1,1,2-Trichloropropane supplier

Name
1,1,2-Trichloropropane
EINECS
CAS No. 598-77-6
Density 1.305g/cm³
Solubility
Melting Point -36.84°C (estimate)
Formula C3H5 Cl3
Boiling Point 125.3°Cat760mmHg
Molecular Weight 147.432
Flash Point 44.3°C
Transport Information
Appearance
Safety Moderately toxic by ingestion. Mildly toxic by inhalation and skin contact. A skin and severe eye irritant. When heated to decomposition it emits toxic fumes of Cl⁻. See also CHLORINATED HYDROCARBONS, ALIPHATIC.
Risk Codes R20/21/22; R36/37/38
Molecular Structure
Hazard Symbols
Synonyms 1,1,2-Trichloropropane
PSA 0.00000
LogP 2.41740

Synthetic route

: 26198-63-0, 78-87-5
1,2-Dichloropropane

: 598-77-6
1,1,2-trichloropropane

Conditions

Conditions	Yield
With aluminum (III) chloride; sulfuryl dichloride at 60℃; for 1h; Reagent/catalyst; Solvent; Inert atmosphere;	33%
With chlorine im Sonnenlichte;
With antimonypentachloride

: 26198-63-0, 78-87-5
1,2-Dichloropropane

A: 3175-23-3
1,2,2-trichloropropane

B: 13116-60-4
1,1,2,2-tetrachloropropane

C: 598-77-6
1,1,2-trichloropropane

D: 96-18-4
1,2,3-trichloropropane

E: 13116-53-5
1,2,2,3-tetrachloropropane

F: 18495-30-2
1,1,2,3-tetrachloropropane

Conditions

Conditions	Yield
With sulfuryl dichloride at 55 - 60℃;	A 18% B 13.2% C 8.9% D 20.3% E 10.1% F 15.6%
With sulfuryl dichloride; 2,2'-azobis(isobutyronitrile) at 55 - 60℃;	A 19.7% B 17.8% C 6.5% D 14.8% E 11.8% F 15.6%
With sulfuryl dichloride at 55 - 60℃; Product distribution / selectivity;
With chlorine; dimethyl 2,2'-azobis(isobutyrate) In tetrachloromethane at 70℃; under 8517.48 Torr; for 32h; Product distribution / selectivity; Inert atmosphere;

...Expand

: 187737-37-7
propene

: 598-77-6
1,1,2-trichloropropane

Conditions

Conditions	Yield
With chlorine at 52 - 65℃; im Dunkeln;

: 26198-63-0, 78-87-5
1,2-Dichloropropane

A: 598-77-6
1,1,2-trichloropropane

B: 96-18-4
1,2,3-trichloropropane

Conditions

Conditions	Yield
With Iodine monochloride at 160℃;
With iron(III) chloride; chlorine at 100℃; under 7224.57 Torr; for 5h; Product distribution / selectivity; Inert atmosphere;
With aluminum (III) chloride; sulfuryl dichloride; iodine at 55 - 60℃; Reagent/catalyst;
With aluminum (III) chloride; sulfuryl dichloride at 55 - 60℃; for 0.5h;
With aluminum (III) chloride; chlorine In tetrachloromethane at 60℃; for 1h; Inert atmosphere; Overall yield = 22 %;

: 540-54-5
1-Chloropropane

: 598-77-6
1,1,2-trichloropropane

Conditions

Conditions	Yield
With chlorine
With antimonypentachloride

: 78-99-9
1,1-dichloropropane

: 598-77-6
1,1,2-trichloropropane

Conditions

Conditions	Yield
With chlorine im Sonnenlichte;
With chlorine
With antimonypentachloride

: 26198-63-0, 78-87-5
1,2-Dichloropropane

: 7647-18-9
antimonypentachloride

: 598-77-6
1,1,2-trichloropropane

: 67-66-3
chloroform

: 78-99-9
1,1-dichloropropane

: 7647-18-9
antimonypentachloride

: 598-77-6
1,1,2-trichloropropane

...Expand

: 26198-63-0, 78-87-5
1,2-Dichloropropane

: 7782-50-5
chlorine

iron: iron

: 598-77-6
1,1,2-trichloropropane

Conditions

Conditions	Yield
bei Siedetemperatur; 1.2-dichloro-propane;

...Expand

: 7446-70-0
aluminium trichloride

: 26198-63-0, 78-87-5
1,2-Dichloropropane

: 7782-50-5
chlorine

A: 3175-23-3
1,2,2-trichloropropane

B: 598-77-6
1,1,2-trichloropropane

...Expand

: 187737-37-7
propene

: 7782-50-5
chlorine

iron: iron

A: 3175-23-3
1,2,2-trichloropropane

B: 26198-63-0, 78-87-5
1,2-Dichloropropane

C: 598-77-6
1,1,2-trichloropropane

...Expand

: 26198-63-0, 78-87-5
1,2-Dichloropropane

: 7782-50-5
chlorine

iron: iron

A: 598-77-6
1,1,2-trichloropropane

B: 96-18-4
1,2,3-trichloropropane

Conditions

Conditions	Yield
at 50 - 55℃; im UV-Licht.Irradiation; 1.2-dichloro-propane;

...Expand

: 7791-25-5
sulfuryl dichloride

: 26198-63-0, 78-87-5
1,2-Dichloropropane

: 105-74-8
dilauryl peroxide

A: 3175-23-3
1,2,2-trichloropropane

B: 598-77-6
1,1,2-trichloropropane

C: 96-18-4
1,2,3-trichloropropane

Conditions

Conditions	Yield
Product distribution; 1.2-dichloro-propane;

...Expand

: 7791-25-5
sulfuryl dichloride

: 26198-63-0, 78-87-5
1,2-Dichloropropane

: 94-36-0
dibenzoyl peroxide

A: 3175-23-3
1,2,2-trichloropropane

B: 598-77-6
1,1,2-trichloropropane

C: 96-18-4
1,2,3-trichloropropane

Conditions

Conditions	Yield
Product distribution; 1.2-dichloro-propane;

...Expand

: 187737-37-7
propene

: 7782-50-5
chlorine

A: 3175-23-3
1,2,2-trichloropropane

B: 26198-63-0, 78-87-5
1,2-Dichloropropane

C: 598-77-6
1,1,2-trichloropropane

D: 96-18-4
1,2,3-trichloropropane

Conditions

Conditions	Yield
at 52 - 66℃; in Gegenwart von fluessigen Anteilen des Reaktionsprodukts; aus 3 Mol Propylen und l Mol Chlor im Dunkeln;

...Expand

: 187737-37-7
propene

: 7782-50-5
chlorine

aqueous KOH: aqueous KOH

A: 3175-23-3
1,2,2-trichloropropane

B: 26198-63-0, 78-87-5
1,2-Dichloropropane

C: 598-77-6
1,1,2-trichloropropane

D: 96-18-4
1,2,3-trichloropropane

Conditions

Conditions	Yield
at 52 - 66℃; aus 3 Mol Propylen und l Mol Chlor im Dunkeln;

...Expand

: 187737-37-7
propene

: 7782-50-5
chlorine

iodo-KI: iodo-KI

A: 3175-23-3
1,2,2-trichloropropane

B: 26198-63-0, 78-87-5
1,2-Dichloropropane

C: 598-77-6
1,1,2-trichloropropane

D: 96-18-4
1,2,3-trichloropropane

Conditions

Conditions	Yield
at 52 - 66℃; aus 3 Mol Propylen und l Mol Chlor im Dunkeln;

...Expand

: 142-28-9
1,3-Dichloropropane

: 627-30-5
1-chloro-3-hydroxypropane

A: 930-37-0
glycidyl methyl ether

B: 1436-34-6
1,2-Epoxyhexane

C: 78-88-6
2,3-Dichloroprop-1-ene

D: 5976-47-6
2-chloroallyl alcohol

E: 3175-23-3
1,2,2-trichloropropane

F: 26198-63-0, 78-87-5
1,2-Dichloropropane

G: 10061-01-5
(Z)-1,3-dichloropropene

H: 13116-58-0
1,2,3-trichloro-1-propene

I: 96-19-5, 13116-58-0, 13116-57-9
(1Z)-1,2,3-trichloroprop-1-ene

J: 2953-50-6
1,3,3-trichloro-propene

K: 2598-01-8
1t,3,3-trichloro-propene

L: 124-48-1
chlorodibromomethane

M: 598-77-6
1,1,2-trichloropropane

N: 616-23-9
2,3-Dichloro-1-propanol

O: 96-23-1
1,3-Dichloro-2-propanol

P: 96-18-4
1,2,3-trichloropropane

Q: 563-57-5
3,3-dichloropropene

R: 2567-14-8
3,3-dichloroallyl chloride

S: 75-07-0
acetaldehyde

T: 107-18-6
allyl alcohol

U: 116-09-6
hydroxy-2-propanone

V: 78-95-5
chloroacetone

W: 120-92-3
cyclopentanone

X: 108-90-7
chlorobenzene

Y: 67-63-0
isopropyl alcohol

Z: 96-24-2
3-monochloro-1,2-propanediol

[: 107-02-8
acrolein

\: 106-89-8
epichlorohydrin

]: 10061-02-6
(E)-1,3-dichloro-prop-1-ene

Conditions

Conditions	Yield
With sodium hydroxide; water at 45 - 62.4℃; under 112.511 - 750.075 Torr; Product distribution / selectivity;

...Expand

: 26198-63-0, 78-87-5
1,2-Dichloropropane

A: 3175-23-3
1,2,2-trichloropropane

B: 13116-60-4
1,1,2,2-tetrachloropropane

C: 598-77-6
1,1,2-trichloropropane

D: 96-18-4
1,2,3-trichloropropane

E: 13116-53-5
1,2,2,3-tetrachloropropane

F: 18495-30-2
1,1,2,3-tetrachloropropane

G: 15104-61-7
1,1,2,3,3-pentachloropropane

Conditions

Conditions	Yield
With sulfuryl dichloride; 2,2'-azobis(isobutyronitrile) at 55 - 60℃;

...Expand

: 26198-63-0, 78-87-5
1,2-Dichloropropane

A: 3175-23-3
1,2,2-trichloropropane

B: 13116-60-4
1,1,2,2-tetrachloropropane

C: 598-77-6
1,1,2-trichloropropane

D: 96-18-4
1,2,3-trichloropropane

E: 18495-30-2
1,1,2,3-tetrachloropropane

Conditions

Conditions	Yield
With chlorine; 2,2'-azobis-(2,4-dimethylvaleronitrile) In tetrachloromethane at 70℃; under 6723.1 Torr; for 3.26667h; Product distribution / selectivity; Inert atmosphere;

...Expand

: 75-29-6
isopropyl chloride

: 598-77-6
1,1,2-trichloropropane

Conditions

Conditions	Yield
With aluminum (III) chloride; sulfuryl dichloride at 55 - 60℃;

: 26198-63-0, 78-87-5
1,2-Dichloropropane

A: 598-77-6
1,1,2-trichloropropane

B: 96-18-4
1,2,3-trichloropropane

C: 16714-68-4
1,1,2,2,3-pentachloropropane

Conditions

Conditions	Yield
With aluminum (III) chloride; sulfuryl dichloride; sodium iodate at 60℃; for 4h;	A 1.4 g B 0.8 g C 2.3 g

...Expand

: 26198-63-0, 78-87-5
1,2-Dichloropropane

A: 598-77-6
1,1,2-trichloropropane

B: 96-18-4
1,2,3-trichloropropane

C: 13116-53-5
1,2,2,3-tetrachloropropane

D: 16714-68-4
1,1,2,2,3-pentachloropropane

Conditions

Conditions	Yield
With aluminum (III) chloride; sulfuryl dichloride; iodine at 55 - 70℃; for 7h; Inert atmosphere;

...Expand

: 26198-63-0, 78-87-5
1,2-Dichloropropane

A: 598-77-6
1,1,2-trichloropropane

B: 96-18-4
1,2,3-trichloropropane

C: 16714-68-4
1,1,2,2,3-pentachloropropane

D: 15600-01-8
1,1,2,2,3,3-hexachloropropane

Conditions

Conditions	Yield
With aluminum (III) chloride; iodine; chlorine In dichloromethane at 70℃; under 7224.57 - 7741.73 Torr; for 2h; Sealed tube;

...Expand

: 598-77-6
1,1,2-trichloropropane

: 430-93-3
2-chloro-1,1-difluoro-propane

Conditions

Conditions	Yield
With hydrogen fluoride; mercury(II) oxide at 100℃;

: 598-77-6
1,1,2-trichloropropane

: 7799-55-5
1,2-dichloro-1-fluoro-propane

Conditions

Conditions	Yield
With hydrogen fluoride; mercury(II) oxide at 100℃;

: 598-77-6
1,1,2-trichloropropane

: 563-58-6
1,1-dichloropropene

Conditions

Conditions	Yield
With sodium hydroxide
With benzyltrimethylammonium chloride; sodium hydroxide In water at 70℃; for 4h;
With sodium hydroxide

: 598-77-6
1,1,2-trichloropropane

: 18495-30-2
1,1,2,3-tetrachloropropane

Conditions

Conditions	Yield
With aluminium trichloride; chlorine

: 598-77-6
1,1,2-trichloropropane

: 201230-82-2
carbon monoxide

: 71-43-2
benzene

A: 778-66-5
1,1-diphenyl-1-propene

B: 1005420-27-8, 10474-32-5, 887255-49-4
(±)-2-methyl-2-phenyl-2,3-dihydro-1H-inden-1-one

Conditions

Conditions	Yield
With aluminium trichloride at 24 - 27℃; for 3h;

...Expand

1,1,2-trichloropropane: 1,1,2-trichloropropane

...Expand

: 598-77-6
1,1,2-trichloropropane

20 percent NaOH: 20 percent NaOH

: 563-58-6
1,1-dichloropropene

: 598-77-6
1,1,2-trichloropropane

: 7647-18-9
antimonypentachloride

: 64240-29-5
1,1,1,2,2-pentachloropropane

Conditions

Conditions	Yield
at 155℃;

: 598-77-6
1,1,2-trichloropropane

: 7664-39-3
hydrogen fluoride

mercury oxide: mercury oxide

A: 430-93-3
2-chloro-1,1-difluoro-propane

B: 7799-55-5
1,2-dichloro-1-fluoro-propane

C: 66794-35-2
1,1,2-trifluoropropane

Conditions

Conditions	Yield
at 100℃;

...Expand

1,1,2-Trichloropropane Chemical Properties

IUPAC Name: 1,1,2-Trichloropropane
Synonyms: 1,1,2-Trichloropropane ;propane, 1,1,2-trichloro-
CAS NO:598-77-6
Molecular Formula of 1,1,2-Trichloropropane(CAS NO.598-77-6):C₃H₅Cl₃
Molecular Weight of 1,1,2-Trichloropropane(CAS NO.598-77-6):147.43
Molecular Structure of 1,1,2-Trichloropropane(CAS NO.598-77-6):
EINECS: 209-951-8
Index of Refraction:1.45
Surface Tension: 28.7 dyne/cm
Density: 1.305 g/cm³
Flash Point: 44.3 °C
Enthalpy of Vaporization: 34.82 kJ/mol
Boiling Point: 125.3 °C at 760 mmHg
Vapour Pressure: 14.8 mmHg at 25°C

1,1,2-Trichloropropane Toxicity Data With Reference

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Source
rabbit	LD50	skin	14100uL/kg (14.1mL/kg)	AMA Archives of Industrial Hygiene and Occupational Medicine. Vol. 10, Pg. 61, 1954.
rat	LC50	inhalation	2000ppm/4H (2000ppm)	AMA Archives of Industrial Hygiene and Occupational Medicine. Vol. 10, Pg. 61, 1954.
rat	LD50	oral	1230mg/kg (1230mg/kg)	AMA Archives of Industrial Hygiene and Occupational Medicine. Vol. 10, Pg. 61, 1954.

1,1,2-Trichloropropane Consensus Reports

Reported in EPA TSCA Inventory.

1,1,2-Trichloropropane Safety Profile

Moderately toxic by ingestion. Mildly toxic by inhalation and skin contact. A skin and severe eye irritant. When heated to decomposition it emits toxic fumes of Cl⁻. See also CHLORINATED HYDROCARBONS, ALIPHATIC.
Risk Statements 20/21/22-36/37/38
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements 26-36/37/39
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
RTECS TZ8925000

Product Name

1,1,2-Trichloropropane

Synthetic route

1,1,2-Trichloropropane Chemical Properties

1,1,2-Trichloropropane Toxicity Data With Reference

1,1,2-Trichloropropane Consensus Reports

1,1,2-Trichloropropane Safety Profile

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