Phenylsilane supplier | CasNO.694-53-1

Name
PHENYLSILANE
EINECS 211-772-5
CAS No. 694-53-1
Article Data53
CAS DataBase
Density 0.877 g/mL at 25 °C(lit.)
Solubility insoluble in water
Melting Point -64 to -68°C
Formula C₆H₈Si
Boiling Point 119.3 °C at 760 mmHg
Molecular Weight 108.215
Flash Point 25.9 °C
Transport Information UN 3399 4.3/PG 2
Appearance clear colorless liquid
Safety 16-43
Risk Codes 11-14/15-20/22-36/37/38
Molecular Structure
Hazard Symbols F,Xn
Synonyms Silane,phenyl- (6CI,8CI,9CI);Monophenylsilane;NSC 179699;SIP 6750.0;Silylbenzene;Z 6047;
PSA 0.00000
LogP -0.32270

Synthetic route

: 1122-58-3
dmap

: C53H101B2Co2P5Si2

A: 694-53-1
phenylsilane

B: C54H101B2Co2N2P5Si

Conditions

Conditions	Yield
In toluene at 65℃; for 4h; Solvent; Inert atmosphere; Glovebox;	A n/a B 86%

...Expand

: 75-16-1
methylmagnesium bromide

: 6157-41-1
sodium bis(benzene-1,2-diolatophenyl)silicate

A: 768-32-1
trimethylphenylsilane

B: 766-77-8
Dimethylphenylsilane

C: 694-53-1
phenylsilane

D: 766-08-5
methylphenylsilane

Conditions

Conditions	Yield
In diethyl ether at 35℃; for 2h;	A 3% B 85% C 6% D 6%
In diethyl ether at 35℃; for 2h; Product distribution; other organometallic compound; var. ratios;	A 3% B 85% C 6% D 6%

...Expand

: 98-13-5
Phenyltrichlorosilane

: 694-53-1
phenylsilane

Conditions

Conditions	Yield
With lithium aluminium tetrahydride In diethyl ether	84%
With lithium aluminium tetrahydride Reduction;	74%
With lithium aluminium tetrahydride; diethyl ether

: 917-54-4
methyllithium

: 6157-41-1
sodium bis(benzene-1,2-diolatophenyl)silicate

A: 768-32-1
trimethylphenylsilane

B: 766-77-8
Dimethylphenylsilane

C: 694-53-1
phenylsilane

D: 766-08-5
methylphenylsilane

Conditions

Conditions	Yield
In diethyl ether at 35℃; for 2h;	A 4% B 81% C 12% D 4%
In tetrahydrofuran at 60℃; for 2h;	A 32% B 49% C 9% D 10%

...Expand

: 75-16-1
methylmagnesium bromide

: 6157-41-1
sodium bis(benzene-1,2-diolatophenyl)silicate

A: 766-77-8
Dimethylphenylsilane

B: 694-53-1
phenylsilane

C: 766-08-5
methylphenylsilane

Conditions

Conditions	Yield
In diethyl ether at 0℃; for 2.5h;	A 12% B 79% C 9%

...Expand

: 6157-41-1
sodium bis(benzene-1,2-diolatophenyl)silicate

: 694-53-1
phenylsilane

Conditions

Conditions	Yield
With lithium aluminium tetrahydride In diethyl ether at 20℃; for 2h;	72%
With lithium aluminium tetrahydride Yield given;

: 16853-85-3
lithium aluminium tetrahydride

: 98-13-5
Phenyltrichlorosilane

: 694-53-1
phenylsilane

Conditions

Conditions	Yield
In not given	69%

: 2996-92-1
phenyl trimethylsiloxane

: 694-53-1
phenylsilane

Conditions

Conditions	Yield
With N,N,N,N,N,N-hexamethylphosphoric triamide; sodium tetrahydroborate; ethyl bromide; tetraoctyl ammonium bromide In benzene-d6 at 20℃; for 24h;	49%
With Y(3+)2C12H21Si(1-)H(1-)*C4H8O; 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane In benzene-d6 at 80℃; for 12h;	8%

: 4206-75-1
phenylchlorosilane

A: 27484-20-4
1,2-diphenyldisilane

B: 50518-29-1
1,2,3-triphenyltrisilane

C: 694-53-1
phenylsilane

D: 775-12-2
diphenylsilane

Conditions

Conditions	Yield
With Mg-anode; stainless steel cathode In tetrahydrofuran for 29h; Electrolysis;	A 38% B n/a C n/a D n/a

...Expand

: 98-13-5
Phenyltrichlorosilane

A: 1631-84-1
dichlorophenylsilane

B: 694-53-1
phenylsilane

C: 4206-75-1
phenylchlorosilane

Conditions

Conditions	Yield
With sodium hydride; lithium chloride In diethylene glycol dimethyl ether at 160℃; for 14h; Inert atmosphere;	A 33% B 19% C 38%
With diisobutylaluminium hydride In toluene Solvent;

...Expand

: 4206-75-1
phenylchlorosilane

A: 27484-20-4
1,2-diphenyldisilane

B: 694-53-1
phenylsilane

C: 775-12-2
diphenylsilane

Conditions

Conditions	Yield
With lithium In tetrahydrofuran; hexane at 20℃; for 2h;	A 30% B n/a C n/a

...Expand

: 775-12-2
diphenylsilane

: 694-53-1
phenylsilane

Conditions

Conditions	Yield
With dihydrogen hexachloroplatinate

: 780-69-8
triethoxyphenylsilane

: 694-53-1
phenylsilane

Conditions

Conditions	Yield
With lithium aluminium tetrahydride In diethyl ether Heating;
With lithium aluminium tetrahydride In diethyl ether
With lithium aluminium tetrahydride In diethyl ether at 20℃;

: 775-12-2
diphenylsilane

A: 1048-08-4
tetraphenylsilane

B: 694-53-1
phenylsilane

C: 789-25-3
HSiPh3

D silane: silane

Conditions

Conditions	Yield
beim Erhitzen;

...Expand

: 775-12-2
diphenylsilane

platinum: platinum

A: 1048-08-4
tetraphenylsilane

B: 694-53-1
phenylsilane

C: 789-25-3
HSiPh3

D silane: silane

Conditions

Conditions	Yield
beim Erhitzen;

...Expand

: 81956-87-8
(η(5)-C5Me5)2HfH2

: 27484-20-4
1,2-diphenyldisilane

: 694-53-1
phenylsilane

: 1066-40-6
Trimethylsilanol

: 1310473-75-6
tris(2-pyridylthio)methyl zinc hydride

: 694-53-1
phenylsilane

: 1122-58-3
dmap

: 1416586-84-9
[[MeC(N(2,6-iPr2C6H3))CHC(Me)(NCH2CH2NMe)]Sc(H)(N(2,6-iPr2C6H3)(SiH2Ph))]

A: 1239886-72-6
[[MeC(N(2,6-iPr2C6H3))CHC(Me)(NCH2CH2NMe)]Sc=N(2,6-iPr2C6H3)(DMAP)]

B: 694-53-1
phenylsilane

Conditions

Conditions	Yield
In benzene-d6 at 25℃; for 1h; Equilibrium constant; Inert atmosphere;

...Expand

: 98-13-5
Phenyltrichlorosilane

A: 694-53-1
phenylsilane

B: 4206-75-1
phenylchlorosilane

Conditions

Conditions	Yield
With diisobutylaluminium hydride

: C35H58N3PSi3

A: 694-53-1
phenylsilane

: C29H50N3PSi2

Conditions

Conditions	Yield
In benzene-d6 at 25℃; for 24h; Thermodynamic data; Equilibrium constant; Temperature; Inert atmosphere;	A n/a B 48.5 %Spectr.

: C36H60N3PSi3

A: 694-53-1
phenylsilane

B: C30H52N3PSi2

Conditions

Conditions	Yield
In benzene-d6 at 25℃; for 20h; Thermodynamic data; Equilibrium constant; Temperature; Inert atmosphere;

: di(cyclohexa-2,5-dien-1-yl)(phenyl)silane

: 694-53-1
phenylsilane

Conditions

Conditions	Yield
With tris(pentafluorophenyl)borate In dichloromethane-d2 at 20℃; for 19h; Catalytic behavior; Glovebox; Sealed tube;

: 591-50-4
iodobenzene

: 694-53-1
phenylsilane

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: bis(tri-t-butylphosphine)palladium(0); diisopropylamine / benzene / 24 h / 20 °C / Glovebox; Sealed tube 2: tris(pentafluorophenyl)borate / dichloromethane-d2 / 19 h / 20 °C / Glovebox; Sealed tube View Scheme

: 6843-66-9
dimethoxy(diphenyl)silane

: 25015-63-8
4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

A: 694-53-1
phenylsilane

B: 775-12-2
diphenylsilane

Conditions

Conditions	Yield
With (η5-C5Me4SiMe3)2YH(thf) In benzene-d6 at 100℃; for 24h; Inert atmosphere;	A 12 %Spectr. B 40 %Spectr.

...Expand

: 108-86-1
bromobenzene

: 694-53-1
phenylsilane

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: magnesium / tetrahydrofuran / Reflux 2: lithium aluminium tetrahydride / diethyl ether / 0 °C View Scheme

: 201230-82-2
carbon monoxide

: C35H42BN4O3RhSi

A: 694-53-1
phenylsilane

: C30H34BN4O4Rh

Conditions

Conditions	Yield
In benzene at 22.84℃; under 760.051 Torr; for 18h; Equilibrium constant; Kinetics; Temperature; Inert atmosphere;

...Expand

: 119-61-9
benzophenone

: 694-53-1
phenylsilane

: 18834-17-8
bis-benzhydryloxy-phenyl-silane

Conditions

Conditions	Yield
With Et2OFe(catecholate-porous organic polymer) In benzene-d6 at 23℃; for 0.0833333h;	100%

: 694-53-1
phenylsilane

: 108-94-1
cyclohexanone

: 39579-30-1
(CyO)2SiHPh

Conditions

Conditions	Yield
With Et2OFe(catecholate-porous organic polymer) In benzene-d6 at 23℃; for 0.0333333h;	100%
Wilkinson's catalyst
Rh catalyst

: 592-42-7
1,5-Hexadien

: 694-53-1
phenylsilane

: [(phenylsilyl)methyl]cyclopentane

Conditions

Conditions	Yield
With <(CH3)5>2YCH3*THF In cyclohexane for 1h; Mechanism; Ambient temperature; other dienes; other silanes;	100%
With (C5Me5)2YCH3*THF In cyclohexane for 1h; Ambient temperature;	100%
With <(CpTMS)2YMe>2 In cyclohexane for 4h; Ambient temperature;	98%

: 694-53-1
phenylsilane

: 98-86-2
acetophenone

: phenyl(1-phenylethoxy)silane

Conditions

Conditions	Yield
With C16H11BrMnN3O3 In tetrahydrofuran at 100℃; for 3h; Reagent/catalyst; Solvent; Time; Inert atmosphere; Sealed tube; Heating; chemoselective reaction;	100%
bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate; (S,S)-2,2''-bis{(R)-1-(di-n-butylphosphino)ethyl}-1,1''-biferrocene In tetrahydrofuran at -40℃; for 48h; hydrosilylation;
With C16H25AlBN6(1+)*C19H3BF15(1-) In chloroform-d1 at 75℃; for 1.5h;

: 694-53-1
phenylsilane

: 107-15-3
ethylenediamine

: N1-(2-phenyl-[1,3,2]diazasilolidin-2-yl)-ethane-1,2-diamine

Conditions

Conditions	Yield
for 0.166667h; Substitution;	100%

: 694-53-1
phenylsilane

: 98-86-2
acetophenone

: 199123-29-0
(PhCH(Me)O)2SiHPh

Conditions

Conditions	Yield
With Et2OFe(catecholate-porous organic polymer) In benzene-d6 at 23℃; for 0.0333333h;	100%
With [{(DIPP-nacnac)CaH(thf)}2] In benzene-d6 at 50℃; for 34h; chemoselective reaction;	95 %Chromat.
With [N,N'-(2,6-pyridinediyldiethylidyne)bis[3-(diphenylphosphino)-1-propanamine]]MnH under 760.051 Torr; for 0.0666667h; Glovebox; Inert atmosphere;
With tris(2-pyridylthio)methyl zinc hydride In benzene-d6 at 20℃; for 0.75h; Catalytic behavior; Inert atmosphere;

: 98-01-1
furfural

: 694-53-1
phenylsilane

: 18752-20-0
tris(furan-2-ylmethoxy)(phenyl)silane

Conditions

Conditions	Yield
With Et2OFe(catecholate-porous organic polymer) In benzene-d6 at 23℃; for 0.0333333h; Concentration; Time;	100%
With C29H30N5PZn In benzene-d6 at 25℃; for 6h; Inert atmosphere;

: 111-66-0
oct-1-ene

: 694-53-1
phenylsilane

: octan-2-yl(phenyl)silane

Conditions

Conditions	Yield
With MesPDI; cobalt(II) stearate In tetrahydrofuran at 60℃; for 5h; Reagent/catalyst;	100%
With C22H31Cl2CoN2P In neat (no solvent) at 60℃; for 24h; Reagent/catalyst; Temperature; Sealed tube; Inert atmosphere; regioselective reaction;	92%
With 2,6-bis[1-(2,4,6-trimethylimino)ethyl]pyridine; C10H14CoO5 In toluene at 60℃; for 24h; Reagent/catalyst; Temperature; regioselective reaction;	91%
With 2,6-bis[1-(2,4,6-trimethylimino)ethyl]pyridine; cobalt(II) tetrafluoroborate hexahydrate In tetrahydrofuran at 20℃; for 4h; Catalytic behavior; Reagent/catalyst; regioselective reaction;	72 %Spectr.

: C16H38O4Si2Y(1+)*C16H44AlSi4(1-)

: 694-53-1
phenylsilane

: C16H44AlSi4(1-)*C8H18O4Y(1+)

Conditions

Conditions	Yield
In tetrahydrofuran for 17h; Inert atmosphere;	100%

: 67373-60-8
B(CH(SiMe3)2)2(OH)

: 694-53-1
phenylsilane

: PhSiH2OB{CH(SiMe3)2}2

Conditions

Conditions	Yield
With barium hexamethyldisilazide tetrahydrofuranate In benzene-d6 at 60℃; for 10h; Kinetics; Reagent/catalyst; Temperature; Inert atmosphere; Sealed tube; chemoselective reaction;	100%

: 694-53-1
phenylsilane

: 536-74-3
phenylacetylene

: phenyl(1-phenylvinyl)silane

Conditions

Conditions	Yield
With C22H28N2; cobalt(II) acetate In tetrahydrofuran at 30℃; for 3h; Catalytic behavior; Temperature; Inert atmosphere;	100%
With lithium triethylborohydride; C12H12Cl2CoN6 In tetrahydrofuran at 40℃; for 20h; Schlenk technique; Inert atmosphere; regioselective reaction;	99%
With ethylmagnesium bromide; C84H104Cl2FeN2 In tetrahydrofuran at 0℃; for 3h; Glovebox; Inert atmosphere; Schlenk technique; regioselective reaction;	92%

: 694-53-1
phenylsilane

: [Bi(C6H4CH2)2S(OTEMP)]

: [Bi(C6H4CH2)2S]2

Conditions

Conditions	Yield
In benzene-d6 at 60℃; for 96h; Inert atmosphere;	100%

: 694-53-1
phenylsilane

: 4206-75-1
phenylchlorosilane

Conditions

Conditions	Yield
With dichloromethane; eosin y at 30℃; Flow reactor; Inert atmosphere; Irradiation; Green chemistry;	99%
With hydrogenchloride In diethyl ether at 80℃; for 35.25h; Temperature; Solvent;	97%
With copper(l) iodide; copper dichloride In diethyl ether at 20℃; for 2h; Inert atmosphere;	91.7%

: 694-53-1
phenylsilane

: 98-13-5
Phenyltrichlorosilane

Conditions

Conditions	Yield
With dichloromethane; eosin y at 50℃; Reagent/catalyst; Temperature; Flow reactor; Inert atmosphere; Irradiation; Green chemistry;	99%
With trichloroisocyanuric acid In dichloromethane for 5h; Heating;	97.5%
With copper(l) iodide; copper dichloride In diethyl ether at 20℃; for 4h; Inert atmosphere;	92.9%
With tellurium tetrachloride In benzene for 6h; Heating;	75%

: 292638-84-7
styrene

: 694-53-1
phenylsilane

: 132904-49-5
(1-phenyl-ethyl)(phenyl)silane

Conditions

Conditions	Yield
With C66H106N4O6Sm2 In toluene at 60℃; for 1h; Catalytic behavior; Solvent; Temperature; Inert atmosphere; Glovebox; Schlenk technique; regioselective reaction;	99%
With Me2SiCp''2CH(SiMe3)2 In benzene for 48h; Ambient temperature;	96%
With C18H19N3Ni(1+)*C32H12BF24(1-) In 1,2-dichloro-ethane at 60℃; for 4h; Inert atmosphere;	96.7%

: 107-10-8
propylamine

: 694-53-1
phenylsilane

: 17864-07-2
(n-PrHN)3SiPh

Conditions

Conditions	Yield
With tris((4,4-dimethyl-2-oxazolinyl)phenylborate) MgMe In benzene at 20℃; for 24h; Inert atmosphere;	99%
With [(Et2N)3U][BPh4] In benzene for 10h; Substitution; Heating;	86.5%
With C18H54LaN3Si6*2C4H8O In benzene-d6 at 25℃; for 0.166667h; Inert atmosphere;	85 %Spectr.

: 694-53-1
phenylsilane

: 75-31-0
isopropylamine

: N,N'-diisopropyl-1-phenylsilanediamine

Conditions

Conditions	Yield
With tris((4,4-dimethyl-2-oxazolinyl)phenylborate) MgMe In benzene at 20℃; for 24h; Inert atmosphere;	99%
With C36H70N8O2Si4Y2 In toluene at 20℃; for 0.25h; Glovebox; Schlenk technique;	92%
at 20℃; for 56h; Substitution;

: 694-53-1
phenylsilane

: 75-64-9
tert-butylamine

: N-tert-butyl-1-phenylsilanamine

Conditions

Conditions	Yield
With C31H52N2PSi4Y In benzene-d6 at 25℃; for 1h; Reagent/catalyst; Glovebox; Inert atmosphere;	99%
With C36H70N8O2Si4Y2 In toluene at 20℃; for 0.25h; Glovebox; Schlenk technique;	96%
With [(Et2N)3U][BPh4] In benzene for 7h; Substitution;	94.8%

(S,S)-ethylene-1,2-bis(η5 -4,5,6,7-tetrahydro-1-indenyl)titanium (S)-1,1'-binapth-2,2'-diolate: (S,S)-ethylene-1,2-bis(η5 -4,5,6,7-tetrahydro-1-indenyl)titanium (S)-1,1'-binapth-2,2'-diolate

: 833-81-8
(E)-1,2-diphenylpropene

: 694-53-1
phenylsilane

: 19643-70-0
(2R)-propane-1,2-diyldibenzene

Conditions

Conditions	Yield
With n-butyllithium In tetrahydrofuran	99%
With n-butyllithium In tetrahydrofuran	0.304g (1.55 mmol, 80%)

...Expand

: 67506-90-5
dimethylbis(η5-pentamethylcyclopentadienyl)thorium

: 598-23-2
3-methyl-but-1-yne

: 694-53-1
phenylsilane

: 252195-84-9
((CH3)5C5)2Th(CCCH(CH3)2)[C(C6H5SiH2)CH(CH(CH3)2)]

Conditions

Conditions	Yield
In benzene stirring (room temp., 12 h), PhSiH3 addn., stirring (6 h); elem. anal.;	99%

...Expand

: 67605-92-9
dimethylbis(η5-pentamethylcyclopentadienyl)uranium

: 598-23-2
3-methyl-but-1-yne

: 694-53-1
phenylsilane

: 252195-79-2
((CH3)5C5)2U(CCCH(CH3)2)(C((C6H5)SiH2)C(H)CH(CH3)2)

Conditions

Conditions	Yield
In benzene stirring (4 h), PhSiH3 addn., stirring (6 h); elem. anal.;	99%

...Expand

: 110-54-3
hexane

: ([PhP(CH2SiMe2NPh)2]Ta)2(μ–η1:η2-N2)(μ-H)2

: 694-53-1
phenylsilane

: ([PhNSiMe2CH2)2PPh]TaH)(μ-H)2(μ-η1:η2-NNSiH2Ph)(Ta[PhNSiMe2CH2)2PPh])*0.5(hexane)

Conditions

Conditions	Yield
In toluene under N2; to a stirred soln. of Ta-contg. compd. (0.350 mmol) in toluenewas added phenylsilane (0.350 mmol) in the same solvent; stirring for 2 4 h at -40°C; solvent was removed under vac.; the residue was triturated under hexanesand left overnight; the ppt. was recovered on a glass frit; elem. anal.;	99%

...Expand

: 801221-16-9
[(phenyl)B(CH2P(iPr)2)3(methyl)iron(II)]

: 694-53-1
phenylsilane

: 881087-52-1
[iron(II)(phenyl)B(CH2P(iPr)2)3(hydride)(η3-H2Si(methylphenyl))]

Conditions

Conditions	Yield
In benzene reactn. of Fe compex with C6H5SiH3 at room temp. for 30 min; detd. by (1)H NMR;	99%

: 929626-72-2
Ti(Si3H5Ph3)(dmpe)2

: 694-53-1
phenylsilane

: Ti(Si4H6Ph4)(dmpe)2

Conditions

Conditions	Yield
In diethyl ether for several weeks at -20°C;	99%

: Ti(CH3)2(1,2-bis(dimethylphosphino)ethane)2

: 694-53-1
phenylsilane

: 929626-72-2
Ti(Si3H5Ph3)(dmpe)2

Conditions

Conditions	Yield
In not given byproducts: CH4, C6H5SiH2CH3; at -20°C for 4 h;	99%

: 694-53-1
phenylsilane

: 62-53-3
aniline

: 1338211-93-0
(PhHN)2SiHPh

Conditions

Conditions	Yield
With [Fe(nacnac)dippCH2SiMe3] In benzene-d6 at 20℃; for 48h;	99%
With tris((4,4-dimethyl-2-oxazolinyl)phenylborate) MgMe In benzene at 20℃; for 24h; Inert atmosphere;	97%
With [IMesMg(2,4,6-Me3C6H2){N(SiMe3)2}] In benzene at 20℃; for 15h; Inert atmosphere; Schlenk technique; Glovebox;

: 694-53-1
phenylsilane

: 244187-81-3
1,3-bis-(2,6-diisopropylphenyl)-imidazol-2-ylidene

: 1402171-53-2
1-phenyl-2,5-bis-(2,6-diisopropylphenyl)-3,4-dehydro-2,5-diazasilinane

Conditions

Conditions	Yield
at 160℃; for 5h; Inert atmosphere;	99%

: 694-53-1
phenylsilane

: 93-61-8
N-methyl-N-phenylformamide

: 121-69-7
N,N-dimethyl-aniline

Conditions

Conditions	Yield
With C27H36Cl2N2Zn at 100℃; for 20h;	99%

: 694-53-1
phenylsilane

: 185999-07-9
tert-butyl(hex-5-enyloxy)diphenylsilane

: tert-butyldiphenyl((6-(phenylsilyl)hexyl)oxy)silane

Conditions

Conditions	Yield
With (tBuPNNiPr)FeCl2; sodium triethylborohydride In toluene at -34 - 20℃; for 8h; Inert atmosphere;	99%

: 67-56-1
methanol

: 694-53-1
phenylsilane

: 2996-92-1
phenyl trimethylsiloxane

Conditions

Conditions	Yield
With potassium hexamethylsilazane In neat liquid at 30℃; for 1h; Catalytic behavior; Kinetics; Reagent/catalyst; Solvent; Temperature; Schlenk technique; Inert atmosphere; chemoselective reaction;	99%
With silver at 20℃; for 2h;	97%
With palladium In tetrahydrofuran at 20℃; for 4h;	95%

Phenylsilane Chemical Properties

Product Name: Phenylsilane
Molecular Structure:
Molecular Formula : C₆H₅SiH₃
Molecular Weight: 108.21
CAS NO: 694-53-1
EINECS : 211-772-5
Density: 0.877
Boiling point: 120 ºC
Melting point: -64 to -68°C
Flash point: 8 ºC
Enthalpy of Vaporization: 34.27 kJ/mol
Boiling Point: 119.3 °C at 760 mmHg
Vapour Pressure: 19.2 mmHg at 25°C
Refractive index n20/D 1.510(lit.)
Storage temp: Flammables area
Sensitive: Air & Moisture Sensitive
Appearance: Silylbenzene (CAS NO. 694-53-1) is clear colorless liquid

Phenylsilane Uses

Silylbenzene (CAS NO. 694-53-1) is used as organic reagents and pharmaceutical intermediates.

Phenylsilane Toxicity Data With Reference

1.		orl-mus LD50:700 mg/kg		85JCAE Prehled Prumyslove Toxikologie; Organicke Latky Marhold, J.,Prague, Czechoslovakia.: Avicenum,1986,1227.
2.		ihl-mus LC50:14,500 mg/m3/2H		85JCAE Prehled Prumyslove Toxikologie; Organicke Latky Marhold, J.,Prague, Czechoslovakia.: Avicenum,1986,1227.

Phenylsilane Consensus Reports

Reported in EPA TSCA Inventory.

Phenylsilane Safety Profile

Hazard CodesF , Harmful Xn
Risk Statements 11-14-15-20/22-36/37/38
R11:Highly flammable.
R14 :Reacts violently with water.
R15:Contact with water liberates extremely flammable gases.
R20/22:Harmful by inhalation and if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements 16-43
S16:Keep away from sources of ignition.
S43:In case of fire use ... (there follows the type of fire-fighting equipment to be used.)
RIDADR UN 3399 4.3/PG 2
WGK Germany 1
RTECS VV4825000
F 10-21
TSCA Yes
HazardClass 4.3
PackingGroup II

Phenylsilane Specification

1.General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors can travel to a source of ignition and flash back. Will burn if involved in a fire. Water Reactive. Material will react with water and may release a flammable and/or toxic gas. Flammable liquid and vapor.
2.Extinguishing Media: Use foam, dry chemical, or carbon dioxide. DO NOT USE WATER!
3.Handling: Use spark-proof tools and explosion proof equipment. Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Avoid ingestion and inhalation.
4.Storage: Keep Silylbenzene (CAS NO. 694-53-1) away from heat, sparks, and flame. Keep away from sources of ignition. Store in a cool, dry place. Store in a tightly closed container. Keep under a nitrogen blanket. Flammables-area.

Product Name

PHENYLSILANE

Synthetic route

Phenylsilane Chemical Properties

Phenylsilane Uses

Phenylsilane Toxicity Data With Reference

Phenylsilane Consensus Reports

Phenylsilane Safety Profile

Phenylsilane Specification

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