-(5-methoxy-2,4-dinitro-phenyl)-2-oxo-propionic acid methyl ester

Conditions

Conditions	Yield
In methanol at -10 - 20℃; Green chemistry; Industrial scale;	85%

...Expand

: 352-70-5
m-Fluorotoluene

: (E)-N-(2-(4-methoxyphenyl)propan-2-yl)-1-phenylmethanimine

: N-(2-(3-fluorophenyl)-1-phenylethyl)-2-(4-methoxyphenyl)propan-2-amine

Conditions

Conditions	Yield
With potassium tert-butylate; 2,2,6,6-tetramethylpiperidinyl-lithium at -40℃; for 18h; Glovebox; Inert atmosphere;	84%

: 352-70-5
m-Fluorotoluene

A: 349-01-9
1-fluoro-5-methyl-2,4-dinitro-benzene

B: 110600-90-3
1-fluoro-3-methyl-2,4-dinitro-benzene

Conditions

Conditions	Yield
With sulfuric acid; nitric acid 1.) not over 35 deg C; 2.) 30 min, room temp.;	A 81% B n/a
With sulfuric acid; nitric acid at 0 - 35℃; for 0.5h;	A 36% B n/a
With sulfuric acid; nitric acid at 35℃; for 0.5h; Cooling with ice; Overall yield = 32 g;	A 36% B n/a

: 352-70-5
m-Fluorotoluene

: 1109-15-5
tris(pentafluorophenyl)borate

: 6016-04-2
N,N’-di(3-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide

: C24H12N4O4*2C18BF15*2C7H7F

Conditions

Conditions	Yield
In benzene at 80℃;	80%

...Expand

: 352-70-5
m-Fluorotoluene

: N-(2-(methylthio)phenyl)ferrocene-1-carboxamide

: 2,5-bis(3-fluorobenzyl)-N-(quinolin-8-yl)ferrocenecarboxamide

Conditions

Conditions	Yield
With di-tert-butyl peroxide; palladium diacetate; iron(II) chloride at 110℃; for 10h; Inert atmosphere; regioselective reaction;	80%

: 3972-65-4
1-bromo-4-tert-butylbenzene

: 352-70-5
m-Fluorotoluene

: 1-(4-(tert-butyl)benzyl)-3-fluorobenzene

Conditions

Conditions	Yield
With Xantphos-Pd-G3; potassium hexamethylsilazane at 110℃; for 12h; Inert atmosphere; Sealed tube;	78%

: 108-31-6
maleic anhydride

: 352-70-5
m-Fluorotoluene

: 3-(4-fluoro-2-methylbenzoyl)-2-propenoic acid

Conditions

Conditions	Yield
With aluminium trichloride In carbon disulfide for 3h; Ambient temperature;	77%

: 352-70-5
m-Fluorotoluene

: 100-51-6
benzyl alcohol

: 834-17-3
3-benzyloxytoluene

Conditions

Conditions	Yield
With 1-methyl-pyrrolidin-2-one; sodium hydride at 100℃; for 15h;	77%

: 352-70-5
m-Fluorotoluene

: 73183-34-3
bis(pinacol)diborane

: 253342-48-2
4,4,5,5-tetramethyl-2-m-tolyl-1,3,2-dioxaborolane

Conditions

Conditions	Yield
With tris-(dibenzylideneacetone)dipalladium(0); lithium hexamethyldisilazane In toluene at 80℃; for 12h; Inert atmosphere; Schlenk technique;	77%

: 95-16-9
1,3-Benzothiazole

: 352-70-5
m-Fluorotoluene

: C14H10FNS

Conditions

Conditions	Yield
With N,N'-difluoro-1,4-diazoniabicyclo<2.2.2>octane bis(tetrafluoroborate); trifluoroacetic acid In acetonitrile at 20℃; for 24h; Irradiation;	77%

: 352-70-5
m-Fluorotoluene

: 75-36-5
acetyl chloride

: 446-29-7
1-(4-fluoro-2-methylphenyl)ethanone

Conditions

Conditions	Yield
With aluminium trichloride In carbon disulfide	76.4%
With aluminium trichloride

: 352-70-5
m-Fluorotoluene

: 67734-35-4
(R)-tert-butyl tert-butanethiosulfinate

: 1361250-93-2
(S)-tert-butyl (3-fluorophenyl)methyl sulfoxide

Conditions

Conditions	Yield
Stage #1: m-Fluorotoluene With 2,2,6,6-tetramethyl-piperidine; n-butyllithium; potassium tert-butylate In tetrahydrofuran; hexane at -78℃; for 0.583333h; Inert atmosphere; Stage #2: (R)-tert-butyl tert-butanethiosulfinate In tetrahydrofuran; hexane Inert atmosphere; optical yield given as %ee; enantioselective reaction;	76%

3-Fluorotoluene Chemical Properties

Molecular Structure of 3-Fluorotoluene (CAS NO.352-70-5):

IUPAC Name: 1-Fluoro-3-methylbenzene
Molecular Formula: C₇H₇F
Molecular Weight: 110.13 g/mol
Density: 1.001 g/cm³
Melting Point: -87 °C
Boiling Point: 118.2 °C at 760 mmHg
Flash Point: 9.4 °C
Water Solubility: immiscible
Index of Refraction: 1.477
Molar Refractivity: 31.07 cm³
Molar Volume: 109.9 cm³
Surface Tension: 27.6 dyne/cm
Enthalpy of Vaporization: 34.16 kJ/mol
Vapour Pressure: 20.1 mmHg at 25 °C
XLogP3: 2.7
H-Bond Acceptor: 1
Exact Mass: 110.053178
MonoIsotopic Mass: 110.053178
Canonical SMILES: CC1=CC(=CC=C1)F
InChI: InChI=1S/C7H7F/c1-6-3-2-4-7(8)5-6/h2-5H,1H3
InChIKey: BTQZKHUEUDPRST-UHFFFAOYSA-N
EINECS: 206-524-8
Product Categories: Aromatic Hydrocarbons (substituted) & Derivatives; Aryl; C7; Halogenated Hydrocarbons

3-Fluorotoluene Uses

3-Fluorotoluene (CAS NO.352-70-5) is used as intermediates of medicine and pesticide.

3-Fluorotoluene Safety Profile

Hazard Codes: F, Irritant Xi
Risk Statements: 11-36/37/38
R11:Highly flammable.
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 16-26-36-37/39
S16:Keep away from sources of ignition.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36:Wear suitable protective clothing.
S37/39:Wear suitable gloves and eye/face protection.
RIDADR: UN 2388 3/PG 2
WGK Germany: 2
RTECS: XT2578000
Hazard Note: Flammable/Irritant
TSCA: T
HazardClass: 3
PackingGroup: II
HS Code: 29036990

3-Fluorotoluene Specification

3-Fluorotoluene (CAS NO.352-70-5) is also named as 1-Fluoro-3-methylbenzene ; 1-Methyl-3-fluorobenzene ; Benzene, 1-fluoro-3-methyl- ; NSC 8860 ; m-Fluorotoluene . 3-Fluorotoluene (CAS NO.352-70-5) is clear colorless to light yellow liquid with an aromatic odor. It is highly flammable. 3-Fluorotoluene may be incompatible with strong oxidizing and reducing agents. It is also may be incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides. 3-Fluorotoluene generates toxic fluoride fumes when burned.Inhalation causes upper respiratory irritation. Irritating to skin and eyes. It may be absorbed through the skin. Prolonged exposure may result in systemic toxic effects. It is harmful if swallowed.

Product Name

3-Fluorotoluene

Synthetic route

3-Fluorotoluene Chemical Properties

3-Fluorotoluene Uses

3-Fluorotoluene Safety Profile

3-Fluorotoluene Specification

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