Trimethylsilyl methacrylate supplier

Name
TRIMETHYLSILYL METHACRYLATE
EINECS
CAS No. 13688-56-7
Article Data15
CAS DataBase
Density 0.888 g/cm³
Solubility
Melting Point
Formula C₇H₁₄O₂Si
Boiling Point 146.824 °C at 760 mmHg
Molecular Weight 158.272
Flash Point 30.079 °C
Transport Information
Appearance clear slightly yellow liquid
Safety 22-26-36/37
Risk Codes 10-36/37/38-42/43
Molecular Structure
Hazard Symbols Xn
Synonyms Methacrylic acid,trimethylsilyl ester (7CI,8CI);Silanol, trimethyl-, methacrylate (6CI);T3633;Trimethylsilyl 2-methylacrylate;
PSA 26.30000
LogP 1.94060

Synthetic route

: 80-62-6
methacrylic acid methyl ester

heptamethyltrisiloxane: heptamethyltrisiloxane

: 13688-56-7
trimethylsilyl methacrylate

Conditions

Conditions	Yield
With tris(pentafluorophenyl)borate; 4-methoxy-phenol In tetrahydrofuran for 0.75h; Green chemistry;	90.1%

: 79-41-4
poly(methacrylic acid)

: 18297-63-7
N,N'-bis(trimethylsilyl)urea

: 13688-56-7
trimethylsilyl methacrylate

Conditions

Conditions	Yield
In dichloromethane at 40℃; for 2h;	80%

: 79-41-4
poly(methacrylic acid)

: 107-46-0
Hexamethyldisiloxane

: 13688-56-7
trimethylsilyl methacrylate

Conditions

Conditions	Yield
With ammonium sulfate at 120℃;	56%

: 75-77-4
chloro-trimethyl-silane

: 79-41-4
poly(methacrylic acid)

: 13688-56-7
trimethylsilyl methacrylate

Conditions

Conditions	Yield
With N,N-diethylaniline
With 1-methyl-1H-imidazole at 45 - 90℃; for 3.75h; Product distribution / selectivity; Inert atmosphere; Industry scale;	99 %Chromat.

: 75-77-4
chloro-trimethyl-silane

: 5536-61-8
sodium methacrylate

: 13688-56-7
trimethylsilyl methacrylate

Conditions

Conditions	Yield
With hydroquinone In benzene

: 43112-38-5
3-(trimethylsilyl)-2-oxazolidinone

: 79-41-4
poly(methacrylic acid)

: 13688-56-7
trimethylsilyl methacrylate

Conditions

Conditions	Yield
With triethylamine In dichloromethane for 0.5h; Ambient temperature;

: 79-41-4
poly(methacrylic acid)

: 999-97-3
1,1,1,3,3,3-hexamethyl-disilazane

: 13688-56-7
trimethylsilyl methacrylate

Conditions

Conditions	Yield
With hydroquinone for 3h; Heating;

: 79-41-4
poly(methacrylic acid)

: 2754-27-0
trimethylsilyl acetate

: 13688-56-7
trimethylsilyl methacrylate

Conditions

Conditions	Yield
In hexane

: 427-36-1
trityl fluoride

: 13688-56-7
trimethylsilyl methacrylate

A: 420-56-4
trimethylsilyl fluoride

B: 19302-93-3
2-methylacrylic acid trityl ester

Conditions

Conditions	Yield
With silicon tetrafluoride In acetonitrile at 14℃; for 6h;	A n/a B 94%

...Expand

: 993-07-7
trimethylsilan

: 13688-56-7
trimethylsilyl methacrylate

: 31469-25-7
1,1-bis(trimethylsiloxy)-2-methylprop-1-ene

Conditions

Conditions	Yield
With 2,6-di-tert-butyl-4-methyl-phenol; rhodium(III) chloride In tetrahydrofuran at 40 - 50℃;	78%

: 13688-56-7
trimethylsilyl methacrylate

: 368-44-5
dichloro(fluoro)(phenyl)silane

: 1357518-85-4
PhSiF[OC(O)CCH3=CH2]2

Conditions

Conditions	Yield
at 20℃; for 7 - 8h;	75.1%

: 13688-56-7
trimethylsilyl methacrylate

: 368-45-6
chloro(difluoro)(phenyl)silane

: 1357518-67-2
PhSiF2OC(O)C(CH3)=CH2

Conditions

Conditions	Yield
at 20℃; for 0.25 - 0.5h;	74%

: 13688-56-7
trimethylsilyl methacrylate

: 50653-07-1
trimethylsilyl triphenyl methyl ether

A: 107-46-0
Hexamethyldisiloxane

B: 19302-93-3
2-methylacrylic acid trityl ester

Conditions

Conditions	Yield
With trimethylsilyl trifluoromethanesulfonate In dichloromethane at 0℃; for 6h;	A n/a B 73%

...Expand

: 13688-56-7
trimethylsilyl methacrylate

: 50653-07-1
trimethylsilyl triphenyl methyl ether

: 19302-93-3
2-methylacrylic acid trityl ester

Conditions

Conditions	Yield
trimethylsilyl trifluoromethanesulfonate In dichloromethane at 0℃; for 6h;	73%

: 4668-00-2
chlorotrimethoxysilane

: 13688-56-7
trimethylsilyl methacrylate

A: 75-77-4
chloro-trimethyl-silane

B: 27719-42-2
trimethoxysilyl methacrylate

Conditions

Conditions	Yield
at 20℃; for 8h;	A n/a B 62%

...Expand

: 13688-56-7
trimethylsilyl methacrylate

: 368-44-5
dichloro(fluoro)(phenyl)silane

: 1344680-46-1
PhSiFClOC(O)C(CH3)=CH2

Conditions

Conditions	Yield
at 20℃; for 0.25 - 0.5h;	58.7%

: 617-86-7
triethylsilane

: 13688-56-7
trimethylsilyl methacrylate

: 2-methyl-1-triethylsiloxy-1-trimethylsiloxy-propene

Conditions

Conditions	Yield
Stage #1: triethylsilane With 1,3,5-trimethyl-2,4,6-tris-(3,5-di-tert-butyl-4-hydroxybenzyl)benzene; tris(pentafluorophenyl)borate at 20℃; for 0.25h; Neat (no solvent); Stage #2: trimethylsilyl methacrylate at 4.5 - 8℃; for 4h; Neat (no solvent); Cooling with ice water; Stage #3: trimethylsilyl methacrylate With triethylamine; tris(pentafluorophenyl)borate more than 3 stages;	49.2%

: 15861-24-2
1H-indole-5-carbonitrile

: 13688-56-7
trimethylsilyl methacrylate

: C13H10N2O

Conditions

Conditions	Yield
Stage #1: trimethylsilyl methacrylate With oxalyl dichloride; N,N-dimethyl-formamide In dichloromethane at 20℃; for 3h; Stage #2: 1H-indole-5-carbonitrile With tetrabutyl ammonium fluoride; sodium hydroxide In dichloromethane	17%

: 13688-56-7
trimethylsilyl methacrylate

: 1-Phenyl-7,7-dihexyl-8,8-dimethyl-7,8-disilabicyclo[2.2.2]octa-2,5-diene

Poly(1,1-dimethyl-2,2-dihexyldisilene)-b-poly(methacrylic acid); Mn=2.4 E4: Poly(1,1-dimethyl-2,2-dihexyldisilene)-b-poly(methacrylic acid); Mn=2.4 E4

Conditions

Conditions	Yield
Stage #1: 1-Phenyl-7,7-dihexyl-8,8-dimethyl-7,8-disilabicyclo[2.2.2]octa-2,5-diene With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.333333h; Polymerization; Stage #2: trimethylsilyl methacrylate In tetrahydrofuran; hexane at -78℃; for 2h; Polymerization; Stage #3: With hydrogenchloride In tetrahydrofuran; hexane Hydrolysis;	15.2%

: 3144-74-9
chloromethyldimethylsilane

: 13688-56-7
trimethylsilyl methacrylate

: 13688-53-4
β--isobuttersaeure-trimethylsilylester

Conditions

Conditions	Yield
dihydrogen hexachloroplatinate In isopropyl alcohol Heating;

: 758-21-4
dimethylethylsilane

: 13688-56-7
trimethylsilyl methacrylate

: 13688-85-2
C11H26O2Si2

: 18157-31-8
(3-chloropropyl)dimethylsilane

: 13688-56-7
trimethylsilyl methacrylate

: 38110-03-1
C12H27ClO2Si2

Conditions

Conditions	Yield
dihydrogen hexachloroplatinate

: 2031-62-1
diethoxymethylane

: 13688-56-7
trimethylsilyl methacrylate

: 23416-03-7
2-Methyl-3-(diethoxy-methylsilyl)-propionsaeure-trimethylsilylester

Conditions

Conditions	Yield
dihydrogen hexachloroplatinate In isopropyl alcohol at 180℃;

: 13175-88-7
ethyldiethoxysilane

: 13688-56-7
trimethylsilyl methacrylate

: 23416-04-8
2-Methyl-3-(diethoxy-ethylsilyl)-propionsaeure-trimethylsilylester

Conditions

Conditions	Yield
dihydrogen hexachloroplatinate In isopropyl alcohol at 180℃;

: 998-30-1
Triethoxysilane

: 13688-56-7
trimethylsilyl methacrylate

: 23416-05-9
2-Methyl-3-triethoxysilyl-propionsaeure-trimethylsilylester

Conditions

Conditions	Yield
dihydrogen hexachloroplatinate In isopropyl alcohol at 180℃;

: 1873-88-7
1,1,1,3,5,5,5-heptamethyltrisiloxan

: 13688-56-7
trimethylsilyl methacrylate

: 63672-03-7
C14H36O4Si4

Conditions

Conditions	Yield
With dihydrogen hexachloroplatinate In isopropyl alcohol

: 13688-56-7
trimethylsilyl methacrylate

: 6997-65-5
methacrylic acid bromide

Conditions

Conditions	Yield
With dibromotriphenylphosphorane In dichloromethane at 15℃; for 0.166667h;

: 13688-56-7
trimethylsilyl methacrylate

: 2638-94-0
4,4'-dicyano-4,4'-azo-di-valeric acid

polymer, obtained by radical polymerization trimethylsilyl methacrylate using 4,4'-azobis(4-cyanopentanoic acid) as an initiator: polymer, obtained by radical polymerization trimethylsilyl methacrylate using 4,4'-azobis(4-cyanopentanoic acid) as an initiator

Conditions

Conditions	Yield
In 1,4-dioxane at 60℃; for 18h;

divinyl benzene: divinyl benzene

: 141-32-2
acrylic acid n-butyl ester

: 13688-56-7
trimethylsilyl methacrylate

poly(butyl acrylate-co-divinyl benzene-co-trimethylsilyl methacrylate): poly(butyl acrylate-co-divinyl benzene-co-trimethylsilyl methacrylate)

...Expand

Trimethylsilyl methacrylate Specification

The 2-Propenoic acid,2-methyl-, trimethylsilyl ester is an organic compound with the formula C₇H₁₄O₂Si. The IUPAC name of this chemical is trimethylsilyl 2-methylprop-2-enoate. With the CAS registry number 13688-56-7, it is also named as Trimethylsilyl-2-methylacrylat.

Physical properties about 2-Propenoic acid,2-methyl-, trimethylsilyl ester are: (1)ACD/LogP: 2.39; (2)ACD/LogD (pH 5.5): 2.39; (3)ACD/LogD (pH 7.4): 2.39; (4)ACD/BCF (pH 5.5): 38.32; (5)ACD/BCF (pH 7.4): 38.32; (6)ACD/KOC (pH 5.5): 473.14; (7)ACD/KOC (pH 7.4): 473.14; (8)#H bond acceptors: 2; (9)#Freely Rotating Bonds: 3; (10)Polar Surface Area: 26.3 Å²; (11)Index of Refraction: 1.414; (12)Molar Refractivity: 44.53 cm³; (13)Molar Volume: 178.1 cm³; (14)Polarizability: 17.65×10^-24cm³; (15)Surface Tension: 20.6 dyne/cm; (16)Density: 0.888 g/cm³; (17)Flash Point: 30.1 °C; (18)Enthalpy of Vaporization: 38.38 kJ/mol; (19)Boiling Point: 146.8 °C at 760 mmHg; (20)Vapour Pressure: 4.55 mmHg at 25°C.

You can still convert the following datas into molecular structure:
(1)SMILES: O=C(O[Si](C)(C)C)\C(=C)C
(2)InChI: InChI=1/C7H14O2Si/c1-6(2)7(8)9-10(3,4)5/h1H2,2-5H3
(3)InChIKey: PGQNYIRJCLTTOJ-UHFFFAOYAV
(4)Std. InChI: InChI=1S/C7H14O2Si/c1-6(2)7(8)9-10(3,4)5/h1H2,2-5H3
(5)Std. InChIKey: PGQNYIRJCLTTOJ-UHFFFAOYSA-N

Product Name

TRIMETHYLSILYL METHACRYLATE

Synthetic route

Trimethylsilyl methacrylate Specification

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