potassium hydrogensulfate
Conditions | Yield |
---|---|
In water byproducts: O2; complete decompn. at room temp. in 3 months; decompn. faster at higher temp.; | 99% |
In water byproducts: O2; complete decompn. at room temp. in 3 months; decompn. faster at higher temp.; | 99% |
With water In sulfuric acid byproducts: O2; react. rate in relation to H2SO4 conc.; |
sulfuric acid
water
A
potassium hydrogensulfate
B
dihydrogen peroxide
Conditions | Yield |
---|---|
In sulfuric acid hydrolysis by heating; simultaneous distn. (by H2O vapor);; distn.; 40-60% aq. soln. of H2O2;; | A n/a B 95% |
In sulfuric acid aq. H2SO4; hydrolysis by heating; simultaneous distn. (by H2O vapor);; distn.; 40-60% aq. soln. of H2O2;; | A n/a B 95% |
In sulfuric acid hydrolysis by heating; simultaneous distn. (by H2O vapor);; distn.;; | A n/a B 92% |
sulfuric acid
water
A
potassium hydrogensulfate
B
dihydrogen peroxide
C
oxygen
D
ozone
Conditions | Yield |
---|---|
In water investigations within the system K2S2O8-H2SO4-H2O at 100 °C, formation of O3 at higher concentrations of H2SO4, mechanism discussed;; |
Conditions | Yield |
---|---|
In sulfuric acid 50-55°C;; 30% aq. soln. of H2O2;; | |
In sulfuric acid aq. H2SO4; 50-55°C;; 30% aq. soln. of H2O2;; |
Conditions | Yield |
---|---|
With sulfuric acid byproducts: SO2, I2; with great amount of concd. H2SO4; | |
With sulfuric acid byproducts: H2S, H2O; with concd. H2SO4; | |
With H2SO4 |
Conditions | Yield |
---|---|
80 °C; cooling to 20 °C; | |
80 °C; cooling to 20 °C; |
Conditions | Yield |
---|---|
With sulfuric acid distn. with concd. H2SO4; | |
With H2SO4 distn. with concd. H2SO4; |
A
potassium hydrogensulfate
B
dinitrogen trioxide
C
Nitrogen dioxide
Conditions | Yield |
---|---|
condensation,distn.; |
Conditions | Yield |
---|---|
With hydrogenchloride In water products pptd. from the cooled soln.;; | |
With HCl In water products pptd. from the cooled soln.;; |
potassium hydrogensulfate
Conditions | Yield |
---|---|
With hydrogenchloride In water satd. soln. of neutral sulfate is distd. with aq. HCl;; | |
With sulfuric acid In melt equiv.; | |
With sulfuric acid In water equiv. ; in soln. of HCl; |
Conditions | Yield |
---|---|
With H2SO4 In hydrogen cyanide |
Conditions | Yield |
---|---|
silver (I) ion In water in alk. soln.; | |
copper(II) ion In water in alk. soln.; | |
cobalt(II) chloride In water in alk. soln.; |
A
manganese(IV) oxide
B
potassium permanganate
C
potassium hydrogensulfate
Conditions | Yield |
---|---|
In water pH above 7-8; different yields depending on temp. and pH; |
acetone
A
potassium hydrogensulfate
B
carbon dioxide
C
acetic acid
Conditions | Yield |
---|---|
With water; silver (I) ion In sulfuric acid Kinetics; | |
With H2O; silver (I) ion In sulfuric acid Kinetics; aq. H2SO4; |
Conditions | Yield |
---|---|
In not given slow react. in neutralic, faster in alkaline soln.; | |
In not given slow react. in neutralic, faster in alkaline soln.; |
Conditions | Yield |
---|---|
In not given in acidic soln.; | |
In not given in acidic soln.; |
Conditions | Yield |
---|---|
With water In water in diluted aq. soln.;; | |
With H2O In water in diluted aq. soln.;; |
Conditions | Yield |
---|---|
With water In water byproducts: H2SO4; neutral soln.; with heating; | |
With H2O In water byproducts: H2SO4; neutral soln.; with heating; |
Conditions | Yield |
---|---|
In water boiling water;; | |
In water boiling water;; |
Conditions | Yield |
---|---|
In solid hydrolysis of K2S2O7 by H2O; |
Conditions | Yield |
---|---|
In neat (no solvent) treating K3VO(SO4)3 with water vapor (150°C); further product: amorphous phase; |
Conditions | Yield |
---|---|
In neat (no solvent) treating K3VO(SO4)3 with water vapor (closed system, 200 - 250°C, 6 h); generating water vapor by annealing sodium sulfate decahydrate in the reaction zone; further product: yellow glass; X-ray phase analysis; |
potassium hydrogensulfate
Conditions | Yield |
---|---|
With sulfuric acid byproducts: HCl; in multiple hearth roaster; | |
With sulfuric acid byproducts: HCl; in a heatable roller; | |
With sulfuric acid byproducts: HCl; molar ratio of educts 1:1; |
A
potassium hydrogensulfate
B
potassium hydroxylamine sulfonate
Conditions | Yield |
---|---|
With water boiling with water or in air; crystn.; |
Conditions | Yield |
---|---|
With potassium hydrogencarbonate In water byproducts: HI; decompn.;; | |
With potassium permanganate; alkali hydroxide In water decompn.;; | |
With I; KHCO3 In water | |
With alkali hydroxide; KMnO4 In water |
potassium hydrogensulfate
Conditions | Yield |
---|---|
With sodium hydroxide In tetrahydrofuran; methanol; water | 99.4% |
potassium hydrogensulfate
tricarbonyl(1-isopropyl-5-methoxy-3,4-dihydronaphthalene)-chromium
Conditions | Yield |
---|---|
In benzene (Ar), refluxed for 1h, poured into NaHCO3; extracted with benzene, washed with brine, dried over MgSO4, solvent evaporated in vac., chromy. (SiO2, ether/hexane); elem. anal., IR, NMR; | 96% |
potassium hydrogensulfate
Conditions | Yield |
---|---|
With barium dihydroxide In methanol; dichloromethane; water under N2; suspn. of Ba(OH)2 in MeOH-H2O added at room temp. to soln. of Fe complex over 5 min; stirred at room temp. for 4 h; acidified with 1 MKHSO4 to pH 1; aq. phase extd. with CH2Cl2; combined org. layers washed with water; dried (Na2SO4); evapd.; purified by column chromy. (silica gel, EtOAc-MeOH 9:1); | 95% |
With lithium hydroxide In methanol; dichloromethane; water under N2; suspn. of LiOH in MeOH-H2O added at room temp. to soln. of Fe complex over 5 min; stirred at room temp. for 4 h; acidified with 1 M KHSO4 to pH 1; aq. phase extd. with CH2Cl2; combined org. layers washed with water; dried (Na2SO4); evapd.; purified by column chromy. (silica gel, EtOAc-MeOH 9:1); | 80% |
potassium hydrogensulfate
(C5H5)Fe(C5H4CH2OC6H4CH2CH(CO2CH3)N(CH2CH2NHC(O)OCH2C6H5)C(O)CH2N2C4H2O2CH3)
(C5H5)Fe(C5H4CH2OC6H4CH2CH(CO2H)N(CH2CH2NHC(O)OCH2C6H5)C(O)CH2N2C4H2O2CH3)
Conditions | Yield |
---|---|
With barium dihydroxide In methanol; dichloromethane; water under N2; suspn. of Ba(OH)2 in MeOH-H2O added at room temp. to soln. of Fe complex over 5 min; stirred at room temp. for 4 h; acidified with 1 MKHSO4 to pH 1; aq. phase extd. with CH2Cl2; combined org. layers washed with water; dried (Na2SO4); evapd.; purified by column chromy. (silica gel, EtOAc-MeOH 9:1); | 95% |
With lithium hydroxide In methanol; dichloromethane; water under N2; suspn. of LiOH in MeOH-H2O added at room temp. to soln. of Fe complex over 5 min; stirred at room temp. for 4 h; acidified with 1 M KHSO4 to pH 1; aq. phase extd. with CH2Cl2; combined org. layers washed with water; dried (Na2SO4); evapd.; purified by column chromy. (silica gel, EtOAc-MeOH 9:1); | 80% |
potassium hydrogensulfate
tert-butyl 4-(hydroxy(pyridin-2-yl)methyl)piperidine-1-carboxylate
methanesulfonyl chloride
tert-butyl 4-((methylsulfonyloxy)(pyridin-2-yl)methyl)piperidine-1-carboxylate
Conditions | Yield |
---|---|
With sodium chloride; sodium hydrogencarbonate; triethylamine In dichloromethane | 94% |
1H-imidazole
potassium hydrogensulfate
(3R,4S)-3-[(S)-1-hydroxypropyl]-1-[(R)-1-phenylethyl]-4-ethynyl-2-azetidinone
tert-butyldimethylsilyl chloride
(3R,4S)-3-[(S)-1-(tert-butyldimethylsilyloxy)propyl]-1-[(R)-1-phenylethyl]-4-ethynyl-2-azetidinone
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide | 93% |
piperidine
potassium hydrogensulfate
methyl ester of (17S)-17-methyl-20-homoisocarbacyclin
(1S,5S,6R,7R)-3-(4-piperidinocarbonylbutyl)-6-[(3S,5S,1E)-3-hydroxy-5-methyl-1-nonenyl]-7-hydroxybicyclo[3.3.0]-2-octene
Conditions | Yield |
---|---|
With nitrogen In toluene | 93% |
potassium hydrogensulfate
methyl-3 hydroxy-3 tetrahydrofuranne
A
2,5-dihydro-3-methyl-furan
B
4-methyl-2,3-dihydrofuran
Conditions | Yield |
---|---|
In 1,3,5-trimethyl-benzene | A n/a B 92.8% |
potassium hydrogensulfate
1-tert-butyl 5-methyl indoline-1,5-dicarboxylate
1-(tert-butoxycarbonyl)-2,3-dihydro-1H-indole-5-carboxylic acid
Conditions | Yield |
---|---|
Stage #1: 1-tert-butyl 5-methyl indoline-1,5-dicarboxylate With lithium hydroxide In tetrahydrofuran; water at 20℃; for 24h; Stage #2: potassium hydrogensulfate In tetrahydrofuran; water | 92% |
potassium hydrogensulfate
Conditions | Yield |
---|---|
In neat (no solvent) sintering (400°C, 30 min), cooling to room temp. (air), addn. of water, stirring (1 h); filtration off, washing (water, alcohol, ether), recrystn. on addn. of K2SO4 (water); elem. anal.; | 90% |
Conditions | Yield |
---|---|
In ethyl acetate | A 78% B 80% |
potassium hydrogensulfate
[Au(SPyCONHCHMeCOOMe)(PPh3)]
[Au(SPyCONHCHMeCOOH)(PPh3)]
Conditions | Yield |
---|---|
Stage #1: [Au(SPyCONHCHMeCOOMe)(PPh3)] With lithium hydroxide In methanol at 20℃; Stage #2: potassium hydrogensulfate In water pH=3 - 4; | 79.5% |
potassium hydrogensulfate
[Au(SPyCONHCH2COOMe)(PPh3)]
[Au(SPyCONHCH2COOH)(PPh3)]
Conditions | Yield |
---|---|
Stage #1: [Au(SPyCONHCH2COOMe)(PPh3)] With lithium hydroxide In methanol at 20℃; Stage #2: potassium hydrogensulfate In water pH=3 - 4; | 76.8% |
potassium hydrogensulfate
6,6-dibromopenicillanic acid
2,2,2-Trichloroethyl chloroformate
Conditions | Yield |
---|---|
With pyridine; sodium chloride; sodium hydrogencarbonate In ethyl acetate | 76% |
potassium hydrogensulfate
methyl 4-(2-nitrophenoxy)phenylacetate
Conditions | Yield |
---|---|
With sodium hydroxide In tetrahydrofuran; methanol; water | 71.8% |
potassium hydrogensulfate
[Au(SPyCONHCHBnCOOMe)(PPh3)]
[Au(SPyCONHCHBnCOOH)(PPh3)]
Conditions | Yield |
---|---|
Stage #1: [Au(SPyCONHCHBnCOOMe)(PPh3)] With lithium hydroxide In methanol at 20℃; Stage #2: potassium hydrogensulfate In water pH=3 - 4; | 71.3% |
4-chloro-2-oxo-1-phenyl-1,2-dihydro-quinoline-3-carboxylic acid ethyl ester
potassium hydrogensulfate
o-toluidine
Conditions | Yield |
---|---|
In chloroform | 69.5% |
potassium hydrogensulfate
[Au(SPyCONHCH(((CH2)2SMe))COOMe)(PPh3)]
[Au(SPyCONHCH(((CH2)2SMe))COOH)(PPh3)]
Conditions | Yield |
---|---|
Stage #1: [Au(SPyCONHCH(((CH2)2SMe))COOMe)(PPh3)] With lithium hydroxide In methanol at 20℃; Stage #2: potassium hydrogensulfate In water pH=3 - 4; | 69.5% |
potassium hydrogensulfate
benzyl bromide
tert-butyl [(1R)-1-(hydroxymethyl)-2-methylpropyl]carbamate
N-TERT-BUTOXYCARBONYL-O-BENZYL-(D)-VALINOL
Conditions | Yield |
---|---|
In water; N,N-dimethyl-formamide | 69% |
In water; N,N-dimethyl-formamide | 69% |
potassium hydrogensulfate
[Au(SPyCO(C4H7N)COOMe)(PPh3)]
[Au(SPyCO(C4H7N)COOH)(PPh3)]
Conditions | Yield |
---|---|
Stage #1: [Au(SPyCO(C4H7N)COOMe)(PPh3)] With lithium hydroxide In methanol at 20℃; Stage #2: potassium hydrogensulfate In water pH=3 - 4; | 68.3% |
potassium hydrogensulfate
Conditions | Yield |
---|---|
byproducts: H2O; heating from 230 °C to 350 °C ; 30-40 mm Hg; | 68% |
byproducts: H2O; heating from 230 °C to 350 °C ; 30-40 mm Hg; | 68% |
heating to red heat; |
Conditions | Yield |
---|---|
With sodium chloride; sodium hydrogencarbonate In tetrahydrofuran | 66% |
potassium hydrogensulfate
tributylphosphine
(4S)-4-tert-butyldimethylsilyloxycyclopent-2-en-1-one
Conditions | Yield |
---|---|
With ammonium chloride; tert.-butyl lithium; sodium hydrogencarbonate In tetrahydrofuran; hexane; dichloromethane | 50% |
Reported in EPA TSCA Inventory.
DOT Classification: 8; Label: Corrosive
The Potassium bisulfate is the potassium salt of bisulfate anion, with the molecular formula KHSO4. It belongs to the product categories of Inorganics; Inorganic Salts; Potassium; Synthetic Reagents. Its EINECS registry number is 231-594-1. With the CAS registry number 7646-93-7, its IUPAC name is called potassium hydrogen sulfate.
Physical properties of Potassium bisulfate: (1)ACD/LogP: -1.03; (2)ACD/LogD (pH 5.5): -5.53; (3)ACD/LogD (pH 7.4): -5.53; (4)ACD/BCF (pH 5.5): 1; (5)ACD/BCF (pH 7.4): 1; (6)#H bond acceptors: 4; (7)#H bond donors: 2; (8)Enthalpy of Vaporization: 62.94 kJ/mol; (9)Boiling Point: 330 °C at 760 mmHg; (10)Vapour Pressure: 3.35E-05 mmHg at 25°C.
Preparation: this chemical can be prepared by K2CO3 and H2SO4. The reaction is as the following:
K2CO3 + H2SO4 → K2SO4↓+CO2↑+H2O
Uses of Potassium bisulfate: This compound is commonly used in the conversion of tartrates to bitartrates in wine. Potassium bisulfate is also used as a disintegrating agent in analytical chemistry.
When you are using this chemical, please be cautious about it as the following:
This chemical may destroy living tissue on contact and may cause burns. In case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice. Whenever you will contact it, please wear suitable protective clothing, gloves and eye/face protection. In case of accident or if you feel unwell seek medical advice immediately (show the label where possible).
You can still convert the following datas into molecular structure:
(1)Canonical SMILES: OS(=O)(=O)[O-].[K+]
(2)InChI: InChI=1S/K.H2O4S/c;1-5(2,3)4/h;(H2,1,2,3,4)/q+1;/p-1
(3)InChIKey: CHKVPAROMQMJNQ-UHFFFAOYSA-M
The toxicity data is as follows:
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
rat | LD50 | oral | 2340mg/kg (2340mg/kg) | Personal Communication from J.V. Marhold, VUOS, 539-18, Pardubice, Czechoslavakia, Mar. 29, 1977Vol. 29MAR1977, |
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