Product Name

  • Name

    Sodium bisulfate

  • EINECS 231-665-7
  • CAS No. 7681-38-1
  • Article Data169
  • CAS DataBase
  • Density 2.103 g/cm3
  • Solubility
  • Melting Point 315 °C
  • Formula NaHSO4
  • Boiling Point 330 °C at 760 mmHg
  • Molecular Weight 120.061
  • Flash Point
  • Transport Information UN 3260
  • Appearance off-white granules, crystals or powder
  • Safety 24-26
  • Risk Codes 41
  • Molecular Structure Molecular Structure of 7681-38-1 (Sodium bisulfate)
  • Hazard Symbols IrritantXi
  • Synonyms WC-Super;WC-Klosettreiniger;WC-Perfect;WC 00;Sodium hydrosulfate;Sodium hydrogen sulfate (NaHSO4);Sodium hydrogen sulfate;Sulfuricacid, monosodium salt (8CI,9CI);Acid sodium sulfate;BIF;Bisulfate of soda;Fanal;Monobasic sodium sulfate;Monosodium hydrogen sulfate;Monosodiumsulfate;Niter cake;Nitre cake;Poultry Litter Treatment;Printgen N;Sodiumacid sulfate;Sodium bisulfate;Sodium bisulphate;
  • PSA 85.81000
  • LogP 0.08540

Synthetic route

sulfuric acid
7664-93-9

sulfuric acid

sodium chloride
7647-14-5

sodium chloride

A

hydrogenchloride
7647-01-0

hydrogenchloride

B

sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

Conditions
ConditionsYield
In not given reaction mixture containing 28 % NaCl and 21 % SO3; reaction at 400 °C;;A n/a
B 98%
In not given reaction mixture containing 28 % NaCl and 21 % SO3; reaction at 400 °C;;A n/a
B 98%
In sulfuric acid
water
7732-18-5

water

iodine
7553-56-2

iodine

sodium hydrogensulfite

sodium hydrogensulfite

A

sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

B

hydrogen iodide
10034-85-2

hydrogen iodide

Conditions
ConditionsYield
In tetradecyl(trihexyl)phosphonium decanoate Reactivity;
sodium chlorite
7758-19-2

sodium chlorite

sodium thiosulfate

sodium thiosulfate

A

sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

B

sodium chloride
7647-14-5

sodium chloride

Conditions
ConditionsYield
With water In not given in neutral soln., equiv. amt. of educts;
With water In not given little excess of NaOCl2;A >99
B n/a
With H2O In not given in neutral soln., equiv. amt. of educts;
With H2O In not given little excess of NaOCl2;A >99
B n/a
iodine
7553-56-2

iodine

sodium thiosulfate

sodium thiosulfate

A

sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

B

hydrogen iodide
10034-85-2

hydrogen iodide

C

Sulfate
14808-79-8

Sulfate

D

tetrathionate(2-)

tetrathionate(2-)

Conditions
ConditionsYield
With water In not given neutral soln.;
With H2O In not given neutral soln.;
bromine
7726-95-6

bromine

sodium thiosulfate

sodium thiosulfate

A

sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

B

hydrogen bromide
10035-10-6, 12258-64-9

hydrogen bromide

Conditions
ConditionsYield
With water In water
With H2O In water
sodium thiosulfate

sodium thiosulfate

A

hydrogenchloride
7647-01-0

hydrogenchloride

B

sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

Conditions
ConditionsYield
With water; chlorine In water
With Cl2; H2O In water
sodium hypoiodite
22468-64-0

sodium hypoiodite

sodium thiosulfate

sodium thiosulfate

A

sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

B

sodium iodide
7681-82-5

sodium iodide

Conditions
ConditionsYield
With water
With H2O
sodium thiosulfate

sodium thiosulfate

periodic acid
13444-71-8

periodic acid

A

sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

B

hydrogen iodide
10034-85-2

hydrogen iodide

Conditions
ConditionsYield
With water In not given with HCl acidified KIO4 soln., at 19.2°C, 31°C and 40°C;
With H2O In not given with HCl acidified KIO4 soln., at 19.2°C, 31°C and 40°C;
sodium hypobromide

sodium hypobromide

sodium thiosulfate

sodium thiosulfate

A

sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

B

sodium bromide
7647-15-6

sodium bromide

Conditions
ConditionsYield
With water
With H2O
sodium hypochlorite
7681-52-9

sodium hypochlorite

sodium thiosulfate

sodium thiosulfate

A

sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

B

sodium chloride
7647-14-5

sodium chloride

Conditions
ConditionsYield
With water
With H2O
carbon dioxide
124-38-9

carbon dioxide

sodium sulfate
7757-82-6

sodium sulfate

barium carbonate

barium carbonate

A

barium sulfate

barium sulfate

B

sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

Conditions
ConditionsYield
With water In water reaction of BaCO3 with Na2SO4, H2O and CO2 at 80°C under formation of a satd. NaHCO3-solution and BaSO4;;
sodium chloride
7647-14-5

sodium chloride

A

hydrogenchloride
7647-01-0

hydrogenchloride

B

sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

Conditions
ConditionsYield
With sulfuric acid In neat (no solvent) reaction at lower temp.;;
With H2SO4 In neat (no solvent) reaction at lower temp.;;
ammonium bisulfate
7803-63-6

ammonium bisulfate

sodium chloride
7647-14-5

sodium chloride

A

sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

B

ammonia
7664-41-7

ammonia

Conditions
ConditionsYield
In neat (no solvent) addn. of NaCl to molten NH4HSO4 leads to the formation of NH4NaSO4 and HCl, which reacts to NH3 and NaHSO4 by further heating;;
In neat (no solvent) addn. of NaCl to molten NH4HSO4 leads to the formation of NH4NaSO4 and HCl, which reacts to NH3 and NaHSO4 by further heating;;
sulfuric acid
7664-93-9

sulfuric acid

sodium iodide
7681-82-5

sodium iodide

A

sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

B

sodium sulfate
7757-82-6

sodium sulfate

Conditions
ConditionsYield
In water byproducts: I2; on synthesis of I2 by treatment of NaI with H2SO4;;
carbon dioxide
124-38-9

carbon dioxide

zinc sulfide

zinc sulfide

A

sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

B

zinc(II) oxide

zinc(II) oxide

Conditions
ConditionsYield
In neat (no solvent) byproducts: CO, S; heating up to 750 °C for 8 h;;
sulfur trioxide
7446-11-9

sulfur trioxide

sodium sulfate
7757-82-6

sodium sulfate

A

sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

B

sodium pyrosulfate

sodium pyrosulfate

Conditions
ConditionsYield
With sulfuric acid In not given NaHS2O7 impurity (Y:<1%);
With H2SO4 In not given NaHS2O7 impurity (Y:<1%);
Glauber's salt

Glauber's salt

hydrogen fluoride
7664-39-3

hydrogen fluoride

A

sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

B

sodium fluoride

sodium fluoride

Conditions
ConditionsYield
In hydrogen fluoride reaction of Na2SO4*10H2O with HF soln.;; pptn. of NaF; NaHSO4 remains disssolved;;
sodium hexafluorosilicate

sodium hexafluorosilicate

sulfuric acid
7664-93-9

sulfuric acid

A

sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

B

hydrogen fluoride
7664-39-3

hydrogen fluoride

C

silicon tetrafluoride
7783-61-1

silicon tetrafluoride

Conditions
ConditionsYield
In not given boiling Na2SiF6 with H2SO4;;
In not given boiling Na2SiF6 with H2SO4;;
sodium nitrate
7631-99-4

sodium nitrate

sulfuric acid
7664-93-9

sulfuric acid

A

sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

B

nitric acid
7697-37-2

nitric acid

Conditions
ConditionsYield
In neat (no solvent) addn. of concd. H2SO4 to solid NaNO3; vac. distn. (77 K);
In not given formation of NaH3(SO4)2 and HNO3 by reaction of NaNO3 with H2SO4; reaction of NaH3(SO4)2 with NaNO3 forming NaHSO4 and HNO3; addition of small portions of NaNO3 and H2SO4 to the retort to prevent foaming over;;
In not given formation of NaH3(SO4)2 and HNO3 by reaction of NaNO3 with H2SO4 below 100 °C; reaction of NaH3(SO4)2 with NaNO3 at higher temperature forming NaHSO4 and HNO3;; heating at 300 °C to remove traces of HNO3;;
sodium iodate

sodium iodate

sodium hydrogensulfite

sodium hydrogensulfite

A

sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

B

water
7732-18-5

water

C

iodine
7553-56-2

iodine

D

sodium sulfate
7757-82-6

sodium sulfate

Conditions
ConditionsYield
In water
In water diminution of the remaining residue by addn. of Ca(2+) by pptn. of I2;;
In water the remaining residue in mother liquor corrodes the apparatus and should be pptd. by CuSO4;;
sodium sulfate
7757-82-6

sodium sulfate

trifluoroacetic acid
76-05-1

trifluoroacetic acid

A

sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

B

sodium 2,2,2-trifluoroacetate
2923-18-4

sodium 2,2,2-trifluoroacetate

hydrogenchloride
7647-01-0

hydrogenchloride

sodium sulfate
7757-82-6

sodium sulfate

A

sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

B

sodium chloride
7647-14-5

sodium chloride

Conditions
ConditionsYield
In neat (no solvent) at 25°C;;
In not given reaction of Na2SO4 with gaseous HCl in coldness;;
In not given reaction of Na2SO4 with gaseous HCl in coldness;;
In neat (no solvent) at 25°C;;
hydrogenchloride
7647-01-0

hydrogenchloride

Glauber's salt

Glauber's salt

A

sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

B

sodium chloride
7647-14-5

sodium chloride

Conditions
ConditionsYield
In neat (no solvent) at 25°C;;
In neat (no solvent) at 25°C;;
ammonium sulfate

ammonium sulfate

sodium sulfate
7757-82-6

sodium sulfate

A

sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

B

ammonia
7664-41-7

ammonia

Conditions
ConditionsYield
introd. of steam makes the react. complete;
With water In not given heating Na2SO4 with (NH4)2SO4 from the ammonia soda process with Na2SO4, NH2 and CO2 in a stream of steam; regeneration of NH3 and NaHSO4 for prepn. of Na2SO4;;
introd. of steam makes the react. complete;
With water In not given heating Na2SO4 with (NH4)2SO4 from the ammonia soda process with Na2SO4, NH2 and CO2 in a stream of steam; regeneration of NH3 and NaHSO4 for prepn. of Na2SO4;;
sodium sulfate
7757-82-6

sodium sulfate

A

sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

B

sodium chloride
7647-14-5

sodium chloride

Conditions
ConditionsYield
With hydrogenchloride In neat (no solvent) equilibrium;;
With hydrogenchloride In water products pptd. from the cooled soln.;;
With HCl In water products pptd. from the cooled soln.;;
sodium sulfate
7757-82-6

sodium sulfate

A

sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

B

sodium hydroxide
1310-73-2

sodium hydroxide

Conditions
ConditionsYield
With water In water hydrolysis;;
With H2O In water hydrolysis;;
sodium sulfate
7757-82-6

sodium sulfate

sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

Conditions
ConditionsYield
With hydrogenchloride In water satd. soln. of neutral sulfate is distd. with aq. HCl;;
With trifluoroacetic acid byproducts: CF3CO2Na;
With CF3CO2H byproducts: CF3CO2Na;
With HCl In water satd. soln. of neutral sulfate is distd. with aq. HCl;;
sodium sulfate
7757-82-6

sodium sulfate

A

sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

B

hypochloric acid
14989-30-1

hypochloric acid

Conditions
ConditionsYield
With water; chlorine In not given byproducts: NaCl; passing Cl2 into a soln. of Na2SO4;;
sodium nitrate
7631-99-4

sodium nitrate

A

sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

B

nitric acid
7697-37-2

nitric acid

Conditions
ConditionsYield
With sulfuric acid byproducts: Na2SO4; distn. with H2SO4,effect of NaNO3:H2SO4 ratio;
With sulfuric acid above 155°C,distn. at 100-140°C and above 200°C at the end,normal pressure;
With H2SO4 above 155°C,distn. at 100-140°C and above 200°C at the end,normal pressure;
With H2SO4 byproducts: Na2SO4; distn. with H2SO4,effect of NaNO3:H2SO4 ratio;
sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

sodium chloride
7647-14-5

sodium chloride

A

hydrogenchloride
7647-01-0

hydrogenchloride

B

sodium sulfate
7757-82-6

sodium sulfate

Conditions
ConditionsYield
In neat (no solvent) at 200 - 450°C;;A 90%
B n/a
In sulfuric acid
sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

dihydropyridinemonocarboxylic acid
13406-98-9

dihydropyridinemonocarboxylic acid

di-tert-butyl dicarbonate
24424-99-5

di-tert-butyl dicarbonate

(S)-(-)-1-(tert-butoxycarbonyl)-2-piperidinecarboxylic acid
26250-84-0

(S)-(-)-1-(tert-butoxycarbonyl)-2-piperidinecarboxylic acid

Conditions
ConditionsYield
With sodium carbonate In 1,4-dioxane; water; ethyl acetate75%
With sodium carbonate In 1,4-dioxane; water; ethyl acetate75%
With sodium carbonate In 1,4-dioxane; water; ethyl acetate75%
sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

3-[(4-tert-butyl-2-thiazolyl)methoxy]-5'-[3-(4-chlorophenylsulfonyl)propyl]-2'-cyanomethoxybenzanilide

3-[(4-tert-butyl-2-thiazolyl)methoxy]-5'-[3-(4-chlorophenylsulfonyl)propyl]-2'-cyanomethoxybenzanilide

3-[(4-tert-butylthiazol-2-yl)methoxy]-5'-[3-(4-chlorobenzenesulfonyl) propyl]-2'-(1H-tetrazol-5-ylmethoxy)benzanilide

3-[(4-tert-butylthiazol-2-yl)methoxy]-5'-[3-(4-chlorobenzenesulfonyl) propyl]-2'-(1H-tetrazol-5-ylmethoxy)benzanilide

Conditions
ConditionsYield
With ammonium chloride In N-methyl-acetamide74%
sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

quinoline-2-carboxylic acid
93-10-7

quinoline-2-carboxylic acid

diethyl ether
60-29-7

diethyl ether

2,3,4,5,6-pentafluorophenol
771-61-9

2,3,4,5,6-pentafluorophenol

quinaldic acid pentafluorophenyl ester

quinaldic acid pentafluorophenyl ester

Conditions
ConditionsYield
With potassium In tetrahydrofuran; hexane; dichloromethane73%
sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

4-methyl-3-nitrobenzaldehyde
31680-07-6

4-methyl-3-nitrobenzaldehyde

A

5(1H-benzoimidazol-2-yl)-2-methyl-phenylamine
292644-33-8

5(1H-benzoimidazol-2-yl)-2-methyl-phenylamine

B

N-[5-(1H-benzimidazol-2-yl)-2-methylphenyl]-N'-(2,3-dihydro-1,4-benzodioxin-6-ylcarbonyl)thiourea

N-[5-(1H-benzimidazol-2-yl)-2-methylphenyl]-N'-(2,3-dihydro-1,4-benzodioxin-6-ylcarbonyl)thiourea

Conditions
ConditionsYield
In N-methyl-acetamide; N,N-dimethyl-formamideA 67%
B n/a
sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

6-amino-5-nitroso-1-n-butyl-1,3-dihydropyrimidine-2,4-dione
76194-06-4

6-amino-5-nitroso-1-n-butyl-1,3-dihydropyrimidine-2,4-dione

5,6-diamino-1-n-butyl-1,3-dihydropyrimidine-2,4-dione
76194-08-6

5,6-diamino-1-n-butyl-1,3-dihydropyrimidine-2,4-dione

Conditions
ConditionsYield
In water65%
sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

{PtI2(en)2}Cl2

{PtI2(en)2}Cl2

{Pt(en)2}{PtI2(en)2}(SO4)2*6H2O

{Pt(en)2}{PtI2(en)2}(SO4)2*6H2O

Conditions
ConditionsYield
In water NaHSO4 in H2O added to the Pt-complexes in H2O, concd. on a steam bath, cooled; crystals filtered off, washed (water); elem. anal., UV;64.4%
sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

dimethyl 2-[4-[2-(5-methyl-2-phenyl-4-oxazolyl)ethoxy]benzyl]malonate
170861-71-9

dimethyl 2-[4-[2-(5-methyl-2-phenyl-4-oxazolyl)ethoxy]benzyl]malonate

methyl iodide
74-88-4

methyl iodide

dimethyl 2-methyl-2-[4-[2-(5-methyl-2-phenyl-4-oxazolyl)ethoxy]benzyl]malonate

dimethyl 2-methyl-2-[4-[2-(5-methyl-2-phenyl-4-oxazolyl)ethoxy]benzyl]malonate

Conditions
ConditionsYield
In N-methyl-acetamide62%
sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

cerium(III) chloride heptahydrate

cerium(III) chloride heptahydrate

K8H[P2W15(NbO2)3O59]*12H2O

K8H[P2W15(NbO2)3O59]*12H2O

water
7732-18-5

water

K6Na4H8[Ce6(H2O)38(P2W15Nb3O62)4]*56H2O

K6Na4H8[Ce6(H2O)38(P2W15Nb3O62)4]*56H2O

Conditions
ConditionsYield
With HCl In water W compd. (0.22 mmol) dissolcved in H2O at 90°C, NaHSO4 (1.44 mmol) added, stirred for 10 min, pH adjusted to 2 (1 M HCl), aq. soln. of EuCl3 (0.39 mmol) added, mixt. stirred at 85°C for 2 h; filtered, concd., crystd. in 1 wk at room temp., elem. anal.;57%
sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

EuCl3*7H2O

EuCl3*7H2O

K8H[P2W15(NbO2)3O59]*12H2O

K8H[P2W15(NbO2)3O59]*12H2O

water
7732-18-5

water

K6Na4H8[Eu6(H2O)38(P2W15Nb3O62)4]*45H2O

K6Na4H8[Eu6(H2O)38(P2W15Nb3O62)4]*45H2O

Conditions
ConditionsYield
With HCl In water W compd. (0.22 mmol) dissolcved in H2O at 90°C, NaHSO4 (1.44 mmol) added, stirred for 10 min, pH adjusted to 2 (1 M HCl), aq. soln. of EuCl3 (0.39 mmol) added, mixt. stirred at 85°C for 2 h; filtered, concd., crystd. in 1 wk at room temp., elem. anal.;51%
sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

p-nitrobenzyl (5R,6R)-6-((S)-1-hydroxyethyl)-2-methylthiopenem-3-carboxylate

p-nitrobenzyl (5R,6R)-6-((S)-1-hydroxyethyl)-2-methylthiopenem-3-carboxylate

ethyl acetate n-hexane

ethyl acetate n-hexane

p-nitrobenzyl (5R,6R)-6-((S)-1-hydroxyethyl)-2-methylsulfinylpenem-3-carboxylate

p-nitrobenzyl (5R,6R)-6-((S)-1-hydroxyethyl)-2-methylsulfinylpenem-3-carboxylate

Conditions
ConditionsYield
With sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid In dichloromethane42%
sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

cyclohexane-1,2-epoxide
286-20-4

cyclohexane-1,2-epoxide

cyclohexanone-2-ol
533-60-8

cyclohexanone-2-ol

Conditions
ConditionsYield
With trifluorormethanesulfonic acid; N-ethyl-N,N-diisopropylamine In dichloromethane; dimethyl sulfoxide39.5%
sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

3-nitro-benzaldehyde
99-61-6

3-nitro-benzaldehyde

A

5(1H-benzoimidazol-2-yl)-2-methyl-phenylamine
292644-33-8

5(1H-benzoimidazol-2-yl)-2-methyl-phenylamine

B

N-[3-(1H-benzimidazol-2-yl)phenyl]-N'-(2,3-dihydro-1,4-benzodioxin-6-ylcarbonyl)thiourea

N-[3-(1H-benzimidazol-2-yl)phenyl]-N'-(2,3-dihydro-1,4-benzodioxin-6-ylcarbonyl)thiourea

Conditions
ConditionsYield
In N,N-dimethyl-formamideA 39%
B n/a
sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

zinc(II) acetate dihydrate
5970-45-6

zinc(II) acetate dihydrate

piperazine hexahydrate
142-63-2

piperazine hexahydrate

copper(I) bromide
7787-70-4

copper(I) bromide

[piperazine(+2H)][NaZn2Cu(sulfite)4]

[piperazine(+2H)][NaZn2Cu(sulfite)4]

Conditions
ConditionsYield
In water High Pressure; under hydrothermal conditions; mixt. of CuBr, Zn acetate, NaHSO4 and piperazine in distd. H2O sealed in autoclave; heated at 100°C for 5 d; cooled to room temp. (0.04°C/min); crystals collected; elem. anal.;38.5%
sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

thiomarinol

thiomarinol

thiomarinol B

thiomarinol B

Conditions
ConditionsYield
With 3-chloro-benzenecarboperoxoic acid In acetone8%
sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

zinc sulfide

zinc sulfide

hydrogen sulfide
7783-06-4

hydrogen sulfide

Conditions
ConditionsYield
In water ZnS (pptd. in the heat, hot washed, well dried and pulverized); amount of H2S depends on concn. of acidic soln.; dilution: 1 mol NaHSO4 in 2 l;;1.84%
In water ZnS (pptd. in the heat, hot washed, well dried and pulverized); amount of H2S depends on concn. of acidic soln.; dilution: 1 mol NaHSO4 in 1 l;;1.67%
In water ZnS (pptd. in the heat, hot washed, well dried and pulverized); amount of H2S depends on concn. of acidic soln.; dilution: 1 mol NaHSO4 in 4 l;;1.95%
In water ZnS (pptd. in the heat, hot washed, well dried and pulverized); amount of H2S depends on concn. of acidic soln.; dilution: 1 mol NaHSO4 in 8 l;;1.89%
sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

ethyl (2E)-3-[4-(methylsulfonyl)phenyl]acrylate
137473-27-9

ethyl (2E)-3-[4-(methylsulfonyl)phenyl]acrylate

3-(4-methanesulfonyl-phenyl)-acrylic acid
5345-30-2, 88899-85-8

3-(4-methanesulfonyl-phenyl)-acrylic acid

Conditions
ConditionsYield
With lithium hydroxide In 1,4-dioxane; ethanol; water
sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

2-chloro-3-trifluoromethylbenzaldehyde
93118-03-7

2-chloro-3-trifluoromethylbenzaldehyde

4-(dicyanomethylene)-2-methyl-6-(p-dimethylaminostyryl)-4H-pyran
96042-30-7

4-(dicyanomethylene)-2-methyl-6-(p-dimethylaminostyryl)-4H-pyran

isopropyl alcohol
67-63-0

isopropyl alcohol

(2-chloro-3-(trifluoromethyl)phenyl)methanol

(2-chloro-3-(trifluoromethyl)phenyl)methanol

Conditions
ConditionsYield
With sodium borohydrid; sodium hydrogencarbonate
sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

oxalyl dichloride
79-37-8

oxalyl dichloride

2-Phenoxyethanol
122-99-6

2-Phenoxyethanol

dimethyl sulfoxide
67-68-5

dimethyl sulfoxide

2-phenoxyethanal
2120-70-9

2-phenoxyethanal

Conditions
ConditionsYield
With triethylamine In n-heptane; 4-(dicyanomethylene)-2-methyl-6-(p-dimethylaminostyryl)-4H-pyran; ethyl acetate
sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

phosphorus(III) tribromide

phosphorus(III) tribromide

1-[2-(2,4-dichlorophenoxy)phenyl]methanol
361212-70-6

1-[2-(2,4-dichlorophenoxy)phenyl]methanol

2-(2,4-dichlorophenoxy)benzyl bromide

2-(2,4-dichlorophenoxy)benzyl bromide

Conditions
ConditionsYield
With sodium hydrogencarbonate In 1,4-dioxane; n-heptane; water; ethyl acetate
sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

1-(bromomethyl)-2-chloro-3-(trifluoromethyl)benzene

1-(bromomethyl)-2-chloro-3-(trifluoromethyl)benzene

(1-(triphenylmethyl)-4,5,6,7-tetrahydro-1H-benzimidazol-5-yl)methanol

(1-(triphenylmethyl)-4,5,6,7-tetrahydro-1H-benzimidazol-5-yl)methanol

(3-(triphenylmethyl)-4,5,6,7-tetrahydro-3H-benzimidazol-5-yl)methanol

(3-(triphenylmethyl)-4,5,6,7-tetrahydro-3H-benzimidazol-5-yl)methanol

A

5-(2-chloro-3-(trifluoromethyl)benzyloxymethyl)-1-triphenylmethyl-4,5,6,7-tetrahydro-1H-benzimidazole

5-(2-chloro-3-(trifluoromethyl)benzyloxymethyl)-1-triphenylmethyl-4,5,6,7-tetrahydro-1H-benzimidazole

B

5-(2-chloro-3-(trifluoromethyl)benzyloxymethyl)-3-triphenylmethyl-4,5,6,7-tetrahydro-3H-benzimidazole

5-(2-chloro-3-(trifluoromethyl)benzyloxymethyl)-3-triphenylmethyl-4,5,6,7-tetrahydro-3H-benzimidazole

Conditions
ConditionsYield
With tetra-(n-butyl)ammonium iodide; sodium hydrogencarbonate In tetrahydrofuran; mineral oil of sodium hydride; water; ethyl acetate
sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

2-(3-(trifluoromethoxy)phenoxy)benzyl bromide

2-(3-(trifluoromethoxy)phenoxy)benzyl bromide

(1-(triphenylmethyl)-4,5,6,7-tetrahydro-1H-benzimidazol-5-yl)methanol

(1-(triphenylmethyl)-4,5,6,7-tetrahydro-1H-benzimidazol-5-yl)methanol

(3-(triphenylmethyl)-4,5,6,7-tetrahydro-3H-benzimidazol-5-yl)methanol

(3-(triphenylmethyl)-4,5,6,7-tetrahydro-3H-benzimidazol-5-yl)methanol

A

5-[2-(3-(trifluoromethoxy)phenoxy)benzyloxymethyl]-3-triphenylmethyl4,5,6,7-tetrahydro-3H-benzimidazole

5-[2-(3-(trifluoromethoxy)phenoxy)benzyloxymethyl]-3-triphenylmethyl4,5,6,7-tetrahydro-3H-benzimidazole

B

5-[2-(3-(trifluoromethoxy)phenoxy)benzyloxymethyl]-1-triphenylmethyl-4,5,6,7-tetrahydro-1H-benzimidazole

5-[2-(3-(trifluoromethoxy)phenoxy)benzyloxymethyl]-1-triphenylmethyl-4,5,6,7-tetrahydro-1H-benzimidazole

Conditions
ConditionsYield
With tetra-(n-butyl)ammonium iodide; sodium hydrogencarbonate In tetrahydrofuran; water; mineral oil
sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

(2-chloro-3-(trifluoromethyl)phenyl)methanol

(2-chloro-3-(trifluoromethyl)phenyl)methanol

1-(bromomethyl)-2-chloro-3-(trifluoromethyl)benzene

1-(bromomethyl)-2-chloro-3-(trifluoromethyl)benzene

Conditions
ConditionsYield
With phosphorus tribromide; sodium hydrogencarbonate In 1,4-dioxane; n-heptane; ethyl acetate
sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

4-(dicyanomethylene)-2-methyl-6-(p-dimethylaminostyryl)-4H-pyran
96042-30-7

4-(dicyanomethylene)-2-methyl-6-(p-dimethylaminostyryl)-4H-pyran

2-(2,4-dichlorophenoxy)benzaldehyde
86309-06-0

2-(2,4-dichlorophenoxy)benzaldehyde

1-[2-(2,4-dichlorophenoxy)phenyl]methanol
361212-70-6

1-[2-(2,4-dichlorophenoxy)phenyl]methanol

Conditions
ConditionsYield
With sodium borohydrid; sodium hydrogencarbonate In n-heptane; ethyl acetate; isopropyl alcohol
sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

2-(3-trifluoromethoxyphenoxy)benzaldehyde

2-(3-trifluoromethoxyphenoxy)benzaldehyde

4-(dicyanomethylene)-2-methyl-6-(p-dimethylaminostyryl)-4H-pyran
96042-30-7

4-(dicyanomethylene)-2-methyl-6-(p-dimethylaminostyryl)-4H-pyran

[2-(3-(trifluoromethoxy)phenoxy)phenyl]methanol

[2-(3-(trifluoromethoxy)phenoxy)phenyl]methanol

Conditions
ConditionsYield
With sodium borohydrid; sodium hydrogencarbonate In n-heptane; water; ethyl acetate; isopropyl alcohol
sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

danishefsky's diene
54125-02-9

danishefsky's diene

2-phenoxyethanal
2120-70-9

2-phenoxyethanal

2-phenoxymethyl-2,3-dihydropyran-4-one

2-phenoxymethyl-2,3-dihydropyran-4-one

Conditions
ConditionsYield
With sodium hydrogencarbonate; Zinc chloride In n-heptane; 4-(dicyanomethylene)-2-methyl-6-(p-dimethylaminostyryl)-4H-pyran; ethyl acetate
sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

Acetylsulfanyl-acetic acid pentafluorophenyl ester

Acetylsulfanyl-acetic acid pentafluorophenyl ester

L-Asp(t-Bu)
3057-74-7

L-Asp(t-Bu)

2-(2-Acetylsulfanyl-acetylamino)-succinic acid 4-tert-butyl ester

2-(2-Acetylsulfanyl-acetylamino)-succinic acid 4-tert-butyl ester

Conditions
ConditionsYield
With triethylamine In dichloromethane
sodium hydrogen sulfate
7681-38-1

sodium hydrogen sulfate

1-formamidino-3,5-dimethylpyrazole

1-formamidino-3,5-dimethylpyrazole

4-[1-(3-Aminopropyl)-5-fluoro-indol-3-yl]-5-(5-fluoro-1-methyl-indol-3-yl)-2,4-dihydro-[1,2,4]triazol-3-one hydrochloride
1349851-50-8

4-[1-(3-Aminopropyl)-5-fluoro-indol-3-yl]-5-(5-fluoro-1-methyl-indol-3-yl)-2,4-dihydro-[1,2,4]triazol-3-one hydrochloride

N-(3-{5-Fluoro-3-[3-(5-fluoro-1-methyl-indol-3-yl)-5-oxo 1,5-dihydro-4H-1,2,4-triazol-4-yl]-indol-1-yl}propyl)guanidine trifluoroacetate
310886-24-9

N-(3-{5-Fluoro-3-[3-(5-fluoro-1-methyl-indol-3-yl)-5-oxo 1,5-dihydro-4H-1,2,4-triazol-4-yl]-indol-1-yl}propyl)guanidine trifluoroacetate

Conditions
ConditionsYield
In methanol; ethanol; water; acetonitrile

Sodium bisulfate Chemical Properties

IUPAC Name: Hydrogen sodium sulfate
The MF of Hydrogen sodium sulfate (7681-38-1) is HNaO4S.

                                   
The MW of Hydrogen sodium sulfate (7681-38-1) is 120.06.
Synonyms of Hydrogen sodium sulfate (7681-38-1): Sodium hydrogensulphate ; Monosodium hydrogen sulfate ; Sodium hydrogen sulfate, solid ; Sodium hydrogen sulphate ; Sulfuric acid monosodium salt ; Sulfuric acid sodium salt
Stability: Stable. Incompatible with strong bases, strong oxidizing agents, sodium carbonate, sodium hypochlorite. May decompose upon exposure to moist air or water
Product Categories: Inorganics
Form: off-white granules, crystals or powder
EINECS: 231-665-7 
Boiling Point: 330 °C
Melting Point: 315 °C 
Density: 2.1 g/ml
Merck: 13,8658

Sodium bisulfate Uses

  Hydrogen sodium sulfate (7681-38-1) is used as a mineral decomposition flux, disinfectants, and manufacturing to help agent such as sodium sulfate and sodium alum.

Sodium bisulfate Production

Acidic salts, such as various BISULFATES, are generally soluble in water. The resulting solutions contain moderate concentrations of hydrogen ions and have pH's of less than 7.0. They react as acids to neutralize bases. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Many of these compounds catalyze organic reactions. The combination of calcium hypochlorite, sodium hydrogen sulfate, starch, and sodium carbonate, when compressed, caused the materials to incandescence, followed by explosion.

Sodium bisulfate Safety Profile

Safety information of Hydrogen sodium sulfate (7681-38-1):
Hazard Codes  Xi
Risk Statements 
41  Risk of serious damage to eyes
Safety Statements 
24  Avoid contact with skin
26  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
RIDADR  3260
WGK Germany  1
RTECS  VZ1860000
F  3
HazardClass  8
PackingGroup  II

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