9-Bromoanthracene supplier | CasNO.1564-64-3

Name
9-Bromoanthracene
EINECS 216-359-3
CAS No. 1564-64-3
Article Data66
CAS DataBase
Density 1.479 g/cm³
Solubility Insoluble in water.
Melting Point 97-100 °C(lit.)
Formula C₁₄H₉Br
Boiling Point 389.7 °C at 760 mmHg
Molecular Weight 257.129
Flash Point 190.3 °C
Transport Information
Appearance white to light yellow crystal powder
Safety 22-24/25
Risk Codes
Molecular Structure
Hazard Symbols Xi
Synonyms 10-Bromoanthracene;9-Anthracenyl bromide;9-Anthracyl bromide;Anthracene,9-bromo-;NSC 803;9-Bromo anthracene;
PSA 0.00000
LogP 4.75550

Synthetic route

: 120-12-7
anthracene

: 1564-64-3
9-Bromoanthracene

Conditions

Conditions	Yield
With bis(trifluoroacetoxy)iodobencene; trimethylsilyl bromide In dichloromethane at 20℃; Inert atmosphere;	100%
With N,N,N’,N’-tetrabromobenzene-1,3-disulfonamide In dichloromethane at 25℃; for 0.583333h;	98%
With copper(ll) bromide In chloroform Reflux;	94%

: 641144-16-3
(10-bromo-9-anthracenyl)boronic acid

: 1564-64-3
9-Bromoanthracene

Conditions

Conditions	Yield
With [Pd(N-phenylbenzaldimine)(OAc)(PPh3)] In tetrahydrofuran at 20℃; for 24h; Schlenk technique; chemoselective reaction;	99%

: 24100-41-2
1-(anthracen-10-yl)-2-bromoethanone

A: 784-04-3
9-acetylanthracene

B: 1564-64-3
9-Bromoanthracene

Conditions

Conditions	Yield
With diethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate; acetic acid for 0.7h; Irradiation; Inert atmosphere;	A 94% B 2%

: 22362-86-3
9-iodoanthracene

: 1564-64-3
9-Bromoanthracene

Conditions

Conditions	Yield
In tetrahydrofuran at 25℃; for 3h; Reagent/catalyst; Time; Temperature;	92%

: 120-12-7
anthracene

A: 1564-64-3
9-Bromoanthracene

B: 523-27-3
9,10-Dibromoanthracene

Conditions

Conditions	Yield
With N-Bromosuccinimide; 2,4,6-trimethylaniline In dichloromethane at 0℃; for 8h; Inert atmosphere; regioselective reaction;	A 84% B 7%
With N-Bromosuccinimide; C5H13NO3S In n-heptane at 60℃; for 4.5h; Darkness;	A 81% B 8%
With N-Bromosuccinimide; iodine In tetrachloromethane Bromination; Heating;

: 523-27-3
9,10-Dibromoanthracene

A: 1564-64-3
9-Bromoanthracene

B: 25882-75-1
9-<4-(N,N-dimethylamino)phenyl>-9,10-dihydroanthracene

C: 101-61-1
4,4'-methylene-bis(N,N-dimethylaniline)

D: N-methyl-N-9-(10-bromoanthryl)methyleneaniline

Conditions

Conditions	Yield
With N,N-dimethyl-aniline In acetonitrile Irradiation; Further byproducts given;	A 70% B 7.2% C 13.4% D 8.2%

...Expand

: 523-27-3
9,10-Dibromoanthracene

: 121-69-7
N,N-dimethyl-aniline

A: 1564-64-3
9-Bromoanthracene

B: 25882-75-1
9-<4-(N,N-dimethylamino)phenyl>-9,10-dihydroanthracene

C: 3571-43-5
crystal violet bromide

D: 101-61-1
4,4'-methylene-bis(N,N-dimethylaniline)

E: N-methyl-N-9-(10-bromoanthryl)methyleneaniline

Conditions

Conditions	Yield
In acetonitrile Product distribution; Irradiation; photolysis;	A 70% B 7.2% C 1.2% D 13.4% E 8.2%

...Expand

: 602-55-1
9-phenylanthracene

: 1564-64-3
9-Bromoanthracene

Conditions

Conditions	Yield
With N-Bromosuccinimide In chloroform at 60℃; for 2h; Inert atmosphere;	61.2%

: 523-27-3
9,10-Dibromoanthracene

: 100-67-4
potassium phenolate

A: 1564-64-3
9-Bromoanthracene

B: 23674-00-2
bromo-9 phenoxy-10 anthracene

C: 84-65-1
9,10-phenanthrenequinone

Conditions

Conditions	Yield
In N,N-dimethyl-formamide at 153℃; for 3h;	A 3% B 35% C 2%

...Expand

: 128-08-5
N-Bromosuccinimide

: 120-12-7
anthracene

: 1564-64-3
9-Bromoanthracene

Conditions

Conditions	Yield
Kinetics;

: 46491-50-3
9,19-Dibromo-9,10-dihydroanthracene

: 1564-64-3
9-Bromoanthracene

Conditions

Conditions	Yield
With toluene; copper(I) bromide

: 120-12-7
anthracene

: 20244-61-5
2,4,4,6-Tetrabromo-2,5-cyclohexadien-1-one

: 1564-64-3
9-Bromoanthracene

Conditions

Conditions	Yield
Kinetics;

: 523-27-3
9,10-Dibromoanthracene

: 1564-64-3
9-Bromoanthracene

: 46491-50-3
9,19-Dibromo-9,10-dihydroanthracene

: 67-66-3
chloroform

: 109-89-7
diethylamine

A: 1564-64-3
9-Bromoanthracene

B: 120-12-7
anthracene

...Expand

: 75-77-4
chloro-trimethyl-silane

: 523-27-3
9,10-Dibromoanthracene

A: 1564-64-3
9-Bromoanthracene

B: 89811-60-9
9-Brom-10-(trimethylsilyl)anthracen

Conditions

Conditions	Yield
With n-butyllithium 1.) ether, pentane, 20 deg C, 45 min, 2.) ether, THF, 20 deg C, 20 h; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;

...Expand

: 120-12-7
anthracene

A: 716-53-0
9-chloroanthracene

B: 1564-64-3
9-Bromoanthracene

C: 22362-86-3
9-iodoanthracene

Conditions

Conditions	Yield
With aluminium trichloride; cyanogen iodide; tetrabutylammomium bromide In diethyl ether; nitromethane at 25℃; for 20h;	A 6 % Chromat. B 88 % Chromat. C 1 % Chromat.

...Expand

: 46491-50-3
9,19-Dibromo-9,10-dihydroanthracene

: 108-88-3
toluene

phenol (1 percent-): phenol (1 percent-)

: 1564-64-3
9-Bromoanthracene

...Expand

: 46491-50-3
9,19-Dibromo-9,10-dihydroanthracene

: 7783-06-4
hydrogen sulfide

: 64-19-7
acetic acid

A: 1564-64-3
9-Bromoanthracene

B: 120-12-7
anthracene

Conditions

Conditions	Yield
at 50℃;

...Expand

: 120-12-7
anthracene

CS2: CS2

bromine (2 atom-weight ): bromine (2 atom-weight )

: 1564-64-3
9-Bromoanthracene

...Expand

: 613-31-0
9,10-dihydroanthracene

A: 1564-64-3
9-Bromoanthracene

B: 523-27-3
9,10-Dibromoanthracene

Conditions

Conditions	Yield
With N-Bromosuccinimide; biphenyl In benzene at 20℃; for 2h; Irradiation;	A 88.9 % Chromat. B 11.1 % Chromat.

: 523-27-3
9,10-Dibromoanthracene

A: 1564-64-3
9-Bromoanthracene

B: 120-12-7
anthracene

Conditions

Conditions	Yield
With sodium hydrogencarbonate; N,N-dimethyl-formamide; palladium dichloride at 120℃; for 18h;

: 77-48-5
1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione

: 120-12-7
anthracene

A: 1564-64-3
9-Bromoanthracene

B: 523-27-3
9,10-Dibromoanthracene

Conditions

Conditions	Yield
Stage #1: 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione; anthracene In ethyl acetate for 2.5h; Refluxing; Stage #2: In tetrahydrofuran

...Expand

: 120-12-7
anthracene

A: 1564-64-3
9-Bromoanthracene

B: 84-65-1
9,10-phenanthrenequinone

Conditions

Conditions	Yield
With dihydrogen peroxide; acetic acid; potassium bromide In water at 60℃; for 6h; regioselective reaction;	A 85 %Spectr. B 15 %Spectr.

: 120-12-7
anthracene

A: 1564-64-3
9-Bromoanthracene

B: 523-27-3
9,10-Dibromoanthracene

C: 84-65-1
9,10-phenanthrenequinone

Conditions

Conditions	Yield
With Oxone; quartz; sodium bromide In n-heptane for 0.333333h; Milling; chemoselective reaction;

...Expand

: 1564-64-3
9-Bromoanthracene

: 1066-54-2
trimethylsilylacetylene

: 104784-61-4
[2-(anthracen-9-yl)ethynyl]trimethylsilane

Conditions

Conditions	Yield
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine In tetrahydrofuran for 15h; Heating;	100%
With piperidine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide In triethylamine at 110℃; Sonogashira Cross-Coupling;	99%
Stage #1: 9-Bromoanthracene; trimethylsilylacetylene With triethylamine for 0.0833333h; Sonogashira coupling; Inert atmosphere; Stage #2: With copper(l) iodide at 50 - 65℃; Sonogashira coupling; Inert atmosphere;	98%

: 1564-64-3
9-Bromoanthracene

: 5720-06-9
2-Methoxyphenylboronic acid

: 1232-27-5
9-(2'-methoxyphenyl)anthracene

Conditions

Conditions	Yield
With potassium phosphate; tris-(dibenzylideneacetone)dipalladium(0); C31H27FeOP In toluene at 70℃; for 24h; Reagent/catalyst; Time; Suzuki-Miyaura Coupling; Schlenk technique; Inert atmosphere; Sealed tube;	100%
With tris-(dibenzylideneacetone)dipalladium(0); potassium phosphate monohydrate; C30H25FeP In toluene at 100℃; for 24h; Suzuki-Miyaura Coupling; Sealed tube;	95%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; toluene for 20h; Heating;	90%

: 685-83-6
bis(diethylamino)chlorophosphine

: 1564-64-3
9-Bromoanthracene

: 925428-12-2
9-anthryl-bis(diethylamino)phosphine

Conditions

Conditions	Yield
With n-butyllithium In diethyl ether; hexane at -78 - 20℃; for 16h;	100%
Stage #1: 9-Bromoanthracene With n-butyllithium In diethyl ether; hexane at -78 - 0℃; for 1h; Inert atmosphere; Stage #2: bis(diethylamino)chlorophosphine In diethyl ether; hexane at -78 - 20℃; Inert atmosphere;

: 1564-64-3
9-Bromoanthracene

: 4688-76-0
2-Biphenylboronic acid

: 849223-96-7
9‐([1,1'‐biphenyl]‐2‐yl)anthracene

Conditions

Conditions	Yield
With potassium phosphate monohydrate; R-Phos; bis(dibenzylideneacetone)-palladium(0) In 1,4-dioxane at 100℃; for 0.5h; Suzuki coupling; Inert atmosphere;	100%

: 1066-35-9
dimethylmonochlorosilane

: 1564-64-3
9-Bromoanthracene

: anthracen-9-yldimethylsilane

Conditions

Conditions	Yield
With n-butyllithium In tetrahydrofuran; hexane at -78 - 20℃; for 1h; Inert atmosphere;	99.4%
Stage #1: 9-Bromoanthracene With n-butyllithium In tetrahydrofuran at -78℃; for 1h; Stage #2: dimethylmonochlorosilane In tetrahydrofuran at -78 - 20℃; for 8h;	59%
With n-butyllithium In diethyl ether; hexane at 25℃; for 72h;	54%
With n-butyllithium In diethyl ether at -40 - 20℃; for 17.5h; Inert atmosphere;	43%

: 1564-64-3
9-Bromoanthracene

: 120-12-7
anthracene

Conditions

Conditions	Yield
With 2-H-1,3-di-tert-butyl-1,3,2-diazaphosphorinane; 2,2'-azobis(isobutyronitrile) In toluene at 90℃; for 5h;	99%
With 1,3-bis(2,6-diisopropylphenyl)-2,4-diphenylimidazole In N,N-dimethyl-formamide at 20℃; for 36h; Glovebox;	98%
With N1,N1,N12,N12-tetramethyl-7,8-dihydro-6H-dipyrido[1,2-a:2,1'-c][1,4]diazepine-2,12-diamine In N,N-dimethyl-formamide at 20℃; Inert atmosphere;	96%

: 1564-64-3
9-Bromoanthracene

: 4485-03-4
9-deuteroanthracene

Conditions

Conditions	Yield
With potassium phosphate; d(4)-methanol; palladium diacetate; catacxium A In toluene at 80℃; for 16h;	99%
With dimethylsulfoxide-d6; 9-N-methylamino-1-oxophenalene; potassium tert-butylate; potassium at 25 - 30℃; for 24h; Inert atmosphere; Glovebox;	74%
With n-butyllithium; water-d2 In diethyl ether at 0℃;	57%

: 1564-64-3
9-Bromoanthracene

: 98-80-6
phenylboronic acid

: 602-55-1
9-phenylanthracene

Conditions

Conditions	Yield
With potassium phosphate; rac-2,8-bis(diphenylphosphanyl)-4,10-dimethyl-6,12-dihydro-5,11-methanodibenzo[b,f][1,5]diazocine; palladium diacetate In toluene at 90℃; Suzuki Coupling; Schlenk technique; Inert atmosphere;	99%
With potassium carbonate In (2)H8-toluene at 100℃; for 24h; Reagent/catalyst; Suzuki-Miyaura Coupling;	99%
With {2,6-bis[(di-1-piperidinylphosphino)amino]phenyl}palladium(II) chloride; potassium carbonate In 1,4-dioxane; water; butan-1-ol at 100℃; for 0.5h; Suzuki-Miyaura reaction;	98%

: 1564-64-3
9-Bromoanthracene

: 5122-94-1
4-biphenylboronic acid

: 9-([1,1'-biphenyl]-4-yl)anthracene

Conditions

Conditions	Yield
With palladium diacetate; potassium carbonate; triphenylphosphine In 1,2-dimethoxyethane; water at 80℃; for 17h; Inert atmosphere;	99%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; toluene for 24h; Inert atmosphere; Reflux; Sealed tube;	90%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene at 90℃; for 16h; Inert atmosphere;	90%

: 1564-64-3
9-Bromoanthracene

: 1158054-27-3
2-bromo-6-[2-(diphenylphosphinoyl)ethyl]pyridine

: 1158054-88-6
2-(9-anthracyl)-6-[2-(diphenylphosphinoyl)ethyl]pyridine

Conditions

Conditions	Yield
Stage #1: 9-Bromoanthracene With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.5h; Stage #2: With zinc(II) chloride In tetrahydrofuran; hexane at 20℃; for 1h; Stage #3: 2-bromo-6-[2-(diphenylphosphinoyl)ethyl]pyridine With tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran; hexane at 60℃; for 24h; Negishi-Takahashi coupling;	99%

: 1564-64-3
9-Bromoanthracene

: 16419-60-6
2-Methylphenylboronic acid

: 23674-13-7
9-(2-methylphenyl)anthracene

Conditions

Conditions	Yield
With tris-(dibenzylideneacetone)dipalladium(0); potassium phosphate monohydrate; C30H25FeP In toluene at 100℃; for 24h; Suzuki-Miyaura Coupling; Sealed tube;	99%
With potassium phosphate; C29H37O2P; palladium diacetate In toluene at 110℃; for 3h; Suzuki-Miyaura Coupling; Inert atmosphere; Schlenk technique;	94%
With potassium phosphate; tris-(dibenzylideneacetone)dipalladium(0); 1′-triethylsilyl-1-(2-(E)-phenylvinyl)-2-(diphenylphosphino)ferrocene In toluene at 70℃; for 24h; Suzuki-Miyaura Coupling; Schlenk technique; Inert atmosphere; Sealed tube;	89%

: 1564-64-3
9-Bromoanthracene

: 89523-63-7
benzylzinc chloride

: 1498-71-1
9-benzylanthracene

Conditions

Conditions	Yield
With palladium; triphenylphosphine In tetrahydrofuran at 70℃; for 24h; Catalytic behavior; Negishi Coupling; Inert atmosphere; Green chemistry;	99%

: 1564-64-3
9-Bromoanthracene

: 195062-57-8
p-tolylboronic pinacol ester

: 23674-14-8
9-(4-methylphenyl)anthracene

Conditions

Conditions	Yield
With bis-triphenylphosphine-palladium(II) chloride; potassium hydroxide In neat (no solvent) at 110℃; for 24h; Suzuki-Miyaura Coupling; Schlenk technique; Inert atmosphere;	99%

: 1564-64-3
9-Bromoanthracene

: 31614-66-1
tributyl(p-tolyl)stannane

: 23674-14-8
9-(4-methylphenyl)anthracene

Conditions

Conditions	Yield
With palladium diacetate; cesium fluoride; tricyclohexylphosphine In neat (no solvent) at 110℃; under 760.051 Torr; for 24h; Stille Cross Coupling; Sealed tube;	99%

: 1564-64-3
9-Bromoanthracene

: 613-31-0
9,10-dihydroanthracene

Conditions

Conditions	Yield
With manganese(II) chloride dihydrate; lithium In tetrahydrofuran at 25℃; for 0.5h; Birch reaction; Inert atmosphere;	98%
With potassium hydroxide semihydrate; phosphorus; water In dimethyl sulfoxide at 100℃; for 3h; Inert atmosphere;	90%
With Dicalcium Nitride Electride In tetrahydrofuran; isopropyl alcohol at 65℃; for 24h; Birch Reduction; Inert atmosphere;	84%
With tetraethylammonium perchlorate; triethylamine In dimethyl sulfoxide at 20℃; for 4h; Electrolysis; Green chemistry;	65%

: 1564-64-3
9-Bromoanthracene

: 5720-07-0
4-methoxyphenylboronic acid

: 23674-15-9
9-(p-methoxyphenyl)anthracene

Conditions

Conditions	Yield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene for 24h; Suzuki Coupling; Reflux; Inert atmosphere;	98%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene at 105℃; for 18h; Temperature; Inert atmosphere;	90%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; toluene at 110℃; for 20h; Temperature; Inert atmosphere;	90%

: 1564-64-3
9-Bromoanthracene

: 13922-41-3
1-Naphthylboronic acid

: 7424-70-6
10-(naphthalen-1-yl)anthracene

Conditions

Conditions	Yield
With potassium phosphate; tris-(dibenzylideneacetone)dipalladium(0); C31H27FeOP In toluene at 70℃; for 24h; Reagent/catalyst; Time; Suzuki-Miyaura Coupling; Schlenk technique; Inert atmosphere; Sealed tube;	98%
With C70H40Cl2F68N2O6Pd2; tetrabutylammomium bromide; potassium carbonate In water at 140℃; for 0.2h; Suzuki-Miyaura reaction; Microwave irradiation;	97%
With tetrabutylammomium bromide; potassium carbonate In ethanol; water; toluene at 70 - 75℃; for 2h; Inert atmosphere;	97.46%

: 1564-64-3
9-Bromoanthracene

: 86853-97-6
7H-Dibenzofluorenone

: 7-(9-anthryl)-7H-dibenzo[c,g]fluoren-7-ol

Conditions

Conditions	Yield
Stage #1: 9-Bromoanthracene With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 1h; Inert atmosphere; Stage #2: 7H-Dibenzofluorenone In tetrahydrofuran; hexane at -78 - 20℃; Inert atmosphere;	98%

: 1564-64-3
9-Bromoanthracene

: 4843-42-9
3-(1-naphthyl)propiolic acid

: 9-((naphthalen-1-yl)ethynyl)anthracene

Conditions

Conditions	Yield
With palladium diacetate; caesium carbonate; XPhos In tetrahydrofuran-d8 for 20h; Sonogashira Cross-Coupling; Glovebox; Schlenk technique; Inert atmosphere; Heating;	98%

: 1564-64-3
9-Bromoanthracene

: 32316-92-0
naphthalene-2-boronic acid

: 7424-72-8
9-(naphthyl-2-yl)anthracene

Conditions

Conditions	Yield
With tetrakis(triphenylphosphine) palladium(0); sodium hydroxide In tetrahydrofuran at 50 - 90℃; for 13h; Inert atmosphere;	97.4%
With potassium carbonate; triphenylphosphine; palladium diacetate In 1,2-dimethoxyethane; water for 8h; Suzuki cross-coupling; Heating;	92%
With potassium carbonate; palladium diacetate; tris-(o-tolyl)phosphine In 1,2-dimethoxyethane; water at 80℃; for 3h; Suzuki-Miyaura coupling;	92%

: 823-96-1
Trimethylboroxine

: 1564-64-3
9-Bromoanthracene

: 779-02-2
9-methylanthracene

Conditions

Conditions	Yield
With C70H40Cl2F68N2O6Pd2; tetrabutylammomium bromide; potassium carbonate In water at 140℃; for 0.2h; Suzuki-Miyaura reaction; Microwave irradiation;	97%

: 1564-64-3
9-Bromoanthracene

: 1888-75-1
isopropyllithium

: 1498-80-2
9-isopropylanthracene

Conditions

Conditions	Yield
With tris-(dibenzylideneacetone)dipalladium(0); monophosphine 1,2,3,4,5-pentaphenyl-1'-(di-tert-butylphosphino)ferrocene In toluene at 20℃; for 1h;	97%
With tris-(dibenzylideneacetone)dipalladium(0); DavePhos In toluene at 20℃; for 1h; Reagent/catalyst;

: 1564-64-3
9-Bromoanthracene

: 3-methoxy-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2-(trimethylsilyl)phenyl trifluoromethanesulfonate

: 5-(anthracen-9-yl)-3-methoxy-2-(trimethylsilyl)phenyl trifluoromethanesulfonate

Conditions

Conditions	Yield
With palladium diacetate; potassium carbonate; XPhos In water; toluene at 80℃; for 18h; Inert atmosphere;	97%

: 256-96-2
dibenzoazepine

: 1564-64-3
9-Bromoanthracene

: N-(9-anthryl)iminostilbene

Conditions

Conditions	Yield
With C30H43O2PC13H12N(1-)CH3O3S(1-)*Pd(2+); lithium hexamethyldisilazane In 1,4-dioxane at 100℃; for 16h; Inert atmosphere;	97%

: 1564-64-3
9-Bromoanthracene

: N-tert-butoxycarbonyl-N,N-bis[4-(di-tert-butylphenylamino)phenyl]amine

: C66H69N3

Conditions

Conditions	Yield
Stage #1: N-tert-butoxycarbonyl-N,N-bis[4-(di-tert-butylphenylamino)phenyl]amine With trifluoroacetic acid at 20℃; for 0.166667h; Stage #2: 9-Bromoanthracene With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate In toluene Inert atmosphere; Reflux;	97%

: 1564-64-3
9-Bromoanthracene

: 917-54-4
methyllithium

: 779-02-2
9-methylanthracene

Conditions

Conditions	Yield
Stage #1: 9-Bromoanthracene With bis(tri-t-butylphosphine)palladium(0); oxygen In toluene at 20℃; for 0.0166667h; Schlenk technique; Stage #2: methyllithium In toluene at 20℃; for 0.0333333h; Schlenk technique;	97%

: 1564-64-3
9-Bromoanthracene

: 1383803-71-1
2-(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)quinoline

: C29H19N

Conditions

Conditions	Yield
Stage #1: 9-Bromoanthracene; 2-(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)quinoline With potassium carbonate In ethanol; toluene for 0.333333h; Inert atmosphere; Stage #2: With tetrakis(triphenylphosphine) palladium(0) In ethanol; toluene Reflux;	97%

: 1564-64-3
9-Bromoanthracene

: 106-49-0
p-toluidine

: 15424-39-2
N-(4-methylphenyl)anthracen-9-amine

Conditions

Conditions	Yield
With bis[chloro(1,2,3-trihapto-allylbenzene)palladium(II)]; C30H42N2; sodium t-butanolate In tetrahydrofuran at 80℃; for 1h; Kinetics; Buchwald-Hartwig Coupling; Glovebox; Inert atmosphere; Molecular sieve; Sealed tube;	97%

9-Bromoanthracene Chemical Properties

Molecule structure of 9-Bromoanthracene (CAS NO.1564-64-3):

IUPAC Name: 9-Bromoanthracene
Molecular Weight: 257.12526 g/mol
Molecular Formula: C₁₄H₉Br
Density: 1.479 g/cm³
Melting Point: 97-100 °C(lit.)
Boiling Point: 389.7 °C at 760 mmHg
Flash Point: 190.3 °C
Index of Refraction: 1.733
Molar Refractivity: 69.62 cm³
Molar Volume: 173.8 cm³
Surface Tension: 51.3 dyne/cm
Enthalpy of Vaporization: 61.41 kJ/mol
Vapour Pressure: 6.28E-06 mmHg at 25 °C
Storage Temp.: 0-6 °C
XLogP3: 5.2
Exact Mass: 255.988763
MonoIsotopic Mass: 255.988763
Canonical SMILES: C1=CC=C2C(=C1)C=C3C=CC=CC3=C2Br
InChI: InChI=1S/C14H9Br/c15-14-12-7-3-1-5-10(12)9-11-6-2-4-8-13(11)14/h1-9H
InChIKey: ZIRVQSRSPDUEOJ-UHFFFAOYSA-N
EINECS: 216-359-3
Product Categories: Aromatic Compounds; blocks; Bromides; Aromatic Halides (substituted); Anthracenes; Anthracene series; Aryl; C13 to C37+; Halogenated Hydrocarbons

9-Bromoanthracene Safety Profile

Hazard Codes: Xi
Safety Statements: 22-24/25
S22:Do not breathe dust.
S24/25:Avoid contact with skin and eyes.
WGK Germany: 3
Hazard Note: Irritant
May cause eye irritation. if absorbed through the skin，it will cause skin irritation.
Ingestion:if swallowed，it May cause the irritation of digestive tract.if inhaled.it May be harmful for your respiratory.

9-Bromoanthracene Specification

9-Bromoanthracene (CAS NO.1564-64-3) is also named as NSC 803 ; Anthracene, 9-bromo- ; 10-Bromoanthracene ; 9-Anthracenyl bromide ; 9-Bromo anthracene . 9-Bromoanthracene (CAS NO.1564-64-3) is white to light yellow crystal powder.

Product Name

9-Bromoanthracene

Synthetic route

9-Bromoanthracene Chemical Properties

9-Bromoanthracene Safety Profile

9-Bromoanthracene Specification

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