Samarium supplier | CasNO.7440-19-9

Name
Samarium
EINECS 231-128-7
CAS No. 7440-19-9
Article Data54
CAS DataBase
Density 7.47 g/mL at 25 °C(lit.)
Solubility Insoluble in water.
Melting Point 1074 °C(lit.)
Formula Sm
Boiling Point 1794 °C(lit.)
Molecular Weight 150.36
Flash Point
Transport Information
Appearance silvery grey powder
Safety 16-30-33
Risk Codes 11-15-33
Molecular Structure
Hazard Symbols F,R
Synonyms SAMARIUM, PLASMA STANDARD SOLUTION;SAMARIUM SINGLE ELEMENT STANDARD;SAMARIUM STANDARD;SAMARIUM ATOMIC ABSORPTION STANDARD SOLUTION;SAMARIUM, AAS STANDARD SOLUTION;SAMARIUM;SAMARIUM ICP STANDARD;SAMARIUM PLASMA EMISSION SPECTROSCOPY STANDARD
PSA 0.00000
LogP 0.00000

Synthetic route

: samarium(III) oxide

: 7440-19-9
samarium

Conditions

Conditions	Yield
With zirconium In neat (no solvent) reduction by heating the pressesd mixture (99.05 Sm2O3, purity of reducing reagent >99.5%) to 1100-1200°C at maximal 2E-4 Torr, distn. of Sm, Mo-vessel;;;	91%
With lanthanum In neat (no solvent) heating in a Ta-vessel to 1450°C at less than 1E-3 Torr for 30min, distn. of Sm;; purity >98%;;	>80
With aluminium In neat (no solvent) reduction, formation of Al-Sm-alloy;;

: samarium(III) oxide

: 7440-45-1
cerium

A: cerium(III) oxide

B: 7440-19-9
samarium

Conditions

Conditions	Yield
vapor pressure of Sm between 1217 and 1473°K given as equation; optimal conditions: 1200°C, 1E-3 Torr;	A n/a B 90%
in vac.;

...Expand

: samarium(III) nitrate

: 7440-19-9
samarium

Conditions

Conditions	Yield
In ethylenediamine Electrolysis; 150V, 4.4mA/cm**2, 0.37g nitrate in ethylene diamine;;	41%

: samarium(III) oxide

: 7439-91-0
lanthanum

A: lanthanum(III) oxide

B: 7440-19-9
samarium

Conditions

Conditions	Yield
in vac.;

...Expand

: samarium diiodide

: 80937-33-3
oxygen

: 7440-23-5
sodium

A: 7440-19-9
samarium

B: samarium(II,III) oxide iodide

C: 7681-82-5
sodium iodide

Conditions

Conditions	Yield
In melt under Ar in a tantalum ampoule, in Na melt, heating to 650 °C for7 d, oxygen as the contamination of SmI2; cooling in air to room temp., selected under a microscope;

...Expand

: samarium(III) oxide

: 7429-90-5
aluminium

A: 1333-84-2, 1344-28-1
aluminum oxide

B: 7440-19-9
samarium

Conditions

Conditions	Yield
in vac.;

...Expand

: 10361-82-7
samarium(III) chloride

: 7440-19-9
samarium

Conditions

Conditions	Yield
In neat (no solvent) reduction with alkali metal between 200 and 400°C; reversible react. >400°C;;
With calcium In neat (no solvent) byproducts: Zn-Sm-alloy; 400-750°C, steel-tube coated with CaO, booster: ZnCl2;; small amounts of alloy;;	0%
In melt Electrolysis; melting at 8V and 30-40A, electrolysis at very high temperatures and 50-100A;;
In melt eutectic KCl/LiCl-mixture, 800°C, 2A/cm**2; cathode: liquid Cd, formation of an alloy, separation of cathode material by distn.;;
In melt eutectic KCl/LiCl-mixture, 800°C, 2A/cm**2; cathode: liquid Mg, Zn or Cd, formation of an alloy, separation of cathode material by distn.;;

: 10361-82-7
samarium(III) chloride

A: 7440-19-9
samarium

B samarium(II) chloride: samarium(II) chloride

Conditions

Conditions	Yield
With sodium In neat (no solvent) reduction of oxide-free chloride;;	A 0% B n/a
With calcium In neat (no solvent) 400-750°C, steel-tube coated with CaO, booster: I2, sulfur or KClO3;;	A 0% B n/a
With calcium In neat (no solvent) byproducts: CaCl2; reduction under Ar, 550-1000°C;;	A 0% B n/a

: 13765-24-7
samarium(III) fluoride

: 7440-19-9
samarium

Conditions

Conditions	Yield
With lithium In neat (no solvent) byproducts: LiF; reduction in a Ta-vessel under Ar, start of react. at 700°C, cooling within 2-3h, removal of excess Li with H2O, mechanical separation of LiF;;
With LiF; CaF2 In melt Electrochem. Process; electrodeposited onto Ni at 850°C;
With LiF; CaF2 In melt Electrochem. Process; electrodeposited onto Mo at 850°C;	0%

: (Sm((CH3)3CCOCHCOC(CH3)3)3)

A: 7440-19-9
samarium

B: 122031-37-2
2,2,6,6-tetramethyl-3,5-heptadionato ion

Conditions

Conditions	Yield
In gaseous matrix Irradiation (UV/VIS); photodissociation (248 nm) in a buffer gas (N2+CH4), heating of precursor; laser-induced fluorescence;

: 13759-87-0
samarium(III) bromide

: 7440-19-9
samarium

Conditions

Conditions	Yield
With Mg or Ca or Na or K or Al or Ba In neat (no solvent) reduction;;

: samarium(III) nitrate pentahydrate

: 7440-19-9
samarium

Conditions

Conditions	Yield
With alfalfa In water Sonication; pH of alfalfa suspn. in H2O was adjusted to 4, 6, 7 and 8 with biphthalates and phosphates, sonication for 15 min, it is added to Sm-salt soln.,sonication for 20 min, 25 °C for 4 h, centrifuging for 30 min at 2000 rpm standing for 72 h;

: samarium(III) tris(2,2,6,6-tetramethyl-3,5-heptanedionate)

: 7440-19-9
samarium

Conditions

Conditions	Yield
In neat (no solvent) Irradiation (UV/VIS); lanthanide compd. photodissociation by excimer laser irradiation at 248 nm; LIF detection;

: SmPt5

: 7440-19-9
samarium

Conditions

Conditions	Yield
heating under vac. at 1600-1670°C for 30-240 min.;

: samarium(III) oxide

A: 7440-19-9
samarium

B: oxygen

Conditions

Conditions	Yield
vapor of the oxide studied at 1950-2350°K (Knudsen-cell); detected by MS;

: samarium(III) oxide

A: 7440-19-9
samarium

B: samarium(II) oxide

C: oxygen

Conditions

Conditions	Yield
vapor of the oxide studied at 2000-2700°K (Knudsen-cell); detected by MS;
vapor of the oxide studied at 1600-1850°C; detected by MS;
vapor of the oxide studied by MS; detected by MS;

...Expand

: samarium dihydride

: 7440-19-9
samarium

Conditions

Conditions	Yield
In neat (no solvent) byproducts: H2; heating (vac., 5°C/min, 550-800°C); DTA monitoring;

: SmF2

A: 7440-19-9
samarium

B: 13765-24-7
samarium(III) fluoride

Conditions

Conditions	Yield
In neat (no solvent) determination of react.-enthalpy at 298K;;

: samarium(II) sulfide

A: 7440-19-9
samarium

B: Sm3S4

Conditions

Conditions	Yield
Knudsen effusion mass spectroscopy; vaporization of SmS at 1381-2014 ° C;

: 13765-24-7
samarium(III) fluoride

A: 7440-19-9
samarium

B: SmF2

Conditions

Conditions	Yield
With Li or Na or Ca or Ba In neat (no solvent) reduction at higher temp.;;	A 0% B n/a

: samarium monofluoride

A: 7440-19-9
samarium

B: 13765-24-7
samarium(III) fluoride

Conditions

Conditions	Yield
In gas 1187K, Ta-Knudsen-cell; equilibrium;;
In neat (no solvent, gas phase) 1187K, Ta-Knudsen-cell; equilibrium;;

: 7439-91-0
lanthanum

: samarium(III) oxide

A: lanthanum(III) oxide

B: 7440-19-9
samarium

Conditions

Conditions	Yield
vapor pressure of Sm between 1225 and 1473 K given as equation; optimal conditions: 1200°C, 1 h, 1E-3 Torr;

...Expand

: graphite

: samarium(III) oxide

A: 7440-19-9
samarium

B: samarium dicarbide

Conditions

Conditions	Yield
2200 K;

...Expand

samarium oxytelluride: samarium oxytelluride

A: 7440-19-9
samarium

B: tellurium

: samarium(III) oxide

Conditions

Conditions	Yield
In neat (no solvent) byproducts: SmTe, Te2; 1788-1972 K;

...Expand

: 7440-19-9
samarium

: 1,3,5,7-cycloocatetraene

samarium cyclooctatetraenide: samarium cyclooctatetraenide

Conditions

Conditions	Yield
With C2H4I2 In 1,2-dimethoxyethane activation of Sm with C2H4I2 soln. (2h,room temp.), flask cooled to -20°C and charged with cyclooctatetraene , after 2h reaction time the flask was warmed to room temp. and the mixture stirred overnight ; suspension; not isolated , GC anal.;	100%

: 7440-19-9
samarium

: 123-54-6
acetylacetone

: tris(acetylacetonate)samarium(III)

Conditions

Conditions	Yield
In gas vac.-cocondensation (1E-4 mmHg) of Sm (1E-5 mole/h) and acetylacetone ()1E-3 mole/h) vapours on a cooled (to 80 K) glass or copper surface, film, then heating to 130-135 K; pumping off H2, heating to 20°C, sublimation (3h, 1E-2 mmHg);	100%

: 7440-19-9
samarium

: 120-12-7
anthracene

: C14H10Sm

Conditions

Conditions	Yield
With C2H4I2 In 1,2-dimethoxyethane activation of Sm with C2H4I2 soln. (2h,room temp.) , flask cooled to -20°C and charged with anthracene , after 2h reaction time the flask was warmed to room temp. and the mixt. stirred overnight ; suspension; not isolated , GC anal.;	100%

: 7440-19-9
samarium

: 886-65-7, 82598-07-0
1,4-diphenyl-1,3-butadiene

: C6H5(CH)4C6H5Sm

Conditions

Conditions	Yield
With C2H4I2 In 1,2-dimethoxyethane activation of Sm with C2H4I2 soln. (2h,room temp.) , flask cooled to -20°C and charged with 1,4-diphenyl-1,3-butadiene , after 2h reaction time the flask was warmed to room temp. and the mixt. stirred overnight; suspension; not isolated , GC anal.;	100%

: 7440-19-9
samarium

: cyclopentadienylthallium(I)

: tris(cyclopentadienyl)(tetrahydrofuran)samarium(III)

Conditions

Conditions	Yield
With mercury In tetrahydrofuran THF was added by syringe to Sm, Tl(C5H5) and Hg at 0°C for 48 h and then 20°C for 24 h under N2; cooled, filtered, filtrate was evapd. to dryness under vac. at room temp.; elem. anal.;	100%
With mercury In tetrahydrofuran THF was added by syringe to Sm, Tl(C5H5) and Hg at 65°C for 65 hand then 20°C for 24 h under N2; cooled, filtered, filtrate was evapd. to dryness under vac. at room temp.; elem. anal.;	100%
With mercury In tetrahydrofuran; diethyl ether THF and Et2O was added by syringe to Sm, Tl(C5H5) and Hg at 0°C for 48 h and then 20°C for 72 h under N2; cooled, filtered, filtrate was evapd. to dryness under vac. at room temp.; elem. anal.;	80%

: 7440-19-9
samarium

: thallium(I) cyclopentadienide

: mercury

: acetonitriletris(cyclopentadienyl)samarium(III)

Conditions

Conditions	Yield
In acetonitrile byproducts: Tl; the solvent was added by syringe to Sm and Tl(C5H5) under N2, Hg was added, stirred at 82°C for 66 h; followed by evapn. to dryness, recrystd. from MeCN; elem. anal.;	100%

...Expand

: 7440-19-9
samarium

: 1493-13-6
trifluorormethanesulfonic acid

: 67-68-5
dimethyl sulfoxide

: samarium(III) triflate - dimethylsulfoxide (1/9.7)

Conditions

Conditions	Yield
With oxygen In dimethyl sulfoxide metal. Sm under O2 atm. treated with DMSO and triflic acid (3 equiv.) in3 portions, heated at 100°C for 10 h;	99%

...Expand

: 7782-49-2
selenium

: 7440-19-9
samarium

: 12775-96-1, 15158-11-9, 15721-63-8, 16941-75-6, 17493-86-6, 19498-52-3, 20499-83-6, 20499-84-7, 20499-85-8, 20499-86-9, 20573-10-8, 20573-11-9, 21595-51-7, 21595-52-8, 22206-52-6, 26445-28-3, 28959-95-7, 37362-93-9, 39417-05-5, 54603-16-6, 54603-23-5, 54603-32-6, 54603-40-6, 54603-48-4, 54603-81-5, 54603-89-3, 56316-56-4, 95985-91-4, 122297-32-9, 7440-50-8
copper

: CuSm3Se4(Se2)

Conditions

Conditions	Yield
In neat (no solvent) mixt. Cu, Sm, and Se was heated at 973 K for 7 days; product was washed with water and dried in air;	99%

...Expand

: 7440-19-9
samarium

: 7440-31-5
tin

: 7440-02-0
nickel

: Sm2NiSn4

Conditions

Conditions	Yield
In neat (no solvent, solid phase) mixt. of Sm, Ni, Sn loaded into Ta tube, heated at 970°C for 36 h, quenched in water, annealed at 700°C for 15 d;	99%
In neat (no solvent, solid phase) mixt. of Sm, Ni, Sn loaded into Nb tube, heated under dynamic vac. at 300°C for 1 d, heated at 950°C for 5 d, cooled to room temp.at 15°C/h;

...Expand

: 7440-55-3
gallium

: 7440-56-4
germanium

: 7440-19-9
samarium

: Sm3Ga9Ge

Conditions

Conditions	Yield
In melt mixing of Sm, Ga and Ge in ratio Sm:Ga:Ge as 1:15:1 under N2; slowly heating (60°C/h) up to 1000°C; holding at 1000°C for 5h; cooling (75°C/h) to 850°C; holding isothermally for 6 days; cooling to 200°C; hot-temp. span-filtration; treatment with 3 M soln. of I2 in DMF for 12-24 h; rinsing with DMF, hot water, drying with acetone and ether;	99%

...Expand

: 7440-19-9
samarium

: 13765-24-7
samarium(III) fluoride

: 7704-34-9
sulfur

: samarium(III) fluoride sulfide

Conditions

Conditions	Yield
In melt metal:metal fluoride:S molar ratio was 2:1:3, quartz crucible, Nb- or Ta-capsule, several days, 850 °C; equimolar amt. of NaCl was used as flux; NaCl was washed out with water;	99%

...Expand

: 109-99-9
tetrahydrofuran

: 7440-19-9
samarium

: 67-72-1
hexachloroethane

: SmCl3(tetrahydrofuran)2

Conditions

Conditions	Yield
In tetrahydrofuran byproducts: C2Cl4; Sonication; inert atmosphere; mass ratio metal : C2Cl6 = 1 : 3, 30 h; pptn. on pentane addn., decantation, washing (pentane), drying (room temp., dry box); elem. anal.;	99%

...Expand

: 7782-49-2
selenium

: 7440-19-9
samarium

: Cs2Se3

: 7440-66-6
zinc

: CsSmZnSe3

Conditions

Conditions	Yield
With CsI In neat (no solvent) mixt. Sm, Cs2Se3, Zn, Se, and CsI was heated in vacuumated sealed tube to 1273 K in 48 h, kept at 1273 K for 50 h, and cooled a 4 K/h to 473 K; react. mixt. was washed with DMF, water, and acetone;	99%

...Expand

: 7647-01-0
hydrogenchloride

: 7440-19-9
samarium

: 7732-18-5
water

: [Sm(chloride)2(water)6]Cl

Conditions

Conditions	Yield
In hydrogenchloride Schlenk techniques; dissolution Sm in concd. aq. HCl (37%); XRD;	99%

...Expand

: 7440-19-9
samarium

: 7732-18-5
water

: 10035-10-6, 12258-64-9
hydrogen bromide

: samarium(III) bromide hexahydrate

Conditions

Conditions	Yield
In hydrogen bromide aq. HBr; Schlenk techniques; dissolution Sm in concd. aq. HBr (48%); XRD;	99%

...Expand

: 7440-19-9
samarium

: 7732-18-5
water

: 10034-85-2
hydrogen iodide

: [Sm(water)9](I)3

Conditions

Conditions	Yield
In further solvent(s) Schlenk techniques; dissolution Sm in concd. aq. HI (55%); XRD;	99%

...Expand

: 7440-19-9
samarium

: 35342-67-7, 35342-68-8
copper (I) tert-butoxide

A: samarium tert-butoxycuprate

B: 12775-96-1, 15158-11-9, 15721-63-8, 16941-75-6, 17493-86-6, 19498-52-3, 20499-83-6, 20499-84-7, 20499-85-8, 20499-86-9, 20573-10-8, 20573-11-9, 21595-51-7, 21595-52-8, 22206-52-6, 26445-28-3, 28959-95-7, 37362-93-9, 39417-05-5, 54603-16-6, 54603-23-5, 54603-32-6, 54603-40-6, 54603-48-4, 54603-81-5, 54603-89-3, 56316-56-4, 95985-91-4, 122297-32-9, 7440-50-8
copper

Conditions

Conditions	Yield
In 1,2-dimethoxyethane all operations in sealed evacuated tubes with thoroughly dried and degassed solvents; Sm cutting and t-BuOCu stirred at ca. 20° for 35 h; excess of Sm and copper ppt. sepd. by centrifugation; reaction mixt. concd. and kept at 80° until complete dissolution of a finely dispersed ppt.; cooled slowly to 20°; crystals sepd. and dried in vacuo; identified by elem. anal., IR spec.;	A 72.9% B 96%

Yield

In 1,2-dimethoxyethane all operations in sealed evacuated tubes with thoroughly dried and degassed solvents; Sm cutting and t-BuOCu stirred at ca. 20° for 35 h; excess of Sm and copper ppt. sepd. by centrifugation; reaction mixt. concd. and kept at 80° until complete dissolution of a finely dispersed ppt.; cooled slowly to 20°; crystals sepd. and dried in vacuo; identified by elem. anal., IR spec.;

A 72.9%
B 96%

...Expand

: 109-99-9
tetrahydrofuran

: 7440-19-9
samarium

: (η(1)-3,5-diphenylpyrazolato)trimethyltin(IV)

A tris(3,5-diphenylpyrazolato)tris(tetrahydrofuran)samarium(III) - tetrahydrofuran (1/3): tris(3,5-diphenylpyrazolato)tris(tetrahydrofuran)samarium(III) - tetrahydrofuran (1/3)

B: 661-69-8
hexamethyldistannane

Conditions

Conditions	Yield
With Hg In tetrahydrofuran (N2), DME added to excess of Nd metal, Sn complex and 1-2 drops of Hg, stirred at room temp. for 5 d, sonicated for 1 d; filtered, concd., crystd. at -20°C, washed (hexane), dried (vac.), elem. anal.;	A 96% B n/a
With Hg In tetrahydrofuran Sonication; (N2), DME added to excess of Nd metal, Sn complex and 1-2 drops of Hg, sonicated at room temp. for 6 d; filtered, concd., crystd. for a few months, elem. anal.;	A 30% B n/a

...Expand

: 7440-56-4
germanium

: 7782-49-2
selenium

: 7440-19-9
samarium

: Cs2Se2

: CsSmGeSe4

Conditions

Conditions	Yield
In neat (no solvent) mixt. Sm, Ge, Se, and Cs2Se2 was heated to 725°C at a rate of 35°C/h, held at 725°C for 150 h and cooled slowly to room temp. at a rate of 4°C/h; product was washed withDMF for 6 h;	95%

...Expand

: 7440-56-4
germanium

: 7782-49-2
selenium

: 7440-19-9
samarium

: potassium polyselenide

: KSmGeSe4

Conditions

Conditions	Yield
In neat (no solvent) mixt. Sm, Ge, Se, and K2Se2 was heated to 725°C at a rate of 35°C/h, held at 725°C for 150 h and cooled slowly to room temp. at a rate of 4°C/h; product was washed withDMF for 6 h;	95%

...Expand

: 7440-19-9
samarium

: 948-65-2
2-phenyl-indole

: 973-17-1
bis(pentafluorophenyl)mercury(II)

: 119127-33-2
bis(2-phenylindol-1-yl)tetrakis(tetrahydrofuran)samarium(II)

Conditions

Conditions	Yield
In tetrahydrofuran byproducts: C6F5H, Hg; (N2); a mixture of Sm, 2-phenylindole and Hg-compound was stirred at room temp. for 12 h; filtered hot through a Celite pad; evapn. of solvent to dryness; elem. anal.;	94%

...Expand

: 110-86-1
pyridine

: 7440-19-9
samarium

: 20364-76-5
bis(pentafluorophenylmercapto)mercury

A: (pyridine)4Sm(SC6F5)3*0.5(pyridine)

B: mercury

Conditions

Conditions	Yield
In pyridine under N2, Schlenk techniques; Sm and Hg(SC6F5)2 (molar ratio 1:1.5) combined in pyridine; stirred overnight; filtered; filtrate reduced in vol. under vac.; layered with hexane; cooled to 5°C; elem. anal.;	A 35% B 93%

...Expand

: 7440-19-9
samarium

: 1202-34-2
di(pyridin-2-yl)amine

: 881881-76-1
[Sm2(2,2'-dipyridylamide)6]

Conditions

Conditions	Yield
With Hg In neat (no solvent) under inert atmosphere; Sm, ligand and Hg (molar ratio 1:5:1) sealed in evacuated Duran glass ampoule; heated to 180°C for 5.5 h and to 220°C for 2.5 h; held for 168 h; cooled to 90°C for 300 h and to room temp. for 6 h; excess of ligand evapd.; elem. anal.;	91%
With 1,2,3,4-tetrahydroquinoline In neat (no solvent) under inert atmosphere; Sm, ligand and C9H11N (molar ratio 1:3:4) degassed; sealed in evacuated Duran glass ampoule; heated to 180°C for 6 h and to 210°C for 3 h; held for 168 h; cooled to 60°C for 480 h and to room temp. for 6 h; washed with hexane or toluene; elem. anal.;	84%

: 7440-19-9
samarium

: mercury(II) iodide

A: samarium diiodide(tetrahydrofuran)2

B: mercury

Conditions

Conditions	Yield
With tetrahydrofuran In tetrahydrofuran React. of HgI2 with excess Sm under N2 in refluxing THF gives yellow (SmI3) and grey (Hg) suspn. in 0.5 h, a blue-green colour (SmI2) develops, heating (72 h).; Filtn., evapn.;	A 91% B n/a
With tetrahydrofuran In tetrahydrofuran React. of HgI2 with excess Sm under N2 in refluxing THF gives yellow (SmI3) and grey (Hg) suspn. in 0.5 h, ablue-green colour (SmI2) develops, heating (22 h).; Filtn., evapn., elem. anal.;	A 72% B n/a

...Expand

: 7440-19-9
samarium

: thallium(I) cyclopentadienide

: tris(cyclopentadienyl)(pyridine)samarium(III)

Conditions

Conditions	Yield
In pyridine byproducts: Tl; the solvent was added by syringe to Sm and Tl(C5H5) under N2, stirred at 115°C for 15 h; product obtained by evapg. the filtered reaction mixt. to dryness; elem. anal.;	91%
With mercury dichloride In pyridine byproducts: Tl; the solvent was added by syringe to Sm and Tl(C5H5) under N2, HgCl2 was added to the reaction mixt., stirred at 115°C for 18 h; product obtained by evapg. the filtered reaction mixt. to dryness, recrystd. from py/THF; elem. anal.;	53%

: 7440-19-9
samarium

: 1666-13-3
diphenyl diselenide

: mercury

: [(THF)2Sm(SPh)(μ2-SePh)2(μ3-SePh)Hg(SePh)]2

Conditions

Conditions	Yield
In tetrahydrofuran under N2; diphenyl diselenide in THF is added to Eu-Hg; after 4 d filtd., the filtrate is concd., layered with diethyl ethercooled to room temp., elem. anal.;	91%

...Expand

: 7440-19-9
samarium

: 7553-56-2
iodine

samarium (III) iodide: samarium (III) iodide

Conditions

Conditions	Yield
In diethyl ether	91%

: 7440-19-9
samarium

: 948-65-2
2-phenyl-indole

: 973-17-1
bis(pentafluorophenyl)mercury(II)

A: 119127-33-2
bis(2-phenylindol-1-yl)tetrakis(tetrahydrofuran)samarium(II)

B: 363-72-4
Pentafluorobenzene

C: mercury

Conditions

Conditions	Yield
With THF In tetrahydrofuran under N2, 12 h at room temp.; filtered, filtrate evapd. to dryness (vac., room temp.);	A 90% B n/a C n/a

...Expand

Samarium Specification

The Samarium is an organic compound with the formula Sm. The IUPAC name of this chemical is samarium. With the CAS registry number 7440-19-9, it is also named as samario. The product's categories are Inorganics; Catalysis and Inorganic Chemistry; Chemical Synthesis; Metals; Samarium; SamariumMetal and Ceramic Science. Besides, it is a silvery grey powder, which should be stored in a cool and dry place.

Preparation: the metal is often prepared by electrolysis of a molten mixture of samarium(III) chloride with sodium chloride or calcium chloride. Samarium can also be obtained by reducing its oxide with lanthanum. The product is then distilled to separate samarium (boiling point 1794 °C) and lanthanum (b. p. 3464 °C).

Uses of Samarium: one of the most important applications of samarium is in samarium-cobalt magnets, which have a nominal composition of SmCo₅ or Sm₂Co₁₇. They have high permanent magnetization, which is about 10,000 times that of iron and is second only to that of neodymium magnets. However, samarium-based magnets have higher resistance to demagnetization, as they are stable to temperatures above 700 °C. These magnets are found in small motors, headphones, high-end magnetic pickups for guitars and related musical instruments. Another important application of samarium and its compounds is as catalyst and chemical reagent. Samarium catalysts assist decomposition of plastics, dechlorination of pollutants.

When you are using this chemical, please be cautious about it as the following:
It is highly flammable and has danger of cumulative effects. Please keep away from sources of ignition - No smoking. Besides, this chemical contacts with water liberates extremely flammable gases. When you are using it, never add water to this product. Take precautionary measures against static discharges.

You can still convert the following datas into molecular structure:
(1)SMILES: [Sm]
(2)InChI: InChI=1/Sm
(3)InChIKey: KZUNJOHGWZRPMI-UHFFFAOYAI
(4)Std. InChI: InChI=1S/Sm
(5)Std. InChIKey: KZUNJOHGWZRPMI-UHFFFAOYSA-N

Product Name

Samarium

Synthetic route

Samarium Specification

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