Product Name

  • Name

    Trichlorovinylsilane

  • EINECS 200-917-8
  • CAS No. 75-94-5
  • Article Data56
  • CAS DataBase
  • Density 1.276 g/cm3
  • Solubility reacts with water
  • Melting Point -95 °C
  • Formula C2H3Cl3Si
  • Boiling Point 91.5 °C at 760 mmHg
  • Molecular Weight 161.49
  • Flash Point 10.6 °C
  • Transport Information UN 1305 3/PG 1
  • Appearance colorless to pale yellow fuming liquid with a pungent odor
  • Safety 16-26-36/37/39-45-8-30-29
  • Risk Codes 11-14-20/21/22-34-20
  • Molecular Structure Molecular Structure of 75-94-5 (Trichlorovinylsilane)
  • Hazard Symbols FlammableF, CorrosiveC
  • Synonyms Silane,trichlorovinyl- (7CI,8CI);A 150 (silane);KA 1003;TSL 8303;Trichlorovinylsilicon;VTCS;Vinylsilicon trichloride;Vinylsilyl trichloride;Vinyltrichlorosilane;Vinyl-trucgkirisukabe;
  • PSA 0.00000
  • LogP 2.36690

Synthetic route

ethene

ethene

A

ethyltrichlorosilane
115-21-9

ethyltrichlorosilane

B

trichlorovinylsilane
75-94-5

trichlorovinylsilane

C

toluene
108-88-3

toluene

D

butenes

butenes

Conditions
ConditionsYield
With (η6-toluene)Ni(SiCl3)2 for 42h; Mechanism; Product distribution; Ambient temperature;A 23%
B 14%
C 98%
D n/a
acetylene
74-86-2

acetylene

trichlorovinylsilane
75-94-5

trichlorovinylsilane

Conditions
ConditionsYield
With tris(triphenylphosphine)ruthenium(II) chloride; trichlorosilane In xylene at 80℃; for 3h;90%
With {Rh(μ-Cl)(CO)(eta.2-cyclooctene)}2; trichlorosilane at 40℃; for 4h;12%
With aluminum oxide; palladium/alumina; trichlorosilane
tetravinylsilane
1112-55-6

tetravinylsilane

A

dichlorodivinylsilane
1745-72-8

dichlorodivinylsilane

B

trichlorovinylsilane
75-94-5

trichlorovinylsilane

C

chlorotrivinylsilane
1871-21-2

chlorotrivinylsilane

Conditions
ConditionsYield
With hydrogenchloride; iron(III) chloride at 24 - 52℃; Product distribution; oth. catalysts;A 13.8%
B 0.5%
C 88%
chlorotrivinylsilane
1871-21-2

chlorotrivinylsilane

A

(n-pr-2-Cl)SiCl3
7787-89-5

(n-pr-2-Cl)SiCl3

B

dichlorodivinylsilane
1745-72-8

dichlorodivinylsilane

C

trichlorovinylsilane
75-94-5

trichlorovinylsilane

Conditions
ConditionsYield
With hydrogenchloride; iron(III) chloride at 24 - 52℃; Product distribution;A 4%
B 73%
C 16%
acetylene
74-86-2

acetylene

A

trichlorovinylsilane
75-94-5

trichlorovinylsilane

B

1,2-bis(trichlorosilyl)ethane
2504-64-5

1,2-bis(trichlorosilyl)ethane

Conditions
ConditionsYield
With trichlorosilane; dichlorotetraammine platinum; silica gel In various solvent(s) at 150℃; under 712.557 Torr;A 72%
B n/a
With di(rhodium)tetracarbonyl dichloride; trichlorosilane at 20℃; for 2h; Yields of byproduct given;A 19.0 % Chromat.
B n/a
With magnesium hydrosilicate; trichlorosilane; platinum
dichlorodivinylsilane
1745-72-8

dichlorodivinylsilane

A

(n-pr-2-Cl)SiCl3
7787-89-5

(n-pr-2-Cl)SiCl3

B

trichlorovinylsilane
75-94-5

trichlorovinylsilane

Conditions
ConditionsYield
With hydrogenchloride; iron(III) chloride at 24 - 52℃; Product distribution;A 19.5%
B 69%
trichloro(2-chloroethyl)silane
6233-20-1

trichloro(2-chloroethyl)silane

trichlorovinylsilane
75-94-5

trichlorovinylsilane

Conditions
ConditionsYield
With ferrosilicon
With copper
With quinoline In quinoline boiling of (CH2ClCH2)SiCl3 with quinoline;;
With quinoline In quinoline boiling of (CH2ClCH2)SiCl3 with quinoline;;
phenylacetylene
536-74-3

phenylacetylene

A

trichlorovinylsilane
75-94-5

trichlorovinylsilane

B

(E)-1-phenyl-2-trichlorosilylethene
3412-59-7

(E)-1-phenyl-2-trichlorosilylethene

Conditions
ConditionsYield
With trichlorosilane; TB*2RhCl3 for 24h; Ambient temperature; Title compound not separated from byproducts;A 95 % Spectr.
B 5 % Spectr.
With trichlorosilane; TB*2RhCl3 for 24h; Ambient temperature;A 95 % Spectr.
B 5 % Spectr.
trichlorosilane
10025-78-2

trichlorosilane

acetylene
74-86-2

acetylene

palladium/ aluminium oxide

palladium/ aluminium oxide

A

trichlorovinylsilane
75-94-5

trichlorovinylsilane

B

1,2-bis(trichlorosilyl)ethane
2504-64-5

1,2-bis(trichlorosilyl)ethane

Conditions
ConditionsYield
at 260 - 300℃;
trichlorosilane
10025-78-2

trichlorosilane

acetylene
74-86-2

acetylene

platinum

platinum

A

trichlorovinylsilane
75-94-5

trichlorovinylsilane

B

1,2-bis(trichlorosilyl)ethane
2504-64-5

1,2-bis(trichlorosilyl)ethane

Conditions
ConditionsYield
at 150 - 250℃; under 12503.6 - 18387.7 Torr;
sulfuryl dichloride
7791-25-5

sulfuryl dichloride

diethyldichlorosilane
1719-53-5

diethyldichlorosilane

dibenzoyl peroxide
94-36-0

dibenzoyl peroxide

A

dichlorodivinylsilane
1745-72-8

dichlorodivinylsilane

B

trichlorovinylsilane
75-94-5

trichlorovinylsilane

C

dichloro-ethyl-vinyl-silane(?)

dichloro-ethyl-vinyl-silane(?)

Conditions
ConditionsYield
Erhitzen des Reaktionsprodukts mit Chinolin auf 230grad;
sulfuryl dichloride
7791-25-5

sulfuryl dichloride

ethyltrichlorosilane
115-21-9

ethyltrichlorosilane

dibenzoyl peroxide
94-36-0

dibenzoyl peroxide

trichlorovinylsilane
75-94-5

trichlorovinylsilane

Conditions
ConditionsYield
Erhitzen des Reaktionsprodukts in Chinolin auf 200-230grad;
quinoline
91-22-5

quinoline

Trichloro-(1-chloro-ethyl)-silane
7787-82-8

Trichloro-(1-chloro-ethyl)-silane

A

tetrachlorosilane
10026-04-7, 53609-55-5

tetrachlorosilane

B

trichlorovinylsilane
75-94-5

trichlorovinylsilane

aluminium trichloride
7446-70-0

aluminium trichloride

Trichloro-(1-chloro-ethyl)-silane
7787-82-8

Trichloro-(1-chloro-ethyl)-silane

A

tetrachlorosilane
10026-04-7, 53609-55-5

tetrachlorosilane

B

trichlorovinylsilane
75-94-5

trichlorovinylsilane

Trichloro-(1-chloro-ethyl)-silane
7787-82-8

Trichloro-(1-chloro-ethyl)-silane

A

tetrachlorosilane
10026-04-7, 53609-55-5

tetrachlorosilane

B

ethene
74-85-1

ethene

C

trichlorovinylsilane
75-94-5

trichlorovinylsilane

Conditions
ConditionsYield
under 610 Torr; Pyrolysis;
chloroethylene
75-01-4

chloroethylene

copper silicon

copper silicon

A

dichlorodivinylsilane
1745-72-8

dichlorodivinylsilane

B

trichlorovinylsilane
75-94-5

trichlorovinylsilane

Conditions
ConditionsYield
at 350 - 400℃;
1,1-dichloroethane
75-34-3

1,1-dichloroethane

silicon-copper

silicon-copper

A

trichlorovinylsilane
75-94-5

trichlorovinylsilane

B

1,2-bis(trichlorosilyl)ethane
2504-64-5

1,2-bis(trichlorosilyl)ethane

C

1,1-bis-dichlorosilanyl-ethane
18090-31-8

1,1-bis-dichlorosilanyl-ethane

D

1,1-Bis(trichlorosilyl)ethane
18076-92-1

1,1-Bis(trichlorosilyl)ethane

Conditions
ConditionsYield
at 360 - 380℃; weitere Produkten: Dichlor-vinyl-silan; 1-Dichlorsilyl-1-trichlorsilyl-aethan;
chloroethylene
75-01-4

chloroethylene

A

ethene
74-85-1

ethene

B

trichlorovinylsilane
75-94-5

trichlorovinylsilane

C

hydrogen chloride, silicon tetrachloride

hydrogen chloride, silicon tetrachloride

Conditions
ConditionsYield
With trichlorosilane at 426.9℃; Equilibrium constant; Thermodynamic data; E(excit.), ΔH, other temp.;
chloroethylene
75-01-4

chloroethylene

silicon
7440-21-3

silicon

A

dichlorovinylsilane
18076-99-8

dichlorovinylsilane

B

dichlorodivinylsilane
1745-72-8

dichlorodivinylsilane

C

trichlorovinylsilane
75-94-5

trichlorovinylsilane

Conditions
ConditionsYield
tin In neat (no solvent) Si-Sn and CH2CHCl at 400°C;; mixt. obtained;;
trichlorosilane
10025-78-2

trichlorosilane

acetylene
74-86-2

acetylene

A

trichlorovinylsilane
75-94-5

trichlorovinylsilane

B

1,2-bis(trichlorosilyl)ethane
2504-64-5

1,2-bis(trichlorosilyl)ethane

Conditions
ConditionsYield
platinum In neat (no solvent) HSiCl3 and acetylene with platinized asbestos as catalyst at 175°C under pressure;;
platinum In neat (no solvent) HSiCl3 and acetylene with platinized asbestos as catalyst at 175°C under pressure;;
platinum In neat (no solvent) HSiCl3 and acetylene with platinized asbestos as catalyst at 175°C under pressure;;
trichlorovinylsilane
75-94-5

trichlorovinylsilane

1,3,5,7,11,13,15-octakis[2-(trichlorosilyl)ethyl]pentacyclo[9.5.1.13,9.15,15.17,13]octasiloxane
214675-88-4

1,3,5,7,11,13,15-octakis[2-(trichlorosilyl)ethyl]pentacyclo[9.5.1.13,9.15,15.17,13]octasiloxane

Conditions
ConditionsYield
With dihydrogen hexachloroplatinate; 2,4,6,8,10,12,14,16,17,18,19,20-dodecaoxa-1,3,5,7,9,11,13,15-octasilapentacyclo[9.5.1.13,9.15,15.17,13]icosan-1,3,5,7,9,11,13,15-octanol In isopropyl alcohol for 22h; Heating;100%
trichlorovinylsilane
75-94-5

trichlorovinylsilane

ethanethiol
75-08-1

ethanethiol

trichloro(2-ethylsulfanylethyl)silane

trichloro(2-ethylsulfanylethyl)silane

Conditions
ConditionsYield
With benzophenone for 4h; Inert atmosphere; UV-irradiation;100%
trichlorovinylsilane
75-94-5

trichlorovinylsilane

tetrakis(2-sulfanylethyl) silicate
1429129-56-5

tetrakis(2-sulfanylethyl) silicate

tetrakis[2-(2-trichlorosilylethylsulfanyl)ethyl] silicate

tetrakis[2-(2-trichlorosilylethylsulfanyl)ethyl] silicate

Conditions
ConditionsYield
With benzophenone In diethyl ether for 4h; Inert atmosphere; UV-irradiation;100%
lauric acid
143-07-7

lauric acid

trichlorovinylsilane
75-94-5

trichlorovinylsilane

Octanoic acid
124-07-2

Octanoic acid

n-tetradecanoic acid
544-63-8

n-tetradecanoic acid

C36H68O6Si
1330066-17-5

C36H68O6Si

Conditions
ConditionsYield
In toluene at 60 - 150℃; for 4h;99.82%
ethanol
64-17-5

ethanol

trichlorovinylsilane
75-94-5

trichlorovinylsilane

Triethoxyvinylsilane
78-08-0

Triethoxyvinylsilane

Conditions
ConditionsYield
In dichloromethane at 50 - 80℃; for 3h;99%
In dichloromethane at 50℃;78%
With tin(IV) chloride; cyclohexene for 1h; Ambient temperature;73.4%
[(cyclopentadienyl)Co(trimethylvinylsilane)2]
189282-65-3

[(cyclopentadienyl)Co(trimethylvinylsilane)2]

trichlorovinylsilane
75-94-5

trichlorovinylsilane

[(cyclopentadienyl)Co(trichlorovinylsilane)2]
1246272-79-6

[(cyclopentadienyl)Co(trichlorovinylsilane)2]

Conditions
ConditionsYield
In diethyl ether byproducts: (CH3)3SiCHCH2; (Ar), Schlenk techniques; dropwise addn. of Si compd. to soln. of Co complex in Et2O at -30°C over 2 min, stirring for 5 min; evapn. under reduced pressure at -20°C, drying under vacuum;99%
trichlorovinylsilane
75-94-5

trichlorovinylsilane

trimethylsilyl trifluoroacetate
400-53-3

trimethylsilyl trifluoroacetate

tris(trifluoroacetoxy)vinylsilane

tris(trifluoroacetoxy)vinylsilane

Conditions
ConditionsYield
With N-benzyl-N,N,N-triethylammonium chloride Substitution;98%
tetramethylorthosilicate
681-84-5

tetramethylorthosilicate

trichlorovinylsilane
75-94-5

trichlorovinylsilane

Polymer; Monomer(s): vinyltrichlorosilane; tetramethylorthosilicate

Polymer; Monomer(s): vinyltrichlorosilane; tetramethylorthosilicate

Conditions
ConditionsYield
With iron(III) chloride at 85℃; for 0.0166667h; polycondensation;98%
trichlorovinylsilane
75-94-5

trichlorovinylsilane

phenyl trimethylsiloxane
2996-92-1

phenyl trimethylsiloxane

Polymer; Monomer(s): vinyltrichlorosilane; phenyltrimethoxysilane

Polymer; Monomer(s): vinyltrichlorosilane; phenyltrimethoxysilane

Conditions
ConditionsYield
With iron(III) chloride at 85℃; polycondensation;98%
trichlorovinylsilane
75-94-5

trichlorovinylsilane

monochloroborane dimethyl sulfide complex
63348-81-2

monochloroborane dimethyl sulfide complex

bis[(α-trichlorosilyl)ethyl]chloroborane

bis[(α-trichlorosilyl)ethyl]chloroborane

Conditions
ConditionsYield
In toluene byproducts: dimethylsulfide; in Ar atmosphere into precooled toluene soln. of trichlorovinylsilane chloroborane-dimethylsulfide in toluene added dropwise at 10 °C for6 h; stirred at room temp. 20 h; dimethylsulfide and toluene removed at 0.02 Torr at 60 °C; elem. anal.;98%
trichlorovinylsilane
75-94-5

trichlorovinylsilane

1,2-bis(trichlorosilyl)ethane
2504-64-5

1,2-bis(trichlorosilyl)ethane

Conditions
ConditionsYield
With trichlorosilane97%
With trichlorosilane; platinum on activated charcoal for 12h; Ambient temperature;92%
With dihydrogen hexachloroplatinate; trichlorosilane at 130℃; for 2.5h; Inert atmosphere;72%
trichlorovinylsilane
75-94-5

trichlorovinylsilane

thiophenol
108-98-5

thiophenol

trichloro(2-phenylsulfanylethyl)silane
33206-97-2

trichloro(2-phenylsulfanylethyl)silane

Conditions
ConditionsYield
With benzophenone for 10h; Inert atmosphere; UV-irradiation;97%
(heating);
trichlorovinylsilane
75-94-5

trichlorovinylsilane

ethane-1,2-dithiol
540-63-6

ethane-1,2-dithiol

trichloro[2-[2-(2-trichlorosilylethylsulfanyl)ethylsulfanyl]ethyl]silane

trichloro[2-[2-(2-trichlorosilylethylsulfanyl)ethylsulfanyl]ethyl]silane

Conditions
ConditionsYield
With benzophenone for 4h; Inert atmosphere; UV-irradiation;97%
ethanol
64-17-5

ethanol

trichlorovinylsilane
75-94-5

trichlorovinylsilane

1-vinyl-1,1,3,3,3-pentaethoxydisiloxane

1-vinyl-1,1,3,3,3-pentaethoxydisiloxane

Conditions
ConditionsYield
With tetrachlorosilane In water at 0℃; for 1h; Concentration; Reflux; Large scale;96.1%
ethene
74-85-1

ethene

A

ethyltrichlorosilane
115-21-9

ethyltrichlorosilane

B

trichlorovinylsilane
75-94-5

trichlorovinylsilane

C

toluene
108-88-3

toluene

D

butenes

butenes

Conditions
ConditionsYield
With (η6-toluene)Ni(SiCl3)2 for 42h; Mechanism; Product distribution; Ambient temperature;A 23%
B 14%
C 98%
D n/a
acetylene
74-86-2

acetylene

A

trichlorovinylsilane
75-94-5

trichlorovinylsilane

B

1,2-bis(trichlorosilyl)ethene
692-52-4

1,2-bis(trichlorosilyl)ethene

Conditions
ConditionsYield
With {palladium-dichloro-(P(C3H7)3)2}; trichlorosilane In xylene at 80℃; for 3h;A 63%
B 12%
With bis(tributylphosphine)dichloropalladium(II); trichlorosilane In xylene at 80℃; for 3h;A 22%
B 63%
chloroethylene
75-01-4

chloroethylene

A

1,1-Dichloro-2,5-dihydro-1H-silole
872-46-8

1,1-Dichloro-2,5-dihydro-1H-silole

B

trichlorovinylsilane
75-94-5

trichlorovinylsilane

C

1,2-bis(trichlorosilyl)ethene
692-52-4

1,2-bis(trichlorosilyl)ethene

D

Phenyltrichlorosilane
98-13-5

Phenyltrichlorosilane

E

1,1,3,3-tetrachloro-1,3-disilacyclohex-4-ene
59361-35-2

1,1,3,3-tetrachloro-1,3-disilacyclohex-4-ene

F

SiCl4

SiCl4

Conditions
ConditionsYield
With hexachlorodisilane at 500℃; for 0.00694444h; Product distribution; Mechanism; other temperature 550 deg C;A 1.52%
B 55.7%
C 3.91%
D 1.06%
E 7.07%
F n/a
trichlorosilane
10025-78-2

trichlorosilane

acetylene
74-86-2

acetylene

trichlorovinylsilane
75-94-5

trichlorovinylsilane

Conditions
ConditionsYield
at 150℃;52%
dihydrogen hexachloroplatinate In ethanol at 125℃; under 1535.79 Torr; Product distribution / selectivity; Inert atmosphere;
platinum In neat (no solvent) HSiCl3 and C2H2 at 130°C with Pt on coal (catalyst);;
platinum In neat (no solvent) HSiCl3 and C2H2 at 175°C with platinized asbestos as catalyst;;
In neat (no solvent) byproducts: Cl3SiCH2CH2SiCl3; passing HSiCl3 and C2H2 through a tube at 610°C;;
1,1-dichloro-2-methyl-1-silacyclobutane
30681-89-1

1,1-dichloro-2-methyl-1-silacyclobutane

A

ethene
74-85-1

ethene

B

trichlorovinylsilane
75-94-5

trichlorovinylsilane

Conditions
ConditionsYield
at 810℃; Product distribution; vacuum flash pyrolysis;A n/a
B 46%
chloroethylene
75-01-4

chloroethylene

Phenyltrichlorosilane
98-13-5

Phenyltrichlorosilane

A

trichlorovinylsilane
75-94-5

trichlorovinylsilane

B

chlorobenzene
108-90-7

chlorobenzene

C

benzene
71-43-2

benzene

Conditions
ConditionsYield
at 630℃; Product distribution; gas phase reaction, quartz tube, contact time 30 sec;A 3%
B 2%
C 34%
chloroethylene
75-01-4

chloroethylene

1-chloro-2-trichlorosilylethylene
690-18-6

1-chloro-2-trichlorosilylethylene

A

trichlorovinylsilane
75-94-5

trichlorovinylsilane

B

1,2-bis(trichlorosilyl)ethene
692-52-4

1,2-bis(trichlorosilyl)ethene

C

trichlorosilylacetylene
13852-14-7

trichlorosilylacetylene

Conditions
ConditionsYield
at 560℃; Product distribution; gas phase reaction, quartz tube, contact time 30 sec;A 6.7%
B 1.7%
C 18.7%
ethyltrichlorosilane
115-21-9

ethyltrichlorosilane

trichlorovinylsilane
75-94-5

trichlorovinylsilane

Conditions
ConditionsYield
With sulfuryl dichloride; dibenzoyl peroxide Erhitzen des Reaktionsprodukts mit Chinolin bis auf 200-230grad;
chloroethylene
75-01-4

chloroethylene

A

dichlorodivinylsilane
1745-72-8

dichlorodivinylsilane

B

trichlorovinylsilane
75-94-5

trichlorovinylsilane

Conditions
ConditionsYield
With copper; silicon at 300 - 350℃;
chloroethylene
75-01-4

chloroethylene

trichlorovinylsilane
75-94-5

trichlorovinylsilane

Conditions
ConditionsYield
With copper; silicon at 300 - 350℃;
With silicon; copper
With Si-Cu In neat (no solvent) Si-Cu (9:1) and CH2CHCl at 300-350°C;;
tetraethoxy orthosilicate
78-10-4

tetraethoxy orthosilicate

trichlorovinylsilane
75-94-5

trichlorovinylsilane

A

Triethoxyvinylsilane
78-08-0

Triethoxyvinylsilane

B

vinyldi(ethoxy)chlorosilane
18187-22-9

vinyldi(ethoxy)chlorosilane

C

vinyl(ethoxy)dichlorosilane
56124-75-5

vinyl(ethoxy)dichlorosilane

Conditions
ConditionsYield
at 20 - 22℃; for 150h;A 2%
B 95%
C 1%
dimethylmonochlorosilane
1066-35-9

dimethylmonochlorosilane

trichlorovinylsilane
75-94-5

trichlorovinylsilane

1-(Chloro-dimethyl-silanyl)-2-trichlorosilanyl-ethane
15411-18-4

1-(Chloro-dimethyl-silanyl)-2-trichlorosilanyl-ethane

Conditions
ConditionsYield
chloroplatinic acid 1,1,3,3-tetramethyl-1,3-divinyldisiloxane complex at 40℃; for 6h;95%
allylboronic acid 2,2-dimethyl-1,3-propanediol ester

allylboronic acid 2,2-dimethyl-1,3-propanediol ester

trichlorovinylsilane
75-94-5

trichlorovinylsilane

C8H14Cl3BO2Si

C8H14Cl3BO2Si

Conditions
ConditionsYield
carbonylchlorohydridobis(tricyclohexylphosphine)ruthenium(II) In dichloromethane at 40℃; for 3h;95%
trichlorovinylsilane
75-94-5

trichlorovinylsilane

potassium tert-butylate
865-47-4

potassium tert-butylate

tris(tert-butoxy)(vinyl)silane
5356-88-7

tris(tert-butoxy)(vinyl)silane

Conditions
ConditionsYield
In hexane at 20℃; for 24h;95%
methanol
67-56-1

methanol

trichlorovinylsilane
75-94-5

trichlorovinylsilane

1-vinyl-1,1,3,3,3-pentamethoxydisiloxane

1-vinyl-1,1,3,3,3-pentamethoxydisiloxane

Conditions
ConditionsYield
With tetrachlorosilane In water at 0℃; for 4h; pH=6; Concentration; Reflux; Large scale;94.8%
propan-1-ol
71-23-8

propan-1-ol

trichlorovinylsilane
75-94-5

trichlorovinylsilane

A

vinyltri-n-propoxysilane
13080-95-0

vinyltri-n-propoxysilane

B

C16H34O5Si2

C16H34O5Si2

Conditions
ConditionsYield
In dichloromethane at 50 - 80℃; for 3h;A 93.2%
B 5.2%
hydroxymethyl tert-butyl peroxide
17742-78-8

hydroxymethyl tert-butyl peroxide

trichlorovinylsilane
75-94-5

trichlorovinylsilane

tris<2-(tert-butyldioxy)methoxy>vinylsilane

tris<2-(tert-butyldioxy)methoxy>vinylsilane

Conditions
ConditionsYield
With triethylamine at -5℃;93%
trichlorovinylsilane
75-94-5

trichlorovinylsilane

1,3-diallyl-4-(trimethylsilyloxy)-2,6-dioxo-1,3,5-triazine
63226-47-1

1,3-diallyl-4-(trimethylsilyloxy)-2,6-dioxo-1,3,5-triazine

tris(diallylisocyanurato)vinylsilane

tris(diallylisocyanurato)vinylsilane

Conditions
ConditionsYield
at 120 - 160℃;93%
ethyl 2-hydroxypropionate
97-64-3, 2676-33-7

ethyl 2-hydroxypropionate

trichlorovinylsilane
75-94-5

trichlorovinylsilane

vinyltris(ethyl lactato)silane
1124196-01-5

vinyltris(ethyl lactato)silane

Conditions
ConditionsYield
With triethylamine In toluene at 20℃; for 3h;93%
trichlorovinylsilane
75-94-5

trichlorovinylsilane

2-[(trimethylsilyl)oxy]benzoic acid trimethylsilyl ester
3789-85-3

2-[(trimethylsilyl)oxy]benzoic acid trimethylsilyl ester

2-chloro-2-vinyl-4H-benzo[d][1,3,2]dioxasilin-4-one

2-chloro-2-vinyl-4H-benzo[d][1,3,2]dioxasilin-4-one

Conditions
ConditionsYield
at 20℃; for 24h;93%
diethylmalate
7554-12-3

diethylmalate

trichlorovinylsilane
75-94-5

trichlorovinylsilane

C26H42O15Si

C26H42O15Si

Conditions
ConditionsYield
With triethylamine In toluene at 20℃; Inert atmosphere;93%
ethanol
64-17-5

ethanol

trichlorovinylsilane
75-94-5

trichlorovinylsilane

A

Triethoxyvinylsilane
78-08-0

Triethoxyvinylsilane

B

1,3-diivinyl-1,1,3,3-tetraethoxydisiloxane
3682-26-6

1,3-diivinyl-1,1,3,3-tetraethoxydisiloxane

Conditions
ConditionsYield
In diethyl ether at 45 - 80℃; for 3h; Product distribution; different chlorosilanes, alcohols, solvents and reaction temperatures;A 92.9%
B 5.5%
trichlorovinylsilane
75-94-5

trichlorovinylsilane

Dimethylphenylsilane
766-77-8

Dimethylphenylsilane

A

Dichloromethylvinylsilane
124-70-9

Dichloromethylvinylsilane

B

1,2-bis(trichlorosilyl)ethane
2504-64-5

1,2-bis(trichlorosilyl)ethane

C

Si,Si,Si-trichloro-Si',Si'-dimethyl-Si'-phenyl-Si,Si'-ethanediyl-bis-silane
17876-66-3

Si,Si,Si-trichloro-Si',Si'-dimethyl-Si'-phenyl-Si,Si'-ethanediyl-bis-silane

D

Phenyltrichlorosilane
98-13-5

Phenyltrichlorosilane

Conditions
ConditionsYield
With dihydrogen hexachloroplatinate Product distribution; Mechanism; Heating; determination of side products;A 0.7%
B 3.5%
C 92.3%
D 0.9%
trichlorovinylsilane
75-94-5

trichlorovinylsilane

ethyltrichlorosilane
115-21-9

ethyltrichlorosilane

Conditions
ConditionsYield
With hydrogen; nickel for 6h;92%
trichlorovinylsilane
75-94-5

trichlorovinylsilane

allyl-trimethyl-silane
762-72-1

allyl-trimethyl-silane

(E)-1-Trichlorosilanyl-3-trimethylsilanyl-propene

(E)-1-Trichlorosilanyl-3-trimethylsilanyl-propene

Conditions
ConditionsYield
[Cl2(PCy3)(IMesH2)Ru(=CHPh)] In dichloromethane for 1h; Heating;92%
[Cl2(PCy3)(IMesH2)Ru(=CHPh)] In dichloromethane for 1h; Heating;

Trichlorovinylsilane Chemical Properties


IUPAC Name: Trichloro(ethenyl)silane 
Empirical Formula: C2H3Cl3Si
Molecular Weight: 161.4897
Canonical SMILES: C=C[Si](Cl)(Cl)Cl
InChI: InChI=1S/C2H3Cl3Si/c1-2-6(3,4)5/h2H,1H2
InChIKey: GQIUQDDJKHLHTB-UHFFFAOYSA-N
EINECS: 200-917-8
Product Categories: Vinyl; Functional Materials; Si (Classes of Silicon Compounds); Si-Cl Compounds; Silane Coupling Agents; Silicon Compounds (for Synthesis); Synthetic Organic Chemistry; Trichlorosilanes; Vinyl Silanes (Silane Coupling Agents); Vinylsilanes, Allylsilanes 
Index of Refraction: 1.454
Molar Refractivity: 34.3 cm3
Molar Volume: 126.5 cm3
Surface Tension: 22.3 dyne/cm
Density: 1.276 g/cm3
Flash Point: 10.6 °C
Enthalpy of Vaporization: 31.77 kJ/mol
Boiling Point: 91.5 °C at 760 mmHg
Vapour Pressure: 60.8 mmHg at 25 °C 
storage temp.: 0-6 °C
Water Solubility: reacts
Sensitive: Moisture Sensitive
Melting Point: -95 °C(lit.)
Classification Code of Trichlorovinylsilane (CAS NO.75-94-5): Skin / Eye Irritant

Trichlorovinylsilane Uses

 Trichlorovinylsilane (CAS NO.75-94-5) can be used for the synthesis of organosilicon compounds.

Trichlorovinylsilane Toxicity Data With Reference

1.    

skn-rbt 10 mg/24H open

    AMIHBC    AMA Archives of Industrial Hygiene and Occupational Medicine. 10 (1954),61.
2.    

skn-rbt 625 mg open SEV

    UCDS**    Union Carbide Data Sheet. (Industrial Medicine and Toxicology Dept., Union Carbide Corp., 270 Park Ave., New York, NY 10017) 1/19 ,1972.
3.    

eye-rbt 50 µg open SEV

    AMIHBC    AMA Archives of Industrial Hygiene and Occupational Medicine. 10 (1954),61.
4.    

orl-rat LD50:1280 mg/kg

    AMIHBC    AMA Archives of Industrial Hygiene and Occupational Medicine. 10 (1954),61.
5.    

ihl-rat LCLo:500 ppm/4H

    UCDS**    Union Carbide Data Sheet. (Industrial Medicine and Toxicology Dept., Union Carbide Corp., 270 Park Ave., New York, NY 10017) 1/19 ,1972.
6.    

skn-rbt LD50:680 mg/kg

    AMIHBC    AMA Archives of Industrial Hygiene and Occupational Medicine. 10 (1954),61.

Trichlorovinylsilane Consensus Reports

Reported in EPA TSCA Inventory.

Trichlorovinylsilane Safety Profile

Moderately toxic by ingestion, inhalation, and skin contact. A corrosive irritant to skin, eyes, and mucous membranes. A very dangerous fire hazard when exposed to heat or flame. Reacts violently with water, moist air, or steam to produce toxic and corrosive fumes. When heated to decomposition it emits toxic fumes of Cl. See also CHLOROSILANES.
Hazard Codes: FlammableF,CorrosiveC
Risk Statements: 11-14-20/21/22-34-20 
R11:Highly flammable. 
R14 :Reacts violently with water. 
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed. 
R20:Harmful by inhalation. 
R34:Causes burns.
Safety Statements: 16-26-36/37/39-45-8-30-29 
S16:Keep away from sources of ignition. 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection. 
S8:Keep container dry. 
S30:Never add water to this product. 
S29:Do not empty into drains.
RIDADR: UN 1305 3/PG 1
WGK Germany: 1
RTECS: VV6125000
F: 21
TSCA; Yes
HazardClass: 3
PackingGroup: I

Trichlorovinylsilane Standards and Recommendations

DOT Classification:  3; Label: Flammable Liquid, Corrosive

Trichlorovinylsilane Specification

 Trichlorovinylsilane (CAS NO.75-94-5), its Synonyms are Silane, trichloroethenyl- ; Silane, trichlorovinyl- ; Silane, vinyl trichloro A-150 ; Silane, vinyltrichloro- ; Trichloro(vinyl)silane ; Trichlorovinyl silicane ; Trichlorovinylsilicon ; Vinylsilicon trichloride ; Vinyltrichlorosilane ; Vtcs . It is colorless to pale yellow fuming liquid with a pungent odor.

Post buying leads

About|Contact|Cas|Product Name|Molecular|Country|Encyclopedia

Message|New Cas|MSDS|Service|Advertisement|CAS DataBase|Article Data|Manufacturers | Chemical Catalog

©2008 LookChem.com,License: ICP

NO.:Zhejiang16009103

complaints:service@lookchem.com Desktop View