Boric acid supplier | CasNO.11113-50-1

Name
Boric acid
EINECS 234-343-4
CAS No. 11113-50-1
Article Data800
CAS DataBase
Density 1.437 g/cm³
Solubility 49.5 g/L (20℃)
Melting Point 170.9oC
Formula BH₃O₃
Boiling Point
Molecular Weight 61.833
Flash Point
Transport Information
Appearance White powder
Safety
Risk Codes T:Toxic;
Molecular Structure
Hazard Symbols R60:;
Synonyms UNII-R57ZHV85D4;
PSA 60.69000
LogP -2.05180

Synthetic route

: 916730-63-7
1-boranyl-1,3,5-triaza-7-phosphaadamantane

: 7732-18-5
water

A: 11113-50-1
boric acid

B: 53597-69-6
(1,3,5-triaza-7-phosphaadamantane)

Conditions

Conditions	Yield
In water; acetone B-complex reacted with water in acetone/water (1:1) at 80°C for ca. 48 h; detn. by IR, 11B-NMR;	A 100% B n/a
In acetone slow reaction of B-complex with water; acceleration at higher temp.;	A 100% B n/a

...Expand

: 4262-38-8
1,3,5,7-Tetra-tert-butyl-2,4,6,8-tetrachloro-[1,3,5,7,2,4,6,8]tetrazatetraborocane

A: 11113-50-1
boric acid

B: 75-64-9
tert-butylamine

Conditions

Conditions	Yield
With water In further solvent(s) byproducts: HCl; solvent cyclohexanol, in tube 20.5 h at 160°C;	A n/a B 97%
With H2O In further solvent(s) byproducts: HCl; solvent cyclohexanol, in tube 20.5 h at 160°C;	A n/a B 97%
With water In xylene byproducts: HCl; in tube 20.5 h boiling;	A n/a B 62%
With H2O In xylene byproducts: HCl; in tube 20.5 h boiling;	A n/a B 62%

: 27120-66-7
closo-1-sulfinic acid-1,12-dicarbadodecaborane(12)

: 7722-84-1
dihydrogen peroxide

A: 226255-50-1
closo-1,12-(H)2-1,12-C2B10(OH)10

B: 396695-66-2
closo-2,3,4,5,6,7,8,9,10,11-decahydroxy-1-sulfonic acid-1,12-dicarbadodecaborane(12)

C: 11113-50-1
boric acid

Conditions

Conditions	Yield
In water aq. 30% H2O2 added to B compd.; refluxed for 3.5 h; monitored by (11)B NMR spectra; cond. HBr added; stirred (room temp., 2 h); kept. (80°C, 8 h); Br2 removed by N2 steam; volatiles removed in vac.; triturated in MeOH; centrifuged; supernatant sepd.; repeated 5 times; residue dissolved in water; filtered; dried;	A 5% B 88% C 3%

...Expand

: [Pt((c-C5H9)7Si7O10(OH)2)(C6H5)(1,2-bis(diphenylphosphino)ethane)]

: 5720-07-0
4-methoxyphenylboronic acid

: [Pt(C6H4OCH3-p)(C6H5)(1,2-bis(diphenylphosphino)ethane)]*H2O

B: 11113-50-1
boric acid

Conditions

Conditions	Yield
In tetrahydrofuran byproducts: (c-C5H9)7Si7O9(OH)3; (Ar); std. Schlenk technique; B compd. was added to soln. of Pt complex in THF; heated at 60°C for 30 min; concd. (vac.); hexane added; cooled at -20°C; filtered; washed (H2O); dried (vac.); elem. anal.;	A 88% B n/a
In benzene-d6 byproducts: (c-C5H9)7Si7O9(OH)3; (Ar); std. Schlenk technique; mixt. of B compd. and Pt complex in C6D6 was heated at 60°C for 30 min; NMR monitoring;
In tetrahydrofuran-d8 byproducts: (c-C5H9)7Si7O9(OH)3; (Ar); std. Schlenk technique; mixt. of B compd. and Pt complex in THF-d8was heated at 60°C for 15 min; NMR monitoring;

...Expand

: 1666-13-3
diphenyl diselenide

: 4844-17-1
2,4,5-triphenyl-1,3-dioxoborole

A: 11113-50-1
boric acid

B: 84-11-7
9,10-phenanthrenequinone

Conditions

Conditions	Yield
In benzene Irradiation (UV/VIS); irrdn. for 2 h 40 min with a 450 W medium pressure mercury lamp (290 to 330 nm), under Ar; extn. (aq. NaOH), dried (Na2SO4), evapd., crystn. from hexane, yields 9,10-phenanthraquinone;	A n/a B 84%

...Expand

: [(Pt(Ph)(1,5-cyclooctadiene))2(μ-OH)](BF4)

: 182482-25-3
2,4,6-trifluorophenylboronic acid

: 899439-56-6
Pt(C6H2F3-2,4,6)(Ph)(1,5-cyclooctadiene)

B: 11113-50-1
boric acid

Conditions

Conditions	Yield
In water; toluene room temp., 1 h, toluene/H2O = 100/1;	A 83% B n/a
In toluene under inert atm. to suspn. Pt complex in toluene water and (C6H2F3-2,4,6)B(OH)2 were added and stirred at room temp. for 1 h; solvent was evapd., residue was extd. by CDCl3; product was identified by NMR;	A 83% B n/a

...Expand

: cesium(1+)*arachno-6-SB9H12(1-)

A: arachno-4-SB8H12

B: 11113-50-1
boric acid

Conditions

Conditions	Yield
With hydrogenchloride; formaldehyd In dichloromethane; water byproducts: H2, CH3OH; addn. of CH2Cl2, aq. soln. of CH2O and aq. HCl to suspn. of B-compd. in H2O, stirring (ambient temp., 20 min); sepn. of CH2Cl2 layer, drying (CaCl2), evapn. to dryness, sublimation (25°C, 1.3 Pa, cold surface at -70°C);	A 81% B n/a

: 31139-16-9
cyanoborane

: 7732-18-5
water

A: 74-90-8
hydrogen cyanide

B: 1333-74-0
hydrogen

C: 11113-50-1
boric acid

Conditions

Conditions	Yield
hydrolysis at 90-95°C;	A 60% B 80% C 60%

...Expand

: 1111-47-3
tris(triphenylsiloxy)borane

: 11113-50-1
boric acid

Conditions

Conditions	Yield
With acetic acid In benzene byproducts: triphenylacetoxysilane; reflux for 3h, molar ratio B-compd.:AcOH=1:3; H3BO3 pptd., elem. anal.;	78%

: 1259401-57-4
[Pt((c-C5H9)7Si7O10(OH)2)(C6H5)(2,2'-bipyridine)]

: 5720-07-0
4-methoxyphenylboronic acid

: [Pt(C6H4OCH3-p)(C6H5)(2,2'-bipyridine)]*H2O

B: 11113-50-1
boric acid

Conditions

Conditions	Yield
In tetrahydrofuran byproducts: (c-C5H9)7Si7O9(OH)3; (Ar); std. Schlenk technique; B compd. was added to soln. of Pt complex in THF; heated at 60°C for 4 h; concd. (vac.); hexane added; cooled at -20°C; filtered; washed (H2O); dried (vac.); elem. anal.;	A 75% B n/a

...Expand

: 20644-59-1
o-carboranylacetic acid

: 443770-01-2
2-aminoethyl β-D-galactopyranosyl-(1->4)-O-β-D-glucopyranoside

A: (2-[(1,2-dicarba-nido-undecaborane(12)-1-yl)acetylamino]ethyl) 4-O-(β-D-galactopyranosyl)-β-D-glucopyranoside(1-)

B: (2-[(1,2-dicarba-closo-dodecaborane(12)-1-yl)acetylamino]ethyl) 4-O-(β-D-galactopyranosyl)-β-D-glucopyranoside

C: 11113-50-1
boric acid

Conditions

Conditions	Yield
With 4-(4,6-dimethoxy[1.3.5]triazin-2-yl)-4-methylmorph In methanol; water under Ar atm. to soln. carbohydrate amine and o-carboranylacetic acid inaq. MeOH 4-(4,6-dimethoxy(1.3.5)triazin-2-yl)4-methylmorpholinium chlor ide was added and stirred at room temp. for 22 h; volatiles were removed in vacuo, residue was dissolved in H2O, reverse-phase chromy. (SepPak C18, H2O -> MeOH);	A 7.6% B 74.2% C n/a

...Expand

: 121-43-7
Trimethyl borate

: 102-24-9
cyclotriboric acid trimethyl ester

A: 67-56-1
methanol

B: 11113-50-1
boric acid

Conditions

Conditions	Yield
With water	A 72.5% B n/a

...Expand

: tetramethyl-tetracarba-closo-docecaborane(12)

A: (CH3)4C4B7H9

B: 11113-50-1
boric acid

Conditions

Conditions	Yield
In ethanol; water stirred in air for 12 h; EtOH removed in vac., extd. (hexane), filtered on SiO2, evapd., productyield dependence on H2O concn. in EtOH (40-60%);	A 48% B 68%

: [(Pt(Ph)(1,5-cyclooctadiene))2(μ-OH)](BF4)

: 98-80-6
phenylboronic acid

: diphenyl(1,5-cyclooctadiene)platinum(II)

B: 11113-50-1
boric acid

Conditions

Conditions	Yield
In water; toluene room temp., 1 h, toluene/H2O = 100/1;	A 66% B n/a
In toluene under inert atm. to suspn. Pt complex in toluene water and PhB(OH)2 wereadded and stirred at room temp. for 1 h; solvent was evapd., residue was extd. by CDCl3; product was identified by NMR;	A 66% B n/a
In toluene room temp., 1 h;	A 38% B n/a

...Expand

: [(Pt(Ph)(1,5-cyclooctadiene))2(μ-OH)](BF4)

: 5720-07-0
4-methoxyphenylboronic acid

: diphenyl(1,5-cyclooctadiene)platinum(II)

: 791838-95-4
(1,5-cyclooctadiene)Pt(C6H4-4-OMe)(C6H5)

C: 11113-50-1
boric acid

Conditions

Conditions	Yield
In toluene room temp., 1 h;	A 64% B 14% C n/a

...Expand

: 99506-47-5
phenyl(m-carboran-9-yl)chloronium tetrafluoroborate

A: 17819-85-1
9-chloro-m-carborane

B: 54360-42-8
9-hydroxy-1,7-dicarba-closo-dodecaborane

C: 11113-50-1
boric acid

Conditions

Conditions	Yield
With water In water stirred for 200 h, 20-40°C; extracted with benzene, evaporated to dryness, chromatographed on silica (1. benzene-hexane (1:1), 2. ether), IR;	A 8% B 56% C 33%

...Expand

: anhydride of boric acid

: 7732-18-5
water

: 11113-50-1
boric acid

Conditions

Conditions	Yield
In water under N2 or Ar; by a react. of B-contg. compd. with H2O; evapn. of water at 80°C under vac.;	52%

: 10294-33-4
boron tribromide

A: boron

B: boron trioxide

C: 10043-11-5
boron nitride

: boron

E: 11113-50-1
boric acid

Conditions

Conditions	Yield
With H2; N2 In neat (no solvent) Electric Arc; pulse heating (plasma, puls repitition rate 5-12,5 Hz, N2 flow 0.2 - 1.65 l/min, H2 flow 1.13 - 3.5 l/min9; further products; X-ray diffraction;	A n/a B n/a C 50% D n/a E n/a

...Expand

: 23704-81-6
1,6-dicarba-closo-decaborane(10)

: 11113-50-1
boric acid

Conditions

Conditions	Yield
With HCl In tetrahydrofuran 25°C, 10 h, acidic hydrolysis;	50%

: 16940-66-2
sodium tetrahydroborate

: 109-63-7
trifluoroborane diethyl ether

A: 13755-29-8
sodium tetrafluoroborate

B: 17702-41-9
nido-decaborane

C: 60-29-7
diethyl ether

D: 11113-50-1
boric acid

Conditions

Conditions	Yield
With potassium permanganate; sulfuric acid In water; diethylene glycol; benzene byproducts: H2; NaBH4 in diglyme heated to 105°C and BF3*OEt2 added for 6 h and stirred for 1 h, mixt. cooled under N2 atm., water added, diglyme removed, H2SO4, benzene and KMnO4 added and react. mixt. stirred at 10°C; mixt. filtered, layers separated, benzene layer washed with water and dried over anhyd. MgSO4, evapd. and sublimed;	A n/a B 47% C n/a D n/a
With sulfuric acid; dihydrogen peroxide; iron(II) sulfate In hexane; water; diethylene glycol byproducts: H2; NaBH4 in diglyme heated to 105°C and BF3*OEt2 added for 6 h and stirred for 1 h, mixt. cooled under N2 atm., water added, diglyme removed, H2SO4, hexane and FeSO4, then H2O2 added and react. mixt. stirred at 35°C; mixt. filtered, layers separated, hexane layer washed with water and dried over anhyd. MgSO4;	A n/a B 44% C n/a D n/a
With sulfuric acid; dihydrogen peroxide In water; diethylene glycol; benzene byproducts: H2; NaBH4 in diglyme heated to 105°C and BF3*OEt2 added for 6 h and stirred for 1 h, mixt. cooled under N2 atm., water added, diglyme removed, H2SO4, benzene and then H2O2 added and react. mixt. stirred for 68 h; mixt. filtered, layers separated, benzene layer washed with water and dried over anhyd. MgSO4;	A n/a B 41.1% C n/a D n/a

...Expand

: 396695-62-8
closo-1,12-bis(sulfonic acid)-1,12-dicarbadodecaborane(12)

: 7722-84-1
dihydrogen peroxide

A: 396695-66-2
closo-2,3,4,5,6,7,8,9,10,11-decahydroxy-1-sulfonic acid-1,12-dicarbadodecaborane(12)

B: closo-2,3,4,5,6,7,8,9,10,11-decahydroxy-1,12-bis(sulfonicacid)-1,12-dicarbadodecaborane(12) hexahydrate

C: 11113-50-1
boric acid

Conditions

Conditions	Yield
In water excess of aq. 30% H2O2 added to B compd.; refluxed for 5 h; monitored by(11)B NMR spectra; concd. HBr added; stirred for 2 h at room temp.; kep t at 80°C for 8 h; Br2 removed by N2 steam; volatiles removed in vac.; triturated in MeOH; centrifuged; supernatant sepd.; repeated 5 times; residue dissolved in water; filtered; dried (mono-sulfonic acid compd.); MeOH washings evapd. slowly (bis-sulfonic acid compd.);	A 15% B 45% C n/a

Yield

In water excess of aq. 30% H2O2 added to B compd.; refluxed for 5 h; monitored by(11)B NMR spectra; concd. HBr added; stirred for 2 h at room temp.; kep t at 80°C for 8 h; Br2 removed by N2 steam; volatiles removed in vac.; triturated in MeOH; centrifuged; supernatant sepd.; repeated 5 times; residue dissolved in water; filtered; dried (mono-sulfonic acid compd.); MeOH washings evapd. slowly (bis-sulfonic acid compd.);

A 15%
B 45%
C n/a

...Expand

: 173788-87-9
2-phenoxy-4-methyl-1,3,2-dioxaborinane

: 98-88-4
benzoyl chloride

A: 7647-01-0
hydrogenchloride

B: 93-99-2
benzoic acid phenyl ester

C: 11113-50-1
boric acid

Conditions

Conditions	Yield
In benzene byproducts: 1,3-butanediol; acylchlorid dropwise addn. to soln. of B-compd., boiling (40 min), 1 d at room temperature, aq. HCl addn.;	A n/a B 43% C n/a

...Expand

: 75-18-3
dimethylsulfide

: 1179328-70-1
[closo-1-CB9H9-1-N2]

A: 201339-68-6
(CH3)2SCB9H9

B: 11113-50-1
boric acid

Conditions

Conditions	Yield
	A 40% B n/a

...Expand

: [(Pt(Ph)(1,5-cyclooctadiene))2(μ-OH)](BF4)

: 182482-25-3
2,4,6-trifluorophenylboronic acid

: 899439-56-6
Pt(C6H2F3-2,4,6)(Ph)(1,5-cyclooctadiene)

: 94352-68-8
Pt(C6H2F3-2,4,6)2(cod)

C: 11113-50-1
boric acid

Conditions

Conditions	Yield
In toluene room temp., 1 h;	A 36% B 1% C n/a

...Expand

: 396695-64-0
closo-1,12-bis(sulfinic acid)-1,12-dicarbadodecaborane(12)

: 7722-84-1
dihydrogen peroxide

A: 396695-66-2
closo-2,3,4,5,6,7,8,9,10,11-decahydroxy-1-sulfonic acid-1,12-dicarbadodecaborane(12)

B: closo-2,3,4,5,6,7,8,9,10,11-decahydroxy-1,12-bis(sulfonicacid)-1,12-dicarbadodecaborane(12) hexahydrate

C: 11113-50-1
boric acid

Conditions

Conditions	Yield
In water excess of aq. 30% H2O2 added to B compd.; refluxed for 5 h; monitored by(11)B NMR spectra; concd. HBr added; stirred for 2 h at room temp.; kep t at 80°C for 8 h; Br2 removed by N2 steam; volatiles removed in vac.; triturated in MeOH; centrifuged; supernatant sepd.; repeated 5 times; residue dissolved in water; filtered; dried (mono-sulfonic acid compd.); MeOH washings evapd. slowly (bis-sulfonic acid compd.);	A 25% B 35% C n/a

Yield

A 25%
B 35%
C n/a

...Expand

: 79193-50-3
2-(1-adamantyl)-1,3,2-dioxaborinane

: 11113-50-1
boric acid

Conditions

Conditions	Yield
With water In neat (no solvent) (N2), boiled with reflux condenser for 30 min; extd. (ether);	29%
With hydrogenchloride; water In diethyl ether Kinetics; byproducts: adamantane, adamantanol; (N2), C10H15B02C3H6 hydrolysed by 5% HCl (stirred at 20°C for several days); GLC;
With water In diethyl ether Kinetics; byproducts: adamantane, adamantanol; (N2), soln. of C10H15B02C3H6 added to water and stirred at 20°C for several days; aq. layer removed, washed (ether); GLC;

: 84633-96-5
bis-9-M-carboranylbromonium borofluoride

: 11113-50-1
boric acid

Conditions

Conditions	Yield
With water soln. of bis(9-m-carboranyl)bromonium borofluoride in water boiled for 4h; diluted with acetone, extn. with CH2Cl2, distn. in vac., addn. of etherpptn. of unreacted carborane, evapn. of aq. ext. left boric acid;	25%

: rubidium chloride

: 11113-50-1
boric acid

: rubidium pentaborate

Conditions

Conditions	Yield
With steam In neat (no solvent) heating of a mixt. of RbCl and boric acid in a stream of water-vapour at 100-150°C;;	100%
With steam In neat (no solvent) heating of a mixt. of RbCl and boric acid in a stream of water-vapour at 100-150°C;;	100%
With water byproducts: HCl; 100-150°C with steam;
With H2O byproducts: HCl; 100-150°C with steam;

: 71-23-8
propan-1-ol

: 69-65-8
mannitol

: 11113-50-1
boric acid

: 1,2,3,4,5,6-hexakis-O-dipropoxyboryl-D-mannitol

Conditions

Conditions	Yield
In toluene boiling a mixt. of D-mannitol, H3BO3, and n-propanol in toluene on a Dean-Stark apparatus (azeotropic removal of H2O);; removal of toluene and propanol; elem. anal.;;	100%

...Expand

: 90-01-7
salicylic alcohol

: 11113-50-1
boric acid

: 791-31-1
triphenylhydroxysilane

: 82172-56-3
2-triphenylsiloxy-4H-1,3,2-benzodioxaborin

Conditions

Conditions	Yield
In benzene byproducts: H2O; azeotropic removal of water; elem. anal.;	100%

...Expand

: 11113-50-1
boric acid

: 120-80-9
benzene-1,2-diol

: 791-31-1
triphenylhydroxysilane

: 82172-55-2
2-triphenylsiloxy-1,3,2-benzodioxaborole

Conditions

Conditions	Yield
In benzene byproducts: H2O; azeotropic removal of water; elem. anal.;	100%

...Expand

: 11113-50-1
boric acid

: 107-21-1
ethylene glycol

: 791-31-1
triphenylhydroxysilane

: 82172-50-7
2-triphenylsiloxy-1,3,2-dioxaborolane

Conditions

Conditions	Yield
In benzene byproducts: H2O; azeotropic removal of water; distd. in vac., elem. anal.;	100%

...Expand

: 739319-89-2
cadmium(II) carbonate

: cadmium(II) fluoride

: 11113-50-1
boric acid

: cadmium fluoroborate

Conditions

Conditions	Yield
With lead(II) fluoride In neat (no solvent, solid phase) at 450 - 800℃; for 48h;	100%

...Expand

: 11113-50-1
boric acid

: 120-80-9
benzene-1,2-diol

: 37737-62-5
tris(catecholato)diboron

Conditions

Conditions	Yield
In toluene Dean-Stark; Reflux;	100%

: antimony pentoxide

: 11113-50-1
boric acid

: 497-19-8
sodium carbonate

: Na2SbB3O8

Conditions

Conditions	Yield
at 750℃; for 72h;	100%

...Expand

: antimony pentoxide

: 11113-50-1
boric acid

: 584-08-7
potassium carbonate

: K2SbB3O8

Conditions

Conditions	Yield
at 750℃; for 72h;	100%

...Expand

: rubidium carbonate

: antimony pentoxide

: 11113-50-1
boric acid

: Rb2SbB3O8

Conditions

Conditions	Yield
at 750℃; for 72h;	100%

...Expand

: ytterbium(III) oxide

: 739319-89-2
cadmium(II) carbonate

: 11113-50-1
boric acid

: 3BO3(3-)*4Cd(2+)*Yb(3+)*O(2-)

Conditions

Conditions	Yield
at 950℃; for 120h;	100%

...Expand

: 86119-84-8, 7664-38-2
phosphoric acid

: 7732-18-5
water

: 11113-50-1
boric acid

: magnesium oxide

: luneburgite

Conditions

Conditions	Yield
for 0.166667h; Heating;	100%

...Expand

: 107641-99-6
2,5-Bis(2-hydroxypropylthio)-1,3,4-thiadiazole

: 10213-78-2
N,N-diethanolstearylamine

: 11113-50-1
boric acid

: C52H102B2N4O6S3

Conditions

Conditions	Yield
for 8h;	100%

...Expand

: C60H48N4O6

: 11113-50-1
boric acid

: C60H42B2N4O6

Conditions

Conditions	Yield
In chloroform for 66h; Reflux;	100%

: fuming sulphuric acid

: 11113-50-1
boric acid

: lead dioxide

: lead(II) borosulfate

Conditions

Conditions	Yield
at 119.84℃; for 24h; Sealed tube;	100%

...Expand

: 106-31-0
butanoic acid anhydride

: C14H11F2NO4

: 11113-50-1
boric acid

: C21H22BF2NO8

Conditions

Conditions	Yield
Stage #1: butanoic acid anhydride; boric acid at 90 - 120℃; for 3h; Inert atmosphere; Stage #2: C14H11F2NO4 at 115℃; for 2h;	100%

...Expand

: rubidium carbonate

: neodymium(III) oxide

: 11113-50-1
boric acid

: germanium dioxide

: RbNdGe2O6

Conditions

Conditions	Yield
Stage #1: rubidium carbonate; neodymium(III) oxide; boric acid; germanium dioxide at 1050℃; for 48h; Stage #2: at 950℃;	100%

...Expand

: ammonium sulfate

: 7664-93-9
sulfuric acid

: 7446-11-9
sulfur trioxide

: 11113-50-1
boric acid

: 3H3N*3H(1+)*B(SO4)3(3-)

Conditions

Conditions	Yield
at 300℃; for 3h;	100%

...Expand

: 1633-05-2
strontium(II) carbonate

: 7664-93-9
sulfuric acid

: 7446-11-9
sulfur trioxide

: 11113-50-1
boric acid

: Sr(2+)*2{B(SO4)2}(1-)=Sr{B(SO4)2}2

Conditions

Conditions	Yield
at 180℃; for 24h;	100%

...Expand

: 11113-50-1
boric acid

: 55478-53-0
pyroglutamoyl chloride

: Li(1+)*C10H10BN2O6(1-)

Conditions

Conditions	Yield
In N,N-dimethyl-formamide at 10℃; under 750.075 Torr; for 12h; Flow reactor;	99.1%

: 488-86-8
croconic acid

: 11113-50-1
boric acid

: 213967-57-8
1,4-Dioxane-2,3,5,6-tetrone

: Li(1+)*C7BO9(1-)

Conditions

Conditions	Yield
In water at 20℃; under 0 Torr; for 8h; Flow reactor;	99.1%

...Expand

: 11113-50-1
boric acid

: 56-35-9
bis(tri-n-butyltin)oxide

: 57754-92-4
(C4H9)3SnOB(OH)2

Conditions

Conditions	Yield
byproducts: H2O; B(OH)3 excess; 160°C;	99%
byproducts: H2O; B(OH)3 excess; 160°C;	99%

: 11113-50-1
boric acid

: vanadia

: 107-15-3
ethylenediamine

: 4H3NC2H4NH3(2+)*V6B20O50H8(8-)*5H2O=(H3NC2H4NH3)4V6B20O50H8*5H2O

Conditions

Conditions	Yield
In melt heating at 180°C for 3 days;	99%

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: 7664-41-7
ammonia

: 11113-50-1
boric acid

: 10043-11-5
boron nitride

Conditions

Conditions	Yield
With multi-walled carbon nanotubes In solid byproducts: CO, H2, H2O; mixt. of multi-walled carbon nanotubes and H3BO3 taken in quartz tube, NH3 gas passed through with 10 sccm flow rate at 200 °C 2 h, temp.slowly raised to 1000 °C for 3 h;	99%
With pyrographite; iron In neat (no solvent) byproducts: CO, H2, H2O; mixt. of activated carbon, H3BO3 and ferric nitrate (mole ratio of 3:1:0.1) taken in quartz tube, dried in oven at 60 °C 6 h, NH3 gas passed through with 10 sccm flow rate, heating at 1300 °C for 4 h;
byproducts: H2O; synthesis of BN coating on the surfaces of carbon nanotubes and nanofibers around 1150°C using infiltration of nanotubes with boric acid and nitridation in ammonia;

: 11113-50-1
boric acid

: 92-44-4
2,3-naphthalenediol

: 1071759-34-6
cinchonidine

: cinchonidinium (bis-2,3-naphthalenediyl)orthoborate salt

Conditions

Conditions	Yield
In acetone mixt. of alkaloid, boric acid and 2,3-dihydroxynaphthalene (molar ratio 1:1:2) dissolved in hot acetone, warmed; evapd., noncryst. solid product;	99%

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: tri(ethylenediamine) cobalt(III) chloride dihydrate

: 86119-84-8, 7664-38-2
phosphoric acid

: 11113-50-1
boric acid

: boron trifluoride monoethylamine

: C2H10N2(2+)*CoB2P3O12(OH)(2-) = [C2H10N2][CoB2P3O12(OH)]

Conditions

Conditions	Yield
In water hydrothermal synthesis (180°C, 5 d); elem. anal.;	99%

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: 636-61-3
D-Malic acid

: 11113-50-1
boric acid

: 1310-73-2
sodium hydroxide

: sodium (S,S,S)-dimalatoborate

Conditions

Conditions	Yield
In water malic acid dissolved in H2O, treated with boric acid, aq. NaOH added, stirred in open flask at 100 °C for ca. 4 h; mixt. evapd.; detd. by NMR, XRD;	99%

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: 11113-50-1
boric acid

: 6-methyl-5-hepten-3-yn-1-ol

: tris(6-methyl-5-hepten-3-yn-1-oxy)borane

Conditions

Conditions	Yield
In toluene byproducts: H2O; (N2); stirring of mixt. of boric acid and 6-methyl-5-hepten-3-yn-1-ol intoluene under reflux for 12 h with removal of water by a Dean-Stark tra p; evapn. of solvent by distn. (180-230°C/0.5 mmHg);	99%

: 1073-72-9
4-hydroxythioanisole

: 11113-50-1
boric acid

: 24676-71-9
sodium 4-methylthio-phenolate

: sodium tetrakis(4-methylthiophenoxy)borate

Conditions

Conditions	Yield
In toluene phenol (excess) and acid heated for 2 h (Dean-Stark trape), volatiles removed (vac.), dissolved (THF), added dropwise to a soln. of Na compd. (THF), stirred for 1-12 h; ppt. filtered, washed (diethyl ether, pentane), dried (high vac.); elem.anal.;	99%

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Boric acid Specification

The Boric acid, with the CAS registry number 11113-50-1, is also known as UNII-R57ZHV85D4 .It belongs to the product categories of UVCBs-inorganic.Its EINECS number is 234-343-4.This chemical's molecular formula is H₃BO₃and molecular weight is 61.83. What's more,Its systematic name is Boric acid.

The Boric acid has many various application, such as in personal care products, food additives, biological insecticides & antiputrefactiva. Except these, it is also used in the glass, ceramics, rubber, fertilisers, flame retardants, paints, industrial fluids, brake fluids, soldering products, film developers and so on.And it is among one kind of 8 Substances of Very High Concern which is issued by the ECHA, as this chemical could cause very serious danger to people's health, including being carcinogenic, inducing the organism's mutation, damage to genital system and so on.

Physical properties about Boric acid are:(1)ACD/LogP: -0.61; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): -0.61; (4)ACD/LogD (pH 7.4): -0.62; (5)ACD/BCF (pH 5.5): 1.00; (6)ACD/BCF (pH 7.4): 1.00; (7)#H bond acceptors: 3; (8)#H bond donors: 3; (9)#Freely Rotating Bonds: 3; (10)Index of Refraction: 1.385; (11)Molar Refractivity: 10.083 cm3; (12)Molar Volume: 43.003 cm3; (13)Surface Tension: 59.1980018615723 dyne/cm; (14)Density: 1.438 g/cm3.

You can still convert the following datas into molecular structure:
(1)SMILES:B(O)(O)O;
(2)Std. InChI:InChI=1S/BH3O3/c2-1(3)4/h2-4H;
(3)Std. InChIKey:KGBXLFKZBHKPEV-UHFFFAOYSA-N.

Product Name

Boric acid

Synthetic route

Boric acid Specification

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