Product Name

  • Name

    Sodium chlorite

  • EINECS 231-836-6
  • CAS No. 7758-19-2
  • Article Data115
  • CAS DataBase
  • Density 1.28 g/cm3 (20oC)
  • Solubility 39 g/100 mL (17 °C) in water
  • Melting Point 190 °C (dec.)
  • Formula NaClO2
  • Boiling Point 112oC
  • Molecular Weight 90.4416
  • Flash Point
  • Transport Information UN 2813 4.3/PG 3
  • Appearance white flakes
  • Safety 17-26-36/37/39-45-50A-38-36
  • Risk Codes 8-22-24-32-34-9-26-25-14-36/37/38-21
  • Molecular Structure Molecular Structure of 7758-19-2 (Sodium chlorite)
  • Hazard Symbols OxidizingO, HarmfulXn, ToxicT, VeryT+
  • Synonyms Sodium chlorite (water disinfection byproducts);Chlorous acid,sodium salt;Textone;Alcide LD;Neo Silox D;Chlorite sodium;EPA Pesticide Chemical Code 020502;Textile;Sodium chlorite [UN1496] [Oxidizer];Chlorous acid, sodium salt;Sodium chlorite 7758-19-2;
  • PSA 40.13000
  • LogP 0.45190

Synthetic route

chlorine dioxide
10049-04-4, 25052-55-5

chlorine dioxide

sodium hydroxide
1310-73-2

sodium hydroxide

sodium chlorite
7758-19-2

sodium chlorite

Conditions
ConditionsYield
With barium dihydroxide; sodium iodide In water byproducts: Ba(IO3)2; introduction of ClO2 in a soln. of 500g NaOH and 275g NaI at 80°C, addn. of Ba(OH)2, pptn. of Ba(IO3)2, filtration;; regeneration of NaI and Ba(OH)2 from Ba(IO3)2;;98%
With NaI; Ba(OH)2 In water byproducts: Ba(IO3)2; introduction of ClO2 in a soln. of 500g NaOH and 275g NaI at 80°C, addn. of Ba(OH)2, pptn. of Ba(IO3)2, filtration;; regeneration of NaI and Ba(OH)2 from Ba(IO3)2;;98%
With sodium perborate In water byproducts: O2, Na2B4O7*10H2O; at 15-35°C in presence of borax;;96%
Hg(b),Na(0-0.1) (X%)

Hg(b),Na(0-0.1) (X%)

chlorine dioxide
10049-04-4, 25052-55-5

chlorine dioxide

sodium chlorite
7758-19-2

sodium chlorite

Conditions
ConditionsYield
In water 20°C, pH=8.2-9.2, several cycles; mechanism discussed;; 0.6-0.8mol NaClO2/l;;80%
chlorine dioxide
10049-04-4, 25052-55-5

chlorine dioxide

iodide
14362-44-8

iodide

A

sodium chlorite
7758-19-2

sodium chlorite

B

iodine
7553-56-2

iodine

Conditions
ConditionsYield
In water Kinetics; react. of ClO2 and I(1-), react. temp. 25°C, pH 2 and 5; monitored by stopped-flow techniques or spectrophotometrically;
sodium chloride
7647-14-5

sodium chloride

A

sodium chlorate

sodium chlorate

B

sodium hypochlorite
7681-52-9

sodium hypochlorite

C

sodium chlorite
7758-19-2

sodium chlorite

D

sodium perchlorate

sodium perchlorate

Conditions
ConditionsYield
In water Electrolysis;
sodium perborate

sodium perborate

potassium iodide
7681-11-0

potassium iodide

sodium chlorite
7758-19-2

sodium chlorite

Conditions
ConditionsYield
In water 15-35°C;;
chlorine dioxide
10049-04-4, 25052-55-5

chlorine dioxide

sodium chlorite
7758-19-2

sodium chlorite

Conditions
ConditionsYield
With Na-amalgame In water Electrolysis; reduction of ClO2 by hydrogen (introduction of ClO2 through a graphite-electrode into H2O, generation of HClO2), react. of generated HClO2 with Na-amalgame-electrode;;
With sodium hydroxide; dihydrogen peroxide In water byproducts: H2O, O2;
With sodium amalgam In water Na-amalgam: cathode of NaCl-electrolysis, mechanism discussed;;
chlorine dioxide
10049-04-4, 25052-55-5

chlorine dioxide

sodium chloride
7647-14-5

sodium chloride

sodium chlorite
7758-19-2

sodium chlorite

Conditions
ConditionsYield
In water Electrolysis; reduction of ClO2 by hydrogen (introduction of ClO2 through a graphite-electrode into aq. NaCl, generation of HClO2), react. of generated HClO2 with NaCl;;
In water Electrolysis; apparatus described;;
chlorine dioxide
10049-04-4, 25052-55-5

chlorine dioxide

sodium oxalate
62-76-0

sodium oxalate

calcium hydroxide

calcium hydroxide

sodium chlorite
7758-19-2

sodium chlorite

Conditions
ConditionsYield
With pyrographite In water byproducts: CaCO3; preparation of a Ca(ClO2)2-soln. by react. of a ClO2/air-mixture (5% ClO2) with Ca(OH)2 and C in H2O, filtration, react. with Na2C2O4;;
chlorine dioxide
10049-04-4, 25052-55-5

chlorine dioxide

sodium hydroxide
1310-73-2

sodium hydroxide

A

sodium chlorate

sodium chlorate

B

sodium chlorite
7758-19-2

sodium chlorite

C

sodium chloride
7647-14-5

sodium chloride

D

zinc(II) hydroxide

zinc(II) hydroxide

Conditions
ConditionsYield
In not given with excess of Zn powder (20-30%), with equiv. amt. of NaOH, filtrating of Zn(OH)2, evapn.; ca. 85 mol-% NaClO2;
In not given with excess of Zn powder (20-30%), with equiv. amt. of NaOH, filtrating of Zn(OH)2, evapn.; ca. 85 mol-% NaClO2;
chlorine dioxide
10049-04-4, 25052-55-5

chlorine dioxide

sodium hydroxide
1310-73-2

sodium hydroxide

A

sodium chlorate

sodium chlorate

B

sodium chlorite
7758-19-2

sodium chlorite

C

water
7732-18-5

water

Conditions
ConditionsYield
In water part of cyclic process;;
chlorine dioxide
10049-04-4, 25052-55-5

chlorine dioxide

sodium hydroxide
1310-73-2

sodium hydroxide

A

sodium chlorite
7758-19-2

sodium chlorite

B

sodium chlorite trihydrate

sodium chlorite trihydrate

Conditions
ConditionsYield
With dihydrogen peroxide In not given byproducts: H2O, O2; evapn. in vacuum; by dissolving in ethanol, pptg. with benzene, made NaCl and NaClO3 free, drying in vacuum;
With dihydrogen peroxide In not given byproducts: H2O, O2; evapn. in vacuum; made NaCl free by recrystn. from water;
With H2O2 In not given byproducts: H2O, O2; evapn. in vacuum; recrystn. from water, the product contains NaCl, NaClO3;
With H2O2 In not given byproducts: H2O, O2; evapn. in vacuum; by dissolving in ethanol, pptg. with benzene, made NaCl and NaClO3 free, drying in vacuum;
With H2O2 In not given byproducts: H2O, O2; evapn. in vacuum; made NaCl free by recrystn. from water;
chlorine dioxide
10049-04-4, 25052-55-5

chlorine dioxide

sodium hydroxide
1310-73-2

sodium hydroxide

A

sodium chlorate

sodium chlorate

B

sodium chlorite
7758-19-2

sodium chlorite

Conditions
ConditionsYield
In water byproducts: H2O; separation of NaClO2 and NaClO3 by fractionated crystn.: introduction of ClO2 at 30°C, pptn. of NaClO3, addn. of H2O to the filtrate until no more NaClO3 (at 5°C) is pptd., pptn. of NaClO2*3H2O at 5°C;; dehydration by melting at 38-45°C, separation of NaClO2;;
In water byproducts: H2O; reaction of ClO2 with an aq. NaOH-soln.; end of slow reaction is detected by discoloration;; product mixture obtained;;
In water byproducts: H2O; reaction of ClO2 with an aq. NaOH-soln.;; product mixture obtained;;
Hg(b),Na(0.01) (X%)

Hg(b),Na(0.01) (X%)

chlorine dioxide
10049-04-4, 25052-55-5

chlorine dioxide

sodium chlorite
7758-19-2

sodium chlorite

Conditions
ConditionsYield
In water react. of Na-amalgam with a 20% NaClO2-soln. containing 3.5g ClO2/l in a vertical tube at ambient temp.; regulation of react. described; mechanism discussed;;97-98
Hg(b),Na(0.25) (X%)

Hg(b),Na(0.25) (X%)

chlorine dioxide
10049-04-4, 25052-55-5

chlorine dioxide

sodium chlorite
7758-19-2

sodium chlorite

Conditions
ConditionsYield
In water byproducts: NaCl, NaClO3, NaOH; react. in presence of NaI, <30°C: introduction of 262g ClO2 in 1l soln. containing 30g NaI, react. with 41kg Na-amalgame; mechanism discussed;; soln. containing 317g NaClO2, 14.3g NaCl, 5.7g NaClO3 and 4.6g NaOH;;
sodium perborate

sodium perborate

chlorine dioxide
10049-04-4, 25052-55-5

chlorine dioxide

sodium chlorite
7758-19-2

sodium chlorite

Conditions
ConditionsYield
In water 15-35°C;;
chlorine dioxide
10049-04-4, 25052-55-5

chlorine dioxide

sodium carbonate
497-19-8

sodium carbonate

calcium hydroxide

calcium hydroxide

sodium chlorite
7758-19-2

sodium chlorite

Conditions
ConditionsYield
With pyrographite In water byproducts: CaCO3; preparation of a Ca(ClO2)2-soln. by react. of a ClO2/air-mixture (5% ClO2) with Ca(OH)2 and C in H2O, filtration, react. with Na2CO3;;
chlorine dioxide
10049-04-4, 25052-55-5

chlorine dioxide

sodium hydrogencarbonate
144-55-8

sodium hydrogencarbonate

sodium chlorite
7758-19-2

sodium chlorite

Conditions
ConditionsYield
With barium peroxide In water byproducts: Ba(OH)2, O2; pptn. of Ba(OH)2 by cooling to 10°C, regeneration of BaO2 from Ba(OH)2;;
With dihydrogen peroxide In water byproducts: O2; reduction with H2O2;;
In water slow reaction;;
In water slow reaction;;
sodium peroxide

sodium peroxide

chlorine dioxide
10049-04-4, 25052-55-5

chlorine dioxide

sodium chlorite
7758-19-2

sodium chlorite

Conditions
ConditionsYield
In water byproducts: O2; reaction of an aq. ClO2-soln. with a Na2O2-soln.;; soln. free of chlorate;;
In water byproducts: O2; reaction of an aq. ClO2-soln. with a Na2O2-soln.;; soln. free of chlorate;;
sodium peroxide

sodium peroxide

chlorine dioxide
10049-04-4, 25052-55-5

chlorine dioxide

sodium chlorite
7758-19-2

sodium chlorite

Conditions
ConditionsYield
In water byproducts: O2; immediately reaction;;
In not given byproducts: O2;
In water byproducts: O2; immediately reaction;;
chlorine dioxide
10049-04-4, 25052-55-5

chlorine dioxide

sodium sulfate
7757-82-6

sodium sulfate

sodium chlorite
7758-19-2

sodium chlorite

Conditions
ConditionsYield
With calcium hydroxide; potassium sulfate In water byproducts: CaSO4, KClO3; react. in H2O, filtration of CaSO4 at 25°C, evapn. of soln. at about 40°C, pptn. of KClO3, evapn. of mother-liquor at 60-70°C, pptn., filtration (recovery of KClO3 from the filtrate);; product-mixture with 95% NaClO2, 5% CaSO4;;
With pyrographite In water react. of a soln. of 20g Na2SO4, 37g CaO and 2.5g charcoal in 360g H2O with ClO2 (dild. with air in a ratio of 1:20);;
With calcium hydroxide; potassium sulfate In water maximal temp.: 70°C;;
barium peroxide
1304-29-6

barium peroxide

chlorine dioxide
10049-04-4, 25052-55-5

chlorine dioxide

sodium sulfate
7757-82-6

sodium sulfate

sodium chlorite
7758-19-2

sodium chlorite

Conditions
ConditionsYield
With barium dihydroxide In not given byproducts: BaCO3; shaking of a ClO2-soln. with an excess of BaO2 until soln. is color- and odorless; pptn. of BaCO3; introduction of ClO2 into the soln. until permanent yellow coloration of the soln.; reaction of formed Ba(ClO2)2 with equivalent amount of Na2SO4 at b.p.;; soln. free of chlorate;;
With Ba(OH)2 In not given byproducts: BaCO3; shaking of a ClO2-soln. with an excess of BaO2 until soln. is color- and odorless; pptn. of BaCO3; introduction of ClO2 into the soln. until permanent yellow coloration of the soln.; reaction of formed Ba(ClO2)2 with equivalent amount of Na2SO4 at b.p.;; soln. free of chlorate;;
chlorine dioxide
10049-04-4, 25052-55-5

chlorine dioxide

sodium sulfate
7757-82-6

sodium sulfate

calcium hydroxide

calcium hydroxide

sodium chlorite
7758-19-2

sodium chlorite

Conditions
ConditionsYield
With pyrographite In water byproducts: CaCO3; preparation of a Ca(ClO2)2-soln. by react. of a ClO2/air-mixture (5% ClO2) with Ca(OH)2 and C in H2O, filtration, react. with Na2SO4;;
sodium nitrate
7631-99-4

sodium nitrate

chlorine dioxide
10049-04-4, 25052-55-5

chlorine dioxide

sodium chlorite
7758-19-2

sodium chlorite

Conditions
ConditionsYield
With potassium hydroxide In water maximal temp.: 70°C;;
With KOH In water maximal temp.: 70°C;;
sodium peroxide

sodium peroxide

sodium perchlorate

sodium perchlorate

sodium chlorite
7758-19-2

sodium chlorite

Conditions
ConditionsYield
In neat (no solvent, solid phase) byproducts: O2;
barium chlorite

barium chlorite

sodium chlorite
7758-19-2

sodium chlorite

Conditions
ConditionsYield
With sodium sulfate In not given
sodium chlorite trihydrate

sodium chlorite trihydrate

sodium chlorite
7758-19-2

sodium chlorite

Conditions
ConditionsYield
dehydratation at 140°C;
In neat (no solvent) dehydration in a desiccator above KOH;;
In neat (no solvent) dehydration in a desiccator above KOH;;
dehydratation at 140°C;
sodium chlorate

sodium chlorate

A

sodium chlorite
7758-19-2

sodium chlorite

B

sodium perchlorate

sodium perchlorate

C

oxygen
80937-33-3

oxygen

D

sodium chloride
7647-14-5

sodium chloride

Conditions
ConditionsYield
byproducts: ClO2; other Radiation; γ irradiation at ambient temp.;
lead chlorite

lead chlorite

sodium carbonate
497-19-8

sodium carbonate

sodium chlorite
7758-19-2

sodium chlorite

Conditions
ConditionsYield
In water react. of Pb(ClO2)2 (pptn. from NaClO2/NaClO3-soln. by addn. of sol. Pb-salts, separation of NaClO3 and NaClO2) with Na2CO3;; >99% NaClO2;;
In water react. of Pb(ClO2)2 (pptn. from NaClO2/NaClO3-soln. by addn. of sol. Pb-salts, separation of NaClO3 and NaClO2) with Na2CO3;; >99% NaClO2;;
sodium hypochlorite
7681-52-9

sodium hypochlorite

sodium chlorite
7758-19-2

sodium chlorite

Conditions
ConditionsYield
Electrolysis;0%
Electrolysis;0%
sodium chlorite
7758-19-2

sodium chlorite

sodium dihydrogenphosphate
10049-21-5

sodium dihydrogenphosphate

2-methyl-but-2-ene
513-35-9

2-methyl-but-2-ene

ethyl 3-formyl-1H-indole-2-carboxylate
18450-27-6

ethyl 3-formyl-1H-indole-2-carboxylate

2-(ethoxycarbonyl)-1H-indole-3-carboxylic acid
441800-93-7

2-(ethoxycarbonyl)-1H-indole-3-carboxylic acid

sodium chlorite
7758-19-2

sodium chlorite

chlorine dioxide
10049-04-4, 25052-55-5

chlorine dioxide

Conditions
ConditionsYield
With sodium persulfate In water98%
With sulfuric acid In water Product distribution / selectivity;72%
With potassium iodide In Citric acid/sodium citrate buffer for 0.0833333h;19%
sodium chlorite
7758-19-2

sodium chlorite

potassium dihydrogen phosphate

potassium dihydrogen phosphate

2-methyl-but-2-ene
513-35-9

2-methyl-but-2-ene

6-[(1R,4R,5S,6R)-6-(tert-Butyloxycarbonylamino)-4,5-isopropylidenedioxy-2-cyclohexen-1-yl]-4-(phenylmethoxy)-1,3-benzodioxole-5-carbaldehyde

6-[(1R,4R,5S,6R)-6-(tert-Butyloxycarbonylamino)-4,5-isopropylidenedioxy-2-cyclohexen-1-yl]-4-(phenylmethoxy)-1,3-benzodioxole-5-carbaldehyde

methyl 6-<(1R,4R,5S,6R)-6-<(tert-butyloxycarbonyl)amino>-4,5-(isopropylidenedioxy)-2-cyclohexen-1-yl>-4-(phenylmethoxy)-1,3-benzodioxole-5-carboxylate
163082-11-9

methyl 6-<(1R,4R,5S,6R)-6-<(tert-butyloxycarbonyl)amino>-4,5-(isopropylidenedioxy)-2-cyclohexen-1-yl>-4-(phenylmethoxy)-1,3-benzodioxole-5-carboxylate

Conditions
ConditionsYield
In water; tert-butyl alcohol98%
sodium chlorite
7758-19-2

sodium chlorite

2-chloro-6-ethylbenzaldehyde
343850-74-8

2-chloro-6-ethylbenzaldehyde

sodium phosphate

sodium phosphate

2-chloro-6-ethylbenzoic acid
343850-75-9

2-chloro-6-ethylbenzoic acid

Conditions
ConditionsYield
With dihydrogen peroxide; sodium hydrogensulfite In water; acetonitrile97%
sodium chlorite
7758-19-2

sodium chlorite

Na2HPO4.12H2O

Na2HPO4.12H2O

4-bromo-2-fluorobenzaldehyde
57848-46-1

4-bromo-2-fluorobenzaldehyde

2-fluoro-4-bromobenzoic acid
112704-79-7

2-fluoro-4-bromobenzoic acid

Conditions
ConditionsYield
With dihydrogen peroxide In water; acetonitrile96%
sodium chlorite
7758-19-2

sodium chlorite

3-bromo-4-fluorobenzaldehyde
77771-02-9

3-bromo-4-fluorobenzaldehyde

3-bromo-4-fluoroaniline
656-64-4

3-bromo-4-fluoroaniline

Conditions
ConditionsYield
With hydrogenchloride; sodium hydroxide; sulfuric acid In tetrahydrofuran; chloroform; water; ethyl acetate95%
sodium chlorite
7758-19-2

sodium chlorite

4-iodo-α-methylbenzeneacetaldehyde
70991-79-6

4-iodo-α-methylbenzeneacetaldehyde

aminosulfonic acid
5329-14-6

aminosulfonic acid

sodium hydrogensulfite

sodium hydrogensulfite

(RS)-2-(4'-iodophenyl)propanoic acid
34645-72-2

(RS)-2-(4'-iodophenyl)propanoic acid

Conditions
ConditionsYield
With sodium hydroxide In water; 1,2-dichloro-ethane94%
sodium chlorite
7758-19-2

sodium chlorite

4-iodo-α-methylbenzeneacetaldehyde
70991-79-6

4-iodo-α-methylbenzeneacetaldehyde

aminosulfonic acid
5329-14-6

aminosulfonic acid

(RS)-2-(4'-iodophenyl)propanoic acid
34645-72-2

(RS)-2-(4'-iodophenyl)propanoic acid

Conditions
ConditionsYield
With sodium hydroxide; sodium hydrogen sulphite In water; 1,2-dichloro-ethane94%
sodium chlorite
7758-19-2

sodium chlorite

sodium hexachloroiridate(IV) hexahydrate

sodium hexachloroiridate(IV) hexahydrate

A

chlorine dioxide
10049-04-4, 25052-55-5

chlorine dioxide

B

hexachloroiridium(III)(3-)

hexachloroiridium(III)(3-)

Conditions
ConditionsYield
With sodium perchlorate In water Kinetics; soln. contg. NaClO2, IrCl6(2-), and 0.2 M NaClO4 allowed to react at 25°C;A 94%
B n/a
2-Mercaptopyridine
2637-34-5

2-Mercaptopyridine

sodium chlorite
7758-19-2

sodium chlorite

2,2'-dipyridyldisulphide
2127-03-9

2,2'-dipyridyldisulphide

Conditions
ConditionsYield
With acetic acid In water92%
sodium chlorite
7758-19-2

sodium chlorite

(1-tritylimidazol-4-yl)carboxaldehyde
33016-47-6

(1-tritylimidazol-4-yl)carboxaldehyde

1H-1-triphenylmethylimidazole-4-carboxylic acid
191103-80-7

1H-1-triphenylmethylimidazole-4-carboxylic acid

Conditions
ConditionsYield
With potassium dihydrogenphosphate In water91%
sodium chlorite

sodium chlorite

sodium dihydrogenphosphate dihydrate

sodium dihydrogenphosphate dihydrate

2-methyl-but-2-ene
513-35-9

2-methyl-but-2-ene

ethyl 2-(4-formylphenoxymethyl)-6,7,8,9-tetrahydro-5H-cyclohepta[b]pyridine-3-carboxylate

ethyl 2-(4-formylphenoxymethyl)-6,7,8,9-tetrahydro-5H-cyclohepta[b]pyridine-3-carboxylate

tert-butyl alcohol
75-65-0

tert-butyl alcohol

ethyl 2-(4-carboxyphenoxymethyl)-6,7,8,9-tetrahydro-5H-cyclohepta[b]pyridine-3-carboxylate

ethyl 2-(4-carboxyphenoxymethyl)-6,7,8,9-tetrahydro-5H-cyclohepta[b]pyridine-3-carboxylate

Conditions
ConditionsYield
In chloroform; water89.1%
sodium chlorite
7758-19-2

sodium chlorite

sodium dihydrogenphosphate
10049-21-5

sodium dihydrogenphosphate

N-(2-t-butyl-5-carbamoylphenyl)-3-(4-formyl-2-methoxyphenyl)octanamide
189092-64-6

N-(2-t-butyl-5-carbamoylphenyl)-3-(4-formyl-2-methoxyphenyl)octanamide

N-(2-t-butyl-5-carbamoylphenyl)-3-(4-carboxy-2-methoxyphenyl)octanamide

N-(2-t-butyl-5-carbamoylphenyl)-3-(4-carboxy-2-methoxyphenyl)octanamide

Conditions
ConditionsYield
With dimethyl sulfoxide In water89%
sodium chlorite
7758-19-2

sodium chlorite

4-(5-(4-(trifluoromethyl)phenyl)-1,2,4-oxadiazol-3-yl)benzaldehyde

4-(5-(4-(trifluoromethyl)phenyl)-1,2,4-oxadiazol-3-yl)benzaldehyde

sodium dihydrogen phosphate

sodium dihydrogen phosphate

2-methyl-but-2-ene
513-35-9

2-methyl-but-2-ene

4-[5-(4-trifluoromethylphenyl)-1,2,4-oxadiazol-3-yl]benzoic acid
480390-90-7

4-[5-(4-trifluoromethylphenyl)-1,2,4-oxadiazol-3-yl]benzoic acid

Conditions
ConditionsYield
With hydrogenchloride In tetrahydrofuran; water; tert-butyl alcohol89%
sodium chlorite
7758-19-2

sodium chlorite

methyl 6-formyl-1-benzothiophene-2-carboxylate
330801-80-4

methyl 6-formyl-1-benzothiophene-2-carboxylate

2-(methoxycarbonyl)-1-benzothiophene-6-carboxylic acid

2-(methoxycarbonyl)-1-benzothiophene-6-carboxylic acid

Conditions
ConditionsYield
In ethyl acetate; acetonitrile87%
sodium chlorite
7758-19-2

sodium chlorite

aqueous sodium sulfite

aqueous sodium sulfite

sodium dihydrogen phosphate

sodium dihydrogen phosphate

2-methyl-but-2-ene
513-35-9

2-methyl-but-2-ene

3-[5-(4-trifluoromethylphenyl)-1,3,4-oxadiazol-2-yl]benzaldehyde
480391-21-7

3-[5-(4-trifluoromethylphenyl)-1,3,4-oxadiazol-2-yl]benzaldehyde

3-[5-(4-trifluoromethylphenyl)-1,3,4-oxadiazol-2-yl]benzoic acid

3-[5-(4-trifluoromethylphenyl)-1,3,4-oxadiazol-2-yl]benzoic acid

Conditions
ConditionsYield
With hydrogenchloride In tetrahydrofuran; water; tert-butyl alcohol87%
sodium chlorite
7758-19-2

sodium chlorite

2-methyl-but-2-ene
513-35-9

2-methyl-but-2-ene

(+/-)-6-Formyl-chroman-2-carbonitrile
227960-40-9

(+/-)-6-Formyl-chroman-2-carbonitrile

(+/-)-2-Cyano-chroman-6-carboxylic acid
227960-41-0

(+/-)-2-Cyano-chroman-6-carboxylic acid

Conditions
ConditionsYield
In tert-butyl alcohol85%
sodium chlorite
7758-19-2

sodium chlorite

3-acetoxyestra-1,3,5(10)-trien-17-one-2-carboxaldehyde
13879-57-7

3-acetoxyestra-1,3,5(10)-trien-17-one-2-carboxaldehyde

sodium phosphate

sodium phosphate

3-acetoxyestra-1,3,5(10)-trien-17-one-2-carboxylic acid
229486-14-0

3-acetoxyestra-1,3,5(10)-trien-17-one-2-carboxylic acid

Conditions
ConditionsYield
With dihydrogen peroxide In water; acetonitrile85%
hydrogenchloride
7647-01-0

hydrogenchloride

sodium chlorite
7758-19-2

sodium chlorite

2-methyl-but-2-ene
513-35-9

2-methyl-but-2-ene

chroman-2-carboxylic acid
51939-71-0

chroman-2-carboxylic acid

(+/-)-2-Cyano-chroman-6-carboxylic acid
227960-41-0

(+/-)-2-Cyano-chroman-6-carboxylic acid

Conditions
ConditionsYield
In tert-butyl alcohol85%
sodium chlorite
7758-19-2

sodium chlorite

2-methyl-but-2-ene
513-35-9

2-methyl-but-2-ene

3β-Benzoyloxy-24(4β)-oxolean-12-ene

3β-Benzoyloxy-24(4β)-oxolean-12-ene

sodium phosphate

sodium phosphate

3β-Benzyloxyolean-12-en-24(4β)-oic acid

3β-Benzyloxyolean-12-en-24(4β)-oic acid

Conditions
ConditionsYield
In water; tert-butyl alcohol85%
sodium chlorite
7758-19-2

sodium chlorite

aminosulfonic acid
5329-14-6

aminosulfonic acid

2-(4-(4-methoxybenzoyl)piperidinylcarbonyl)-4-methylpyridine-5-carboxylic acid

2-(4-(4-methoxybenzoyl)piperidinylcarbonyl)-4-methylpyridine-5-carboxylic acid

Conditions
ConditionsYield
In water85%
1,4-dioxane
123-91-1

1,4-dioxane

sodium chlorite
7758-19-2

sodium chlorite

2,6-dimethoxy-1-naphthalenecarbaldehyde
55218-08-1

2,6-dimethoxy-1-naphthalenecarbaldehyde

recorcinol
108-46-3

recorcinol

2,6-dimethoxy-1-naphthalenecarboxylic acid
125342-90-7

2,6-dimethoxy-1-naphthalenecarboxylic acid

Conditions
ConditionsYield
With acetic acid In water; tert-butyl alcohol84%
sodium chlorite
7758-19-2

sodium chlorite

(R)-4-[1-(3-cyclopentyloxy-4-methoxyphenyl)-2-(pyridin-4-yl)ethyl]phenylacetaldehyde

(R)-4-[1-(3-cyclopentyloxy-4-methoxyphenyl)-2-(pyridin-4-yl)ethyl]phenylacetaldehyde

2-methyl-but-2-ene
513-35-9

2-methyl-but-2-ene

sodium phosphate

sodium phosphate

(R)-4-[1-(3-Cyclopentyloxy-4-methoxyphenyl)-2-(pyridin-4-yl)ethyl]phenylacetic acid
192767-19-4

(R)-4-[1-(3-Cyclopentyloxy-4-methoxyphenyl)-2-(pyridin-4-yl)ethyl]phenylacetic acid

Conditions
ConditionsYield
With acetic acid In water; tert-butyl alcohol83%

Sodium Chlorite Specification

Sodium Chlorite(CAS NO.7758-19-2) is also named as Alcide LD; CCRIS 1426; Caswell No. 755; Chlorite sodium; Chlorous acid, sodium salt; EPA Pesticide Chemical Code 020502; HSDB 733; Neo Silox D; Textile; Textone; UNII-G538EBV4VF. Sodium Chlorite is white flakes. It is soluble in water. It is corrosive to skin and/or metals. Sodium Chlorite is an oxidizing agent. Sodium chlorite reacts very violently with organic materials containing divalent sulfur or with free sulfur (may ignite). Inhalation, ingestion or skin contact with Sodium Chlorite may cause severe injury or death.

Preparation of Sodium Chlorite: Sodium chlorite is derived indirectly from sodium chlorate, NaClO3. First, the explosively unstable gas chlorine dioxide, ClO2 is produced by reducing sodium chlorate in a strong acid solution with a suitable reducing agent (for example, sodium chloride, sulfur dioxide, or hydrochloric acid). The chlorine dioxide is then absorbed into an alkaline solution and reduced with hydrogen peroxide, H2O2 yielding sodium chlorite.
Sodium chlorite is also manufactured from chlorine dioxide, sodium hydroxide, and calcium hydroxide.
4NaOH + Ca(OH)2 + C + 4ClO2 → 4NaClO2 + CaCO3 + 3H2O
After filtering oil, the calcium carbonate, the solution of sodium chlorite(NaClO2) is evaporated and drum-dried.

Uses of Sodium Chlorite: The main application of Sodium Chlorite is the generation of chlorine dioxide for bleaching and stripping of textiles, pulp, and paper. It is also used for disinfection of a few municipal water treatment plants after conversion to chlorine dioxide. In organic synthesis, sodium chlorite is frequently used as a reagent in the Pinnick oxidation for the oxidation of aldehydes to carboxylic acids.

When you are using this chemical, please be cautious about it as the following:
1. Keep away from combustible material;
2. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice;
3. Wear suitable protective clothing, gloves and eye/face protection;
4. In case of accident or if you feel unwell, seek medical advice immediately (show label where possible);
5. In case of insufficient ventilation, wear suitable respiratory equipment;

You can still convert the following datas into molecular structure:
(1)InChI=1S/ClHO2.Na/c2-1-3;/h(H,2,3);/q;+1/p-1;
(2)InChIKey=UKLNMMHNWFDKNT-UHFFFAOYSA-M;
(3)SmilesCl(=O)[O-].[Na+]

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
guinea pig LD50 oral 300mg/kg (300mg/kg)   Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 45(4), Pg. 6, 1980.
man TDLo oral 143mg/kg (143mg/kg) KIDNEY, URETER, AND BLADDER: "CHANGES IN TUBULES (INCLUDING ACUTE RENAL FAILURE, ACUTE TUBULAR NECROSIS)"

LUNGS, THORAX, OR RESPIRATION: CYANOSIS

GASTROINTESTINAL: NAUSEA OR VOMITING
Renal Failure. Vol. 15, Pg. 645, 1993.
 
mouse LD50 oral 350mg/kg (350mg/kg)   Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 45(4), Pg. 6, 1980.
rat LC50 inhalation 230mg/m3/4H (230mg/m3)   National Technical Information Service. Vol. OTS0534543,
rat LD50 oral 165mg/kg (165mg/kg)   Yakkyoku. Pharmacy. Vol. 31, Pg. 959, 1980.
rat LD50 oral 165mg/kg (165mg/kg) LIVER: "JAUNDICE, OTHER OR UNCLASSIFIED"

KIDNEY, URETER, AND BLADDER: INTERSTITIAL NEPHRITIS
Yakkyoku. Pharmacy. Vol. 31, Pg. 959, 1980.

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