Product Name

Stability

    Stable. Incompatible with strong oxidizing agents, nitrates,nitric acid, selenium, zinc. Flammable. Powdered metal may be pyrophoric.

Toxicology

    Many cadmium compounds are believed to be carcin
  • Melting Point 320.9ºC
  • Formula Cd
  • Boiling Point 765ºC
  • Molecular Weight 112.41
  • Flash Point
  • Transport Information
  • Appearance silvery white metal
  • Safety 53-45-61-60-43-7/8-26
  • Risk Codes R20/21/22;R50/53;
  • Molecular Structure Molecular Structure of 7440-43-9 (Cadmium)
  • Hazard Symbols ToxicTVeryT+DangerousNFlammableFIrritantXi
  • Synonyms C.I. 77180;
  • PSA 0.00000
  • LogP -0.00250

Synthetic route

hydrogen
1333-74-0

hydrogen

cadmium(II) oxide

cadmium(II) oxide

cadmium
7440-43-9

cadmium

Conditions
ConditionsYield
3h at 290-300°C, flowing hydrogen, react. start even at 282°C;100%
below temp. of sintering;
cadmium sulfate

cadmium sulfate

aluminium
7429-90-5

aluminium

A

aluminum(III) sulfate

aluminum(III) sulfate

B

cadmium
7440-43-9

cadmium

Conditions
ConditionsYield
In water Al powder activated with HCl; pptn. of Cd;A n/a
B 100%
In water Al powder activated with HCl; pptn. of Cd;A n/a
B 100%
In water Al wire; incomplete pptn. of Cd; pptn. within some minutes in presence of sodium potassium tartrate;
In water Al wire; incomplete pptn. of Cd; pptn. within some minutes in presence of sodium potassium tartrate;
vanadocene

vanadocene

bis-{tris-(pentafluoro phenyl) germanium} cadmium
35098-95-4

bis-{tris-(pentafluoro phenyl) germanium} cadmium

A

(C5H5)2VGe(C6F5)3

(C5H5)2VGe(C6F5)3

B

cadmium
7440-43-9

cadmium

Conditions
ConditionsYield
In toluene to Cd compd. soln. added complex soln., reacted for 20 h at 20°C; Cd centrifugated, org. layer decanted, concd. (vac.), pptd. (hexane, for 24 h at -78°C);A 79%
B 100%
1,2-dimethoxyethanebis(pentadeuterocyclopentadienyl)ytterbium(II)

1,2-dimethoxyethanebis(pentadeuterocyclopentadienyl)ytterbium(II)

cadmium(II) chloride
10108-64-2

cadmium(II) chloride

A

chlorobis(cyclopentadienyl)ytterbium(III)-tetrahydrofuran(2:1)

chlorobis(cyclopentadienyl)ytterbium(III)-tetrahydrofuran(2:1)

B

cadmium
7440-43-9

cadmium

Conditions
ConditionsYield
In tetrahydrofuran N2-atmosphere; stirring Yb-complex with 0.5 equiv. of halide (room temp., 16 h); filtration, washing (THF), evapn. (vac.), drying (vac.);A 80%
B 100%
Mn(92.5),Fe(b) (X%)

Mn(92.5),Fe(b) (X%)

cadmium(II) sulphide

cadmium(II) sulphide

cadmium
7440-43-9

cadmium

Conditions
ConditionsYield
equiv amts. of educts, 950°C, 4h, 1 atm, 0.5 l/h N2;97%
with 25% excess of ferromanganese, 900°C;95%
Mn(98.43),Fe(0.97) (X%)

Mn(98.43),Fe(0.97) (X%)

cadmium(II) sulphide

cadmium(II) sulphide

cadmium
7440-43-9

cadmium

Conditions
ConditionsYield
finely powdered Mn. equiv amts. of educts, 950°C, 4h, 1 atm, 0.5 l/h N2;97%
sodium tri-tert-butylsilanide
103349-41-3

sodium tri-tert-butylsilanide

cadmium(II) iodide

cadmium(II) iodide

A

disupersilylcadmium
60349-27-1

disupersilylcadmium

B

cadmium
7440-43-9

cadmium

Conditions
ConditionsYield
In tetrahydrofuran byproducts: NaI, tBu3SiH; N2 atm.; molar ratio CdI2:RNa 1:2, 20°C; evapn., extraction (pentane), filtn., crystn. (48 h, -23°C); elem. anal.;A 91%
B n/a
vanadocene

vanadocene

dipropylcadmium
5905-48-6

dipropylcadmium

A

(C5H5)2V(C3H7)

(C5H5)2V(C3H7)

B

cadmium
7440-43-9

cadmium

Conditions
ConditionsYield
In toluene byproducts: C3H8, C3H6; addn. of vanadocene in toluene to Cd-compd. at -78°C, brought to room temp.; crystn.; elem. anal.;A 90%
B n/a
vanadocene

vanadocene

dimethylcadmium
506-82-1

dimethylcadmium

A

dimethylvanadocene
62363-03-5

dimethylvanadocene

B

cadmium
7440-43-9

cadmium

Conditions
ConditionsYield
In neat (no solvent) V-compd. added to Cd-compd. at room temp., immediate reaction; extd. (pentane);A 90%
B n/a
1-lithio-2,6-bis[(diethylamino)methyl]benzene

1-lithio-2,6-bis[(diethylamino)methyl]benzene

cadmium(II) chloride
10108-64-2

cadmium(II) chloride

A

bis[2,6-bis(diethylaminomethyl)phenyl]cadmium
204863-82-1

bis[2,6-bis(diethylaminomethyl)phenyl]cadmium

B

cadmium
7440-43-9

cadmium

Conditions
ConditionsYield
In diethyl ether byproducts: LiCl; Ar atmosphere, in the dark, addn. of portions of soln. of lithium compound to metal chloride, warming, stirring (room temp., 16 h); removement of solvent (vacuum), suspension (n-pentane), filtration, reductn. of volume, crystn. (-20°C); elem. anal.;A 62%
B n/a
cadmium(II) chloride
10108-64-2

cadmium(II) chloride

2-(dimethylaminoethyl)phenyllithium

2-(dimethylaminoethyl)phenyllithium

A

bis(2-diethylaminomethylphenyl)cadmium
204863-78-5

bis(2-diethylaminomethylphenyl)cadmium

B

cadmium
7440-43-9

cadmium

Conditions
ConditionsYield
In diethyl ether byproducts: LiCl; Ar atmosphere, in the dark, addn. of metal chloride soln. to soln. of lithium compound, warming, stirring (room temp., 14 h); removement of solvent (vacuum), suspension (n-hexane), filtration, reductn. of volume, crystn. (-20°C); elem. anal.;A 59%
B n/a
(Et3Ge)2Cd
4149-24-0

(Et3Ge)2Cd

titanium tetrachloride
7550-45-0

titanium tetrachloride

A

titanium(III) chloride tetrahydrofuran

titanium(III) chloride tetrahydrofuran

bis(triethylgermylcadmiumtitanium bipyridyl dichloride)

bis(triethylgermylcadmiumtitanium bipyridyl dichloride)

C

TiCl1.7*1.5(C5H4N)2

TiCl1.7*1.5(C5H4N)2

D

bis(triethylgermyl)(dipyridyl)cadmium

bis(triethylgermyl)(dipyridyl)cadmium

E

cadmium
7440-43-9

cadmium

Conditions
ConditionsYield
With (C5H4N)2 In tetrahydrofuran byproducts: (CH3CH2)3GeCl; (dry Ar); soln. of (Et3Ge)2Cd added to TiCl4*2THF at -20°C; 1 h;after 20 h at 20°C Cd and TiCl3*3THF pptd.; bipy added to THF soln., kept for 24 h at 20°C, TiCl1.7*1.5bipy pptd.; THF removed in vacuo, residue washed (hexane), dried; elem. anal.;A 55%
B 44.6%
C 2%
D n/a
E 5%
bis(3-lithiopropyl)methylamine

bis(3-lithiopropyl)methylamine

cadmium(II) chloride
10108-64-2

cadmium(II) chloride

A

Cd(C7H15N)

Cd(C7H15N)

B

(5,13-diaza)-5,13-dimethyl-1,9-dicadmacyclohexadecane

(5,13-diaza)-5,13-dimethyl-1,9-dicadmacyclohexadecane

C

cadmium
7440-43-9

cadmium

Conditions
ConditionsYield
In diethyl ether byproducts: LiCl; Ar atmosphere, in the dark, addn. of portions of soln. of lithium compound to metal chloride, warming, stirring (room temp., 12 h); removement of solvent (vacuum), suspension (n-pentane), filtration, reductn. of volume, crystn. (-20°C); elem. anal.;A 0%
B 49%
C n/a
nickelocene
1271-28-9

nickelocene

dipropylcadmium
5905-48-6

dipropylcadmium

A

(C3H7)CdNi(C5H5)(C3H7)CdNi(C3H7)(C5H5)Cd(C3H7)

(C3H7)CdNi(C5H5)(C3H7)CdNi(C3H7)(C5H5)Cd(C3H7)

B

cadmium
7440-43-9

cadmium

Conditions
ConditionsYield
In toluene byproducts: C3H8, C3H6; under Ar or in a vac.; addn. of Cd-compd. to soln. of Ni-compd. at -78°C, brought to room temp., kept for 3d, pptn.; decantation, washed (toluene); elem. anal.;A 0.85%
B <0.01
nickel(II) sulfate heptahydrate

nickel(II) sulfate heptahydrate

cadmium(II)

cadmium(II)

cadmium
7440-43-9

cadmium

Conditions
ConditionsYield
In water Electrolysis; electrolysis of 144 g/l NiSO4*7H2O, 10 g/l H3BO3 and 1.3 g/l Cd-salt at 20 °C; (the Cd concentration and the color of the cover depended on the current density and the Cd concentration of the electrolyte);;
In water Electrolysis; electrolysis of 144 g/l NiSO4*7H2O, 10 g/l H3BO3 and 1.3 g/l Cd-salt at 20 °C; (the Cd concentration and the color of the cover depended on the current density and the Cd concentration of the electrolyte);;
potassium tetracyanocadmate(II)

potassium tetracyanocadmate(II)

cadmium
7440-43-9

cadmium

Conditions
ConditionsYield
In water Electrolysis; 15-20°C, 0.5 A/dm^2; Cd layer sepd. from polished steel;
With potassium In ammonia pptn.;
In water
With K In ammonia
potassium tetracyanocadmate(II)

potassium tetracyanocadmate(II)

potassium
7440-09-7

potassium

cadmium
7440-43-9

cadmium

Conditions
ConditionsYield
In ammonia pyrophoric Cd dust product;
In ammonia
tricadmium phosphate

tricadmium phosphate

cadmium
7440-43-9

cadmium

Conditions
ConditionsYield
With H3PO4; NH4Cl; NH4ClO4 In water Electrolysis; current d. and bath compn. given, Cd cathode, Cd anode;
cadmium subchloride

cadmium subchloride

water
7732-18-5

water

A

cadmium(II) chloride
10108-64-2

cadmium(II) chloride

B

cadmium
7440-43-9

cadmium

Conditions
ConditionsYield
decomposition in presence of water;;
decomposition in presence of water;;
cadmium(II) cyanide

cadmium(II) cyanide

cadmium
7440-43-9

cadmium

Conditions
ConditionsYield
In further solvent(s) Electrolysis; 100°C, Cu cathode, Pt anode, bath compn., current d. given; solvent: acetamide;
With potassium cyanide In not given Electrolysis; deposition of Cd by electrolysis of a soln. containing 0.1 n-Cd(CN)2 and excess of 0.3 n-KCl at 18 °C; deposition potential 2.6 V at usual temps.;;
In ammonia Electrolysis; satd. soln. of Cd(CN)2, Cu cathode, Pt anode, current d. given;
zinc(II) cyanide
557-21-1

zinc(II) cyanide

2Na(1+)*Cd(CN)4(2-)=Na2{Cd(CN)4}

2Na(1+)*Cd(CN)4(2-)=Na2{Cd(CN)4}

cadmium
7440-43-9

cadmium

Conditions
ConditionsYield
With NaOH; NaCN Electrolysis; 20°C; compn. of agitated bath in g/l: upto 16 Cd in form of Na2{Cd(CN)4}, 60 Zn(CN)2, 60 NaOH, 40 NaCN; pptn. of Cd begins at <-1.0 V, beginning Zn deposition at ca. -1.25 to -1.3 V;
With NaOH; NaCN Electrolysis; 20°C; compn. of agitated bath in g/l: 2 Cd in form of Na2{Cd(CN)4}, 100 Zn(CN)2, 100 NaOH, 160 NaCN; current density < 0.2 A/dm^2; final cathodic potential: ca. -1.5 V;
sodium tri-tert-butylsilanide
103349-41-3

sodium tri-tert-butylsilanide

cadmium(II) iodide

cadmium(II) iodide

cadmium
7440-43-9

cadmium

Conditions
ConditionsYield
In tetrahydrofuran byproducts: NaI, Si2(tBu)6; N2 atm.; alkane as solvent (pentane or heptane), room temp., molar ratioRNa:CdI2 2:1;
cadmium sulfate

cadmium sulfate

cadmium amidosulfate

cadmium amidosulfate

cadmium
7440-43-9

cadmium

Conditions
ConditionsYield
In not given deposition of Cd on polished cylindric Zn slab from soln. of CdSO4 and Cd(SO3NH2)2; 18°C;;
nickel arsenide

nickel arsenide

cadmium(II) oxide

cadmium(II) oxide

A

trisodium arsenate

trisodium arsenate

B

nickel
7440-02-0

nickel

C

cadmium
7440-43-9

cadmium

Conditions
ConditionsYield
With sodium hydroxide In melt byproducts: H2O; in molten NaOH; analogous reaction with natural arsenides;
With NaOH In melt byproducts: H2O; in molten NaOH; analogous reaction with natural arsenides;
cadmium(II) sulphide

cadmium(II) sulphide

cadmium
7440-43-9

cadmium

Conditions
ConditionsYield
With hydrogen byproducts: H2S; >450°C or between 524-1152°C; equil.;
With aluminium reduction of CdS with Al;;
With calcium carbide 800°C;
cadmium(II) sulphide

cadmium(II) sulphide

A

sulfur
7704-34-9

sulfur

B

cadmium
7440-43-9

cadmium

Conditions
ConditionsYield
>444°C;
>444°C;
cadmium(II) sulphide

cadmium(II) sulphide

cadmium(II) oxide

cadmium(II) oxide

cadmium
7440-43-9

cadmium

Conditions
ConditionsYield
byproducts: SO2;0%
byproducts: SO2;0%
arsenic

arsenic

cadmium(II) sulphide

cadmium(II) sulphide

sodium hydroxide
1310-73-2

sodium hydroxide

A

sodium sulfide

sodium sulfide

B

trisodium arsenate

trisodium arsenate

C

cadmium
7440-43-9

cadmium

Conditions
ConditionsYield
In melt in NaOH melt;
In melt in NaOH melt;
tellurium

tellurium

Rb2Te3

Rb2Te3

cadmium
7440-43-9

cadmium

Rb2Cd3Te4

Rb2Cd3Te4

Conditions
ConditionsYield
In neat (no solvent) 1:3:1 mixt. at 773°C for 6 ds, slowly cooled to room temp.; XRD;100%
tellurium

tellurium

Cs2Te3

Cs2Te3

cadmium
7440-43-9

cadmium

Cs2Cd3Te4

Cs2Cd3Te4

Conditions
ConditionsYield
In neat (no solvent) 1:3:1 mixt. at 873°C for 6 ds, slowly cooled to room temp.; XRD;100%
tellurium

tellurium

potassium
7440-09-7

potassium

cadmium
7440-43-9

cadmium

potassium cadmium(II) telluride

potassium cadmium(II) telluride

Conditions
ConditionsYield
In neat (no solvent, solid phase) under Ar; mixt. was heated to 523 K for 1 d, then heated at 1023 K for 1d, then cooled to 773 K at 2 K/h, kept at 773 K for 3 d, then cooled to 473 K at 2 K/h in 5 d before switching off the furnace; XRD;100%
calcium
7440-70-2

calcium

platinum
7440-06-4

platinum

cadmium
7440-43-9

cadmium

Ca6PtCd11

Ca6PtCd11

Conditions
ConditionsYield
In neat (no solvent) at 600 - 950℃; for 111h; Sealed tube; Schlenk technique; Inert atmosphere; Glovebox;100%
bismuth
7440-69-9

bismuth

selenium
7782-49-2

selenium

caesium selenide

caesium selenide

cadmium
7440-43-9

cadmium

Cs1.13Cd1.13Bi2.87Se6

Cs1.13Cd1.13Bi2.87Se6

Conditions
ConditionsYield
In neat (no solvent) at 750℃; for 48h; Inert atmosphere;100%
bismuth
7440-69-9

bismuth

selenium
7782-49-2

selenium

rubidium

rubidium

cadmium
7440-43-9

cadmium

Rb2CdBi6Se11

Rb2CdBi6Se11

Conditions
ConditionsYield
In melt mixt. heated at 750°C for 72 h with rocking in evacuated silica tubes; cooled to 550°C (5°/h), then to 50°C in 10 h;99%
bismuth
7440-69-9

bismuth

selenium
7782-49-2

selenium

caesium
7440-46-2

caesium

cadmium
7440-43-9

cadmium

CsCdBi3Se6

CsCdBi3Se6

Conditions
ConditionsYield
In melt mixt. heated at 750°C for 2 h with rocking in evacuated silica tubes; cooled to 550°C (20°/h), then to room temp. in 10 h;99%
arsenic

arsenic

mercury

mercury

mercury dichloride

mercury dichloride

cadmium
7440-43-9

cadmium

6Hg(2+)*4As(2-)*CdCl6(4-)*0.5Hg=[Hg6As4][CdCl6]Hg0.5

6Hg(2+)*4As(2-)*CdCl6(4-)*0.5Hg=[Hg6As4][CdCl6]Hg0.5

Conditions
ConditionsYield
In neat (no solvent, solid phase) mixt. of HgCl2, Hg, Cd, As (6:1:2:8 molar ratio) heated at 450°C for 120 h; XRD, TGA;99%
arsenic

arsenic

mercury dibromide

mercury dibromide

cadmium
7440-43-9

cadmium

6Hg(2+)*4As(2-)*CdBr6(4-)=[Hg6As4][CdBr6]

6Hg(2+)*4As(2-)*CdBr6(4-)=[Hg6As4][CdBr6]

Conditions
ConditionsYield
In neat (no solvent, solid phase) mixt. of HgBr2, Cd, As (3:1:4 molar ratio) heated at 350°C for 120 h; TGA, XRD;99%
In neat (no solvent, solid phase) mixt. of HgBr2, Cd, As (1:0.5:1 molar ratio) heated at 350°C for 120 h; elem. anal.;
copper(l) iodide
7681-65-4

copper(l) iodide

Iodotrifluoroethylene
359-37-5

Iodotrifluoroethylene

cadmium
7440-43-9

cadmium

trifluorovinyl copper
102682-87-1

trifluorovinyl copper

Conditions
ConditionsYield
In N,N-dimethyl-formamide byproducts: CdI2; N2; slight excess of acid-washed Cd powder added to alkene soln.; mild exothermic reaction after induction period; removal of excess Cd by press. filtrn. under N2; stirring mixt. at 0 °C for half h with CuI or CuBr; final warming to room temp.; (19)F NMR;99%
arsenic

arsenic

mercury(I) iodide

mercury(I) iodide

cadmium
7440-43-9

cadmium

2Hg2As(1+)*CdI4(2-)=(Hg2As)2(CdI4)

2Hg2As(1+)*CdI4(2-)=(Hg2As)2(CdI4)

Conditions
ConditionsYield
In neat (no solvent, solid phase) mixt. was heated at 320°C for 120 h; XRD;99%
antimony
7440-36-0

antimony

mercury(I) iodide

mercury(I) iodide

mercury

mercury

cadmium
7440-43-9

cadmium

6Hg(2+)*4Sb(2-)*CdI6(4-)*0.6Hg=[Hg6Sb4][CdI6]Hg0.6

6Hg(2+)*4Sb(2-)*CdI6(4-)*0.6Hg=[Hg6Sb4][CdI6]Hg0.6

Conditions
ConditionsYield
In neat (no solvent, solid phase) mixt. of Hg2I2, Hg, Cd, Sb (3:1:1:4 molar ratio) heated at 350°C for 120 h; TGA, XRD;99%
antimony
7440-36-0

antimony

barium peroxide
1304-29-6

barium peroxide

barium
7440-39-3

barium

cadmium
7440-43-9

cadmium

A

Ba3Cd2Sb4

Ba3Cd2Sb4

B

Ba11Cd6Sb12

Ba11Cd6Sb12

C

Ba5Cd2O0.7Sb5

Ba5Cd2O0.7Sb5

Conditions
ConditionsYield
In neat (no solvent) (Ar or vac.); heated to 900°C at a rate of 200°C/h, kept at 900°C for 20 h, cooled to 500°C at a rate of 5°C/h; allowed to cool to room temp.;A 1%
B 1%
C 99%
cesium sulfide

cesium sulfide

bismuth(III) sulfide

bismuth(III) sulfide

sulfur
7704-34-9

sulfur

cadmium
7440-43-9

cadmium

A

Cs1.43Cd1.43Bi2.57S6

Cs1.43Cd1.43Bi2.57S6

B

cadmium(II) sulphide

cadmium(II) sulphide

Conditions
ConditionsYield
Stage #1: cesium sulfide; bismuth(III) sulfide; sulfur; cadmium In neat (no solvent) at 300℃; for 7h; Sealed tube;
Stage #2: In neat (no solvent) at 450℃; for 12h; Sealed tube;
Stage #3: In neat (no solvent) at 700℃; for 48h; Sealed tube;
A 99%
B n/a
3-phenylacrylic acid hydrazide
3538-69-0

3-phenylacrylic acid hydrazide

cadmium
7440-43-9

cadmium

Cd(C9H9N2O)2(H2O)2*2H2O

Cd(C9H9N2O)2(H2O)2*2H2O

Conditions
ConditionsYield
With Et4NClO4 In acetone byproducts: H2; Electrolysis; electrolysis (25 V, 4 h); filtn., evapn., collection, vashing (Et2O), drying (vac.); elem. anal.;97%
N,N'-bis(3-hydroxysalicylidene)-1,3-diamino-2-propanol
266689-62-7

N,N'-bis(3-hydroxysalicylidene)-1,3-diamino-2-propanol

cadmium
7440-43-9

cadmium

[Cd2[(O2C6H3CHNCH2)2CHOH](H2O)2]

[Cd2[(O2C6H3CHNCH2)2CHOH](H2O)2]

Conditions
ConditionsYield
In acetonitrile byproducts: H2; Electrolysis; The metal was used as the anode, and tetramethylammonium perchlorate assupporting electrolyte. 17.6 V initial voltage, 11400 s; filtration, washing (acetonitrile, Et2O), elem. anal.;97%
ethyl iodide
75-03-6

ethyl iodide

cadmium
7440-43-9

cadmium

A

ethylcadmium iodide
17068-35-8

ethylcadmium iodide

B

cadmium(II) iodide

cadmium(II) iodide

Conditions
ConditionsYield
In acetone Kinetics; react. of Cd with EtI in acetone (EtI:Cd 1:6.7 (moles), EtI:solvent 1:4 (v/v), 300 K);;A 4%
B 96%
In N,N-dimethyl acetamide Kinetics; react. of Cd with EtI in dimethylacetamide (EtI:Cd 1:6.7 (moles), EtI:solvent 1:4 (v/v), 300 K);;A 95%
B 5%
In pyridine Kinetics; react. of Cd with EtI in pyridine (EtI:Cd 1:6.7 (moles), EtI:solvent 1:4 (v/v), 300 K);;A 93%
B 7%
3-aza-N-(2-[1-aza-2-(5-nitro-2-hydroxyphenyl)-vinyl]phenyl)-4-(5-nitro-2-hydroxyphenyl)but-3-enamide
311779-14-3

3-aza-N-(2-[1-aza-2-(5-nitro-2-hydroxyphenyl)-vinyl]phenyl)-4-(5-nitro-2-hydroxyphenyl)but-3-enamide

cadmium
7440-43-9

cadmium

[Cd(II)(3-aza-N-(2-(1-aza-2-(5-nitro-2-oxyphenyl)-vinyl)phenyl)-4-(5-nitro-2-oxyphenyl)but-3-enamide)(H2O)]
874112-40-0

[Cd(II)(3-aza-N-(2-(1-aza-2-(5-nitro-2-oxyphenyl)-vinyl)phenyl)-4-(5-nitro-2-oxyphenyl)but-3-enamide)(H2O)]

Conditions
ConditionsYield
With Me4NClO4 In acetonitrile Electrochem. Process; small amt. of Me4NClO4 added to soln. of ligand in MeCN, electrolyzed (metal anode, Pt cathode) at 9.7-60.4 V for 8340 s; filtered, washed with MeCN and Et2O, dried in vac.; elem anal.;96%
2,6-bis(1-[2-(tosylamino)phenylimino]ethyl)pyridine
660394-39-8

2,6-bis(1-[2-(tosylamino)phenylimino]ethyl)pyridine

cadmium
7440-43-9

cadmium

[Cd(C5H3N(C(CH3)NC6H4NSO2C6H4CH3)2)(H2O)]*H2O

[Cd(C5H3N(C(CH3)NC6H4NSO2C6H4CH3)2)(H2O)]*H2O

Conditions
ConditionsYield
With (CH3)4NClO4; Pt In acetone Electrolysis; suspn. of ligand in warm acetone (contained Me4NClO4 as supporting electrolyte) electrolysed for 2.5 h (10 mA) using metal plate as anode and Ptwire as cathode; solid washed with Et2O, dried in vac., elem. anal.;95%
cesium sulfide

cesium sulfide

sulfur
7704-34-9

sulfur

cadmium
7440-43-9

cadmium

10Cs(1+)*Cd4Sn4S17(10-)=Cs10Cd4Sn4S17

10Cs(1+)*Cd4Sn4S17(10-)=Cs10Cd4Sn4S17

Conditions
ConditionsYield
In neat (no solvent, solid phase) all manipulations under N2 atm.; calcd. amts. of elements and K2S sealedunder vac. in silica tube and heated to 500°C (50°C/h) fo r 4 d, cooled to room temp. (5°C/h); excess flux (K2S) removed with MeOH; elem. anal.;95%
1,10-Phenanthroline
66-71-7

1,10-Phenanthroline

3-phenylacrylic acid hydrazide
3538-69-0

3-phenylacrylic acid hydrazide

cadmium
7440-43-9

cadmium

Cd(C9H9N2O)2*C12H8N2*2H2O = Cd(C9H9N2O)2C12H8N2*2H2O

Cd(C9H9N2O)2*C12H8N2*2H2O = Cd(C9H9N2O)2C12H8N2*2H2O

Conditions
ConditionsYield
With Et4NClO4 In acetone byproducts: H2; Electrolysis; electrolysis (25 V, 3 h); elem. anal.;95%
antimony
7440-36-0

antimony

caesium
7440-46-2

caesium

cadmium
7440-43-9

cadmium

Cs8Cd18Sb28

Cs8Cd18Sb28

Conditions
ConditionsYield
In melt stoich. amounts of Cs, Cd and Sb heated at 550°C for 10 h in welded niobium containers under vac., cooled (5°C/h); elem. anal. (ICP-OES);95%
rubidium sulfide

rubidium sulfide

bismuth(III) sulfide

bismuth(III) sulfide

sulfur
7704-34-9

sulfur

cadmium
7440-43-9

cadmium

Rb1.54Cd1.54Bi2.46S6

Rb1.54Cd1.54Bi2.46S6

Conditions
ConditionsYield
Stage #1: rubidium sulfide; bismuth(III) sulfide; sulfur; cadmium In neat (no solvent) at 300℃; for 7h; Inert atmosphere;
Stage #2: In neat (no solvent) at 800℃; for 24h; Inert atmosphere;
95%
1,4-Butanedithiol
1191-08-8

1,4-Butanedithiol

cadmium
7440-43-9

cadmium

Cd(S2C4H8-1,4)

Cd(S2C4H8-1,4)

Conditions
ConditionsYield
In acetonitrile byproducts: H2; Electrolysis; electrochemical cell with a platinum cathode and a Cd-anode attached to a platinum wire, in presence of Et4NClO4, N2 bubbled slowly through the soln., reaction time: 2.5 h, 20 V; filtered, washed with CH3CN, dried in vac.; elem. anal.;94%

Cadmium Consensus Reports

NTP 10th Report on Carcinogens. IARC Cancer Review: Group 1 IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 58 , 1993,p. 119.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Sufficient Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 2 , 1973,p. 74.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Sufficient Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 11 , 1976,p. 39.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Human Sufficient Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 58 , 1993,p. 119.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Human Limited Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 7 , 1987,p. 139.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Limited Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 58 , 1993,p. 119.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) . Cadmium and its compounds are on the Community Right-To-Know List. Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program.

Cadmium Standards and Recommendations

OSHA PEL: TWA 5 μg(Cd)/m3
ACGIH TLV: TWA 0.01 mg(Cd)/m3 (metal), Suspected Human Carcinogen; TWA 0.002 mg(Cd)/m3 (respirable dust), Suspected Human Carcinogen); BEI: 5 μg/g creatinine in urine; 5 μg/L in blood
DFG MAK: DFG BAT: Blood 1.5 μg/dL; Urine 15 μg/dL. MAK: Animal Carcinogen, Suspected Human Carcinogen
NIOSH REL: (Cadmium) Reduce to lowest feasible level

Cadmium Analytical Methods

For occupational chemical analysis use OSHA: #ID-125 G or NIOSH: Cadmium, 7048; Welding and Brazing Fume, 7200; Elements, 7300.

Cadmium Specification

The Cadmium, with the cas registry number 7440-43-9, is a kind of silvery white metal. It is soluble in hot sulfuric acid, diluted nitric acid and insoluble in water. Being stable chemically. it is incompatible with strong oxidizing agents, nitrates, nitric acid, selenium, zinc. And its product categories are including Metals; Inorganics; Analytical Reagents; Replacement Kit Items; Water Test; Metal and Ceramic Science; Cadmium; Reagent Plus; CadmiumEssential Chemicals; CadmiumMetal and Ceramic Science; Catalysis and Inorganic Chemistry; Chemical Synthesis; Routine Reagents.

The characteristics of this chemical are as follows: (1)#H bond acceptors: 0; (2)#H bond donors: 0; (3)#Freely Rotating Bonds: 0; (4)Polar Surface Area: 0; (5)Exact Mass: 113.903358; (6)MonoIsotopic Mass: 113.903358; (7)Heavy Atom Count: 1; (8)Covalently-Bonded Unit Count: 1.

The production method of this chemical is below: Prepare the metal cadmium as the raw material and then go thought the  process of decompression, distillation and rectification to get this chemical.

As to its usage, it is widely applied in many ways. It could be used in producing cadmium salt, cadmium mercuryvapourlamp, smoke bomb, pigment, alloy, welding flux and metallurgy deoxidizing agent; It could also be used as the semiconductor high-purity material.

When you are using this chemical, you should be very cautious. For one thing, it is irritant which may cause inflammation to the skin or other mucous membranes, and is irritating to eyes and skin. For another thing, for being a kind of toxic chemical which may at very low levels cause damage to health, it will be very dangrous if by inhalation and if swallowed. Besides, it may cause cancer and then has possible risk of irreversible effects. It has the danger of serious damage to health by prolonged exposure. In addition, it will be dangerous for the environment which may present an immediate or delayed danger to one or more components of the environment. Being very toxic to aquatic organisms, it may cause long-term adverse effects in the aquatic environment. Beside all these. it is highly flammable which may catch fire in contact with air, only needing brief contact with an ignition source. And it has a very low flash point or evolve highly flammable gases in contact with water.

Due to so many dangers, you could take different measures to deal with different cases. Avoid exposure - obtain special instructions before use. If in case of contact with eyes, rinse immediately with plenty of water and seek medical advice; If in case of fire use ... (there follows the type of fire-fighting equipment to be used.)
S7:Keep container tightly closed; If in case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) And when store it, keep it in a dry and cool place and this material and its container must be disposed of as hazardous waste. Then remember to avoid releasing to the environment, and you could also refer to special instructions / safety data sheets.

Additionally, you could convert the following datas into the molecular structure:
(1)Canonical SMILES: [Cd]
(2)InChI: InChI=1S/Cd
(3)InChIKey: BDOSMKKIYDKNTQ-UHFFFAOYSA-N 

Below are the toxicity information of this chemical:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
human LCLo inhalation 39mg/m3/20M (39mg/m3) CARDIAC: OTHER CHANGES

VASCULAR: THROMBOSIS DISTANT FROM INJECTION SITE

LUNGS, THORAX, OR RESPIRATION: RESPIRATORY DEPRESSION
American Industrial Hygiene Association Journal. Vol. 31, Pg. 180, 1970.
 
man LDLo unreported 15mg/kg (15mg/kg)   "Poisoning; Toxicology, Symptoms, Treatments," 2nd ed., Arena, J.M., Springfield, IL, C.C. Thomas, 1970Vol. 2, Pg. 73, 1970.
man TCLo inhalation 88ug/m3/8.6Y (0.088mg/m3) KIDNEY, URETER, AND BLADDER: PROTEINURIS Archives of Environmental Health. Vol. 28, Pg. 147, 1974.
mouse LD50 intraperitoneal 5700ug/kg (5.7mg/kg)   Toxicology and Applied Pharmacology. Vol. 37, Pg. 403, 1976.
 
mouse LD50 oral 890mg/kg (890mg/kg)   "Aktual'nye Problemy Gigieny Truda. Current Problems of Labor Hygiene," Tarasenko, N.Y., ed. Moscow, Pervyi Moskovskii Meditsinskii Inst., 1978Vol. -, Pg. 14, 1978.
mouse LD50 unreported 890mg/kg (890mg/kg)   Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 22(5), Pg. 6, 1978.
rabbit LDLo intravenous 5mg/kg (5mg/kg)   Journal of Obstetrics and Gynaecology of the British Empire. Vol. 35, Pg. 693, 1928.
rabbit LDLo oral 70mg/kg (70mg/kg)   Archives des Maladies Professionnelles de Medecine du Travail et de Securite Sociale. Vol. 34, Pg. 127, 1973.
rabbit LDLo subcutaneous 6mg/kg (6mg/kg)   "Problemes de Toxicologie Alimentaire," Truhaut, R., Paris, France, L'evolution Pharmaceutique, 1955Vol. -, Pg. -, 1955.
rat LC50 inhalation 25mg/m3/30M (25mg/m3) LUNGS, THORAX, OR RESPIRATION: DYSPNEA Sangyo Igaku. Japanese Journal of Industrial Health. Vol. 16, Pg. 212, 1974.
rat LD50 oral 2330mg/kg (2330mg/kg)   "Evaluation of the Impact of Cadmium on the Health of Man", Oxford, UK. Pergamon Press Ltd., 1978Vol. -, Pg. 67, 1978.
rat LD50 unreported 1140mg/kg (1140mg/kg)   Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 22(5), Pg. 6, 1978.

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