Conditions | Yield |
---|---|
With (η6-toluene)Ni(SiCl3)2 for 42h; Mechanism; Product distribution; Ambient temperature; | A 23% B 14% C 98% D n/a |
Conditions | Yield |
---|---|
With tris(triphenylphosphine)ruthenium(II) chloride; trichlorosilane In xylene at 80℃; for 3h; | 90% |
With {Rh(μ-Cl)(CO)(eta.2-cyclooctene)}2; trichlorosilane at 40℃; for 4h; | 12% |
With aluminum oxide; palladium/alumina; trichlorosilane |
tetravinylsilane
A
dichlorodivinylsilane
B
trichlorovinylsilane
C
chlorotrivinylsilane
Conditions | Yield |
---|---|
With hydrogenchloride; iron(III) chloride at 24 - 52℃; Product distribution; oth. catalysts; | A 13.8% B 0.5% C 88% |
chlorotrivinylsilane
A
(n-pr-2-Cl)SiCl3
B
dichlorodivinylsilane
C
trichlorovinylsilane
Conditions | Yield |
---|---|
With hydrogenchloride; iron(III) chloride at 24 - 52℃; Product distribution; | A 4% B 73% C 16% |
Conditions | Yield |
---|---|
With trichlorosilane; dichlorotetraammine platinum; silica gel In various solvent(s) at 150℃; under 712.557 Torr; | A 72% B n/a |
With di(rhodium)tetracarbonyl dichloride; trichlorosilane at 20℃; for 2h; Yields of byproduct given; | A 19.0 % Chromat. B n/a |
With magnesium hydrosilicate; trichlorosilane; platinum |
Conditions | Yield |
---|---|
With hydrogenchloride; iron(III) chloride at 24 - 52℃; Product distribution; | A 19.5% B 69% |
Conditions | Yield |
---|---|
With ferrosilicon | |
With copper | |
With quinoline In quinoline boiling of (CH2ClCH2)SiCl3 with quinoline;; | |
With quinoline In quinoline boiling of (CH2ClCH2)SiCl3 with quinoline;; |
phenylacetylene
A
trichlorovinylsilane
B
(E)-1-phenyl-2-trichlorosilylethene
Conditions | Yield |
---|---|
With trichlorosilane; TB*2RhCl3 for 24h; Ambient temperature; Title compound not separated from byproducts; | A 95 % Spectr. B 5 % Spectr. |
With trichlorosilane; TB*2RhCl3 for 24h; Ambient temperature; | A 95 % Spectr. B 5 % Spectr. |
trichlorosilane
acetylene
A
trichlorovinylsilane
B
1,2-bis(trichlorosilyl)ethane
Conditions | Yield |
---|---|
at 260 - 300℃; |
trichlorosilane
acetylene
A
trichlorovinylsilane
B
1,2-bis(trichlorosilyl)ethane
Conditions | Yield |
---|---|
at 150 - 250℃; under 12503.6 - 18387.7 Torr; |
sulfuryl dichloride
diethyldichlorosilane
dibenzoyl peroxide
A
dichlorodivinylsilane
B
trichlorovinylsilane
Conditions | Yield |
---|---|
Erhitzen des Reaktionsprodukts mit Chinolin auf 230grad; |
sulfuryl dichloride
ethyltrichlorosilane
dibenzoyl peroxide
trichlorovinylsilane
Conditions | Yield |
---|---|
Erhitzen des Reaktionsprodukts in Chinolin auf 200-230grad; |
quinoline
Trichloro-(1-chloro-ethyl)-silane
A
tetrachlorosilane
B
trichlorovinylsilane
aluminium trichloride
Trichloro-(1-chloro-ethyl)-silane
A
tetrachlorosilane
B
trichlorovinylsilane
Trichloro-(1-chloro-ethyl)-silane
A
tetrachlorosilane
B
ethene
C
trichlorovinylsilane
Conditions | Yield |
---|---|
under 610 Torr; Pyrolysis; |
Conditions | Yield |
---|---|
at 350 - 400℃; |
1,1-dichloroethane
A
trichlorovinylsilane
B
1,2-bis(trichlorosilyl)ethane
C
1,1-bis-dichlorosilanyl-ethane
D
1,1-Bis(trichlorosilyl)ethane
Conditions | Yield |
---|---|
at 360 - 380℃; weitere Produkten: Dichlor-vinyl-silan; 1-Dichlorsilyl-1-trichlorsilyl-aethan; |
Conditions | Yield |
---|---|
With trichlorosilane at 426.9℃; Equilibrium constant; Thermodynamic data; E(excit.), ΔH, other temp.; |
chloroethylene
silicon
A
dichlorovinylsilane
B
dichlorodivinylsilane
C
trichlorovinylsilane
Conditions | Yield |
---|---|
tin In neat (no solvent) Si-Sn and CH2CHCl at 400°C;; mixt. obtained;; |
trichlorosilane
acetylene
A
trichlorovinylsilane
B
1,2-bis(trichlorosilyl)ethane
Conditions | Yield |
---|---|
platinum In neat (no solvent) HSiCl3 and acetylene with platinized asbestos as catalyst at 175°C under pressure;; | |
platinum In neat (no solvent) HSiCl3 and acetylene with platinized asbestos as catalyst at 175°C under pressure;; | |
platinum In neat (no solvent) HSiCl3 and acetylene with platinized asbestos as catalyst at 175°C under pressure;; |
trichlorovinylsilane
1,3,5,7,11,13,15-octakis[2-(trichlorosilyl)ethyl]pentacyclo[9.5.1.13,9.15,15.17,13]octasiloxane
Conditions | Yield |
---|---|
With dihydrogen hexachloroplatinate; 2,4,6,8,10,12,14,16,17,18,19,20-dodecaoxa-1,3,5,7,9,11,13,15-octasilapentacyclo[9.5.1.13,9.15,15.17,13]icosan-1,3,5,7,9,11,13,15-octanol In isopropyl alcohol for 22h; Heating; | 100% |
Conditions | Yield |
---|---|
With benzophenone for 4h; Inert atmosphere; UV-irradiation; | 100% |
trichlorovinylsilane
tetrakis(2-sulfanylethyl) silicate
Conditions | Yield |
---|---|
With benzophenone In diethyl ether for 4h; Inert atmosphere; UV-irradiation; | 100% |
lauric acid
trichlorovinylsilane
Octanoic acid
n-tetradecanoic acid
C36H68O6Si
Conditions | Yield |
---|---|
In toluene at 60 - 150℃; for 4h; | 99.82% |
Conditions | Yield |
---|---|
In dichloromethane at 50 - 80℃; for 3h; | 99% |
In dichloromethane at 50℃; | 78% |
With tin(IV) chloride; cyclohexene for 1h; Ambient temperature; | 73.4% |
[(cyclopentadienyl)Co(trimethylvinylsilane)2]
trichlorovinylsilane
[(cyclopentadienyl)Co(trichlorovinylsilane)2]
Conditions | Yield |
---|---|
In diethyl ether byproducts: (CH3)3SiCHCH2; (Ar), Schlenk techniques; dropwise addn. of Si compd. to soln. of Co complex in Et2O at -30°C over 2 min, stirring for 5 min; evapn. under reduced pressure at -20°C, drying under vacuum; | 99% |
Conditions | Yield |
---|---|
With N-benzyl-N,N,N-triethylammonium chloride Substitution; | 98% |
Conditions | Yield |
---|---|
With iron(III) chloride at 85℃; for 0.0166667h; polycondensation; | 98% |
Conditions | Yield |
---|---|
With iron(III) chloride at 85℃; polycondensation; | 98% |
trichlorovinylsilane
monochloroborane dimethyl sulfide complex
Conditions | Yield |
---|---|
In toluene byproducts: dimethylsulfide; in Ar atmosphere into precooled toluene soln. of trichlorovinylsilane chloroborane-dimethylsulfide in toluene added dropwise at 10 °C for6 h; stirred at room temp. 20 h; dimethylsulfide and toluene removed at 0.02 Torr at 60 °C; elem. anal.; | 98% |
Conditions | Yield |
---|---|
With trichlorosilane | 97% |
With trichlorosilane; platinum on activated charcoal for 12h; Ambient temperature; | 92% |
With dihydrogen hexachloroplatinate; trichlorosilane at 130℃; for 2.5h; Inert atmosphere; | 72% |
Conditions | Yield |
---|---|
With benzophenone for 10h; Inert atmosphere; UV-irradiation; | 97% |
(heating); |
Conditions | Yield |
---|---|
With benzophenone for 4h; Inert atmosphere; UV-irradiation; | 97% |
Conditions | Yield |
---|---|
With tetrachlorosilane In water at 0℃; for 1h; Concentration; Reflux; Large scale; | 96.1% |
Conditions | Yield |
---|---|
With (η6-toluene)Ni(SiCl3)2 for 42h; Mechanism; Product distribution; Ambient temperature; | A 23% B 14% C 98% D n/a |
Conditions | Yield |
---|---|
With {palladium-dichloro-(P(C3H7)3)2}; trichlorosilane In xylene at 80℃; for 3h; | A 63% B 12% |
With bis(tributylphosphine)dichloropalladium(II); trichlorosilane In xylene at 80℃; for 3h; | A 22% B 63% |
chloroethylene
A
1,1-Dichloro-2,5-dihydro-1H-silole
B
trichlorovinylsilane
C
1,2-bis(trichlorosilyl)ethene
D
Phenyltrichlorosilane
E
1,1,3,3-tetrachloro-1,3-disilacyclohex-4-ene
Conditions | Yield |
---|---|
With hexachlorodisilane at 500℃; for 0.00694444h; Product distribution; Mechanism; other temperature 550 deg C; | A 1.52% B 55.7% C 3.91% D 1.06% E 7.07% F n/a |
Conditions | Yield |
---|---|
at 150℃; | 52% |
dihydrogen hexachloroplatinate In ethanol at 125℃; under 1535.79 Torr; Product distribution / selectivity; Inert atmosphere; | |
platinum In neat (no solvent) HSiCl3 and C2H2 at 130°C with Pt on coal (catalyst);; | |
platinum In neat (no solvent) HSiCl3 and C2H2 at 175°C with platinized asbestos as catalyst;; | |
In neat (no solvent) byproducts: Cl3SiCH2CH2SiCl3; passing HSiCl3 and C2H2 through a tube at 610°C;; |
Conditions | Yield |
---|---|
at 810℃; Product distribution; vacuum flash pyrolysis; | A n/a B 46% |
chloroethylene
Phenyltrichlorosilane
A
trichlorovinylsilane
B
chlorobenzene
C
benzene
Conditions | Yield |
---|---|
at 630℃; Product distribution; gas phase reaction, quartz tube, contact time 30 sec; | A 3% B 2% C 34% |
chloroethylene
1-chloro-2-trichlorosilylethylene
A
trichlorovinylsilane
B
1,2-bis(trichlorosilyl)ethene
C
trichlorosilylacetylene
Conditions | Yield |
---|---|
at 560℃; Product distribution; gas phase reaction, quartz tube, contact time 30 sec; | A 6.7% B 1.7% C 18.7% |
Conditions | Yield |
---|---|
With sulfuryl dichloride; dibenzoyl peroxide Erhitzen des Reaktionsprodukts mit Chinolin bis auf 200-230grad; |
Conditions | Yield |
---|---|
With copper; silicon at 300 - 350℃; |
Conditions | Yield |
---|---|
With copper; silicon at 300 - 350℃; | |
With silicon; copper | |
With Si-Cu In neat (no solvent) Si-Cu (9:1) and CH2CHCl at 300-350°C;; |
tetraethoxy orthosilicate
trichlorovinylsilane
A
Triethoxyvinylsilane
B
vinyldi(ethoxy)chlorosilane
C
vinyl(ethoxy)dichlorosilane
Conditions | Yield |
---|---|
at 20 - 22℃; for 150h; | A 2% B 95% C 1% |
dimethylmonochlorosilane
trichlorovinylsilane
1-(Chloro-dimethyl-silanyl)-2-trichlorosilanyl-ethane
Conditions | Yield |
---|---|
chloroplatinic acid 1,1,3,3-tetramethyl-1,3-divinyldisiloxane complex at 40℃; for 6h; | 95% |
Conditions | Yield |
---|---|
carbonylchlorohydridobis(tricyclohexylphosphine)ruthenium(II) In dichloromethane at 40℃; for 3h; | 95% |
trichlorovinylsilane
potassium tert-butylate
tris(tert-butoxy)(vinyl)silane
Conditions | Yield |
---|---|
In hexane at 20℃; for 24h; | 95% |
Conditions | Yield |
---|---|
With tetrachlorosilane In water at 0℃; for 4h; pH=6; Concentration; Reflux; Large scale; | 94.8% |
Conditions | Yield |
---|---|
In dichloromethane at 50 - 80℃; for 3h; | A 93.2% B 5.2% |
hydroxymethyl tert-butyl peroxide
trichlorovinylsilane
Conditions | Yield |
---|---|
With triethylamine at -5℃; | 93% |
trichlorovinylsilane
1,3-diallyl-4-(trimethylsilyloxy)-2,6-dioxo-1,3,5-triazine
Conditions | Yield |
---|---|
at 120 - 160℃; | 93% |
ethyl 2-hydroxypropionate
trichlorovinylsilane
vinyltris(ethyl lactato)silane
Conditions | Yield |
---|---|
With triethylamine In toluene at 20℃; for 3h; | 93% |
Conditions | Yield |
---|---|
at 20℃; for 24h; | 93% |
Conditions | Yield |
---|---|
With triethylamine In toluene at 20℃; Inert atmosphere; | 93% |
ethanol
trichlorovinylsilane
A
Triethoxyvinylsilane
B
1,3-diivinyl-1,1,3,3-tetraethoxydisiloxane
Conditions | Yield |
---|---|
In diethyl ether at 45 - 80℃; for 3h; Product distribution; different chlorosilanes, alcohols, solvents and reaction temperatures; | A 92.9% B 5.5% |
trichlorovinylsilane
Dimethylphenylsilane
A
Dichloromethylvinylsilane
B
1,2-bis(trichlorosilyl)ethane
C
Si,Si,Si-trichloro-Si',Si'-dimethyl-Si'-phenyl-Si,Si'-ethanediyl-bis-silane
D
Phenyltrichlorosilane
Conditions | Yield |
---|---|
With dihydrogen hexachloroplatinate Product distribution; Mechanism; Heating; determination of side products; | A 0.7% B 3.5% C 92.3% D 0.9% |
Conditions | Yield |
---|---|
With hydrogen; nickel for 6h; | 92% |
Conditions | Yield |
---|---|
[Cl2(PCy3)(IMesH2)Ru(=CHPh)] In dichloromethane for 1h; Heating; | 92% |
[Cl2(PCy3)(IMesH2)Ru(=CHPh)] In dichloromethane for 1h; Heating; |
IUPAC Name: Trichloro(ethenyl)silane
Empirical Formula: C2H3Cl3Si
Molecular Weight: 161.4897
Canonical SMILES: C=C[Si](Cl)(Cl)Cl
InChI: InChI=1S/C2H3Cl3Si/c1-2-6(3,4)5/h2H,1H2
InChIKey: GQIUQDDJKHLHTB-UHFFFAOYSA-N
EINECS: 200-917-8
Product Categories: Vinyl; Functional Materials; Si (Classes of Silicon Compounds); Si-Cl Compounds; Silane Coupling Agents; Silicon Compounds (for Synthesis); Synthetic Organic Chemistry; Trichlorosilanes; Vinyl Silanes (Silane Coupling Agents); Vinylsilanes, Allylsilanes
Index of Refraction: 1.454
Molar Refractivity: 34.3 cm3
Molar Volume: 126.5 cm3
Surface Tension: 22.3 dyne/cm
Density: 1.276 g/cm3
Flash Point: 10.6 °C
Enthalpy of Vaporization: 31.77 kJ/mol
Boiling Point: 91.5 °C at 760 mmHg
Vapour Pressure: 60.8 mmHg at 25 °C
storage temp.: 0-6 °C
Water Solubility: reacts
Sensitive: Moisture Sensitive
Melting Point: -95 °C(lit.)
Classification Code of Trichlorovinylsilane (CAS NO.75-94-5): Skin / Eye Irritant
Trichlorovinylsilane (CAS NO.75-94-5) can be used for the synthesis of organosilicon compounds.
1. | skn-rbt 10 mg/24H open | AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. 10 (1954),61. | ||
2. | skn-rbt 625 mg open SEV | UCDS** Union Carbide Data Sheet. (Industrial Medicine and Toxicology Dept., Union Carbide Corp., 270 Park Ave., New York, NY 10017) 1/19 ,1972. | ||
3. | eye-rbt 50 µg open SEV | AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. 10 (1954),61. | ||
4. | orl-rat LD50:1280 mg/kg | AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. 10 (1954),61. | ||
5. | ihl-rat LCLo:500 ppm/4H | UCDS** Union Carbide Data Sheet. (Industrial Medicine and Toxicology Dept., Union Carbide Corp., 270 Park Ave., New York, NY 10017) 1/19 ,1972. | ||
6. | skn-rbt LD50:680 mg/kg | AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. 10 (1954),61. |
Reported in EPA TSCA Inventory.
Moderately toxic by ingestion, inhalation, and skin contact. A corrosive irritant to skin, eyes, and mucous membranes. A very dangerous fire hazard when exposed to heat or flame. Reacts violently with water, moist air, or steam to produce toxic and corrosive fumes. When heated to decomposition it emits toxic fumes of Cl−. See also CHLOROSILANES.
Hazard Codes: F,C
Risk Statements: 11-14-20/21/22-34-20
R11:Highly flammable.
R14 :Reacts violently with water.
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed.
R20:Harmful by inhalation.
R34:Causes burns.
Safety Statements: 16-26-36/37/39-45-8-30-29
S16:Keep away from sources of ignition.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
S8:Keep container dry.
S30:Never add water to this product.
S29:Do not empty into drains.
RIDADR: UN 1305 3/PG 1
WGK Germany: 1
RTECS: VV6125000
F: 21
TSCA; Yes
HazardClass: 3
PackingGroup: I
DOT Classification: 3; Label: Flammable Liquid, Corrosive
Trichlorovinylsilane (CAS NO.75-94-5), its Synonyms are Silane, trichloroethenyl- ; Silane, trichlorovinyl- ; Silane, vinyl trichloro A-150 ; Silane, vinyltrichloro- ; Trichloro(vinyl)silane ; Trichlorovinyl silicane ; Trichlorovinylsilicon ; Vinylsilicon trichloride ; Vinyltrichlorosilane ; Vtcs . It is colorless to pale yellow fuming liquid with a pungent odor.
About|Contact|Cas|Product Name|Molecular|Country|Encyclopedia
Message|New Cas|MSDS|Service|Advertisement|CAS DataBase|Article Data|Manufacturers | Chemical Catalog
©2008 LookChem.com,License: ICP
NO.:Zhejiang16009103
complaints:service@lookchem.com Desktop View