Product Name

  • Name

    Phenethyl phenylacetate

  • EINECS 203-013-1
  • CAS No. 102-20-5
  • Article Data50
  • CAS DataBase
  • Density 1.082 g/cm3
  • Solubility 15.56-22mg/L at 20-22℃
  • Melting Point 28 °C(lit.)
  • Formula C16H16O2
  • Boiling Point 359.9 °C at 760 mmHg
  • Molecular Weight 240.302
  • Flash Point 145.8 °C
  • Transport Information
  • Appearance
  • Safety 26-36
  • Risk Codes 36/38
  • Molecular Structure Molecular Structure of 102-20-5 (Phenethyl phenylacetate)
  • Hazard Symbols IrritantXi
  • Synonyms Benzylcarbinyl a-toluate;NSC 6676;Phenethyl phenylacetate;Phenylethyl phenylacetate;b-Phenylethyl phenylacetate;Aceticacid, phenyl-, phenethyl ester (6CI,7CI,8CI);2-Phenylethyl phenylacetate;
  • PSA 26.30000
  • LogP 3.01500

Synthetic route

2-phenylethanol
60-12-8

2-phenylethanol

A

phenyl-acetic acid phenethyl ester
102-20-5

phenyl-acetic acid phenethyl ester

B

phenylacetaldehyde
122-78-1

phenylacetaldehyde

Conditions
ConditionsYield
With silica gel; 4-acetylamino-2,2,6,6-tetramethylpiperidine-1-oxoammonium perchlorate In dichloromethaneA 4%
B 99%
With pyridine; 4-acetylamino-2,2,6,6-tetramethylpiperidine-N-oxyl; iodine; sodium hydrogencarbonate In dichloromethane; water at 20 - 25℃; for 3h;A 58.7%
B 41.3%
With oxygen at 120℃; for 5h; Neat (no solvent);
With pyridine; 4-acetylamino-2,2,6,6-tetramethyl-1-piperidinoxy; iodine; sodium hydrogencarbonate In dichloromethane; water at 20 - 22℃; for 3h; Catalytic behavior; Time;A 71 %Chromat.
B 23 %Chromat.
With 2,6-dimethylpyridine; 4-acetylamino-2,2,6,6-tetramethyl-1-piperidinoxy; iodine; sodium hydrogencarbonate In dichloromethane; water at 20 - 22℃; for 3h; Catalytic behavior; Time;A 12 %Chromat.
B 86 %Chromat.
phenylacetic acid
103-82-2

phenylacetic acid

2-phenylethanol
60-12-8

2-phenylethanol

phenyl-acetic acid phenethyl ester
102-20-5

phenyl-acetic acid phenethyl ester

Conditions
ConditionsYield
With potassium hydroxide98.6%
With C10H10Zr(2+)*2CF3O3S(1-)*C4H8O at 80℃; for 24h; Sealed tube;95%
With silica gel-immobilized perchloric acid at 80℃; for 6h; Fischer esterification; Inert atmosphere; Neat (no solvent);94%
2-phenylethanol
60-12-8

2-phenylethanol

phenyl-acetic acid phenethyl ester
102-20-5

phenyl-acetic acid phenethyl ester

Conditions
ConditionsYield
With periodic acid; pyridinium chlorochromate In acetonitrile at 0 - 20℃; for 2h;94%
With sodium bromite In water; acetic acid for 10h; Ambient temperature;91%
With peracetic acid; sodium bromide In ethyl acetate at 39.9℃; for 2h;86%
2-phenylethanol
60-12-8

2-phenylethanol

tert-butylamine
75-64-9

tert-butylamine

A

phenyl-acetic acid phenethyl ester
102-20-5

phenyl-acetic acid phenethyl ester

B

2-methyl-N-phenethylpropan-2-amine
24070-10-8

2-methyl-N-phenethylpropan-2-amine

Conditions
ConditionsYield
With 3 A molecular sieve; potassium carbonate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene; [Ru(p-cumene)Cl2]2 In toluene at 110℃; for 24h; Product distribution; Further Variations:; Catalysts;A 7%
B 88%
With 3 A molecular sieve; potassium carbonate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene; [Ru(p-cumene)Cl2]2 In toluene at 110℃; for 24h;A 61%
B n/a
phenylacetaldehyde
122-78-1

phenylacetaldehyde

phenyl-acetic acid phenethyl ester
102-20-5

phenyl-acetic acid phenethyl ester

Conditions
ConditionsYield
With Rh(PhBP3)(H)2(NCMe); hydrogen In toluene at 20℃; under 760.051 Torr; for 0.166667h; Tishchenko reaction;85%
2-phenylethanol
60-12-8

2-phenylethanol

phenylacetylene
536-74-3

phenylacetylene

A

phenylacetic acid
103-82-2

phenylacetic acid

B

phenyl-acetic acid phenethyl ester
102-20-5

phenyl-acetic acid phenethyl ester

Conditions
ConditionsYield
With dihydrogen peroxide; methyltrioxorhenium(VII) for 48h;A 50%
B 47%
2-phenylethanol
60-12-8

2-phenylethanol

A

phenyl-acetic acid phenethyl ester
102-20-5

phenyl-acetic acid phenethyl ester

B

toluene
108-88-3

toluene

Conditions
ConditionsYield
With [RuCl2(p-cymene)(iPr2-imy)]; potassium hydroxide; tricyclohexylphosphine In 1,3,5-trimethyl-benzene at 163℃; for 18h; Inert atmosphere;A 48%
B 7%
2-phenylethanol
60-12-8

2-phenylethanol

di-n-propylamine
142-84-7

di-n-propylamine

A

phenyl-acetic acid phenethyl ester
102-20-5

phenyl-acetic acid phenethyl ester

B

2-phenyl-N,N-dipropylacetamide
25173-09-5

2-phenyl-N,N-dipropylacetamide

Conditions
ConditionsYield
With C15H22Cl2N2Ru; potassium tert-butylate In toluene for 24h; Inert atmosphere; Reflux;A 21%
B 44%
2-phenylethanol
60-12-8

2-phenylethanol

dibenzylamine
103-49-1

dibenzylamine

A

phenyl-acetic acid phenethyl ester
102-20-5

phenyl-acetic acid phenethyl ester

B

N,N-dibenzyl-2-phenylacetamide
102459-18-7

N,N-dibenzyl-2-phenylacetamide

Conditions
ConditionsYield
With C15H22Cl2N2Ru; potassium tert-butylate In toluene for 24h; Inert atmosphere; Reflux;A 19%
B 40%
phenylacetic acid
103-82-2

phenylacetic acid

A

2-phenylethanol
60-12-8

2-phenylethanol

B

phenyl-acetic acid phenethyl ester
102-20-5

phenyl-acetic acid phenethyl ester

Conditions
ConditionsYield
With rhenium-catalyst at 149℃; under 117681 Torr; Hydrogenation;
With tin(II) trifluoromethanesulfonate; tris(2,4-pentanedionato)ruthenium(III); hydrogen; [2-((diphenylphospino)methyl)-2-methyl-1,3-propanediyl]bis[diphenylphosphine] In water; toluene at 160℃; under 45004.5 Torr; for 48h; Reagent/catalyst; Autoclave;A 49 %Chromat.
B 20 %Chromat.
phenylacetic acid
103-82-2

phenylacetic acid

phenyl-acetic acid phenethyl ester
102-20-5

phenyl-acetic acid phenethyl ester

Conditions
ConditionsYield
With sulfuric acid bei der elektrolytischen Reduktion an einer Bleikathode;
With tin(II) trifluoromethanesulfonate; tris(2,4-pentanedionato)ruthenium(III); hydrogen; [2-((diphenylphospino)methyl)-2-methyl-1,3-propanediyl]bis[diphenylphosphine] In toluene at 160℃; under 45004.5 Torr; for 48h; Reagent/catalyst; Autoclave;26 %Chromat.
aluminum ethoxide
555-75-9

aluminum ethoxide

phenylacetaldehyde
122-78-1

phenylacetaldehyde

phenyl-acetic acid phenethyl ester
102-20-5

phenyl-acetic acid phenethyl ester

phenylacetyl chloride
103-80-0

phenylacetyl chloride

phenyl-acetic acid phenethyl ester
102-20-5

phenyl-acetic acid phenethyl ester

Conditions
ConditionsYield
With triphenylstannane
Ethyl 2-phenylethanoate
101-97-3

Ethyl 2-phenylethanoate

A

Phenylessigsaeurehexylester
5421-17-0

Phenylessigsaeurehexylester

B

phenyl-acetic acid phenethyl ester
102-20-5

phenyl-acetic acid phenethyl ester

C

phenylacetic acid octyl ester
122-45-2

phenylacetic acid octyl ester

Conditions
ConditionsYield
Product distribution; competition reaction with n-hexanol, n-octanol and phenylethanol; selectivity of catalysis with SiO2, also mod. with Ph-CH<(EtO)3SiO>-P(O)(OEt)(OHex) or H2SO4;
diethyl ether
60-29-7

diethyl ether

phenylacetyl chloride
103-80-0

phenylacetyl chloride

benzene
71-43-2

benzene

magnesium

magnesium

magnesium iodide

magnesium iodide

A

phenyl-acetic acid phenethyl ester
102-20-5

phenyl-acetic acid phenethyl ester

B

acid C18H18O3 of mp: 198 degree

acid C18H18O3 of mp: 198 degree

phenylacetic acid
103-82-2

phenylacetic acid

sulfuric acid
7664-93-9

sulfuric acid

phenyl-acetic acid phenethyl ester
102-20-5

phenyl-acetic acid phenethyl ester

Conditions
ConditionsYield
at 70℃; bei der Elektrolyse an einer Bleikathode.Diazotization;
phenylacetic acid
103-82-2

phenylacetic acid

rhenium

rhenium

A

2-phenylethanol
60-12-8

2-phenylethanol

B

phenyl-acetic acid phenethyl ester
102-20-5

phenyl-acetic acid phenethyl ester

Conditions
ConditionsYield
at 150℃; under 117681 Torr; Hydrogenation;
2-phenylethanol
60-12-8

2-phenylethanol

sulfuric acid
7664-93-9

sulfuric acid

dichromate

dichromate

A

phenyl-acetic acid phenethyl ester
102-20-5

phenyl-acetic acid phenethyl ester

B

benzaldehyde
100-52-7

benzaldehyde

C

acetic acid
64-19-7

acetic acid

D

benzoic acid
65-85-0

benzoic acid

2-phenylethanol
60-12-8

2-phenylethanol

benzyl alcohol
100-51-6

benzyl alcohol

A

benzyl 2-phenylacetate
102-16-9

benzyl 2-phenylacetate

B

benzoic acid benzyl ester
120-51-4

benzoic acid benzyl ester

C

2-Phenylethyl benzoate
94-47-3

2-Phenylethyl benzoate

D

phenyl-acetic acid phenethyl ester
102-20-5

phenyl-acetic acid phenethyl ester

Conditions
ConditionsYield
With magnesium nitride; [RuCl2(p-cymene)(iPr2-imy)]; potassium tert-butylate; tricyclohexylphosphine tetrafluoroborate In toluene at 110℃; for 24h; Schlenk technique; Inert atmosphere;
1-Phenylethanol
98-85-1, 13323-81-4

1-Phenylethanol

2-phenylethanol
60-12-8

2-phenylethanol

A

phenyl-acetic acid phenethyl ester
102-20-5

phenyl-acetic acid phenethyl ester

B

acetophenone
98-86-2

acetophenone

Conditions
ConditionsYield
With magnesium nitride; [RuCl2(p-cymene)(iPr2-imy)]; potassium tert-butylate; tricyclohexylphosphine tetrafluoroborate In toluene at 110℃; for 24h; Schlenk technique; Inert atmosphere;
phenylacetic acid
103-82-2

phenylacetic acid

1,1-diphenylethanol
599-67-7

1,1-diphenylethanol

2-phenylethanol
60-12-8

2-phenylethanol

4-nitrobenzaldehdye
555-16-8

4-nitrobenzaldehdye

4-methoxy-benzaldehyde
123-11-5

4-methoxy-benzaldehyde

4-methoxy-aniline
104-94-9

4-methoxy-aniline

2,2-Dimethyl-1,3-propanediol
126-30-7

2,2-Dimethyl-1,3-propanediol

A

1,1-Diphenylethylene
530-48-3

1,1-Diphenylethylene

B

4-methoxy-N-(4-nitrobenzylidene)aniline
5455-87-8

4-methoxy-N-(4-nitrobenzylidene)aniline

C

p-methoxybenzaldehyde neopentyl glycol acetal
6290-08-0

p-methoxybenzaldehyde neopentyl glycol acetal

D

phenyl-acetic acid phenethyl ester
102-20-5

phenyl-acetic acid phenethyl ester

E

N-(4-methoxy benzylidene)-4-methoxyaniline
1749-08-2

N-(4-methoxy benzylidene)-4-methoxyaniline

Conditions
ConditionsYield
With toluene-4-sulfonic acid In toluene for 48h; Inert atmosphere; Reflux; Dean-Stark;A 99 %Spectr.
B 75 %Spectr.
C 72 %Spectr.
D 59 %Spectr.
E 5 %Spectr.
phenylacetic acid
103-82-2

phenylacetic acid

1,1-diphenylethanol
599-67-7

1,1-diphenylethanol

2-phenylethanol
60-12-8

2-phenylethanol

4-chlorobenzaldehyde
104-88-1

4-chlorobenzaldehyde

4-nitrobenzaldehdye
555-16-8

4-nitrobenzaldehdye

4-methoxy-aniline
104-94-9

4-methoxy-aniline

2,2-Dimethyl-1,3-propanediol
126-30-7

2,2-Dimethyl-1,3-propanediol

A

1,1-Diphenylethylene
530-48-3

1,1-Diphenylethylene

B

4-methoxy-N-(4-nitrobenzylidene)aniline
5455-87-8

4-methoxy-N-(4-nitrobenzylidene)aniline

C

2-(4-chlorophenyl)-5,5-dimethyl-1,3-dioxane
6283-10-9

2-(4-chlorophenyl)-5,5-dimethyl-1,3-dioxane

D

5,5-dimethyl-2-(4-nitro-phenyl)-[1,3]dioxane
838-42-6

5,5-dimethyl-2-(4-nitro-phenyl)-[1,3]dioxane

E

N-(4-chlorobenzylidene)-4-methoxyaniline
1749-03-7

N-(4-chlorobenzylidene)-4-methoxyaniline

F

phenyl-acetic acid phenethyl ester
102-20-5

phenyl-acetic acid phenethyl ester

Conditions
ConditionsYield
With toluene-4-sulfonic acid In toluene for 48h; Inert atmosphere; Reflux; Dean-Stark;A 99 %Spectr.
B 52 %Spectr.
C 52 %Spectr.
D 48 %Spectr.
E 43 %Spectr.
F 99 %Spectr.
phenylacetic acid
103-82-2

phenylacetic acid

1,1-diphenylethanol
599-67-7

1,1-diphenylethanol

2,4-dinitrobenzaldehyde
528-75-6

2,4-dinitrobenzaldehyde

2-phenylethanol
60-12-8

2-phenylethanol

4-chloro-aniline
106-47-8

4-chloro-aniline

2,2-Dimethyl-1,3-propanediol
126-30-7

2,2-Dimethyl-1,3-propanediol

2,4-Dimethoxybenzaldehyde
613-45-6

2,4-Dimethoxybenzaldehyde

A

1,1-Diphenylethylene
530-48-3

1,1-Diphenylethylene

B

phenyl-acetic acid phenethyl ester
102-20-5

phenyl-acetic acid phenethyl ester

C

2-(2,4-dimethoxyphenyl)-5,5-dimethyl-1,3-dioxane
1620217-69-7

2-(2,4-dimethoxyphenyl)-5,5-dimethyl-1,3-dioxane

D

4-chloro-N-(2,4-dinitrobenzylidene)aniline
354538-08-2

4-chloro-N-(2,4-dinitrobenzylidene)aniline

Conditions
ConditionsYield
With toluene-4-sulfonic acid In toluene for 48h; Inert atmosphere; Reflux; Dean-Stark;A 99 %Spectr.
B 99 %Spectr.
C 74 %Spectr.
D 83 %Spectr.
phenylacetic acid
103-82-2

phenylacetic acid

1,1-diphenylethanol
599-67-7

1,1-diphenylethanol

2,4-dinitrobenzaldehyde
528-75-6

2,4-dinitrobenzaldehyde

2-phenylethanol
60-12-8

2-phenylethanol

4-methoxy-aniline
104-94-9

4-methoxy-aniline

2,2-Dimethyl-1,3-propanediol
126-30-7

2,2-Dimethyl-1,3-propanediol

phenylboronic acid
98-80-6

phenylboronic acid

A

1,1-Diphenylethylene
530-48-3

1,1-Diphenylethylene

B

N-(2,4-dinitrobenzylidene)-4-methoxyaniline
354538-06-0

N-(2,4-dinitrobenzylidene)-4-methoxyaniline

C

phenyl-acetic acid phenethyl ester
102-20-5

phenyl-acetic acid phenethyl ester

D

5,5-dimethyl-2-phenyl-1,3,2-dioxaborinane
5123-13-7

5,5-dimethyl-2-phenyl-1,3,2-dioxaborinane

Conditions
ConditionsYield
With toluene-4-sulfonic acid In toluene for 48h; Inert atmosphere; Reflux; Dean-Stark;A 98 %Spectr.
B 93 %Spectr.
C 99 %Spectr.
D 99 %Spectr.
phenylacetic acid
103-82-2

phenylacetic acid

1,1-diphenylethanol
599-67-7

1,1-diphenylethanol

2,4-dinitrobenzaldehyde
528-75-6

2,4-dinitrobenzaldehyde

2-phenylethanol
60-12-8

2-phenylethanol

pentafluorophenylboronic acid
1582-24-7

pentafluorophenylboronic acid

4-methoxy-aniline
104-94-9

4-methoxy-aniline

2,2-Dimethyl-1,3-propanediol
126-30-7

2,2-Dimethyl-1,3-propanediol

A

1,1-Diphenylethylene
530-48-3

1,1-Diphenylethylene

B

N-(2,4-dinitrobenzylidene)-4-methoxyaniline
354538-06-0

N-(2,4-dinitrobenzylidene)-4-methoxyaniline

C

phenyl-acetic acid phenethyl ester
102-20-5

phenyl-acetic acid phenethyl ester

D

(2,3,4,5,6-pentafluorophenyl)-5,5-dimethyl-1,3,2-dioxaborinane
1262967-46-3

(2,3,4,5,6-pentafluorophenyl)-5,5-dimethyl-1,3,2-dioxaborinane

Conditions
ConditionsYield
With toluene-4-sulfonic acid In toluene for 48h; Inert atmosphere; Reflux; Dean-Stark;A 99 %Spectr.
B 97 %Spectr.
C 99 %Spectr.
D 74 %Spectr.
phenylacetic acid
103-82-2

phenylacetic acid

1,1-diphenylethanol
599-67-7

1,1-diphenylethanol

2,4-dinitrobenzaldehyde
528-75-6

2,4-dinitrobenzaldehyde

2-phenylethanol
60-12-8

2-phenylethanol

4-methoxy-aniline
104-94-9

4-methoxy-aniline

2,2-Dimethyl-1,3-propanediol
126-30-7

2,2-Dimethyl-1,3-propanediol

2,4-Dimethoxybenzaldehyde
613-45-6

2,4-Dimethoxybenzaldehyde

A

1,1-Diphenylethylene
530-48-3

1,1-Diphenylethylene

B

N-(2,4-dinitrobenzylidene)-4-methoxyaniline
354538-06-0

N-(2,4-dinitrobenzylidene)-4-methoxyaniline

C

phenyl-acetic acid phenethyl ester
102-20-5

phenyl-acetic acid phenethyl ester

D

2-(2,4-dimethoxyphenyl)-5,5-dimethyl-1,3-dioxane
1620217-69-7

2-(2,4-dimethoxyphenyl)-5,5-dimethyl-1,3-dioxane

E

N-(2,4-dimethoxybenzylidene)-4-methoxyaniline
123794-61-6

N-(2,4-dimethoxybenzylidene)-4-methoxyaniline

Conditions
ConditionsYield
With toluene-4-sulfonic acid In toluene for 48h; Inert atmosphere; Reflux; Dean-Stark;A 99 %Spectr.
B 84 %Spectr.
C 96 %Spectr.
D 77 %Spectr.
E 9 %Spectr.
phenylacetic acid
103-82-2

phenylacetic acid

1,1-diphenylethanol
599-67-7

1,1-diphenylethanol

2,4-dinitrobenzaldehyde
528-75-6

2,4-dinitrobenzaldehyde

2-phenylethanol
60-12-8

2-phenylethanol

2,2-Dimethyl-1,3-propanediol
126-30-7

2,2-Dimethyl-1,3-propanediol

aniline
62-53-3

aniline

2,4-Dimethoxybenzaldehyde
613-45-6

2,4-Dimethoxybenzaldehyde

A

1,1-Diphenylethylene
530-48-3

1,1-Diphenylethylene

B

phenyl-acetic acid phenethyl ester
102-20-5

phenyl-acetic acid phenethyl ester

C

2-(2,4-dimethoxyphenyl)-5,5-dimethyl-1,3-dioxane
1620217-69-7

2-(2,4-dimethoxyphenyl)-5,5-dimethyl-1,3-dioxane

D

1-(2,4-dinitrophenyl)-N-phenylmethanimine
149742-71-2, 97946-02-6

1-(2,4-dinitrophenyl)-N-phenylmethanimine

Conditions
ConditionsYield
With toluene-4-sulfonic acid In toluene for 48h; Inert atmosphere; Reflux; Dean-Stark;A 99 %Spectr.
B 98 %Spectr.
C 80 %Spectr.
D 86 %Spectr.
phenylacetic acid
103-82-2

phenylacetic acid

1,1-diphenylethanol
599-67-7

1,1-diphenylethanol

2,4-dinitrobenzaldehyde
528-75-6

2,4-dinitrobenzaldehyde

2-phenylethanol
60-12-8

2-phenylethanol

cyclohexylamine
108-91-8

cyclohexylamine

2,2-Dimethyl-1,3-propanediol
126-30-7

2,2-Dimethyl-1,3-propanediol

2,4-Dimethoxybenzaldehyde
613-45-6

2,4-Dimethoxybenzaldehyde

A

1,1-Diphenylethylene
530-48-3

1,1-Diphenylethylene

B

phenyl-acetic acid phenethyl ester
102-20-5

phenyl-acetic acid phenethyl ester

C

2-(2,4-dimethoxyphenyl)-5,5-dimethyl-1,3-dioxane
1620217-69-7

2-(2,4-dimethoxyphenyl)-5,5-dimethyl-1,3-dioxane

D

N-(2,4-dinitrobenzylidene)cyclohexanamine
553662-91-2

N-(2,4-dinitrobenzylidene)cyclohexanamine

Conditions
ConditionsYield
With toluene-4-sulfonic acid In toluene for 48h; Inert atmosphere; Reflux; Dean-Stark;A 99 %Spectr.
B 43 %Spectr.
C 95 %Spectr.
D 72 %Spectr.
phenylacetic acid
103-82-2

phenylacetic acid

1,1-diphenylethanol
599-67-7

1,1-diphenylethanol

2,4-dinitrobenzaldehyde
528-75-6

2,4-dinitrobenzaldehyde

2-phenylethanol
60-12-8

2-phenylethanol

benzaldehyde
100-52-7

benzaldehyde

4-methoxy-aniline
104-94-9

4-methoxy-aniline

2,2-Dimethyl-1,3-propanediol
126-30-7

2,2-Dimethyl-1,3-propanediol

A

1,1-Diphenylethylene
530-48-3

1,1-Diphenylethylene

B

5,5-dimethyl-2-phenyl-[1,3]dioxane
776-88-5

5,5-dimethyl-2-phenyl-[1,3]dioxane

C

N-(2,4-dinitrobenzylidene)-4-methoxyaniline
354538-06-0

N-(2,4-dinitrobenzylidene)-4-methoxyaniline

D

phenyl-acetic acid phenethyl ester
102-20-5

phenyl-acetic acid phenethyl ester

E

[4-(benzylideneamino)phenyl]methanol
783-08-4

[4-(benzylideneamino)phenyl]methanol

Conditions
ConditionsYield
With toluene-4-sulfonic acid In toluene for 48h; Inert atmosphere; Reflux; Dean-Stark;A 99 %Spectr.
B 79 %Spectr.
C 92 %Spectr.
D 98 %Spectr.
E 5 %Spectr.
methanol
67-56-1

methanol

phenyl-acetic acid phenethyl ester
102-20-5

phenyl-acetic acid phenethyl ester

benzeneacetic acid methyl ester
101-41-7

benzeneacetic acid methyl ester

Conditions
ConditionsYield
With 1-butyl-3-methylimidazolium tetrachloridoferrate(III) at 146.84℃; for 6h; Reagent/catalyst;96.6%
phenyl-acetic acid phenethyl ester
102-20-5

phenyl-acetic acid phenethyl ester

di(2-phenylethyl) ether
2396-53-4

di(2-phenylethyl) ether

Conditions
ConditionsYield
With triiron dodecarbonyl; 1,1,3,3-Tetramethyldisiloxane In toluene at 100℃; for 2h; Inert atmosphere; Schlenk technique;85%
phenyl-acetic acid phenethyl ester
102-20-5

phenyl-acetic acid phenethyl ester

allyl bromide
106-95-6

allyl bromide

phenethyl 2-phenylpent-4-enoate
1181399-18-7

phenethyl 2-phenylpent-4-enoate

Conditions
ConditionsYield
With caesium hydroxide monohydrate; 2,7-bis[O(9)-allylhydrocinchonidinium-N-methyl]naphthalene dibromide In dichloromethane at -40℃; for 23h; Inert atmosphere; optical yield given as %ee; enantioselective reaction;77%
phenyl-acetic acid phenethyl ester
102-20-5

phenyl-acetic acid phenethyl ester

2-phenylethyl 2-oxo-2-phenylacetate
244263-79-4

2-phenylethyl 2-oxo-2-phenylacetate

Conditions
ConditionsYield
Stage #1: phenyl-acetic acid phenethyl ester With tert.-butylhydroperoxide; copper(II) oxide In water at 110℃; for 4.5h;
Stage #2: With pyridine In water at 50℃; for 4h;
61%
phenyl-acetic acid phenethyl ester
102-20-5

phenyl-acetic acid phenethyl ester

styrene
292638-84-7

styrene

Conditions
ConditionsYield
at 315 - 320℃;
phenyl-acetic acid phenethyl ester
102-20-5

phenyl-acetic acid phenethyl ester

A

styrene
292638-84-7

styrene

B

phenylacetic acid
103-82-2

phenylacetic acid

Conditions
ConditionsYield
at 315 - 320℃;
phenyl-acetic acid phenethyl ester
102-20-5

phenyl-acetic acid phenethyl ester

benzylmagnesium chloride
6921-34-2

benzylmagnesium chloride

tribenzylcarbinol
6712-97-6

tribenzylcarbinol

Conditions
ConditionsYield
With diethyl ether
phenyl-acetic acid phenethyl ester
102-20-5

phenyl-acetic acid phenethyl ester

styrene oxide
96-09-3

styrene oxide

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 315 - 320 °C
2: peroxybenzoic acid; chloroform / 0 °C
View Scheme
phenyl-acetic acid phenethyl ester
102-20-5

phenyl-acetic acid phenethyl ester

2-phenyl-acrylic Acid Phenethyl Ester
880348-56-1

2-phenyl-acrylic Acid Phenethyl Ester

Conditions
ConditionsYield
With tetra-(n-butyl)ammonium iodide; potassium carbonate; paraformaldehyde In diethyl ether; toluene1.48 g (60%)
phenyl-acetic acid phenethyl ester
102-20-5

phenyl-acetic acid phenethyl ester

allyl bromide
106-95-6

allyl bromide

(+/-)-phenethyl 2-phenylpent-4-enoate
1181399-16-5

(+/-)-phenethyl 2-phenylpent-4-enoate

Conditions
ConditionsYield
With caesium hydroxide monohydrate; tetrabutylammomium bromide In dichloromethane at 0 - 20℃; for 16h; Inert atmosphere;
phenyl-acetic acid phenethyl ester
102-20-5

phenyl-acetic acid phenethyl ester

2-phenylethanol
60-12-8

2-phenylethanol

Conditions
ConditionsYield
Stage #1: phenyl-acetic acid phenethyl ester With iron (II) stearate; ethylenediamine In toluene at 20℃; for 0.0833333h; Inert atmosphere; Schlenk technique;
Stage #2: In toluene at 100℃; for 20h; Inert atmosphere; Schlenk technique;
84 %Chromat.
Stage #1: phenyl-acetic acid phenethyl ester With C33H58FeN3PSi2; phenylsilane In toluene at 20℃; for 4h; Inert atmosphere; Glovebox; Green chemistry;
Stage #2: With sodium hydroxide In toluene for 1h; Green chemistry;

Phenethyl Phenylacetate Chemical Properties

Name:  Phenethyl phenylacetate
Synonyms: FEMA 2866;BETA PHENYL ETHYL PHENYL ACETATE;B-PHENYLETHYL PHENYLACETATE;2-PHENYLETHYL PHENYLACETATE;PHENYL ETHYL PHENYL ACETATE;PHENYLACETIC ACID 2-PHENYLETHER ESTER;PHENYLACETIC ACID 2-PHENYLETHYL ESTER;PHENETHYL PHENYLACETATE
CAS: 102-20-5
Molecular Formula:  C16H16O2
Molecular Weight:  240.30
CAS Registry Number:  102-20-5
EINECS:  203-013-1
Density:  1.082
Melting point:  28 oC
Boiling point:  325 oC
Refractive index:  1.55
Flash point:  113 oC
FEMA:  2866
refractive index:  n20/D 1.55(lit.)
Beilstein/Gmelin: 2214383
Beilstein Reference: 3-09-00-02183
Solubility in water:  Insoluble
Vapor Pressure: 2.3E-5 (25 C)
Heat Of Vaporization: 60.6 kJ/mol

Phenethyl Phenylacetate Uses

Food additive

Phenethyl Phenylacetate Toxicity Data With Reference

RTECS  AJ3255000

Phenethyl Phenylacetate Safety Profile

Hazard Codes:  Xi
Risk Codes:  R36/38  
Safety Description:  S26;S36    
WGK Germany:  2
First Aid Measures
Ingestion
If swallowed, wash out mouth with water provided person is conscious and then call a physician.
Inhalation
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Skin
In case of contact,  wash skin with soap and plenty of water right away.
Eyes
In case of contact, flush eyes with plenty of water for 15 minutes or more.
Personal Protection
Wear protective gloves and goggles.

Phenethyl Phenylacetate Specification

This product should be kept tightly closed and stored in a cool dry place.

Small spills/leaks
Sweep up,  place in a bag and hold for waste disposal. Avoid raising dust. Ventilate area and wash spill site after material pickup is complete.

Post buying leads

About|Contact|Cas|Product Name|Molecular|Country|Encyclopedia

Message|New Cas|MSDS|Service|Advertisement|CAS DataBase|Article Data|Manufacturers | Chemical Catalog

©2008 LookChem.com,License: ICP

NO.:Zhejiang16009103

complaints:service@lookchem.com Desktop View