Conditions | Yield |
---|---|
With phosphonic Acid; methanesulfonic acid; sodium iodide In water at 95℃; for 72h; Inert atmosphere; | 98.7% |
(4-bromo-phenyl)-acetic acid methyl ester
2-(4-bromophenyl)-acetic acid
Conditions | Yield |
---|---|
With sodium hydroxide for 2h; Heating; | 93% |
With sodium hydroxide In tetrahydrofuran; methanol; water at 23℃; for 12h; |
carbon monoxide
1-bromomethyl-4-bromobenzene
2-(4-bromophenyl)-acetic acid
Conditions | Yield |
---|---|
With chloro(1,5-cyclooctadiene)rhodium(I) dimer; potassium iodide In formic acid at 60℃; under 760 Torr; for 18h; Carbonylation; | 93% |
With cobalt(II) pyridine-2-carboxylate; palladium diacetate; sodium hydroxide In methanol at 180℃; under 11251.1 Torr; for 6h; Autoclave; | 93% |
Ethyl 4-bromophenylacetate
2-(4-bromophenyl)-acetic acid
Conditions | Yield |
---|---|
With water; sodium hydroxide In 1,4-dioxane at 60℃; for 2h; pH=10 - 14; | 93% |
carbon dioxide
hydrazone of p-bromobenzaldehyde
2-(4-bromophenyl)-acetic acid
Conditions | Yield |
---|---|
With 1,1'-bis-(diphenylphosphino)ferrocene; [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; caesium carbonate; cesium fluoride In N,N-dimethyl-formamide at 80℃; under 760.051 Torr; for 24h; chemoselective reaction; | 88% |
Conditions | Yield |
---|---|
With cobalt(II) pyridine-2-carboxylate; palladium diacetate; sodium hydroxide In methanol at 180℃; under 11251.1 Torr; for 6h; Autoclave; | 88% |
2-(4-bromophenyl)-acetic acid
Conditions | Yield |
---|---|
With bismuth(III) chloride; water In acetonitrile at 50℃; for 1h; | 85% |
Conditions | Yield |
---|---|
With Oxone; iodine In 1,2-dimethoxyethane; water at 20℃; for 4h; regioselective reaction; | 83% |
With D-glucose; oxygen In aq. phosphate buffer at 30℃; for 10h; pH=8; Green chemistry; Enzymatic reaction; regioselective reaction; | 71% |
carbon monoxide
1-bromomethyl-4-bromobenzene
A
para-bromotoluene
B
2-(4-bromophenyl)-acetic acid
Conditions | Yield |
---|---|
With palladium hydroxide, 20 wt% on carbon; tetrabutylammomium bromide; water In tetrahydrofuran at 110℃; under 7500.75 Torr; for 4h; Sealed tube; Autoclave; | A 9 %Chromat. B 82% |
2-(4-bromophenyl)-acetic acid
Conditions | Yield |
---|---|
With boron trifluoride diethyl etherate; water In 1,4-dioxane at 175℃; for 0.5h; Microwave irradiation; Green chemistry; | 78% |
Conditions | Yield |
---|---|
With silver(I) acetate; sodium acetate; palladium dichloride at 130℃; for 24h; Schlenk technique; Inert atmosphere; chemoselective reaction; | 63% |
A
4-bromophenylacetic acid 2-deuterio-2,2-dichloroethyl ester
B
2-(4-bromophenyl)-acetic acid
Conditions | Yield |
---|---|
With indium; deuterated ammonium chloride In tetrahydrofuran-d8; water-d2 at 20℃; for 40h; Reflux; chemoselective reaction; | A 3% B 54% |
carbon monoxide
1-bromomethyl-4-bromobenzene
A
4,4'-dibromobibenzyl
B
1,3-bis(4-bromophenyl)propan-2-one
C
(4-Bromo-phenyl)-acetic acid 4-bromo-benzyl ester
D
2-(4-bromophenyl)-acetic acid
Conditions | Yield |
---|---|
iron pentacarbonyl; tetrabutylammonium sulfate In sodium hydroxide; dichloromethane at 25℃; under 760 Torr; for 24h; | A 7% B 9% C 22% D 50% |
carbon dioxide
2-[(4-bromophenyl)methyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
2-(4-bromophenyl)-acetic acid
Conditions | Yield |
---|---|
With potassium ethoxide In 1,4-dioxane at 100℃; for 24h; | 50% |
1-bromomethyl-4-bromobenzene
A
4,4'-dibromobibenzyl
B
1,3-bis(4-bromophenyl)propan-2-one
C
(4-Bromo-phenyl)-acetic acid 4-bromo-benzyl ester
D
2-(4-bromophenyl)-acetic acid
Conditions | Yield |
---|---|
With calcium hydroxide In dichloromethane; water at 20℃; for 23h; | A 5 % Spectr. B 62 % Spectr. C 11 % Spectr. D 4% |
Conditions | Yield |
---|---|
With water; bromine; mercury(II) oxide |
phenylacetic acid
A
ortho-bromophenylacetic acid
B
2-(4-bromophenyl)-acetic acid
Conditions | Yield |
---|---|
With bromine | |
With bromine; mercury(II) oxide | |
With water; bromine; mercury(II) oxide |
4-Bromophenylacetonitrile
2-(4-bromophenyl)-acetic acid
Conditions | Yield |
---|---|
With sulfuric acid | |
With potassium hydroxide | |
With hydrogenchloride at 100℃; im Rohr; |
Conditions | Yield |
---|---|
With morpholine; sulfur Erwaermen des Reaktionsprodukts mit aethanol. Natronlauge; | |
Multi-step reaction with 2 steps 1: BF3*O(C2H5)3, Pb(OAc)4 / benzene / 12 h / Ambient temperature 2: 93 percent / aq. NaOH / 2 h / Heating View Scheme | |
Stage #1: para-bromoacetophenone With morpholine; toluene-4-sulfonic acid; sulfur at 120℃; Stage #2: With tetrabutylammomium bromide; sodium hydroxide In ethanol; water at 100℃; for 4h; | |
Stage #1: para-bromoacetophenone With morpholine; toluene-4-sulfonic acid; sulfur at 120℃; Stage #2: With tetrabutylammomium bromide; sodium hydroxide at 100℃; |
1-(2,2,2-trichloroethyl)-4-bromobenzene
2-(4-bromophenyl)-acetic acid
Conditions | Yield |
---|---|
With sulfuric acid | |
With sulfuric acid at 80 - 90℃; for 6h; Inert atmosphere; | 117.4 g |
A
phenylacetic acid
B
2-oxo-2-phenylethyl 2-phenylacetate
C
acetophenone
D
2-(4-bromophenyl)-acetic acid
Conditions | Yield |
---|---|
With N,N-dimethyl-aniline In acetonitrile for 2h; Mechanism; Irradiation; sensitized deprotection; competing bromide and carboxylate elimination; |
phenylacetic acid
water
bromine
A
ortho-bromophenylacetic acid
B
2-(4-bromophenyl)-acetic acid
phenylacetic acid
N-Bromosuccinimide
water
A
ortho-bromophenylacetic acid
B
benzaldehyde
C
2-(4-bromophenyl)-acetic acid
2-(4-bromophenyl)-1-morpholinoethanethione
2-(4-bromophenyl)-acetic acid
Conditions | Yield |
---|---|
With sodium hydroxide; N-benzyl-N,N,N-triethylammonium chloride at 100℃; for 8h; |
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: S; p-toluenesulfonic acid / 8 h / 120 - 130 °C 2: aq. NaOH; triethyl benzyl ammonium chloride / 8 h / 100 °C View Scheme |
3-(4-bromo-phenyl)-2-thioxo-propionic acid
2-(4-bromophenyl)-acetic acid
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: aqueous ethanol; hydroxylamine 3: ethanolic KOH-solution View Scheme |
3-(4-bromo-phenyl)-2-hydroxyimino-propionic acid
2-(4-bromophenyl)-acetic acid
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 2: ethanolic KOH-solution View Scheme |
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: Bromierung 2: ethanol 3: sulfuric acid View Scheme |
2-(4-bromophenyl)-acetic acid
2-(4-bromophenyl)acetyl chloride
Conditions | Yield |
---|---|
With thionyl chloride | 100% |
With thionyl chloride In dichloromethane | 100% |
With thionyl chloride In toluene | 100% |
methanol
2-(4-bromophenyl)-acetic acid
(4-bromo-phenyl)-acetic acid methyl ester
Conditions | Yield |
---|---|
With chloro-trimethyl-silane for 15h; Ambient temperature; | 100% |
With hydrogenchloride for 1h; Heating; | 100% |
With hydrogenchloride for 3h; Heating; | 100% |
phenylboronic acid
2-(4-bromophenyl)-acetic acid
(4-biphenylyl)acetic acid
Conditions | Yield |
---|---|
With sodium carbonate; Pd-complex on fluorous reversed silica gel In water at 80℃; for 16h; Suzuki reaction; | 100% |
With carbon-doped cobalt; C118H94N4O7P8; palladium diacetate; sodium carbonate In tetrahydrofuran; water at 20 - 60℃; for 14h; Suzuki Coupling; Inert atmosphere; | 100% |
With palladium diacetate; potassium carbonate In water; toluene at 65℃; for 20h; Solvent; Suzuki-Miyaura Coupling; | 100% |
4-fluoroboronic acid
2-(4-bromophenyl)-acetic acid
2-(4'-fluoro-[1,1'-biphenyl]-4-yl)acetic acid
Conditions | Yield |
---|---|
With tetrakis(triphenylphosphine) palladium(0); caesium carbonate In toluene at 95℃; for 4h; Suzuki-Miyaura Coupling; | 100% |
With 2C2H5NO2*Pd(2+)*2Cl(1-); potassium carbonate In water at 20℃; for 6h; Suzuki-Miyaura Coupling; Green chemistry; | 96% |
With potassium carbonate In water at 20℃; for 4h; Suzuki-Miyaura Coupling; Green chemistry; | 96% |
Stage #1: 4-fluoroboronic acid; 2-(4-bromophenyl)-acetic acid With sodium carbonate; palladium 10% on activated carbon In water; isopropyl alcohol at 65 - 70℃; Suzuki Coupling; Stage #2: With sulfuric acid; water | 75% |
benzyl bromide
2-(4-bromophenyl)-acetic acid
benzyl 2-(4-bromophenyl)acetate
Conditions | Yield |
---|---|
With caesium carbonate In N,N-dimethyl-formamide at 20 - 100℃; | 100% |
With potassium carbonate In acetone for 12h; Reflux; Inert atmosphere; | 95% |
With potassium carbonate In N,N-dimethyl-formamide at 0 - 100℃; Inert atmosphere; | 73% |
4-aminotetrahydropyran
2-(4-bromophenyl)-acetic acid
2-(4-bromophenyl)-N-(tetrahydropyran-4-yl)acetamide
Conditions | Yield |
---|---|
With 4-methyl-morpholine; benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane; N,N-dimethyl-formamide at 20℃; for 16h; Cooling with ice; | 100% |
2-(3,4-dimethoxyphenyl)-ethylamine
2-(4-bromophenyl)-acetic acid
2-(4-bromophenyl)-N-(3,4-dimethoxyphenethyl)acetamide
Conditions | Yield |
---|---|
With diethyl cyanophosphonate; triethylamine In N,N-dimethyl-formamide at 0 - 20℃; | 100% |
Stage #1: 2-(4-bromophenyl)-acetic acid With benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 20℃; for 0.166667h; Stage #2: 2-(3,4-dimethoxyphenyl)-ethylamine With triethylamine In dichloromethane at 20℃; | 90% |
Conditions | Yield |
---|---|
In methanol at 20℃; | 100% |
Conditions | Yield |
---|---|
Stage #1: 2-(4-bromophenyl)-acetic acid With dimethylsulfide borane complex In tetrahydrofuran at 0 - 20℃; for 3h; Stage #2: With hydrogenchloride; water In tetrahydrofuran at 0 - 80℃; for 0.5h; | 99% |
With lithium aluminium tetrahydride In diethyl ether at 20℃; for 0.25h; | 92% |
With C25H42N6Rh(1+)*CF3O3S(1-); phenylsilane In tetrahydrofuran at 30℃; for 20h; Catalytic behavior; Reagent/catalyst; Inert atmosphere; | 88% |
5,6-dimethoxy-2-(N-propylamino)indan
2-(4-bromophenyl)-acetic acid
2-(4-bromo-phenyl)-N-(5,6-dimethoxy-indan-2-yl)-N-propyl-acetamide
Conditions | Yield |
---|---|
With diethyl cyanophosphonate; triethylamine In dichloromethane at 20℃; for 24h; | 99% |
4-methoxyphenylboronic acid
2-(4-bromophenyl)-acetic acid
2-(4'-methoxy-[1,1'-biphenyl]-4-yl)acetic acid
Conditions | Yield |
---|---|
With sodium carbonate; Pd-complex on fluorous reversed silica gel In water at 80℃; for 16h; Suzuki reaction; | 99% |
With potassium carbonate In water at 20℃; for 4h; Suzuki-Miyaura Coupling; Green chemistry; | 97% |
With 2C2H5NO2*Pd(2+)*2Cl(1-); potassium carbonate In water at 20℃; for 6h; Suzuki-Miyaura Coupling; Green chemistry; | 92% |
With tetrakis(triphenylphosphine) palladium(0); caesium carbonate In toluene at 95℃; for 4h; Suzuki-Miyaura Coupling; | 52% |
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; caesium carbonate In methanol at 65℃; for 24h; |
1-methyl-piperazine
2-(4-bromophenyl)-acetic acid
2-(4-bromophenyl)-1-(4-methylpiperazin-1-yl)ethan-1-one
Conditions | Yield |
---|---|
With 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; N-ethyl-N,N-diisopropylamine In dichloromethane at 20℃; for 20h; | 99% |
With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 20℃; for 19h; | 3.20 g |
ethanol
phenylboronic acid
2-(4-bromophenyl)-acetic acid
4-biphenylylacetic acid ethyl ester
Conditions | Yield |
---|---|
With tetra-butylammonium acetate; Pd EnCat-30TM In water at 120℃; for 0.166667h; Suzuki cross-coupling; microwave irradiation; | 99% |
6,7-dimethoxy-3-(4-methoxyphenyl)-1-(prop-2-en-1-yl)-1H-quinolin-2-one
2-(4-bromophenyl)-acetic acid
Conditions | Yield |
---|---|
With caesium carbonate; triphenylphosphine; [Pd(OAc)2] In water; N,N-dimethyl-formamide at 120℃; for 16h; Heck reaction; | 99% |
methyl iodide
2-(4-bromophenyl)-acetic acid
(4-bromo-phenyl)-acetic acid methyl ester
Conditions | Yield |
---|---|
With potassium carbonate In acetone at 60℃; | 99% |
With potassium carbonate In acetone at 60℃; | 99% |
With 1,8-diazabicyclo[5.4.0]undec-7-ene In acetonitrile at 0 - 20℃; for 2h; | 75% |
2-(4-bromophenyl)-acetic acid
Ethyl 4-bromophenylacetate
Conditions | Yield |
---|---|
With sulfuric acid In ethanol | 99% |
With toluene-4-sulfonic acid In diethyl ether; ethanol | |
Multi-step reaction with 2 steps 1: oxalyl dichloride / N,N-dimethyl-formamide; dichloromethane / 20 °C / Inert atmosphere 2: triethylamine; dmap / dichloromethane / 0 - 20 °C / Inert atmosphere View Scheme |
1-(tert-butoxycarbonyl)-4-aminopiperidine
2-(4-bromophenyl)-acetic acid
4-[2-(4-bromophenyl)acetylamino]piperidine-1-carboxylic acid tert-butyl ester
Conditions | Yield |
---|---|
With O-(benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium tetrafluoroborate; N-ethyl-N,N-diisopropylamine In dichloromethane at 20℃; | 99% |
With 4-methyl-morpholine; benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane; N,N-dimethyl-formamide at 0 - 20℃; for 1.25h; | 96.9% |
With 4-methyl-morpholine; benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane; N,N-dimethyl-formamide at 20℃; for 16h; Cooling with ice; | 96.9% |
Stage #1: 1-(tert-butoxycarbonyl)-4-aminopiperidine; 2-(4-bromophenyl)-acetic acid With N-ethyl-N,N-diisopropylamine In dichloromethane at 20℃; for 0.0833333h; Stage #2: With O-(benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium tetrafluoroborate In dichloromethane at 20℃; for 3h; | 93% |
2-(4-bromophenyl)-acetic acid
2-(4-bromo-phenyl)-3-hydroxy-propenal
Conditions | Yield |
---|---|
With trichlorophosphate In N,N-dimethyl-formamide at 4 - 75℃; for 16h; Inert atmosphere; | 99% |
trifluoroacetic acid
1-t-Butoxycarbonylpiperazine
2-(4-bromophenyl)-acetic acid
Conditions | Yield |
---|---|
Stage #1: 1-t-Butoxycarbonylpiperazine; 2-(4-bromophenyl)-acetic acid With N-ethyl-N,N-diisopropylamine; N-[(dimethylamino)-3-oxo-1H-1,2,3-triazolo[4,5-b]pyridin-1-yl-methylene]-N-methylmethanaminium hexafluorophosphate In N,N-dimethyl-formamide at 20℃; Stage #2: trifluoroacetic acid In dichloromethane at 20℃; for 1h; | 99% |
1-t-Butoxycarbonylpiperazine
2-(4-bromophenyl)-acetic acid
C17H23BrN2O3
Conditions | Yield |
---|---|
With 4-methyl-morpholine; benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In N,N-dimethyl-formamide at 20℃; | 98% |
Conditions | Yield |
---|---|
With dmap; dicyclohexyl-carbodiimide In dichloromethane at 20℃; | 98% |
Conditions | Yield |
---|---|
With acetic anhydride; triethylamine for 5h; Knoevenagel Condensation; Reflux; | 98% |
Conditions | Yield |
---|---|
With triethylamine; 1,1'-carbonyldiimidazole In dichloromethane at 0 - 30℃; | 98% |
1-methyl-1-azaspiro<4.5>decan-10-amine
2-(4-bromophenyl)-acetic acid
2-(4-Bromo-phenyl)-N-((5S,6R)-1-methyl-1-aza-spiro[4.5]dec-6-yl)-acetamide
Conditions | Yield |
---|---|
With 1,1'-carbonyldiimidazole In dichloromethane for 2h; | 97% |
Conditions | Yield |
---|---|
With sulfuric acid for 24h; Reflux; | 97% |
With toluene-4-sulfonic acid for 3h; Reflux; | 97% |
With toluene-4-sulfonic acid Inert atmosphere; | 96% |
2-(4-bromophenyl)-acetic acid
Conditions | Yield |
---|---|
With dicyclohexyl-carbodiimide In toluene at 20℃; for 0.25h; Inert atmosphere; | 97% |
With 2,4,6-trimethyl-pyridine; bis(trichloromethyl) carbonate In tetrahydrofuran for 0.0166667h; | |
With dicyclohexyl-carbodiimide In toluene at 20℃; for 0.25h; |
4-bromo-phenol
2-(4-bromophenyl)-acetic acid
4-bromophenyl 2-(4-bromophenyl)acetate
Conditions | Yield |
---|---|
With dmap In dichloromethane at 0 - 20℃; | 97% |
N-(7-amino-1,8-naphthyridin-2-yl)-2-ethylhexanamide
2-(4-bromophenyl)-acetic acid
N-(7-(2-(4-bromophenyl)acetamido)-1,8-naphthyridin-2-yl)-2-ethylhexanamide
Conditions | Yield |
---|---|
With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 0 - 25℃; Inert atmosphere; | 97% |
3-trifluoromethylaniline
2-(4-bromophenyl)-acetic acid
2-(4-bromo-phenyl)-N-(3-trifluoromethyl-phenyl)-acetamide
Conditions | Yield |
---|---|
With O-(benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium tetrafluoroborate; N-ethyl-N,N-diisopropylamine In N,N-dimethyl-formamide at 20℃; for 12h; | 97% |
The IUPAC name of this chemical is 2-(4-bromophenyl)acetic acid. With the CAS registry number 1878-68-8, it is also named as Acide p-bromophenylacetique. The product's categories are Phenylacetic acid series; Fine Chemical & Intermediates; Bromides; Carboxes; Acids and Derivatives; Aromatic Phenylacetic Acids and Derivatives; Aromatics Compounds; Aromatics; Carbonyl Compounds; Carboxylic Acids. It is white solid slightly which is soluble in water. Additionally, 4-Bromophenylacetic acid should be sealed in the container and stored in the cool and dry place.
The other characteristics of this product can be summarized as: (1)ACD/LogP: 2.28; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 0.93; (4)ACD/LogD (pH 7.4): -0.84; (5)ACD/BCF (pH 5.5): 1.41; (6)ACD/BCF (pH 7.4): 1; (7)ACD/KOC (pH 5.5): 18.39; (8)ACD/KOC (pH 7.4): 1; (9)#H bond acceptors: 2; (10)#H bond donors: 1; (11)#Freely Rotating Bonds: 2 ; (12)Index of Refraction: 1.592; (13)Molar Refractivity: 45.05 cm3; (14)Molar Volume: 133 cm3; (15)Polarizability: 17.86×10-24 cm3; (16)Surface Tension: 51.3 dyne/cm; (17)Enthalpy of Vaporization: 59.98 kJ/mol; (18)Vapour Pressure: 9.03E-05 mmHg at 25°C; (19)Rotatable Bond Count: 2; (20)Exact Mass: 213.962942; (21)MonoIsotopic Mass: 213.962942; (22)Topological Polar Surface Area: 37.3; (23)Heavy Atom Count: 11; (24)Complexity: 139.
Preparation of 4-Bromophenylacetic acid: It can be obtained by 1-bromo-4-bromomethyl-benzene and carbon monoxide. This reaction needs reagent [RhCl(1,5-cyclooctadiene)]2 and KI and solvent formic acid at temperature of 60 °C and pressure of 760. The reaction time is 18 hours. The yield is 93 %.
Uses of 4-Bromophenylacetic acid: It can react with phthalic acid anhydride to get 3-(4-bromo-benzylidene)-3H-isobenzofuran-1-one. This reaction needs reagent NaOAc at temperature of 230 - 240 °C. The reaction time is 3 hours. The yield is 82 %.
When you are using this chemical, please be cautious about it as the following:
It is iarmful if swallowed and irritating to eyes, respiratory system and skin. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. If you want to contact this product, you must wear suitable gloves and eye/face protection.
People can use the following data to convert to the molecule structure.
1. SMILES:Brc1ccc(cc1)CC(=O)O
2. InChI:InChI=1/C8H7BrO2/c9-7-3-1-6(2-4-7)5-8(10)11/h1-4H,5H2,(H,10,11)
3. InChIKey:QOWSWEBLNVACCL-UHFFFAOYAS
The following are the toxicity data which has been tested.
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
mouse | LD50 | intraperitoneal | 1050mg/kg (1050mg/kg) | Farmaco, Edizione Scientifica. Vol. 13, Pg. 286, 1958. |
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