Product Name

  • Name

    Sodium tetraphenylboron

  • EINECS 205-605-5
  • CAS No. 143-66-8
  • Article Data33
  • CAS DataBase
  • Density 1.15 g/cm3
  • Solubility Soluble in water
  • Melting Point 300 °C
  • Formula C24H20BNa
  • Boiling Point
  • Molecular Weight 342.224
  • Flash Point
  • Transport Information
  • Appearance white powder
  • Safety 26-36/37
  • Risk Codes 22-36/37/38
  • Molecular Structure Molecular Structure of 143-66-8 (Sodium tetraphenylboron)
  • Hazard Symbols HarmfulXn,IrritantXi
  • Synonyms Borate(1-),tetraphenyl-, sodium (8CI,9CI);Kalibor;Kalignost;Kariporu K;Sodiumtetrakis(phenyl) borate;Sodium tetraphenylborate(NaPh4B);Sodium tetraphenylborate(1-);Sodiumtetraphenylboride(1-);Tetraphenyl boron sodium salt;Tetraphenyl sodium borate;
  • PSA 0.00000
  • LogP 3.06400

Synthetic route

phenylmagnesium bromide

phenylmagnesium bromide

sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

Conditions
ConditionsYield
With boron trifluoride diethyl etherate anschliessendes Behandeln mit H2O und NaCl;
With sodium tetrafluoroborate; diethyl ether anschliessendes Behandeln mit wss.NaCl;
triphenylborane
960-71-4

triphenylborane

sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

Conditions
ConditionsYield
With sodium tetraethylborate In xylene Heating;
sodium perchlorate

sodium perchlorate

potassium tetraphenylborate
3244-41-5

potassium tetraphenylborate

A

potassium perchlorate

potassium perchlorate

B

sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

Conditions
ConditionsYield
In acetone filtration, evapn. of filtrate;
In acetone filtration, evapn. of filtrate;
trifluoroborane diethyl ether
109-63-7

trifluoroborane diethyl ether

phenylmagnesium bromide
100-58-3

phenylmagnesium bromide

sodium chloride
7647-14-5

sodium chloride

sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

Conditions
ConditionsYield
extrn. with dry acetone;
In diethyl ether; water ether layer is evapd.; residue dissolved in water; satd. with NaCl;
extrn. with dry acetone;
In diethyl ether; water ether layer is evapd.; residue dissolved in water; satd. with NaCl;
sodium tetrafluoroborate
13755-29-8

sodium tetrafluoroborate

phenylmagnesium bromide
100-58-3

phenylmagnesium bromide

sodium chloride
7647-14-5

sodium chloride

sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

Conditions
ConditionsYield
In tetrahydrofuran; water THF layer is again treated with aq. NaCl;
In tetrahydrofuran C6H5Mg is reacted with Na; poured into satd. soln. of NaCl; extrn. with THF; removing solvent in vac., stirring with CHCl3;
In not given organic layer is evapd.; residue freeing from biphenyl by extrn. with CHCl3; recrystn. from ether;
boron trifluoride
7637-07-2

boron trifluoride

sodium carbonate
497-19-8

sodium carbonate

phenylmagnesium bromide
100-58-3

phenylmagnesium bromide

sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

Conditions
ConditionsYield
In diethyl ether; water distilling off the ether, adding H2O and calcd. amt. of Na2CO3;
In diethyl ether; water distilling off the ether, adding H2O and calcd. amt. of Na2CO3;
sodium
7440-23-5

sodium

boron trichloride
10294-34-5

boron trichloride

chlorobenzene
108-90-7

chlorobenzene

sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

Conditions
ConditionsYield
With hydrogenchloride In xylene below 30°C; reaction mixture pured into ice, organic layer separated, washed with water, aqueous layers are neutralized with 6N HCl;
sodium methylate
124-41-4

sodium methylate

trifluoroborane diethyl ether
109-63-7

trifluoroborane diethyl ether

phenylmagnesium bromide
100-58-3

phenylmagnesium bromide

sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

Conditions
ConditionsYield
With ammonium salt
trifluoroborane diethyl ether
109-63-7

trifluoroborane diethyl ether

phenylmagnesium bromide
100-58-3

phenylmagnesium bromide

sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

Conditions
ConditionsYield
With sodium carbonate; sodium chloride In diethyl ether water cooling, stirring, adding the BF3*(C2H5)2O soln. drop by drop, evapn. of solvent, taking up the residue with water; precipitation of Mg by adding of Na2CO3, saturation with NaCl, extrn. in Soxlet-equipment with ether;55-60
With Na2CO3; NaCl In diethyl ether water cooling, stirring, adding the BF3*(C2H5)2O soln. drop by drop, evapn. of solvent, taking up the residue with water; precipitation of Mg by adding of Na2CO3, saturation with NaCl, extrn. in Soxlet-equipment with ether;55-60
ammonium tetraphenylborate
14637-34-4

ammonium tetraphenylborate

sodium hydroxide
1310-73-2

sodium hydroxide

A

ammonia
7664-41-7

ammonia

B

sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

Conditions
ConditionsYield
In water little excess of NaOH, boiling;
In water little excess of NaOH, boiling;
sodium tetrafluoroborate
13755-29-8

sodium tetrafluoroborate

phenylmagnesium bromide
100-58-3

phenylmagnesium bromide

sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

Conditions
ConditionsYield
In diethyl ether heating on water bath;
With sodium chloride In diethyl ether; water 2 h stirring, addn. of reaction mixture to a satd. aq. NaCl soln.; extrn. the aq. layer with ether two times, evapn. in vac.; recrystn. in ether at 0°C;
In diethyl ether heating on water bath;
With NaCl In diethyl ether; water 2 h stirring, addn. of reaction mixture to a satd. aq. NaCl soln.; extrn. the aq. layer with ether two times, evapn. in vac.; recrystn. in ether at 0°C;
tris(2-methoxyethyl)borate
14983-42-7

tris(2-methoxyethyl)borate

sodium carbonate
497-19-8

sodium carbonate

phenylmagnesium bromide
100-58-3

phenylmagnesium bromide

sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

Conditions
ConditionsYield
In water converted to the ammonium salt with NH4Cl solution (after removing the biaryls with benzene) and is then reconverted;
phenylmagnesium chloride
100-59-4

phenylmagnesium chloride

sodium carbonate
497-19-8

sodium carbonate

tris(2-(2-methoxyethoxy)ethyl) borate
6378-62-7

tris(2-(2-methoxyethoxy)ethyl) borate

sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

Conditions
ConditionsYield
In water converted to the ammonium salt with NH4Cl solution (after removing the biaryls with benzene) and is then reconverted;
sodium methylate
124-41-4

sodium methylate

ammonium tetraphenylborate
14637-34-4

ammonium tetraphenylborate

sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

Conditions
ConditionsYield
In methanol refluxed equimolar amts. of educts under N2, solvent is subsequently evapd. and residue crystd. from ether; recrystn. from CHCl3;
potassium tetraphenylborate
3244-41-5

potassium tetraphenylborate

sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

Conditions
ConditionsYield
In acetone with cation-exchanger called Levatit S 100 or Permutit RS;
In water; acetone passing the soln. through a Na form cation exchanger;
In water; acetone passing the soln. through a Na form KU-2 resin cation exchanger;
In acetone with cation-exchanger called Levatit S 100 or Permutit RS;
diphenylboronchloride
3677-81-4

diphenylboronchloride

sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

Conditions
ConditionsYield
With sodium In 1,2-dimethoxyethane byproducts: NaCl; Sonication; allowed to react with 2 equivs. of Na in DME with ultrasonic promotion;
bromobenzene
108-86-1

bromobenzene

sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

Conditions
ConditionsYield
Stage #1: bromobenzene With magnesium In diethyl ether Reflux;
Stage #2: With sodium tetrafluoroborate In diethyl ether for 48h;
sodium tetrafluoroborate
13755-29-8

sodium tetrafluoroborate

phenyl halide

phenyl halide

sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

Conditions
ConditionsYield
Stage #1: sodium tetrafluoroborate With magnesium In tetrahydrofuran; ethylene dibromide for 0.0166667h; Sealed tube; Inert atmosphere; Schlenk technique;
Stage #2: phenyl halide In tetrahydrofuran; ethylene dibromide at 20℃; for 12h; Sealed tube; Inert atmosphere; Schlenk technique;
sodium tetrafluoroborate
13755-29-8

sodium tetrafluoroborate

bromobenzene
108-86-1

bromobenzene

sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

Conditions
ConditionsYield
With magnesium In tetrahydrofuran at 0 - 20℃; for 12h; Inert atmosphere;
2,2-diiodo-5,6-dimethyl-1,3-dihydro-2-telluraindene
127797-34-6

2,2-diiodo-5,6-dimethyl-1,3-dihydro-2-telluraindene

sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

2-phenyl-2-iodo-5,6-dimethyl-1,3-dihydro-2-telluraindene
127797-35-7

2-phenyl-2-iodo-5,6-dimethyl-1,3-dihydro-2-telluraindene

Conditions
ConditionsYield
In ethanol for 0.25h; Heating;100%
sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

tetraisopropylphosphonium iodide
92209-07-9

tetraisopropylphosphonium iodide

tetraisopropylphosphonium tetraphenylborate
92209-04-6

tetraisopropylphosphonium tetraphenylborate

Conditions
ConditionsYield
In methanol at 52℃; the structure of the product was investigated by X-ray spectroscopy;100%
1-methyl-1H-imidazole
616-47-7

1-methyl-1H-imidazole

2,4,6-trichloropyrimidine
3764-01-0

2,4,6-trichloropyrimidine

sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

1,1',1''-(pyrimidin-2,4,6-triyl)-tris-3-methylimidazolium tris(tetraphenylborate)

1,1',1''-(pyrimidin-2,4,6-triyl)-tris-3-methylimidazolium tris(tetraphenylborate)

Conditions
ConditionsYield
In ethyl acetate Ambient temperature;100%
2,4,6-trichloropyrimidine
3764-01-0

2,4,6-trichloropyrimidine

sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

1,1',1''-(pyrimidin-2,4,6-triyl)-tris-4-dimethylaminopyridinium tris(tetraphenylborate)

1,1',1''-(pyrimidin-2,4,6-triyl)-tris-4-dimethylaminopyridinium tris(tetraphenylborate)

Conditions
ConditionsYield
In ethyl acetate Ambient temperature;100%
In ethyl acetate100%
sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

5-tert-Butyl-2-chloro-3,3-diphenyl-1-trimethylsilanyl-2,3-dihydro-1H-[1,2,3]azadiphosphol-3-ium; chloride

5-tert-Butyl-2-chloro-3,3-diphenyl-1-trimethylsilanyl-2,3-dihydro-1H-[1,2,3]azadiphosphol-3-ium; chloride

C24H20B(1-)*C21H29ClNP2Si(1+)

C24H20B(1-)*C21H29ClNP2Si(1+)

Conditions
ConditionsYield
In dichloromethane -40 deg C. then room temp., 1 h;100%
m-bromobenzoic acid
585-76-2

m-bromobenzoic acid

sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

3-phenylbenzoic acid
716-76-7

3-phenylbenzoic acid

Conditions
ConditionsYield
With sodium carbonate; palladium dichloride In water at 100℃; for 4h; other reagent, temperature, reaction time;100%
With palladium on activated charcoal; sodium carbonate for 3h; Heating;90%
With palladium on activated charcoal; sodium carbonate at 20℃; for 24h; Product distribution; influence of catalyst, reaction time, temperature;61%
With palladium diacetate; sodium hydroxide In water at 25℃; for 2h; Product distribution; other reagent, reaction time, temperature;100 % Chromat.
With sodium carbonate; palladium on activated charcoal In water for 1h; Suzuki reaction; Heating;97 % Chromat.
sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

n-octanoic acid chloride
111-64-8

n-octanoic acid chloride

n-octanophenone
1674-37-9

n-octanophenone

Conditions
ConditionsYield
With palladium diacetate; sodium carbonate In acetone at 20℃; for 0.0833333h;100%
With sodium carbonate; palladium diacetate In acetone at 20℃; for 0.0833333h; Suzuki reaction;98%
sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

1,4,7-tri(4-hexynyl)-1,4,7-triazacyclononane
330804-78-9

1,4,7-tri(4-hexynyl)-1,4,7-triazacyclononane

C24H39N3*C24H20B(1-)*Na(1+)

C24H39N3*C24H20B(1-)*Na(1+)

Conditions
ConditionsYield
In methanol100%
sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

[Ru(bis(N-methylimidazol-2-yl)methane))(CO)2Cl2]

[Ru(bis(N-methylimidazol-2-yl)methane))(CO)2Cl2]

C24H20B(1-)*C9H12N4*H(1+)

C24H20B(1-)*C9H12N4*H(1+)

Conditions
ConditionsYield
With trifluoroacetic acid100%
sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

diphenyl acetylene
501-65-5

diphenyl acetylene

Triphenylethylene
58-72-0

Triphenylethylene

Conditions
ConditionsYield
With water; acetic acid; bis-triphenylphosphine-palladium(II) chloride at 20℃; for 6h;100%
With bis-triphenylphosphine-palladium(II) chloride; water; acetic acid at 20℃; for 6h; Catalytic behavior; Reagent/catalyst; Temperature; Inert atmosphere; Sealed tube;94%
Conditions
ConditionsYield
In 1,2-dimethoxyethane Irradiation (UV/VIS); under Ar; mole ratio NaBPh4 : CuI = 1 : 1; irradn. (254 nm) for 1 h gave deposition of Cu; deposit sepd., washed with acetone and water, and dried in vac. to give pure Cu;100%
Conditions
ConditionsYield
In 1,2-dimethoxyethane Irradiation (UV/VIS); under Ar; mole ratios NaBPh4 : Zn(acac)2 : Cu(acac)2 = 20 : 7 : 3; irradn. (254 nm) for 18 h gave deposition only of Cu;A 100%
B 0%
sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

zinc(II) iodide

zinc(II) iodide

Conditions
ConditionsYield
In 1,2-dimethoxyethane Irradiation (UV/VIS); under Ar; mole ratio NaBPh4 : ZnI2 = 2 : 1; irradn. (254 nm) for 2 h gave deposition of Zn; deposit sepd., washed with acetone and water, and dried in vac. to give pure Zn;100%
trans-acetonitrile-bis(1,2-bis(dimethylphosphino)ethane)chloroiron(II) chloride
110005-53-3

trans-acetonitrile-bis(1,2-bis(dimethylphosphino)ethane)chloroiron(II) chloride

sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

trans-{iron(II)Cl(MeNC)(Me2PCH2CH2PMe2)2}{BPh4}
110022-38-3

trans-{iron(II)Cl(MeNC)(Me2PCH2CH2PMe2)2}{BPh4}

Conditions
ConditionsYield
In acetonitrile 1 equiv. NaBPh4 added to a soln. of (FeCl(NCMe)(dmpe)2)Cl;; filtration; elem. anal.;;100%
ReO2(1+)*6C5H5N*ReO4(1-)=ReO2(C5H5N)4ReO4*2C5H5N

ReO2(1+)*6C5H5N*ReO4(1-)=ReO2(C5H5N)4ReO4*2C5H5N

sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

ReO2(C5H5N)4(1+)*B(C6H5)4(1-)
84417-09-4

ReO2(C5H5N)4(1+)*B(C6H5)4(1-)

Conditions
ConditionsYield
With pyridine In acetone NaBPh4 in acetone was added to a soln. of Re-compound in pyridine with 2 drops of pyridine;; H2O was added, ppt. was collected, dried, recrystd. from acetone-ether;elem. anal.;;100%
bis(triphenylphosphine)iridium(I) carbonyl chloride
15318-31-7, 14871-41-1, 59246-46-7

bis(triphenylphosphine)iridium(I) carbonyl chloride

sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

[Ir(CO)3(triphenylphosphine)2]BPh4
59809-88-0

[Ir(CO)3(triphenylphosphine)2]BPh4

Conditions
ConditionsYield
With carbon monoxide In tetrahydrofuran a portion of NaBPh4 was added to a soln. of Ir-complex in THF that has been satd. with CO, mixt. was stirred for 30 min; THF was removed, residue extd. with CH2Cl2, filtered into a Schlenk flask, stirred under CO for 15 min, pentane was added to form a ppt. which can be recrystd. from CH2Cl2-pentane;100%
(trichlorostannyl)hexakis(tert-butyl isocyanide)molibdenum(II) hexafluorophosphate

(trichlorostannyl)hexakis(tert-butyl isocyanide)molibdenum(II) hexafluorophosphate

sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

Mo(CNC(CH3)3)7(2+)*2B(C6H5)4(1-)=[Mo(CNC(CH3)3)7][B(C6H5)4]2

Mo(CNC(CH3)3)7(2+)*2B(C6H5)4(1-)=[Mo(CNC(CH3)3)7][B(C6H5)4]2

Conditions
ConditionsYield
In methanol stirred for 4 h, addn. of Na(BPh4);100%
cis,trans-[dicarbonylbis(trimethylphosphine)(methyl)iodoiron(II)]
33542-07-3

cis,trans-[dicarbonylbis(trimethylphosphine)(methyl)iodoiron(II)]

sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

(CO)2CH3Fe(P(CH3)3)2P(CH3)2C6H5(1+)*B(C6H5)4(1-)
80700-08-9, 80736-08-9

(CO)2CH3Fe(P(CH3)3)2P(CH3)2C6H5(1+)*B(C6H5)4(1-)

Conditions
ConditionsYield
In methanol at -30°C;100%
[Ru3(C10H15)3(μ-H)3(μ3-η(3):η(3)-benzene)](BF4)2

[Ru3(C10H15)3(μ-H)3(μ3-η(3):η(3)-benzene)](BF4)2

sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

[Ru3(C10H15)3(μ-H)3(μ3-η(3):η(3)-benzene)](B(C6H5)4)2*2acetone

[Ru3(C10H15)3(μ-H)3(μ3-η(3):η(3)-benzene)](B(C6H5)4)2*2acetone

Conditions
ConditionsYield
In methanol room temperature;100%
pyridine-2-thione
2637-34-5

pyridine-2-thione

copper(ll) sulfate pentahydrate

copper(ll) sulfate pentahydrate

sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

Cu(1+)*2SC5H4NH*B(C6H5)4(1-)*H2O = [Cu(SC5H4NH)2]B(C6H5)4*H2O

Cu(1+)*2SC5H4NH*B(C6H5)4(1-)*H2O = [Cu(SC5H4NH)2]B(C6H5)4*H2O

Conditions
ConditionsYield
In methanol; water (air); addn. of the ligand in MeOH to a soln. of the Cu salt in H2O, stirring (5 min), filtration, addn. of aq. NaBPh4, stirring (10 min); filtration, washing (H2O), drying (vac.), stirring with Et2O, filtration, repeating this extn., drying (vac.); elem.anal.;100%
Pd(P(C6H5)3)2(Cl)CH2CC(C6H5)
166543-59-5, 257300-22-4

Pd(P(C6H5)3)2(Cl)CH2CC(C6H5)

PdCl(P(C6H5)3)2(C(C6H5)CCH2)
166543-59-5, 257300-22-4

PdCl(P(C6H5)3)2(C(C6H5)CCH2)

sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

Pd(P(C6H5)3)2(CH2CHCHC6H5)(1+)*B(C6H5)4(1-)=[Pd(P(C6H5)3)2(CH2CHCHC6H5)]B(C6H5)4
166939-88-4

Pd(P(C6H5)3)2(CH2CHCHC6H5)(1+)*B(C6H5)4(1-)=[Pd(P(C6H5)3)2(CH2CHCHC6H5)]B(C6H5)4

Conditions
ConditionsYield
In chloroform-d1; [(2)H6]acetone stoich. amts.; room temp., 5 min.; (1)H NMR monitoring;100%
PdCl(P(C6H5)3)2(CH2CCSi(CH3)3)
100228-92-0

PdCl(P(C6H5)3)2(CH2CCSi(CH3)3)

sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

Pd(P(C6H5)3)2(CH2CHCHSi(CH3)3)(1+)*B(C6H5)4(1-)=[Pd(P(C6H5)3)2(CH2CHCHSi(CH3)3)]B(C6H5)4
166734-87-8

Pd(P(C6H5)3)2(CH2CHCHSi(CH3)3)(1+)*B(C6H5)4(1-)=[Pd(P(C6H5)3)2(CH2CHCHSi(CH3)3)]B(C6H5)4

Conditions
ConditionsYield
In chloroform-d1; [(2)H6]acetone stoich. amts.; room temp., 5 min.; (1)H NMR monitoring;100%
ethene
74-85-1

ethene

[1,2-bis(diisopropylphosphino)ethane]chloro(pentamethylcyclopentadienyl)ruthenium(II)
171511-86-7

[1,2-bis(diisopropylphosphino)ethane]chloro(pentamethylcyclopentadienyl)ruthenium(II)

sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

((CH3)5C5)Ru(C2H4)((((CH3)2CH)2PCH2)2)(1+)*B(C6H5)4(1-)=[((CH3)5C5)Ru(C2H4)((((CH3)2CH)2PCH2)2)][B(C6H5)4]
181778-61-0

((CH3)5C5)Ru(C2H4)((((CH3)2CH)2PCH2)2)(1+)*B(C6H5)4(1-)=[((CH3)5C5)Ru(C2H4)((((CH3)2CH)2PCH2)2)][B(C6H5)4]

Conditions
ConditionsYield
In methanol C2H4-atmosphere; stirring (10 min); filtering, washing (EtOH, petroleum ether), drying (vac.); elem. anal.;100%
tetrakis(pyridine)platinum(II) chloride trihydrate

tetrakis(pyridine)platinum(II) chloride trihydrate

sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

[Pt(C5H5N)4](2+)*2B(C6H5)4(1-)=[Pt(C5H5N)4][B(C6H5)4]2

[Pt(C5H5N)4](2+)*2B(C6H5)4(1-)=[Pt(C5H5N)4][B(C6H5)4]2

Conditions
ConditionsYield
In water stirring (1 h, room temp.); washing (H2O, iPrOH, Et2O), drying (vac.);100%
tris([tri(tert-butyl)phosphine]gold(I))oxonium tetrafluoroborate

tris([tri(tert-butyl)phosphine]gold(I))oxonium tetrafluoroborate

sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

phenyl[tri(tert-butyl)phosphine]gold(I)
172532-09-1

phenyl[tri(tert-butyl)phosphine]gold(I)

Conditions
ConditionsYield
In ethanol byproducts: NaBF4, PhBO; N2-atmosphere; excess NaBPh4, stirring at room temp. in absence of direct light for 15 d (crystn.);100%
dichloro(benzene)ruthenium(II) dimer
37366-09-9

dichloro(benzene)ruthenium(II) dimer

cyclopentadienylthallium(I)

cyclopentadienylthallium(I)

sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

(η(6)-benzene)(η(5)-2,4-cyclopentadien-1-yl)ruthenium tetraphenylborate
72804-54-7

(η(6)-benzene)(η(5)-2,4-cyclopentadien-1-yl)ruthenium tetraphenylborate

Conditions
ConditionsYield
In water; acetonitrile N2-atmosphere; stirring Ru-complex with excess TlCp (in dark, in MeCN, 5h), filtration, addn. of H2O, filtration, addn. of excess NaBPh4 (in H2 O), stirring for 30 min; pptn. on concn., filtration, washing (H2O), drying (vac.); can be recrystallized (MeCN/Et2O); elem. anal.;100%
dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer

dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer

P,P,P'-tris[(+)-9-phenyldeltacyclan-8-yl]-1,2-bis(phosphanyl)benzene

P,P,P'-tris[(+)-9-phenyldeltacyclan-8-yl]-1,2-bis(phosphanyl)benzene

sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

[Cp*Rh(P,P,P'-tris[(+)-9-phenyldeltacyclan-8-yl]-1,2-bis(phosphanyl)benzene)Cl]BPh4

[Cp*Rh(P,P,P'-tris[(+)-9-phenyldeltacyclan-8-yl]-1,2-bis(phosphanyl)benzene)Cl]BPh4

Conditions
ConditionsYield
In methanol under N2 atm. soln. ligand and ((Cp*RhCl)2(μ-Cl))2 in MeOH was stirred at room temp. for 30 min, NaBPh4 was added and stirred for 2 h; solvent was removed in vacuo, residue was dissolved in CH2Cl2 and filtered through Celite, solvent was removed; elem. anal.;100%
(η(5)-C5H5)2Ti(η(2)-CO(i-Pr))I
66320-81-8

(η(5)-C5H5)2Ti(η(2)-CO(i-Pr))I

sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

ethenetetracarbonitrile
670-54-2

ethenetetracarbonitrile

(η(5)-C5H5)2Ti(η(2)-CO(i-Pr))(NCBPh3)
179097-41-7

(η(5)-C5H5)2Ti(η(2)-CO(i-Pr))(NCBPh3)

Conditions
ConditionsYield
In methanol Ar-atmosphere; mixing equimolar amts. of Ti-complex and TCNE, addn. of 2equiv. NaBPh4;100%
sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

N,N'-dimethylimidazolium-2-carboxylate
536755-29-0

N,N'-dimethylimidazolium-2-carboxylate

1,3-dimethylimidazolium tetraphenylborate
478081-95-7

1,3-dimethylimidazolium tetraphenylborate

Conditions
ConditionsYield
With water In tetrahydrofuran Inert atmosphere;100%
sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

1,3-bis(2,6-diisopropylphenyl)imidazolinium-2-carboxylate

1,3-bis(2,6-diisopropylphenyl)imidazolinium-2-carboxylate

1,3-bis(2,6-diisopropylphenyl)-imidazolium tetraphenylborate

1,3-bis(2,6-diisopropylphenyl)-imidazolium tetraphenylborate

Conditions
ConditionsYield
With water In tetrahydrofuran Inert atmosphere;100%

Sodium tetraphenylboron Chemical Properties

 Empirical Formula: C24H20BNa
Molecular Weight: 342.2164 
EINECS: 205-605-5
Melting point: 300 °C
Storage tempreture: 2-8 °C
Solubility: Soluble in water
Sensitive: Light sensitive
Appearance: White powder
Structure of Sodium tetraphenylboron (CAS NO.143-66-8):
                          
IUPAC Name: Sodium tetraphenylboranuide
Canonical SMILES: [B-](C1=CC=CC=C1)(C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4.[Na+]
InChI: InChI=1S/C24H20B.Na/c1-5-13-21(14-6-1)25(22-15-7-2-8-16-22,23-17-9-3-10-18-23)24-19-11-4-12-20-24;/h1-20H;/q-1;+1
InChIKey: HFSRCEJMTLMDLI-UHFFFAOYSA-N
Product Category of Sodium tetraphenylboron (CAS NO.143-66-8): Boron compounds;Organometallics;Na (Sodium) Compounds (excluding simple sodium salts);Analytical Chemistry;Ion Association;Tetraphenylborates;Typical Metal Compounds

Sodium tetraphenylboron Toxicity Data With Reference

 

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
rat LD50 oral 288mg/kg (288mg/kg) BEHAVIORAL: MUSCLE WEAKNESS National Technical Information Service. Vol. OTS0555250,

Sodium tetraphenylboron (CAS NO.143-66-8) hasn't been listed as a carcinogen by NTP, IARC, ACGIH, or CA Prop 65. And the toxicological properties have not been fully investigated. You can see actual entry in RTECS for complete information.

Sodium tetraphenylboron Safety Profile

Hazard Codes: HarmfulXn,IrritantXi
Risk Statements: 22-36/37/38 
R22:Harmful if swallowed. 
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 26-36/37-36 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36/37:Wear suitable protective clothing and gloves. 
S36:Wear suitable protective clothing.

Sodium tetraphenylboron Specification

  (R)-2-Amino-3-methoxypropanoic acid hydrochloride , its cas register number is Sodium tetraphenylborate ; Tetraphenylboron sodium ; and Tetraphenyl boron sodium salt . It is hazardous, so the first aid measures and others should be known. Such as: When on the skin: first, should flush skin with plenty of water immediately for at least 15 minutes while removing contaminated clothing. Secondly, get medical aid. Or in the eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Then get medical aid soon. While, it's inhaled: Remove from exposure and move to fresh air immediately. Give artificial respiration while not breathing. When breathing is difficult, give oxygen. And as soon as to get medical aid. Then you have the ingesting of the product: Wash mouth out with water, and get medical aid immediately. Notes to physician: Treat supportively and symptomatically.
In addition, Sodium tetraphenylboron (CAS NO.143-66-8) is light sensitive. It is not compatible with strong oxidizing agents, and you must not take it with incompatible materials, light, excess heat. And also prevent it to broken down into hazardous decomposition products: Carbon monoxide, carbon dioxide, metallic oxides, boron oxides.

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