sodium tetraphenyl borate
Conditions | Yield |
---|---|
With boron trifluoride diethyl etherate anschliessendes Behandeln mit H2O und NaCl; | |
With sodium tetrafluoroborate; diethyl ether anschliessendes Behandeln mit wss.NaCl; |
Conditions | Yield |
---|---|
With sodium tetraethylborate In xylene Heating; |
Conditions | Yield |
---|---|
In acetone filtration, evapn. of filtrate; | |
In acetone filtration, evapn. of filtrate; |
trifluoroborane diethyl ether
phenylmagnesium bromide
sodium chloride
sodium tetraphenyl borate
Conditions | Yield |
---|---|
extrn. with dry acetone; | |
In diethyl ether; water ether layer is evapd.; residue dissolved in water; satd. with NaCl; | |
extrn. with dry acetone; | |
In diethyl ether; water ether layer is evapd.; residue dissolved in water; satd. with NaCl; |
sodium tetrafluoroborate
phenylmagnesium bromide
sodium chloride
sodium tetraphenyl borate
Conditions | Yield |
---|---|
In tetrahydrofuran; water THF layer is again treated with aq. NaCl; | |
In tetrahydrofuran C6H5Mg is reacted with Na; poured into satd. soln. of NaCl; extrn. with THF; removing solvent in vac., stirring with CHCl3; | |
In not given organic layer is evapd.; residue freeing from biphenyl by extrn. with CHCl3; recrystn. from ether; |
boron trifluoride
sodium carbonate
phenylmagnesium bromide
sodium tetraphenyl borate
Conditions | Yield |
---|---|
In diethyl ether; water distilling off the ether, adding H2O and calcd. amt. of Na2CO3; | |
In diethyl ether; water distilling off the ether, adding H2O and calcd. amt. of Na2CO3; |
sodium
boron trichloride
chlorobenzene
sodium tetraphenyl borate
Conditions | Yield |
---|---|
With hydrogenchloride In xylene below 30°C; reaction mixture pured into ice, organic layer separated, washed with water, aqueous layers are neutralized with 6N HCl; |
sodium methylate
trifluoroborane diethyl ether
phenylmagnesium bromide
sodium tetraphenyl borate
Conditions | Yield |
---|---|
With ammonium salt |
trifluoroborane diethyl ether
phenylmagnesium bromide
sodium tetraphenyl borate
Conditions | Yield |
---|---|
With sodium carbonate; sodium chloride In diethyl ether water cooling, stirring, adding the BF3*(C2H5)2O soln. drop by drop, evapn. of solvent, taking up the residue with water; precipitation of Mg by adding of Na2CO3, saturation with NaCl, extrn. in Soxlet-equipment with ether; | 55-60 |
With Na2CO3; NaCl In diethyl ether water cooling, stirring, adding the BF3*(C2H5)2O soln. drop by drop, evapn. of solvent, taking up the residue with water; precipitation of Mg by adding of Na2CO3, saturation with NaCl, extrn. in Soxlet-equipment with ether; | 55-60 |
ammonium tetraphenylborate
sodium hydroxide
A
ammonia
B
sodium tetraphenyl borate
Conditions | Yield |
---|---|
In water little excess of NaOH, boiling; | |
In water little excess of NaOH, boiling; |
sodium tetrafluoroborate
phenylmagnesium bromide
sodium tetraphenyl borate
Conditions | Yield |
---|---|
In diethyl ether heating on water bath; | |
With sodium chloride In diethyl ether; water 2 h stirring, addn. of reaction mixture to a satd. aq. NaCl soln.; extrn. the aq. layer with ether two times, evapn. in vac.; recrystn. in ether at 0°C; | |
In diethyl ether heating on water bath; | |
With NaCl In diethyl ether; water 2 h stirring, addn. of reaction mixture to a satd. aq. NaCl soln.; extrn. the aq. layer with ether two times, evapn. in vac.; recrystn. in ether at 0°C; |
tris(2-methoxyethyl)borate
sodium carbonate
phenylmagnesium bromide
sodium tetraphenyl borate
Conditions | Yield |
---|---|
In water converted to the ammonium salt with NH4Cl solution (after removing the biaryls with benzene) and is then reconverted; |
phenylmagnesium chloride
sodium carbonate
tris(2-(2-methoxyethoxy)ethyl) borate
sodium tetraphenyl borate
Conditions | Yield |
---|---|
In water converted to the ammonium salt with NH4Cl solution (after removing the biaryls with benzene) and is then reconverted; |
Conditions | Yield |
---|---|
In methanol refluxed equimolar amts. of educts under N2, solvent is subsequently evapd. and residue crystd. from ether; recrystn. from CHCl3; |
Conditions | Yield |
---|---|
In acetone with cation-exchanger called Levatit S 100 or Permutit RS; | |
In water; acetone passing the soln. through a Na form cation exchanger; | |
In water; acetone passing the soln. through a Na form KU-2 resin cation exchanger; | |
In acetone with cation-exchanger called Levatit S 100 or Permutit RS; |
Conditions | Yield |
---|---|
With sodium In 1,2-dimethoxyethane byproducts: NaCl; Sonication; allowed to react with 2 equivs. of Na in DME with ultrasonic promotion; |
Conditions | Yield |
---|---|
Stage #1: bromobenzene With magnesium In diethyl ether Reflux; Stage #2: With sodium tetrafluoroborate In diethyl ether for 48h; |
Conditions | Yield |
---|---|
Stage #1: sodium tetrafluoroborate With magnesium In tetrahydrofuran; ethylene dibromide for 0.0166667h; Sealed tube; Inert atmosphere; Schlenk technique; Stage #2: phenyl halide In tetrahydrofuran; ethylene dibromide at 20℃; for 12h; Sealed tube; Inert atmosphere; Schlenk technique; |
Conditions | Yield |
---|---|
With magnesium In tetrahydrofuran at 0 - 20℃; for 12h; Inert atmosphere; |
2,2-diiodo-5,6-dimethyl-1,3-dihydro-2-telluraindene
sodium tetraphenyl borate
2-phenyl-2-iodo-5,6-dimethyl-1,3-dihydro-2-telluraindene
Conditions | Yield |
---|---|
In ethanol for 0.25h; Heating; | 100% |
sodium tetraphenyl borate
tetraisopropylphosphonium iodide
tetraisopropylphosphonium tetraphenylborate
Conditions | Yield |
---|---|
In methanol at 52℃; the structure of the product was investigated by X-ray spectroscopy; | 100% |
1-methyl-1H-imidazole
2,4,6-trichloropyrimidine
sodium tetraphenyl borate
Conditions | Yield |
---|---|
In ethyl acetate Ambient temperature; | 100% |
Conditions | Yield |
---|---|
In ethyl acetate Ambient temperature; | 100% |
In ethyl acetate | 100% |
sodium tetraphenyl borate
Conditions | Yield |
---|---|
In dichloromethane -40 deg C. then room temp., 1 h; | 100% |
Conditions | Yield |
---|---|
With sodium carbonate; palladium dichloride In water at 100℃; for 4h; other reagent, temperature, reaction time; | 100% |
With palladium on activated charcoal; sodium carbonate for 3h; Heating; | 90% |
With palladium on activated charcoal; sodium carbonate at 20℃; for 24h; Product distribution; influence of catalyst, reaction time, temperature; | 61% |
With palladium diacetate; sodium hydroxide In water at 25℃; for 2h; Product distribution; other reagent, reaction time, temperature; | 100 % Chromat. |
With sodium carbonate; palladium on activated charcoal In water for 1h; Suzuki reaction; Heating; | 97 % Chromat. |
Conditions | Yield |
---|---|
With palladium diacetate; sodium carbonate In acetone at 20℃; for 0.0833333h; | 100% |
With sodium carbonate; palladium diacetate In acetone at 20℃; for 0.0833333h; Suzuki reaction; | 98% |
sodium tetraphenyl borate
1,4,7-tri(4-hexynyl)-1,4,7-triazacyclononane
Conditions | Yield |
---|---|
In methanol | 100% |
sodium tetraphenyl borate
Conditions | Yield |
---|---|
With trifluoroacetic acid | 100% |
Conditions | Yield |
---|---|
With water; acetic acid; bis-triphenylphosphine-palladium(II) chloride at 20℃; for 6h; | 100% |
With bis-triphenylphosphine-palladium(II) chloride; water; acetic acid at 20℃; for 6h; Catalytic behavior; Reagent/catalyst; Temperature; Inert atmosphere; Sealed tube; | 94% |
copper(l) iodide
sodium tetraphenyl borate
copper
Conditions | Yield |
---|---|
In 1,2-dimethoxyethane Irradiation (UV/VIS); under Ar; mole ratio NaBPh4 : CuI = 1 : 1; irradn. (254 nm) for 1 h gave deposition of Cu; deposit sepd., washed with acetone and water, and dried in vac. to give pure Cu; | 100% |
sodium tetraphenyl borate
copper(II) acetylacetonate
zinc(II) acetylacetonate
A
copper
B
zinc
Conditions | Yield |
---|---|
In 1,2-dimethoxyethane Irradiation (UV/VIS); under Ar; mole ratios NaBPh4 : Zn(acac)2 : Cu(acac)2 = 20 : 7 : 3; irradn. (254 nm) for 18 h gave deposition only of Cu; | A 100% B 0% |
Conditions | Yield |
---|---|
In 1,2-dimethoxyethane Irradiation (UV/VIS); under Ar; mole ratio NaBPh4 : ZnI2 = 2 : 1; irradn. (254 nm) for 2 h gave deposition of Zn; deposit sepd., washed with acetone and water, and dried in vac. to give pure Zn; | 100% |
trans-acetonitrile-bis(1,2-bis(dimethylphosphino)ethane)chloroiron(II) chloride
sodium tetraphenyl borate
trans-{iron(II)Cl(MeNC)(Me2PCH2CH2PMe2)2}{BPh4}
Conditions | Yield |
---|---|
In acetonitrile 1 equiv. NaBPh4 added to a soln. of (FeCl(NCMe)(dmpe)2)Cl;; filtration; elem. anal.;; | 100% |
sodium tetraphenyl borate
ReO2(C5H5N)4(1+)*B(C6H5)4(1-)
Conditions | Yield |
---|---|
With pyridine In acetone NaBPh4 in acetone was added to a soln. of Re-compound in pyridine with 2 drops of pyridine;; H2O was added, ppt. was collected, dried, recrystd. from acetone-ether;elem. anal.;; | 100% |
bis(triphenylphosphine)iridium(I) carbonyl chloride
sodium tetraphenyl borate
[Ir(CO)3(triphenylphosphine)2]BPh4
Conditions | Yield |
---|---|
With carbon monoxide In tetrahydrofuran a portion of NaBPh4 was added to a soln. of Ir-complex in THF that has been satd. with CO, mixt. was stirred for 30 min; THF was removed, residue extd. with CH2Cl2, filtered into a Schlenk flask, stirred under CO for 15 min, pentane was added to form a ppt. which can be recrystd. from CH2Cl2-pentane; | 100% |
sodium tetraphenyl borate
Conditions | Yield |
---|---|
In methanol stirred for 4 h, addn. of Na(BPh4); | 100% |
cis,trans-[dicarbonylbis(trimethylphosphine)(methyl)iodoiron(II)]
sodium tetraphenyl borate
Dimethyl(phenyl)phosphine
(CO)2CH3Fe(P(CH3)3)2P(CH3)2C6H5(1+)*B(C6H5)4(1-)
Conditions | Yield |
---|---|
In methanol at -30°C; | 100% |
sodium tetraphenyl borate
Conditions | Yield |
---|---|
In methanol room temperature; | 100% |
Conditions | Yield |
---|---|
In methanol; water (air); addn. of the ligand in MeOH to a soln. of the Cu salt in H2O, stirring (5 min), filtration, addn. of aq. NaBPh4, stirring (10 min); filtration, washing (H2O), drying (vac.), stirring with Et2O, filtration, repeating this extn., drying (vac.); elem.anal.; | 100% |
Pd(P(C6H5)3)2(Cl)CH2CC(C6H5)
PdCl(P(C6H5)3)2(C(C6H5)CCH2)
sodium tetraphenyl borate
Pd(P(C6H5)3)2(CH2CHCHC6H5)(1+)*B(C6H5)4(1-)=[Pd(P(C6H5)3)2(CH2CHCHC6H5)]B(C6H5)4
Conditions | Yield |
---|---|
In chloroform-d1; [(2)H6]acetone stoich. amts.; room temp., 5 min.; (1)H NMR monitoring; | 100% |
PdCl(P(C6H5)3)2(CH2CCSi(CH3)3)
sodium tetraphenyl borate
Pd(P(C6H5)3)2(CH2CHCHSi(CH3)3)(1+)*B(C6H5)4(1-)=[Pd(P(C6H5)3)2(CH2CHCHSi(CH3)3)]B(C6H5)4
Conditions | Yield |
---|---|
In chloroform-d1; [(2)H6]acetone stoich. amts.; room temp., 5 min.; (1)H NMR monitoring; | 100% |
ethene
[1,2-bis(diisopropylphosphino)ethane]chloro(pentamethylcyclopentadienyl)ruthenium(II)
sodium tetraphenyl borate
((CH3)5C5)Ru(C2H4)((((CH3)2CH)2PCH2)2)(1+)*B(C6H5)4(1-)=[((CH3)5C5)Ru(C2H4)((((CH3)2CH)2PCH2)2)][B(C6H5)4]
Conditions | Yield |
---|---|
In methanol C2H4-atmosphere; stirring (10 min); filtering, washing (EtOH, petroleum ether), drying (vac.); elem. anal.; | 100% |
sodium tetraphenyl borate
Conditions | Yield |
---|---|
In water stirring (1 h, room temp.); washing (H2O, iPrOH, Et2O), drying (vac.); | 100% |
sodium tetraphenyl borate
phenyl[tri(tert-butyl)phosphine]gold(I)
Conditions | Yield |
---|---|
In ethanol byproducts: NaBF4, PhBO; N2-atmosphere; excess NaBPh4, stirring at room temp. in absence of direct light for 15 d (crystn.); | 100% |
dichloro(benzene)ruthenium(II) dimer
sodium tetraphenyl borate
(η(6)-benzene)(η(5)-2,4-cyclopentadien-1-yl)ruthenium tetraphenylborate
Conditions | Yield |
---|---|
In water; acetonitrile N2-atmosphere; stirring Ru-complex with excess TlCp (in dark, in MeCN, 5h), filtration, addn. of H2O, filtration, addn. of excess NaBPh4 (in H2 O), stirring for 30 min; pptn. on concn., filtration, washing (H2O), drying (vac.); can be recrystallized (MeCN/Et2O); elem. anal.; | 100% |
sodium tetraphenyl borate
Conditions | Yield |
---|---|
In methanol under N2 atm. soln. ligand and ((Cp*RhCl)2(μ-Cl))2 in MeOH was stirred at room temp. for 30 min, NaBPh4 was added and stirred for 2 h; solvent was removed in vacuo, residue was dissolved in CH2Cl2 and filtered through Celite, solvent was removed; elem. anal.; | 100% |
(η(5)-C5H5)2Ti(η(2)-CO(i-Pr))I
sodium tetraphenyl borate
ethenetetracarbonitrile
(η(5)-C5H5)2Ti(η(2)-CO(i-Pr))(NCBPh3)
Conditions | Yield |
---|---|
In methanol Ar-atmosphere; mixing equimolar amts. of Ti-complex and TCNE, addn. of 2equiv. NaBPh4; | 100% |
sodium tetraphenyl borate
N,N'-dimethylimidazolium-2-carboxylate
1,3-dimethylimidazolium tetraphenylborate
Conditions | Yield |
---|---|
With water In tetrahydrofuran Inert atmosphere; | 100% |
sodium tetraphenyl borate
Conditions | Yield |
---|---|
With water In tetrahydrofuran Inert atmosphere; | 100% |
Empirical Formula: C24H20BNa
Molecular Weight: 342.2164
EINECS: 205-605-5
Melting point: 300 °C
Storage tempreture: 2-8 °C
Solubility: Soluble in water
Sensitive: Light sensitive
Appearance: White powder
Structure of Sodium tetraphenylboron (CAS NO.143-66-8):
IUPAC Name: Sodium tetraphenylboranuide
Canonical SMILES: [B-](C1=CC=CC=C1)(C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4.[Na+]
InChI: InChI=1S/C24H20B.Na/c1-5-13-21(14-6-1)25(22-15-7-2-8-16-22,23-17-9-3-10-18-23)24-19-11-4-12-20-24;/h1-20H;/q-1;+1
InChIKey: HFSRCEJMTLMDLI-UHFFFAOYSA-N
Product Category of Sodium tetraphenylboron (CAS NO.143-66-8): Boron compounds;Organometallics;Na (Sodium) Compounds (excluding simple sodium salts);Analytical Chemistry;Ion Association;Tetraphenylborates;Typical Metal Compounds
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
rat | LD50 | oral | 288mg/kg (288mg/kg) | BEHAVIORAL: MUSCLE WEAKNESS | National Technical Information Service. Vol. OTS0555250, |
Sodium tetraphenylboron (CAS NO.143-66-8) hasn't been listed as a carcinogen by NTP, IARC, ACGIH, or CA Prop 65. And the toxicological properties have not been fully investigated. You can see actual entry in RTECS for complete information.
Hazard Codes: Xn,Xi
Risk Statements: 22-36/37/38
R22:Harmful if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 26-36/37-36
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37:Wear suitable protective clothing and gloves.
S36:Wear suitable protective clothing.
(R)-2-Amino-3-methoxypropanoic acid hydrochloride , its cas register number is Sodium tetraphenylborate ; Tetraphenylboron sodium ; and Tetraphenyl boron sodium salt . It is hazardous, so the first aid measures and others should be known. Such as: When on the skin: first, should flush skin with plenty of water immediately for at least 15 minutes while removing contaminated clothing. Secondly, get medical aid. Or in the eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Then get medical aid soon. While, it's inhaled: Remove from exposure and move to fresh air immediately. Give artificial respiration while not breathing. When breathing is difficult, give oxygen. And as soon as to get medical aid. Then you have the ingesting of the product: Wash mouth out with water, and get medical aid immediately. Notes to physician: Treat supportively and symptomatically.
In addition, Sodium tetraphenylboron (CAS NO.143-66-8) is light sensitive. It is not compatible with strong oxidizing agents, and you must not take it with incompatible materials, light, excess heat. And also prevent it to broken down into hazardous decomposition products: Carbon monoxide, carbon dioxide, metallic oxides, boron oxides.
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