Product Name

  • Name

    Dodecyl acrylate

  • EINECS 218-463-4
  • CAS No. 2156-97-0
  • Article Data22
  • CAS DataBase
  • Density 0.875 g/cm3
  • Solubility 1μg/L at 20℃
  • Melting Point 4oC
  • Formula C15H28O2
  • Boiling Point 306.2 °C at 760 mmHg
  • Molecular Weight 240.386
  • Flash Point 110.4 °C
  • Transport Information UN 3082 9/PG 3
  • Appearance
  • Safety 26-28-61
  • Risk Codes 36/37/38-51/53
  • Molecular Structure Molecular Structure of 2156-97-0 (Dodecyl acrylate)
  • Hazard Symbols IrritantXi, DangerousN
  • Synonyms Acrylicacid, dodecyl ester (6CI,7CI,8CI);Ageflex FA 12;Blemmer LA;KU-LA;LA;Lauryl acrylate;Light Acrylate L-A;NK Ester LA;NSC 24177;Photomer 4812;SR 335;SR 498D;Sartomer 335;Viscoat LA;n-Dodecyl acrylate;
  • PSA 26.30000
  • LogP 4.63650

Synthetic route

1-dodecyl alcohol
112-53-8

1-dodecyl alcohol

acrylic acid
79-10-7

acrylic acid

lauryl acrylate
2156-97-0

lauryl acrylate

Conditions
ConditionsYield
With 10H-phenothiazine; hydroquinone at 110 - 130℃; for 4h;95.8%
With toluene-4-sulfonic acid; hydroquinone In toluene at 130℃; for 3h; Inert atmosphere;85%
With toluene-4-sulfonic acid; hydroquinone In toluene at 130℃; for 4h; Inert atmosphere;76%
With phosphoric acid; (p-tolueneslfonic acid, sulfosalicylic acid, resin KU-2x8); hydroquinone In toluene Heating;
With hydroquinone In cyclohexane at 120 - 140℃; for 6h;
1-dodecyl alcohol
112-53-8

1-dodecyl alcohol

acryloyl chloride
814-68-6

acryloyl chloride

lauryl acrylate
2156-97-0

lauryl acrylate

Conditions
ConditionsYield
With triethylamine In tetrahydrofuran at 10 - 20℃; for 3h;84%
With triethylamine In dichloromethane at 0℃; for 3h;65%
With triethylamine In dichloromethane at 20℃;
In dichloromethane at 0 - 20℃; Inert atmosphere; Alkaline conditions;
1-dodecyl alcohol
112-53-8

1-dodecyl alcohol

acryloyl-1,3-oxazolidin-2-one
2043-21-2

acryloyl-1,3-oxazolidin-2-one

lauryl acrylate
2156-97-0

lauryl acrylate

Conditions
ConditionsYield
With ytterbium(III) triflate In acetonitrile at 90℃; for 48h; Sealed tube; Inert atmosphere;70%
Acrylic acid 12-iodo-dodecyl ester
109182-98-1

Acrylic acid 12-iodo-dodecyl ester

A

pentadecanolide
106-02-5

pentadecanolide

B

lauryl acrylate
2156-97-0

lauryl acrylate

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile); tertbutyltin hydride In benzene for 3h; Heating;A 55%
B 21%
1-dodecyl alcohol
112-53-8

1-dodecyl alcohol

acrylic acid
79-10-7

acrylic acid

A

lauryl acrylate
2156-97-0

lauryl acrylate

B

3-(dodecyloxy)-3-oxopropyl acrylate

3-(dodecyloxy)-3-oxopropyl acrylate

Conditions
ConditionsYield
With sodium hydrogen sulfate at 110℃; for 2h;A 36%
B 40.5%
1-dodecyl alcohol
112-53-8

1-dodecyl alcohol

acrylic acid methyl ester
292638-85-8

acrylic acid methyl ester

lauryl acrylate
2156-97-0

lauryl acrylate

Conditions
ConditionsYield
With toluene-4-sulfonic acid; hydroquinone Abdestillieren des entstandenen Methanols als Azeotrop mit Methylacrylat;
at 60 - 70℃;
1-dodecyl alcohol
112-53-8

1-dodecyl alcohol

acetylene
74-86-2

acetylene

lauryl acrylate
2156-97-0

lauryl acrylate

Conditions
ConditionsYield
With hydrogenchloride; tetracarbonyl nickel
1-dodecyl alcohol
112-53-8

1-dodecyl alcohol

acetylene
74-86-2

acetylene

carbon monoxide

carbon monoxide

lauryl acrylate
2156-97-0

lauryl acrylate

Conditions
ConditionsYield
With tetrahydrofuran; copper(ll) bromide; nickel dibromide at 200℃; under 40 - 50 Torr;
With hydrogenchloride; tetracarbonyl nickel
diethyl ether dicarboxylic acid-(2.2')-didodecyl ester

diethyl ether dicarboxylic acid-(2.2')-didodecyl ester

lauryl acrylate
2156-97-0

lauryl acrylate

Conditions
ConditionsYield
With sulfuric acid; β-naphthol at 288 - 310℃; under 21 Torr;
1,12-dodecandiol
5675-51-4

1,12-dodecandiol

lauryl acrylate
2156-97-0

lauryl acrylate

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: 38 percent / carbon tetrabromide, triphenylphosphine / tetrahydrofuran / 20 h / Ambient temperature
2: 2.3 g / triethylamine / CH2Cl2 / Ambient temperature
3: 2.7 g / sodium iodide / butan-2-one / 3 h / Heating
4: 21 percent / tertbutyltin hydride, AIBN / benzene / 3 h / Heating
View Scheme
12-bromododecanol
3344-77-2

12-bromododecanol

lauryl acrylate
2156-97-0

lauryl acrylate

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 2.3 g / triethylamine / CH2Cl2 / Ambient temperature
2: 2.7 g / sodium iodide / butan-2-one / 3 h / Heating
3: 21 percent / tertbutyltin hydride, AIBN / benzene / 3 h / Heating
View Scheme
12-bromododecanyl acrylate
112231-59-1

12-bromododecanyl acrylate

lauryl acrylate
2156-97-0

lauryl acrylate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 2.7 g / sodium iodide / butan-2-one / 3 h / Heating
2: 21 percent / tertbutyltin hydride, AIBN / benzene / 3 h / Heating
View Scheme
lauryl acrylate
2156-97-0

lauryl acrylate

2,2'-iminobis[ethanol]
111-42-2

2,2'-iminobis[ethanol]

3-[bis-(2-hydroxy-ethyl)-amino]-propionic acid dodecyl ester

3-[bis-(2-hydroxy-ethyl)-amino]-propionic acid dodecyl ester

Conditions
ConditionsYield
at 50℃; Michael addition;100%
Octanethiol
111-88-6

Octanethiol

lauryl acrylate
2156-97-0

lauryl acrylate

dodecyl 3-(octylthio)propanoate

dodecyl 3-(octylthio)propanoate

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile) at 115℃; for 24h; Sealed tube;99%
pyridine-4-carbaldehyde
872-85-5

pyridine-4-carbaldehyde

lauryl acrylate
2156-97-0

lauryl acrylate

C21H33NO3

C21H33NO3

Conditions
ConditionsYield
With 1,4-diaza-bicyclo[2.2.2]octane In toluene at 20℃; for 8h;95%
lauryl acrylate
2156-97-0

lauryl acrylate

dimethyl 3-phenylcyclohexa-1,4-diene-1,2-dicarboxylate
192884-89-2, 1013643-92-9

dimethyl 3-phenylcyclohexa-1,4-diene-1,2-dicarboxylate

A

1-dodecyl propionate
6221-93-8

1-dodecyl propionate

B

biphenyl-2,3-dicarboxylic acid dimethyl ester
50402-81-8

biphenyl-2,3-dicarboxylic acid dimethyl ester

Conditions
ConditionsYield
With palladium 10% on activated carbon In water at 120℃; for 6h;A 0.077 mmol
B 95%
lauryl acrylate
2156-97-0

lauryl acrylate

1-deoxy-1-(methylamino)-D-glucitol
6284-40-8

1-deoxy-1-(methylamino)-D-glucitol

C22H45NO7

C22H45NO7

Conditions
ConditionsYield
In 1,4-dioxane; water at 50℃; for 5h;91%
pyridine-2-carbaldehyde
1121-60-4

pyridine-2-carbaldehyde

lauryl acrylate
2156-97-0

lauryl acrylate

C21H33NO3

C21H33NO3

Conditions
ConditionsYield
With 1,4-diaza-bicyclo[2.2.2]octane In toluene at 20℃; for 8h;90%
lauryl acrylate
2156-97-0

lauryl acrylate

rac-Pro-OH
609-36-9

rac-Pro-OH

C20H37NO4

C20H37NO4

Conditions
ConditionsYield
In ethanol at 75℃; for 8h; Michael Addition;88%
lauryl acrylate
2156-97-0

lauryl acrylate

5-Iodo-2'-deoxyuridine
54-42-2

5-Iodo-2'-deoxyuridine

dodecyl (E)-3-(1-((2R,4S,5R)-4-hydroxy-5-(hydroxymethyl)-tetrahydrofuran-2-yl)-2,4-dioxo-1,2,3,4-tetrahydropyrimidin-5-yl)acrylate

dodecyl (E)-3-(1-((2R,4S,5R)-4-hydroxy-5-(hydroxymethyl)-tetrahydrofuran-2-yl)-2,4-dioxo-1,2,3,4-tetrahydropyrimidin-5-yl)acrylate

Conditions
ConditionsYield
Stage #1: 5-Iodo-2'-deoxyuridine With C26H32N8O6P2PdS2 In acetonitrile at 80℃; for 0.0833333h; Heck Reaction; Inert atmosphere;
Stage #2: lauryl acrylate With triethylamine In acetonitrile at 80℃; for 8h; Heck Reaction; Inert atmosphere;
86%
lauryl acrylate
2156-97-0

lauryl acrylate

[2,2']bipyridinyl-4,4'-dicarbaldehyde
99970-84-0

[2,2']bipyridinyl-4,4'-dicarbaldehyde

C42H64N2O6

C42H64N2O6

Conditions
ConditionsYield
With 1,4-diaza-bicyclo[2.2.2]octane In methanol at 20℃; for 12h; Reagent/catalyst; Morita-Baylis-Hillman Alkylation;84%
lauryl acrylate
2156-97-0

lauryl acrylate

N-(3-methoxyphenyl)-2-methylpropanamide
71182-37-1

N-(3-methoxyphenyl)-2-methylpropanamide

C26H41NO4
1222482-64-5

C26H41NO4

Conditions
ConditionsYield
With tetrakis(acetonitrile)palladium(II) tetrafluoroborate; silver nitrate; p-benzoquinone In water at 20℃; for 20h; Fujiwara-Moritani reaction; regiospecific reaction;80%
3-pyridinecarboxaldehyde
500-22-1

3-pyridinecarboxaldehyde

lauryl acrylate
2156-97-0

lauryl acrylate

dodecyl 2-(hydroxy(pyridine-3-yl)methyl)acrylate

dodecyl 2-(hydroxy(pyridine-3-yl)methyl)acrylate

Conditions
ConditionsYield
With 1,4-diaza-bicyclo[2.2.2]octane In toluene at 20℃; for 8h;78%
With 1,4-diaza-bicyclo[2.2.2]octane In octanol at 20℃; for 22h; Baylis-Hillman Reaction;71%
lauryl acrylate
2156-97-0

lauryl acrylate

4'-methyl-2,2'-bipyridine-4-carboxylaldehyde
104704-09-8

4'-methyl-2,2'-bipyridine-4-carboxylaldehyde

C27H38N2O3

C27H38N2O3

Conditions
ConditionsYield
With 1,4-diaza-bicyclo[2.2.2]octane In methanol at 20℃; for 12.4h; Morita-Baylis-Hillman Alkylation;78%
iodobenzene
591-50-4

iodobenzene

lauryl acrylate
2156-97-0

lauryl acrylate

trans-dodecyl-3-phenylprop-2-enoate
146354-36-1

trans-dodecyl-3-phenylprop-2-enoate

Conditions
ConditionsYield
With triethylamine In N,N-dimethyl acetamide at 90℃; for 9h;77%
With triethylamine In dimethyl sulfoxide at 90℃; for 9h; Reagent/catalyst;
lauryl acrylate
2156-97-0

lauryl acrylate

N,8-dimethylindolizine-2-carboxamide

N,8-dimethylindolizine-2-carboxamide

dodecyl (E)-3-(8-methyl-2-(methylcarbamoyl)indolizin-3-yl)acrylate

dodecyl (E)-3-(8-methyl-2-(methylcarbamoyl)indolizin-3-yl)acrylate

Conditions
ConditionsYield
With silver hexafluoroantimonate; [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; copper(II) acetate monohydrate In tetrahydrofuran at 20℃; Inert atmosphere; regioselective reaction;76%
tert-Butylacetic acid
1070-83-3

tert-Butylacetic acid

lauryl acrylate
2156-97-0

lauryl acrylate

C19H34O4

C19H34O4

Conditions
ConditionsYield
With disodium hydrogenphosphate; palladium(II) trifluoroacetate; N-acetyl-L-valine; silver carbonate at 120℃; for 12h;76%
1-methyl-1H-indole-2,3-dione
2058-74-4

1-methyl-1H-indole-2,3-dione

lauryl acrylate
2156-97-0

lauryl acrylate

C24H35NO4

C24H35NO4

Conditions
ConditionsYield
With 1,4-diaza-bicyclo[2.2.2]octane In toluene at 20℃; for 8h;72%
lauryl acrylate
2156-97-0

lauryl acrylate

di-tert-butyl ((butane-1,4-diylbis(azanediyl))bis(propane-3,1-diyl))dicarbamate
140652-55-7

di-tert-butyl ((butane-1,4-diylbis(azanediyl))bis(propane-3,1-diyl))dicarbamate

C50H98N4O8

C50H98N4O8

Conditions
ConditionsYield
In isopropyl alcohol at 90℃; for 2h;72%
lauryl acrylate
2156-97-0

lauryl acrylate

dodecyl acrylate-d3

dodecyl acrylate-d3

Conditions
ConditionsYield
With platinum on carbon; water-d2; hydroquinone; isopropyl alcohol at 120℃; for 24h; Reagent/catalyst; Time; Sealed tube; Inert atmosphere;71%
lauryl acrylate
2156-97-0

lauryl acrylate

N-(3-isopropoxyphenyl)acetamide
256425-12-4

N-(3-isopropoxyphenyl)acetamide

C26H41NO4
1222482-60-1

C26H41NO4

Conditions
ConditionsYield
With tetrakis(acetonitrile)palladium(II) tetrafluoroborate; silver nitrate; p-benzoquinone In water at 20℃; for 20h; Fujiwara-Moritani reaction; regiospecific reaction;70%
Indole-3-carboxaldehyde
487-89-8

Indole-3-carboxaldehyde

lauryl acrylate
2156-97-0

lauryl acrylate

(E)-dodecyl 3-(3-formyl-1H-indol-4-yl)acrylate

(E)-dodecyl 3-(3-formyl-1H-indol-4-yl)acrylate

Conditions
ConditionsYield
With silver hexafluoroantimonate; dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; copper diacetate at 110℃; for 4h; Inert atmosphere; regioselective reaction;64%
lauryl acrylate
2156-97-0

lauryl acrylate

1,4-diaminobutane
110-60-1

1,4-diaminobutane

dilauryl spermate

dilauryl spermate

Conditions
ConditionsYield
In tetrahydrofuran for 36h; Ambient temperature;58%
1-octyloxy-2,2,6,6-tetramethylpiperidin-4-one oxime

1-octyloxy-2,2,6,6-tetramethylpiperidin-4-one oxime

lauryl acrylate
2156-97-0

lauryl acrylate

lauryl 3-[N-(1-octyloxy-2,2,6,6-tetramethylpiperidin-4-yl)-N-hydroxyamino]propionate

lauryl 3-[N-(1-octyloxy-2,2,6,6-tetramethylpiperidin-4-yl)-N-hydroxyamino]propionate

Conditions
ConditionsYield
With hydrogenchloride; platinum In methanol52%
lauryl acrylate
2156-97-0

lauryl acrylate

C17H27NO5

C17H27NO5

10-(5'-(dodecyloxycarbonyl)-4',5'-dihydroisoxazol-3'-yl)methyldeoxoartemisinin

10-(5'-(dodecyloxycarbonyl)-4',5'-dihydroisoxazol-3'-yl)methyldeoxoartemisinin

Conditions
ConditionsYield
With sodium hypochlorite; triethylamine In dichloromethane at 20℃;46%
furan-3-carboxaldehyde
498-60-2

furan-3-carboxaldehyde

lauryl acrylate
2156-97-0

lauryl acrylate

dodecyl 2-(furan-3-yl(hydroxy)methyl)acrylate

dodecyl 2-(furan-3-yl(hydroxy)methyl)acrylate

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene at 20℃; for 48h; Baylis-Hillman reaction;40%
furfural
98-01-1

furfural

lauryl acrylate
2156-97-0

lauryl acrylate

dodecyl 2-[(furan-2-yl)(hydroxy)methyl]acrylate
1092799-80-8

dodecyl 2-[(furan-2-yl)(hydroxy)methyl]acrylate

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene at 0 - 25℃; Baylis-Hillman reaction;36%

Dodecyl acrylate Chemical Properties

Molecular structure of 2-Propenoic acid, dodecyl ester (CAS NO.2156-97-0) is:

Product Name: 2-Propenoic acid, dodecyl ester
CAS Registry Number: 2156-97-0
IUPAC Name: Dodecyl prop-2-enoate
Molecular Weight: 240.38162 [g/mol]
Molecular Formula: C15H28O2
XLogP3: 6.2
H-Bond Donor: 0
H-Bond Acceptor: 2 
EINECS: 218-463-4
Refractive index: 1.445
Surface Tension: 29.9 dyne/cm
Density: 0.875 g/cm3
Flash Point: 110.4 °C
Enthalpy of Vaporization: 54.67 kJ/mol
Boiling Point: 306.2 °C at 760 mmHg
Vapour Pressure: 0.000784 mmHg at 25°C
Other Registry Number: 199685-42-2
Product Categories: Functional Monomer; Monomer

Dodecyl acrylate Safety Profile

Safty information about 2-Propenoic acid, dodecyl ester (CAS NO.2156-97-0) is:
Hazard Codes: IrritantXi; DangerousN
Risk Statements: 36/37/38-51/53
Safety Statements: 26-28-61 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S28:After contact with skin, wash immediately with plenty of soap-suds. 
S51/53:Use only in well ventilated areas and avoid exposure - obtain special instructions before use.
RIDADR: UN 3082 9/PG 3
WGK Germany: 2

Dodecyl acrylate Specification

 2-Propenoic acid, dodecyl ester , its cas register number is 2156-97-0. It also can be called AI3-03198 ; Acrylic acid, dodecyl ester ; Dodecyl acrylate ; Lauryl acrylate ; NSC 24177 ; n-Dodecyl acrylate ; n-Lauryl acrylate .

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