Conditions | Yield |
---|---|
With 10H-phenothiazine; hydroquinone at 110 - 130℃; for 4h; | 95.8% |
With toluene-4-sulfonic acid; hydroquinone In toluene at 130℃; for 3h; Inert atmosphere; | 85% |
With toluene-4-sulfonic acid; hydroquinone In toluene at 130℃; for 4h; Inert atmosphere; | 76% |
With phosphoric acid; (p-tolueneslfonic acid, sulfosalicylic acid, resin KU-2x8); hydroquinone In toluene Heating; | |
With hydroquinone In cyclohexane at 120 - 140℃; for 6h; |
Conditions | Yield |
---|---|
With triethylamine In tetrahydrofuran at 10 - 20℃; for 3h; | 84% |
With triethylamine In dichloromethane at 0℃; for 3h; | 65% |
With triethylamine In dichloromethane at 20℃; | |
In dichloromethane at 0 - 20℃; Inert atmosphere; Alkaline conditions; |
Conditions | Yield |
---|---|
With ytterbium(III) triflate In acetonitrile at 90℃; for 48h; Sealed tube; Inert atmosphere; | 70% |
Acrylic acid 12-iodo-dodecyl ester
A
pentadecanolide
B
lauryl acrylate
Conditions | Yield |
---|---|
With 2,2'-azobis(isobutyronitrile); tertbutyltin hydride In benzene for 3h; Heating; | A 55% B 21% |
Conditions | Yield |
---|---|
With sodium hydrogen sulfate at 110℃; for 2h; | A 36% B 40.5% |
Conditions | Yield |
---|---|
With toluene-4-sulfonic acid; hydroquinone Abdestillieren des entstandenen Methanols als Azeotrop mit Methylacrylat; | |
at 60 - 70℃; |
Conditions | Yield |
---|---|
With hydrogenchloride; tetracarbonyl nickel |
Conditions | Yield |
---|---|
With tetrahydrofuran; copper(ll) bromide; nickel dibromide at 200℃; under 40 - 50 Torr; | |
With hydrogenchloride; tetracarbonyl nickel |
lauryl acrylate
Conditions | Yield |
---|---|
With sulfuric acid; β-naphthol at 288 - 310℃; under 21 Torr; |
Conditions | Yield |
---|---|
Multi-step reaction with 4 steps 1: 38 percent / carbon tetrabromide, triphenylphosphine / tetrahydrofuran / 20 h / Ambient temperature 2: 2.3 g / triethylamine / CH2Cl2 / Ambient temperature 3: 2.7 g / sodium iodide / butan-2-one / 3 h / Heating 4: 21 percent / tertbutyltin hydride, AIBN / benzene / 3 h / Heating View Scheme |
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: 2.3 g / triethylamine / CH2Cl2 / Ambient temperature 2: 2.7 g / sodium iodide / butan-2-one / 3 h / Heating 3: 21 percent / tertbutyltin hydride, AIBN / benzene / 3 h / Heating View Scheme |
12-bromododecanyl acrylate
lauryl acrylate
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 2.7 g / sodium iodide / butan-2-one / 3 h / Heating 2: 21 percent / tertbutyltin hydride, AIBN / benzene / 3 h / Heating View Scheme |
Conditions | Yield |
---|---|
at 50℃; Michael addition; | 100% |
Conditions | Yield |
---|---|
With 2,2'-azobis(isobutyronitrile) at 115℃; for 24h; Sealed tube; | 99% |
Conditions | Yield |
---|---|
With 1,4-diaza-bicyclo[2.2.2]octane In toluene at 20℃; for 8h; | 95% |
lauryl acrylate
dimethyl 3-phenylcyclohexa-1,4-diene-1,2-dicarboxylate
A
1-dodecyl propionate
B
biphenyl-2,3-dicarboxylic acid dimethyl ester
Conditions | Yield |
---|---|
With palladium 10% on activated carbon In water at 120℃; for 6h; | A 0.077 mmol B 95% |
Conditions | Yield |
---|---|
In 1,4-dioxane; water at 50℃; for 5h; | 91% |
Conditions | Yield |
---|---|
With 1,4-diaza-bicyclo[2.2.2]octane In toluene at 20℃; for 8h; | 90% |
Conditions | Yield |
---|---|
In ethanol at 75℃; for 8h; Michael Addition; | 88% |
Conditions | Yield |
---|---|
Stage #1: 5-Iodo-2'-deoxyuridine With C26H32N8O6P2PdS2 In acetonitrile at 80℃; for 0.0833333h; Heck Reaction; Inert atmosphere; Stage #2: lauryl acrylate With triethylamine In acetonitrile at 80℃; for 8h; Heck Reaction; Inert atmosphere; | 86% |
Conditions | Yield |
---|---|
With 1,4-diaza-bicyclo[2.2.2]octane In methanol at 20℃; for 12h; Reagent/catalyst; Morita-Baylis-Hillman Alkylation; | 84% |
Conditions | Yield |
---|---|
With tetrakis(acetonitrile)palladium(II) tetrafluoroborate; silver nitrate; p-benzoquinone In water at 20℃; for 20h; Fujiwara-Moritani reaction; regiospecific reaction; | 80% |
Conditions | Yield |
---|---|
With 1,4-diaza-bicyclo[2.2.2]octane In toluene at 20℃; for 8h; | 78% |
With 1,4-diaza-bicyclo[2.2.2]octane In octanol at 20℃; for 22h; Baylis-Hillman Reaction; | 71% |
Conditions | Yield |
---|---|
With 1,4-diaza-bicyclo[2.2.2]octane In methanol at 20℃; for 12.4h; Morita-Baylis-Hillman Alkylation; | 78% |
Conditions | Yield |
---|---|
With triethylamine In N,N-dimethyl acetamide at 90℃; for 9h; | 77% |
With triethylamine In dimethyl sulfoxide at 90℃; for 9h; Reagent/catalyst; |
lauryl acrylate
Conditions | Yield |
---|---|
With silver hexafluoroantimonate; [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; copper(II) acetate monohydrate In tetrahydrofuran at 20℃; Inert atmosphere; regioselective reaction; | 76% |
Conditions | Yield |
---|---|
With disodium hydrogenphosphate; palladium(II) trifluoroacetate; N-acetyl-L-valine; silver carbonate at 120℃; for 12h; | 76% |
Conditions | Yield |
---|---|
With 1,4-diaza-bicyclo[2.2.2]octane In toluene at 20℃; for 8h; | 72% |
lauryl acrylate
di-tert-butyl ((butane-1,4-diylbis(azanediyl))bis(propane-3,1-diyl))dicarbamate
Conditions | Yield |
---|---|
In isopropyl alcohol at 90℃; for 2h; | 72% |
lauryl acrylate
Conditions | Yield |
---|---|
With platinum on carbon; water-d2; hydroquinone; isopropyl alcohol at 120℃; for 24h; Reagent/catalyst; Time; Sealed tube; Inert atmosphere; | 71% |
Conditions | Yield |
---|---|
With tetrakis(acetonitrile)palladium(II) tetrafluoroborate; silver nitrate; p-benzoquinone In water at 20℃; for 20h; Fujiwara-Moritani reaction; regiospecific reaction; | 70% |
Conditions | Yield |
---|---|
With silver hexafluoroantimonate; dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; copper diacetate at 110℃; for 4h; Inert atmosphere; regioselective reaction; | 64% |
Conditions | Yield |
---|---|
In tetrahydrofuran for 36h; Ambient temperature; | 58% |
lauryl acrylate
Conditions | Yield |
---|---|
With hydrogenchloride; platinum In methanol | 52% |
lauryl acrylate
Conditions | Yield |
---|---|
With sodium hypochlorite; triethylamine In dichloromethane at 20℃; | 46% |
Conditions | Yield |
---|---|
With 1,8-diazabicyclo[5.4.0]undec-7-ene at 20℃; for 48h; Baylis-Hillman reaction; | 40% |
furfural
lauryl acrylate
dodecyl 2-[(furan-2-yl)(hydroxy)methyl]acrylate
Conditions | Yield |
---|---|
With 1,8-diazabicyclo[5.4.0]undec-7-ene at 0 - 25℃; Baylis-Hillman reaction; | 36% |
Molecular structure of 2-Propenoic acid, dodecyl ester (CAS NO.2156-97-0) is:
Product Name: 2-Propenoic acid, dodecyl ester
CAS Registry Number: 2156-97-0
IUPAC Name: Dodecyl prop-2-enoate
Molecular Weight: 240.38162 [g/mol]
Molecular Formula: C15H28O2
XLogP3: 6.2
H-Bond Donor: 0
H-Bond Acceptor: 2
EINECS: 218-463-4
Refractive index: 1.445
Surface Tension: 29.9 dyne/cm
Density: 0.875 g/cm3
Flash Point: 110.4 °C
Enthalpy of Vaporization: 54.67 kJ/mol
Boiling Point: 306.2 °C at 760 mmHg
Vapour Pressure: 0.000784 mmHg at 25°C
Other Registry Number: 199685-42-2
Product Categories: Functional Monomer; Monomer
Safty information about 2-Propenoic acid, dodecyl ester (CAS NO.2156-97-0) is:
Hazard Codes: Xi; N
Risk Statements: 36/37/38-51/53
Safety Statements: 26-28-61
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S28:After contact with skin, wash immediately with plenty of soap-suds.
S51/53:Use only in well ventilated areas and avoid exposure - obtain special instructions before use.
RIDADR: UN 3082 9/PG 3
WGK Germany: 2
2-Propenoic acid, dodecyl ester , its cas register number is 2156-97-0. It also can be called AI3-03198 ; Acrylic acid, dodecyl ester ; Dodecyl acrylate ; Lauryl acrylate ; NSC 24177 ; n-Dodecyl acrylate ; n-Lauryl acrylate .
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